METHOD FOR PRODUCING PERSONALIZED COSMETICS

Abstract

The invention belongs to the field of personalized cosmetics which, in terms of their composition, are determined by the end user (personalized), and it relates to a method for producing said cosmetics, and to dosing containers for the production thereof, and also to the use of cosmetic mixtures in the dosing containers and the use of the dosing containers for carrying out the method.

Claims

1. A method of producing a cosmetic formulation in domestically customary amounts, controllable by and/or according to the wishes of the end user of the cosmetic formulation (“personalization”), in a device having a mixing device a) and at least one dispensing device b) equipped with at least 2 dispensing vessels, in which a base mixture is present in one of the dispensing vessels b1) and the active cosmetic ingredients suitable for personalization in the other of the dispensing vessels b2), in which the contents of the dispensing vessels b1) and b2) are emptied into the mixing device a) and mixed in the mixing device, wherein the contents of the dispensing vessel b1) comprising the base mixture are emptied into the mixing device together with at least one emollient, at least one interface-active substance, and at least one rheology modifier, where the base mixture has a ratio of emollient:interface-active substance in the range from 1:4 to 25:1.

2. The method according to claim 1, wherein the base mixture comprises at least one emollient selected from the group consisting of esters of C.sub.2-C.sub.12 dicarboxylic acids with linear or branched alcohols having 1 to 22 carbon atoms, mono- and/or dicarbonates of linear or branched C.sub.6-C.sub.22 fatty alcohols, hydrocarbons, esters of linear C.sub.6-C.sub.22 fatty acids with linear or branched C.sub.6-C.sub.22 fatty alcohols, liquid mono-/di-/triglyceride mixtures based on C.sub.6-C.sub.18 fatty acids, vegetable fats and oils, and Guerbet alcohols based on fatty alcohols having 6 to 18 carbon atoms.

3. The method according to claim 1, wherein the base mixture comprises at least one nonionic and/or anionic interface-active substance.

4. The method according to claim 1, wherein the base mixture comprises at least one cationic and/or ampholytic or zwitterionic interface-active substance.

5. The method according to claim 1, wherein the base mixture comprises at least one rheology modifier selected from the group consisting of anionic, nonionic, cationic and/or zwitterionic polymers, inorganic substances selected from the group consisting of fumed silicas, bentonites and hectorites, and organic substances selected from the group consisting of fats, waxes, alcohols, and hydrocarbons having a melting point above 45° C.

6. The method according to claim 1, wherein the base mixture has a weight ratio of emollient:(interface-active substance+rheology modifier) in the range from 1:10 to 10:1.

7. The method according to claim 1, wherein b1) comprises 0.5% to 75% by weight of emollient 1% to 30% by weight of interface-active substance 1.5% to 30% by weight of rheology modifier 0% to 50% by weight of active cosmetic ingredients 0% to 25% by weight of cosmetic auxiliaries and additives 0% to 90% by weight of water, under the condition that all constituents add up to 100% by weight.

8. The method according to claim 1, wherein the cosmetic formulation comprises the base mixture in b1) in amounts of at least 5% by weight to not more than 80% by weight, based on the cosmetic formulation.

9. The method according to claim 1, wherein the active cosmetic ingredients for personalization in b2) are selected from the group consisting of active biogenic ingredients, UV light protection filters, self-tanning agents, insect repellents, antioxidants, film formers, sensory additives, effect pigments, tyrosine inhibitors (depigmenting agents), coolants, perfume oils, dyes, and humectants.

10. The method according to claim 1, wherein active cosmetic ingredients for personalization in b2) are present in an amount of at least 1% to not more than 20% by weight, based on the cosmetic formulation.

11. The method according to claim 1, wherein the dispensing device is equipped with a further dispensing vessel b3) and optionally a dispensing vessel b4).

12. The method according to claim 11, wherein the active cosmetic ingredients for personalization in the dispensing vessel b3) and/or optionally the dispensing vessel b4) are selected from the group consisting of active biogenic ingredients, UV light protection filters, self-tanning agents, insect repellents, antioxidants, film formers, sensory additives, effect pigments, tyrosine inhibitors (depigmenting agents), coolants, perfume oils, dyes, and humectants.

13. The method according to claim 11, wherein the active cosmetic ingredients in the dispensing vessel b3) and/or optionally in the dispensing vessel b4) are each present in amounts of 0.01% to not more than 20% by weight, based on the cosmetic formulation.

14. The method according to claim 1, wherein, for the production of a sunscreen as the cosmetic formulation, b1) comprises a base mixture of 10% to 60% by weight of at least one emollient, 1% to 20% by weight of anionic interface-active substances, 1% to 20% by weight of nonionic interface-active substance, 1.5% to 8% by weight of rheology modifier, 5% to 50% by weight of UV filters and optionally further active cosmetic ingredients, 0% to 25% by weight of cosmetic auxiliaries or additives, and 0% to 40% by weight of water, under the condition that the anionic and nonionic interface-active substance add up to 3% to not more than 30% by weight and all constituents add up to 100% by weight, and b2) comprises active cosmetic ingredients for personalization, cosmetic auxiliaries and additives, and any b3) and optionally b4) comprise further active cosmetic ingredients for personalization, auxiliaries and additives, and emollients.

15. The method according to claim 1, wherein, for the production of a skin lotion as the cosmetic formulation, b1) comprises a base mixture of 15% to 75% by weight of at least one emollient, 0.5% to 15% by weight of nonionic interface-active substance, 0.5% to 15% by weight of anionic interface-active substances, 2% to 30% by weight of rheology modifier, 0.0% to 25% by weight of cosmetic auxiliaries and additives, 0.0% to 25% by weight of active cosmetic ingredients, and 0.0% to 70% by weight of water, under the condition that the anionic and nonionic interface-active substance add up to 1% to not more than 20% by weight and all constituents add up to 100% by weight, and b2) comprises active cosmetic ingredients for personalization, auxiliaries and additives, and emollients, and any b3) and optionally b4) comprise further active cosmetic ingredients for personalization, auxiliaries and additives, and emollients.

16. The method according to claim 1, wherein, for the production of a conditioner formulation for hair as the cosmetic formulation, b1) comprises a base mixture of 0.5% to 10% by weight of emollient, 3.0% to 20% by weight of interface-active substance, 3.0% to 20% by weight of rheology modifier, 0% to 25% by weight of active cosmetic ingredients, 0% to 25% by weight of cosmetic auxiliaries and additives, and 0% to 90% by weight of water, under the condition that all constituents add up to 100% by weight, and b2) comprises active cosmetic ingredients for personalization, auxiliaries and additives, and any b3) and optionally b4) comprise further active cosmetic ingredients for personalization and auxiliaries and additives.

17. The method according to claim 1, wherein the device additionally has a water tank c).

18. The method according to claim 17, wherein the contents from the dispensing vessels b1) and b2) and any b3) and optionally b4) are emptied into the mixing device a) and mixed with water from the water tank c).

19. The method according to claim 18, wherein the contents from the dispensing vessels b1) and b2) and any further dispensing vessel b3) and optionally further dispensing vessel b4) are emptied into the mixing device a) and mixed with water at least in amounts of 35% by weight—based on the cosmetic formulations—from the water tank c).

20. The method according to claim 1, wherein the mixing in the mixing device a) is conducted in a mixing vessel a1) having a retractable stirrer at the base of the mixing vessel a1).

21. The method according to claim 18, wherein the mixing is followed by a retraction of the stirrer at the base of the mixing vessel a1) and closure of the mixing vessel.

22. The method according to claim 1, wherein the dispensing vessels b1), b2) and any further dispensing vessel b3) and optionally further dispensing vessel b4), before being emptied into the mixing vessel a1), are heated in a heating system d).

23. The method according to claim 11, wherein the dispensing vessels b1), b2), any b3) and any b4) are capsules.

24. The method according to claim 1, wherein the device is controlled by information or data transmitted electronically to the device or end user by a QR code.

25. The method according to claim 1, wherein the end user provides the dispensing device b) with the dispensing vessels b1), b2), and any further dispensing vessel b3) and optionally further dispensing vessel b4), in accordance with the information or data transmitted electronically to the end user.

26. The method according to claim 1, wherein the method temperatures of the heating system for the dispensing vessels and/or the amounts of water are controlled by means of the water tank via information/data on the outer wall of the dispensing vessels in a form of a QR code.

27. A dispensing vessel comprising a base mixture of at least one emollient, at least one interface-active substance and at least one rheology modifier for the production of domestically customary amounts of cosmetic formulations that can be produced immediately in situ by or at the wish of the end user and are variable in terms of their composition, according to the method of claim 1.

28. A dispensing vessel comprising active cosmetic ingredients for personalization selected from the group consisting of active biogenic ingredients, UV light protection filters, self-tanning agents, insect repellents, antioxidants, film formers, sensory additives, effect pigments, tyrosine inhibitors (depigmenting agents), coolants, perfume oils, dyes and humectants, for production of domestically customary amounts of a cosmetic formulation that are produced immediately in situ by the end user and are variable in terms of their composition, according to the method of claim 1.

29.-33. (canceled)

Description

EXAMPLES

[0346] Capsules in the various sizes “big” (capacity 11.4 ml), “medium” (capacity 2.25 ml) and “small” (capacity 0.9 ml) were filled and sealed. The “big” capsule, corresponding to b1), comprised the base mixture of the corresponding cosmetic formulation. The “medium” capsules b2) comprised the cosmetic ingredients needed for fulfilment of the personalized customer wishes (for example in capsules b2) a, b2) b or b2) c; see example 1). Capsules b3) and b4) comprised cosmetic ingredients that served for fulfilment of optional personalized customer wishes.

[0347] A capsule machine according to international patent application WO2018073541 was utilized. For production, according to the personalized customer wishes, the capsules were inserted into the devices intended. In examples 9, 10 and 11, capsule b1) was heated to 85° C. After the machine had been switched on, the capsule contents were pushed into the container; according to the cosmetic formulation chosen, water was pumped in from the separate water tank. The type of capsule(s) to be selected and the amount of water were recorded in a program for operation of the capsule machine. The amount of water required was dispensed from a water tank. If required, the water can be heated in a separate “boiler”. In examples 9, 10 and 11, the water was heated. The contents of the capsules inserted were expressed automatically and emptied into the container with stirrer (mixing device a). Stirring in the container a1) was effected at room temperature or while heating (examples 9, 10 and 11 at max. 85° C.) and at up to 5000 revolutions/min for about 2-30 minutes. The exact method conditions were controlled automatically via the programming of the capsule machine. Different amounts of formulation were produced->20, 25 or 30 g.

Example 1: Sunscreen Milk SPF 15

[0348] In example 1, various sunscreen milk formulations were produced, always by insertion of capsule b1) with one of capsules b2) a, b or c. The choice of capsule b2) depends on the wishes of the end user. Any of the 3 possible combinations gave a stable sun milk. Personalization was also possible with a further capsule b3) and b4). Capsule b1)+b2a) gave a preserved perfumed sun milk with SPF15. Capsule b1)+b2)a+b3)a gave a preserved perfumed sun milk with SPF15 and additional anti-aging effect.

TABLE-US-00002 Concentration in overall Amount formulation in required Capsule Ingredient (chemical name) % by wt. Function for 30 g b1) Di-n-Butyl adipate 4.5 Emollient 1.35 b1) Undecane, Tridecane 6.0 Emollient 1.8 C8-C18 Alkyl Ester 2.0 Emollient 0.6 Di-n-Octyl carbonate 4.25 Emollient 1.275 Caprylic/capric triglyceride 1.0 Emollient 0.3 Dodecyl glucoside 0.15 Interface-active 0.045 substance Polyglycerin poly-12- 1.2 Interface-active 0.36 hydroxystearic acid ester substance Polyethylene glycol (7) Dodecyl 1.35 Interface-active 0.405 Ether Citrate substance Sodium Stearoyl Glutamate 0.2 Interface-active 0.06 substance Sodium Acrylates Copolymer 1.0 Rheology modifier 0.3 p-Methoxycinnamic acid 2-ethyl- 2.85 UV Filter 0.855 hexylester 2,4-Diethylamino 2.85 UV Filter 0.855 Hydroxybenzoyl Hexyl Benzoate 2,4,6-Trianilino-(p-carbo-2′- 0.9 UV Filter 0.27 Ethylhexyl-1′-oxy)-1,3,5-Triazine 2,4-bis-{[4-(2-ethylhexyloxy)-2- 0.75 UV Filter 0.225 hydroxy]phenyl}-6-(4- methoxyphenyl)-(1,3,5)-triazine Benzyldimethylstearylammonium 0.6 Rheology modifier 0.18 Hectorite 2-Phenoxyethanol, 1.0 Preservatives 0.3 Phenylmethanol, Ethylhexylglycerin Phenylpropanol, 1,2- 1.0 Preservation aid 0.3 Propanediol, 1,2-Octanediol, Tocopherol 4-Methyl-1,3-dioxolan-2-one 0.15 Auxiliary 0.045 Triethanolamine 0.3 Neutralizing agent 0.09 Sodium Hydroxide (50%) 0.2 Neutralizing agent 0.06 Water, demin. 2.15 0.645 b2) a Water, Pentylene Glycol, 1.0 Active biogenic 0.3 Hamamelis Virginiana leaf ingredient extract, Xanthan gum, Caprylyl Glycol Glycerin 2.0 Humectants 0.6 Phenylpropanol, 1,2- 0.5 Preservation aid 0.15 Propanediol, 1,2-Octanediol, Tocopherol b2) b Glycerin 3.00 Humectants 0.9 b2) c D-Panthenol 2.00 Active biogenic 0.6 ingredient Glycerin 2.00 Humectants 0.6 optionally: b3) a Water, Pentylene Glycol, 1.0 Active biogenic 0.3 Hamamelis Virginiana leaf ingredient extract, Xanthan gum, Caprylyl Glycol Glycerin 2.0 Humectants 0.6 Phenylpropanol, 1,2- 0.5 Preservation aid 0.15 Propanediol, 1,2-Octanediol, Tocopherol b3) b Glycerin 3.00 Humectants 0.9 b3) c D-Panthenol 2.00 Active biogenic 0.6 ingredient Glycerin 2.00 Humectants 0.6 optionally b4) a Perfume 1 0.40 Perfume oil 0.12 C8-C18 Alkyl Ester 2.00 Emollient 0.6 b4) b Perfume 2 0.20 Perfume oil 0.06 C8-C18 Alkyl Ester 2.00 Emollient 0.6 b4) c Perfume 3 0.20 Perfume oil 0.06 C8-C18 Alkyl Ester 2.00 Emollient 0.6 Water Water, demin. ad 100 Make tank up to 30 g

[0349] All sunscreen milk formulations produced were homogeneous and stable.

Example 2: Sunscreen Milk SPF 40 or 50

[0350] Analogously to example 1, various sunscreen formulations were produced, with personalization of capsule b1) with capsule b2) and optionally with one of the further capsules b3) and b4).

[0351] Capsule b2) once again comprises a mixture comprising UV filters when a sun milk with an SPF of 50 rather than 40 is desired.

TABLE-US-00003 Concentration in overall Amount Ingredient formulation in required Capsule (chem. name) % by wt. Function for 20 g b1) Di-n-Butyl adipate 12.9 Emollient 2.58 b1) Di-n-Octyl carbonate 8.5 Emollient 1.7 Caprylic/capric triglyceride 0.5 Emollient 0.1 Sodium Acrylates Copolymer 0.5 Rheology 0.1 modifier Polyethylene glycol (7) Dodecyl 3.87 Interface-active 0.774 Ether Citrate substance Polyglycerin poly-12- 3.44 Interface-active 0.688 hydroxystearic acid ester substance Dodecyl Glucoside 0.43 Interface-active 0.086 substance Sodium Stearoyl Glutamate 0.2 Interface-active 0.04 substance Water, demin. 1.43 0.286 Benzyldimethylstearylammonium 1.2 Rheology 0.24 Hectorite modifier 4-Methyl-1,3-dioxolan-2-one 0.3 Auxiliary 0.06 p-Methoxycinnamic acid 2- 8.2 UV Filter 1.64 ethylhexylester 2,4-Diethylamino 8.2 UV Filter 1.64 Hydroxybenzoyl Hexyl Benzoate 2,4,6-Trianilino-(p-carbo-2′- 2.58 UV Filter 0.516 Ethylhexyl-1′-oxy)-1,3,5-Triazine 2,4-bis-{[4-(2-ethylhexyloxy)-2- 2.0 UV Filter 0.4 hydroxy]phenyl}-6-(4- methoxyphenyl)-(1,3,5)-triazine Sodium Hydroxide (50% 0.4 Neutralizing 0.08 solution) agent Triethanolamine 0.86 Neutralizing 0.172 agent b2) Di-n-Butyl adipate 2.1 Emollient 0.42 Polyethylene glycol (7) Dodecyl 0.63 Interface-active 0.126 Ether Citrate substance Polyglycerin poly-12- 0.56 Interface-active 0.112 hydroxystearic acid ester substance Dodecyl Glucoside 0.07 Interface-active 0.014 substance p-Methoxycinnamic acid 2-ethyl- 1.4 UV Filter 0.28 hexylester 2,4-Diethylamino 1.3 UV Filter 0.26 Hydroxybenzoyl Hexyl Benzoate 2,4,6-Trianilino-(p-carbo-2′- 0.42 UV Filter 0.084 Ethylhexyl-1′-oxy)-1,3,5-Triazine 2,4-bis-{[4-(2-ethylhexyloxy)-2- 0.35 UV Filter 0.07 hydroxy]phenyl}-6-(4- methoxyphenyl)-(1,3,5)-triazine Triethanolamine 0.14 Neutralizing 0.028 agent Water, demin. 0.07 0.014 optionally b3) a Dipropylheptyl carbonate 5 Emollient 1.25 2-Phenoxyethanol, 1 Preservative 0.25 Ethylhexylglycerin Perfume 1 1 Perfume oil 0.25 b3) b Undecane, Tridecane 5 Emollient 1.25 2-Phenoxyethanol, 1 Preservative 0.25 Ethylhexylglycerin Perfume 2 1 Perfume oil 0.25 b3) c 2-Propylheptyl Octanoate 5 Emollient 1.25 2-Phenoxyethanol, 1 Preservative 0.25 Ethylhexylglycerin Perfume 3 1 Perfume oil 0.25 optionally b4) a Water, Pentylene Glycol, 1 Active biogenic 0.25 Hamamelis Virginiana leaf ingredient extract, Xanthan gum, Caprylyl Glycol b4) b Glycerin 2.0 Humectants 0.5 b4) c D-Panthenol 2.0 Active biogenic 0.5 ingredient Water tank Water, demin. ad 100 Make up to 20 g Make up to 20 g

[0352] All sun milk formulations produced were homogeneous and stable.

Example 3: Skin Lotion

[0353] Analogously to example 1, various skin lotions were produced, with personalization of capsule b1) with one of capsules b2) and optionally one of the further capsules b3) and optionally one of capsules b4).

TABLE-US-00004 Concentration in overall Amount Ingredient formulation in required Capsule (chem. name) % by wt. Function for 30 g b1) C20 Guerbet Alcohol 3.0 Emollient 0.9 Undecane, Tridecane 1.0 Emollient 0.3 Di-n-Octyl carbonate 0.85 Emollient 0.255 Sodium Polyacrylate 0.7 Rheology modifier 0.21 Dodecyl Glucoside 0.75 Interface-active 0.225 substance Polyglycerin poly-12- 0.75 Interface-active 0.225 hydroxystearic acid ester substance Benzyldimethylstearylammonium 0.12 Rheology modifier 0.036 Hectorite 4-Methyl-1,3-dioxolan-2-one 0.03 Auxiliary 0.009 Glycerin 0.75 Humectants 0.225 2-Phenoxyethanol, 1.0 Preservatives 0.3 Ethylhexylglycerin Phenylpropanol, 1,2- 1.0 Preservation aid 0.3 Propanediol, 1,2-Octanediol, Tocopherol Water, demin. 0.75 0.225 b2) a Water, Pentylene Glycol, 1.0 Active biogenic 0.3 Hamamelis Virginiana leaf ingredient extract, Xanthan gum, Caprylyl Glycol Glycerin 2.0 Humectants 0.6 Phenylpropanol, 1,2- 0.5 Preservation aid 0.15 Propanediol, 1,2-Octanediol, Tocopherol b2) b Glycerin 3.0 Humectants 0.9 b2) c D-Panthenol 2.0 Active biogenic 0.6 ingredient Glycerin 2.0 Humectants 0.6 optionally: b3) a Water, Pentylene Glycol, 1.0 Active biogenic 0.3 b3) a Hamamelis Virginiana leaf ingredient extract, Xanthan gum, Caprylyl Glycol Glycerin 2.0 Humectants 0.6 Phenylpropanol, 1,2- 0.5 Preservation aid 0.15 Propanediol, 1,2-Octanediol, Tocopherol b3) b Glycerin 3.0 Humectants 0.9 b3) c D-Panthenol 2.0 Active biogenic 0.6 ingredient Glycerin 2.0 Humectants 0.6 optionally b4) a Perfume 1 0.4 Perfume oil 0.12 C8-C18 Alkyl Ester 2.0 Emollient 0.6 b4) b Perfume 2 0.2 Perfume oil 0.06 C8-C18 Alkyl Ester 2.0 Emollient 0.6 b4) c Perfume 3 0.2 Perfume oil 0.06 C8-C18 Alkyl Ester 2.0 Emollient 0.6 Water tank Water, demin. ad 100 Make up to 30 g

[0354] Homogeneous stable skin lotions are obtained.

Example 4: Face Serum

[0355] Analogously to example 1, various face sera were produced, with personalization of capsule b1) with one of capsules b2) and optionally one of the further capsules b3) and optionally one of capsules b4).

TABLE-US-00005 Concentration in overall Amount Ingredient formulation in required Capsule (chem. name) % by wt. Function for 30 g b1) Shea Butter 1.0 Emollient 0.3 b1) Di-n-Octyl carbonate 5.0 Emollient 1.5 2-Propylheptyl Octanoate 6.0 Emollient 1.8 C8-C18 Alkyl Ester 6.0 Emollient 1.8 Pentaerythrityl Distearate 2.0 Rheology modifier 0.6 Sodium Polyacrylate 0.4 Rheology modifier 0.12 Polyacrylic Acid 0.1 Rheology modifier 0.03 Disodium C16-18 Alkyl 0.8 Interface-active 0.24 Sulfosuccinate substance Aluminum Starch 2.0 Sensory additive 0.6 Octenylsuccinate 1,2-Hexanediol, 1,2- 0.5 Preservation aid 0.15 Octanediol Hydroxyacetophenone 0.5 Auxiliary 0.15 Cassia Angustifolia 0.1 Active biogenic 0.03 Polysaccharides ingredient Water 11.6 3.48 b2) a Argania Spinosa Leaf 0.15 Active biogenic 0.045 Extract, Maltodextrin ingredient Glycerin 3.0 Humectants 0.9 b2) b Glycerin 3.0 Humectants 0.9 Glycerin, Water, Khaya 1.0 Active biogenic 0.3 Senegalensis Bark ingredient Extract, Maltodextrin b2) c Water, Butylene Glycol, 3.0 Active biogenic 0.9 Pentylene Glycol, ingredient Sarcosine, Xanthan Gum Glycerin 3.0 Humectants 0.9 b2) d Water, Butylene Glycol, 1.0 Active biogenic 0.3 Pentylene Glycol, Achillea ingredient Millefolium Extract, Xanthan Gum Glycerin 3.0 Humectants 0.9 b2) e Pisum Sativum (Pea) 0.2 Active biogenic 0.06 Extract, Cyclodextrin ingredient Glycerin 3.0 Humectants 0.9 optionally: b3) a Argania Spinosa Leaf 0.15 Active biogenic 0.045 Extract, Maltodextrin ingredient Glycerin 3.0 Humectants 0.9 b3) b Glycerin 3.0 Humectants 0.9 Glycerin, Water, Khaya 1.0 Active biogenic 0.3 Senegalensis Bark ingredient Extract, Maltodextrin b3) c Water, Butylene Glycol, 3.0 Active biogenic 0.9 Pentylene Glycol, ingredient Sarcosine, Xanthan Gum Glycerin 3.0 Humectants 0.9 b3) d Water, Butylene Glycol, 1.0 Active biogenic 0.3 Pentylene Glycol, Achillea ingredient Millefolium Extract, Xanthan Gum Glycerin 3.0 Humectants 0.9 b3) e Pisum Sativum (Pea) 0.2 Active biogenic 0.06 Extract, Cyclodextrin ingredient Glycerin 3.0 Humectants 0.9 optionally b4) a Perfume 1 0.2 Perfume oil 0.06 2-Propylheptyl Octanoate 2.0 Emollient 0.6 b4) b Perfume 2 0.2 Perfume oil 0.06 2-Propylheptyl Octanoate 2.0 Emollient 0.6 b4) c Perfume 3 0.2 Perfume oil 0.06 2-Propylheptyl Octanoate 2.0 Emollient 0.6 Water tank Water, demin. ad 100 Make up to 30 g

[0356] Homogeneous stable face sera were obtained.

Example 5: Face Fluid

[0357] Analogously to example 1, various face fluids were produced, with personalization of capsule b1) with one of capsules b2) and optionally with one of capsules b3).

TABLE-US-00006 Concentration in overall Amount Ingredient formulation in required Capsule (chem. name) % by wt. Function for 30 g b1) Sodium Stearoyl Glutamate 0.8 Interface-active 0.24 substance Argania Spinosa Kernel Oil 1.0 Emollient 0.3 C8-C18 Alkyl Ester 2.0 Emollient 0.6 C12-15 alkyl benzoates 2.0 Emollient 0.6 Undecane, Tridecane 2.0 Emollient 0.6 Di-n-Octyl carbonate 2.125 Emollient 0.765 Behenyl Alcohol 3.0 Rheology modifier 0.9 Xanthan Gum 0.3 Rheology modifier 0.09 Polyacrylamidomethylpropane 0.24 Rheology modifier 0.072 Sulfonic Acid Benzyldimethylstearylammonium 0.3 Rheology modifier 0.09 Hectorite 2-Phenoxyethanol, 1.0 Preservatives 0.3 Ethylhexylglycerin 1,3-butanediol 3.0 Humectants 0.9 4-Methyl-1,3-dioxolan-2-one 0.075 Auxiliary 0.0225 Water 22.16 6.648 b2) a 1,3-butanediol 2.0 Humectants 0.6 Bixa Orellana Seed Extract, 0.25 Active biogenic 0.075 Maltodextrin ingredient b2) b 1,3-butanediol 2.0 Humectants 0.6 Argania Spinosa Leaf Extract, 0.15 Active biogenic 0.045 Maltodextrin ingredient b2) c 1,3-butanediol 2.0 Humectants 0.6 Aqua, Dimethyl Isosorbide, 2.0 Active biogenic 0.6 Polysorbate 20, Acetyl ingredient Tetrapeptide-11, Acetyl Tetrapeptide-9 optionally b3) a Perfume 1 0.2 Perfume oil 0.06 Sodium Acrylates Copolymer 0.25 Rheology modifier 0.075 Caprylic/capric triglyceride 0.25 Emollient 0.075 Water 0.5 0.15 b3) b Perfume 2 0.2 Perfume oil 0.06 Sodium Acrylates Copolymer 0.25 Rheology modifier 0.075 Caprylic/capric triglyceride 0.25 Emollient 0.075 Water 0.5 0.15 b3) c Perfume 3 0.2 Perfume oil 0.06 Sodium Acrylates Copolymer 0.25 Rheology modifier 0.075 Caprylic/capric triglyceride 0.25 Emollient 0.075 Water 0.5 0.15 Water tank Water, demin. ad 100 Make up to 30 g

[0358] Homogeneous stable face fluids were obtained.

Example 6: Skin Cream

[0359] Analogously to example 1, various skin creams were produced, with personalization of capsule b1) with one of capsules b2) and optionally with one of capsules b3).

TABLE-US-00007 Concentration overall Amount Ingredient formulation in required Capsule (chem. name) % by wt. Function for 30 g b1) Sucrose Polystearate 1.7 Interface-active 0.51 substance Sodium Stearoyl 0.2 Interface-active 0.06 Glutamate substance Cetyl/stearyl alcohol 3.0 Rheology modifier 0.9 Cetyl Palmitate 0.3 Rheology modifier 0.09 Glyceryl Stearates 1.0 Rheology modifier 0.3 Xanthan Gum 0.3 Rheology modifier 0.09 Shea Butter 3.0 Emollient 0.9 Octyl Decanoate/Octyl 4.6 Emollient 1.38 Octanoate Caprylic/capric 3.0 Emollient 0.9 triglyceride Sodium benzoate 0.55 Preservatives 0.165 Glycerin 3.0 Humectants 0.9 Water 20.35 6.105 b2) a Caprylic/capric 0.5 Emollient 0.15 triglyceride Maltodextrin, Nephelium 0.1 Active biogenic 0.03 Lappaceum Leaves ingredient Extract Sodium Acrylates 0.5 Rheology modifier 0.15 Copolymer Water 1.0 0.3 b2) b Caprylic/capric 0.5 Emollient 0.15 triglyceride Octyldodecanol, 2.0 Active biogenic 0.6 Hydrogenated Coco- ingredient Glycerides, Helianthus Annuus Seed Extract Sodium Acrylates 0.5 Rheology modifier 0.15 Copolymer Water 1.0 0.3 b2) c Caprylic/capric 0.5 Emollient 0.15 triglyceride Brassica Campestris 1.0 Active biogenic 0.3 (Rapeseed) Sterols ingredient Sodium Acrylates 0.5 Rheology modifier 0.15 Copolymer Water 1.0 0.3 optionally b3) a Perfume 1 0.2 Perfume oil 0.06 Octyl Decanoate/Octyl 1.0 Emollient 0.3 Octanoate b3) b Perfume 2 0.2 Perfume oil 0.06 Octyl Decanoate/Octyl 1.0 Emollient 0.3 Octanoate b3) c Perfume 3 0.2 Perfume oil 0.06 Octyl Decanoate/Octyl 1.0 Emollient 0.3 Octanoate Water tank Water, demin. ad 100 Make up to 30 g

[0360] Homogeneous stable skin creams were obtained.

Example 7: Skin Lotion

[0361] Analogously to example 1, various skin lotions were produced, with personalization of capsule b1) with one of capsules b2) and optionally with one of capsules b3).

TABLE-US-00008 Concentration in overall Amount Ingredient formulation in required Capsule (chem. name) % by wt. Function for 30 g b1) Behenyl Alcohol, 1.5 Interface-active 0.45 ethoxylated (25 EO units) substance 2-Propylheptyl Octanoate 2.0 Emollient 0.6 C8-C18 Alkyl Ester 2.0 Emollient 0.6 Dipropylheptyl carbonate 2.0 Emollient 0.6 Behenyl Alcohol 1.0 Rheology modifier 0.3 Sodium Polyacrylate 0.5 Rheology modifier 0.15 Xanthan Gum 0.1 Rheology modifier 0.03 2-Phenoxyethanol, 1.0 Preservatives 0.3 Ethylhexylglycerin Glycerin 3.0 Humectants 0.9 Disodium 0.02 Complexing agents 0.006 Ethylenediaminetetraacetate Water 24.88 Solvents 7.464 b2) a Glycerin 2.0 Humectants 0.6 Glycerin, Nephelium 2.0 Active biogenic 0.6 Lappaceum Peel Extract ingredient b2) b Glycerin 2.0 Humectants 0.6 Glycerin, Water, Inonotus 1.0 Active biogenic 0.3 Obliquus (Mushroom) ingredient Extract b2) c Glycerin 2.0 Humectants 0.6 Glycerin, Water, Sodium 5.0 Active biogenic 1.5 PCA, Urea, Trehalose, ingredient Hexylene Glycol, Polyquaternium-51, Triacetin, Caprylyl Glycol, Sodium Hyaluronate optionally b3) a Perfume 1 0.3 Perfume oil 0.09 2-Propylheptyl Octanoate 2.0 Emollient 0.6 b3) b Perfume 2 0.3 Perfume oil 0.09 2-Propylheptyl Octanoate 2.0 Emollient 0.6 b3) c Perfume 3 0.3 Perfume oil 0.09 2-Propylheptyl Octanoate 2.0 Emollient 0.6 Water tank Water, demin. ad 100 Make up to 30 g

[0362] Homogeneous stable skin lotions were obtained.

Example 8: Skin Lotion

[0363] Analogously to example 1, various skin lotions were produced, with personalization of capsule b1) with one of capsules b2) and optionally with one of capsules b3).

TABLE-US-00009 Concentration in overall Amount Ingredient formulation in required Capsule (chem. name) % by wt. Function for 30 g b1) Disodium C16-18 Alkyl 0.2 Interface-active 0.06 Sulfosuccinate substance Hexadecyl D-glucoside, 1.0 Interface-active 0.3 Octadecyl D-glucoside substance 2-Propylheptyl Octanoate 3.0 Emollient 0.9 Passionflower oil 1.0 Emollient 0.3 Octyl Decanoate/Octyl 3.0 Emollient 0.9 Octanoate Cetyl/stearyl alcohol 1.0 Rheology modifier 0.3 Pentaerythrityl Distearate 1.0 Rheology modifier 0.3 Sodium Polyacrylate 0.5 Rheology modifier 0.15 Xanthan Gum 0.1 Rheology modifier 0.03 2-Phenoxyethanol, 1.0 Preservatives 0.3 Ethylhexylglycerin Glycerin 3.0 Humectants 0.9 Water, demin. 23.2 5.385 b2) a 1,2-Propanediol 2.0 Humectants 0.6 Water, β-Glucan, 2- 2.5 Active biogenic 0.75 Phenoxyethanol ingredient b2) b Glycerin 1.5 Humectants 0.45 Glyceryl Glucoside, 3.0 Active biogenic 0.9 Glycerin ingredient b2) c Glycerin 2.0 Humectants 0.6 Water, Dimethyl 2.0 Active biogenic 0.6 Isosorbide, Polysorbate ingredient 20, Acetyl Tetrapeptide- 11, Acetyl Tetrapeptide-9 optionally b3) a Perfume 1 0.1 Perfume oil 0.03 Passionflower oil 2.0 Emollient 0.6 b3) b Perfume 2 0.1 Perfume oil 0.03 Passionflower oil 2.0 Emollient 0.6 b3) c Perfume 3 0.1 Perfume oil 0.03 Passionflower oil 2.0 Emollient 0.6 Water tank Water, demin. ad 100 Make up to 30 g

[0364] Homogeneous stable skin lotions were obtained.

Example 9: Hair Conditioner

[0365] Analogously to example 1, various conditioner formulations were produced by personalization of capsule b1) with one of capsules b2).

TABLE-US-00010 Concentration in overall Amount Ingredient formulation in required Capsule (chem. name) % by wt. Function for 30 g b1) Hexadecyltrimethylammonium 4.0 Interface-active 1.2 b1) chloride substance Cetyl/stearyl alcohol 3.5 Rheology modifier 1.05 Glyceryl Laurate 0.5 Rheology modifier 0.15 Octanoic/Decanoic Acid 1.5 Emollient 0.45 Triglyceride Dioctyl ether 0.5 Emollient 0.15 Glycerin 1.0 Humectants 0.3 Sodium benzoate 0.5 Preservatives 0.15 Citric acid 0.4 Neutralizing agent 0.12 Water, demin. 17.0 5.1 b2) a Water, Pyridoxine HCl, 3.0 Active biogenic 0.9 Niacinamide, Glycerin, ingredient Panthenol, Hydrolyzed Yeast Protein, Threonine, Allantoin, Biotin b2) b Hydrolyzed Rice Protein 1.0 Active biogenic 0.3 ingredient b2) c Panthenol, Propylene glycol 2.0 Active biogenic 0.6 ingredient b2) d Argania Spinosa Kernel Oil 1.0 Emollient 0.3 Water tank Water, demin. ad 100 Make up to 30 g

[0366] Homogeneous stable conditioner formulations were obtained.

Example 10 Conditioner for the Hair

[0367] Analogously to example 1, various conditioner formulations were produced, with personalization of capsule b1) with one of capsules b2) and optionally one of the further capsules b3) and optionally one of capsules b4).

TABLE-US-00011 Concentration in overall Amount Ingredient formulation in required Capsule (chem. name) % by wt. Function for 30 g b1) Hexadecyltrimethylammonium 4.0 Interface-active 1.2 chloride substance Cetyl/stearyl alcohol 3.5 Rheology modifier 1.05 C16-C18 Triglycerides 2.0 Emollient 0.6 Glycerin 1.0 Humectants 0.3 Sodium benzoate 0.5 Preservatives 0.15 Citric acid 0.5 Neutralizing agent 0.15 Water, demin. 17.0 5.1 b2) a Panthenol, Propylene glycol 2.0 Active biogenic 0.6 ingredient b2) b Water, Glycerin, Moringa 2.0 Active biogenic 0.6 Oleifera Seed Extract ingredient b2) c Octyldodecanol, 2.0 Active biogenic 0.6 Hydrogenated Coco- ingredient Glycerides, Helianthus Annuus Seed Extract b2) d Hydrolyzed Rice Protein 2.0 Active biogenic 0.6 ingredient Optionally: b3) a Panthenol, Propylene glycol 2.0 Active biogenic 0.6 ingredient b3) b Water, Glycerin, Moringa 2.0 Active biogenic 0.6 Oleifera Seed Extract ingredient b3) c Octyldodecanol, 2.0 Active biogenic 0.6 Hydrogenated Coco- ingredient Glycerides, Helianthus Annuus Seed Extract b3) d Hydrolyzed Rice Protein 2.0 Active biogenic 0.6 ingredient Optionally: b4) a Perfume 1 0.5 Perfume oil 0.15 b4) b Perfume 2 0.5 Perfume oil 0.15 b4) c Perfume 3 0.5 Perfume oil 0.15 Water tank Water, demin. ad 100 Make up to 30 g

[0368] Homogeneous stable conditioner formulations were obtained.

Example 11: Conditioner Formulations for the Hair

[0369] Analogously to example 1, various conditioner formulations were produced by personalization of capsule b1) with one of capsules b2).

TABLE-US-00012 Concentration in overall Amount Ingredient formulation in required Capsule (chem. name) % by wt. Function for 30 g b1) Sodium Hexadecyl 0.84 Interface-active 0.252 Sulfate/Sodium substance Octadecyl Sulfate Hexadecyl D- 0.1 Interface-active 0.03 glucoside, Octadecyl substance D-glucoside Lecithin 1.12 Interface-active 0.336 substance Cetyl/stearyl alcohol 4.3 Rheology modifier 1.29 C20 Guerbet Alcohol 0.5 Emollient 0.15 C16-C18 0.84 Emollient 0.252 Triglycerides Sodium benzoate 0.5 Preservatives 0.15 Citric acid 0.55 Neutralizing agent 0.165 Water, demin. 25.0 7.5 b2) a Water, Pyridoxine 3.0 Active biogenic 0.9 HCl, Niacinamide, ingredient Glycerin, Panthenol, Hydrolyzed Yeast Protein, Threonine, Allantoin, Biotin b2) b Hydrolyzed Rice 1.0 Active biogenic 0.3 Protein ingredient b2) c Octyldodecanol, 2.0 Active biogenic 0.6 Hydrogenated Coco- ingredient Glycerides, Helianthus Annuus Seed Extract b2) d Octadecenyl 1.0 Emollient 0.3 Docosenoate Water tank Water, demin. ad 100 Make up to 30 g

[0370] Homogeneous stable conditioner formulations were obtained.

Comparative Example: Skin Serum/Comparison with Example 4

[0371] The ingredients was stirred in the amounts specified, stored for one day and then introduced into capsule b1). Even before the capsule had been closed, separation phenomena were observed. Analogously to example 4, capsule b1) was personalized in each case with one of capsules b2). The ratio of emollient:interface-active substance was outside the range of the invention at 38.5:1.

TABLE-US-00013 Concentration in overall Amount Ingredient formulation in required Capsule (chem. name) % by wt. Function for 30 g b1) Dioctyl ether 3.0 Emollient 0.9 Di-n-Octyl carbonate 1.7 Emollient 0.51 C8-C18 Alkyl Ester 3.0 Emollient 0.9 Benzyldimethylstearylammonium 0.24 Rheology modifier 0.072 Hectorite Sodium Polyacrylate 0.5 Rheology modifier 0.15 Polyacrylic Acid 0.3 Rheology modifier 0.09 Disodium C16-18 Alkyl 0.2 Interface-active 0.06 Sulfosuccinate substance propylene glycol 2.0 Humectants 0.6 butylene glycol 2.0 Humectants 0.6 Glycerin 5.0 Humectants 1.5 2-Phenoxyethanol, 1.0 Preservatives 0.3 Ethylhexylglycerin 4-Methyl-1,3-dioxolan-2-one 0.06 Auxiliary 0.018 Ethanol 3.0 Preservatives 0.9 Water 18.0 5.4 b2) a Argania Spinosa Leaf Extract, 0.15 Active biogenic 0.045 Maltodextrin ingredient Glycerin 3.0 Humectants 0.9 b2) b Glycerin 3.0 Humectants 0.9 Glycerin, Water, Khaya 1.0 Active biogenic 0.3 Senegalensis Bark Extract, ingredient Maltodextrin b2) c Water, Butylene Glycol, 3.0 Active biogenic 0.9 Pentylene Glycol, Sarcosine, ingredient Xanthan Gum Glycerin 3.0 Humectants 0.9 b2) d Water, Butylene Glycol, 1.0 Active biogenic 0.3 b2) d Pentylene Glycol, Achillea ingredient Millefolium Extract, Xanthan Gum Glycerin 3.0 Humectants 0.9 b2) e Pisum Sativum (Pea) Extract, 0.2 Active biogenic 0.06 Cyclodextrin ingredient Glycerin 3.0 Humectants 0.9 Water tank Water, demin. ad 100 Make up to 30 g

[0372] The formulations obtained from b1)+any one of the b2) capsules each resulted in unstable skin sera that showed separation of water after storage at room temperature for 3 days.

[0373] Table 1 shows the amount of the base mixture b1) in % by weight for emollient, interface-active substances and rheology modifiers, and the defined ratios of the above examples:

TABLE-US-00014 b1 % % interf.- (base) emollient act. S. G % rheol. % water Example in g E in b1 in b1 R in b1 in b1 E:G E:(G + R) 1 10.320 51.6 8.4 4.7 6.3 6.1:1 3.9:1 2 11.102 39.5 14.3 3.1 2.6 2.8:1 2.3:1 3 3.210 45.3 14.0 7.7 7.0 3.2:1 2.1:1 4 10.800 50.0 2.2 6.9 32.2 22.5:1  5.5:1 5 12.128 23.6 2.0 9.5 54.8 11.9:1  2.1:1 6 12.300 25.9 4.6 11.2 49.6 5.6:1 1.6:1 7 11.400 15.8 3.9 4.2 65.5 .sup. 4:1 1.9:1 8 9.825 21.4 3.7 7.9 54.8 5.8:1 1.8:1 9 8.670 6.9 13.8 13.8 58.8 .sup. 1:2 .sup. 1:3 10 8.550 7.0 14.0 12.3 59.6 .sup. 1:2 .sup. 1:3 11 10.125 4.0 6.1 12.7 74.1 .sup. 2:3 .sup. 1:5 Comp. ex. vs. ex. 4 11.970 19.3 0.5 2.5 45.1 38.5:1  6.4:1