DYEING COMPOSITION COMPRISING A SPECIFIC ANTHRAQUINONE CATIONIC DIRECT DYE, A CATIONIC SURFACTANT, AN AMPHOTERIC OR ZWITTERIONIC SURFACTANT AND A FATTY ALCOHOL

Abstract

The invention relates to a composition for dyeing human keratin fibers, preferably the hair, comprising: —one or more anthraquinone cationic direct dyes; —one or more polyols, —one or more anionic surfactants, and—one or more nonionic polysaccharides.

Claims

1-17. (canceled)

18. A composition for dyeing keratin fibers, comprising: (a) at least one cationic direct dye of formula (I): ##STR00017## wherein: R.sup.1, R.sup.2 and R.sup.3 are independently chosen from a hydrogen atom or an optionally substituted (C.sub.1-C.sub.8)alkyl group; R.sup.4 represents a hydrogen atom or an optionally substituted (C.sub.1-C.sub.8)alkyl group; R.sup.5 represents a hydrogen atom, an optionally substituted (C.sub.1-C.sub.8)alkyl group, an optionally substituted (C.sub.1-C.sub.8)alkylene group, a halogen, a hydroxyl group, or a (C.sub.1-C.sub.8)alkoxy group; n represents a number between 1 and 8; and Q.sup.− represents an organic or mineral anionic counterion, (b) at least one cationic surfactant, (c) at least one amphoteric or zwitterionic surfactant, and (d) at least one fatty alcohol.

19. The composition of claim 18, comprising at least one cationic direct dye chosen from cationic dyes of formula (I′) or (I″): ##STR00018## wherein Q.sup.− represents an anionic counterion.

20. The composition of claim 18, comprising at least one cationic direct dye chosen from HC Blue 16 or HC Blue 17.

21. The composition of claim 18, wherein the total amount of cationic direct dyes of formula (I) ranges from 0.01% to 15% by weight, relative to the total weight of the composition.

22. The composition of claim 18, comprising at least one cationic surfactant (b) chosen from: cationic surfactants corresponding to the general formula (II): ##STR00019## wherein: the groups R.sub.1 to R.sub.4 are independently chosen from a linear or branched aliphatic group comprising from 1 to 30 carbon atoms, or an aromatic group, wherein at least one of the groups R.sub.1 to R.sub.4 represents a linear or branched aliphatic radical comprising from 8 to 30 carbon atoms, and X.sup.− is an anion chosen from halides, phosphates, acetates, lactates, (C.sub.1-C.sub.4)alkyl sulfates, (C.sub.1-C.sub.4)alkylsulfonates, or (C.sub.1-C.sub.4)alkylarylsulfonates, quaternary ammonium salts of imidazoline of formula (III): ##STR00020## wherein: R.sub.5 represents an alkenyl or alkyl group comprising from 8 to 30 carbon atoms, R.sub.6 represents a hydrogen atom, a C.sub.1-C.sub.4 alkyl group, or an alkenyl or alkyl group comprising from 8 to 30 carbon atoms, R.sub.7 represents a C.sub.1-C.sub.4 alkyl group, R.sub.8 represents a hydrogen atom or a C.sub.1-C.sub.4 alkyl group, and X.sup.− is an anion chosen from halides, phosphates, acetates, lactates, alkyl sulfates, alkylsulfonates or alkylarylsulfonates in which the alkyl and aryl groups comprise, respectively, from 1 to 20 carbon atoms and from 6 to 30 carbon atoms, quaternary diammonium or triammonium salts of formula (IV): ##STR00021## wherein: R.sub.9 denotes an alkyl radical comprising from 16 to 30 carbon atoms, which is optionally hydroxylated and/or optionally interrupted with one or more oxygen atoms, R.sub.10 is chosen from hydrogen or an alkyl radical comprising from 1 to 4 carbon atoms or a group (R.sub.9a)(R.sub.10a)(R.sub.11a)N—(CH.sub.2).sub.3, R.sub.9a, R.sub.10a, R.sub.11a, R.sub.11, R.sub.12, R.sub.13 and R.sub.14, which may be identical or different, are chosen from hydrogen or an alkyl radical comprising from 1 to 4 carbon atoms, and X.sup.− is an anion chosen from halides, acetates, phosphates, nitrates, (C.sub.1-C.sub.4)alkyl sulfates, (C.sub.1-C.sub.4)alkylsulfonates, and (C.sub.1-C.sub.4)alkylarylsulfonates, or quaternary ammonium salts of formula (V): ##STR00022## wherein: R.sub.15 is chosen from C.sub.1-C.sub.6 alkyl groups or C.sub.1-C.sub.6 hydroxyalkyl or dihydroxyalkyl groups, R.sub.16 is chosen from: the group: ##STR00023## the groups R.sub.20, which are linear or branched, saturated or unsaturated C.sub.1-C.sub.22 hydrocarbon-based groups, or a hydrogen atom, R.sub.18 is chosen from: the group: ##STR00024## the groups R.sub.22, which are linear or branched, saturated or unsaturated C.sub.1-C.sub.6 hydrocarbon-based groups, or a hydrogen atom, R.sub.17, R.sub.19 and R.sub.21, which may be identical or different, are chosen from linear or branched, saturated or unsaturated C.sub.7-C.sub.21 hydrocarbon-based groups; r, s, and t, which may be identical or different, are integers ranging from 2 to 6; y is an integer ranging from 1 to 10; x and z, which may be identical or different, are integers ranging from 0 to 10; and X.sup.− is a simple or complex and organic or mineral anion; with the provisos that: the sum x+y+z is from 1 to 15, when x is 0 then R.sub.16 denotes R.sub.20, and when z is 0 then R.sub.18 denotes R.sub.22.

23. The composition of claim 22, comprising at least one cationic surfactant chosen from those of formula (II) or of formula (V).

24. The composition of claim 18, where the total amount of cationic surfactants ranges from 0.1% to 15% by weight, relative to the total weight of the composition.

25. The composition of claim 18, comprising at least one amphoteric or zwitterionic surfactant chosen from (C.sub.8-C.sub.20)alkylbetaines, (C.sub.8-C.sub.20)alkylamido(C.sub.3-C.sub.8)alkylbetaines, or mixtures of two or more thereof.

26. The composition of claim 18, wherein the total amount of amphoteric or zwitterionic surfactants ranges from 0.1% to 20% by weight, relative to the total weight of the composition.

27. The composition of claim 18, comprising at least one fatty alcohol chosen from linear or branched, saturated or unsaturated fatty alcohols comprising from 8 to 40 carbon atoms.

28. The composition of claim 18, comprising at least one solid fatty alcohol.

29. The composition of claim 18, further comprising at least one polysaccharide.

30. The composition of claim 29, wherein the total amount of polysaccharides ranges from 0.01% to 20% by weight, relative to the total weight of the composition.

31. The composition of claim 18, further comprising at least one silicone.

32. The composition of claim 31, wherein the total amount of silicones ranges from 0.01% to 30% by weight, relative to the total weight of the composition.

33. The composition of claim 18, further comprising at least one basifying agent.

34. A method for dyeing keratin fibers comprising applying to the keratin fibers a composition comprising: (a) at least one cationic direct dye of formula (I): ##STR00025## wherein: R.sup.1, R.sup.2 and R.sup.3 are independently chosen from a hydrogen atom or an optionally substituted (C.sub.1-C.sub.8)alkyl group; R.sup.4 represents a hydrogen atom or an optionally substituted (C.sub.1-C.sub.8)alkyl group; R.sup.5 represents a hydrogen atom, an optionally substituted (C.sub.1-C.sub.8)alkyl group, an optionally substituted (C.sub.1-C.sub.8)alkylene group, a halogen, a hydroxyl group, or a (C.sub.1-C.sub.8)alkoxy group; n represents a number between 1 and 8; and Q.sup.− represents an organic or mineral anionic counterion, (b) at least one cationic surfactant, (c) at least one amphoteric or zwitterionic surfactant, and (d) at least one fatty alcohol.

35. The method of claim 34, wherein the total amount of cationic direct dyes of formula (I) ranges from 0.01% to 15% by weight, relative to the total weight of the composition.

36. The method of claim 34, wherein the total amount of cationic surfactants ranges from 0.1% to 15% by weight, relative to the total weight of the composition.

37. The method of claim 34, wherein the total amount of amphoteric or zwitterionic surfactants ranges from 0.1% to 20% by weight, relative to the total weight of the composition.

Description

EXAMPLES

[0292] In the examples that follow, all the amounts are given as weight percentages of active material (AM) relative to the total weight of the composition, unless otherwise specified.

Example 1

[0293] Compositions A and B were prepared from the ingredients whose contents are indicated in the table below:

TABLE-US-00001 TABLE 1 A B (comparative) CETEARYL ALCOHOL 7 7 PROPYLENE GLYCOL 2 2 XIAMETER MEM-8299 1.8 (raw material) 1.8 (raw material) EMULSION AMODIMETHICONE 1.03 1.03 TRIDECETH-6 0.09 0.09 CETRIMONIUM CHLORIDE 0.018 0.018 SCLEROTIUM GUM 1 1 ETHANOLAMINE 0.04 0.04 COCAMIDOPROPYL BETAINE 3.8 — BEHENTRIMONIUM 3.16 6.96 CHLORIDE HC BLUE NO. 16 1 1 Preserving agent 0.74 0.74 Water qs 100 qs 100 pH 6.7 ± 0.3 6.7 ± 0.3

[0294] Measurement of the Viscosity of the Compositions:

[0295] The viscosity is measured by means of a Rheomat RM 180 rheometer (200 rpm, 21.9° C., measurement at 30 s, spindle 3).

[0296] The results obtained are as follows (expressed in mPa.Math.s):

TABLE-US-00002 TABLE 2 Composition A Composition B Viscosity 815 mPa .Math. s 1060 mPa .Math. s

[0297] Composition A according to the invention has a lower viscosity than comparative composition B. Thus, composition A according to the invention is easy to use, that is to say easy to apply and to spread uniformly on the hair.

[0298] Dyeing Results:

[0299] Compositions A and B are applied to locks of natural 90% gray hair, in a proportion of 5 g of composition per gram of lock of hair.

[0300] The locks were then placed on hotplates thermostatically regulated at 27° C. After a leave-on time of 15 minutes, the locks are rinsed and dried.

[0301] The coloration of the locks of hair is evaluated in the L*a*b* system, with a MINOLTA CM2002 ® spectrophotometer.

[0302] In this system, L* represents the intensity; the lower the value of L*, the more intense and powerful the coloring.

TABLE-US-00003 TABLE 3 L* A (invention) 35.32 B (comparative) 37.94

[0303] A more powerful coloring of the locks is obtained with composition A according to the invention than with composition B.

[0304] Study of the Color of the Rinsing Water (Bleeding Test) after One Shampoo Wash:

[0305] Compositions A and B were applied to locks of natural gray hair in a proportion of 5 g of composition per gram of hair. At the end of a leave-on time of 15 min, the hair is rinsed and then washed with a standard shampoo. It is observed that the color of the rinsing water for the locks dyed with composition A is lighter than that of the locks dyed with composition B: there is less bleeding of the color with composition A according to the invention compared to composition B.

Example 2

[0306] Compositions A1 and B1 were prepared from the ingredients whose contents are indicated in the table below:

TABLE-US-00004 TABLE 4 A1 invention B1 comparative PROPYLENE GLYCOL 2 2 AMODIMETHICONE 1 1 SCLEROTIUM GUM 1 1 ETHANOLAMINE 0.04 0.04 DISODIUM COCOAMPHODIACETATE 3.8 3.8 DIPALMITOYLETHYL 3.16 — HYDROXYETHYLMONIUM METHOSULFATE CETEARYL ALCOHOL 7.37 7.37 HC BLUE NO. 16 1 1 Preservative 0.74 0.74 Water Qs 100 Qs 100 pH 6.7 +/− 0.3 6.7 +/− 0.3

[0307] Dyeing Results:

[0308] Compositions A1 and B1 are applied to locks of permed wave white hair, in a proportion of 5 g of composition per gram of lock of hair.

[0309] The locks were then placed on hotplates thermostatically regulated at 27° C. After a leave-on time of 15 minutes, the locks are rinsed and dried.

[0310] The coloration of the locks of hair is evaluated in the L*a*b* system, with a MINOLTA CM2002 ® spectrophotometer.

[0311] In this system, L* represents the intensity; the lower the value of L*, the more intense and powerful the coloring.

TABLE-US-00005 TABLE 5 L* A (invention) 33.76 B (comparative) 37.61

[0312] A more powerful coloring of the locks is obtained with composition A1 according to the invention than with composition B1.

[0313] Study of the Color of the Rinsing Water (Bleeding Test) after One Shampoo Wash:

[0314] Compositions A1 and B1 were applied to locks of hair in a proportion of 5 g of composition per gram of hair. At the end of a leave-on time of 15 min, the hair is rinsed and then washed with a standard shampoo. It is observed that the color of the rinsing water for the locks dyed with composition A1 is lighter than that of the locks dyed with composition B1: there is less bleeding of the color with composition A1 according to the invention compared to composition B1.