Method of producing long body
11315707 · 2022-04-26
Assignee
Inventors
Cpc classification
B32B27/322
PERFORMING OPERATIONS; TRANSPORTING
H01B7/0838
ELECTRICITY
B32B2597/00
PERFORMING OPERATIONS; TRANSPORTING
B32B27/304
PERFORMING OPERATIONS; TRANSPORTING
B32B2327/18
PERFORMING OPERATIONS; TRANSPORTING
B32B37/12
PERFORMING OPERATIONS; TRANSPORTING
B32B7/12
PERFORMING OPERATIONS; TRANSPORTING
B32B37/06
PERFORMING OPERATIONS; TRANSPORTING
B32B2307/54
PERFORMING OPERATIONS; TRANSPORTING
B32B37/144
PERFORMING OPERATIONS; TRANSPORTING
B32B7/02
PERFORMING OPERATIONS; TRANSPORTING
B32B2371/00
PERFORMING OPERATIONS; TRANSPORTING
International classification
B32B37/12
PERFORMING OPERATIONS; TRANSPORTING
B32B7/12
PERFORMING OPERATIONS; TRANSPORTING
B32B37/06
PERFORMING OPERATIONS; TRANSPORTING
B32B7/02
PERFORMING OPERATIONS; TRANSPORTING
Abstract
There is provided a method of producing a long body covered with a covering layer, in which the long body includes at least plural electric wires and/or tubes, the covering layer includes at least a specific intermediate layer and a specific outermost layer, the method including at least: covering the long body with the covering layer; and fixing positions of the plural electric wires and/or tubes.
Claims
1. A method of producing a long body covered with a covering layer, wherein the long body at least includes a plurality of covering targets selected from the group consisting of electric wires and tubes, the covering layer at least includes an intermediate layer and an outermost layer, the intermediate layer employs a resin film having a density ρ1 of 0.2 g/cm.sup.3 or more and 1.8 g/cm.sup.3 or less and having a PV1 value, which is a surface peak-to-valley value, of 5 μm or more, the outermost layer employs a resin film having a density ρ2 of 1.2 g/cm.sup.3 or more and 2.5 g/cm.sup.3 or less, the method comprises at least: covering the long body with the covering layer, wherein the intermediate layer is positioned closer to the covering targets than the outermost layer; and fixing positions of the plurality of covering targets with the covering layer, and the following formulas (1) and (3) are satisfied in the case that a PV2 value, which is a surface peak-to-valley value of the outermost layer, is 5 μm or less, and the following formulas (2) and (3) are satisfied in the case that the PV2 value is larger than 5 μm:
PV1−PV2≥2 μm (1)
PV2−PV1>0 μm (2)
ρ2−ρ1≥0.1 g/cm.sup.3 (3),
2. The method of producing the long body covered with the covering layer according to claim 1, wherein the intermediate layer has a porous structure including a plurality of pores.
3. The method of producing the long body covered with the covering layer according to claim 1, wherein the covering layer further includes a functional layer.
4. The method of producing the long body covered with the covering layer according to claim 2, wherein the covering layer further includes a functional layer.
Description
BRIEF DESCRIPTION OF DRAWINGS
(1)
(2)
(3)
(4)
(5)
DESCRIPTION OF EMBODIMENTS
(6) Preferred embodiments of the present invention will be hereinafter described with reference to the drawings. The embodiments to be described below are not intended to restrict the claimed invention and not every combination of features described in each embodiment is indispensable for the invention.
(7)
(8) In the example of long body shown in
(9) As another example of long body that is different from the one shown in
(10)
(11) A resin film having a density ρ1 of 0.2 g/cm.sup.3 or more and 1.8 g/cm.sup.3 or less is used as the intermediate layer 112. The PV1 value of the surface of the resin film constituting the intermediate layer 112 is 5 μm or more. It is preferable that the resin constituting the intermediate layer 112 is a fluororesin such as polytetrafluoroethylene (PTFE), a tetrafluoroethylene-perfluoroalkylvinyl ether copolymer (PFA), a tetrafluoroethylene-hexafluoropropylene copolymer (FEP), or polyvinylidene fluoride (PVDF), a polyolefin resin such as polyethylene (PE), or the like.
(12) It is preferable that as mentioned above, the resin film having a density ρ1 of 0.2 g/cm.sup.3 or more and 1.8 g/cm.sup.3 or less is used as the intermediate layer 112, more preferably a resin film having a density ρ1 of 0.3 g/cm.sup.3 or more and 1.3 g/cm.sup.3 or less and particularly preferably a resin film having a density ρ1 of 0.4 g/cm.sup.3 or more and 1.0 g/cm.sup.3 or less. For example, the density of a polytetrafluoroethylene (PTFE) resin or a polyethylene (PE) resin can be controlled by processing conditions performed thereon. These resins can be worked into a porous structure by stretching. Thus, to lower the density, a porous structure composed of plural fibrils and pores formed between the fibrils can be obtained by, after the resin is molded into a sheet form, stretching the molded sheet while heating. Basically, the density is lowered by increasing the stretching ratio. In the case that stretching is performed by a single-axis stretching method in which stretching is performed from one direction, a resin film that has plural consecutive nodes and is high in physical strength can be formed. In the case that stretching is performed by a two-axis stretching method in which stretching is performed from two directions, a resin film that is lower in density can be formed, and the flexibility is increased further. The density can be also controlled by adjusting the firing temperature and time of the firing of a molded sheet and adjusting a fired state as a completely fired state, a half-fired state, or an unfired state. Furthermore, for example, it is possible to use a resin film that is worked into a porous structure through foaming at the time of extrusion molding or a resin film that is worked into a porous structure by mixing a resin and a solvent at a high temperature and then separating the mixture into two layers by lowering the temperature.
(13) A resin film having a density ρ2 of 1.2 g/cm.sup.3 or more and 2.5 g/cm.sup.3 or less can be used in the outermost layer 113.
(14) It is preferable that the resin constituting the outermost layer 113 is a fluororesin such as PTFE, tetrafluoroethylene-perfluoroalkylvinyl ether copolymer (PFA), a tetrafluoroethylene-hexafluoropropylene copolymer (FEP), a tetrafluoroethylene-ethylene copolymer (ETFE), or polychlorotrifluoroethylene (PCTFE) or a resin that does not contain a plasticizer such as polyether ether ketone (PEEK) or polyimide (PI). In general, a resin film having a thickness of 5 to 100 μm is used in the outermost layer 113.
(15) In the case that the PV2 value of the surface of the resin film constituting the outermost layer 113 is 5 μm or less, resin films are used so that the PV1 value of the surface of the resin film constituting the intermediate layer 112 and the PV2 value of the surface of the resin film constituting the outermost layer 113 satisfy a relationship of PV1−PV2≥2 μm and that the density ρ2 of the resin film constituting the outermost layer 113 and the density ρ1 of the resin film constituting the intermediate layer 112 satisfy a relationship of ρ2−ρ1≥0.1 g/cm.sup.3. In the case that the PV2 value of the surface of the resin film constituting the outermost layer 113 is larger than 5 μm, resin films are used that the PV1 value and the PV2 value satisfy a relationship of PV2−PV1>0 μm and that the density ρ2 of the resin film constituting the outermost layer 113 and the density ρ1 of the resin film constituting the intermediate layer 112 satisfy a relationship of ρ2−ρ1≥0.1 g/cm.sup.3. The PV1-PV2 relationship suitable for the invention is switched at a point where the PV2 of the surface of the long body produced by the production method according to the invention is just equal to 5 μm. It is preferable that a relationship of ρ2−ρ1≥0.3 g/cm.sup.3 be satisfied, and more preferable that a relationship of ρ2−ρ1≥1.0 g/cm.sup.3 be satisfied.
(16) The long body produced by the production method according to the invention can attain the object of the invention by the above-described constitution. While being high in flexibility, the long body can lower the degree of adhesion of foreign matters remaining on the surface of the covering layer. That is, foreign matters such as a very small amount of oil, surrounding particles, chemicals, and water in surrounding air are hard to adhere during, for example, cable handling, a process of attachment to an assembly or a machine, and operation of a machine, and can be removed easily. As a result, the long body is hard to pollute the surroundings when placed in a clean environment, and hardly generates out gas, dust particles due to wear of the long body itself, and the likes. As such, the long body as not polluting the surroundings can be obtained.
(17)
(18)
(19) The invention will be described in more detail using Examples described below. The Examples described below are not intended to restrict the claimed invention.
EXAMPLES
(20) <Measurement of Peak-to-Valley (PV) Value>
(21) A measurement was performed using a white light interference microscope New View 6300 manufactured by Zygo Corporation. A white LED was used as a light source and a Gaussian filter was used for surface filtering processing. A measurement resolution in the height direction was 0.1 nm. The observation magnification was set at fifty times and a high-frequency-side cutoff frequency (filter high wavelength) and a low-frequency-side cutoff frequency (filter low wavelength) were set at 0.00250 mm and 0.80000 mm, respectively. A surface shape was measured and a peak-to-valley (PV) value was calculated. Measurement data was analyzed using analysis software: MetroPro.
(22) <Measurement of Density ρ>
(23) A specific weight that was measured by DENSIMETER H manufactured by Toyo Seiki Seisaku-sho, Ltd. according to a collecting gas over water prescribed in JIS K 6301 was employed as a density.
(24) <Evaluation of Cleanliness>
(25) Foreign matter hardly adhesive property and foreign matter easily removable property were evaluated for adhesion of foreign matter to a long body. To evaluate the hardly adhesive property and easily removable property, ink was applied to the surface, and then an adhering state of ink and an amount of ink component that remained after the ink was wiped out by a cotton cloth, were checked. The ink component adhering state and an ink residual amount were evaluated in five levels. A case that no ink component adhered was evaluated to be “5”, a case that an ink component adhered slightly but was able to be removed completely by wiping-out was evaluated to be “4”, a case that an ink component adhered slightly and a trace of ink was slightly found after wiping-out was evaluated to be “3”, a case that ink adhered and a trace of ink was found after wiping-out was evaluated to be “2”, and a case that ink adhered and almost ink was not removed by wiping-out was evaluated to be “1”.
Example 1
(26) A PTFE resin film was used as an outermost layer and another PTFE resin film was used as an intermediate layer located inside the outermost layer. Resin films that had been cut so as to have a prescribed width were prepared. A thickness, a PV value, and a density of the resin film of each of the outermost layer or the intermediate layer were measured. Results are shown in Table 1.
(27) Next, a covering layer was produced by laminating and heating the two resin films. Covering targets were prepared in such a manner that one FEP electric wire, one FEP electric wire, one cable obtained by twisting four PFA electric wires together, one cable obtained by twisting two PFA electric wires together, and one FEP tube were arranged horizontally. A long body was produced by disposing the covering layers over and under the arranged covering targets and fixing the positions of the respective covering targets by heating web portions.
(28) An evaluation result of cleanliness is shown in Table 1.
Example 2
(29) A PTFE resin film was used as an outermost layer, a 0.02-μm-thick FEP resin film was used as an adhesive layer located inside the outermost layer, another PTFE resin film was used as an intermediate layer located further inside, and a 0.02-μm-thick FEP resin film was used as an adhesive layer located still further inside. Resin films that had been cut so as to have a prescribed width were prepared. A thickness, a PV value, and a density of the resin film of each of the outermost layer or the intermediate layer were measured. Results are shown in Table 1.
(30) Next, a covering layer was produced by laminating and heating the four resin films. Covering targets were prepared in such a manner that one FEP electric wire, one FEP electric wire, one cable obtained by twisting four PFA electric wires together, one cable obtained by twisting two PFA electric wires together, and one FEP tube were arranged horizontally. A long body was produced by disposing the covering layers over and under the arranged covering targets and fixing the positions of the respective covering targets by heating web portions.
(31) An evaluation result of cleanliness is shown in Table 1.
Example 3
(32) A PTFE resin film was used as an outermost layer, a 0.02-μm-thick FEP resin film was used as an adhesive layer located inside the outermost layer, another PTFE resin film was used as an intermediate layer located further inside, and a 0.02-μm-thick FEP resin film was used as an adhesive layer located still further inside. Resin films that had been cut so as to have a prescribed width were prepared. A thickness, a PV value, and a density of the resin film of each of the outermost layer or the intermediate layer were measured. Results are shown in Table 1.
(33) Next, a covering layer was produced by laminating and heating the four resin films. Covering targets were prepared in such a manner that one FEP electric wire, one FEP electric wire, one cable obtained by twisting four PFA electric wires together, one cable obtained by twisting two PFA electric wires together, and one FEP tube were arranged horizontally. A long body was produced by disposing the covering layers over and under the arranged covering targets and fixing the positions of the respective covering targets by heating web portions.
(34) An evaluation result of cleanliness is shown in Table 1.
Example 4
(35) An FEP resin film was used as an outermost layer, a PTFE resin film was used as an intermediate layer inside the outermost layer, and a 0.02-μm-thick FEP resin film was used as an adhesive layer located further inside. Resin films that had been cut so as to have a prescribed width were prepared. A thickness, a PV value, and a density of the resin film of each of the outermost layer or the intermediate layer were measured. Results are shown in Table 1.
(36) Next, a covering layer was produced by laminating and heating the three resin films. Covering target was prepared by twisting one cable obtained by twisting four PFA electric wires together and four FEP electric wires together. A long body was produced by winding the covering layer around the outside of the twisted covering target so as to doubly overlap, and fixing the positions of the respective covering targets by heating.
(37) An evaluation result of cleanliness is shown in Table 1.
Example 5
(38) A PEEK resin film was used as an outermost layer, a PTFE resin film was used as an intermediate layer located inside the outermost layer, and a 0.02-μm-thick FEP resin film was used as an adhesive layer located further inside. Resin films that had been cut so as to have a prescribed width were prepared. A thickness, a PV value, and a density of the resin film of each of the outermost layer or the intermediate layer were measured. Results are shown in Table 1.
(39) Next, a covering layer was produced by laminating and heating the three resin films. Covering targets were prepared in such a manner that one FEP electric wire, one FEP electric wire, one cable obtained by twisting four PFA electric wires together, one cable obtained by twisting two PFA electric wires together, and one FEP tube were arranged horizontally. A long body was produced by disposing the covering layers over and under the arranged covering targets and fixing the positions of the respective covering targets by heating web portions.
(40) An evaluation result of cleanliness is shown in Table 1.
Example 6
(41) A PTFE resin film was used as an outermost layer and a PE resin film was used as an intermediate layer located inside the outermost layer. Resin films that had been cut so as to have a prescribed width were prepared. A thickness, a PV value, and a density of the resin film of each of the outermost layer or the intermediate layer were measured. Results are shown in Table 1.
(42) Next, a covering layer was produced by laminating and heating the two resin films. Covering targets were prepared in such a manner that one FEP electric wire, one FEP electric wire, one cable obtained by twisting four PFA electric wires together, one cable obtained by twisting two PFA electric wires together, and one FEP tube were arranged horizontally. A long body was produced by disposing the covering layers over and under the arranged covering targets and fixing the positions of the respective covering targets by heating web portions.
(43) An evaluation result of cleanliness is shown in Table 1.
Example 7
(44) A PTFE resin film was used as an outermost layer and another PTFE resin film was used as an intermediate layer located inside the outermost layer. Resin films that had been cut so as to have a prescribed width were prepared. A thickness, a PV value, and a density of the resin film of each of the outermost layer or the intermediate layer were measured. Results are shown in Table 2.
(45) Next, a covering layer was produced by laminating and heating the two resin films. Covering targets were prepared in such a manner that one FEP electric wire, one FEP electric wire, one cable obtained by twisting four PFA electric wires together, one cable obtained by twisting two PFA electric wires together, and one FEP tube were arranged horizontally. A long body was produced by disposing the covering layers over and under the arranged covering targets and fixing the positions of the respective covering targets by heating web portions.
(46) An evaluation result of cleanliness is shown in Table 2.
Example 8
(47) An FEP resin film was used as an outermost layer, a PTFE resin film was used as an intermediate layer located inside the outermost layer, and a 0.02-μm-thick FEP resin film was used as an adhesive layer located further inside. Resin films that had been cut so as to have a prescribed width were prepared. A thickness, a PV value, and a density of the resin film of each of the outermost layer or the intermediate layer were measured. Results are shown in Table 2.
(48) Next, each covering layer was produced by laminating and heating the three resin films. Covering targets were prepared in such a manner that one FEP electric wire, one FEP electric wire, one cable obtained by twisting four PFA electric wires together, one cable obtained by twisting two PFA electric wires together, and one FEP tube were arranged horizontally. Along body was produced by disposing the covering layers over and under the arranged covering targets and fixing the positions of the respective covering targets by heating web portions.
(49) An evaluation result of cleanliness is shown in Table 2.
Example 91
(50) A PTFE resin film was used as an outermost layer, another PTFE resin film was used as an intermediate layer located inside the outermost layer, and a 0.02-μm-thick FEP resin film was used as an adhesive layer located further inside. Resin films that had been cut so as to have a prescribed width were prepared. A thickness, a PV value, and a density of the resin film of each of the outermost layer or the intermediate layer were measured. Results are shown in Table 2.
(51) Next, a covering layer was produced by laminating and heating the three resin films. Covering target was prepared by twisting one cable obtained by twisting four PFA electric wires together and four FEP electric wires together. A long body was produced by winding the covering layer around the outside of the twisted covering target so as to doubly overlap, and fixing the positions of the respective covering target by heating.
(52) An evaluation result of cleanliness is shown in Table 2.
Example 10
(53) A PTFE resin film was used as an outermost layer, a 0.02-μm-thick FEP resin film was used as an adhesive layer located inside the outermost layer, another PTFE resin film was used as an intermediate layer further inside, and a 0.02-μm-thick FEP resin film was used as an adhesive layer located still further inside. Resin films that had been cut so as to have a prescribed width were prepared. A thickness, a PV value, and a density of the resin film of each of the outermost layer or the intermediate layer were measured. Results are shown in Table 2.
(54) Next, a covering layer was produced by laminating and heating the four resin films. Covering targets were prepared in such a manner that one FEP electric wire, one FEP electric wire, one cable obtained by twisting four PFA electric wires together, one cable obtained by twisting two PFA electric wires together, and one FEP tube were arranged horizontally. A long body was produced by disposing the covering layers over and under the arranged covering targets and fixing the positions of the respective covering targets by heating web portions.
(55) An evaluation result of cleanliness is shown in Table 2.
Example 11
(56) A PEEK resin film was used as an outermost layer, a PTFE resin film was used as an intermediate layer located inside the outermost layer, and a 0.02-μm-thick FEP resin film was used as an adhesive layer located further inside. Resin films that had been cut so as to have a prescribed width were prepared. A thickness, a PV value, and a density of the resin film of each of the outermost layer or the intermediate layer were measured. Results are shown in Table 2.
(57) Next, a covering layer was produced by laminating and heating the three resin films. Covering targets were prepared in such a manner that one FEP electric wire, one FEP electric wire, one cable obtained by twisting four PFA electric wires together, one cable obtained by twisting two PFA electric wires together, and one FEP tube were arranged horizontally. A long body was produced by disposing the covering layers over and under the arranged covering targets and fixing the positions of the respective covering targets by heating web portions.
(58) An evaluation result of cleanliness is shown in Table 2.
Example 12
(59) A PTFE resin film was used as an outermost layer and a PE resin film was used as an intermediate layer located inside the outermost layer. Resin films that had been cut so as to have a prescribed width were prepared. A thickness, a PV value, and a density of the resin film of each of the outermost layer or the intermediate layer were measured. Results are shown in Table 2.
(60) Next, a covering layer was produced by laminating and heating the two resin films. Covering targets were prepared in such a manner that one FEP electric wire, one FEP electric wire, one cable obtained by twisting four PFA electric wires together, one cable obtained by twisting two PFA electric wires together, and one FEP tube were arranged horizontally. A long body was produced by disposing the covering layers over and under the arranged covering targets and fixing the positions of the respective covering targets by heating web portions.
(61) TABLE-US-00001 TABLE 1 Ex. 1 Ex. 2 Ex. 3 Ex. 4 Ex. 5 Ex. 6 Thickness of 0.84 0.12 0.80 0.40 0.80 0.80 intermediate layer (mm) Thickness of 0.10 0.01 0.10 0.03 0.01 0.01 outermost layer (mm) PV1 (μm) 9.40 7.47 5.95 8.10 8.10 9.80 PV2 (μm) 1.40 0.76 3.90 0.12 1.63 1.40 PV1 − PV2 (μm) 8.00 6.71 2.05 7.98 6.47 8.40 ρ1 (g/cm.sup.3) 0.67 0.45 1.78 0.75 1.15 0.45 ρ2 (g/cm.sup.3) 2.15 1.75 2.10 2.20 1.26 2.25 ρ2 − ρ1 (g/cm.sup.3) 1.48 1.30 0.32 1.45 0.11 1.80 Cleanliness 5 5 5 5 4 5
(62) TABLE-US-00002 TABLE 2 Ex. 7 Ex. 8 Ex. 9 Ex. 10 Ex. 11 Ex. 12 Thickness of 0.84 0.12 0.40 0.80 0.40 0.80 intermediate layer (mm) Thickness of 0.10 0.01 0.02 0.01 0.01 0.01 outermost layer (mm) PV1 (μm) 8.15 7.47 8.10 7.47 5.95 8.13 PV2 (μm) 9.10 8.15 11.41 7.60 6.81 10.42 PV2 − PV1 (μm) 0.95 0.68 3.31 0.13 0.86 2.29 ρ1 (g/cm.sup.3) 0.78 0.50 1.10 0.67 0.80 0.45 ρ2 (g/cm.sup.3) 1.85 1.75 1.58 2.15 1.30 2.15 ρ2 − ρ1 (g/cm.sup.3) 1.07 1.25 0.48 1.48 0.50 1.70 Cleanliness 5 4 4 4 4 4
(63) Each Example exhibited good results, that is, was superior in bendability, flexibility, and cleanliness and the covering layer themselves of long body produced less amounts of pollutants, which means a low degree of pollution caused in the surroundings.
INDUSTRIAL APPLICABILITY
(64) The long body according to the invention is superior in slipperiness, bendability, and flexibility and is low in pollution caused in the surroundings, and thus, can be used in semiconductor manufacturing machines and measurement instruments that a cleanliness is required.
DESCRIPTION OF SYMBOLS
(65) 100: Long body (flat shape), 110: Covering layer, 112: Intermediate layer, 113: Outermost layer, 200: Long body (round shape), 210: Covering layer.
CITATION LIST
Patent Literature
(66) Patent document 1: JP-A-2006-19125