Method for Degassing Water and Gas Balancing Filter
20220153610 · 2022-05-19
Inventors
Cpc classification
A01K63/042
HUMAN NECESSITIES
C02F1/20
CHEMISTRY; METALLURGY
International classification
C02F1/20
CHEMISTRY; METALLURGY
A01K63/04
HUMAN NECESSITIES
Abstract
A method for degassing carbon dioxide from a stream of water is provided, whereby water is supplied at a predefined volumetric flow to a gas balancing filter, wherein the water in a first step is collected in a basin with a free upper surface and a depth and in a second step is allowed to flow out of the basin through at least one orifice provided beneath the free upper surface and in a third step the water flowing out of the orifice is allowed to free-fall a distance D through a controlled atmosphere and is then collected in a further basin provided beneath the basin. The invention comprises the further steps that the first, second and third steps are repeated two or more times with basins provided consecutively below each other. A gas balancing filter is also provided.
Claims
1. A method for degassing carbon dioxide from a stream of water, whereby water with a predefined volumetric flow is supplied to a gas balancing filter, wherein the water in a first step is collected in a basin with a free upper surface and a depth (H) and in a second step is allowed to flow out of the basin through at least one orifice provided beneath the free upper surface and in a third step, the water flowing out of the at least one orifice is allowed to free-fall a distance (D) through a controlled atmosphere and is then collected in a further basin provided beneath the basin, wherein the predefined volumetric flow of the water is selected; the at least one orifice is dimensioned; and the depth (H) of the basin is defined by the distance between the free upper surface and the at least one orifice such that a predefined minimum average residence time for the water in the basin is between 8 and 15 seconds.
2. The method according to claim 1, wherein the first, second and third steps are repeated two or more times.
3. The method according to claim 2, wherein the first, second and third steps are repeated two or more times by using a plurality of basins provided consecutively below each other.
4. The method according to claim 1, further comprising providing a stream of air across the free upper surface of the basin.
5. The method according to claim 1, further comprising providing one or more additional orifices at a level above the at least one orifice to ensure against overflow.
6. The method according to claim 1, wherein the water supplied to the gas balancing filter is water from an aquatic animal culture which is CO.sub.2 rich and depleted of O.sub.2.
7. The method of claim 6, further comprising pumping water from the further basin back into the aquatic animal culture.
8. A gas balancing filter for degassing CO.sub.2 from a stream of water, wherein the gas balancing filter comprises a top basin arranged to collect a predefined volumetric flow of water to be degassed, wherein the top basin is configured to contain a water column having a free water surface and a depth (H) larger than a predefined level, wherein the top basin comprises one or more orifices arranged below the level of the free water surface, wherein the gas balancing filter is configured to discharge water from the top basin out through the one or more orifices and ensure that the water discharged from the top basin out through the one or more orifices will free-fall a distance (D) through a controlled atmosphere, wherein the gas balancing filter comprises a lower basin provided below the top basin and arranged such that the predefined volumetric flow of water flows through one or more orifices within the lower basin, wherein for the lower basin: a ratio (R.sub.L) between an average horizontal cross-sectional area (A.sub.column) of a water column in the lower basin and a sum of areas (A.sub.O) of the one or more orifices below the water column in the lower basin; and a height of the lower basin is selected such that
9. The gas balancing filter according to claim 8, wherein the lower basin has a bottom plate with a raised portion that is only inundated in case of an overflow event.
10. The gas balancing filter according to claim 8, further comprising a lowermost basin.
11. The gas balancing filter according to claim 10, wherein a fan and a manifold provide a stream of air across a free upper surface of the lowermost basin.
12. The gas balancing filter according to claim 8, wherein a fan and a manifold provide a stream of air across a free upper surface of the lower basin.
13. The gas balancing filter according to claim 8, wherein a supply line carrying CO.sub.2 rich and O.sub.2 depleted water from an aquatic animal culture is arranged at the top basin, and a retrieval line is connected to a lowermost basin to retrieve CO.sub.2 depleted water to be pumped back into the aquatic animal culture.
14. The gas balancing filter according to claim 8, wherein, in a lowermost basin, a manifold plate is provided that has a range of water exit openings provided at the intersection of a bottom of the lowermost basin and the manifold plate.
15. The gas balancing filter according to claim 14, wherein the manifold plate is arranged between and fastened to the bottom of the lowermost basin and an upright outer sidewall of the lowermost basin.
16. The gas balancing filter according to claim 8, wherein a ratio (R.sub.T) between an average horizontal cross-sectional area (A.sub.column) of the water column in the top basin and a sum of areas (A.sub.O) of the one or more orifices below the water column in the top basin is in a range of 0.5-5%.
17. The gas balancing filter according to claim 16, wherein the ratio (R.sub.L) is smaller than the ratio (R.sub.T).
18. The gas balancing filter according to claim 8, wherein the lower basin is configured to contain a water column having a larger depth (H) than a depth of the water column that the top basin is configured to contain.
19. The gas balancing filter according to claim 8, wherein a bottom plate of the top basin has a smaller area than a bottom plate of the lower basin.
20. A method for degassing carbon dioxide from a stream of water, comprising: arranging a top basin to collect a predefined volumetric flow of water to be degassed, the top basin configured to contain a water column having a free water surface and a depth (H) larger than a predefined level, wherein the top basin comprises one or more orifices arranged below the level of the free water surface; discharging water from the top basin out through the one or more orifices and ensuring that the water discharged from the top basin out through the one or more orifices will free-fall a distance (D) through a controlled atmosphere; and providing a lower basin below the top basin and arranged such that the predefined volumetric flow of water flows through one or more orifices within the lower basin, wherein for the lower basin: a ratio (R.sub.L) between an average horizontal cross-sectional area (A.sub.column) of a water column in the lower basin and a sum of areas (A.sub.O) of the one or more orifices below the water column in the lower basin; and a height of the lower basin is selected such that
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0048] The invention will become more fully understood from the detailed description given herein below. The accompanying drawings are given by way of illustration only, and thus, they are not limitative of the present invention. In the accompanying drawings:
[0049]
[0050]
[0051]
[0052]
[0053]
[0054]
[0055]
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[0058]
DETAILED DESCRIPTION
[0059] Referring now in detail to the drawings for the purpose of illustrating embodiments of the present invention, a gas balancing filter 2 of the present invention is illustrated in
[0060]
[0061] In
[0062] When a predefined volumetric flow of the water is arranged along with orifices 8 which are outlined with regard to number per area bottom surface and dimensioned with respect to diameters and further the basin has a depth defined by the distance between the free upper surface 10 and the orifices 8, it may be achieved that a predefined minimum average residence time is provided for the water in each of the basins 6.2, 6.3 placed under an uppermost basin 6.1 and above a lowermost basin 6.4. The predefined volumetric flow is provided to an uppermost basin 6.1, and preferably the uppermost basin 6.1 is dimensioned with regard to vertical extent and orifice number and size in much the same way as underlying basins 6.2, 6.3 (apart from a lowermost basin, which shall not allow the water to trickle out into a controlled atmosphere, and thus has a differently shaped exit) even if a residence time is not required in the uppermost basin.
[0063] The residence time in basins 6.2, 6.3 below the uppermost basin 6.1 is important as CO.sub.2 in the water resides partially as dissolved CO.sub.2 and partially as carbonic acid, the two forming an equilibrium in the water. CO.sub.2 cannot exit the water and enter the atmosphere around or above the water unless it is dissolved as CO.sub.2 in the water. Thus, even if the water quickly loses its dissolved CO.sub.2, carbonic acid remains within the water, but once the CO.sub.2 is out of the water, a new equilibrium state may form, in which a portion of the remaining carbonic acid is converted to CO.sub.2. However, this process is time-consuming and thus the residence time in each of the basins 6.2, 6.3 below the uppermost basin 6.1 and above the lowermost basin 6.4 helps in allowing more CO.sub.2 to leave the water and enter the controlled atmosphere. The construction of the gas balancing filter 2 with at least two layers of trickle-down orifices and a residence time before each trickle-down event is instrumental in ensuring that the resulting water is well free of CO.sub.2.
[0064] It is to be understood that in order to reach a given residence time, when a predefined volumetric flow of water is given, and a preferred diameter of the at least one orifice is given, it is required to calculate the number of orifices per square measure of basin bottom. The orifice diameter is determined by the available space or distance D between the underside of a basin and the free upper surface 10 of the water in a below arranged basin, as the larger holes or orifices shall give a larger diameter of the water column below the orifice, and thus a longer time is demanded for the CO.sub.2 to exit the water and enter the controlled atmosphere.
[0065] It is also to be understood that the system of basins stacked above each other which is provided according to the invention also allows for some self-regulating mechanisms regarding water flow. In case the pumping action increases to the volumetric water flow, this will cause rising level or depth between the free surface and the bottom of the basins. Accordingly, this will cause a higher flow rate out of the orifices at the bottom due to increased hydrostatic pressure. If the pumping action is reduced, the depth of the basins and thus the flow rate out of the basins will be decreased. In both cases a residence time in each basin shall not be affected to any significant extent, and thus the process in the gas balancing filter is not very dependent on a constant flow of water through the system. However, the system shall be designed to deal with a predefined volumetric flow of water, at which flow an optimized performance is obtained.
[0066] It may happen during use that orifices are blocked such as by growth of bacteria or microorganisms or by deposit of solid particles in the water, and in this case an overflow may be the result with water flowing out of the gas balancing filter or causing the gas balancing filter to sustain damage or even break down. To avoid this, any basin above the lowermost basin 6.4 and below the uppermost basin 6.1 comprises a section of orifices which are provided in a raised bottom portion. These orifices may be significantly larger than the usual orifices and/or placed at a reduced distance from each other. Thus, if the usual orifices become blocked or an excessive pumping action becomes necessary, water may rise in each basin such that the raised bottom portions become inundated and water shall be allowed to at least trickle down to a below arranged basin through the further orifices of the raised bottom portions. This may be to the detriment of the performance of the gas balancing filter, however, it may nonetheless ensure its survival as a functioning part of a husbandry with fish or other animals living submerged in the water.
[0067] In
[0068]
[0069]
[0070]
[0071] In
[0072] In
[0073] In an embodiment of the gas balancing filter, the gas balancing filter has a length of about 10 meters, a height of around 3 meters. The average residence time is around 10-13 seconds at normal volumetric flow rate.
[0074] In the disclosed embodiment the orifices are round, but oval, star-shaped or slit formed orifices may be used or combinations thereof.
[0075] A bottom surface according to the embodiment disclosed in
[0076] A bottom of the uppermost basin may be dimensioned using a second plate, which has slightly above 1200 holes per m.sup.2 (same diameter of the orifices at nominally 4 mm as above) and this may result in a slightly lower depth of around 70 mm given the same predefined volumetric flow and size of an uppermost basin 6.1 as for the above two consecutively arranged basins 6.2 and 6.3. As mentioned, the uppermost basin 6.1 need not provide a residence time, as no new equilibrium is desired for the water flowing onto this basin.
[0077] The raised portions of bottom plate 44 shown in
[0078] When a depth of basins 6.2 and 6.3 and 6.4 (not being an uppermost basin 6.1) has been defined, also the free fall distance D shall be defined, as the distances between the basins is given by the constructional measures of the gas balancing filter. In the embodiment disclosed in
[0079]
[0080] In an embodiment, the predefined volumetric flow of water is 25-200 L. In an embodiment, the predefined volumetric flow of water is 50-100 L. In an embodiment, the predefined volumetric flow of water is 65-85 L.
[0081] The top basin 6.1 is configured to contain a water column having a free water surface and a depth H.sub.1 larger than a predefined level (e.g. the height of the basin 6.1 (measured from the bottom plate 38). The orifices 8 of the top basin 6.1 are arranged below the level of the free surface of the water. The gas balancing filter is configured to discharge water from the top basin 6.1 out through orifices 8 and ensure that the water discharged from the top basin 6.1 out through the one or more orifices 8 will free-fall a distance D through a controlled atmosphere.
[0082]
[0083] A water column is indicated above an orifice 8 in both the top basin 6.1 and the second basin 6.2. The horizontal cross-sectional areas A.sub.Column 1, A.sub.Column 2 of each are indicated.
[0084] The pressure P.sub.T at the water surface of the top basin 6.1 is indicated. Likewise, the pressure P.sub.B at the water surface of the top basin 6.1 is indicated. A Cartesian coordinate system with a vertical axis Z, and two horizontal axes X, Z of the top basin 6.1 is indicated.
[0085] When considering a first point at the bottom and a second point at the top surface of the water column in the top basin 6.1, we can use Bernoulli's Equation that reads:
P+½ρu.sup.2+μgy=constant (1)
where P is the pressure, ρ is the density of water, u is the speed, g is acceleration due to gravity and y is the vertical position.
[0086] When inserting the values for a point at the bottom and a point at the top surface of the water in one of the basins one finds that:
P.sub.T+ρgy.sub.T+½ρu.sub.T.sup.2=P.sub.B+ρgy.sub.B+½ρy.sub.B.sup.2 (2)
where P.sub.T is the pressure at the top of the water column in the basin. y.sub.T is the vertical position of the top of the water column in the basin, u.sub.T is the speed of the water at the top portion of the basin, P.sub.B is the pressure at the outlet of the orifice 8, y.sub.B is the vertical position of the orifice 8, u.sub.B is the speed of the water leaving the orifice 8. For simplicity we assume that the horizontally velocity of the water can be neglected.
[0087] We assume that y.sub.B=0 and u.sub.T=0 and Y.sub.T=H. Moreover, we expect that P.sub.T=P.sub.B=0 (defining the ambient pressure as zero) since the atmospheric pressure is present both at the top surface of the water column and at the points at which the water leaves the orifices 8. Accordingly, one can derive that:
ρgH=½ρu.sub.B.sup.2 (3)
[0088] Now it follows that
u.sub.B=√{square root over (2gH)} (4)
[0089] This means that the speed of the water leaving an orifice 8 depends only on the depth H of the water column. The Q.sub.i flow through an orifice 8 having an area A.sub.O(i) is given by:
Q.sub.i=A.sub.O(i)u.sub.B(i) (5)
where u.sub.B(i) is the speed of the water being discharged through the orifice 8 having an area A.sub.O(i). When applying a horizontally arranged bottom plate 38 with N orifices 8 of equal area A.sub.O(i)=A.sub.O, the speed u.sub.B of the water being discharged through the orifices is the same. Accordingly, one can deduce that:
Q=Σ.sub.i=1.sup.NA.sub.O(i)u.sub.B(i)=NA.sub.Ou.sub.B=NA.sub.O√{square root over (2gH)} (6)
[0090] The average residence time T of water in the basin having an area A.sub.basin and a water column depth H is given by:
where R is the ratio between the total area of the orifices 8 and the area of the bottom plate 38 of the basin.
[0091] The second basin 6.2 is designed in such a manner that
is in the range between 8-15 seconds, preferably between 10 and 13 seconds.
[0092] By a residence time in this range, there is sufficient time for the carbonic acid to reach an equilibrium state with any remaining dissolved CO.sub.2 after a free fall event. The majority of dissolved CO.sub.2 having been diffused out of the water and into the controlled atmosphere.
[0093] The velocity u.sub.B of water that leaves the orifices 8 from the bottom plate 38 of the top basin 6.1 is indicated. Likewise, the velocity u.sub.B′ of water that leaves the orifices 8 from the bottom plate 38 of the second basin 6.2 is indicated.
[0094] If the flow through the orifices 8 of the bottom plate 38 of the top basin 6.1 is larger than the flow through the orifices 8 of the bottom plate 38 of the second basin 6.2, the depth H.sub.2 will increase to a greater depth H.sub.3 as indicated in basin 6.2. Consequently, when the water level raises in a basin 6.1, 6.2, the flow through the flow through the orifices 8 of the bottom plate 38 will increase in accordance with equation (6):
Q=Σ.sub.i=1.sup.NA.sub.O(i)=NA.sub.Ou.sub.B=NA.sub.O√{square root over (2gH)} (6)
[0095] Accordingly, instead of extending the processing time according to the flow increment, the gas balancing filter is configured to automatically increase the flow out of a basin if the flow into the basin is increased.
LIST OF REFERENCE NUMERALS
[0096] 2 Gas balancing filter [0097] 4 Stream of water [0098] 6.1 Uppermost basin [0099] 6.2 Second basin [0100] 6.3 Third basin [0101] 6.4 Lowermost basin [0102] 8 Orifice [0103] 10 Free upper surface [0104] 14 Raised bottom part [0105] 16 Fan [0106] 18 Manifold [0107] 20 Aquatic animal culture [0108] 22 Supply line [0109] 24 Retrieval line [0110] 26 Manifold plate [0111] 28 Lowermost basin bottom [0112] 30 Upright outer sidewall [0113] 32 Biological water treatment facility [0114] 34 Range of openings [0115] 36 Partition wall [0116] 38 Bottom plate [0117] 40 Integrated support beams [0118] 42 Rail [0119] 44 Raised portion of bottom plate [0120] D Free fall distance [0121] Q.sub.Air Air flow [0122] Q.sub.Water Water flow [0123] Q, Q.sub.i Flow [0124] d Diameter of orifices [0125] H, H.sub.1, H.sub.2, H.sub.3 Depth [0126] P, P.sub.T, P.sub.B Pressure [0127] A.sub.Column 1, A.sub.Column 2 Area [0128] A.sub.O, A.sub.O(i) Orifice area [0129] X, Y, Z Axis [0130] P, P.sub.B, P.sub.T Pressure [0131] ρ Density [0132] u, u.sub.i, u.sub.T, u.sub.B, u.sub.B′ Velocity [0133] g Acceleration due to gravity [0134] y, y.sub.B, Y.sub.T Vertical position [0135] T Residence time [0136] N Number of orifices [0137] R, R.sub.L, R.sub.T Ratio between the total area of the orifices and the area of the bottom plate [0138] A.sub.basin Area of basin