PARALLEL-FLOW REGENERATIVE SHAFT KILN AND METHOD FOR CALCINING CARBONATE ROCK
20230257302 · 2023-08-17
Assignee
- MAERZ OFENBAU AG (Zurich, CH)
- Thyssenkrupp Ag (Essen, DE)
- thyssenkrupp Industrial Solutions AG (Essen, DE)
Inventors
Cpc classification
F27B1/24
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F27B1/005
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F27D2007/063
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F27B1/02
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F27D2019/0009
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F27B1/26
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
International classification
F27B1/02
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F27B1/00
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F27B1/24
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F27B1/26
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Abstract
A method for calcining and cooling material such as carbonate rocks may be employed in a parallel-flow regenerative shaft kiln that has two shafts, which are operated alternately as a calcining shaft and as a regenerative shaft. Material flows through a preheating zone, a calcining zone, and a cooling zone to a product outlet. At least one gas flow is compressed by a high-pressure fan and introduced into the parallel-flow regenerative shaft kiln. The high-pressure fan is configured as an axial fan or as a radial fan, having an impeller through which flow takes place axially or radially. A parallel-flow regenerative shaft kiln may also be utilized to perform such methods.
Claims
1.-17. (canceled)
18. A method for calcining and cooling material in a parallel-flow regenerative shaft kiln that has two shafts that are operated alternately as a calcining shaft and as a regenerative shaft, the method comprising: causing the material to flow through a preheating zone, a calcining zone, and a cooling zone to a product outlet; and compressing a gas flow with a high-pressure fan and introducing the gas flow into the parallel-flow regenerative shaft kiln, wherein the high-pressure fan is an axial fan or a radial fan that has an impeller through which flow takes place axially or radially.
19. The method of claim 18 wherein the gas flow comprises: a cooling air flow that is introduced into the cooling zone; a combustion air flow that is introduced into the preheating zone and/or the calcining zone; and/or a fuel gas flow that is introduced into the preheating zone and/or the calcining zone.
20. The method of claim 18 wherein for switchover between the operation of a first shaft as the calcining shaft and as the regenerative shaft, the method comprises: ending feeding of fuel into the first shaft operated as the calcining shaft; reducing a gas quantity to the high-pressure fan with a swirl regulator disposed in the high-pressure fan; closing a shutoff facility between the high-pressure fan and the first shaft so that less of or none of the gas flow compressed by the high-pressure fan enters the first shaft; opening a drain valve disposed downstream of the high-pressure fan to let gas compressed by the high-pressure fan out of a conduit; and feeding fuel into the a second of the two shafts.
21. The method of claim 18 wherein for switchover between the operation of a first shaft as the calcining shaft and as the regenerative shaft, the method comprises: ending feeding of fuel into the first shaft operated as the calcining shaft; reducing a speed of the high-pressure fan by not more than 50% to 65% and/or closing a shutoff facility between the high-pressure fan and the first shaft so that less of or none of the gas flow compressed by the high-pressure fan enters the first shaft; and feeding fuel into a second of the two shafts.
22. The method of claim 21 wherein simultaneously with or following the step whereby less or none of the gas flow compressed by the high-pressure fan enters the first shaft, the method comprises increasing a speed of an off-gas fan for conveying off-gas out of the parallel-flow regenerative shaft kiln.
23. The method of claim 21 wherein following the step whereby less or none of the gas flow compressed by the high-pressure fan enters the first shaft, the method comprises opening an off-gas shutoff facility in an off-gas conduit to conduct off-gases out of the first shaft operated as the calcining shaft.
24. The method of claim 18 comprising discharging calcined material from the parallel-flow regenerative shaft kiln with a discharge system, wherein the discharge system includes the product outlet and, downstream of the product outlet, a buffer store with a second product outlet, wherein the calcined material is discharged continuously from the parallel-flow regenerative shaft kiln during operation of a shaft as the calcining shaft, wherein there is no discharge of calcined material from the parallel-flow regenerative shaft kiln during switchover between the operation of a first shaft as the calcining shaft and the operation of the first shaft as the regenerative shaft.
25. The method of claim 18 comprising ascertaining a pressure within a first shaft of the two shafts, wherein the product outlet for letting calcined material out of the first shaft operated as calcining shaft is opened if the pressure falls below a predetermined limit.
26. A parallel-flow regenerative shaft kiln for calcining and cooling material, comprising: two shafts that are operated alternately as a calcining shaft and as a regenerative shaft, wherein each shaft in a flow direction of material has a preheating zone for preheating material, a calcining zone for calcining material, and a cooling zone for cooling material; and a high-pressure fan that is configured and disposed for compressing a gas stream introduced into the parallel-flow regenerative shaft kiln, wherein the high-pressure fan is configured as an axial fan or as a radial fan and includes an impeller through which flow can take place axially or radially.
27. The parallel-flow regenerative shaft kiln of claim 26 comprising: a combustion air inlet for letting combustion air and/or a fuel gas into the preheating zone and/or the calcining zone; and a cooling air inlet for letting cooling air into the cooling zone, wherein the combustion air inlet and/or the cooling air inlet is connected to the high-pressure fan or, respectively, to high-pressure fans.
28. The parallel-flow regenerative shaft kiln of claim 26 comprising an open-loop/closed-loop controller that is connected to a fuel inlet for letting in fuel gas and is configured to provide for an operating state for switchover between operation of a first shaft of the two shafts as the calcining shaft and operation of the first shaft as the regenerative shaft, wherein the open-loop/closed-loop controller is configured to stop feeding fuel gas through the fuel inlet during the switchover.
29. The parallel-flow regenerative shaft kiln of claim 28 wherein the open-loop/closed-loop controller is connected to the high-pressure fan and is configured to during the switchover reduce a speed of the high-pressure fan by not more than 50% to 65%.
30. The parallel-flow regenerative shaft kiln of claim 28 wherein each of the two shafts has an off-gas outlet for letting off-gases out of the respective shaft, wherein each off-gas outlet is connected to a fan, wherein the open-loop/closed-loop controller is configured to increase a speed of the fan during the switchover.
31. The parallel-flow regenerative shaft kiln of claim 30 wherein each off-gas outlet is connected via an off-gas conduit to the fan, wherein at least one off-gas shutoff facility is disposed in the off-gas conduit and is connected to the open-loop/closed-loop controller, wherein the open-loop/closed-loop controller is configured such that during the switchover the open-loop/closed-loop controller opens the off-gas shutoff facility following the increase of the speed of the fan.
32. The parallel-flow regenerative shaft kiln of claim 28 wherein each shaft of the two shafts has a product outlet for letting calcined material out of the respective shaft and has a pressure-measuring facility for ascertaining a pressure within the respective shaft, wherein the open-loop/closed-loop controller is connected to the product outlet and to the pressure-measuring facility of each shaft and is configured to open the respective product outlet if the pressure falls below a predetermined limit.
33. The parallel-flow regenerative shaft kiln of claim 26 wherein each shaft has a discharge system with a first product outlet for letting calcined material out of the respective shaft, a buffer store downstream of the first product outlet, and a second product outlet.
34. The parallel-flow regenerative shaft kiln of claim 28 wherein the high-pressure fan is a first high-pressure fan, the parallel-flow regenerative shaft kiln comprising a second high-pressure fan, wherein each high-pressure fan is assigned a shutoff facility that in a closed position prevents a flow of gas from the respective high-pressure fan into the shaft, wherein the open-loop/closed-loop controller is connected to the shutoff facility and is configured to move the shutoff facility into the closed position during the switchover.
Description
DESCRIPTION OF THE DRAWINGS
[0068] The invention is elucidated in more detail below by means of a number of exemplary embodiments with reference to the appended figures.
[0069]
[0070]
[0071]
[0072]
[0073] Each shaft 12 at its upper end also has a combustion air inlet 16 for letting combustion air or fuel gas in. The combustion air is, for example, air, oxygen-enriched air or pure oxygen. The fuel gas is, for example, blast-furnace gas or another fuel gas having a calorific value of less than 6.6 MJ/Nm.sup.3. Furthermore, each shaft 12 has an off-gas outlet 18 for letting kiln off-gases out of the respective shaft 12.
[0074] At the lower end of each shaft 12 there is a product outlet 20 for letting out the material calcined in the respective shaft 12. The product outlet 20 comprises, for example, flaps, which can be opened and closed automatically in particular. The calcined material is conducted for example into a bunker 22 which follows on from the product outlets 20 of the shafts 12. The bunker 22 is configured illustratively in the form of a hopper and has, illustratively, a bunker outlet 24 for letting the material out of the bunker 22. The bunker, furthermore, has an outgoing-air outlet 23 for letting outgoing air out of the bunker 22. The outgoing-air outlet 23 is followed by an outgoing-air filter 25 and a low-pressure fan 27 for dedusting the off-gas.
[0075] Each shaft 12 at its lower end has a cooling air inlet 26 for letting cooling air into the respective shaft 12. In the operation of the PFR shaft kiln 10, the material for calcining flows from top to bottom through the respective shaft 12, with the cooling air flowing through the respective shaft 12 from bottom to top, in countercurrent flow to the material. The kiln off-gas is removed from the shaft 12 through the off-gas outlet 18.
[0076] The materials inlet 14 and the combustion air inlet 16 are followed below them, in the flow direction of the material, by the preheating zone 28 of the respective shaft 12. In the preheating zone 28, the material and the combustion air or, optionally, the material and the fuel gas are preheated preferably to about 700° C. The respective shaft 12 is preferably filled with material for calcining up to the upper boundary face 30 of the preheating zone 28. The material and optionally the fuel, more particularly the fuel gas, are charged into the respective shaft 12 preferably above the preheating zone 28. At least part of the preheating zone 28, and the part of the respective shaft 12 that follows it in the flow direction of the material, are surrounded, for example with a refractory lining.
[0077] Disposed optionally in the preheating zone 28 are a plurality of burner lances 32, serving in each case as an inlet for fuel, such as a fuel gas, oil or ground solid fuel, for example. The PFR shaft kiln 10 preferably has a cooling facility 33 for cooling the burner lances. The cooling facility comprises a plurality of cooling-air circuit lines 35, which extend annularly around the shaft region in which the burner lances 32 are disposed. Cooling air for cooling the burner lances 32 flows through the cooling-air circuit lines 35.
[0078] In each shaft 12 there are preferably a plurality of—for example, twelve—burner lances 32, which are disposed at substantially uniform distances from one another. The burner lances 32 have an L shape, for example, and extend preferably in the horizontal direction into the respective shaft 12 and in a vertical direction within the shaft 12, more particularly in the flow direction of the material. The ends of the burner lances 32 of one shaft 12 are preferably all disposed at the same height level. The plane on which the ends of the lances 32 are disposed is preferably in each case the lower boundary face 34 of the respective preheating zone 32, 34. Alternatively or additionally to the burner lances 32, slits in the shaft wall may also form inlets for letting combustion air into the shaft.
[0079] The preheating zone 28 is followed in the flow direction of the material by the calcining zone 36. In the calcining zone 36, the fuel is burned and the preheated material is calcined at a temperature of about 1000° C. The PFR shaft kiln 10 additionally has an overflow duct 38 for providing a gas connection between the two shafts 12.
[0080] At the product outlet end of each shaft 12 there is preferably a discharge facility 44 disposed. The discharge facilities 44 comprise, for example, horizontal plates, preferably a discharge table 46, which allow the material to pass through laterally between the discharge table 46 and the housing wall of the PFR shaft kiln. The discharge facility 44 is implemented preferably as a push table or rotary table or as a table with push-type scraper means. This enables a uniform throughput rate of the calcination material through the shafts 12. The discharge facility 44 further comprises, illustratively, a discharge hopper 48, which follows the discharge table and has the product outlet 20 mounted on its lower end.
[0081] In the operation of the PFR shaft kiln 10, one of the shafts 12 is active in each case, with the respective other shaft 12 being passive. The active shaft 12 is referred to as the calcining shaft, and the passive shaft 12 as the regenerative shaft. The PFR shaft kiln 10 is operated cyclically; a typical number of cycles is, for example, 75 to 150 cycles per day. After the cycle time has expired, the function of the shafts 12 is swapped. This procedure is repeated continuously.
[0082] Material such as limestone or dolomite rock is charged into the shafts 12 in alternation via the materials inlets 14. In the shaft 12 operated as calcining shaft, a fuel or an oxidizing gas such as, for example, air, oxygen-enriched air or pure oxygen is introduced into the calcining shaft via the burner lances 32. The material for calcining is heated in the preheating zone 28 of the calcining shaft to a temperature of about 700° C.
[0083] The PFR shaft kiln 10 has, for example, a round, oval, rectangular or polygonal cross section. Furthermore, the PFR shaft kiln 10 optionally has a gas collector duct 50 in the form of an annular space. The gas collector duct 50 extends preferably circumferentially around the lower region of the calcining zone 36, more particularly below the burner lances 32. Each shaft 12 may have a respective gas collector duct 50, with the gas collector ducts 50 being disposed at the height level of the overflow duct 38 for connection of the two shafts 12. The gas collector ducts 50 of the two shafts 12 have a gas connection to one another by way in particular of the overflow duct 38. In particular, the gas collector duct 50 has a gas connection to the cooling zone 42, and so the cooling gas flows at least partly into the gas collector duct 50.
[0084] This construction leads advantageously to a more uniform distribution of gas and of temperature in the shafts 12 and hence to better product quality and lower pollutant emissions. Another advantage of this construction is that any unburned fuel gases which flow out of the preheating zone 28 into the overflow channel 38, together with the cooling air fed to the calcining shaft, undergo afterburning there more effectively, because the gas duct volume is substantially greater.
[0085] The PFR shaft kiln further comprises, preferably, a cooling facility 51 for cooling the shaft region which includes the calcining zone 36. In particular, the region of the calcining zone 36 that projects into the cooling zone 42 is cooled by means of the cooling facility 51. The cooling facility 51 preferably comprises a plurality of circuit lines 52, which extend externally around the calcining zone of the shaft 12 and through which cooling air flows. Illustratively, the circuit lines 52 are mounted only around the lower region—the region adjacent to the cooling zone 42—of the calcining zone 36.
[0086] The combustion air inlet 16, the cooling air inlet 26, the burner lances 32, and the cooling-air circuit lines 35, 52 are each connected via conduits to a fan 55a,b, more particularly a high-pressure fan 54a-c. The high-pressure fans 54a-c serve to compress the respective process gases and are preferably configured in such a way that they each generate a pressure of about 300 mbar to 500 mbar, more particularly about 400 mbar. Each fan 55a-c, and each high-pressure fan 54a-c, is preferably assigned a shutoff facility 57a-e. The shutoff facility is, for example, a flap or a valve and is preferably configured in such a way that in a closed position it prevents a flow of gas from the respective fan 54a-c, 55a-c, more particularly from the high-pressure fan 54a-c, into the shaft 12. The combustion air conduit 62 and the cooling air conduits 56, 60, 68 preferably each have a shutoff facility 57a-e which is downstream of the respective fan 54a-c, 55a-c. In the closed position of the shutoff facility 57, there is preferably no possibility of a flow of gas from the respective conduit 56, 60, 62, 68 into the surroundings.
[0087] The cooling air inlet 26, for letting cooling air into the cooling zone 42, is connected more particularly to a high-pressure fan 54a via a cooling air conduit 56. The cooling air conduit 56 comprises a depressurization facility 58, such as a valve or a flap, for example, which can be brought, preferably steplessly, from an open position, in which cooling air flows from the cooling air conduit 56 into the surroundings, into a closed position, in which no cooling air emerges from the cooling air conduit 56.
[0088] The cooling facility 51 for cooling the shaft region which includes the calcining zone is connected, preferably via a cooling air conduit 60, to a fan 55a and optionally to a further fan 55b. The fans 55a, b are configured for example as medium-pressure or high-pressure fans, and so they generate in particular a pressure of about 50 mbar to 150 mbar, preferably 80 mbar to 120 mbar, more particularly 100 mbar.
[0089] The combustion air inlet 16, for letting combustion air into the preheating zone 28, is connected more particularly to a high-pressure fan 54b via a combustion air conduit 62. The combustion air conduit 62 comprises a depressurization facility 64, such as a valve or a flap, for example, which can be brought preferably steplessly from an open position, in which combustion air flows from the combustion air conduit 62 into the surroundings, into a closed position, in which no combustion air emerges from the combustion air conduit 62. Combustion air conduit 62 further preferably comprises a distributor facility 66, such as, for example, a gas diverter or a flap for conducting the combustion air to the respective shaft 12 operated as calcining shaft. The configuration of the distributor facility 66 is preferably such that it can be operated in at least two position: in a first position, combustion air is able to flow exclusively into the combustion air inlet 16 of the first shaft 12, and, in a second position, combustion air is able to flow exclusively into the combustion air inlet 16 of the second shaft 12.
[0090] The cooling facility 33 for cooling the burner lances 32, more particularly the cooling-air circuit line 35, is connected preferably via a cooling air conduit 68 to a high-pressure fan 54c.
[0091] The off-gas outlet 18 for letting the kiln off-gases out of the PFR shaft kiln is connected to a fan 55c preferably via an off-gas conduit 70. The fan 55c is configured, for example, for medium pressure, and so it generates in particular a pressure of about 20 mbar to 60 mbar, preferably 25 mbar to 50 mbar, more particularly 35 mbar. Furthermore, the off-gas outlet 18 is connected preferably to an off-gas filter 72 disposed upstream of the fan 55c. The off-gas conduit 70 additionally has, illustratively, two off-gas shutoff facilities 71, more particularly valves or flaps. In the flow direction of the off-gas, downstream of each off-gas outlet 18, there is preferably a respective off-gas shutoff facility 71 disposed, and so each off-gas outlet is preferably assigned an off-gas shutoff facility 71. The off-gas shutoff facility 71 can be moved between a closed position, in which no off-gas can flow from the shaft 12 through the off-gas conduit 70, and an open position, in which off-gas can flow through the off-gas conduit 70.
[0092] Optionally it is conceivable to charge the fuel, more particularly the fuel gas, into the calcining shaft of the PFR shaft kiln 10 by way of the combustion air inlet 16. In this embodiment of the PFR shaft kiln, the fuel gas is more particularly blast-furnace gas, having for example a calorific value of less than 6.6 MJ/Nm.sup.3. The fuel gas 63, more particularly the blast-furnace gas, is introduced in this embodiment into the combustion air conduit 62, and the combustion air is guided in particular through the burner lances into the shaft 12. The combustion air is, for example, oxygen-containing air, more particularly oxygen-enriched air, or a gas having an oxygen fraction of about 80%, or virtually pure oxygen.
[0093] This method reduces the quantities of gas which flow through the calcining zone 36 and through the preheating zone 28 of the regenerative shaft considerably; the gases flowing through the preheating zone 28 of the regenerative shaft contain no excess heat and preferably have an off-gas temperature of around 100° C. Owing to the smaller quantities of gas there is a considerable reduction in the pressure loss of the kiln as a whole, leading to a considerable saving in terms of electrical energy at the process gas compressors.
[0094]
[0095]
[0096]
[0097] The PFR shaft kiln 10 of
[0098] In the operation of the PFR shaft kiln 10 represented in
[0107] The open-loop/closed-loop controller 78 is preferably configured to provide open-loop/closed-loop control of the method steps described above.
[0108] In the case of a connection system of the high-pressure fans 57a-c as represented in
[0119] In step b the quantity of gas is reduced by—for example—at least 50% to 65%. The quantity of gas is reduced by means of the swirl regulator 53, more particularly by way of a change to the work angles of the guide vanes of the swirl regulator 53. During the switchover procedure, the speed of the high-pressure fan 54a-c is preferably kept substantially constant or is reduced only slightly, more particularly by not more than 10% to 30%.
[0120] The quantity of gas which flows through the conduit into the high-pressure fan 54a-c is preferably ascertained by means of the flow rate-measuring facility 47. The opening width of the drain valve 49 is preferably steplessly adjustable. The opening width of the drain valve 49 and/or the swirl regulator 53 are/is preferably adjusted as a function of the quantity of gas ascertained by means of the flow rate-measuring facility 47. A target value for the quantity of gas is preferably determined beforehand.
[0121] If the figure ascertained for the quantity of gas exceeds the predetermined target value, then for example the swirl regulator 53 is adjusted, and more particularly the work angle of the guide vanes is adjusted, in such a way that the quantity of gas entering the high-pressure fan 54a-c is reduced. If the value ascertained for the quantity of gas falls below the predetermined target value, then for example the swirl regulator 53, and more particularly the work angle of the guide vanes, is adjusted in such a way that the quantity of gas entering the high-pressure fan 54a-c is increased.
[0122] If the value ascertained for the quantity of gas exceeds the predetermined target value, the opening width of the drain valve 49 is preferably increased. If the value ascertained for the quantity of gas falls below the predetermined target value, the opening width of the drain valve 49 is reduced.
[0123] The connection system represented in
LIST OF REFERENCE SYMBOLS
[0124] 10 PFR shaft kiln [0125] 12 shaft [0126] 14 materials inlet for letting in limestone [0127] 16 combustion air inlet [0128] 18 off-gas outlet [0129] 20 product outlet [0130] 22 bunker [0131] 23 outgoing-air outlet [0132] 24 bunker outlet [0133] 25 outgoing-air filter [0134] 26 cooling air inlet [0135] 27 low-pressure fan [0136] 28 preheating zone [0137] 30 upper boundary face of the preheating zone [0138] 32 burner lances [0139] 33 cooling facility [0140] 34 lower boundary face of the preheating zone/upper boundary face of the calcining zone [0141] 35 cooling-air circuit lines [0142] 36 calcining zone [0143] 38 overflow duct [0144] 40 lower boundary face of the calcining zone/upper boundary face of the cooling zone [0145] 42 cooling zone [0146] 44 discharge facility [0147] 45 pressure-measuring facility [0148] 46 discharge table [0149] 47 flow rate-measuring facility [0150] 48 discharge hopper [0151] 49 drain valve [0152] 50 gas collector duct [0153] 51 cooling facility [0154] 52 cooling-air circuit lines [0155] 53 swirl regulator [0156] 54a-c high-pressure fan [0157] 55a-c fan [0158] 56 cooling air conduit [0159] 57a-e shutoff facility [0160] 58 depressurization facility [0161] 60 cooling air conduit [0162] 62 combustion air conduit [0163] 63 fuel gas [0164] 64 depressurization facility [0165] 66 distributor facility [0166] 68 cooling air conduit [0167] 70 off-gas conduit [0168] 71 off-gas shutoff facility [0169] 72 off-gas filter [0170] 74 buffer store [0171] 75 discharge system [0172] 76 product outlet [0173] 78 open-loop/closed-loop controller