WATER BASED SEMI-SYNTHETIC METALWORKING FLUID COMPOSITION

Abstract

The present invention describes a water based semi-synthetic metal working fluid comprising a base oil, an organic acid, emulsifiers, optionally a concentrate additive, water and a microbial growth control agent which comprises a glycol ether amine.

Claims

1. A semi-synthetic metal working fluid, comprising: a. at least one base oil; b. at least one microbial growth control agent comprising a glycol ether amine with the structure of: ##STR00002##  wherein R.sup.1 is a C1-C6 alkyl group and R.sup.2 is CH.sub.3 or CH.sub.2—CH.sub.3 and R.sup.3 is CH.sub.3 or CH.sub.2—CH.sub.3, and m is 0 to 6; c. one or more organic acids, d. one or more emulsifiers, e. optionally, one or more additives, and f. water.

2. The semi-synthetic metal working fluid of claim 1, wherein R.sup.1 of the microbial growth control agent is a C.sub.3-C.sub.4 alkyl group.

3. The semi-synthetic metal working fluid of claim 1, wherein the glycol ether amine is selected from the group consisting of 2-butoxy-ethanamine, 1-methoxy-2-propanamine, 1-butoxy-2-propanamine, 1-[1-methyl-2-(1-methyl-2-propoxyethoxy)ethoxy]-2-propanamine1-(2-butoxy-1-methylethoxy)-2-propanamine, 1-(2-methoxy-1-methylethoxy)-2-propanamine or 1-(1-methyl-2-propoxyethoxy)-2-propanamine.

4. The semi-synthetic metal working fluid of claim 1, wherein the microbial growth control agent further comprises another amine.

5. The semi-synthetic metal working fluid of claim 1, wherein m is from 0 to 2 in the microbial growth control agent.

6. The semi-synthetic metal working fluid of claim 1, wherein the base oil is selected from naphthenic oils, paraffinic oils, ester oils and mixtures thereof.

7. The semi-synthetic metal working fluid of claim 1, wherein the emulsifier is selected from C.sub.16-C.sub.18 alcohols which have been ethoxylated or propoxylated, ethoxylated C.sub.12-C.sub.15 alcohols, sodium alkane sulfonate and alky ether carboxylates and mixtures thereof.

8. The semi-synthetic metal working fluid of claim 1, wherein the solubilizer is selected from ethylhexoic acid, azelaic acid, toll oil fatty acid, 12-hydoxyl-(cis)-9-octadecenoic acid, dicarboxylic acid, 9-octadecenoic acid and mixtures thereof.

9. The semi-synthetic metal working fluid of claim 1, wherein the additive is present and is selected from diethylene glycol butyl ether, ethylene glycol monobutyl ether, propylene glycol butyl ether and mixtures thereof.

10. The semi-synthetic metal working fluid of claim 1, wherein the microbial growth control agent is present in an amount of from 6 to 15 percent by weight of the semi-synthetic metal working fluid.

11. The semi-synthetic metal working fluid of claim 1, wherein the base oil is present in an amount of from 10 to 45 percent by weight of the semi-synthetic metal working fluid.

12. The semi-synthetic metal working fluid of claim 1, wherein the emulsifier is present in an amount of from 5 to 20 percent by weight of the semi-synthetic metal working fluid.

13. The semi-synthetic metal working fluid of claim 1, wherein the solubilizer is present in an amount of from 3 to 10 percent by weight of the semi-synthetic metal working fluid.

14. The semi-synthetic metal working fluid of claim 1, wherein the water is present in an amount of from 20 to 60 percent by weight of the semi-synthetic metal working fluid.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0009] FIG. 1 is a bar graph showing the foaming heights and the defoaming times for Comparative Example 1 and examples 1-6 of the present invention.

DETAILED DESCRIPTION

[0010] The present invention relates to semi-synthetic metal working fluids. These MWFs comprise water, one or more base oils, one or more solubilizers, one or more emulsifiers, optionally one or more additives and one or more microbial growth control agents, where the microbial growth control agent comprises at least a glycol ether amine.

[0011] The water used in the present formulations is preferably deionized water, and may comprise from at least 20, preferably 25, 30, or even 35 percent by weight of the formulation up to a maximum of 65, 60, 55 or even 50 percent by weight of the formulation. It is contemplated that these formulations may be further diluted with additional water prior to use, altering these ranges accordingly. For example, prior to use, the formulations may be diluted such that the base oil concentration is from 1 to 20 percent by weight of the diluted formulation, more typically 5 to 7 percent by weight.

[0012] The semi-synthetic MWFs of the present invention also include a base oil. The base oil can be any base oil generally known in the art for use in MWFs. Preferably the base oil is a base oil selected from naphthenic oils, paraffinic oils or ester oils, or combinations thereof. The concentration of the base oil(s) in the MWF may range from 5, 7, 10, or 15 percent by weight of the formulation up to 50, 45, 40, or 35 percent of the formulation.

[0013] The semi-synthetic MWFs of the present invention also include a microbial growth control agent and/or biocide, which may be described, in one embodiment, as a glycol ether amine. Suitable glycol ether amines include, but are not limited to: 2-butoxy-ethanamine, 1-methoxy-2-propanamine, 1-butoxy-2-propanamine, 1-[1-methyl-2-(1-methyl-2-propoxyethoxy)ethoxy]-2-propanamine1-(2-butoxy-1-methylethoxy)-2-propanamine, 1-(2-methoxy-1-methylethoxy)-2-propanamine and 1-(1-methyl-2-propoxyethoxy)-2-propanamine, and 2-amino-2-methyl-2-propanol. It was surpassingly found that such glycol ether amines are good biocides against bacteria and other microbes present in MWFs.

[0014] In another embodiment, the presently disclosed biocidal composition may be a composition comprising at least a glycol ether amine, wherein the primary ether amine compound is of the formula below:

##STR00001##

[0015] Wherein R1 is a C1-C6 alkyl group, more preferably C3-C4 alkyl group, and R2 and R3 are independently CH3 or CH2-CH3, and, m is 0 to 6, or, preferably, from 0 to 2.

[0016] The concentration of the glycol ether amine(s) in the MWF may range from 1, 4, 6, 8, or 10 percent by weight of the formulation up to 30, 25, 15, or 12 percent of the formulation.

[0017] The microbial growth control agent may further comprise one or more additional glycol ether amines which may be used in combination with the above disclosed materials to achieve a certain microbial growth control targets.

[0018] The semi-synthetic MWFs of the present invention also include one or more organic acids as solubilizers. Preferred organic acids include 2-ethylhexoic acid, azelaic acid, toll oil fatty acid, 12-hydoxyl-(cis)-9-octadecenoic acid, dicarboxylic acid, and 9-octadecenoic acid. The concentration of the organic acid in the MWF may range from 2, 3, 4, or 5 percent by weight of the formulation up to 12, 10, 8, or 7 percent of the formulation.

[0019] The semi-synthetic MWFs of the present invention also include one or more emulsifiers. The emulsifier may be anionic, cationic or nonionic. Examples of suitable anionic surfactants or emulsifiers are alkali metal, ammonium and amine soaps; the fatty acid part of such soaps contains preferably at least 10 carbon atoms. The soaps can also be formed “in situ;” in other words, a fatty acid can be added to the oil phase and an alkaline material to the aqueous phase.

[0020] Other examples of suitable anionic surfactants or emulsifiers are alkali metal salts of alkyl-aryl sulfonic acids, sodium dialkyl sulfosuccinate, sulfated or sulfonated oils, e.g., sulfated castor oil; sulfonated tallow, and alkali salts of short chain petroleum sulfonic acids.

[0021] Suitable cationic surfactants or emulsifiers are salts of long chain primary, secondary or tertiary amines, such as oleylamide acetate, cetylamine acetate, di-dodecylamine lactate, the acetate of aminoethyl-aminoethyl stearamide, dilauroyl triethylene tetramine diacetate, 1-aminoethyl-2-heptadecenyl imidazoline acetate; and quaternary salts, such as cetylpyridinium bromide, hexadecyl ethyl morpholinium chloride, and diethyl di-dodecyl ammonium chloride.

[0022] Examples of suitable nonionic surfactants or emulsifiers are condensation products of higher fatty alcohols with ethylene oxide, such as the reaction product of oleyl alcohol with 10 ethylene oxide units; condensation products of alkylphenols with ethylene oxide, such as the reaction product of isoctylphenol with 12 ethylene oxide units; condensation products of higher fatty acid amides with 5, or more, ethylene oxide units; polyethylene glycol esters of long chain fatty acids, such as tetraethylene glycol monopalmitate, hexaethyleneglycol monolaurate, nonaethyleneglycol monostearate, nonaethyleneglycol dioleate, tridecaethyleneglycol monoarachidate, tricosaethyleneglycol monobehenate, tricosaethyleneglycol dibehenate, polyhydric alcohol partial higher fatty acid esters such as sorbitan tristearate, ethylene oxide condensation products of polyhydric alcohol partial higher fatty acid esters, and their inner anhydrides (mannitol-anhydride, called Mannitan, and sorbitol-anhydride, called Sorbitan), such as glycerol monopalmitate reacted with 10 molecules of ethylene oxide, pentaerythritol monooleate reacted with 12 molecules of ethylene oxide, sorbitan monostearate reacted with 10-15 molecules of ethylene oxide, mannitan monopalmitate reacted with 10-15 molecules of ethylene oxide; long chain polyglycols in which one hydroxyl group is esterified with a higher fatty acid and other hydroxyl group is etherified with a low molecular alcohol, such as methoxypolyethylene glycol 550 monostearate (550 meaning the average molecular weight of the polyglycol ether). A combination of two or more of these surfactants may be used; e.g., a cationic may be blended with a nonionic or an anionic with a nonionic.

[0023] Suitable emulsifiers include C16-18 alcohols which have been ethoxylated or propoxylated; ethoxylated C12-C15 alcohols; sodium alkane sulfonate and alky ether carboxylates.

[0024] The concentration of the emulsifier(s) in the MWF may range from 4, 5, 6, 8, or 10 percent by weight of the formulation up to 25, 20, 15, or 12 percent of the formulation.

[0025] The semi-synthetic MWFs of the present invention may also include one or more additives. Preferred additives include diethylene glycol butyl ether, ethylene glycol monobutyl ether, and propylene glycol butyl ether. The concentration of the additive(s) in the MWF may range from 0.0, 0.3, 0.5, 1.0, or 1.5 percent by weight of the formulation up to 2.5, 2.0, or 1.8 percent of the formulation.

[0026] The semi-synthetic MWFs of the present invention may also include other additives to provide additional functionality as generally known in the art.

Examples

[0027] An experiment to test the efficacy of the presently disclosed semi-synthetic MWFs and others may be conducted as follows. A series of 7 semi-synthetic MWFs are prepared as indicated in Table 1. Each example is identical except for a different amine as a microbial growth control agent as shown in Table 2.

TABLE-US-00001 TABLE 1 Diluted Metalworking Fluid Ingredients Ingredient details percentage Base oil Naphthenic oil 12.5 wt % Organic acid Azelaic acid 4.5 wt % Toll oil fatty acid 4.5 wt % Emulsifiers UCONTM Metalworking 8.4 wt % EMU 50 UCONTM Metalworking 2.0 wt % EMU 60 Sodium alkane sulfonate 2.5 wt % Amine See Table 2 10.7 wt % Additive Diethylene glycol butyl ether 2.0 wt % Deionized water / 52.9 wt %

TABLE-US-00002 TABLE 2 Ether Amines Tested Example Amine Product Name Comparative MEA + TEA Monoethanolamine (3.9 wt %), Example 1 Triethanolamine (6.8 wt %) Example 1 PM amine 1-methoxy-2-propanamine Example 2 PnB amine 1-butoxy-2-propanamine Example 3 EB amine 2-butoxy-ethanamine Example 4 TPnP amine 1-[1-methyl-2-(1-methyl-2- propoxyethoxy)ethoxy]-2- propanamine Example 5 DPnB amine 2-propanamine, 1-(2-butoxy-1- methylethoxy)- Example 6 DPnP amine 1-(1-methyl-2-propoxyethoxy)-2- propanamine

Test 1 Thermal Stability of Semi-Synthetic Fluid

[0028] A portion of each of the seven examples described above are stored at 500 (±3° C.) and a portion was stored at 0° C. (±1° C.) for 20 hours. Afterwards the samples are observed, and the results are shown in table 3, with “pass” indicating a single-phase clear material:

TABLE-US-00003 TABLE 3 Thermal stability performance Semi-synthetic Hot aging stability Cold aging stability fluid amine test 50° C., 20 h test 0° C., 20 h Comparative MEA + TEA Hazy Hazy Example 1 Example 1 PM amine Pass Hazy Example 2 PnB amine Pass Pass Example 3 EB amine Hazy Pass Example 4 TPnP amine Separated Pass Example 5 DPnB amine Hazy Pass Example 6 DPnp amine Pass Pass

[0029] As shown in the above Table, the inventive composition (Examples 1-6) have demonstrated better stability than the comparative example 1, because all the examples have passed the stability test at least one of the temperatures.

Test 2 Foaming Tests

[0030] 5.0 g of each of the first seven semi-synthetic fluid concentrates are added into a 250 mL cylinder containing 95 mL hard water (50 ppm, Ca(CO3)2 equivalents). After closing the cylinder with the stopper, the cylinder is inverted 60 times within 1 min. The foam volume height immediately after completing the inversions (0 sec) and time until the foam height was reduced 0 cm are recorded and presented in FIG. 1:

[0031] As shown in the above Table, the inventive compositions (Examples 1-5) have a better low foam performance than the comparative example 1 (MEA+TEA), because all the examples show lower foam height and lower defoaming time.

Test 3 Anti-Corrosion Test

[0032] To evaluate the anti-corrosion capability of semi-synthetic solutions, 5 ml of each of the hard water solutions used in test 2 are added to a 35 mm by 10 mm plastic petri dish along with 4.0 (±0.1) gm of cast icon chips and stored at 25′C for 24 h. After this period the corrosion status of the iron chips are observed, and area percentage observed to be affected is recorded in Table 4.

TABLE-US-00004 TABLE 4 Anti-Corrosion Performance Semi-synthetic Glycol Corrosion area fluid ether amine percentage (%) Comparative MEA + TEA 0 Example 1 Example 1 PM amine 0 Example 2 PnB amine 4 Example 3 EB amine 0 Example 4 TPnP amine 32 Example 5 DPnB amine 11 Example 6 DPnp amine 0

[0033] As shown in the above Table 4, the inventive composition (Examples 1, 3, 6) have an equivalent anti-corrosion capability with comparative example 1 (MEA+TEA).