SOLID POLYMER ELECTROLYTES FOR SOLID-STATE LITHIUM METAL BATTERIES

Abstract

A solid polymer electrolyte including a comb-chain crosslinked network formed by reacting poly(glycidyl methacrylate) with a functionalized poly(ethylene glycol) or functionalized poly(ethylene oxide). Batteries including the solid polymer electrolytes, a cathode, and a metal anode or one or more lithium salts are also described. A process of preparing the solid polymer electrolyte involves reacting a poly(glycidyl methacrylate) with a functionalized poly(ethylene glycol) or functionalized poly(ethylene oxide) to form a crosslinked network in a single-step polymerization process. The solid polymer electrolyte provides improved resistance to lithium dendrite formation and has excellent physical and electrical properties that make it particularly suitable for use in lithium batteries.

Claims

1. A solid polymer electrolyte comprising a comb-chain crosslinked network formed by reacting poly(glycidyl methacrylate) with a functionalized poly(ethylene glycol) or functionalized poly(ethylene oxide) in the presence of one or more lithium salts.

2. The solid polymer electrolyte of claim 1, wherein the poly(glycidyl methacrylate) has from 10 to 5000 epoxide groups or 1,420 to 710,000 g/mol of number average molecular weight.

3. The solid polymer electrolyte of claim 1, wherein the poly(glycidyl methacrylate) has from 50 to 1000 epoxide groups or 7,100 to 142,000 of number average molecular weight.

4. The solid polymer electrolyte of claim 1, wherein the functionalized poly(ethylene glycol) is an amine-terminated diterminal functionalized poly(ethylene glycol), and the poly(glycidyl methacrylate) is reacted with the amine-terminated diterminal functionalized poly(ethylene glycol).

5. The solid polymer electrolyte of claim 1, wherein the functionalized poly(ethylene oxide) is an amine-terminated diterminal functionalized poly(ethylene oxide), and the poly(glycidyl methacrylate) is reacted with the amine-terminated diterminal functionalized poly(ethylene oxide).

6. The solid polymer electrolyte of claim 1, where poly(glycidyl methacrylate) is reacted with the functionalized poly(ethylene glycol) or the functionalized poly(ethylene oxide) in a molar ratio between epoxide and PEG or PEO of from 1:1 to 60:1.

7. The solid polymer electrolyte of claim 1, where poly(glycidyl methacrylate) is reacted with the functionalized poly(ethylene glycol) or functionalized poly(ethylene oxide) in a molar ratio between epoxide and PEG or PEO of from 2:1 to 10:1.

8. The solid polymer electrolyte of claim 1, where the functionalized poly(ethylene glycol) is an amine-terminated diterminal functionalized poly(ethylene glycol), and the poly(glycidyl methacrylate) is reacted with the amine-terminated diterminal functionalized poly(ethylene glycol) in a molar ratio between epoxide and PEG or PEO of from 2:1 to 40:1.

9. The solid polymer electrolyte of claim 8, wherein the amine-terminated diterminal functionalized poly(ethylene glycol), has a number average molecular weight of from about 200 g/mol to about 30,000 g/mol.

10. The solid polymer electrolyte of claim 8, wherein the amine-terminated diterminal functionalized poly(ethylene glycol), has a number average molecular weight of from about 1,000 g/mol to about 6,000 g/mol.

11. The solid polymer electrolyte of claim 1, wherein the poly(glycidyl methacrylate has a number average molecular weight of from about 1,420 to about 710,000 g/mol, or from about 7,100 to about 142,000 g/mol.

12. The solid polymer electrolyte of claim 1, wherein an overall ionic conductivity of the solid polymer electrolyte is 1.3×10.sup.−4 S cm.sup.−1 or greater, at 20° C. and the solid polymer electrolyte has a toughness as measured at 25° C. of greater than 0.1 M.Math.J.Math.m.sup.3.

13. A battery comprising the solid polymer electrolyte of claim 1, a cathode, and a metal anode.

14. A battery comprising the solid polymer electrolyte of claim 1 and one or more lithium salts.

15. The battery of claim 14, wherein a molar ratio of epoxide groups of the poly(glycidyl methacrylate) to the one or more lithium salts is from 1:1 to 20:1.

16. The battery of claim 14, wherein the one or more lithium salts have anion(s) selected from the group consisting of bis(trifluoromethanesulfonyl)imide, bis(trifluoromethane)sulfonamide, hexafluoroarsenate, hexfluorophosphate, perchlorate, tetrafluoroborate, tris(pentafluoroethyl)trifluorophosphate, trifluoromethanesulfonate, bis(fluorosulfonyl)imide, cyclo-difluoromethane-1,1-bis(sulfonyl)imide, cyclo-hexafluoropropane-1,1-bis(sulfonyl)imide, bis(perfluoroethyanesulfonyl)imide, bis(oxalate)borate, difluoro(oxalato)borate, dicyanotriazolate, tetracyanoborate, dicyanotriazolate, dicyano-trifluoromethyl-imidazole, and dicyano-pentafluoroethyl-imidazole.

17. The battery of claim 13, wherein the solid polymer electrolyte is a membrane having a thickness of less than 35 μm.

18. A process of preparing the solid polymer electrolyte of claim 1, comprising reacting the poly(glycidyl methacrylate) with the functionalized poly(ethylene glycol) or the functionalized poly(ethylene oxide) in the presence of one or more lithium salts to form a crosslinked network in a single-step polymerization process.

19. The process of claim 18, wherein the functionalized poly(ethylene glycol) is an amine-terminated diterminal functionalized poly(ethylene glycol), and the poly(glycidyl methacrylate) is reacted with the amine-terminated diterminal functionalized poly(ethylene glycol).

20. The process of claim 18, wherein the solid polymer electrolyte is prepared in the presence of a solvent, which is removed during/after the reaction, the solvent is selected from the group consisting of tetrahydrofuran, diethyl ether, acetonitrile, ethyl acetate, and methyl acetate and the electrolyte is prepared in the presence of lithium bis(trifluoromethane)sulfonimide.

21-23. (canceled)

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0025] FIG. 1A shows a schematic of network formed from small molar mass crosslinker (hollow circles).

[0026] FIG. 1B shows a schematic of network formed by a comb-chain crosslinker.

[0027] FIG. 2A shows a photograph of the obtained ConSPE membranes.

[0028] FIG. 2B shows another photograph of the obtained ConSPE membranes.

[0029] FIG. 2C shows a Scanning electron microscope (SEM) image of 4PGMA-PEG6k ConSPE membrane.

[0030] FIG. 3A shows Fourier Transform Infrared (FTIR) spectra of the PGMA-PEG ConSPE.

[0031] FIG. 3B shows an enlarged portion of the spectra of FIG. 3A between 550 cm.sup.−1 and 1400 cm.sup.−1.

[0032] FIGS. 4A-4D show thermal and electrochemical properties of PGMA-PEG ConSPEs.

[0033] FIG. 4A shows Differential scanning calorimetry (DSC) second heating thermograms.

[0034] FIG. 4B shows the temperature dependence of ionic conductivities (ionic conductivities of POSS-4PEG2k and MPEG2000 are from Refs..sup.30 and .sup.35, respectively).

[0035] FIG. 4C shows a comparison of ionic conductivities at 25° C., 40° C., and 90° C., and ethylene oxide (EO) weight percent in the network.

[0036] FIG. 4D shows linear sweep voltammetry (LSV) curves for various products (LSV curve of POSS-4PEG2k is from Ref..sup.30.)

[0037] FIG. 5 shows thermogravimetric analysis (TGA) curves of the PGMA-PEG ConSPEs.

[0038] FIG. 6 shows Fogel-Tamman-Fulcher (VTF) fitting of the temperature-dependent ionic conductivity for ConSPEs.

[0039] FIG. 7 shows the chronoamperometry profiles and the impedance responses before and after a chronoamperometry test for the symmetrical lithium cells with 4PGMA-PEG6k ConSPE at 90° C.

[0040] FIG. 8A shows stress-strain curves for 4PGMA-PEG2k at 25° C. and 90° C.

[0041] FIG. 8B shows stress-strain curves for 2PGMA-PEG2k at 25° C. and 90° C.

[0042] FIG. 8C shows stress-strain curves for 4PGMA-PEG6k at 25° C. and 90° C.

[0043] FIG. 8D shows stress-strain curves for 2PGMA-PEG6k at 25° C. and 90° C.

[0044] FIG. 9A shows the time-voltage profiles of symmetrical lithium cells with the 4PGMA-PEG6k ConSPE at 90° C. and 1 mA cm.sup.−2 with an areal capacity of 3 mAh cm.sup.−2.

[0045] FIG. 9B shows the time-voltage profiles of symmetrical lithium cells with the 4PGMA-PEG6k ConSPE at 90° C. and 2 mA cm.sup.−2 with an areal capacity of 2 mAh cm.sup.−2.

[0046] FIG. 9C shows the time-voltage profiles of symmetrical lithium cells with the 4PGMA-PEG6k ConSPE at 25° C. and 0.05 mA cm.sup.−2 with an areal capacity of 0.05 mAh cm.sup.−2.

[0047] FIG. 9D shows the correlation of normalized short-circuit time t.sub.sc for Li/ConSPE/Li cells 9 mA cm.sup.−2, 3 mAh cm.sup.−2, (at least two cells were tested for each con ConSPE and the average values were used) with ConSPE toughness and modulus.

[0048] FIG. 9E shows a comparison of normalized short-circuit time t.sub.sc for 4PGMA-PEG6k ConSPE developed in this work with the state-of-the-art SPEs.

[0049] FIG. 10A shows time-dependent voltage profiles of symmetrical lithium cells at 90° C. and 1 mA cm.sup.−2 with an areal capacity of 3 mAh cm.sup.−2 for 4PGMA-PEG2k.

[0050] FIG. 10B shows time-dependent voltage profiles of symmetrical lithium cells at 90° C. and 1 mA cm.sup.−2 with an areal capacity of 3 mAh cm.sup.−2 for 2PGMA-PEG2k.

[0051] FIG. 10C shows time-dependent voltage profiles of a symmetrical lithium cells at 90° C. and 1 mA cm.sup.−2 with an areal capacity of 3 mAh cm.sup.−2 for 2PGMA-PEG6k ConSPEs.

[0052] FIGS. 11A-11C show X-ray photoelectron spectroscopy (XPS) spectra for the lithium surface of a symmetrical Li/4PGMA-PEG6k/Li cell after cycling at 90° C. and 1 mA cm.sup.−2 before etching with an Ar ion gun (1 kV for 1 min).

[0053] FIG. 11A shows the XPS spectra for elemental carbon before etching.

[0054] FIG. 11B shows the XPS spectra for elemental oxygen before etching.

[0055] FIG. 11C shows the XPS spectra for elemental fluorine before etching.

[0056] FIGS. 11D-11F show XPS spectra for the lithium surface of a symmetrical Li/4PGMA-PEG6k/Li cell after cycling at 90° C. and 1 mA cm.sup.−2 after etching with an Ar ion gun (1 kV for 1 min).

[0057] FIG. 11D shows the XPS spectra for elemental carbon after etching.

[0058] FIG. 11E shows the XPS spectra for elemental oxygen after etching.

[0059] FIG. 11F shows the XPS spectra for elemental fluorine after etching.

[0060] FIGS. 12A-12G show full battery performance of ConSPE-based fuel cells.

[0061] FIG. 12A shows Li/LiFePO.sub.4 battery performance for the 4PGMA-PEG6k ConSPE in terms of discharge capacity and Coulombic efficiency %.

[0062] FIG. 12B shows Li/LiFePO.sub.4 battery performance for the 4PGMA-PEG6k ConSPE in terms of charge-discharge curves under different current rates at 90° C.

[0063] FIG. 12C shows Li/LiFePO.sub.4 battery performance for the 4PGMA-PEG6k ConSPE in terms of discharge capacity and coulombic efficiency % at 90° C. under a 1C rate.

[0064] FIG. 12D shows Li/LiFePO.sub.4 battery performance for the 4PGMA-PEG6k ConSPE in terms of discharge capacity and coulombic efficiency % at 25° C. under a 0.1 C rate.

[0065] FIG. 12E shows SEM images of lithium anode surfaces before rate tests at 90° C.

[0066] FIG. 12F-12G show SEM Images of lithium anode surfaces after rate tests at 90° C.

[0067] FIGS. 12H-12I show Li/Li/Ni.sub.0.6Mn.sub.0.2Co.sub.0.2O.sub.2 battery performance of 4 PGMA-PEG6k ConSPE at 90° C. under a current density of 20 mA g.sup.−1.

[0068] FIG. 12H shows the discharge capacity and coulombic efficiency %.

[0069] FIG. 12I shows the charge-discharge curves for the 1.sup.st and 50.sup.th cycles.

[0070] FIGS. 13A-13B show Li/LiFePO.sub.4 battery performance of 4 PGMA-PEG6k ConSPE.

[0071] FIG. 13A shows the discharge capacity and coulombic efficiency at 50° C. under different C rates.

[0072] FIG. 13B shows the charge-discharge curves at 25° C., 50° C., and 90° C.

[0073] FIG. 14A shows a schematic of network formed by a comb-chain crosslinker.

[0074] FIG. 14B shows the Li/LiFePO.sub.4 battery performance in terms of voltage.

[0075] FIG. 14C shows the Li/LiFePO.sub.4 battery performance in terms of discharge capacity and coulombic efficiency.

DETAILED DESCRIPTION

[0076] Poly(glycidyl methacrylate)-based ConSPEs are synthesized using a facile one-pot method. The chemical, thermal, mechanical, and electrochemical properties of the ConSPEs are carefully characterized. The correlation between the network structure and ConSPE performance is shown by preparing a series of ConSPEs with different crosslinking densities and network mesh sizes through changing the poly(glycidyl methacrylate) monomer/PEG molar ratio and PEG molar mass, respectively. The prepared PGMA-PEG ConSPEs exhibited superior overall properties and improved LMB device performance compared with the state-of-the-art SPEs with an ionic conductivity of 1.31×10.sup.−4 S cm.sup.−1 at 40° C., high electrochemical stability over 5.3 V vs. Li/Li.sup.+, excellent toughness, excellent lithium dendrite resistance up to 2 mA cm.sup.−2, and superior battery performance over a wide temperature range from 25° C. to 90° C.

[0077] As shown in FIG. 1, the homogeneously crosslinked network of poly(glycidyl methacrylate)-PEG ConSPEs (denoted as xPGMA-PEGn, in which x denotes the molar ratio of poly(glycidyl methacrylate) monomer/PEG, and n is the PEG molar mass, as shown in Table 1) was formed by the reaction between epoxy groups from PGMA and amine groups from amine-terminated PEG. Lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) (molar ratio of ethylene oxide (EO)/Li.sup.+=16) with high ionic conductivity and thermal stability.sup.9 was employed as the lithium salt. The obtained ConSPE membranes are transparent and flexible, with a smooth surface as observed from photographs and scanning electron microscopy (SEM) image in FIG. 2. Fourier transform infrared (FTIR) spectra (FIG. 3) indicate that all the ConSPE samples are highly crosslinked since the majority of epoxy groups have reacted after crosslinking.

[0078] Thermal properties of the as-prepared PGMA-PEG ConSPEs were evaluated using differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA), and the results are shown in FIG. 4A and FIG. 5, respectively. The glass transition temperature, T.sub.g, and the degree of crystallinity, X.sub.c, of the ConSPE samples are listed in Table 1. T.sub.g of PGMA homopolymer is 62° C. For ConSPEs, due to the large PEG content, PEG dominates the system. The ConSPE T.sub.gs range from −47.2 to −39.1° C. and it decreases with the EO content in the network. There is no PEG crystallization peak for the two ConSPE samples with PEG2k, indicating that the PEG crystallization was completely suppressed after crosslinking. For ConSPEs with PEG6k, DSC heating curves show a recrystallization exothermic peak before crystal melting. The endothermic melting peaks are located between 32° C. and 33° C., which are much lower than the melting temperature of PEG6k homopolymer (around 60° C.). The degree of crystallinity X.sub.c of ConSPE samples can be calculated from the equation

X.sub.c=(ΔH.sub.m−ΔH.sub.c)/(ΔH.sub.m,0×w))  (1)

in which ΔH.sub.m, ΔH.sub.c, ΔH.sub.m,0 and w denote the ConSPE melting enthalpy, enthalpy of recrystallization, the melting enthalpy of a 100% crystalline form of PEO (196.6 J g.sup.−1),.sup.33 and the PEG weight percentage in the ConSPE, respectively. Relatively low X.sub.cs of 14.5% and 15.6% are found for these two ConSPEs as shown in Table 1, suggesting that a small portion of the PEG is crystallized in the sample. From the TGA curves shown in FIG. 5, it can be seen that thermal decomposition temperatures T.sub.5% (temperature when 5% weight loss occurs) for the PGMA-PEG ConSPEs are between 325° C. and 351° C., confirming its high thermal stability, which is crucial for high temperature applications as well as mitigating the safety hazard triggered by thermal runaway..sup.34

TABLE-US-00001 TABLE 1 Characteristics of PGMA-PEG ConSPEs. Ionic conductivity Oxidation EO wt/% EO wt/% T.sub.g X.sub.c [mS cm.sup.−1] potential ConSPE in network in ConSPE [° C.] [%] 25° C. 40° C. 90° C. [V] t.sub.Li+ 2PGMA-PEG2k 87.2 64.3 −42.9 — 0.021 0.066 0.854 5.3 0.188 4PGMA-PEG2k 77.3 58.6 −39.1 — 0.003 0.012 0.203 5.5 0.150 2PGMA-PEG6k 95.5 68.7 −47.2 15.6 0.033 0.131 1.22 5.5 0.234 4PGMA-PEG6k 91.3 66.6 −46.0 14.5 0.025 0.092 1.02 5.7 0.172

[0079] Ionic conductivities of PGMA-PEG ConSPEs were measured using AC impedance spectroscopy. FIG. 4B and Table 1 show that the ionic conductivities increase with temperature, and the curves can be fitted with the Vogel-Tammann-Fulcher (VTF) equation (FIG. 6, Table 2), demonstrating that the ion transport in PGMA-PEG ConSPEs is facilitated by polymer chain reptation..sup.36 EO weight ratio in the network and ionic conductivities at 25° C., 40° C. and 90° C. for the ConSPEs are listed and plotted in Table 1 and FIG. 4C. For all the ConSPE samples, with the increase of EO weight ratio in the network, the ionic conductivity increases and the activation energy decreases, which is because PEG acts as the lithium ion solvating medium and increasing the PEG content could decrease T.sub.g and also increase the number of dissociated ions since the EO/Li molar ratio remains constant. Among all the ConSPEs, 2PGMA-PEG6k shows the highest ionic conductivity of 1.31×10.sup.−4 S cm.sup.−1 at 40° C. and 1.22×10.sup.−3 S cm.sup.−1 at 90° C., which are comparable to the state-of-the-art all-solid-state SPEs,.sup.18, 24 compositem.sup.37, 38 and plasticized.sup.25, 39 polymer electrolytes. Compared with poly(ethylene glycol) methyl ether (MPEG, =2k)-LiTFSI SPE,.sup.35 PGMA-PEG ConSPEs show similar ionic conductivities at high temperature (≥50° C.) and one order of magnitude higher below 40° C., which is due to the suppression of PEG crystallization as confirmed by DSC results. Moreover, ionic conductivities of the previously reported POSS-4PEG2k SPE.sup.18, 30 are plotted in FIGS. 4B and 4C for comparison. The 2PGMA-PEG2k ConSPE with the same epoxy/amine ratio and PEG molar mass exhibits 1.3-1.8 times higher ionic conductivities than POSS-4PEG2k, which can be attributed to the higher EO weight ratio in the network (87.2% vs. 80.0% for POSS-4PEG2k).

[0080] The electrochemical stability is evaluated by linear sweep voltammetry (LSV). As shown in FIG. 4D and Table 1, compared with linear PEO-based SPEs and POSS-4PEG2k SPE (4-4.5 V),.sup.30, 40 the anodic stability of the ConSPEs dramatically enhances to over 5.3 V vs. Li/Li.sup.+, and increases with the increase of PGMA content, which could be attributed to the robust cross-linking network structure and the ester groups in PGMA that act as a protective layer for EO groups..sup.41 The higher anodic stability of ConSPEs with PEG6k compared to those with PEG2k is likely due to less terminal groups that are unstable at high voltage..sup.42 The remarkable electrochemical stability enables the combination of ConSPEs with high-voltage cathodes (LiNi.sub.xMn.sub.yCo.sub.1-x-yO.sub.2, LiCoO.sub.2, et al.) for high-energy-density LMBs. The lithium ion transference numbers t.sub.Li+ of PGMA-PEG ConSPEs are between 0.150 and 0.234 (FIG. 7, Table 1), which are typical for PEO-based SPEs..sup.8, 18, 43

[0081] Sufficient mechanical strength is essential for successful battery applications and lithium dendrite growth resistance.sup.44 during repeated cycling in LMBs. The mechanical properties of PGMA-PEG ConSPEs were investigated by tensile tests at both 25° C. and 90° C., and the results are shown in FIG. 8 and Table 3. For ConSPEs with PEG2k, there is no significant change from 25° C. to 90° C. since PEG crystallization is completely suppressed. While for ConSPEs with PEG6k, due to partial crystallization of PEG, the modulus and toughness decrease when the temperature rises to 90° C. When increasing the PEG molar mass from 2k to 6k g mol.sup.−1, ConSPE modulus decreases while its elongation-at-break and toughness significantly increase. 4PGMA-PEG6k ConSPE shows the highest toughness at both 25° C. and 90° C. The mechanical properties of the POSS-PEG SPE are also listed in Table 3 for comparison. The toughness of 2PGMA-PEG2k ConSPE is 5.6 times that of the POSS-4PEG2k SPE with the same epoxy/amine ratio and PEG molar mass, which confirms our strategy that employing high-functionality PGMA as the crosslinker would generate a more robust network.

[0082] Lithium plating-stripping tests were employed to evaluate the lithium deposition stability and the lithium dendrite resistance of the PGMA-PEG ConSPEs. As shown in FIG. 9, symmetrical lithium cells with the 4PGMA-PEG6k ConSPE exhibits a short circuit time t.sub.sc of 580 h when cycled at 90° C. under the current density of 1 mA cm.sup.−2 with an areal capacity of 3 mAh cm.sup.−2, and 266 h under 2 mA cm.sup.−2 with 2 mAh cm.sup.−2. Even at 25° C., the cell is able to deliver stable cycling under the current density of 0.05 mA cm.sup.−2 with the areal capacity of 0.05 mAh cm.sup.−2 for over 6000 h, indicating high stability with lithium and excellent lithium dendrite resistance of the ConSPE. FIG. 10 shows the time-voltage profiles for the other three ConSPEs. All samples exhibit stable lithium plating-stripping behavior over 100 h at 90° C. under 1 mA cm.sup.−2 with the areal capacity of up to 3 mAh cm.sup.−2. In the previous study, t.sub.sc is proved to be proportional to the SPE thickness..sup.45 Therefore, the t.sub.sc values from previous literatures and in this work are normalized using a thickness of 100 μm as the benchmark. While plotting normalized t.sub.sc versus ConSPE modulus, a bell-shaped curve is seen in FIG. 9D, indicating an optimum modulus for cell cycling, which is consistent with our previous report..sup.46 The plotting of normalized t.sub.sc versus ConSPE toughness (FIG. 9D) indicates that the normalized t.sub.sc monotonically increases from 208 h to 315 h as the ConSPE toughness changed from 0.03 to 1.08 MJ m.sup.−3. This confirms our hypothesis that rather than modulus, toughness which reflects both strength and extensibility.sup.39 plays an important role in lithium dendrite resistance.

[0083] The short circuit time t.sub.sc of ConSPEs is compared with the previously reported SPEs with different molecular architectures, as shown in FIG. 9E. The 4PGMA-PEG6k ConSPE shows better performance than linear PEO SPEs,.sup.47 copolymer SPEs.sup.20, 48 and other cross-linked SPEs..sup.18, 24, 30, 32, 49 In particular, it demonstrates impressive performance at a high current density, which is desired for future LMB applications.

[0084] The surface chemistry of lithium in the symmetrical Li/4PGMA-PEG6k/Li cell after cycling was examined by X-ray photoelectron spectroscopy (XPS), and the spectra for C 1s, O 1s, and F is are shown in FIG. 11. The signals for N 1s and S 2p are too weak to be analyzed. The lithium surface contains similar components (C—C, C—OR, LiF, Li—OR, Li.sub.2CO.sub.3) to Li/PEO-LiTFSI SPE surface.sup.50 with strong LiF and Li.sub.2CO.sub.3 signals and less salt degradation products (Li.sub.2S, Li.sub.2S.sub.2, Li.sub.2SO.sub.3, Li.sub.3N) compared to Li/POSS-PEG SPE surface,.sup.46 which is attributed to the more integrated and robust PGMA-PEG network. Compared with the spectra before etching, the spectra after etching with Ar ion gun (1 kV for 1 min), which correspond to the inner SEI composition, show higher content of inorganic species LiF, LiOH and Li.sub.2CO.sub.3, and lower content of aliphatic carbon (C—C) and ether carbon (C—OR) from the polymer, exhibiting a construction similar to the mosaic-type SEI model..sup.51 COOR mainly derived from the decomposition of the ester group in PGMA also increases after etching, which may form a protective layer together with the inorganic species to protect the lithium anode and prevent the further decomposition of the lithium salts.

[0085] Since the 4PGMA-PEG6k ConSPE sample shows high ionic conductivity, good electrochemical stability, and outstanding mechanical strength, it was chosen for further LMB performance study. Because of the excellent mechanical toughness of the 4PGMA-PEG6k sample, an ultra-thin self-standing membrane with a thickness of about 20-30 μm was obtained. Thin SPEs are desired to improve the energy and power density of LMBs..sup.52 Since there is limited room for SPE conductivity improvement due to the chain reptation nature, thinner SPE membranes with lower SPE resistance can compensate for the relatively low SPE conductivity. Current ultrathin SPE membranes are obtained using a porous fiber scaffold infiltrated with polymer electrolytes..sup.52 The increased initial viscosity and chain entanglement before crosslinking of the ConSPE's of the present invention significantly improve the processability of the SPE, which enables ˜20 μm SPE fabrication.

[0086] Li/LiFePO.sub.4 batteries were assembled using the ultra-thin 4PGMA-PEG6k ConSPE sample and cycled at different temperatures. FIGS. 12A, 12B show the battery performance at 90° C. under different current rates. The battery can deliver successful cycling even when the current rate reaches up to 10 C, and the discharge capacity reaches about 157, 152, 139, 129, 108 and 59 mAh g.sup.−1 under the current rates of 0.2 C, 0.5 C, 1 C, 2 C, 5 C, and 10 C, respectively, with stable cycling for each current rate. The discharge voltage plateau located at 3.4, 3.4, 3.38, 3.37, 3.3, and 3.18 V vs. Li/Li′, exhibiting typical characteristics of Li/LiFePO.sub.4 battery..sup.32, 53, 54 When cycled under a 1 C rate, the battery delivers stable discharge capacity with a capacity retention of 86.4% after 200 cycles (FIG. 12C), and the average Coulombic efficiency (CE) is 99.5%, revealing remarkable stability of the battery system. The discharge capacities for the battery at 50° C. are 138, 119, and 108 mAh g.sup.−1 under 0.2 C, 0.5 C, and 1 C (FIG. 13), and remain stable in the continuous cycling. Moreover, the ultra-thin ConSPE membrane enables successful cycling at a low temperature of 25° C., with a discharge capacity of about 120 mAh g.sup.−1 at 0.1 C rate, and capacity retention of 92.2% after 140 cycles. SEM images of lithium anode surface after cycling at 90° C. (FIG. 12E-12G) show a compact nodular morphology without the presence of lithium dendrites, confirming the excellent lithium dendrite resistance of ConSPEs. Compared with previously reported SPEs,.sup.18, 30, 46, 55-57 the ConSPE developed in this work delivers comparable or better performance at 90° C., and the discharge capacity for the ConSPE at 50° C. is even higher than the reported data obtained at 60° C.

[0087] Owing to the excellent anodic stability of 5.3 V vs. Li/Li′, the PGMA-PEG ConSPE can also achieve stable cycling for LMBs using high-voltage LiNi.sub.0.6Mn.sub.0.2Co.sub.0.2O.sub.2 cathode.sup.58-60 (FIGS. 12H-12I. The Li/LiNi.sub.0.6Mn.sub.0.2Co.sub.0.2O.sub.2 battery with the 4PGMA-PEG6k ConSPE exhibits an initial discharge capacity of about 160 mAh g.sup.−1 at 90° C. under the current density of 20 mA g.sup.−1, with a capacity retention close to 80% after 50 cycles, showing that the prepared PGMA-PEG ConSPEs have great potential for high-energy-density LMBs.

[0088] A series of solid polymer electrolytes were prepared using comb-chain PGMA as the crosslinker. The novel nanoscale network structure dramatically improves the network mechanical properties, which is demonstrated to be critical to lithium dendrite resistance. The ConSPEs show an impressively high ionic conductivity of 1.31×10.sup.−4 S cm.sup.−1 at 40° C. with excellent thermal stability and anodic stability. Li/LiFePO.sub.4 batteries with the ConSPE deliver high discharge capacity and good cycling performance up to 10 C rate. The battery also allows stable cycling at 25° C. In addition, stable cycling could be achieved for Li/LiNi.sub.0.6Mn.sub.0.2Co.sub.0.2O.sub.2 batteries with the ConSPE, exhibiting the great potential for the ConSPE in high-energy-density LMBs. These remarkable results reveal that the newly developed PGMA-PEG ConSPE is a promising electrolyte system for high-performance and dendrite-free LMBs.

Examples

Materials

[0089] Poly(glycidyl methacrylate) (PGMA, =15k), poly(ethylene glycol) diamine (M.sub.n=2000 or 6000, PEG2k/PEG6k), lithium bis(trifluoromethane)sulfonimide (LiTFSI) and tetrahydrofuran (THF) were purchase from Aldrich. Lithium foil was purchased from Alfa Aesar. LiFePO.sub.4 and super P conductive carbon black were obtained from MTI. LiNi.sub.0.6Mn.sub.0.2Co.sub.0.2O.sub.2 was synthesized using a coprecipitation and calcination method..sup.1 All materials were used as received.

Preparation of PGMA-PEG ConSPEs

[0090] PGMA, PEG (2k or 6k) and LiTFSI (EO/Li=16) were dissolved in THF with different GMA/PEG molar ratio as shown in Table 1. The solution was then cast on a glass slide. After most of the solvent was slowly evaporated, the glass slide with the membrane was heated under vacuum at 90° C. for 24 h and 120° C. for over 8 h to ensure the complete reaction. The obtained membrane was transferred into the glove box for further test.

Characterization

[0091] A Thermo Scientific Nicolet iS50 Fourier transform infrared spectroscopy (FTIR) spectrometer was used to collect FTIR spectra. Differential scanning calorimetry (DSC, TA 2000) was performed between −90 and 150° C. under the nitrogen atmosphere with a 10° C. min.sup.−1 heating/cooling rate. Thermal gravimetric analysis (TGA, Perkin Elmer TGA 7) was performed with a 20° C. min.sup.−1 heating rate under the nitrogen atmosphere. Tensile tests were performed with a 10 mm min.sup.−1 rate, and at least three samples were tested for each ConSPE at one temperature. A Princeton Applied Research Parstat 2273 Potentiostat was employed to test the ionic conductivity using AC impedance spectroscopy with the ConSPEs sandwiched between two stainless steels. Linear sweep voltammetry (LSV) was employed at 90° C. using a 1 mV s.sup.−1 rate with a stainless steel as the working electrode and a lithium foil as the reference electrode.

[0092] For the preparation of LiFePO.sub.4 and LiNi.sub.0.6Mn.sub.0.2Co.sub.0.2O.sub.2 cathodes, the mixture of active material, super P and 4PGMA-PEG6k precursor in THF/H.sub.2O with the weight ratio of 60/8/32 was cast on stainless steel, and cured under vacuum at 120° C. The active material loading is 2-3 mg cm.sup.−2. Li/LiFePO.sub.4 and Li/LiNi.sub.0.6Mn.sub.0.2Co.sub.0.2O.sub.2 batteries were assembled by placing the cathode, the ConSPE membrane and a lithium foil in sequence. The theoretical capacity of 170 mAh g.sup.−1 was used to calculate the current rate for Li/LiFePO.sub.4 batteries. The Li/LiNi.sub.0.6Mn.sub.0.2Co.sub.0.2O.sub.2 batteries were pre-cycled under the current density of 10 mA g.sup.−1 for two cycles before cycling under 20 mA g.sup.−1 between 4.2 V and 2.6 V.

[0093] As shown in the FTIR spectra, bands at 947, 1350 and 2874 cm.sup.−1 belong to CH2 on PGMA and PEG chains. The band at around 1090 cm.sup.−1 corresponds to the C—O—C stretching of PEG chains. The band at 1731 cm.sup.−1 belongs to the C═O stretching vibration of PGMA. The bands of the TFSI anion are located at 652, 740, 789, 1054, 1184, 1228 and 1333 cm.sup.−1. The broad band at 3200-3700 cm.sup.−1 belongs to the N—H and O—H stretching vibration. For all the ConSPE samples, the absence of characteristic peak for the epoxy group at 910 cm.sup.−1 indicates that most of the epoxy groups have reacted.

[0094] The temperature-dependent ionic conductivities for ConSPEs are fitted by Vogel-Tammann-Fulcher (VTF) equation σ=A*T.sup.1/2*exp(−B/(T−T.sub.0)), shown in FIG. 6. The parameters A, B, T.sub.0, and activation energy E.sub.a are listed in Table 2. For 2PGMA-PEG6k and 4PGMA-PEG6k, since the ConSPEs melted at about 30° C., the VTF fitting was conducted between 40° C. and 100° C.

TABLE-US-00002 TABLE 2 VTF fitting parameters of the ConSPE samples. ConSPE A (S cm.sup.−1 K.sup.1/2) B (K) T.sub.0 (K) E.sub.a (kJ mol.sup.−1) 2PGMA-PEG2k 6.52 988.6 198.2 8.2 4PGMA-PEG2k 13.10 1574.5 169.6 13.1 2PGMA-PEG6k 0.64 399.6 243.1 3.3 4PGMA-PEG6k 1.79 638.9 222.0 5.3

TABLE-US-00003 TABLE 3 Mechanical properties of PGMA-PEG ConSPEs. Young's Tensile modulus/ strength/ Elongation Toughness/ ConSPE MPa MPa at break/% MJ m.sup.−3 25° C. 2PGMA-PEG2k 2.2 1.0 65 0.39 4PGMA-PEG2k 12.6 4.3 54 1.33 2PGMA-PEG6k 1.6 0.8 95 0.50 4PGMA-PEG6k 3.4 3.5 238 4.60 POSS-4PEG2k 2.3 0.5 25 0.07 90° C. 2PGMA-PEG2k 1.9 0.7 60 0.26 4PGMA-PEG2k 11.6 3.2 37 0.82 2PGMA-PEG6k 0.5 0.1 28 0.03 4PGMA-PEG6k 2.0 1.3 129 1.08 POSS-4PEG2k 2.2 0.4 21 0.05

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