PROCESS FOR THE PRODUCTION OF A COMPOSITE MATERIAL FROM TEXTILE WASTE AND POLYETHYLENE FILM WASTE

Abstract

The invention relates to a process for the production of a composite material from textile waste and polyethylene film waste, characterized in that it comprises the following steps: a) comminuting the textile waste into the fraction up to 15 mm in size, b) comminuting the polyethylene film into the fraction up to 15 mm in size, c) separating metal parts from the comminuted textiles, d) separating metal parts and unwanted plastics from the comminuted film, e) further comminuting the textiles into the fraction up to 5 mm in size, f) mixing the comminuted textiles with the comminuted film, said textiles constituting 10-50% of the mixture, g) plasticizing, homogenizing and extruding the obtained mixture in an extruder at the temperature of 170-240° C. and under the pressure of 8-15 MPa.

Claims

1. A process for the production of a composite material from textile waste and polyethylene film waste, characterized in that it comprises the following steps: a) comminuting the textile waste into the fraction up to 15 mm in size, b) comminuting the polyethylene film into the fraction up to 15 mm in size, c) separating metal parts from the comminuted textiles, d) separating metal parts and unwanted plastics from the comminuted film, e) further comminuting textiles into the fraction up to 5 mm in size, f) mixing the comminuted textiles with the comminuted film, said textiles constituting 10-50% of the mixture, g) plasticizing, homogenizing and extrading the obtained mixture in an extruder at the temperature of 170-240° C. and under the pressure of 8-15 MPa.

2. The process according to claim 1, characterized in that the textiles comprise synthetic fibers at the level of at least 30%.

3. The process according to claim 1, characterized in that the textiles constitute 28% of the mixture.

4. The process according to claim 1, characterized in that, in step e), the textiles are comminuted into the fraction up to 2 mm in size.

5. The process according to claim 1, characterized in that, in step b), the polyethylene film is comminuted into the fraction up to 10 mm in size.

6. The process according to claim 1, characterized in that, in step g), the mixture is admixed with additives in the amount up to 4%, selected from a group comprising compatibilizers, lubricants and colorants.

7. The process according to claim 1, characterized in that it further comprises granulating the composite material obtained in step g).

8. The process according to claim 2, characterized in that the textiles constitute 28% of the mixture.

9. The process according to claim 2, characterized in that, in step e), the textiles are comminuted into the fraction up to 2 mm in size.

10. The process according to claim 8, characterized in that, in step e), the textiles are comminuted into the fraction up to 2 mm in size.

11. The process according to claim 2, characterized in that, in step b), the polyethylene film is comminuted into the fraction up to 10 mm in size.

12. The process according to claim 3, characterized in that, in step b), the polyethylene film is comminuted into the fraction up to 10 mm in size.

13. The process according to claim 10, characterized in that, in step b), the polyethylene film is comminuted into the fraction up to 10 mm in size.

14. The process according to claim 2, characterized in that, in step g), the mixture is admixed with additives in the amount up to 4%, selected from a group comprising compatibilizers, lubricants and colorants.

15. The process according to claim 3, characterized in that, in step g), the mixture is admixed with additives in the amount up to 4%, selected from a group comprising compatibilizers, lubricants and colorants.

16. The process according to claim 4, characterized in that, in step g), the mixture is admixed with additives in the amount up to 4%, selected from a group comprising compatibilizers, lubricants and colorants.

17. The process according to claim 13, characterized in that, in step g), the mixture is admixed with additives in the amount up to 4%, selected from a group comprising compatibilizers, lubricants and colorants.

18. The process according to claim 2, characterized in that it further comprises granulating the composite material obtained in step g).

19. The process according to claim 3, characterized in that it further comprises granulating the composite material obtained in step g).

20. The process according to claim 17, characterized in that it further comprises granulating the composite material obtained in step g).

Description

[0009] The object of the invention is to provide a process for the production of a composite material from textile waste and polyethylene film waste, which despite the instability of the raw textile stream, does not require a meticulous sorting and waste preparation process, and simultaneously provides a composite material of desired physical-chemical properties and is environmentally friendly.

[0010] The invention relates to a process for the production of a composite material from textile waste and polyethylene film waste, characterized in that it comprises the following steps: [0011] a) comminuting the textile waste into the fraction up to 15 mm in size, [0012] b) comminuting the polyethylene film into the fraction up to 15 mm in size, [0013] c) separating metal parts from the comminuted textiles, [0014] d) separating metal parts and unwanted plastics from the comminuted film, [0015] e) further comminuting textiles into the fraction up to 5 mm in size, [0016] f) mixing the comminuted textiles with the comminuted film, said textiles constituting 10-50% of the mixture, [0017] g) plastificating, homogenizing and extruding the obtained mixture in an extruder at the temperature of 170-240° C. and under the pressure of 8-15 MPa.

[0018] In a preferred embodiment of the invention, the textiles comprise synthetic fibers at the level of at least 30%.

[0019] In another preferred embodiment, the textiles constitute 28% of the mixture.

[0020] Preferably, in step e), the textiles are comminuted into the fraction up to 2 mm in size.

[0021] Preferably, in step b), the polyethylene film is comminuted into the fraction up to 10 mm in size.

[0022] In another embodiment of the process according to the invention, in step g), the mixture is admixed with additives in the amount up to 4%, selected from the group comprising compatibilizers, lubricants and colorants.

[0023] In a preferred embodiment, the process according to the invention further comprises granulating the composite material obtained in step g).

[0024] Reduction of the influence of the kind of processed textile waste fibers on the physical-chemical properties of the produced composite was attained by proper selection of process parameters such as the ratio of amount of the textile component to the polyethylene component, the degree of comminution of the textile component and polyethylene component, and the temperature and pressure of the process. As a result, it is possible to produce a composite material from textile waste and polyethylene film waste with the desired physical-chemical properties, without meticulous sorting and preparing the waste. Moreover, the process according to the invention is environmentally friendly because it reduces CO.sub.2 emissions. According to the report CO.sub.2-kantallen afvelscheiding, SenterNovem, September 2007, the produced composite material allows one to reduce about 3 kg of CO.sub.2 per each unburned kilogram of textile waste.

[0025] The invention is illustrated by the following example.

[0026] Textile waste was supplied in the form of whole clothes packed in bales weighing up to 25 kg. The textiles were visually inspected with regard to the level of soil, dampness and uniformity of textile kinds in a bale, and statistically verified with regard to the presence of raw materials other than textiles (e.g. shoes, toys, purses etc.) in the supply. Then, the textiles were sorted into textiles with predominant content of natural fibers, textiles with predominant content of synthetic fibers and textiles not suitable for the process (too damp, too soiled and containing a considerable percentage of unwanted admixed materials). Polyethylene film waste was supplied packed in bales weighing up to 25 kg. The film was visually inspected with regard to the level of soil, dampness and uniformity of film kinds in a bale and the bales were statistically verified with regard to the presence of raw materials other than the film (e.g. textile remnants, additives, etc.) in the supply.

[0027] The textiles were transported by a belt conveyor to a shredder equipped with sieves with 15 mm holes wherein the textiles were comminuted into the fraction up to 15 mm in size. Subsequently, the comminuted textiles were transported by a conveyor into a separation assembly (separators) wherein the undesired parts (‘undesired’ means not being textiles, including metal parts, parts made of plastics) were separated from the remaining comminuted textile part. The textiles without the unwanted parts were transported by a screw conveyor to a final shredder wherein the textiles were comminuted to a fraction of the size presented in Table 1. The comminuted textiles were stored in a textile buffer container.

[0028] The film was transported by a belt conveyor to a shredder equipped with sieves with 15 mm holes wherein the film was comminuted into flakes up to 15 mm in size. Subsequently, the comminuted film was transported by a belt conveyor into a separator wherein the undesired parts (‘undesired’ means not being the film flakes, including metal parts, parts made of plastics not corresponding to the predetermined basis weight of a flake after comminution, paper) were separated. The separator detected and separated the undesired parts from the remaining comminuted film part. The comminuted film without the unwanted parts was stored in a film buffer container.

[0029] The comminuted textiles and film were dosed from the buffer containers into a mixer by means of a screw conveyor in controlled and precisely defined amounts presented in Table 1. The amounts of the dosed components were controlled by adjusting the rotational speed of the screw. The components were mixed continuously. The paddles of the mixer were positioned at a 45-degree angle relative to the axis of the mixer to provide flow of the components through the mixer. The flow was controlled by adjusting the size of the outlet opening of the mixer. In the mixer, the materials were mixed. The obtained mixture was transported by means of the conveyor to a mixture buffer container.

[0030] The mixture from the buffer container was dosed to a twin-screw extruder with conical screw geometry, at a dosing rate of 400 kg/h. The temperature in individual sections of the extruder was S1: 180° C., S2: 180° C., S3: 190° C., S4: 190° C. and S5: 200° C., and the pressure at melting was 9 MPa. The rotational speed of the extruder was 90 rpm. The mixture was admixed with additives, i.e. resins based on ethylene/vinyl acetate copolymer (the commercial product Elvax) and maleic anhydride-grafted resins (the commercial product Fusabond), in the amounts presented in Table 1. In the extruder, the mixture was plasticized, degassed, homogenized and granulated. The composite material was produced in the form of granules having 4 mm diameter.

[0031] Table 1 shows the composition and parameters of various composite material samples produced according to the above-described process. Each sample relates to a composite material produced from a separate textile waste supply.

TABLE-US-00001 TABLE 1 Sample name #2 #3 #4 MIX 1 MIX 2 MIX 3 MIX 4 Textile fraction size (mm) up to 2 up to 2 up to 2 up to 5 up to 5 powder up to 2 Film fraction size (mm) up to 15 up to 15 up to 15 up to 15 up to 15 up to 15 up to 15 Textile content (%) 10 28 48 36 50 50 48 Film content (%) 89 68 48 60 46 46 48 Fusabond (%) 0.5 2 2 2 2 2 2 Elvax (%) 0.5 2 2 2 2 2 2 Melt flow index (g/10 min) 190° C.; 2.16 kg 0 0 0 0 0 0 0 190° C.; 5.00 kg 0.071 0.067 0.218 0.061 0 0.055 0.218 190° C.; 10.00 kg 0.345 0.312 1.158 0.5 0.046 0.426 1.158 Density (g/cm.sup.3) 0.986 0.998 1.15 1.107 1.193 1.162 1.15 Bulk density (g/cm.sup.3) 0.267 0.319 0.317 0.315 0.295 0.316 0.317 Tensile strength (Mpa) 17.2 11.4 11.14 12.23 16.7 11.96 11.14 True tensile stress (Mpa) 10.37 8.1 9.66 1.64 16.68 8.87 9.66 Elongation at maximum stress (%) 4.28 3.43 1.38 3.17 1.81 1.96 1.38 Elongation at break (%) 4.83 1.64 1.59 1.08 1.83 2.7 1.59 Water absorption (%) 0.46 0.94 1.24 0.95 1.48 1.14 1.24

[0032] The data in Table 1 show that the composite materials produced by the process according to the invention from textile waste derived from different supplies exhibit similar physical-chemical properties for samples with similar composition of the raw textile and film.

[0033] The composite material produced by the process according to the invention is applicable for forming (e.g. by the extrusion method) various final products, such as: posts, profiles, planks (including tongue-and-groove planks), clothing hangers, picnic tables and benches, street lamp bodies.