BEARING ASSEMBLY WITH SURFACE LAYER

Abstract

A bearing assembly is disclosed that includes a first component with a first bearing surface, and a second component with a second bearing surface. A fluid is disposed between the first bearing surface and the second bearing surface supporting the first bearing surface and the second bearing surface in a non-contact rotational relationship. The first bearing surface, or the second bearing surface, or both the first bearing surface and the second bearing surface include a surface layer with solid lubricant 2D nanoparticles in a matrix.

Claims

1.-17. (canceled)

18. A bearing comprising a support, a bump foil over the support, a top foil over the bump foil, and a surface layer over the bump foil comprising solid lubricant 2D nanoparticles in a matrix, said nanoparticles having 1 to 20 atoms along a first dimension and being present in the surface layer in a concentration of 35 wt. % to 72 wt. % based on total weight of the surface layer.

19. The bearing of claim 18, wherein the solid lubricant 2D nanoparticles comprise graphene, hexagonal boron nitride, molybdenum disulfide or combinations thereof graphene.

20. The bearing of claim 18, wherein the solid lubricant 2D nanoparticles have a thickness of 1 to 20 atomic layers and include an x-y planar dimension of 10 nm to 25 μm.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0005] Subject matter of this disclosure is particularly pointed out and distinctly claimed in the claims at the conclusion of the specification. The foregoing and other features, and advantages of the present disclosure are apparent from the following detailed description taken in conjunction with the accompanying drawings in which:

[0006] FIG. 1 is a partial cross-sectional view of an example embodiment of a journal bearing;

[0007] FIG. 2 is a partial exploded view of an example embodiment thrust bearing; and

[0008] FIG. 3 is a schematic cross-sectional view of an air cycle machine.

DETAILED DESCRIPTION

[0009] With reference now to the Figures, FIG. 1 is a cross-sectional view of an example embodiment of a fluid film journal bearing assembly (journal bearing 100). The journal bearing 100 includes a journal sleeve 102 that defines an outer diameter surface 104 and an inner diameter surface 106. The journal sleeve 102 is substantially cylindrical and is arranged about a central axis. It should be noted that the journal sleeve can have a conventional cylindrical shape, or can be shaped with a weight-reduced profile, or configured as other shapes or configurations, and FIG. 1 merely presents an exemplary configuration of a journal bearing 100.

[0010] In FIG. 1, a number of foils are arranged inside the journal sleeve 102. The journal bearing 100 includes a bump foil 108, an intermediate foil 110, and a top foil 122. The bump foil 108, the intermediate foil 110, and the top foil 112 are each formed from thin sheets of material (e.g., nickel-based alloys, steel, or similar materials) wrapped in a generally cylindrical shape and positioned in a bore of the journal sleeve 102. The bump foil 108 is corrugated, allowing a working fluid and/or cooling fluid to flow through the spaces formed between adjacent corrugations. The bump foil 108 is positioned adjacent to the inner diameter surface 106 of the journal sleeve 102. The foils 108, 110, and 112 are retained relative to the journal sleeve 102 with bent portions 114 that engage a key slot 116. A rotating component 118, such as a shaft can be positioned inside the journal bearing 100, radially inward from the top foil 112. The rotating component 118 is typically in close proximity to the top foil 112, but for ease of illustration is shown in a partial exploded view with an exaggerated distance between the top foil 112 and the rotating component 118. During operation, moving air generated by action of the rotating component 118 urges pressurized air radially outward against the compliant foil structure 108, 110, and 112 to create a fluid air layer separating the rotating component 118 and the journal bearing 100.

[0011] As further shown in FIG. 1, a surface layer 120, which is exposed to a bearing surface of a rotating component, is disposed over (in this case, radially inward from) the top foil 112. The surface layer 120 comprises solid lubricant 2D nanoparticles in a matrix. In some embodiments, the surface layer can have a thickness in a range with a low end of 2 nm, 8, nm, or 12 nm, and a high end of 65 nm, 40 nm, or 20 nm. All possible combinations of the above-mentioned range endpoints (excluding impossible combinations where a low endpoint would have a greater value than a high endpoint) are explicitly included herein as disclosed ranges. The surface layers discussed herein can be included as a surface layer on either or both of the bearing surfaces of relative motion. For example, in the case of the example embodiment such as FIG. 1 showing a bearing assembly comprising a rotating member 118 and a journal bearing 100, the surface layer can be on the surface of the bearing surface on the radially inner surface of top foil 112 as shown for surface layer 120 in FIG. 1, or the surface layer can be on the radially outer surface of the rotating member 118, or the surface layer can be on the surface of the bearing surface on the radially inner surface of top foil 112 as shown for surface layer 120 in FIG. 1 and on the radially outer surface of the rotating member 118.

[0012] The matrix of a surface layer such as surface layer 120 can include any sort of matrix material, including but not limited to polymers, ceramics, metal, or matrix materials that can form a continuous phase. In some embodiments, the matrix material comprises a polyamide polymer, a polyimide polymer, or a copolymer comprising polyamide or polyimide segments. In some embodiments, the matrix material comprises a polyamide-polyimide copolymer. Various application techniques for creation or application of the surface layer can be utilized by the skilled person. For example, a surface layer can be applied as a polymer coating by spray application of a liquid or powder coating composition comprising a polymer matrix material and dispersed solid lubricant 2D nanoparticles followed by curing to coalesce and solidify the coating. In some embodiments, the solid lubricant 2D nanoparticles are present in the surface layer at a concentration in a range with a low end of 35 wt. %, 45 wt. %, or 58 wt. %, and a high end of 72 wt. %, 68 wt. %, or 62 wt. %, based on the total coating solids. All possible combinations of the above-mentioned range endpoints (excluding impossible combinations where a low endpoint would have a greater value than a high endpoint) are explicitly included herein as disclosed ranges. The surface layer can also include various other materials. For example, in the case of polymer coatings, the surface layer can include various polymer coating additives (e.g., curing agents, antioxidants, coating aids, fillers, etc.).

[0013] Various materials can be utilized as solid lubricant 2D nanoparticles. As used herein, the term “2D” includes particles with a smallest dimension, or thickness, of 1 to 20 molecular layers, and one or more anisotropic dimensions along lines or planes that diverge from the thickness. In some embodiments, the anisotropic dimensions can extend beyond 100 nm, although this is not necessary. In some embodiments, the 2D nanoparticles can have an aspect ratio, defined as the ratio of the largest dimension to the smallest dimension of at least 10. In some embodiments, the 2D nanoparticles can have an aspect ratio, defined as the ratio of the largest dimension to the smallest dimension of at least 100. In some embodiments, the 2D nanoparticles can have an even higher aspect ratio of at least 2500. Higher levels of aspect ratios can be obtained at relatively complete levels of exfoliation, including to the level of a single molecular layer. As mentioned above, the 2D nanoparticles can have a thickness ranging from 1 to 20 molecular layers. In some embodiments, the 2D nanoparticles can have a thickness ranging from 1 to 15 molecular layers. In some embodiments, the 2D nanoparticles can have a thickness ranging from 1 to 10 molecular layers. In some embodiments, the 2D nanoparticles can have a thickness ranging from 1 to 5 molecular layers. In some embodiments, the 2D nanoparticles can have a thickness ranging from 1 to 4 molecular layers. In some embodiments, the 2D nanoparticles can have a thickness ranging from 1 to 3 molecular layers. In some embodiments, the 2D nanoparticles can have a thickness ranging from 1 to 2 molecular layers. In some embodiments, the 2D nanoparticles can have a thickness of 1 molecular layer. In some embodiments, the 2D nanoparticles can have a have a mean diameter in a range with a low end of 10 nm, 90 nm, or 1 μm, and a high end of 13 μm, 7 μm, or 5 μm. Mean diameter for 2D nanoparticles can be determined using commercially available electron microscopy measurement tools. All possible combinations of the above-mentioned range endpoints (excluding impossible combinations where a low endpoint would have a greater value than a high endpoint) are explicitly included herein as disclosed ranges. As the term “lubricant” is used herein with respect to the solid 2D nanoparticles, the solid 2D nanoparticles are considered as “lubricant” nanoparticles if the coating has a coefficient of friction that is less than a coefficient of friction of a comparison coating of the same matrix material but without the solid 2D nanoparticles. Examples of materials for the solid lubricant 2D nanoparticles include graphene, hexagonal boron nitride, or molybdenum disulfide. In some embodiments, the surface layer can include lubricant materials in addition to the solid lubricant 2D nanoparticles. Examples of such additional solid lubricant particles or nanoparticles include particles or nanoparticles of materials such as graphene, hexagonal boron nitride, or hexagonal molybdenum disulfide of different particle sizes than the solid lubricant 2D nanoparticles.

[0014] Solid 2D nanoparticles can be prepared by various techniques. Graphene, for example, can be prepared by different techniques including chemical vapor deposition onto a substrate up to a target thickness followed by removal of graphene from the substrate. Solid 2D nanoparticles, including graphene, hexagonal boron nitride, and hexagonal molybdenum disulfide, can also be prepared by exfoliation of a parent molecular three-dimensional material such as graphite, unexfoliated hexagonal boron nitride, or unexfoliated hexaganol molybdenum disulfide. Various exfoliation techniques can be used, including mechanical exfoliation, sonic exfoliation, thermal exfoliation, or chemical exfoliation. Many exfoliation techniques can be controlled (e.g., by controlling duration, reaction conditions such as agitation speed or temperature, or materials, or both duration and reaction conditions or materials) to produce solid 2D nanoparticles with particle size and configuration in a target range.

[0015] The bearing assembly shown in FIG. 1 is just one of many possible example embodiments. Another example embodiment is shown in FIG. 2, in which an exploded view is shown of an example embodiment of a hydrodynamic fluid film thrust bearing assembly (“thrust bearing 200”), which represents another type of foil hydrodynamic bearing. As is apparent from the Figures, the thrust bearing 200 of FIG. 2 has a different construction than the journal bearing 100 of FIG. 1. This is because journal bearings, such as shown in FIG. 1, operate with radial loads, whereas thrust bearings, as shown in FIG. 2, operate with axial loads. However, both types of bearings operate similarly by employing hydrodynamic fluid films, such as air or other fluids, to both provide bearing lubricant and cooling.

[0016] In the example embodiment of FIG. 2, the thrust bearing 200 includes three layers, but may include more or fewer layers. A first layer 202 comprises multiple arcuate top foils 204 that are spaced circumferentially relative to one another about a central axis. The top foils 204 are supported by a second layer 206 having a corresponding number of arcuate bump foils 208 arranged circumferentially beneath the top foils 204. The bump foils 208 are corrugated to provide cushioning and accommodate a cooling airflow through the thrust bearing 200. A third layer 210 is provided as an annular main plate 212 that supports the bump foils 208. The three layers 202, 206, and 210 can be secured to one another, for example, by spot welding. A rotating component 214, such as a thrust plate on an end of a rotating shaft can be positioned adjacent to the top foils 204. The rotating component 214 is typically in close proximity to the top foils 204, but for ease of illustration is shown in a partial exploded view with an exaggerated distance between the top foil 204 and the rotating component 214. During operation, moving air generated by action of the rotating component 214 urges pressurized air against the compliant foil structure to create a fluid air layer separating the rotating component 214 and the thrust bearing 200. As with the journal bearing 100 of FIG. 1, the surface layer (not shown) can be on the surface of the bearing surface on the radially inner surface of top foil 204, or the surface layer can be on the radially outer surface of the rotating component 214, or the surface layer can be on the surface of the bearing surface on the radially inner surface of top foil 204 and on the radially outer surface of the rotating component 214.

[0017] In some embodiments, the above described hydrodynamic bearings can be employed in an air cycle machine such as those employed on aircraft. The hydrodynamic bearings provide a long lasting bearing with minimal to no required maintenance. This is because the bearings employ air as both a lubricating fluid and as a cooling fluid, which means that separate lubricating or cooling liquids are not typically required. An example embodiment of an air cycle machine is shown in FIG. 3. As shown in FIG. 3, an air cycle machine 300 is part of an environmental control system that is configured to supply conditioned air, for example, to a cabin of an aircraft. The air cycle machine 300 is a four-wheel air cycle machine, with four rotors on a single shaft 304. The four rotors are fixed together and are supported by bearing elements. There are, thus, four bearings configured within the air cycle machine 300 which are arranged along an airflow passage 306, which is represented by the path of arrows in FIG. 3. The air flow passage 306 provides air as both a lubricating fluid for the hydrodynamic bearings and as a cooling air flow to remove heat generated by the bearings during operation.

[0018] In the example configuration of FIG. 3, two of the four bearings are thrust bearings and two are journal bearings, as described above. The thrust bearings are located at the inlet side of the airflow passage 306, with the journal bearings located further downstream in the airflow passage 306. A first thrust bearing 308 is configured as an outboard thrust bearing and a second thrust bearing 310 is configured as an inboard thrust bearing. After the thrust bearings 308 and 310, in the direction of the airflow passage 306, a first journal bearing 312 is configured as a turbine journal bearing and then, toward the outlet of the airflow passage 306, a second journal bearing 314 is configured as a fan journal bearing. The thrust bearings 308 and 310 are configured to operate with axial loads, and the journal bearings 312 and 314 are configured to operate with radial loads within the engine 302. As a non-limiting example, the air cycle machine 300 may operate at 20,000-50,000 RPM. However, other rotational speeds of operation may be used.

[0019] While the present disclosure has been described in detail in connection with only a limited number of embodiments, it should be readily understood that the present disclosure is not limited to such disclosed embodiments. Rather, the present disclosure can be modified to incorporate any number of variations, alterations, substitutions or equivalent arrangements not heretofore described, but which are commensurate with the spirit and scope of the present disclosure. Additionally, while various embodiments of the present disclosure have been described, it is to be understood that aspects of the present disclosure may include only some of the described embodiments. Accordingly, the present disclosure is not to be seen as limited by the foregoing description, but is only limited by the scope of the appended claims.