MAGNESIUM-LITHIUM-ALUMINUM-ZINC ALLOY SUITABLE FOR BEING PROCESSED THROUGH AIR MELT AND STRUCTURAL ARTICLE

Abstract

A Mg—Li—Al—Zn alloy is disclosed. The Mg—Li—Al—Zn alloy comprises, in weight percent: 5-15% Li, 1.5-9.0% Al, 0.5-1.5% Zn, 0.4-1.3% Y, 0.18-1.01% Nd, 0.09-0.65% Ce, and the balance Mg and incidental impurities. Experimental data have proved that, this novel Mg—Li—Al—Zn alloy has a flashover temperature in a range between 620° C. and 700° C., such that the flashover temperature of the specifically-designed Mg—Li—Al—Zn alloy is greater than that of commercial LAZ521, LAZ721, LAZ771, LAZ921, and LAZ1491 alloys. Therefore, the Mg—Li—Al—Zn alloy of the present invention can be processed to be a structural article through air melt and casting process.

Claims

1. A magnesium-lithium-aluminum-zinc alloy, having a melting temperature and a flashover temperature greater than the melting temperature, and comprising, in weight percent: 5-15% Li; 1.5-9.0% Al; 0.5-1.5% Zn; 0.4-1.3% Y; 0.18-1.01% Nd; 0.09-0.65% Ce; and the balance Mg and incidental impurities.

2. The magnesium-lithium-aluminum-zinc alloy of claim 1, wherein the flashover temperature is in a range between 620° C. and 700° C.

3. The magnesium-lithium-aluminum-zinc alloy of claim 1, wherein after being cold rolled to have a thickness reduction of 54%, the magnesium-lithium-aluminum-zinc alloy having a yield strength in a range between 201 MPa and 240 MPa.

4. The magnesium-lithium-aluminum-zinc alloy of claim 1, wherein after being cold rolled to have a thickness reduction of 54%, the magnesium-lithium-aluminum-zinc alloy having a percentage elongation in a range between 20% and 25%.

5. The magnesium-lithium-aluminum-zinc alloy of claim 1, being produced by using a manufacturing method selected from a group consisting of: vacuum arc melting process, electric resistance wire heating process, induction heating process, rapid solidification process, mechanical alloying method in combination with spark plasma sintering process, and powder metallurgic method.

6. The magnesium-lithium-aluminum-zinc alloy of claim 1, wherein the magnesium-lithium-aluminum-zinc alloy is an alloy bulk made by sequentially applying a melting process and a solidification process to a virgin material.

7. The magnesium-lithium-aluminum-zinc alloy of claim 1, wherein the magnesium-lithium-aluminum-zinc alloy is processed to be in an as-cast state, or being in a heat-treated state after being applied with a heat treatment that is selected from a group consisting of precipitation hardening treatment, annealing treatment and homogenization treatment.

8. An article, being made of a magnesium-lithium-aluminum-zinc alloy having a melting temperature and a flashover temperature greater than the melting temperature; wherein the magnesium-lithium-aluminum-zinc alloy comprises, in weight percent: 5-15% Li; 1.5-9.0% Al; 0.5-1.5% Zn; 0.4-1.3% Y; 0.18-1.01% Nd; 0.09-0.65% Ce; and the balance Mg and incidental impurities.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0023] The invention as well as a preferred mode of use and advantages thereof will be best understood by referring to the following detailed description of an illustrative embodiment in conjunction with the accompanying drawings, wherein:

[0024] FIG. 1 shows a real image of a sample E in an experimental group;

[0025] FIG. 2 shows a real image of a sample F in the experimental group;

[0026] FIG. 3 shows a bar chart for presenting percentage elongation (% EL) of a sample G in the experimental group and a sample D in a control group; and

[0027] FIG. 4 shows a bar chart for presenting yield strength (YS) and % EL of the sample G in the experimental group.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0028] To more clearly describe a magnesium-lithium-aluminum-zinc alloy suitable for being processed through air melt according to the present invention, embodiments of the present invention will be described in detail with reference to the attached drawings hereinafter.

[0029] The present invention discloses a magnesium-lithium-aluminum-zinc alloy (abbreviated to Mg—Li—Al—Zn alloy), comprising, in weight percent: 5-15% Li, 1.5-9.0% Al, 0.5-1.5% Zn, 0.4-1.3% Y, 0.18-1.01% Nd, 0.09-0.65% Ce, and the balance Mg and incidental impurities. Particularly, this Mg—Li—Al—Zn alloy has a melting temperature and a flashover temperature that is greater than the melting temperature. Therefore, a metal-made structural article can be produced by sequentially applying an air melt process and a casting process to the Mg—Li—Al—Zn alloy.

[0030] When conducting the manufacture of the Mg—Li—Al—Zn alloy, the Mg—Li—Al—Zn alloy can be processed to be an alloy bulk made by sequentially applying a melting process and a solidification process to a virgin material. In addition, it is allowable to produce the Mg—Li—Al—Zn alloy by using any one possible manufacturing method, for example, vacuum arc melting method, electric resistance wire heating method, induction heating process, electric induction heating method, rapidly solidification method, mechanical alloying method, and powder metallurgic method. Moreover, during the manufacture of the Mg—Li—Al—Zn alloy, it is also allowable to process the Mg—Li—Al—Zn alloy to be in an as-cast state, or to make the Mg—Li—Al—Zn alloy be in a heat-treated state by utilizing a heat treatment, such as precipitation hardening treatment, annealing treatment, and homogenization treatment.

[0031] In general, method for making a metal-made structural article comprises the steps of: (1) disposing a metal material in a crucible, and then melting the metal material by using air melt; and (2) after scooping-up the slag from the crucible, filling the melted metal material into a casting mold, thereby processing the melted metal material to be a structural article. However, it is a pity that the commercial LAZ521, LAZ721, LAZ771, LAZ921, and LAZ1491 alloys all cannot be processed to be a structural article by using above-mentioned method due to having a flashover temperature lower than the melting temperature thereof. It is worth noting that, the Mg—Li—Al—Zn alloy of the present invention has a flashover temperature in a range between 620° C. and 700° C., such that the flashover temperature of the Mg—Li—Al—Zn alloy of the present invention is greater than that of commercial LAZ521, LAZ721, LAZ771, LAZ921, and LAZ1491 alloys. As a result, the Mg—Li—Al—Zn alloy of the present invention can be processed to be a structural article like bicycle wheel rim and computer housing case by using above-mentioned method.

[0032] Inventors of the present invention have completed experiments in order to prove that the Mg—Li—Al—Zn alloy can indeed be made.

First Experiment

[0033] In the first experiment, two samples of alloys are fabricated by vacuum arc melting process. The following table (1) lists each sample's elemental composition.

TABLE-US-00001 TABLE 1 LAZ521 + 0.78Y + LAZ521 0.65 Nd + 0.41Ce Sample A — in control group Sample — A in experimental group

[0034] According to table (1), it is known that sample A in control group is a commercial LAZ521 alloy. Engineers skilled in development and manufacture of LAZ alloys certainly know that, the LAZ521 alloy contains, in weight percent: 5% Li, 2% Al, 1% Zn, and the balance Mg and incidental impurities (e.g., Mn). On the other hand, the sample A in experimental group is made by utilizing a vacuum arc melting furnace to process a commercial LAZ521 alloy, 0.78 wt % yttrium with form of powder or piece, 0.65 wt % neodymium with form of powder or piece, and 0.41 wt % cerium with form of powder or piece to be a Mg—Li—Al—Zn alloy.

Second Experiment

[0035] In the second experiment, two samples of alloys are fabricated by vacuum arc melting process. The following table (2) lists each sample's elemental composition.

TABLE-US-00002 TABLE 2 LAZ721 + 0.34Y + LAZ721 0.41 Nd + 0.28Ce Sample B — in control group Sample — B in experimental group

[0036] According to table (2), it is known that sample B in control group is a commercial LAZ721 alloy. Engineers skilled in development and manufacture of LAZ alloys certainly know that, the LAZ721 alloy contains, in weight percent: 7% Li, 2% Al, 1% Zn, and the balance Mg and incidental impurities (e.g., Mn). On the other hand, the sample B in experimental group is made by utilizing a vacuum arc melting furnace to process a commercial LAZ721 alloy, 0.34 wt % yttrium with form of powder or piece, 0.41 wt % neodymium with form of powder or piece, and 0.28 wt % cerium with form of powder or piece to be a Mg—Li—Al—Zn alloy.

Third Experiment

[0037] In the third experiment, two samples of alloys are fabricated by vacuum arc melting process. The following table (3) lists each sample's elemental composition.

TABLE-US-00003 TABLE 3 LAZ771 + 0.92Y + LAZ771 0.46 Nd + 0.28Ce Sample C — in control group Sample — C in experimental group

[0038] According to table (3), it is known that sample C in control group is a commercial LAZ771 alloy. Engineers skilled in development and manufacture of LAZ alloys certainly know that, the LAZ771 alloy contains, in weight percent: 7% Li, 7% Al, 1% Zn, and the balance Mg and incidental impurities (e.g., Mn). On the other hand, the sample C in experimental group is made by utilizing a vacuum arc melting furnace to process a commercial LAZ771 alloy, 0.92 wt % yttrium with form of powder or piece, 0.46 wt % neodymium with form of powder or piece, and 0.28 wt % cerium with form of powder or piece to be a Mg—Li—Al—Zn alloy.

Fourth Experiment

[0039] In the fourth experiment, three samples of alloys are fabricated by vacuum arc melting process. The following table (4) lists each sample's elemental composition.

TABLE-US-00004 TABLE 4 LAZ921 + LAZ921 + 0.63Y + 0.57Y + 0.51 Nd + 0.14 Nd + LAZ921 0.25Ce 0.08Ce Sample D — — in control group Sample — D E in experimental group

[0040] According to table (4), it is known that sample D in control group is a commercial LAZ921 alloy. Engineers skilled in development and manufacture of LAZ alloys certainly know that, the LAZ921 alloy contains, in weight percent: 9% Li, 2% Al, 1% Zn, and the balance Mg and incidental impurities (e.g., Mn). On the other hand, the sample D in experimental group is made by utilizing a vacuum arc melting furnace to process a commercial LAZ921 alloy, 0.63 wt % yttrium with form of powder or piece, 0.51 wt % neodymium with form of powder or piece, and 0.25 wt % cerium with form of powder or piece to be a Mg—Li—Al—Zn alloy. Moreover, the sample E in experimental group is made by utilizing the vacuum arc melting furnace to process a commercial LAZ921 alloy, 0.57 wt % yttrium with form of powder or piece, 0.14 wt % neodymium with form of powder or piece, and 0.08 wt % cerium with form of powder or piece to be a Mg—Li—Al—Zn alloy.

Fifth Experiment

[0041] In the fifth experiment, two samples of alloys are fabricated by vacuum arc melting process. The following table (5) lists each sample's elemental composition.

TABLE-US-00005 TABLE 5 LAZ1491 + 1.2Y + LAZ1491 0.8 Nd + 0.6Ce Sample E — in control group Sample — F in experimental group

[0042] According to table (5), it is known that sample E in control group is a commercial LAZ1491 alloy. Engineers skilled in development and manufacture of LAZ alloys certainly know that, the LAZ1491 alloy contains, in weight percent: 14% Li, 9% Al, 1% Zn, and the balance Mg and incidental impurities (e.g., Mn). On the other hand, the sample F in experimental group is made by utilizing a vacuum arc melting furnace to process a commercial LAZ1491 alloy, 1.2 wt % yttrium with form of powder or piece, 0.8 wt % neodymium with form of powder or piece, and 0.6 wt % cerium with form of powder or piece to be a Mg—Li—Al—Zn alloy.

[0043] Testing data of the samples in control group and the samples in experimental group are integrated in following table (6A), table (6B), table (7A), and table (7B).

TABLE-US-00006 TABLE 6A Sample A Sample B Sample C in control in control in control group group group (LAZ521) (LAZ721) (LAZ771) Flashover 580.1 550.3 513.9 temperature 574.5 569.3 522.1 (° C.) 585.4 570.1 531.6 Melting 603.4 590.4 592.1 temperature (° C.)

TABLE-US-00007 TABLE 6B Sample D Sample E in control in control group group (LAZ921) (LAZ1491) Flashover 587.5 489.6 temperature 570.3 461.2 (° C.) 571.1 483.8 Melting 580.4 550.5 temperature (° C.)

TABLE-US-00008 TABLE 7A Sample A in Sample B in Sample C in experimental experimental experimental group group group Flashover 636.5 669.5 612.8 temperature 622.7 642.7 653.2 (° C.) 621.5 644.5 607.4 Melting 604.4 590.4 595.6 temperature (° C.)

TABLE-US-00009 TABLE 7B Sample D in Sample E in Sample F in experimental experimental experimental group group group Flashover 704.9 664.2 607.3 temperature 626.0 641.1 632.1 (° C.) 651.1 636.8 630.1 Melting 581 582.4 550.5 temperature (° C.)

[0044] On the other hand, FIG. 1 shows a real image of the sample E in experimental group, and FIG. 2 shows a real image of the sample F in experimental group. It is worth explaining that, T1, T2 and T3 labeled in the real image of FIG. 1 and the real image of

[0045] FIG. 2 are sampling positions. When collecting the testing data of the sample E, three test materials are token out from the sampling positions T1, T2 and T3, respectively, and then a flashover temperature measurement, a melting temperature measurement and a composition analysis of the three test materials are completed. Likewise, when collecting the testing data of the sample F, three test materials are token out from the sampling positions T1, T2 and T3, respectively, and then a flashover temperature measurement, a melting temperature measurement and a composition analysis of the three test materials are completed. As a result, the testing data of the sample E in experimental group is summarized in following table (8), and the testing data of the sample F in experimental group is summarized in following table (9).

TABLE-US-00010 TABLE 8 sampling Li Al Zn Y Nd Ce position (w t%) (wt %) (wt %) (wt %) (wt %) (wt %) T1 9.255 1.755 0.957 0.771 0.549 0.379 T3 9.311 1.547 1.030 0.425 0.354 0.261

TABLE-US-00011 TABLE 9 sampling Li Al Zn Y Nd Ce position (wt %) (wt %) (wt %) (wt %) (wt %) (wt %) T1 14.9454 7.8382 0.6834 1.7853 1.2268 0.8044 T3 15.7985 7.4111 0.6967 0.6074 0.4779 0.3569

Sixth Experiment

[0046] Inventors of the present invention further completes a sixth experiment. In the sixth experiment, three samples of alloys are fabricated by vacuum arc melting process. The following table (10) lists each sample's elemental composition.

TABLE-US-00012 TABLE 10 LAZ921 + LAZ921 + LAZ921 + 0.35Y + 0.57Y + 0.58Y + 0.36 Nd + 0.14 Nd + 0.49 Nd + 0.25Ce 0.08Ce 0.32Ce Sample in G H I experimental group

[0047] Engineers skilled in development and manufacture of LAZ alloys certainly know that, the commercial LAZ921 alloy contains, in weight percent: 9% Li, 2% Al, 1% Zn, and the balance Mg and incidental impurities (e.g., Mn). On the other hand, the sample G in experimental group is made by utilizing a vacuum arc melting furnace to process a commercial LAZ921 alloy, 0.35 wt % yttrium with form of powder or piece, 0.36 wt % neodymium with form of powder or piece, and 0.25 wt % cerium with form of powder or piece to be a Mg—Li—Al—Zn alloy. Moreover, the sample H in experimental group is made by utilizing a vacuum arc melting furnace to process a commercial LAZ921 alloy, 0.57 wt % yttrium with form of powder or piece, 0.14 wt % neodymium with form of powder or piece, and 0.08 wt % cerium with form of powder or piece to be a Mg—Li—Al—Zn alloy. In addition, the sample I in experimental group is made by utilizing a vacuum arc melting furnace to process a commercial LAZ921 alloy, 0.58 wt % yttrium with form of powder or piece, 0.49 wt % neodymium with form of powder or piece, and 0.32 wt % cerium with form of powder or piece to be a Mg—Li—Al—Zn alloy. Testing data of the foregoing three samples are integrated in following table (11).

TABLE-US-00013 TABLE 11 Sample G in Sample H in Sample 1 in experimental experimental experimental group group group Flashover 630.5 643.0 645.8 temperature 625.5 633.0 622.0 (° C.) 628.5 632.3 635.9 Melting 581.5 584.5 582.3 temperature (° C.)

[0048] Furthermore, inventors of the present invention also complete a mechanical property measurement of the sample G in the experimental group and the sample D in the control group. FIG. 3 shows a bar chart for presenting percentage elongation (% EL) of the sample G in the experimental group and the sample D in a control group. According to FIG. 3, it is found that the sample D processed to be in an as-cast state exhibits 24.6% EL. However, after being cold rolled to have a thickness reduction of 51%, the sample D has the lower percentage elongation (from 24.6% EL rolling down to 11.9% EL). On the other hand, the sample G (i.e., the Mg—Li—Al—Zn alloy of the present invention) processed to be in an as-cast state exhibits 31.0% EL, and has a slightly lower percentage elongation (from 31.0% EL rolling down to 23.7% EL) after being cold rolled to have a thickness reduction of 51%. Therefore, testing data of FIG. 3 have proved that, the Mg—Li—Al—Zn alloy of the present invention is superior to the commercial LAZ alloy in resistance against cold work hardening.

[0049] In addition, inventors of the present invention also complete a yield strength (YS) measurement of the sample G in the experimental group. FIG. 4 shows a bar chart for presenting yield strength (YS) and % EL of the sample G in the experimental group. According to testing data of FIG. 2, it is understood that, after being cold rolled to have a thickness reduction of 54%, the Mg—Li—Al—Zn alloy has a yield strength in a range between 201 MPa and 240 MPa. Therefore, testing data of FIG. 4 have proved that, the Mg—Li—Al—Zn alloy of the present invention is superior to the commercial LAZ alloy in yield strength.

[0050] Therefore, above descriptions have introduced the Mg—Li—Al—Zn alloy suitable for being processed through air melt according to the present invention completely and clearly. Moreover, the above description is made on embodiments of the present invention. However, the embodiments are not intended to limit the scope of the present invention, and all equivalent implementations or alterations within the spirit of the present invention still fall within the scope of the present invention.