DOSING PUMP FOR DOSING ANTISCALANT INTO A MEMBRANE-BASED WATER TREATMENT SYSTEM
20220127163 · 2022-04-28
Inventors
- Victor Augusto Yangali-Quintanilla (Ulstrup, DK)
- Dominik Marek Dominiak (Lodz, PL)
- Wilhelmus Johannes Cornelis Van De Ven (Viborg, DK)
Cpc classification
C02F1/008
CHEMISTRY; METALLURGY
C02F2303/14
CHEMISTRY; METALLURGY
B01D61/10
PERFORMING OPERATIONS; TRANSPORTING
B01D61/025
PERFORMING OPERATIONS; TRANSPORTING
C02F2209/006
CHEMISTRY; METALLURGY
B01D65/08
PERFORMING OPERATIONS; TRANSPORTING
B01D65/02
PERFORMING OPERATIONS; TRANSPORTING
B01D2321/40
PERFORMING OPERATIONS; TRANSPORTING
C02F2303/22
CHEMISTRY; METALLURGY
International classification
B01D61/02
PERFORMING OPERATIONS; TRANSPORTING
B01D61/10
PERFORMING OPERATIONS; TRANSPORTING
B01D65/08
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A dosing pump (19) doses antiscalant into a membrane-based water treatment system (1). The dosing pump (19) includes a displacement body for pumping antiscalant into the membrane-based water treatment system (1) in doses. A motor drives the displacement body. A control module controls the motor. The control module is configured to vary the dosage of antiscalant pumped into the water treatment system (1) based on a temperature corrected system variable (SVTc) being based on a plurality of operating variables of the water treatment system (1).
Claims
1. A dosing pump for dosing antiscalant into a membrane-based water treatment system, the dosing pump comprising: a displacement body for pumping antiscalant into a membrane-based water treatment system in doses; a motor for driving the displacement body; and a control module configured to control the motor and to vary a dosage of antiscalant pumped into the water treatment system based on a temperature corrected system variable based on a plurality of operating variables of the water treatment system.
2. The dosing pump according to claim 1, wherein the control module is configured to receive the temperature corrected system variable or to determine the temperature corrected system variable or to receive the temperature corrected system variable and to determine the temperature corrected system variable.
3. The dosing pump according to claim 1, wherein the plurality of operating variables of the water treatment system comprises at least one operating variable of the group of operating variables consisting of: feed pressure, feed electrical conductivity, feed temperature, feed pH, difference between feed pressure and concentrate pressure, permeate pressure, permeate temperature and permeate electrical conductivity.
4. The dosing pump according to claim 1, wherein the control module is configured to recursively adapt the dosage of antiscalant pumped into the water treatment system based on a previously determined value of the temperature corrected system variable as feedback value.
5. The dosing pump according to claim 1, wherein the control module is configured to adapt the dosage of antiscalant pumped into the water treatment system upon a change of a slope of the temperature corrected system variable.
6. The dosing pump according to claim 1, wherein the temperature corrected system variable is a temperature corrected net driving pressure or a temperature corrected permeate flow or a temperature corrected net driving pressure and a temperature corrected permeate flow or a combination of a temperature corrected net driving pressure and a temperature corrected permeate flow.
7. The dosing pump according to claim 6, wherein the control module is configured to recursively reduce the dosage of antiscalant pumped into the water treatment system as long as the slope of the temperature corrected net driving pressure does not increase or as long as the slope of the temperature corrected permeate flow does not decrease or as long as the slope of the temperature corrected net driving pressure does not increase and as long as the slope of the temperature corrected permeate flow does not decrease.
8. The dosing pump according to claim 6, wherein the control module is configured to increase the dosage of antiscalant pumped into the water treatment system if the slope of the temperature corrected net driving pressure has increased or if the slope of the temperature corrected net permeate flow has decreased or if the slope of the temperature corrected net driving pressure has increased and the slope of the temperature corrected net permeate flow has decreased.
9. The dosing pump according to claim 6, wherein the control module is configured to recursively increase the dosage of antiscalant pumped into the water treatment system as long as the slope of the temperature corrected net driving pressure is above an initial slope or as long as the slope of the temperature corrected permeate flow is below an initial slope or as long as the slope of the temperature corrected net driving pressure is above an initial slope and as long as the slope of the temperature corrected permeate flow is below an initial slope.
10. A dosing system for dosing antiscalant into a membrane-based water treatment system, the dosing system comprising: a dosing pump comprising a displacement body for pumping antiscalant into a membrane-based water treatment system in doses, a motor for driving the displacement body, and a control module configured to control the motor and to vary a dosage of antiscalant pumped into the water treatment system based on a temperature corrected system variable based on a plurality of operating variables of the water treatment system; and a plurality of sensors for determining the plurality of operating variables of the water treatment system.
11. The dosing system according to claim 10, further comprising a calculation module configured to determine the temperature corrected system variable.
12. The dosing system according to claim 11, wherein the calculation module is configured to receive the plurality of operating variables of the water treatment system from the plurality of sensors.
13. The dosing system according to claim 11, wherein the calculation module is remotely located from the dosing pump and in signal communication with the control module and the plurality of sensors.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0056] In the drawings:
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DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS
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[0067] Therefore, the membrane-based water treatment system 1 is equipped with a first embodiment of a dosing system for dosing antiscalant into the feed line 13 of the membrane-based water treatment system 1. The dosing system comprises a dosing pump 19 for dosing antiscalant from an antiscalant reservoir 21 into the feed line 13. An inlet port 23 of the dosing pump 19 is in fluid connection with an intake port 20 within the antiscalant reservoir 21 and an outlet port 25 of the dosing pump 19 is in fluid connection with the feed line 13. A check valve 27 before the feed line 13 prevents water pressure in the feed line 13 from pushing back antiscalant towards the dosing pump 19. Another check valve 28 upstream the inlet port 23 of the dosing pump 19 and downstream of the intake port 20 prevents antiscalant pressure in the reservoir 21 from pushing antiscalant towards the dosing pump 19. The filling level of antiscalant in the reservoir 21 is monitored by a fluid level sensor 29 controlling an angled valve 31 downstream of the outlet port 25 of the dosing pump 19 via a signal line 33. The angled valve 31 may be shut if the level of antiscalant in the reservoir 21 falls below a minimum threshold.
[0068] The dosing system further comprises a plurality of sensors 35, i.e. eight sensors, for determining a plurality of operating variables, i.e. eight variables, of the water treatment system 1. The feed line 13 is equipped with a feed electrical conductivity sensor 35a, a feed temperature sensor 35b, a feed pH sensor 35c and a pressure sensor 35d. The feed line 13 is further equipped with a feed flow sensor 37a for measuring the flow in the feed line 13. The feed electrical conductivity sensor 35a, the feed temperature sensor 35b, the feed pH sensor 35c and the feed flow sensor 37a are located upstream of the feed pump 18, whereas the feed pressure sensor 35d is located downstream of the feed pump 18 and upstream of the vessel 5. A concentrate pressure sensor 35e is located downstream the discharge port 11 at the discharge line 17 for determining the concentrate pressure P.sub.c. The permeate line 15 is equipped with a permeate pressure sensor 35f, a permeate temperature sensor 35g and a permeate electrical conductivity sensor 35h of the dosing system. Furthermore, the permeate line 15 is equipped with a permeate flow sensor 37b, which may be used to determine a temperature corrected permeate flow PFTc. The permeate pressure sensor 35f is located closest to the vessel 5 downstream the outlet port 9. The eight sensors 35 of the dosing system are in signal communication with a control module, comprising one or more processors, of the dosing pump 19 via wireless or cabled signal line 39 with associated transmitters and receivers. The control module of the dosing pump 19 is configured to receive and process the operating variables provided by the sensors 35 via signal line 39. The control module of the dosing pump 19 determines here a temperature corrected net driving pressure NDPTc as temperature corrected system variable SVTc based on the plurality of received operating variables and varies the dosage of antiscalant fed into the feed line 13 based on the determined NDPTc.
[0069] The control module of the dosing pump 19 determines a net driving pressure (NDP) by:
wherein P.sub.f denotes the feed pressure, ΔP.sub.fc is the difference between the feed pressure P.sub.f and the concentrate pressure P.sub.c, P.sub.p is the permeate pressure, π.sub.fc is the feed-concentrate osmotic pressure, and π.sub.p is the permeate osmotic pressure. NDPTc may then be determined by: NDPTc=NDP.Math.TCF, wherein TCF is a temperature correction factor being a function of a membrane-specific temperature correction constant C.sub.t and the feed temperature T.sub.f: TCF=f(C.sub.t,T.sub.f).
[0070] The output of the feed pressure sensor 35d, i.e. feed pressure P.sub.f, and of the concentrate pressure sensor 35e, i.e. concentrate pressure P.sub.c, are combined to the differential pressure ΔP.sub.fc=P.sub.f−P.sub.c as one of the operating variables for determining NDPTc. The variables feed electrical conductivity γ.sub.f and feed temperature T.sub.f are used to determine the temperature correction factor TCF and the feed-concentrate osmotic pressure π.sub.fc. The temperature correction factor TCF depends on the membrane type and is thus provided by the membrane manufacturer. A plurality of TCF formula options is stored in a database for a plurality of membrane types and products. The correct TCF formula may be selected from the database dependent on the membrane type used in the water treatment system. For instance, TCF for a composite membrane may be given as:
wherein the actual feed temperature T.sub.f is input in ° K. For instance, if T.sub.f is 15° C., i.e. 288.15° K, TCF may be 0.734. If there is no TCF formula given or available for the used membrane type, a default TCF formula may be assumed to be: TCF=1.03.sup.(T.sup.
[0071] The osmotic pressure π may be derived of the van't Hoff formula π=R.Math.T.Math.ϕ.Math.Σ.sub.iα.sub.ic.sub.i, wherein R is the universal gas constant, T is the temperature in ° K., ϕ is the osmotic coefficient, α.sub.i is the activity coefficient for ionic species i and c.sub.i is the concentration of ionic species i. The feed-concentrate osmotic pressure π.sub.fc may be deduced therefrom to be:
wherein the actual feed temperature T.sub.f is input in ° K. and c.sub.fc is the concentration of salts in the feed-concentrate. The concentration of salts in the feed-concentrate c.sub.fc can be derived from the concentration of salts in the feed c.sub.f by making use of the total recovery Rec:
wherein CP is the water-dependent concentration polarization factor typically in the range of 1 to 2, e.g. CP=1.1 for low brackish groundwater. Recovery Rec=Q.sub.p/Q.sub.f may be assumed to be a given fixed nominal target value, typically in the range of 30% to 90%, or may be determined from the measurements of the flow sensors 37a,b.
[0072] The concentration of salts in the feed c.sub.f in units of mg/l may be determined by using the measurement of the feed electrical conductivity γ.sub.f in units of μS/cm: c.sub.f=0.76.Math.γ.sub.f−3.07. For example, if γ.sub.f is 1500 μS/cm, c.sub.f is 1136.93 mg/l. If the total recovery is 70% for an application in low brackish groundwater, i.e. CP=1.1, the concentration of salts in the feed-concentrate c.sub.fc is 2151 mg/l, which results in a feed-concentrate osmotic pressure π.sub.fc of 1.65 bar.
[0073] NDP and NDPTc may now already be available if the permeate pressure P.sub.p and zero permeate osmotic pressure π.sub.p can be assumed to be constants or zero in case no permeate sensors 35f-h were available. However, the measured permeate pressure P.sub.p and the measured permeate electrical conductivity γ.sub.p are available from respective sensors 35f-h in the shown example. The net driving pressure NDP and thus the temperature corrected net driving pressure NDPTc may be more precisely determined by adding the measured permeate pressure P.sub.p to NDP and subtracting the permeate osmotic pressure π.sub.p from NDP. As the concentration of salts in the permeate is generally quite low, the osmotic pressure π.sub.p in units of bar may be derived directly from the measured permeate electrical conductivity γ.sub.p in units of μS/cm by: π.sub.p=7.49.Math.10.sup.−4.Math.γ.sub.p−0.19.Math.10.sup.−3. For instance, if the permeate electrical conductivity m is 13 μS/cm, π.sub.p would be 0.01 bar.
[0074] Thus, if the feed pressure sensor shows 9.41 bar, the concentrate pressure sensor shows 9.11 bar, the permeate pressure sensor shows 0.03 bar, the feed electrical conductivity sensor shows 1500 μS/cm, the permeate electrical conductivity sensor shows 13 μS/cm and the feed temperature sensor shows 15° C., NDP would be 7.59 bar and NDPTc would be 5.57 bar for a membrane with TCF=0.734 at 15° C.
[0075] An alternative choice of the temperature corrected system variable (SVTc) may be a temperature corrected permeate flow (PFTc) being defined herein as:
wherein Q.sub.p denotes the permeate flow measured by permeate flow sensor 37b and TCF is the same temperature correction factor as described above. If Q.sub.f is 10.0 m.sup.3/h and TCF=0.747, then PTFc would be 13.39 m.sup.3/h.
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[0085] The skilled reader will readily understand that
[0086] Where, in the foregoing description, integers or elements are mentioned which have known, obvious or foreseeable equivalents, then such equivalents are herein incorporated as if individually set forth. Reference should be made to the claims for determining the true scope of the present disclosure, which should be construed so as to encompass any such equivalents. It will also be appreciated by the reader that integers or features of the disclosure that are described as optional, preferable, advantageous, convenient or the like are optional and do not limit the scope of the independent claims.
[0087] The above embodiments are to be understood as illustrative examples of the disclosure. It is to be understood that any feature described in relation to any one embodiment may be used alone, or in combination with other features described, and may also be used in combination with one or more features of any other of the embodiments, or any combination of any other of the embodiments. While at least one exemplary embodiment has been shown and described, it should be understood that other modifications, substitutions and alternatives are apparent to one of ordinary skill in the art and may be changed without departing from the scope of the subject matter described herein, and this application is intended to cover any adaptations or variations of the specific embodiments discussed herein.
[0088] In addition, “comprising” does not exclude other elements or steps, and “a” or one does not exclude a plural number. Furthermore, characteristics or steps which have been described with reference to one of the above exemplary embodiments may also be used in combination with other characteristics or steps of other exemplary embodiments described above. Method steps may be applied in any order or in parallel or may constitute a part or a more detailed version of another method step. It should be understood that there should be embodied within the scope of the patent warranted hereon all such modifications as reasonably and properly come within the scope of the contribution to the art. Such modifications, substitutions and alternatives can be made without departing from the spirit and scope of the disclosure, which should be determined from the appended claims and their legal equivalents.
[0089] While specific embodiments of the invention have been shown and described in detail to illustrate the application of the principles of the invention, it will be understood that the invention may be embodied otherwise without departing from such principles.