POTENTIAL MEASURING DEVICE AND METHOD
20220128454 · 2022-04-28
Assignee
Inventors
Cpc classification
G01R19/16528
PHYSICS
G01N17/02
PHYSICS
G01R19/2506
PHYSICS
C23F2213/31
CHEMISTRY; METALLURGY
C23F2213/21
CHEMISTRY; METALLURGY
C23F13/04
CHEMISTRY; METALLURGY
G01R19/0053
PHYSICS
International classification
Abstract
A portable unit is arranged to measure a value for polarized potential in a corrosion protection system comprising a protected structure, an anode and a reference electrode, which portable unit is connectable to the protected structure and to the reference electrode. The portable unit is arranged toperform voltage measurements to detect and monitor an instant-off sequence, wherein the corrosion protection system is turned off for a predetermined time period during normal operation. If an instant-off sequence is detected, then a voltage measurement is performed to measure a voltage signal representing a direct current potential curve for the corrosion protection system during the instant-off sequence. A step response detected in the voltage signal during an initial IR drop and a subsequent voltage decay are analysed. An initial value for the voltage signal at the time of the step response is determined and displayed as a value for polarized potential.
Claims
1. Portable unit arranged to measure a value for polarized potential in a corrosion protection system comprising a protected structure, an anode and a reference electrode, which portable unit is connectable to the protected structure and to the reference electrode; characterized in that the portable unit is arranged to perform voltage measurements to detect and monitor an instant-off sequence, wherein the corrosion protection system is turned off for a predetermined time period during normal operation; and if an instant-off sequence is detected, then the portable unit is arranged to: perform voltage measurements during the instant-off sequence; measure a voltage signal representing a direct current potential curve for the corrosion protection system during the instant-off sequence; detect a step response in the voltage signal during an initial IR drop and a subsequent voltage decay during the instant-off sequence; analyse the detected step response in the voltage signal; and determine an initial value for the voltage signal at the time of the step response and display the initial value as a value for polarized potential.
2. Portable unit according to claim 1, characterized in that the portable unit is arranged to analyse oscillations and reduce noise in the voltage signal during the detected step response by means of an algorithm, in order to resolve the voltage signal into a series of data points during a settling time of the step response and to determine the initial value for the voltage signal at the time of the step response.
3. Portable unit according to claim 2, characterized in that the portable unit is arranged to determine the initial value for the voltage signal at the time of the step response by means of a curve fitting process applied to the series of data points.
4. Portable unit according to claim 3, characterized in that the portable unit is arranged to apply a retrograde extrapolation to the curve fitting process.
5. Portable unit according to claim 1, characterized in that the portable unit is arranged to request a user input selecting a reference electrode type currently used.
6. Portable unit according to claim 5, characterized in that the portable unit is arranged to convert the determined value for polarized potential to a value for polarized potential for a selectable type of reference electrode other than the reference electrode currently used.
7. Portable unit according to claim 1, characterized in that the portable unit is arranged to determine that the corrosion protection system is an operational impressed current corrosion protection system if an instant-off sequence is detected and the determined value for polarized potential is within a predetermined range.
8. Portable unit according to claim 1, characterized in that the portable unit is arranged to determine that the impressed current corrosion protection system is operated in a back-up mode, using a sacrificial anode, if an instant-off sequence is detected and the initial IR drop towards the polarized potential is below a predetermined value.
9. Portable unit according to claim 7, characterized in that the portable unit is arranged to determine that the corrosion protection system is a sacrificial anode corrosion protection system if an instant-off sequence is not detected and the determined value for polarized potential is below the predetermined range.
10. Method for measuring a value for polarized potential in a corrosion protection system comprising a protected structure, an anode and a reference electrode, wherein a portable unit is connectable to the protected structure and to the reference electrode; characterized by the portable unit performing the steps of: monitoring and detecting an instant-off sequence, wherein the corrosion protection system is turned off for a predetermined time period during normal operation; and if an instant-off sequence is detected, then: performing voltage measurements during the instant-off sequence; measuring a voltage signal representing a direct current potential curve for the corrosion protection system during the instant-off sequence; detecting a step response in the voltage signal during an initial IR drop and a subsequent voltage decay during the instant-off sequence; analysing the detected step response in the voltage signal; and determining an initial value for the voltage signal at the time of the step response and displaying the initial value as a value for polarized potential.
11. Method according to claim 10, characterized by performing the further step of: analysing oscillations in the voltage signal during the detected step response by means of an algorithm and resolving the voltage signal into a series of data points during a settling time of the step response and to determining the initial value for the voltage signal at the time of the step response.
12. Method according to claim 10, characterized by performing the further step of: estimating the initial value for the voltage signal at the time of the step response by applying a curve fitting process to the series of data points.
13. Method according to claim 12, characterized by performing the further step of: applying a retrograde extrapolation to the curve fitting process.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0044] With reference to the appended drawings, below follows a more detailed description of embodiments of the invention cited as examples. In the drawings:
[0045]
[0046]
[0047]
[0048]
[0049]
[0050]
[0051]
[0052]
DETAILED DESCRIPTION OF EXAMPLE EMBODIMENTS OF THE INVENTION
[0053]
[0054] Regulation of the voltage and current output from the direct current power source is controlled to automate the current output while the voltage output is varied, or to automate the voltage output while the current output is varied. This allows the corrosion protection level to be maintained under changing conditions, e.g. variations in water resistivity, water temperature or water velocity. In a sacrificial anode system, increases in the seawater resistivity can cause a decrease in the anode output and a decrease in the amount of protection provided, while a change from stagnant conditions results in an increase in current demand to maintain the required protection level. With ICCP systems protection does not decrease in the range of standard seawater nor does it change due to moderate variations in current demand. An advantage of ICCP systems is that they can provide constant monitoring of the electrical potential at the water/protected structure interface and can adjust the output to the anodes in relation to this. An ICCP system comprising a reference electrode is more effective and reliable than sacrificial anode systems where the level of protection is unknown and uncontrollable.
[0055] The corrosion protection system in this example is an impressed current cathodic protection (ICCP) arrangement using the propellers 102, 103 as a cathode 115. In this example, hull mounted anodes (not shown) connected to the positive terminal 111 are used. In
[0056]
[0057] The control unit 213 is adapted to measure an electrical potential of the cathode 217 with a reference electrode 224 (R) as a ground reference. The electrical potential of the cathode 217 is measured using a voltage sensor 230. The electrical potential is indicative of the surface polarization at the interface between the cathode 217 and an electrolyte W; in this case water. The control unit 213 is further adapted to control the electrical power to the active anode 215 (A) and the cathode 217 (C) based at least partly on the measured electrical potential of the cathode 217 with the reference electrode 224 (R) as a ground reference. Through the control of the electrical power, a first electrical current (indicated by an arrow in
[0058] More specifically, the parameter of interest for control of the corrosion protection of the cathode 217 is the electrical potential of the cathode 217 with the reference electrode as a ground reference, corresponding to the surface polarization at the interface between the cathode 217 and the water W, and the electrical power to the active anode 215 and the cathode 217 is subjected to a closed loop control so as for said surface polarization to assume a desired value.
[0059] Thus, the corrosion protection system for the cathode 217 comprises an ICCP system with the active anode 215, the reference electrode 224, the battery 210 and the control unit 213. In
[0060] The control unit 213 further comprises a number of controllable switches for controlling different functions of the corrosion protection system. A first switch 231 is arranged between the positive terminal of the battery 210 and the anode 215, which first switch 231 is normally closed to supply the anode with power during an active corrosion protection mode. When opened, the first switch 231 disconnects the active anode 215 from the positive terminal of the battery 210. A second switch 232 is arranged between the negative terminal of the battery 210 and the cathode 217, which second switch 232 is normally switched to a closed position to maintain a closed circuit including the active anode 215, the cathode 217 and the battery 210 during active corrosion protection mode, wherein a current I.sub.1 flows from the battery 210 to the active anode 215. When opened, the second switch 232 can disconnect the cathode 217 from the negative terminal of the battery 210. A third switch 233 is arranged between the negative terminal of the battery 210 and the anode 215, which third switch 233 is normally open during active corrosion protection mode. When closed, the third switch 233 can connect the active anode 217 to the negative terminal of the battery 210. A fourth switch 234 is arranged to connect or disconnect a sacrificial, or passive anode 226 (PW) to or from the corrosion protection system. The fourth switch 234 is a three-position switch that is normally in a first position (lower contactor in
[0061] The corrosion protection system for the cathode 217 comprises a passive corrosion protection system with the passive anode 226 and the control unit 213. Should a fault occur in the active corrosion protection system, then the fourth switch 234 is switched from its open position to a first closed position (centre contactor in
[0062]
[0063]
[0064]
[0065] The control unit 513 is adapted to measure an electrical potential of the cathode 517 (C) with a reference electrode 524 (R) as a ground reference. The electrical potential of the cathode 517 is measured using a voltage sensor 530. The electrical potential is indicative of the surface polarization at the interface between the cathode 517 and an electrolyte G; in this case the surrounding ground. The control unit 513 is further adapted to control the electrical power to the active anode 515 (A) and the cathode 517 (C) based at least partly on the measured electrical potential of the cathode 517 (C) with the reference electrode 524 (R) as a ground reference. Through the control of the electrical power, the electrical current, through an electrical circuit comprising the active anode 215, the cathode 517 and the electrolyte G, is controlled. The parameter of interest for control of the corrosion protection of the cathode 517 is the electrical potential of the cathode 517 with the reference electrode 524 as a ground reference, corresponding to the surface polarization at the interface between the cathode 517 and the ground G, and the electrical power to the active anode 515 and the cathode 517 is subjected to a closed loop control so as for said surface polarization to assume a desired value. In this way, the corrosion protection system for the cathode 517 comprises an ICCP system with the active anode 515, the reference electrode 524, the power source 510 and the control unit 513. In
[0066]
[0067]
[0068] With an ICCP system there is a large ohmic potential drop, or IR drop, in the electrolyte (water or soil) that makes it practically impossible to get a true potential reading of the polarized potential. As described above, the IR drop is a potential drop due to solution resistance. It is the difference in potential required to move ions through the electrolyte. IR drop results from the electric current flow in ionic electrolytes like dilute acids, saltwater, certain types of soil, etc. The IR drop is an unwanted quality and it must be removed to obtain an accurate measurement of polarized potential. During operation of the ICCP system, a control unit will impress a current onto the anode and creating a negative cathodic voltage, or impressed potential U.sub.i. The impressed potential U.sub.i will be greater than the value of polarized potential U.sub.p in order to compensate for the IR drop. Therefore, ICCP systems are operated by making instant-off potential readings at certain intervals in order to determine if it needs to adjust the current output to maintain a desired or target polarized potential U.sub.t. The instant-off potential represents an effective on-potential, without the IR-drop compensation. The value of polarized potential is measured by interrupting the current for a short period of time and measuring the potential immediately following the interruption of the CP rectifier.
[0069] The potential curve in
[0070]
[0071] The accuracy of the initial value for the voltage signal at the time t.sub.0 of the step response S can be improved by means of a curve fitting process applied to the series of data points. Curve fitting can involve either interpolation, where an exact fit to the data is required, or smoothing, in which a function is constructed that approximately fits the data. A retrograde extrapolation using the fitted curve in the range of the observed data at the time of the step response can be performed to determine a value for the initial value representing the value of polarized potential U.sub.p at the time t.sub.0 of the step response.
[0072] The initial value representing the value of polarized potential U.sub.p determined by the above process is then displayed to the user. If the determined polarizing potential U.sub.p differs from the desired polarizing potential U.sub.t, or is outside an allowable polarizing potential range, then the control unit will adjust the impressed potential U.sub.i up or down accordingly. For example, when the protected cathode is a steel structure immersed in seawater, then an expected polarized potential is −800 mV if the selected reference electrode is of the saturated calomel electrode (SCE) type. Alternatively, when the protected cathode is a steel structure buried in soil, then an expected polarized potential is −850 mV if the selected reference electrode is of the Cu/CuSO.sub.4 type. As described above, the user can be prompted to input the type of reference electrode used during the measurement.
[0073] As a result of the measurements and the interpretation of the potential curve, the portable unit can also indicate the system status. According to one example, the portable unit can be arranged to determine that the corrosion protection system is an operational ICCP system if an instant-off sequence is detected and the determined value for polarized potential is within an allowable predetermined range. According to a further example, the portable unit can be arranged to determine that the corrosion protection system is an ICCP system operated in a back-up mode, using a sacrificial anode, if an instant-off sequence is detected but the initial IR drop towards the polarized potential is below a predetermined value. The predetermined value can be set relatively low as the IR drop for an ICCP system operating in a back-up mode is negligible compared to the corresponding value for an operational system. This can indicate a power supply problem or failure relating to an AC/DC rectifier, a shore power connection or insufficient battery charge. According to a further example, the portable unit can be arranged to determine that the corrosion protection system is a non-operational ICCP system if an instant-off sequence is not detected and the determined value for polarized potential is constant and below the predetermined range. In this way, the unit is able to measure a DC voltage and to interpret the measured potential signal for a structure connected to an ICCP system that operates using instant-off potential measurements and read off the value of polarized potential from that curve. The unit will also tell the user whether the system is operational in an ICCP mode or provides protection from a sacrificial anode only.
[0074] It is to be understood that the present invention is not limited to the embodiments described above and illustrated in the drawings; rather, the skilled person will recognize that many changes and modifications may be made within the scope of the appended claims.