RECOMPRESSED TRANSCRITICAL CYCLE WITH POST-EXPANDING IN CRIOGENIC- OR LOW-TEMPERATURE APPLICATIONS, AND/OR WITH COOLANTS
20220154593 · 2022-05-19
Inventors
- Salvatore DE RINALDIS (San Donato Milanese (Milano), IT)
- Massimiliano SBARSI (San Donato Milanese (Milano), IT)
- Lucio AURILIO (San Donato Milanese (Milano), IT)
- Anton Marco FANTOLINI (San Donato Milanese (Milano), IT)
Cpc classification
F01K19/02
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F01K25/10
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F01D15/10
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F01K7/06
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
International classification
Abstract
A process for regasifying a fluid and producing electrical energy includes subjecting a working fluid to 1) high-pressure pumping, 2) heating in a recovery unit to obtain a heated flow, the heating step comprising a low-temperature heat recovery step 2a) and a high-temperature heat recovery step 2b), 3) further heating to obtain a further heated flow, 4) expanding in a turbine, with production of electrical energy, to obtain an expanded flow, 5) cooling in a recovery unit by heat exchange, in a step 5a) with the flow of step 2b) and in a step 5b) with the flow of step 2a) to obtain a cooled flow, 6) expanding with production of mechanical energy, and 7) condensing the flow of working fluid. After step 5), a portion of the flow of working fluid is not subjected to step 6) and is subjected to a recompressing step.
Claims
1. A process for regasifying a fluid and producing electrical energy, said process comprising subjecting a flow of a working fluid to the steps of: 1) high-pressure pumping, 2) heating in a recovery unit, thus obtaining a heated flow, said heating step comprising a low-temperature heat recovery step 2a) and a high-temperature heat recovery step 2b), 3) further heating, thus obtaining a further heated flow, 4) expanding in a turbine, with production of electrical energy, thus obtaining an expanded flow, 5) cooling in a recovery unit by heat exchange, in a step 5a) with the flow of step 2b) and in a step 5b) with the flow of step 2a), thus obtaining a cooled flow, 6) expanding with production of mechanical energy, and 7) condensing said flow of the working fluid and regasifying said flow, wherein, after step 5), a portion of the flow of said working fluid is not subjected to step 6) but is subjected to a recompressing step.
2. The process of claim 1, wherein a recompressed flow of said working fluid is obtained from the recompressing step, which is joined to the flow of the working fluid obtained from step 2a).
3. The process of claim 1, wherein step 3) is carried out by a high-temperature heat source.
4. The process of claim 1, wherein step 7) is carried out by heat exchange with said fluid to be regasified.
5. The process of claim 1, wherein step 7) is carried out by indirect heat exchange by an intermediate working fluid, which acquires heat in said step 7) and gives heat to said fluid to be regasified in a subsequent step.
6. The process claim 1, wherein a step of superheating said fluid to be regasified is carried out after step 7).
7. The process of claim 6, wherein said superheating step is carried out by a low-temperature heat source.
8. A liquefied natural gas (LNG) regasification line comprising a regasification section, wherein step 7) of a process for regasifyinq a fluid and producing electrical energy, said process comprising subjecting a flow of a working fluid to the steps of: 1) high-pressure pumping, 2) heating in a recovery unit, thus obtaining a heated flow, said heating step comprising a low-temperature heat recovery step 2a) and a high-temperature heat recovery step 2b), 3) further heating, thus obtaining a further heated flow, 4) expanding in a turbine, with production of electrical energy, thus obtaining an expanded flow, 5) cooling in a recovery unit by heat exchange, in a step 5a) with the flow of step 2b) and in a step 5b) with the flow of step 2a), thus obtaining a cooled flow, 6) expanding with production of mechanical energy, and 7) condensing said flow of the working fluid and regasifying said flow, wherein, after step 5), a portion of the flow of said working fluid is not subjected to step 6) but is subjected to a recompressing step, is carried out in said regasification section.
9. A liquefied natural gas (LNG) regasification system, comprising one or more regasification lines according to claim 8.
Description
BRIEF DESCRIPTION OF THE FIGURES
[0040]
[0041]
[0042]
[0043]
DETAILED DESCRIPTION OF THE INVENTION
[0044] The present invention in particular is described in relation to regasifying liquefied natural gas (LNG), but it is equally applicable for regasifying or the vaporization of other liquefied fluids stored at low temperatures (lower than about 0° C.) or at cryogenic temperatures (lower than −45° C.)
[0045] The present invention for example, is applied for regasifying a liquefied gas selected from the group which comprises for example: air, nitrogen, commercially available hydrocarbon compounds such as alkanes, among which for example, propane and butane, or alkenes, among which for example, ethylene and propylene.
[0046] The terms “evaporation” and “vaporization” applicable to LNG are to be intended as synonyms in the continuation of the description.
[0047] Further, “liquefied natural gas”, later also called “liquefied gas”, in the present description means a liquid obtained from natural gas after suitable refining and dehydrating processes and successive cooling and condensation steps.
[0048] More generally, “liquefied gas” in the present description means a fluid having a mainly liquid component.
[0049] Further, the term “low-temperature heat source” in the present description means for example: ambient air, seawater, low-temperature solar thermal, exhaust heat of a low-temperature thermodynamic cycle, low-temperature process and/or machinery heat recovery.
[0050] A low-temperature source generally operates at temperatures which are lower than 180° C., preferably lower than 120° C.
[0051] The term “high-temperature heat source” instead means for example: high-temperature thermal solar, exhaust heat of a high-temperature thermodynamic cycle, exhaust gas of a gas turbine or internal combustion engine, high-temperature process and/or machinery heat recovery.
[0052] A high-temperature source generally operates at temperatures which are greater than 180° C., preferably greater than 300° C., and even more preferably greater than 400° C. and beyond.
[0053] For the purposes of the present invention, it may be provided for a same low- or high-temperature heat source to feed several heating systems.
[0054] In the following description, the term “seawater” refers not only to seawater which is pumped and suitably processed to remove sediments and conveniently pumped (for example at about 2 bar), but more generally, environmental water obtained from rivers, canals, wells, natural basins such as lakes, etc. and artificial basins.
[0055] For the purposes of the present invention, the working fluid is CO.sub.2.
[0056] For the purposes of the present invention, an intermediate working fluid is a fluid capable of carrying out a heat transfer from one cycle to another.
[0057] Such an intermediate working fluid may for example, carry out a heat transfer from a first power cycle (to which reference may be made as topping cycle) to a second power cycle (to which reference may be made as bottoming cycle).
[0058] In one aspect of the invention, the bottoming cycle is a power cycle equal to the topping cycle.
[0059] In a preferred aspect, the intermediate working fluid is different from the working fluid of the topping cycle.
[0060] For the purposes of the present invention, a working fluid is involved which is different from CO.sub.2 and preferably is a gas or a gas mixture selected from the group comprising: hydrocarbons, nitrogen, CO.sub.2 and coolants.
[0061] According to a first object, the present invention describes a process for regasifying a fluid and for producing electrical energy.
[0062] As described above, such a fluid preferably is liquefied natural gas (LNG).
[0063] In a particular aspect of the present invention, the process comprises the employment of a working fluid, which preferably is CO.sub.2.
[0064] More specifically, the process comprises the steps of subjecting said working fluid to the steps of: [0065] 1) high-pressure pumping, [0066] 2) heating in a recovery unit, thus obtaining a heated flow, [0067] 3) heating through a high-temperature source, obtaining a further heated flow, [0068] 4) expanding in a turbine, with production of electrical energy (through a generator), thus obtaining an expanded flow, [0069] 5) cooling in a recovery unit, thus obtaining a cooled flow, [0070] 6) expanding with the production of mechanical energy, [0071] 7) condensing said flow of the working fluid and regasifying said fluid.
[0072] For the purposes of the present invention, step 1) increases the pressure up to beyond 150 bar.
[0073] With regards to step 2), it comprises a low-temperature heat recovery step 2a) (LTR) and a high-temperature heat recovery step 2b) (HTR).
[0074] More specifically, step 2a) increases the temperature up to about 200° C.
[0075] For the purposes of the present invention, step 5) is carried out in the same recovery unit as step 2); indeed, the heat exchange of step 5) is carried out with the flow of step 2b) (high-temperature recovery or step 5a)) and 2a) (low-temperature recovery or step 5b), respectively, and allows a cooled flow to be obtained.
[0076] For the purposes of the present invention, after step 5), and more specifically step 5b), a portion of the flow of the working fluid is not subjected to the expansion step 6), rather is subjected to a recompressing step.
[0077] A recompressed flow of working fluid is obtained from the recompressing step, which is then combined with the flow obtained from step 2a) and subjected to the subsequent steps of the process.
[0078] With regards to the heating step 3), it is carried out by means of a high-temperature heat source.
[0079] According to a preferred aspect of the present invention, the working fluid is CO.sub.2 and such an expansion step 4) is therefore a supercritical or transcritical expansion step.
[0080] Electrical energy is produced with step 4).
[0081] For the purposes of the present invention, step 6) to which a portion of the working fluid is subjected, is a subcritical expansion step.
[0082] With reference to the condensation step 7), it is carried out by heat exchange with the fluid to be regasified.
[0083] According to a first aspect of the invention depicted for example, in
[0084] According to an alternative embodiment of the present invention depicted in
[0085] More specifically, such an indirect exchange occurs by means of an intermediate working fluid, as described above.
[0086] Such an intermediate working fluid circulates within a cycle, called bottoming cycle.
[0087] More in detail, said bottoming cycle comprises a first exchanger COND1 (which corresponds to the condenser of step 7) and which is the condenser of the topping cycle), inside of which the heat exchange is carried out between the working fluid and said intermediate working fluid which is thus heated, and a second exchanger COND2, inside of which the heat exchange is carried out between the intermediate working fluid and the fluid to be regasified, to which heat is yielded.
[0088] As described above in particular, the intermediate working fluid of the bottoming cycle is different from the CO.sub.2 (or from the working fluid of the topping cycle) and preferably is a gas or a gas mixture selected from the group comprising: hydrocarbons, nitrogen, CO.sub.2 and coolants.
[0089] As described above, the working fluid may be CO.sub.2; alternatively, a working fluid may be employed mainly consisting of CO.sub.2 but with the addition of hydrocarbon/additive mixtures which allow this fluid to be liquefied at higher temperatures than the ambient temperature or than the one of the available cold fluid.
[0090] According to an aspect of the invention, a further superheating step of said fluid to be regasified may be conducted after step 7).
[0091] More in detail, such a further step is carried out by means of a low-temperature heat source.
[0092] For the purposes of the present invention, the described process may further comprise a step of regulating the circulating mass flow of CO.sub.2 in the cycle, where the CO.sub.2 is kept at the liquid state (also by virtue of the frigories provided by the cold source, and pressurized).
[0093] For this purpose, the system may comprise a CO.sub.2 storage tank.
[0094] Such an adjustment advantageously allows the power of the cycle to be regulated.
[0095] In one aspect of the present invention depicted for example, in
[0096] According to another aspect of the present invention not shown in the Figures, the turbine may actuate the low-pressure pump and/or the high-pressure pump.
[0097] According to a second object of the present invention, there is described a regasification line for a fluid, preferably the liquefied natural gas (LNG) which allows producing electrical energy by means of the above-described process.
[0098] An LNG regasification system comprising one or more regasification lines is also an object of the present invention.
[0099] The term “regasification line” means that independent and replicable portion of the system that includes the structures, the equipment, the machinery and the systems for regasifying a given flow of the liquefied natural gas (LNG).
[0100] Such structures, equipment, machinery and systems in particular originate from the tank (TANK) in which the LNG is stored, comprise cryogenic pumps, possibly low- and high-pressure pumps and a BOG compressor, which may be common to several regasification lines, and a regasification section, and end with the regasified LNG introduction point into the distribution network of the gas itself.
[0101] For the purposes of the present invention, the regasification section is the condenser inside of which the condensation step 7) of the working fluid occurs, according to the above-described process.
[0102] Alternatively, a regasification line of the present invention may be provided in energy by-pass configuration with respect to a traditional technology of an existing system.
[0103] As shown in
[0104] According to an alternative embodiment of the present invention, the process described may be integrated with a conventional technology of SCV type.
[0105] Here, a coil containing condensing CO.sub.2 or a suitable fluid (such as, for example water-glycol) which exchanges heat with the condensing CO.sub.2 heats the vaporization bath.
[0106] The layouts proposed may also be applied for making systems for regasifying technical gas (such as, for example hydrogen, air, nitrogen or other gas) or systems with low- or cryogenic-temperature fluid storages, also for cryogenic depots or storages.
[0107] When an export of electrical energy is not provided, to balance out the electric and heat loads, the power cycle may operate on a fraction of the LNG, regasifying the remaining fraction of LNG, with other systems and/or employing the surplus of electric power to feed air heating technologies.
[0108] The values indicated in the following section refer to a reference regasification system by way of explanation but are in any case valid if considered as specific/unitary value. Further, the results obtained in terms of extractible net electric power and thermodynamic efficiency of the cycle refer to a pressure of 100 to 250 or 150 to 350 bar and beyond A, and at a temperature of about 350° C. to 550° C. or 450° C. to 650° C., up to 700° C. and beyond, at the transcritical expansion turbine input, where applicable.
[0109] Please note the reference diagram in
[0110] CO.sub.2 Circuit
[0111] The fluid cooled by the two heat exchangers (HTR and LTR) (5) is divided into two flows, one of which is sent (13) to a further expander (SC EXP) and is expanded at a variable pressure between 8 and 45 bar (6) prior to being sent to condenser COND1, thus extracting an overall increased work (TC EXP and SC EXP). By condensing at a lower pressure with respect to the diagram in
[0112] As described above, there may be the option of configuring turbomachinery (
[0113] Liquefied Natural Gas (LNG) Circuit
[0114] 123.61 t/h of LNG are drawn at the temperature of −156.6° C. and at a pressure of 90.5 bar A (100). Then, LNG receives heat in COND 1 (24.34 MWt), reaching the temperature of 2.5° C. (101).
[0115] Note the same reference diagram in
[0116] LNG is not entirely regasified, i.e. up to a temperature of 2.5° C., by means of the condensation of the power cycle. The remaining portion is regasified through an ambient means, which, in the case described below, corresponds to seawater. The difference between the two diagrams is indicated by a dotted line (
[0117] CO.sub.2 Circuit
[0118] With respect to a diagram similar to the one in
[0119] Liquefied Natural Gas (LNG) Circuit
[0120] The output temperature of the natural gas (LNG regasifying) is lower given that it is heated with the CO.sub.2 cycle through the same condenser (COND 1) with a variable reached temperature between −55° C. and 0° C. (101). Therefore, a further superheating fluid is required to heat the natural gas at the required temperature, included between 0 and 10° C. (in the particular case: 2.5° C.). For this purpose, the natural gas is sent into an ambient air cooler or into an optional seawater circuit SH (102).
[0121] With respect to the diagram in
[0122] CO.sub.2 Circuit
[0123] 123.61 t/h of LNG are drawn at the temperature of −156.6° C. and at a pressure of 90.5 bar A (100). Then, LNG receives heat (16.53 MWt if, as indicated above, the pressure CO2 circuit side to the flow (3) is equal to 45 bar) in COND1 up to reaching a temperature of −50° C. (101). The remaining part of the vaporization, which is dependent on the preceding heat exchange in COND1, is completed in heater SH where the LNG receives heat from the seawater circulating in a dedicated circuit and reaches a temperature of 2.5° C. (102).
[0124] Seawater Circuit
[0125] The seawater circuit (not shown) completes the vaporization of the LNG from the temperature reached in COND1 through the heat exchange with the CO.sub.2 and up to the temperature of 2.5° C. in series at COND 1.
[0126] With reference to the same example indicated above and described in the sub-sections “CO.sub.2 Circuit” and “LNG Circuit”, 1340.1 t/h of seawater at the temperature of 9° C. and at atmospheric pressure are drawn at the seawater intake and pumped at the pressure of about 2 bar A by means of a pump. The flow is then fed to heater SH (7.82 MWt) where it is cooled by 5° C. and discharged into the sea, thus allowing the vaporization of the LNG from the temperature obtained at the output of COND1 up to reaching a temperature of 2.5° C., which is not obtainable with condenser COND1 alone.
[0127]
[0128] The advantages offered by the present invention are apparent to a person skilled in the art from the description above.
[0129] Considering the conventional regasifying technologies, the main advantages of the solution appear to be: [0130] reduction of the consumption of fuel gas with respect to SCV technology, the advantage expressed in terms of Fuel Gas Saving (FGS)=(Gas cycle consumption−SCV or ORV consumption/SCV or ORV consumption) [%] up to 60% (30%) with energy surplus availability; [0131] reduction of CO.sub.2 emissions up to 60% (30%), (proportionately to the reduction of the fuel gas consumption, with respect to a conventional SCV and ORV technology); [0132] the production of electrical energy may be employed to meet the system needs and for exporting the same; [0133] specific technical problems are avoided or significantly reduced both for the above-mentioned ORV and for SCV; [0134] all the advantages associated with the employment of carbon dioxide as working fluid can be exploited: low freezing point, stability.
[0135] Further, more in detail, the following was positively noted: [0136] the availability of a cold well, represented by the LNG or other technical gas to be regasified or by a storage at low or cryogenic temperatures, which allows the CO.sub.2 to be liquefied at different pressures, thus obtaining (Brayton-Rankine) transcritical CO.sub.2 power generating cycles, with significantly greater efficiency than CO.sub.2 (supercritical) Brayton cycles; [0137] the employment of a pump for compressing condensed CO.sub.2 allows a reduction of the power required by the cycle and of the system cost to be obtained with respect to the employment of the primary compressor required in the supercritical CO.sub.2 Brayton cycles; [0138] engineering simplicity, especially for retrofitting existing systems; CO.sub.2 power cycle may be integrated in a conventional SCV technology, as described above; [0139] the possibility of including a CO.sub.2 storage tank (not depicted in the Figures) allows the power of the cycle to be regulated by regulating the mass flow circulating in the cycle, where CO.sub.2 is kept in the liquid state also by virtue of the frigories provided by the cold source, and pressurized: this allows a given operating flexibility to be obtained also in the startup and stop steps and in potential emergency scenarios; and it simplifies the design of the storage tank, which may operate at lower pressures and with smaller volumes.
[0140] With respect more specifically to CO.sub.2 transcritical power generating cycles, the following advantages can be acknowledged: [0141] CO.sub.2 transcritical power generating cycles allow the expansion from high pressures in supercritical step to low pressures in subcritical step, under condition of condensing the CO.sub.2 at low temperatures, using LNG or a fluid with adequate thermal level as a cold well, by means of one or more expansion turbines, exploiting the specific high work of the fluid at high pressures: by allowing an increased expansion ratio of the turbines, this generates sufficient power to feed the utilities of the LNG regasification system or also a surplus of generated electric power available to feed possible external utilities; [0142] the optimization of the transcritical CO.sub.2 cycle allows an increased share of frigories available during the LNG vaporization to be used, and drastically reduces the consumption of energy required to regasify LNG.
[0143] With reference to the drawings in
[0146] With reference to the diagram in
[0148] Overall, the cascade power generating cycles may be combined so as to best exploit the features and constraints thereof to the advantage of regasifying the LNG, thus improving the employment of the frigories (vaporization curve). Although they have increased engineering complexity, they allow the overall system efficiency to be improved.
[0149] In the case of a CO.sub.2 topping cycle and a bottoming cycle with fluid different from CO.sub.2 as described above: [0150] the condensation of the CO.sub.2 is carried out by means of the vaporization of the fluid in the bottoming cycle which occurs at temperatures which are compatible with the solidification of the CO.sub.2 and which condenses, recuperating the LNG frigories with a more efficient LNG vaporization curve and the possibility of recuperating all the frigories available in the LNG; [0151] the addition of the topping cycle allows the extraction of increased power with respect to the system with only bottoming cycle and the possibility of best exploiting the available heat sources, especially if at high temperature, thus allowing the recuperation of this heat to be distributed between the two cycles; in particular, the range of condensation temperatures of the CO.sub.2 (comprised between the triple point at −56.56° C. and the critical temperature of +30.98° C.) allows a bottoming cycle with organic fluid to be coupled in an optimal manner to one of the innovative CO.sub.2 cycles proposed in this paper and the pressure jumps in the two-cycle turbines to be optimized.
[0152] Further, the CO.sub.2 topping cycle is a supercritical/transcritical cycle with recovery unit and recompressor, therefore the energy available at high temperature is exploited well in a high efficiency topping cycle, instead designating the energy at lower temperatures (the one discharged from the topping cycle) to the ORC bottoming cycle. The two cascade cycles (CO.sub.2 topping cycle and ORC bottoming cycle) are optimized with the heat inputs in the temperature ranges appropriate thereto, with benefits to the overall efficiency and simplification in designing the turbomachinery.
[0153] All the embodiments of the invention may operate in configuration both of energy by-pass at a conventional regasifying technology for an existing system (such as for example, shown in