ELECTRONIC FUSE (E-FUSE) WITH DISPLACEMENT-PLATED E-FUSE TERMINALS
20220165530 · 2022-05-26
Assignee
Inventors
Cpc classification
H01L21/76849
ELECTRICITY
H01L21/76805
ELECTRICITY
H01L23/5256
ELECTRICITY
International classification
Abstract
An electronic fuse (e-fuse) module may be formed in copper interconnect in an integrated circuit device. A pair of e-fuse terminals may be formed by forming a pair of spaced-apart e-fuse terminal structures (e.g., copper damascene structures) and forming a conductive barrier region on each e-fuse terminal structure. The barrier regions may be formed by displacement plating a conductive barrier layer, e.g., comprising CoWP, CoWB, Pd, CoP, Ni, Co, or Ni—Co alloy, on each e-fuse terminal structure. An e-fuse element, e.g., comprising NiCr, TiW, TiWN, or Al, may be formed on the barrier regions of the pair of e-fuse terminals to define a conductive path between the pair of e-fuse terminal structures through the e-fuse element and through the barrier region on each e-fuse terminal structure. The barrier regions may protect the e-fuse terminal structures (e.g., copper structures) from corrosion and/or diffusion.
Claims
1-11. (canceled)
12. An integrated circuit structure, comprising: an electronic fuse (e-fuse) module, comprising: a pair of spaced-apart e-fuse terminals spaced apart from each other in a dielectric region, each of the e-fuse terminals comprising: an e-fuse terminal structure formed in the dielectric region; and a barrier region at a top of the e-fuse terminal structure; an e-fuse element formed on the pair of spaced-apart e-fuse terminals to define a conductive path between the pair of e-fuse terminal structures through the e-fuse element and through the barrier region at the top of each metal e-fuse terminal structure.
13. The integrated circuit structure of claim 12, wherein the barrier region at the top of each e-fuse terminal structure comprises a displacement-plated barrier region.
14. The integrated circuit structure of claim 12, wherein the barrier region at the top of each e-fuse terminal structure comprises cobalt tungsten phosphide (CoWP).
15. The integrated circuit structure of claim 12, wherein the e-fuse terminal structures each comprise copper damascene structures.
16. The integrated circuit structure of claim 12, wherein the e-fuse element fully covers a top area of each e-fuse terminal.
17. The integrated circuit structure of claim 12, wherein the e-fuse element covers only a partial portion of a top area of each e-fuse terminal.
18. The integrated circuit structure of claim 12, wherein the e-fuse film includes (a) a pair of terminal regions, each covering a top area of one of the e-fuse terminals and (b) a connecting region connecting the pair of terminal regions, the connecting region having a smaller width than a width of each of the terminal regions.
19. An integrated circuit structure, comprising: an electronic fuse (e-fuse) module comprising: a pair of spaced-apart e-fuse terminals, each comprising: an e-fuse terminal structure formed in a first metal layer; and a barrier region formed on the e-fuse terminal structure; and an e-fuse element formed on the pair of spaced-apart e-fuse terminals to define a conductive path connecting the pair of e-fuse terminal structures through the e-fuse element and through the barrier region formed on each e-fuse terminal structure; and an interconnect structure comprising: an interconnect element formed in the first metal layer; and a barrier region formed on the interconnect element.
20. The integrated circuit structure of claim 19, wherein the barrier region formed on each e-fuse terminal structure and the barrier region formed on the interconnect trench element each comprise a displacement-plated barrier region.
21. The integrated circuit structure of claim 19, wherein the barrier region formed on each e-fuse terminal structure and the barrier region formed on the interconnect trench element each comprise cobalt tungsten phosphide (CoWP).
22. The integrated circuit structure of claim 19, wherein the pair of e-fuse terminal structures and the interconnect trench element comprise copper damascene structures.
23. The integrated circuit structure of claim 19, further comprising an e-fuse film region formed on the barrier region formed on the interconnect trench element and spaced apart from the e-fuse element, wherein the e-fuse film region and the e-fuse element are formed from a common e-fuse film.
24. The integrated circuit structure of claim 19, wherein the e-fuse element comprises NiCr, TiW, TiWN, or Al.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0033] Example aspects of the present disclosure are described below in conjunction with the figures, in which:
[0034]
[0035]
[0036]
[0037]
[0038] It should be understood that the reference number for any illustrated element that appears in multiple different figures has the same meaning across the multiple figures, and the mention or discussion herein of any illustrated element in the context of any particular figure also applies to each other figure, if any, in which that same illustrated element is shown.
DETAILED DESCRIPTION
[0039] Embodiments of the present disclosure provide e-fuse modules formed in copper interconnect. In some embodiments, an e-fuse module incudes a pair of e-fuse terminals each including an e-fuse terminal structure (e.g., copper damascene structure) and a barrier region formed on top of the e-fuse terminal structure (e.g., to protect the metal from corrosions and/or diffusion), where the barrier region is conductive, and an e-fuse element formed on and bridging the conductive barrier regions, to thereby conductively connect the e-fuse terminal structures to each other.
[0040] Statements and references herein regarding a displacement-plated barrier region providing protection against copper corrosion and diffusion mean the displacement-plated barrier region provides at least a partial barrier against copper corrosion and diffusion. For example, the disclosed displacement-plated barrier regions may provide functional reliability for the relevant device (e.g., e-fuse module or device including the e-fuse module) over a 10 year period at normal device operating temperatures (−40° C. to 125° C.).
[0041] In some embodiments the barrier regions are formed by displacement plating a barrier material on each e-fuse terminal structure to define a pair of displacement-plated e-fuse terminals, and the e-fuse element is formed on the pair of displacement-plated e-fuse terminals. Each displacement-plated e-fuse terminal may include a displacement-plated barrier region formed on a copper e-fuse terminal structure, e.g., a Cu damascene trench structure formed in a Cu interconnect layer. The e-fuse element formed on the displacement-plated e-fuse terminals provide a conductive path connecting the pair of Cu e-fuse terminal structures through the e-fuse element and through the displacement-plated barrier regions. The barrier regions may both (a) provide a conductive contact between the e-fuse element and e-fuse terminal structures and (b) protect upper surfaces of the e-fuse terminal structures during the manufacture of the e-fuse module. In some embodiments the barrier region may comprise CoWP, CoWB, Pd, CoP, Ni, Co, Ni—Co alloy, or any other suitable material. Although the present disclosure focuses on embodiments formed in Cu interconnect, in other embodiments the e-fuse module may be formed in damascene interconnect of other metals, for example iridium (Ir), rhodium (Rh), ruthenium (Ru), or cobalt (Co).
[0042] In other embodiments, the barrier regions on the e-fuse terminal structures may be formed by another process. For example, a layer of barrier material (e.g., Ta/TaN) may be deposited over the pair of e-fuse terminal structures and etched to define a discrete barrier region on each e-fuse terminal structure.
[0043]
[0044] E-fuse terminals 206 and lower interconnect structure 208 may each comprise a trench element 210, which trench element 210 may be formed of Cu, formed in a common metal interconnect layer M.sub.x (where x refers the level of interconnect metal in the IC structure 200), at any depth in the IC structure 200. In some embodiments, e.g., where the e-fuse module 202 is used for programming by a group of transistors, it may be beneficial to form the e-fuse module 202 as close as possible to the transistors, to drive the required program current (e.g., 1-10 mA) to “burn” the e-fuse element without causing negative side effects, for example voltage drop due to interconnect resistance, Joule heating, or electromigration. Thus, in some embodiments the e-fuse terminals 206 may be formed in the metal 1 layer (x=1) or metal 2 layer (x=2).
[0045] In particular, the trench elements 210 define a pair of e-fuse terminal structures 211, and a lower interconnect element 212. Each trench element 210 may be formed over a barrier layer 214 (e.g., a Ta/TaN bilayer) deposited in a respective trench formed in a dielectric region 215. In some embodiments, the trench elements 210 may be formed by a Cu damascene process in which the barrier layer material (e.g., Ta/TaN bilayer), followed by copper, are deposited and plated over the dielectric region 215 and extending down into the trench openings formed in the dielectric region 215, followed by a chemical mechanical polishing (CMP) process to remove unwanted copper at the top of the structure.
[0046] The e-fuse terminals 206 and lower interconnect structure 208 may be formed over and electrically connected to various IC circuitry 205, e.g., including transistors and programming control circuitry, by respective contact vias 209 formed prior to the e-fuse terminal structures 211 and lower interconnect structure 208.
[0047] As shown, a barrier region 216, which is conductive and thus may be referred to as “conductive barrier region 216,” may be formed on each trench element 210. In some embodiments, barrier regions 216 may be formed by displacement plating a top surface of each trench element 210 (e.g., after the CMP discussed above) with a conductive material at the top of each trench element 210, in which case barrier region 216 may be referred to as “displacement-plated barrier region 216.” For example, a barrier region 216 of CoWB, Pd, CoP, Ni, Co, Ni—Co alloy, or any other suitable metal may be displacement-plated on each trench element 210 (e.g., Cu damascene trench element).
[0048] In other embodiments, barrier regions 216 may be formed by depositing a layer of conductive barrier material over the pair of e-fuse terminal structures and etching the barrier material layer to define a discrete barrier region 216 on each e-fuse terminal structure, in which case barrier region 216 may be termed “discrete barrier region 216.” The conductive barrier material may comprise any conductive material suitable to prevent or inhibit corrosion and/or diffusion of the underlying e-fuse terminal structures (e.g., Cu damascene structures), for example, Ta/TaN, TiN, or TiW.
[0049] The barrier regions 216 formed on e-fuse terminal structures 211 define a conductive path between the e-fuse element 222 and the Cu e-fuse terminal structures 211, as indicated by the double-headed arrow CP in
[0050] In addition, the barrier regions 216 may protect each trench element 210 during and after the remaining construction of the e-fuse module 202 and interconnect structure 204, e.g., to prevent or reduce corrosion and/or diffusion of trench elements 210, which may be important for the resulting reliability of the e-fuse module 202 and interconnect structure 204. Thus, the barrier regions 216 may be formed from material(s) suitable for both (a) providing an effective electrical contact (e.g., having a contact resistance less than 1 ohm) between the e-fuse element 222 and e-fuse terminal structures 211 and (b) protecting trench elements 210 (including e-fuse terminal structures 211 and lower interconnect element 212) from corrosion and diffusion (e.g. copper corrosion and copper diffusion), e.g., during and after the manufacturing of the IC structure 200. For example, the barrier regions 216 may provide a device reliability of over 10 years under normal operating conditions (e.g., normal operating temperatures). In some embodiments, the barrier regions 216 may comprise CoWP, found to be particularly suitable for the properties discussed above. Other suitable materials for the barrier region 216 may include CoWB, Pd, CoP, Ni, Co, Ni—Co alloy, or other suitable material.
[0051] Barrier regions 216 may be formed with a specified or target thickness, whether formed by displacement plating or by a deposition and etch process as disclosed above. For example, barrier regions 216 may be formed with a thickness that is (a) sufficiently thick to provide an effective barrier against corrosion and/or diffusion and also to allow effective control of the plating/deposition process for barrier regions 216, but (b) relatively thin relative to the underlying trench elements 210, as the barrier regions 216 are typically less conductive than the underlying trench elements 210 (e.g., copper) and may thus reduce the effectiveness of the various conductive components, e.g., interconnect structure 204. Thus, in some embodiments, barrier regions 216, whether formed by displacement plating or by a deposition and etch process as disclosed above, may be formed with a vertical thickness in the range of 100 Å-300 Å, for example about 200 Å.
[0052] As discussed in more detail below, the e-fuse element 222 may be formed by (a) depositing an e-fuse film 220, e.g., comprising NiCr, TiW, TiWN, or Al, over the e-fuse terminals 206 and lower interconnect structure 208, and (b) patterning the e-fuse film 220 to define (i) the e-fuse element 222 bridging the e-fuse terminals 206 and (ii) an e-fuse film region 224 over the lower interconnect structure 208. An e-fuse cap 230 (e.g., comprising silicon nitride or silicon oxide) may be formed over the e-fuse film 220, and an optional dielectric barrier layer 234 may be formed over the e-fuse cap. The dielectric barrier layer 234 may be optional, e.g., depending on (a) the suitability of underlying layers (including the barrier regions 216) to act as a copper diffusion barrier, (b) etch stop requirements for building the next level of interconnect structure, as defined by the particular design specification, and/or other relevant considerations. For example, in some embodiments e-fuse cap 230 is formed from SiN and provides an additional copper diffusion barrier and etch stop layer, such that the dielectric barrier layer 234 may be omitted.
[0053] Lower interconnect structure 208 may connect to interconnect circuitry in other metal layer(s). For example, in the example shown in
[0054] In some embodiments, e-fuse element 222 may comprise NiCr, TiW, TiWN, or Al with a thickness in the range of 50 Å-1000 Å, which may provide a sheet resistance Rs in the range of 10-1000 Ω/square. In the low resistance state, the e-fuse element 222 may have a resistance in the range of 100 ohms to 1,000 ohms, e.g., about 500 ohms, and in the high resistance state a resistance in the range of 100 Ω/and 100 MΩ, e.g., about 1 MΩ. In some embodiments, the e-fuse module may have a resistance in the range of 300-500Ω in the low resistance state, and a resistance of greater than 1 MΩ in the high resistance state.
[0055] Although metal layers M.sub.x and M.sub.x+1 may comprise copper as discussed above, in other embodiments metal layer M.sub.x and/or M.sub.x+1 (and thus trench elements 210 and/or upper interconnect element 242) may be formed from other metal(s), for example Iridium (Ir), Rhodium (Rh), Ruthenium (Ru), or Cobalt (Co). The various barrier layers, e.g., barrier regions 216, the optional dielectric barrier layer 234, and/or dielectric barrier layer 246 may be adjusted accordingly, i.e. the constituent elements thereof, based on the selected interconnect metal.
[0056]
[0057] As shown in
[0058] Each trench element 310 may be formed over a barrier layer 320 (e.g., a Ta/TaN bilayer) deposited in a respective trench opening. In one embodiment, the trench elements 310 may be formed by a Cu damascene process in which Cu is deposited over dielectric region 312 and extends down into trench openings formed in dielectric region 312, followed by CMP process to remove unwanted Cu at the top of the structure. Dielectric region 312 may include one or more dielectric materials, e.g., at least one silicon oxide, fluorosilicate glass (FSG), organosilicate glass (OSG), porous OSG, or other low-k dielectric material, e.g., having a dielectric constant less than 4.
[0059] After the CMP process, an exposed top surface 325 of each trench element 310 is typically susceptible to oxidation, for example from the oxygen in the air, moisture in the air, or water residue left from a post CMP clean. Exposure to light may further accelerate such oxidation or corrosion process. Such corrosion can result in yield loss and reliability failure of the resulting IC device. Thus, it may be beneficial to protect the upper surface of each trench element 310 soon after the CMP to reduce this corrosion risk.
[0060] Thus, as shown in
[0061] In other embodiments, barrier regions 324 may be formed by depositing a layer of conductive barrier material over the structure, thus covering the top surfaces 325 of trench elements 310 and top surfaces of dielectric region 312, and etching the barrier material layer (e.g., at locations between the various trench elements 310) to define a discrete barrier region 325 on each trench element 310 (including each e-fuse terminal structure 314 and lower interconnect element 316). The conductive barrier material may comprise any conductive material suitable to prevent or inhibit corrosion and/or diffusion of the underlying trench elements 310 (e.g., Cu damascene structures), for example, Ta/TaN, TiN, or TiW.
[0062] The barrier region 324 formed at the top of each trench element 310 may (a) protect the top surface 325 of the trench element 310 from copper corrosion, e.g., during construction of the e-fuse module 302 and interconnect structure 304, and (b) reduce diffusion from the trench element 310, e.g., into underlying or neighboring silicon, which may improve reliability performance. In addition, the barrier regions 324 formed on each e-fuse terminal structure 314 may provide an effective electrical contact (e.g., contact resistance of less than 1 ohm) between the respective e-fuse terminal structure 314 and an overlying e-fuse element 330a (discussed below).
[0063] Using a displacement plating process to form barrier regions 324 on each trench element 310, as disclosed above, allows for selective formation of a metal diffusion barrier on each trench element 310, but not on the areas of dielectrics region 312 between the trench elements 310. This may be advantageous over other techniques for forming a separate barrier region over trench element 310, for example the disclosed process of depositing a layer of barrier material (e.g., Ta/TaN layer) over the full wafer and etching selected areas (e.g., between the various trench elements 310), which may involve additional process steps and thus additional cost as compared with a displacement plating process.
[0064] Next, as shown in
[0065] The dielectric cap layer 332 may be formed to protect the underlying e-fuse film 330 during construction of the e-fuse module 302, for example, to protect the e-fuse film from an oxidation during an ash process (photoresist removal step), which may affect the performance of the resulting e-fuse module 302. The dielectric cap layer 332 may comprise silicon nitride, silicon oxide, or other suitable cap material to protect the e-fuse film 330, and may be deposited by chemical vapor deposition (CVD) or other suitable deposition technique.
[0066] Next, as shown in
[0067] In this embodiment, the patterned photomask 340 fully covers the patterned copper layer M.sub.x, or in other words, the patterned photomask 340 covers the full area (from the top view shown in
[0068] In addition, patterning the larger percentage of the wafer area may substantially reduce the subsequent plasma etch burden (by reducing the area to etch). In addition, the risk of plasma etch penetrating through the barrier regions 324 at the top of each trench element 310 may be reduced or eliminated. Moreover, by pattering the full copper layer M.sub.x, the photomask may be generated in a straightforward manner, e.g., by first reverse tuning the mask used to form the trench layer M.sub.x (e.g., by switching from glass to chrome or from chrome or glass), then performing a logic “OR” of the reverse tuned mask with the e-fuse module pattern.
[0069] Next, as shown in
[0070] The e-fuse element 330a formed on the pair of e-fuse terminals 322 as disclosed above thereby defines a conductive path, indicated by double-headed arrow CP, between the two e-fuse terminal structures 314 through the barrier regions 324 and through the e-fuse element 330a. In some embodiments, e-fuse element 330a may comprise NiCr, TiW, TiWN, or Al with a thickness in the range of 50 Å-1000 Å, which may provide a sheet resistance Rs in the range of 10-1000 Ω/square. In some embodiments, the e-fuse element 330a may have a resistance in the range of 100 ohms to 1,000 ohms, e.g., about 500 ohms, in a low resistance state, and a resistance in the range of 100 KΩ/and 100 MΩ, e.g., about 1 MΩ in a high resistance state. In some embodiments, the e-fuse element 330a may have a resistance in the range of 300-500Ω in the low resistance state, and a resistance of greater than 1 MΩ in the high resistance state.
[0071] Next, as shown in the cross-sectional side view of
[0072]
[0073] Thus, the state of IC structure 900 shown in
[0074]