System and method for monitoring a fire suppression blend

Abstract

Disclosed herein is a system and method for monitoring a gaseous fire suppression blend. The system includes a sensor array having a plurality of sensors disposed in a protected space, wherein the sensor array can detect and quantify more than one component of the gaseous fire suppression blend.

Claims

1. A system for monitoring a gaseous fire suppression blend comprising: a sensor array having a plurality of sensors disposed in a protected space, wherein the sensor array detects and quantifies a first fire suppression agent of the gaseous fire suppression blend using absorption at a first characteristic wavelength and the sensor array detects and quantifies a second fire suppression agent of the gaseous fire suppression blend using absorption at a second characteristic wavelength wherein the first characteristic wavelength is different from the second characteristic wavelength.

2. The system of claim 1, wherein each of the plurality of sensors are optical sensors that emit and detect multiple wavelengths.

3. The system of claim 2, wherein each of the plurality of optical sensors has a lower detection limit less than a desired minimum concentration of the gaseous fire suppression blend components.

4. The system of claim 2, wherein each of the plurality of optical sensors has an upper detection limit greater than a maximum allowed concentration of the gaseous fire suppression blend components.

5. The system of claim 2, wherein signals from the plurality of optical sensors are processed by a central control unit.

6. The system of claim 5, wherein the plurality of optical sensors are connected to the central control unit by fiber optic cable.

7. The system of claim 1, wherein each of the plurality of sensors comprise a single source which can emit multiple wavelengths and a single detector which can detect multiple wavelengths.

8. The system of claim 1, wherein each of the plurality of sensors comprise a single source which can emit multiple wavelengths and multiple detectors which can detect single wavelengths.

9. The system of claim 1, wherein each of the plurality of sensors comprise multiple sources which emit single wavelengths and multiple detectors which detect single wavelengths.

10. The system of claim 1, wherein the plurality of sensors are disposed at different locations in the protected space.

11. The system of claim 1, wherein the plurality of sensors comprise sensor tubes and a vacuum source.

12. The system of claim 11, wherein the sensor tubes are in operable communication with a central analyzer.

13. The system of claim 12, wherein the central analyzer comprises a central spectrophotometer that emits and detects multiple wavelengths.

14. The system of claim 1, wherein the first and second wavelengths are chosen from the group consisting of 268 nm, 307 nm, 3000 cm.sup.−1, 2360 cm.sup.−1, and 1680-1640 cm.sup.−1.

15. A method of monitoring a gaseous fire suppression blend in a protected space comprising: measuring absorption at a first characteristic wavelength and a second characteristic wavelength using a sensor array and determining concentration of a first fire suppression agent of the gaseous fire suppression blend based on the absorption at the first characteristic wavelength and determining concentration of a second fire suppression agent of the gaseous of the fire suppression blend based on the absorption at the second characteristic wavelength.

16. The method of claim 15, wherein the concentrations of the first and second components of the gaseous fire suppression blend is measured over time using multiple samples.

17. The method of claim 15, wherein the concentrations of the first and second components of the gaseous fire suppression blend is measured continuously.

18. The method of claim 15, wherein light absorption of the sample at the characteristic wavelengths is compared to a calibration curve to determine concentration.

19. The method of claim 15, wherein measuring the concentration employs sensors located at the different locations in the protected space.

20. The method of claim 15, wherein measuring the concentration employs a central analyzer using samples collected by sensors located at different locations in the protected space.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) The following descriptions should not be considered limiting in any way. With reference to the accompanying drawings, like elements are numbered alike:

(2) FIGS. 1 and 2 show exemplary systems for monitoring a gaseous fire suppression blend.

DETAILED DESCRIPTION

(3) A detailed description of one or more embodiments of the disclosed apparatus and method are presented herein by way of exemplification and not limitation with reference to the Figures.

(4) Due to concerns about ozone depletion associated with HALON 1301 there is great interest in developing the use of gaseous fire suppression blends that pose less of an ozone depletion risk. Suggested replacements for HALON 1301 include CF.sub.3I and blends including CF.sub.3I such as CF.sub.3I/HFC-125, CF.sub.3I/HCFO-1233zd(E), CF.sub.3I/Novec 1230 and CF.sub.3I/CO.sub.2. Currently there is no system or method for detecting the different components of these blends simultaneously or their distribution in a protected space. Each component of the gaseous fire suppression blend may have different distribution rate in the protected space due to differences in molecular weight and other physical characteristics. Accordingly, there is currently no way to assure that the desired blend proportions are distributed throughout the volume (space) to be protected.

(5) This need can be addressed by a system and method for monitoring the concentration of gaseous fire suppression blend components. The system and method take advantage of the fact that each component of the gaseous fire suppression blend has at least one characteristic wavelength. A characteristic wavelength is defined herein as a wavelength at which only one component of the gaseous fire suppression blend absorbs. This allows the system and method disclosed herein to use the characteristic wavelength for each component to determine the concentration of that component in the sample taken from that location at that point in time. Because the method of measurement is non-destructive the same sample can be used to determine the concentration of each component of the gaseous fire suppression blend. It is contemplated that useful wavelengths include wavelengths in the infrared, visible and ultraviolet spectrums. Exemplary components and wavelengths are shown in the table below.

(6) TABLE-US-00001 Spectral Characteristic Suppression Agent Region Frequency Reason CF.sub.3I UV 268 nm C—I electronic Transition Novec 1230 UV 307 nm C═O electronic transition HFC-125 IR 3000 cm.sup.−1 C—H stretch CO.sub.2 IR 2360 cm.sup.−1 C═O Stretch HCFO-1233zd(E) IR 1680-1640 cm.sup.−1 C═C stretch

(7) The amount of absorption can be correlated to the corresponding concentration of the component using a calibration curve established using known concentrations the component to generate the curve.

(8) Exemplary blends and the associated wavelength combinations are shown in the following table.

(9) TABLE-US-00002 Blend No. Component 1 Component 2 Frequencies 1 CF.sub.3I HFC-125 268 nm/3000 cm.sup.−1 2 CF.sub.3I Novec 1230 268 nm/307 nm .sup.  3 CF.sub.3I CO.sub.2 268 nm/2360 cm.sup.−1 4 CF.sub.3I HCFO-1233zd(E) 268 nm/1680 cm.sup.−1 5 Novec 1230 CO.sub.2 307 nm/2360 cm.sup.−1

(10) The system includes a sensor array. The sensor array includes a plurality of sensors disposed in the protected space. The sensor array may include greater than or equal to 10 sensors, or, greater than or equal to 15 sensors, or, greater than or equal to 20 sensors. The sensors may distributed throughout the protected space at regular intervals or a specified locations.

(11) The sensor may be an optical sensor which can emit and detect the desired wavelengths. The sensor may include several subunits each of which can emit and detect a single wavelength or a range of wavelengths. Alternatively, the sensor may include a multiwavelength source and a multiwavelength detector. In yet another option, the sensor may include a multiwavelength source and multiple detectors. The sensor may transmit the data to a central control unit to be compared to an appropriate calibration curve. Alternatively, the data can be compared to an appropriate calibration curve within the sensor and the results transmitted to a central unit.

(12) The optical sensors may be connected to the central control unit using fiber optic cable. When connected by fiber optic cable the central control unit may function as the light source with the detector(s) located within the sensor. The sensor can include a single detector for multiple wavelengths, multiple detectors for single wavelengths or multiple detectors which can detect a range of wavelengths.

(13) The optical sensor has a lower detection limit less half than the desired minimum concentration of the gaseous fire suppression blend component that it is measuring. The lower detection limit of the optical sensor may be an order of magnitude less than the desired minimum concentration of the gaseous fire suppression blend component. The optical sensor has an upper detection limit two times greater than a maximum allowed concentration of the gaseous fire suppression blend component it is measuring.

(14) Alternatively the sensor may include a vacuum pump and sensor tubes which obtain samples and communicate the samples to a central analyzer for analysis. The central analyzer may be a spectrophotometer that employs the desired wavelengths and correlates the absorption to concentration using a calibration curve. The central analyzer has a lower detection limit less than half the desired minimum concentration of the gaseous fire suppression blend components and an upper detection limit two times greater than the maximum allowed concentration of the gaseous fire suppression blend components.

(15) The protected space may be sampled at a single point in time, at several points in time, or over a period time. When sampled over a period of time multiple samples/data points may be obtained or the protected space may be sampled continuously.

(16) Turning now to the Figures, FIG. 1 shows an exemplary system for monitoring a gaseous fire suppression blend. Multiple sensors 20 are located in a protected space 10. Only one sensor 20 is shown in FIG. 1 for simplicity. Each sensor includes subunits 30, each having a wavelength source and detector. Each sensor subunit is connected to a central control unit 50 by fiber optic cables 40. While FIG. 1 shows each sensor subunit individually connected, it is also contemplated that the subunits from a single sensor may be connected to the central control unit through a shared connection. The central control unit may be optionally connected to a data collection and storage device 60.

(17) FIG. 2 shoes an exemplary system for monitoring a gaseous fire suppression blend. Multiple sensors 20 are located in a protected space 10. One sensor is shown for simplicity. The sensor 20 includes at least one tube 70 that can withdraw the sample from the protected space using a vacuum (vacuum source not shown). While FIG. 2 shows sensor 20 employing two tubes 70 it is contemplated that a single tube could suffice because the measurement method is non-destructive. The tubes 70 deliver the samples to the central analyzer 80. When there is a single tube connecting the sensor and the central analyzer the central analyzer will analyze for the components of the blend as desired. There is also the possibility of two central analyzers. The central analyzer may be optionally connected to a data collection and storage device 60.

(18) The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the present disclosure. As used herein, the singular forms “a”, “an” and “the” are intended to include the plural forms as well, unless the context clearly indicates otherwise. It will be further understood that the terms “comprises” and/or “comprising,” when used in this specification, specify the presence of stated features, integers, steps, operations, elements, and/or components, but do not preclude the presence or addition of one or more other features, integers, steps, operations, element components, and/or groups thereof.

(19) While the disclosure has been described with reference to an exemplary embodiment or embodiments, it will be understood by those skilled in the art that various changes may be made and equivalents may be substituted for elements thereof without departing from the scope of the present disclosure. In addition, many modifications may be made to adapt a particular situation or material to the teachings of the present disclosure without departing from the essential scope thereof. Therefore, it is intended that the disclosure not be limited to the particular embodiment disclosed as the best mode contemplated for carrying out this disclosure, but that the disclosure will include all embodiments falling within the scope of the claims.