DEVICE, EXCHANGE UNIT, KIT, AND METHOD FOR REDUCING THE ODOR OF TANNED LEATHER

Abstract

The invention relates to a device for reducing the odor of tanned leather, comprising a treatment chamber, which is designed to dry tanned leather and/or treat dried leather, and at least one odor reducing reservoir, wherein the at least one odor reducing reservoir has at least one odor-neutralizing substance, and a gas-exchange connection is provided between the treatment chamber and the odor reducing reservoir.

Claims

1. A device for odor reduction of tanned leather, comprising a treatment space, which is arranged for drying tanned leather and/or for treating dry leather, and at least one odor-reduction reservoir, wherein the at least one odor-reduction reservoir has at least one odor-neutralizing substance, wherein a gas-exchange compound is arranged between the treatment space and the odor-reduction reservoir, wherein the at least one odor-reduction reservoir is arranged in a chamber separated from the treatment space, which is connected via at least one gas exchange line to the treatment space, in such a way that a closed or closable system of treatment space, gas exchange line and chamber is configured, in which a circulating gas stream can be generated, wherein in operation, thus with movement of the treatment space, the chamber does not move with it, but remains stationary.

2. The device as claimed in claim 1, wherein the treatment space is arranged so that it is movable, wherein leather placed therein is moved along during operation, and/or wherein the treatment space is configured as a drum tumbler for tumbling dry leather, for example as a tumbling drum or drum tumbler, and/or as a drying chamber for drying tanned leather, for example as a drying tunnel, and/or wherein the treatment space has a closable opening.

3. The device as claimed in claim 1, wherein a filter, in particular a particle filter is arranged in a or the chamber and/or in a or the gas exchange line.

4. The device as claimed in claim 1, wherein the device has a gas exchange device, by means of which active gas exchange can be effected between the at least one odor-reduction reservoir and the treatment space, for example wherein the gas exchange device is configured as a fan and/or as a compressor.

5. The device as claimed in claim 1, wherein the at least one odor-neutralizing substance is arranged in an interchangeable replaceable unit.

6. The device as claimed in claim 1, wherein the at least one odor-reduction reservoir has a holder and a replaceable unit that is usable in the holder and is interchangeable, with the at least one odor-neutralizing substance, for example wherein the replaceable unit is configured as a cartridge and/or as a pad and/or as an odor filter.

7. The device as claimed in claim 1, wherein the at least one odor-neutralizing substance is dry and/or recyclable and/or reactivatable and/or is a liquid absorbent material that is incorporated in a dry, porous carrier material, and/or wherein the at least one odor-neutralizing substance is at least one or a combination of two or more substances selected from the group comprising carbon-containing absorbents, mineral absorbents, coffee, coffee grounds, activated carbon, cyclodextrins, zeolite, zinc compounds, coffee-based activated carbon.

8. The device as claimed in claim 1, wherein the at least one odor-neutralizing substance is fine-grained and/or pulverulent and/or wherein the odor-neutralizing substance is mixed with a filler, preferably wherein the particle size of the filler is greater than or less than the particle size of the odor-neutralizing substance, in particular so that the gas permeability of the odor-neutralizing substance is increased by the filler, for example wherein the filler is cellulose and/or a polymer and/or a mineral filler, such as zeolite and/or vermiculite.

9. The device as claimed in claim 1, wherein the device has a fragrance reservoir with at least one odorant, wherein a gas-exchange compound is arranged between the treatment space and the fragrance reservoir, for example wherein the fragrance reservoir is arranged within a gas stream set up between treatment space and odor-reduction reservoir in the direction of flow toward the odor-reduction reservoir and/or in a or the chamber separated from the treatment space; and/or wherein the device has at least one nebulizer device, preferably wherein the device has a first nebulizer device and a second nebulizer device, in particular wherein the first nebulizer device is assigned to the treatment space and/or the second nebulizer device is assigned to a or the gas exchange line.

10. A replaceable unit with at least one odor-neutralizing substance for inserting in a holder of an odor reduction reservoir of a device for odor reduction of tanned leather as claimed in claim 1, preferably wherein the at least one odor-neutralizing substance is at least one or a combination of two or more substances selected from the group comprising carbon-containing absorbents, mineral absorbents, coffee, coffee grounds, activated carbon, cyclodextrins, zeolite, zinc compounds, coffee-based activated carbon.

11. A kit for retrofitting a tumbling device for tumbling dry leather and/or a drying device for drying tanned leather, comprising at least one replaceable unit as claimed in claim 10 and a holder for holding and/or fixing the replaceable unit.

12. A method for reducing the odor of tanned leather by means of a device for odor reduction as claimed in claim 1, comprising the steps: providing tanned leather in a, preferably closable, treatment space, setting up a preferably continuous gas exchange between the treatment space and an odor-reduction reservoir, which has at least one odor-neutralizing substance, wherein a gas circulation is arranged between the treatment space and the odor-reduction reservoir; wherein preferably dry leather is used or wherein the leather is dried during odor neutralization and/or the leather is moved, in particular is tumbled, within the treatment space and/or wherein all process steps of the method are carried out during a usual treatment of leather in the treatment space.

13. The method as claimed in claim 12, wherein the at least one odor-neutralizing substance is dry and/or recyclable and/or reactivatable and/or is a liquid material that is incorporated in a dry, porous carrier material, and/or wherein the at least one odor-neutralizing substance comprises at least one or a combination of two or more substances selected from the group comprising carbon-containing absorbents, mineral absorbents, coffee, coffee grounds, activated carbon, cyclodextrins, zeolite, zinc compounds, coffee-based activated carbon.

14. The method as claimed in claim 12, wherein the leather is treated with at least one odorant arranged in a fragrance reservoir, wherein a gas exchange is set up between the treatment space and the fragrance reservoir.

15. The method as claimed in claim 12, wherein all process steps are carried out without radical-releasing treatment of leather, in particular wherein no photolytic treatment and/or no ozonolytic treatment and/or no electrochemical treatment and/or no oxidative treatment and/or no thermolytic treatment is carried out, in particular preferably wherein there is no formation of chromium(VI) compounds.

16. The method as claimed in claim 12, wherein the method for odor reduction is applied as part of a method of manufacture of tanned leather, in particular in such a way that odor reduction is carried out during tumbling of the leather, preferably in a drum tumbler.

Description

[0044] The invention is now described in more detail on the basis of several embodiment examples, but it is not limited to these embodiment examples. Further embodiment examples result from combining the features of individual or several claims with one another and/or with individual or several features of the embodiment examples.

[0045] The figures show:

[0046] FIG. 1 a simplified schematic side view of a first embodiment of a device according to the invention for reducing the odor of tanned leather, wherein the device is arranged as a tumbling device,

[0047] FIG. 2 a longitudinal view of the device from FIG. 1,

[0048] FIG. 3 a top view of the device from FIGS. 1 and 2,

[0049] FIG. 4 a simplified schematic perspective view of a further embodiment of a device according to the invention for reducing the odor of tanned leather, wherein gas circulation is indicated with the broad arrows,

[0050] FIG. 5 a further perspective view of the device from FIG. 4, wherein the particles generated in the treatment space during leather tumbling are indicated,

[0051] FIG. 6 a further perspective view of the device from FIG. 4, wherein moisture is sprayable in the gas stream and/or the treatment space via a humidifier,

[0052] FIG. 7 a schematic representation of a further possible embodiment variant of a device according to the invention.

[0053] FIGS. 1 to 7 show several embodiments of a device for reducing the odor of tanned leather, which is designated in each case as 1 throughout.

[0054] The device 1 has a treatment space 2, which is arranged for treating leather. The treatment space 2 may for example, as shown in FIGS. 1-7, be configured as a drum tumbler 7.

[0055] However, other configurations are also possible, in which the treatment space 2 is for example arranged for drying tanned leather.

[0056] The device 1 has at least one odor-reduction reservoir 3, which is arranged outside the aforementioned treatment space 2. The odor-reduction reservoir 3 has at least one odor-neutralizing substance 4, which is arranged inside the odor reduction reservoir 3.

[0057] According to an alternative or supplementary embodiment of the device 1, the odor-neutralizing substance 3 may be arranged inside the treatment space 2. What is decisive is that a gas-exchange compound 5 is provided between the treatment space 2 and the odor-reduction reservoir 3, and thus between the odor-neutralizing substance 4 and the leather.

[0058] The gas-exchange compound 5 between the treatment space 2 and the odor-reduction reservoir 3 may for example be provided by at least one gas exchange line 6.

[0059] The treatment space 2 configured as a tumbling drum is arranged rotatably about a rotation axis. Treatment of the leather is possible by rotation of the treatment space 2. The leather may therefore be rotated together with the treatment space 2, so that it is tumbled in the treatment space 2. During tumbling, odor reduction can take place simultaneously.

[0060] The treatment space 2 has a closable opening, via which the tanned leather can be fed into the treatment space 2. The opening may be closed for example by means of a door or hatch.

[0061] The odor-reduction reservoir 3 is arranged or configured in a chamber 8 spatially separated from the treatment space 2.

[0062] The device 1 has several gas exchange lines 6. A gas exchange line 6 leads from the treatment space 2 to the chamber 8 and a gas exchange line 6 leads from the chamber 8 back into the treatment space 2. Thus, a closed system 9 is set up from the treatment space 2, the gas exchange lines 6 and the chamber 8. Therefore a gas stream and/or gas circulation 16 can be set up inside the closed system 9. Thus, multiple treatment of the gas stream 16 with the odor-neutralizing substance 4 is possible, as the gas stream 16 is led repeatedly through the odor-reduction reservoir 3.

[0063] Treatment of the leather within the treatment space 2 may result in separation of particles from the leather. So as to be able to minimize the dust burden of a space in which the device 1 is arranged, the device 1 may have a particle filter 10. The aforementioned gas stream 16 can be filtered by the particle filter 10, so that on completion of treatment of the leather, a high proportion of the particles have been removed from the air inside the treatment space 2 by the particle filter 10.

[0064] In order to accelerate gas exchange between the treatment space 2 and the odor-reduction reservoir 3, the device 1 may have a gas exchange device 11. The gas exchange device 11 may for example be configured as a fan and/or as a compressor, wherein the gas exchange device 11 may be integrated in the system 9. As a result, active gas exchange is possible between the at least one odor-reduction reservoir 3 and the treatment space 2.

[0065] The odor-neutralizing substance 4 may be arranged in a replaceable unit 12. The replaceable unit 12 has the advantage that it is easier to replace an odor-neutralizing substance that has exceeded its maximum usability. The odor-neutralizing substance 4 may therefore be replaced easily by replacing the complete replaceable unit 12.

[0066] So as to be able to fix the replaceable unit 12 in the odor-reduction reservoir 3, the odor-reduction reservoir 3 may have a holder 13, into which the replaceable unit 12 can be inserted. A nonpositive-fit and/or positive-fit connection may be arranged between the holder 13 and the replaceable unit.

[0067] The replaceable unit 12 may for example be configured as a cartridge and/or as a pad and/or as an odor filter.

[0068] The odor-neutralizing substance 4 is preferably in dry form, so that for example it may be pulverulent. It may be particularly advantageous if the odor-neutralizing substance 4 is recyclable, i.e. reusable. It may then be particularly advantageous if the odor-neutralizing substance 4 is for example reactivatable by heat treatment. When the odor-neutralizing substance reaches its maximum usage time, it is particularly advantageous if the odor-neutralizing substance 4 is compostable, to avoid garbage.

[0069] So as to be able to increase the permeability of the odor-neutralizing substance 4 for the gas stream 16, the odor-neutralizing substance 4 may be mixed with a filler. In particular, the particle size of the filler may be greater than or less than the particle size of the odor-neutralizing substance, so that the gas permeability of the odor-neutralizing substance is increased by the filler. The particle size of the filler may be greater than the particle size of the odor-neutralizing material. The filler may be for example cellulose and/or a polymer and/or a mineral filler, such as zeolite. For example, the filler may be cellulose (in particular antidust-based-cellulose) and/or a polymer and/or a mineral filler, such as zeolite and/or vermiculite. The filler may be free from additives, such as in particular free from flame retardants and/or other chemicals. The average particle size of the filler may be 3-8 mm, in particular 3-6 mm.

[0070] The odor-neutralizing substance 4 may be for example at least one or a combination of two or more substances 4 selected from the group comprising carbon-containing absorbents, mineral absorbents, coffee, coffee grounds, activated carbon, cyclodextrins, zeolite, zinc compounds, coffee-based activated carbon.

[0071] The device 1 may further have a fragrance reservoir 14 with at least one odorant 15 arranged therein. The reservoir 14 may for example be arranged or configured in a chamber 8, in particular in the aforementioned chamber 8 or a further chamber 8. With the odorant 15 it is possible for the leather treated by odor neutralization to be treated with a desired fragrance.

[0072] The fragrance reservoir 15 may be arranged downstream in the direction of flow of the odor-reduction reservoir 13, inside a gas stream 16 directed between the treatment space 2 and the odor-reduction reservoir 13.

[0073] As shown in FIG. 6, the device 1 may have at least one humidifier 17. The humidifier 17 may for example be configured as at least one nebulizer device 18. By means of the nebulizer device 18 and/or the humidifier 17 it is possible to feed a liquid, in particular water or an aqueous solution, into the gas stream 16 and/or the treatment space 2 for example by sprinkling or spraying. An additional treatment of the tanned leather may thus take place. A sensor for determining moisture, in particular air humidity, may be provided in the treatment space 2. Also preferably, a control unit may be provided, which is arranged for controlling the moisture via the humidifier 17 as a function of the measured moisture, preferably automatically by activation and deactivation of the humidifier 17.

[0074] FIG. 7 shows the schematic structure of a further embodiment variant, which basically corresponds to the embodiment variant described above. In addition, the device 1 shown in FIG. 7 has two nebulizer devices 18, which may be configured identically or differently.

[0075] A first nebulizer device 18 is assigned to the treatment space 2, for injecting liquid in particular as mist and/or in the form of spray into the treatment space 2. For example, water and/or an additive may be fed into the treatment space 2 and onto the leather being treated therein. The additive may for example be an additional odor-neutralizing substance 4 and/or some other substance for treating leather. In particular, the additive may be odor-neutralizing cyclodextrins, which are for example in aqueous solution. The cyclodextrins may have an additional odor-reducing action. According to an alternative embodiment variant, the odor-reduction reservoir 3 may be replaced by the nebulizer device 18, if this is set up for releasing an odor-neutralizing substance 4.

[0076] The at least one nebulizer device 18 may have an outlet, for example a spraying nozzle, which can release liquid in the treatment space 2 and/or in the gas exchange line 6. The liquid may also be transported with the gas stream into the treatment space 2, if direct release in the treatment space 2 is not provided.

[0077] In the direction of flow 16 of the gas stream, the nebulizer device 18 assigned to the gas exchange line 6 may be arranged within the gas exchange line 6 before the filter 10 and/or before the odor-reduction reservoir 3 and/or before the fragrance reservoir 14. This has the advantage that the filter 10 filters out solids, such as cyclodextrins, which are introduced into the gas stream 16 by the nebulizer device 18, before the gas stream 16 enters the treatment space 2. This can prevent solids coming into contact with the leather.

Tests Carried Out

[0078] I. First Pilot Test

[0079] I.1 Material and Equipment

[0080] I.1.1

[0081] Sample A: 10 hides (corresponding to crust leather) tanned with a chromium-containing retanning formulation #1 (without treatment for odor reduction as described and claimed herein).

[0082] I.1.2

[0083] Sample B: 10 hides (corresponding to crust leather) tanned with a chromium-containing retanning formulation #1 (with treatment for odor reduction as described and claimed herein).

[0084] I.1.3

[0085] Milling drum (tumbling drum) made by the company Erretre.

[0086] I.1.4

[0087] Activated carbon was used as odor-neutralizing substance. The activated carbon was used in the form of an activated carbon filter.

[0088] I.1.5

[0089] Filter size: 20 cm×25 cm×3 cm, preferably the filter material may also have a volume of two to three liters.

[0090] I.2 Test Procedure

[0091] I.2.1 Sample A

[0092] (reference example, corresponds to the prior art)

[0093] The hides for Sample A were put in a tumbling drum and were tumbled for 4 hours in the tumbling drum at 35° C. and 35% RH.

[0094] I.2.2 Sample B

[0095] (corresponding to a sample that was produced by means of the invention)

[0096] The hides for Sample B were tumbled in the tumbling drum for the same length of time and in the same conditions as for Sample A. In addition, throughout the treatment time in the tumbling drum, gas exchange was arranged between the tanned hides and a filter (1500 cc) containing 700 grams of activated carbon.

[0097] I.2.3 Odor Sampling

[0098] After the tumbling process, the two samples A and B were treated separately, so that there could not be any corruption of the result.

[0099] One odor sample was taken from each of the two samples A and B and was analyzed in an odor test according to VDA 270 C3.

[0100] I.2.4 VDA 270 Scoring

[0101] In the VDA 270 test, only the odor intensity is determined, on a scale from degree 1 to degree 6, where: [0102] Degree 1: imperceptible [0103] Degree 2: weakly perceptible, but not disturbing [0104] Degree 3: clearly perceptible, but not disturbing [0105] Degree 4: disturbing [0106] Degree 5: very disturbing [0107] Degree 6: unacceptable

[0108] I.3 Results

[0109] One set of the odor samples taken was evaluated for odor by customers and another set was evaluated in-house at TFL.

[0110] I.3.1 Result from customers

[0111] Sample A Degree 4

[0112] Sample B Degree 3

[0113] I.3.2 Result at TFL

[0114] Sample A Degree 4

[0115] Sample B Degree 3-4

[0116] II. Second Pilot Test

[0117] II.1 Material and Equipment

[0118] II.1.1

[0119] Sample C: 10 hides (corresponding to crust leather) tanned with a chromium-free retanning formulation #2 (without treatment for odor reduction as described and claimed herein).

[0120] II.1.2

[0121] Sample D: 10 hides (corresponding to crust leather) tanned with a chromium-free retanning formulation #2 (with treatment for odor reduction as described and claimed herein).

[0122] II.1.3 Further Materials

[0123] The other materials correspond to those already used in the first pilot test.

[0124] 11.2 Test procedure

[0125] The test procedure corresponds to the test procedure of the first pilot test.

[0126] II.3 Results

[0127] One set of the odor samples taken was evaluated for odor by customers and a further set was evaluated in-house at TFL.

[0128] II.3.1 Result from Customers

[0129] Sample C Degree 3-4

[0130] Sample D Degree 3-4

[0131] II.3.2 Result at TFL

[0132] Sample C Degree 4

[0133] Sample D Degree 3-4

[0134] III. Third Pilot Test

[0135] III.1 Material and Equipment

[0136] III.1.1

[0137] Sample E: 10 splits (corresponding to crust leather) tanned with a chromium-containing retanning formulation #3 (without treatment for odor reduction as described and claimed herein).

[0138] III.1.2

[0139] Sample F: 10 splits (corresponding to crust leather) tanned with a chromium-containing retanning formulation #3 (with treatment for odor reduction as described and claimed herein).

[0140] III.1.3 Further Materials

[0141] The other materials correspond to those already used in the first pilot test.

[0142] III.2 Test Procedure

[0143] The test procedure corresponds to the test procedure of the first pilot test.

[0144] III.3 Results

[0145] One set of the odor samples taken was evaluated for odor by customers and another set was evaluated in-house at TFL.

[0146] III.3.1 Result from Customers

[0147] Sample E Degree 2-3

[0148] Sample F Degree 2

[0149] III.3.2 Result at TFL

[0150] Sample E Degree 3

[0151] Sample F Degree 2-3

LIST OF REFERENCE SYMBOLS

[0152] 1 device [0153] 2 treatment space [0154] 3 odor-reduction reservoir [0155] 4 odor-neutralizing substance [0156] 5 gas-exchange compound [0157] 6 gas exchange line [0158] 7 drum tumbler [0159] 8 chamber [0160] 9 system; closed system [0161] 10 filter; particle filter [0162] 11 gas exchange device [0163] 12 replaceable unit [0164] 13 holder [0165] 14 fragrance reservoir [0166] 15 odorant [0167] 16 gas stream; gas circulation [0168] 17 humidifier [0169] 18 nebulizer device