OPTICAL CABLE REINFORCEMENT WITH LOW ACIDITY
20230273384 · 2023-08-31
Inventors
- Sergey Vladimirovich Chernykh (Hickory, NY, US)
- Tomasz Kazmierczak (Lodz, PL)
- Martina Petra Richter-Bühling (Neustadt bei Coburg, DE)
Cpc classification
D02G3/02
TEXTILES; PAPER
D07B2801/10
TEXTILES; PAPER
D07B2801/10
TEXTILES; PAPER
D10B2321/0211
TEXTILES; PAPER
D07B1/14
TEXTILES; PAPER
G02B6/4431
PHYSICS
D07B2205/2014
TEXTILES; PAPER
D07B2205/2014
TEXTILES; PAPER
D07B2201/2095
TEXTILES; PAPER
D07B1/147
TEXTILES; PAPER
International classification
Abstract
Embodiments of the disclosure relate to an optical fiber cable. The optical fiber cable includes a cable jacket having an interior surface and an exterior surface. The interior surface defines a central bore extending along a longitudinal axis of the optical fiber cable, and the exterior surface defines an outermost surface of the optical fiber cable. At least one subunit is disposed within the central bore. Each of the at least one subunit includes at least one optical fiber disposed within a buffer tube. A plurality of ultrahigh molecular weight polyethylene (UHMWPE) tensile yarns are positioned around the at least one subunit and extend along the longitudinal axis. A layer of a bedding compound is disposed between the plurality of UHMWPE tensile yarns and the cable jacket.
Claims
1. An optical fiber cable, comprising: a cable jacket comprising an interior surface and an exterior surface, the interior surface defining a central bore extending along a longitudinal axis of the optical fiber cable and the exterior surface defining an outermost surface of the optical fiber cable; at least one subunit disposed within the central bore, each of the at least one subunit comprising at least one optical fiber disposed within a buffer tube; a plurality of ultrahigh molecular weight polyethylene (UHMWPE) tensile yarns positioned around the at least one subunit and extending along the longitudinal axis; and a layer of a bedding compound disposed between the plurality of UHMWPE tensile yarns and the cable jacket.
2. The optical fiber cable of claim 1, wherein the optical fiber cable achieves an a1 rating when tested according to EN 50267-2-3.
3. The optical fiber cable of claim 1, wherein the bedding compound comprises 10 wt% -30 wt% of a polymeric binder and 70 wt% - 85 wt% of a flame-retardant additive.
4. The optical fiber cable of claim 1, wherein the plurality of UHMWPE tensile yarns comprises at least one yarn embedded in the bedding compound.
5. The optical fiber cable of claim 1, wherein gasses evolved from combustion of the plurality of UHMWPE tensile yarns comprises a conductivity of 0.50 .Math.S/mm of less as measured in an aqueous solution according to EN 50267-2-3.
6. The optical fiber cable of claim 1, wherein the optical fiber cable does not comprise aramid yarns.
7. An optical fiber cable, comprising: a cable jacket comprising an interior surface and an exterior surface, the interior surface defining a central bore extending along a longitudinal axis of the optical fiber cable and the exterior surface defining an outermost surface of the optical fiber cable; at least one subunit disposed within the central bore, each of the at least one subunit comprising at least one optical fiber disposed within a buffer tube; and a plurality of tensile yarns disposed within the central bore and around the at least one subunit and extending along the longitudinal axis; wherein the plurality of tensile yarns comprises basalt yarns.
8. The optical fiber cable of claim 7, wherein the plurality of tensile yarns further comprises yarns of at least one other material.
9. The optical fiber cable of claim 8, wherein the yarns of at least one other material comprises at least one of UHMWPE yarns, glass fiber yarns, liquid crystal polymer yarns, low shrink polyester yarns, or carbon fiber yarns.
10. The optical fiber cable of claim 7, wherein the optical fiber cable achieves an a1 rating when tested according to EN 50267-2-3.
11. The optical fiber cable of claim 7, wherein the plurality of tensile yarns does not comprise aramid yarns.
12. A method of manufacturing an optical fiber cable, the method comprising: arranging a plurality of tensile yarns around at least one subunit, each of the at least one subunit comprising at least one optical fiber disposed within a buffer tube, wherein the plurality of tensile yarns comprise at least one of ultra-high molecular weight polyethylene (UHMWPE) yarns or basalt yarns; extruding a cable jacket around the plurality of tensile yarns, the cable jacket comprising an interior surface and an exterior surface, wherein the exterior surface is an outermost surface of the optical fiber cable and wherein the interior surface is arranged facing the plurality of tensile yarns.
13. The method of claim 12, wherein the plurality of tensile yarns are UHMWPE yarns.
14. The method of claim 13, further comprising forming a layer of a bedding compound around the at least one subunit prior to extruding the cable jacket.
15. The method of claim 14, wherein forming the layer of the bedding compound further comprises forming the layer around the plurality of tensile yarns such that the layer is disposed between the interior surface of the cable jacket and the plurality of tensile yarns.
16. The method of claim 14, wherein forming the layer of the bedding compound further comprises embedding the plurality of tensile yarns in the layer of the bedding compound.
17. The method of claim 12, wherein the plurality of tensile yarns comprise the basalt yarns and yarns of at least one other material.
18. The method of claim 17, wherein the yarns of at least one other material comprise yarns of at least one of UHMWPE, glass fiber, liquid crystal polymer, low shrink polyester, or carbon fiber.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0009] The accompanying drawings are included to provide a further understanding and are incorporated in and constitute a part of this specification. The drawings illustrate one or more embodiment(s), and together with the description serve to explain principles and the operation of the various embodiments.
[0010]
[0011]
[0012]
[0013]
[0014]
[0015]
[0016]
[0017]
DETAILED DESCRIPTION
[0018] Referring generally to the figures, various embodiments of an optical fiber cable having low acid gases evolved during combustion are provided. The optical fiber cable includes tensile elements made from ultra-high molecular weight polyethylene (UHMWPE) and/or basalt yarns. As compared to conventional tensile elements made from aramid yarns, the yarns of the tensile elements included in the presently disclosed optical fiber cables produce gasses during combustion that have a lower conductivity, allowing the optical fiber cable to achieve an a1 rating according to EN 50267-2-3. Advantageously, the UHMWPE and basalt yarns provide enhanced mechanical properties and are relatively less expensive than aramid yarns. Further, despite the relatively lower operational temperature of UHMWPE yarns, embodiments of the optical fiber cables include a layer of a bedding compound that allows for the cable jacket of the optical fiber cable to be extruded around the UHMWPE yarns without degrading the mechanical properties of the UHMWPE yarns. Each of these exemplary embodiments will be described in greater detail below, and these exemplary embodiments are provided by way of illustration, and not by way of limitation. These and other aspects and advantages will be discussed in relation to the embodiments provided herein.
[0019]
[0020] A plurality of tensile yarns 20 are arranged around the subunits 12. As will be discussed more fully below, the tensile yarns 20 are comprised of yarns of at least one of ultra-high molecular weight polyethylene (UHMWPE) or basalt. These yarns produce gasses during combustion that exhibit reduced conductivity in an aqueous solution as compared to conventionally used aramid yarns. Further, the mechanical properties of tensile yarns 20 made of UHMWPE or basalt are not substantially reduced and are, in some cases, improved over the mechanical properties of conventional aramid tensile yarns. In the embodiment depicted in
[0021] In embodiments, the tensile yarns 20 are surrounded by a layer of a bedding compound 22, which is surrounded by a cable jacket 24. In embodiments, the layer of bedding compound 22 has a thickness of up to 5 mm (e.g., 0.1 mm to 5 mm). The cable jacket 24 includes an interior surface 26 and an exterior surface 28. The interior surface 26 defines a central bore 30 along a longitudinal axis of the optical fiber cable 10. The subunits 12, central strength member 14, tensile yarns 20, and bedding compound 22 (collectively, the cable core 32) are contained within the central bore 30 of the cable jacket 24. As shown in
[0022] In embodiments, the cable jacket 24 comprises at least one of high-density polyethylene (HDPE), medium density polyethylene (MDPE), linear low density polyethylene (LLDPE), a flame retardant non-corrosive material, or a low smoke, zero halogen material, among others. In fabricating the optical fiber cable 10, the cable jacket 24 may be extruded over the cable core 32, which requires the material of the cable jacket 24 to be extruded in a molten state at a relatively high temperature (e.g., over 200° C.). These temperatures do not affect basalt fibers in the tensile yarns 20, but UHMWPE has a melting temperature of about 134° C. Accordingly, tensile yarns 20 made of UHMWPE fibers should be prevented from reaching or remaining at that temperature for an extended period of time. This can be accomplished by providing a thermal insulation barrier between the tensile yarns 20 and the cable jacket 24. In this regard, the previously-mentioned bedding compound 22 provides thermal insulation between the cable jacket 24 and the tensile yarns 20 to prevent the tensile yarns 20 from reaching or remaining at or above their melting temperature for an extended period of time while the cable jacket 24 cools on the cable processing line.
[0023] The bedding compound 22 is a layer of a highly-filled polymer material. In particular embodiments, the bedding compound 22 is comprised of 70% to 85% by weight of a mineral-based flame-retardant additive, such as aluminum trihydrate or magnesium hydroxide. In embodiments, a portion of the mineral-based flame-retardant additive may be substituted with calcium carbonate. The polymer binder of the bedding compound 22 is comprised of 10% to 30% by weight of a thermoplastic blend of polyolefin elastomers (e.g., EVA, EBA, EMA, EPR, EPDM rubber, and/or styrene-ethylene/butylene-styrene (SEBS)) or polyolefins (e.g., low density polyethylene (LDPE), linear low density polyethylene (LLDPE, and/or polypropylene (PP)). The bedding compound 22 may also comprise a coupling system, such as a maleic acid anhydride-grafted polyolefin, a vinyl-silane, or an aminosilane, in an amount of 0.5% to 4% by weight. Further, the bedding compound 20 may include thermal stabilizers, antioxidants, and or processing additives in the amount of 0.1% to 1.0% each. In embodiments, the bedding compound 22 has a density of 1.7 g/cm.sup.3 or greater.
[0024] As can be seen in
[0025] As mentioned above, the optical fiber cables 10 including tensile yarns 20 as disclosed herein evolve combustion gasses having lower conductivity and a similar acidity in solution when compared to conventional cables having aramid tensile yarns. The acidity and conductivity of the gasses evolved from combustion of an optical fiber cable 10 as measured in an aqueous solution are relevant in terms of its burn performance according to EN 50267-2-3 (IEC 60754-2). In particular, EN 50267-2-3 sets forth the test method and procedure for determining the degree of acidity of gases evolved during the combustion of the optical fiber cable based on a weighted average of pH and conductivity of the combustion gasses of the constituent materials as measured in an aqueous solution. Table 1, below, provides an example calculation based on a conventional cable having aramid tensile yarns.
TABLE-US-00001 Acidity Calculation for Combustion Gasses of a Cable having Aramid Yarns Constituent Material kg/km pH value Conductivity (.Math.S/mm) pH Weighted Value Conductivity Weighted Value Optical Fiber Glass 0.16 6.0 0.8 1.6 × 10.sup.-7 0.1 Tensile Yarns Aramid 0.50 6.6 17.4 1.3 × 10.sup.-7 8.8 Cable Jacket FRNC 2.39 5.1 0.6 1.9 × 10.sup.-5 1.4 Total: 3.05 1.9 × 10.sup.-5 10.3
[0026] The acronym “FRNC” in Table 1 refers to a flame retardant, non-corrosive jacket material. The cable included three aramid yarns (1680 dtex). From the data in the table, the pH weighted value for the cable is about 5.2 (-log(1.9 × 10.sup.-5/3.05)), and the conductivity weighted value is about 3.38 .Math.S/mm (10.3/3.05), which is higher than allowed for an a1 rating.
[0027] As shown in Tables 2 and 3, below, using UHMWPE or basalt yarns does not increase the pH weighted value, but the conductivity weighted value is substantially decreased. In particular, both the cables having the UHMWPE and basalt tensile yarns maintained the pH weighted value of about 5.2, but both cables also exhibited a conductivity weighted value of about 0.5 .Math.S/mm. The cable in Table 2 included three UHMWPE yarns, and the cable in Table 3 included six basalt yarns.
TABLE-US-00002 Acidity Calculation for Combustion Gasses of a Cable having UHMWPE Yarns Constituent Material Kg/km pH value Conductivity (.Math.S/mm) pH Weighted Value Conductivity Weighted Value Optical Fiber Glass 0.16 6.0 0.8 1.6 × 10.sup.-7 0.1 Tensile Yarns UHMWPE 1.08 5.2 0.34 6.8 × 10.sup.-6 0.4 Cable Jacket FRNC 2.39 5.1 0.6 1.9 × 10.sup.-5 1.4 Total: 3.63 1.9 × 10.sup.-5 1.9
TABLE-US-00003 Acidity Calculation for Combustion Gasses of a Cable having Basalt Yarns Constituent Material Kg/km pH value Conductivity (.Math.S/mm) pH Weighted Value Conductivity Weighted Value Optical Fiber Glass 0.16 6.0 0.8 1.6 × 10.sup.-7 0.1 Tensile Yarns Basalt 0.90 5.7 0.2 1.8 × 10.sup.-6 0.2 Cable Jacket FRNC 2.39 5.1 0.6 1.9 × 10.sup.-5 1.4 Total: 3.63 1.9 × 10.sup.-5 1.7
[0028] According to EN 50267-2-3, a cable can be rated a1, a2, or a3. A cable with an a1 rating produces combustion gasses having a conductivity in aqueous solution of less than 2.5 .Math.S/mm and a pH of greater than 4.3. A cable with an a2 rating produces combustion gasses having a conductivity in aqueous solution of less than 10 .Math.S/mm and a pH of greater than 4.3, and a cable with an a3 rating is unable to meet the requirements of a1 or a2. Here, the cable having the aramid tensile yarns is only able to achieve an a2 rating, whereas both of the cables having the UHMWPE and basalt tensile yarns are able to achieve the more stringent a1 rating.
[0029] Advantageously, the enhanced acidity properties do not come at the expense of the mechanical and thermal properties of the tensile yarns. Table 4, below, lists mechanical properties of the UHMWPE and basalt fiber yarns in comparison to conventional aramid yarns. UHMWPE fibers have generally a higher tensile modulus, a higher tensile strength, and a higher elongation at break than aramid fibers. The mechanical properties of basalt fibers substantially overlap with those of aramid fibers in terms of tensile modulus, tensile strength, and elongation at break.
TABLE-US-00004 Mechanical properties of Tensile Yarns by Material Material UHMWPE Basalt Aramid Tensile Modulus GPa 109-132 85-100 70.5-112.4 g/den 1267-1552 555-885 N/tex 112-137 49-78.1 Tensile Strength GPa 3.3-3.9 1.8-3.1 2.92-3.0 g/den 38-45 23 N/tex 3.4-4.0 2.03-2.08 Elongation at Break (%) 3-4 2.5-3.5 2.4-3.6
[0030] With respect to thermal properties, basalt fibers have a significantly greater operational temperature range than aramid fibers. Basalt fibers can be used continuously at temperatures up to 460° C. and can operate for short durations at temperatures up to 1000° C. Aramid fibers, by comparison, have a continuous operation range of about 150° C. to 170° C. and a maximum short term operational temperature of up to about 200° C.
[0031] In order to enhance the mechanical properties of basalt yarns, the basalt yarns, in embodiments, are incorporated into composite yarns with at least one other non-aramid yarn. Example yarns for the composite strand are comprised of at least one of UHMWPE, glass fiber, liquid crystal polymer (LCP), low shrink polyester, or carbon fiber. In embodiments, the composite yarns are in the form of at least one of interplay hybrids, intermingled hybrids, selective placement hybrids, and super-hybrid composites. Table 5, below, provides a list of the mechanical properties of certain materials that can be used to form a composite yarn with basalt.
TABLE-US-00005 Mechanical and Thermal Properties of Fibers for Basalt Composite Yarns Material Glass Fiber LCP Carbon Fiber Tensile Modulus GPa 70-75 75-100 230-600 Tensile Strength GPa 2.2-2.4 3.0-3.2 3.3-3.5 g/den 6-9 23-30 23-50 Elongation at Break (%) 3.5-5.5 2.8-3.8 3.3-3.5 Max. Service Temp. (°C) 380 150 500 Conductivity (.Math.S/mm) 0.14 1.3 -- pH 6.0 5.0 --
[0032] As mentioned above, basalt yarns 20 are not expected to experience any issues during normal processing as a result of cable jacket extrusion. However, as discussed above, the UHMWPE fibers have a melting point below the temperature at which the cable jacket is typically extruded. In order to simulate the effect of processing on the UHMWPE tensile yarns 20, the yarns 20 were tested for the mechanical properties of elongation at break, breaking tenacity (tensile strength), and tensile modulus before and after annealing treatments. The measured property referenced in the following discussion represents the average value for the specimens tested.
[0033] The elongation at break before annealing was about 3.75%. After annealing at 60° C. for fifteen minutes, the elongation at break was still about 3.7%. When subjected to an annealing treatment at 120° C. for fifteen minutes, elongation at break only decreased to 3.5%. Thus, when exposed to an annealing treatment to simulate processing conditions, the UHMWPE yarns did not exhibit a substantial decrease in elongation at break.
[0034] The breaking tenacity (tensile strength) was tested in a similar manner with samples being tested before an annealing treatment and after two separate annealing treatments. Prior to annealing, the UHMWPE yarns exhibited a breaking tenacity of about 2950 mN/tex. After annealing at 60° C. for fifteen minutes, the breaking tenacity increased to about 3150 mN/tex, and after annealing at 120° C. for fifteen minutes, the breaking tenacity was about 3000 mN/tex. Thus, the temperatures associated with processing of the UHMWPE yarns tend to increase the mechanical property of breaking tenacity.
[0035] The tensile modulus was also tested in the before and after annealing conditions. Prior to annealing, the UHMWPE yarns exhibited a tensile modulus of about 95 N/tex. After annealing at 60° C. for fifteen minutes, the tensile modulus of the UHMWPE yarns increased to about 100 N/tex, and after annealing at 120° C. for fifteen minutes, the tensile modulus only decreased to about 99 N/tex, which was more than the initial, unannealed tensile modulus.
[0036] Having demonstrated through simulated processing that the properties of the UHMWPE yarns can be maintained at the temperatures associated with cable jacket extrusion, the UHMWPE yarns were incorporated into an optical fiber cable. The optical fiber cable 10 constructed using the UHMWPE yarns is shown in
[0037] In order to confirm that the mechanical properties of the UHMWPE yarns were not substantially diminished as a result of the processing conditions, the UHMWPE yarns were removed from the optical fiber cable 10 and tested to determine the properties of elongation at break, breaking tenacity (tensile strength), and tensile modulus according to the same procedure described above with respect to the specimens tested before and after the annealing treatments. The elongation at break for the UHMWPE yarns removed from the cable 10 was about 4.3%. The breaking tenacity was about 2700 mN/tex, and the tensile modulus was about 70 N/tex. Thus, after processing, the UHMWPE yarns exhibited an elongation at break in line with what was predicted from the simulations. The breaking tenacity and tensile modulus were lower than what was predicted from the simulation, but the measured values were still within an acceptable range to act as tensile yarns 20.
[0038] The UHMWPE tensile yarns 20 and/or basalt tensile yarns 20 can be incorporated into a variety of other optical fiber cable 10 constructions as shown in
[0039] Referring first to
[0040] The embodiment depicted in
[0041] The embodiment depicted in
[0042] The embodiments depicted in
[0043]
[0044] In each of these embodiments, the tensile yarns 20 includes at least one UHMWPE yarns or basalt yarns, and the tensile yarns 20 do not include aramid yarns. In particular, the embodiments without a layer of bedding compound 22 (e.g., as shown in
[0045] Unless otherwise expressly stated, it is in no way intended that any method set forth herein be construed as requiring that its steps be performed in a specific order. Accordingly, where a method claim does not actually recite an order to be followed by its steps or it is not otherwise specifically stated in the claims or descriptions that the steps are to be limited to a specific order, it is in no way intended that any particular order be inferred. In addition, as used herein, the article “a” is intended to include one or more than one component or element, and is not intended to be construed as meaning only one.
[0046] It will be apparent to those skilled in the art that various modifications and variations can be made without departing from the spirit or scope of the disclosed embodiments. Since modifications, combinations, sub-combinations and variations of the disclosed embodiments incorporating the spirit and substance of the embodiments may occur to persons skilled in the art, the disclosed embodiments should be construed to include everything within the scope of the appended claims and their equivalents.