Methods of forming laminated glass structures
11318717 · 2022-05-03
Assignee
Inventors
- Dominick John Forenz (Hammondsport, NY, US)
- Michael William Price (Corning, NY, US)
- Mary Rosettie (Corning, NY, US)
- Eric Joseph Teator (Corning, NY, US)
Cpc classification
B32B17/1099
PERFORMING OPERATIONS; TRANSPORTING
B32B17/10247
PERFORMING OPERATIONS; TRANSPORTING
B28D7/02
PERFORMING OPERATIONS; TRANSPORTING
B28D1/183
PERFORMING OPERATIONS; TRANSPORTING
B28D1/04
PERFORMING OPERATIONS; TRANSPORTING
B32B17/10018
PERFORMING OPERATIONS; TRANSPORTING
B28D1/18
PERFORMING OPERATIONS; TRANSPORTING
International classification
B32B7/14
PERFORMING OPERATIONS; TRANSPORTING
C03B33/07
CHEMISTRY; METALLURGY
B28D1/04
PERFORMING OPERATIONS; TRANSPORTING
B28D1/18
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A method of field shaping a laminated glass structure is provided. The method includes providing the laminated glass structure comprising a flexible glass sheet having a thickness of no greater than about 0.3 mm laminated to a non-glass substrate by an adhesive material. The laminated glass structure is field cut using a handheld power tool thereby forming a shaped laminated glass structure. An edge strength of a cut edge of the shaped laminated glass structure at least about 20 MPa.
Claims
1. A method of field shaping a laminated glass structure, the method comprising: providing the laminated glass structure comprising a flexible glass sheet having a thickness of no greater than about 0.3 mm laminated to a non-glass substrate by an adhesive material; supporting the laminated glass structure on a support surface such that the non-glass substrate is located between the flexible glass sheet and the support surface; field cutting the laminated glass structure using a cutting tool of a handheld power tool in a climb cut orientation applying a compressive force to a surface of the flexible glass sheet that is opposite the non-glass substrate in a direction of movement of the handheld power tool thereby forming a shaped laminated glass structure; finishing a cut edge of the shaped laminated glass structures to form a finished cut edge wherein said finishing uses abrasive particles having an average diameter of less than about ¼ of the thickness of the flexible glass sheet and wherein a glass edge strength of the finished cut edge of the shaped laminated glass structure is at least about 20 MPa.
2. The method of claim 1, wherein a glass edge strength of a cut edge of the shaped laminated glass structure is at least about 50 MPa.
3. The method of claim 1, wherein the step of field cutting comprises cutting the laminated glass structure at an installation location for the shaped laminated glass structure.
4. The method of claim 1, further comprising applying a mask along an intended cutting line on a surface of the flexible glass sheet.
5. The method of claim 1, further comprising applying a fluid to a surface of the flexible glass sheet.
6. The method of claim 1, wherein the handheld power tool is a router comprising a compression router bit.
7. The method of claim 1, wherein the handheld power tool is a tile saw.
8. The method of claim 1, wherein the handheld power tool includes a table saw.
9. A method of field shaping a laminated glass structure, the method comprising: providing the laminated glass structure comprising a flexible glass sheet having a thickness of no greater than about 0.3 mm laminated to a non-glass substrate by an adhesive material; supporting the laminated glass structure on a support surface such that the non-glass substrate is located between the flexible glass sheet and the support surface; field cutting the laminated glass structure using a cutting tool of a handheld power tool in a climb cut orientation applying a compressive force to a surface of the flexible glass sheet that is opposite the non-glass substrate in a direction of movement of the handheld power tool thereby forming a shaped laminated glass structure wherein the handheld power tool includes a cutting tool having an abrasive coating of abrasive particles having an average diameter of less than about ¼ of the thickness of the flexible glass sheet and wherein a glass edge strength of a cut edge of the shaped laminated glass structure is at least about 20 MPa.
10. The method of claim 9, further comprising applying a mask along an intended cutting line on a surface of the flexible glass sheet.
11. The method of claim 9, further comprising applying a fluid to a surface of the flexible glass sheet.
12. The method of claim 9, wherein the glass edge strength of the cut edge of the shaped laminated glass structure is at least about 50 MPa.
13. The method of claim 9, wherein the step of field cutting comprises cutting the laminated glass structure at an installation location for the shaped laminated glass structure.
14. The method of claim 9, wherein the handheld power tool is a tile saw.
15. The method of claim 14, wherein the tile saw includes a cutting wheel coated with diamond powder.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) These and other features, aspects and advantages of the present disclosure are better understood when the following detailed description of the disclosure is read with reference to the accompanying drawings, in which:
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DETAILED DESCRIPTION
(16) In the following detailed description, for purposes of explanation and not limitation, example embodiments disclosing specific details are set forth to provide a thorough understanding of various principles of the present disclosure. However, it will be apparent to one having ordinary skill in the art, having had the benefit of the present disclosure, that the present disclosure may be practiced in other embodiments that depart from the specific details disclosed herein. Moreover, descriptions of well-known devices, methods and materials may be omitted so as not to obscure the description of various principles of the present disclosure. Finally, wherever applicable, like reference numerals refer to like elements.
(17) Ranges can be expressed herein as from “about” one particular value, and/or to “about” another particular value. When such a range is expressed, another embodiment includes from the one particular value and/or to the other particular value. Similarly, when values are expressed as approximations, by use of the antecedent “about,” it will be understood that the particular value forms another embodiment. It will be further understood that the endpoints of each of the ranges are significant both in relation to the other endpoint, and independently of the other endpoint.
(18) Directional terms as used herein—for example up, down, right, left, front, back, top, bottom—are made only with reference to the figures as drawn and are not intended to imply absolute orientation.
(19) Unless otherwise expressly stated, it is in no way intended that any method set forth herein be construed as requiring that its steps be performed in a specific order. Accordingly, where a method claim does not actually recite an order to be followed by its steps or it is not otherwise specifically stated in the claims or descriptions that the steps are to be limited to a specific order, it is no way intended that an order be inferred, in any respect. This holds for any possible non-express basis for interpretation, including: matters of logic with respect to arrangement of steps or operational flow; plain meaning derived from grammatical organization or punctuation; the number or type of embodiments described in the specification.
(20) As used herein, the singular forms “a,” “an” and “the” include plural referents unless the context clearly dictates otherwise. Thus, for example, reference to a “component” includes aspects having two or more such components, unless the context clearly indicates otherwise.
(21) Although glass is an inherently strong material, its strength and mechanical reliability is a function of its surface defect or flaw size density distribution and the cumulative exposure of stress to the material over time. During an entire product life cycle, a laminated glass structure may be subjected to various kinds of static and dynamic mechanical stresses. Embodiments described herein generally relate to methods of shaping (e.g., cutting) laminated glass structures in the field, such as at an installation location that is remote from the location where the lamination took place. Particular examples discussed herein relate to laminated glass structures where the non-glass substrate is a polymer and/or metal or metal alloy, such as stainless steel, aluminum, nickel, magnesium, brass, bronze, titanium, tungsten, copper, cast iron or a noble metal.
(22) Referring to
(23) The non-glass substrate 18 may be formed using a polymer material, for example, any one or more of polyethylene teraphthalate (PET), polyethylene Naphthalate (PEN), ethylene tetrafluoroethylene (ETFE), or thermopolymer polyolefin (TPO™—polymer/filler blends of polyethylene, polypropylene, block copolymer polypropylene (BCPP), or rubber), polyesters, polycarbonate, polyvinylbuterate, polyvinyl chloride, polyethylene and substituted polyethylenes, polyhydroxybutyrates, polyhydroxyvinylbutyrates, polyetherimides, polyamides, polyethylenenaphalate, polyimides, polyethers, polysulphones, polyvinylacetylenes, transparent thermoplastics, transparent polybutadienes, polycyanoacrylates, cellulose-based polymers, polyacrylates and polymethacrylates, polyvinylalcohol, polysulphides, polyvinyl butyral, polymethyl methacrylate and polysiloxanes. It is also possible to use polymers which can be deposited/coated as pre-polymers or pre-compounds and then converted, such as epoxy-resins, polyurethanes, phenol-formaldehyde resins, and melamine-formaldehyde resins. Many display and electrical applications may prefer acrylic based polymers, silicones and such structural aiding layers, for example, commercially available SentryGlas® from DuPont. The polymer layers may be transparent for some applications, but need not be for other applications.
(24) An adhesive layer 20 may be formed of an adhesive material 22 that may be used to laminate the flexible glass layer 12 to the non-glass substrate layer 16 at the interfaces between their respective broad surfaces 24 and 26. The adhesive material 22 may be a non-adhesive interlayer, an adhesive, a sheet or film of adhesive, a liquid adhesive, a powder adhesive, a pressure sensitive adhesive, an ultraviolet-light curable adhesive, a thermally curable adhesive, or other similar adhesive or combination thereof. The adhesive material 22 may assist in attaching the flexible glass 14 to the non-glass substrate 18 during lamination. Some examples of low temperature adhesive materials include Norland 68 cured by UV, Flexcon V29TT, 3M OCA 8211, 8212, 8146,and 8172 (bonded by pressure at room temperature), 3M 4905, OptiClear® adhesive, silicones, acrylates, optically clear adhesives, encaptulant material, polyurethane polyvinylbutyrates, ethylenevinylacetates, ionomers, and wood glues. Typical graphic adhesives such as Graphicmount and Facemount may also be used (as available from LexJet Corporation, located in Sarasota Fla., for example). Some examples of higher temperature adhesive materials include DuPont SentryGlas, DuPont PV 5411, Japan World Corporation material FAS and polyvinyl butyral resin. The adhesive layer 20 may be thin, having a thickness less than or equal to about 1000 μm, including less than or equal to about 500 μm, about 250 μm, less than or equal to about 50 μm, less than or equal to 40 μm, less than or equal to about 25 μm, or between about 0.1 mm and about 5 mm. The adhesives may also contain other functional components such as color, decoration, heat or UV resistance, AR filtration etc. The adhesive material 22 may be optically clear on cure, or may otherwise be opaque. In embodiments where the adhesive material 22 is a sheet or film of adhesive, the adhesive material 22 may have a decorative pattern or design visible through the thickness of the flexible glass, as shown in
(25) In
(26) The flexible glass sheet 14 may have a thickness 34 of about 0.3 mm or less including but not limited to thicknesses of, for example, about 0.01-0.05 mm, about 0.05-0.1 mm, about 0.1-0.15 mm, about 0.15-0.3 mm, about 0.100 to about 0.200 mm, 0.3, 0.275, 0.25, 0.225, 0.2, 0.19, 0.18, 0.17, 0.16, 0.15, 0.14, 0.13, 0.12, 0.11, 0.10, 0.09, 0.08 0.07, 0.06, 0.05, 0.04, 0.03, 0.02, or 0.01 mm. The flexible glass sheet 14 may be formed of glass, a glass ceramic, a ceramic material or composites thereof. A fusion process (e.g., downdraw process) that forms high quality flexible glass sheets can be used in a variety of devices and one such application is flat panel displays. Glass sheets produced in a fusion process have surfaces with superior flatness and smoothness when compared to glass sheets produced by other methods. The fusion process is described in U.S. Pat. Nos. 3,338,696 and 3,682,609. Other suitable glass sheet forming methods include a float process, updraw and slot draw methods. Additionally, the flexible glass sheet 14 may also contain anti-microbial properties by using a chemical composition for the glass including an Ag ion concentration on the surface in the range greater than 0 to 0.047 μg/cm.sup.2, further described in U.S. Patent Application Publication No. 2012/0034435 A1. The flexible glass 14 may also be coated with a glaze composed of silver, or otherwise doped with silver ions, to gain the desired anti-microbial properties, as further described in U.S. Patent Application Publication No. 2011/0081542 A1. Additionally, the flexible glass 14 may have a molar composition of 50% SiO.sub.2, 25% CaO, and 25% Na.sub.2O to achieve the desired anti-microbial effects.
(27) Once the flexible glass sheet 14 is formed, it may be laminated to the non-glass substrate 18 using a variety of apparatus and processes. Some examples include sheet-to-sheet lamination where pressure and/or heat are used to bond the flexible glass sheet 14 to the non-glass substrate 18, for example, using the adhesive material 22. As another example, a roll-to-sheet or roll-to-roll lamination method may be used where; again, pressure is used to bond a continuous ribbon of flexible glass sheet 14 from a supply roll to a non-glass substrate 18 either as a continuous substrate from a supply roll or a plurality of individual substrates. While it may be possible to form the laminated glass structure to a final, desired dimension, it may be the case that some type of shaping (e.g., cutting) of the laminated glass structure will be needed after the laminated glass structure is formed. In these instances, the laminated glass structure may be referred to as a preform laminated glass structure in that the preform laminated glass structure will undergo final processing in the field, for example, at an installation site to desired dimensions.
(28) Without wishing to be bound by theory, one difficulty that may be encountered during cutting of the laminated glass structures to a predetermined dimension in the field is maintaining an acceptable edge quality of the flexible glass sheet 14. Edge quality of the flexible glass sheet 14 is related to edge strength and the possibility of initiation/formation of undesirable or unintended cracks and fractures in the flexible glass sheet 14. In some embodiments, it may be desirable to maintain a predetermined edge strength in the flexible glass sheet 14 after cutting. For example, maintaining an edge strength in the flexible glass sheet 14 of at least about 20 MPa can allow the flexible glass sheet 14 of the laminated glass structure 10 to survive end use conditions, such as handling and installation, without forming cracks and fractures in the flexible glass sheet 14. However, specialized tools for cutting the flexible glass sheet 14 are generally not available in the field (e.g., at the location of installation). It has been found that, under predetermined conditions, power hand tools, such as tile saws and routers and table saws, which are not typically used for cutting at least one of the materials in the laminated glass structure can be used to cut the laminated glass structures 10 (e.g., flexible glass sheet 14, adhesive material 22 and non-glass substrate 18), and with a subsequent edge finishing process maintain a predetermined edge strength of at least about 20 MPa in the flexible glass sheets 14. Edge finishing of the laminated glass structures 10 using sand paper of greater grit size may be employed to further improve the glass edge quality and strength.
(29) Referring to
(30) A liquid or fluid, for example, a cutting fluid 132, such as water or other liquid solution, may be supplied to the surface 114 of the preform laminated glass structure 102 from a fluid supply (e.g., a water tap). The cutting fluid 132 may be applied through the handheld tile saw 130 or by any other suitable method, such as from a container or using a hose. The cutting fluid 132 can reduce friction between a cutting edge 136 of a cutting wheel 138 of the handheld tile saw 130, while also protecting the cut edges 126 and 128 and surface 114 of the preform laminated glass structure 102 from scratches and contamination caused by the deposit of abrasive particles or chips made during the machining process. On the other hand, dry cutting is beneficial in some instances.
(31) A cut may be initiated by the operator using the handheld tile saw 130 (e.g., such as commercially available from Ryobi Limited) while the cutting fluid 132 is applied. The handheld tile saw may be power operated, for example, using an electrical outlet or battery. The cutting wheel 138 may be operated in a climb cut orientation. As used herein, a “climb cut orientation” refers to the cutting tool applying a compressive stress Sc to the flexible glass sheet during a cutting operation moving in direction D (
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(33) Referring back to
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(35) A cut may be initiated by the operator using the handheld router 184 (e.g., such as commercially available from Porter-Cable Corporation). The handheld router 184 may be power operated, for example, using an electrical outlet or battery. A router bit 200 may be operated in a climb cut orientation using a compression bit. The feed or cutting rate can be dependent on the preform laminated glass structure 182 (glass thickness, type and thickness of the non-glass substrate and adhesive). For example, the cutting rate may be between about 10 inches per minute and about eight feet per minute. According to other aspects, the cutting rate may be between about 1 inch per minute and about 10 inches per minute. Real time observation may be used to adjust the cutting rate. The router bit 200 may be any suitable compression type, such as a diamond coated or carbide compression cutting bit (e.g., commercially available from Harvey Tool, or SGS) having counteracting flute geometries that compress the glass material inwardly. Router bits may also be downward fluted bits having various coatings such as TiN, TiCN, ZrCr and others. Additionally, chip breaker bits may be used as well. Once a cut is initiated, the cut may be made along the entire length of the intended cutting line 202 to inhibit or reduce cracking of the flexible glass sheet 188 and to produce cut laminated glass structures 204 and 206. Once the cut is complete, the mask 192 can be removed and the cut laminated glass structures 204 and 206 can be rinsed and dried.
(36) Router cuts can be made unmasked and without a cutting fluid. In some embodiments, a masking (e.g., with tape) may be provided to minimize damaging the flexible glass sheet by kerf material. Router cuts may also follow a specified tool path to provide the climb cut orientation (depending on the flute direction of the router bit), compression and to minimize glass edge and substrate damage. Router bits that do not apply compression to the flexible glass layer burring the initial plunge or puncture of the laminated glass structure 210 can result in significant glass fracturing. For example, referring to
(37) Table I, below, illustrates various cutting parameters for shaping laminated glass structures. Table I is exemplary and not meant to be exhaustive as other cutting tools may be employed and due to variation in equipment from manufacturer to manufacturer.
(38) TABLE-US-00001 TABLE I Cutting Finishing Router Tile Saw Table Saw Router Tile Saw Table Saw Cutter Router and/or Mill Bit Diamond Coated Blade Carbide Tip Blade Style Compression/Down Can Vary with Cross Cut Flute Laminate Composition Can Vary with and Laminate Chip Breaker Bits Composition Diameters Variable depending Variable depending 10″ upon Laminate stack- upon Laminate stack- up and Radius up requirements Speed 5,000-30,000 rpm Can Vary with 3500-6000 rpm Laminate Composition Cutting Rate 10 in. to 8 ft./min. ≅4 ft./min. 4 ft.-7 ft./minute Pattern Traditional Straight Traditional Straight cut Traditional Cut, or Center Pierce - Straight cut cut out to edge, trim perimeter Type of Cut Compression or Compression or Compression or Climb Cut Climb Cut Climb Cut Straight, Holes, Straight, Holes, Straight Straight Non-linear Non-linear Some Linear Internal Some Linear Shapes Internal Shapes (size dependent) (size dependent) Wet or Dry Cut Wet or Dry Wet Only Dry Only Orbital Sander Y Y Y Manual Sand Y Y Y Belt Sander Y Y Y Coated Compliant Ball Y Y Y Sander Guinevere System Y Y Y Sander Paper SiC or AlOx SiC or AlOx SiC or AlOx Grit Size 240-800 240-800 240-800 Finishing Direction Linear/Orbital/ Linear/Orbital/ Linear/Orbital/ Circumferential Circumferential Circumferential Time to Finish 12 inches 1-10 minutes 1-10 minutes 1-10 minutes Substrate Substrate Substrate Dependent Dependent Dependent Wet or Dry Finishing Wet/Dry Wet/Dry Wet/Dry Substrate Substrate Substrate Dependent Dependent Dependent
(39) The systems and methods of field shaping laminated glass structures described above allow for use of hand held and semi-automated cutting and finishing tools, such as tile saws, diamond saws, table saws, routers, wire saws, orbital sanders and other grinding and polishing tools (e.g., Dremel® rotary tools, RotoZip® saws, orbital sanders, and belt sanders) with minimal damage while maintaining edge strengths of the flexible glass sheets of at least about 20 MPa, for example about 40 MPa, 50 MPa, 60 MPa, 70 MPa, 80 MPa, 90 MPa, 100 MPa, or higher, for example. The laminated glass structures may be masked to prevent incidental scratching of the flexible glass sheets by the tools and inhibit attachment of glass particles to the flexible glass sheet. Glass chips as large as 900 to 1200 microns, and in other examples as large as 900 to 3000 μm can be created during cutting which can be finished with a secondary one or two-step finishing process to obtain glass chip sizes less than 10 microns, such as less than five microns in depth. Use of climb cutting orientations apply a compressive force to the flexible glass sheet during cutting using the cutting tool which allows for edge strengths of the flexible glass sheets to be maintained above 20 MPa, for example, about 40 MPa, 50 MPa, 60 MPa, 70 MPa, 80 MPa, 90 MPa, 100 MPa, or higher, for example. For example, for diamond blade cutting, the rotation of the cutting wheel should be in the climb direction, contacting the flexible glass sheet first as the cutting wheel is rotated. For router cutting, compression bits with downwardly turned flutes may be utilized.
(40) It should be emphasized that the above-described embodiments of the present disclosure, including any embodiments, are merely possible examples of implementations, merely set forth for a clear understanding of various principles of the disclosure. Many variations and modifications may be made to the above-described embodiments of the disclosure without departing substantially from the spirit and various principles of the disclosure. All such modifications and variations are intended to be included herein within the scope of this disclosure and the present disclosure and protected by the following claims.