Device and method for reinforcing recycled aggregate based on in-situ C-S-H production

Abstract

A device and method for reinforcing recycled aggregate based on in-situ C—S—H production including a first, second, third chamber, and a blast drier. A spray structure arranged on the top of the third chamber; the first and second chamber connected to the spray structure through pumps. A hollowed container arranged at the bottom of the spray structure. A certain gap reserved between the bottom of the container and the bottom of the third chamber, the bottom of the third chamber is provided with at least one drain outlet; the blast drier connected to the bottom of the third chamber, and a cover is arranged on the top of the third chamber. The first chamber contains calcium hydroxide solution. The second chamber contains a mixed solution of TEOS, water and anhydrous ethanol. The container is arranged in the third chamber, and the container is used to contain to-be-treated recycled aggregate.

Claims

1. A device for reinforcing a recycled aggregate based on in-situ C—S—H production, the device comprising: a first chamber, a second chamber, a third chamber, and a blast drier, wherein the first chamber, the second chamber, and the third chamber are sealed; a spray structure is arranged at a top of the third chamber, the first chamber and the second chamber are connected to the spray structure through pipes and pumps, a container with hollowed walls is arranged on a bottom of the spray structure, hollowed portions of the hollowed walls are smaller than a grain size of the recycled aggregate, a certain gap is reserved between a bottom of the container and a bottom of the third chamber, the bottom of the third chamber is provided with at least one drain outlet; and the blast drier is connected to the bottom of the third chamber, and a cover is arranged on a top of the third chamber.

2. The device according to claim 1, wherein a plurality of spray heads is arranged on the spray structure, and a spray area of the spray heads uniformly covers a cross section of the container.

3. The device according to claim 1, wherein two gas distributors are located between the blast drier and the third chamber, and the two gas distributors are symmetrically arranged on two sides of the third chamber.

4. The device according to claim 1, wherein the device for reinforcing recycled aggregate based on in-situ C—S—H production further comprises a vacuum device which connects to the third chamber.

5. The device according to claim 4, wherein two connection points are arranged between the third chamber and the vacuum device, and the two connection points are symmetrically arranged relative to the third chamber.

6. The device according to claim 1, wherein there are two drain outlets, which are respectively connected to the first chamber and the second chamber.

7. A method for reinforcing a recycled aggregate based on in-situ C—S—H production, the method comprising: 1) sieving the recycled aggregate to remove waste particles in the recycled aggregate, and removing mud and incompletely stripped mortar on a surface of the recycled aggregate; 2) loading the recycled aggregate into a container after cleaning the recycled aggregate, and placing the container in a third chamber; 3) switching on a blast drier, switching off the blast drier after the recycled aggregate in the third chamber is dried, and then switching on a vacuum device to vacuumize the third chamber; 4) conveying a mixed solution of anhydrous ethanol, water and tetraethoxysilane (TEOS) into a spray device of the third chamber; evenly spraying the mixed solution onto the recycled aggregate by the spray device; and after a first period of soaking, discharging out the mixed solution and switching on the blast drier to dry the recycled aggregate; 5) switching on the vacuum device to vacuumize the third chamber; 6) conveying a calcium hydroxide solution into the spray device on the third chamber; evenly spraying the calcium hydroxide solution onto the recycled aggregate by the spray device; and after a second period of soaking, discharging out the calcium hydroxide solution and switching on the blast drier to dry the recycled aggregate.

8. The method according to claim 7, wherein, in step 4), a molar ratio of anhydrous ethanol to water to TEOS is 3.5-4.5:1:2.5-3.5.

9. The method according to claim 8, wherein the second period of soaking is 10 to 20 h.

10. The method according to claim 7, wherein, in step 6), the calcium hydroxide solution is a saturated calcium hydroxide solution; and the second period of soaking is 10 to 20 h.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) The drawings of the specification which constitute part of the present application are used to provide the further understanding of the present application, and the exemplary embodiments of the present application and the description thereof are used to explain the present application, and do not constitute an improper limitation to the present application.

(2) FIG. 1 is a schematic diagram of the recycled aggregate device in the present invention;

(3) FIG. 2 is a picture of treated recycled aggregate using the present invention;

(4) FIG. 3 is a picture of the products in voids of the treated recycled aggregate;

(5) FIG. 4 is a crushing value test for the recycled aggregate;

(6) FIG. 5 is a water absorption rate graph of the recycled aggregate;

(7) FIG. 6 is a crushing value graph of the recycled aggregate; and

(8) FIG. 7 is a picture of the crushed recycled aggregate.

(9) In the drawings, 1. Vacuum device; 2. Valve A; 3. Third chamber; 4. Solution spray device; 5. Valve B; 6. Second chamber; 7. Blast drier; 8. Valve D; 9. Recycled aggregate container; 10. Valve C; and 11. First chamber.

DETAILED DESCRIPTION

(10) It should be pointed out that the following detailed description is illustrative, and is intended to provide the further description of the present application. Unless otherwise specified, all the technological and scientific terms used herein have the same meanings as generally understood by those of ordinary skill in the art covering the present application.

(11) It should be noted that the terms used herein are merely intended to describe the specific embodiments rather than limit the exemplary embodiments according to the present application. As used herein, unless otherwise explicitly specified in the context, the singular form is also intended to include the plural form, and in addition. It should also be understood that, in the present specification, the terms “include” and/or “comprise” indicate the existence of features, steps, operations, devices, components and/or their combination.

Embodiment 1

(12) The present embodiment can be used for a factory for mass-reinforcing recycled aggregate based on the in-situ C—S—H production method, see FIG. 1. The present invention can integrate a variety of functions, such as cleaning of recycled aggregate, reinforcement of recycled aggregate, drying of recycled aggregate. The treated recycled aggregate can be used directly for the concrete production and its modified strength and water absorption rate can be kept for a long time. The device for treating recycled aggregate mainly includes a first chamber 11, a second chamber 6, a third chamber 3, a vacuum device 1, a solution spray device 4, a recycled aggregate container 9, and a blast drier 7.

(13) The first chamber 11, the second chamber 6 and the third chamber 3 are connected to each other. A plurality of valves is arranged between the chambers (FIG. 1), namely valve A2, valve B5, valve D8, and valve C10. The shape and volume of each chamber are not limited, but each chamber must have good sealing performance, which can be used to store solutions. The first chamber 11 is a calcium hydroxide solution storage chamber, which is connected to the third chamber 3. The Valve A2 and valve C10 are located on the connecting pipe. Through this pipe, the calcium hydroxide solution can flow to the third chamber 3 or back to the first chamber 11 for recycling. The first chamber 11 can be used for the preparation or replacement of the calcium hydroxide solution. The second chamber 6 is a storage chamber for the mixed solution of anhydrous ethanol, water and TEOS. The second chamber 6 is connected to the third chamber 3, Valve B5 and valve D8 are designed on the connecting pipe. Through the connecting pipe, the mixed solution can flow to the third chamber 3 or back to the third chamber 3 for recycling. The second chamber 6 can be used for the preparation or replacement of the mixed solution (the mixed solution of anhydrous ethanol, water and TEOS). The third chamber 3 is the main reinforcing place for the recycled aggregate. The to-be-treated recycled aggregate is sequentially soaked in the mixed solution (the mixed solution of anhydrous ethanol, water and TEOS), the calcium hydroxide solution and dried in the third chamber 3.

(14) The vacuum device is arranged at the outside of the third chamber 3. Vacuuming orifices are symmetrically arranged on two sidewalls of the third chamber 3. The vacuum device is connected to the vacuuming orifices to vacuumize the third chamber 3. The symmetric arrangement of the vacuuming orifices can facilitate the third chamber 3 to achieve a vacuum negative pressure state to accelerate the permeation of the solution into the recycled aggregate, increasing the efficiency of reinforcing the recycled aggregate and shortening the time period for the recycled aggregate treatment.

(15) The solution spray device is located on the top of the third chamber 3 and above the recycled aggregate container. Its spraying area fully covering the recycled aggregate container. It can evenly spray the solution to the first chamber 11 and the second chamber 6 so that the aggregate can be sufficiently and completely soaked.

(16) The recycled aggregate container 9 is a cover-less cuboid with a function of containing the to-be-treated recycled aggregate. Four sides of the recycled aggregate container are designed to be hollow. The hollowed parts are smaller than the recycled aggregate. The bottom of the recycled aggregate container 9 is slightly higher than the bottom of the third chamber 3 to ensure that the redundant solution can be gathered to flow back to the first chamber 11 (or the second chamber 6) via the valve C10 (or the valve D8) after the sufficient soaking of recycled aggregate through spraying.

(17) The blast drier is arranged on the bottom of the third chamber 3, and is connected to sidewalls of the third chamber 3 through two connection points. The two connection points are symmetrically arranged on the sidewalls of the third chamber 3. The recycled aggregate in the third chamber 3 can be easily dried.

(18) The specific steps are as follows:

(19) (1) Sieving of recycled aggregate:

(20) The crushed recycled aggregates were sieved using a square hole sieve. Aggregates having grain size between 9.5 and 13.2 mm were used for the subsequent test.

(21) (2) Cleaning of aggregate:

(22) The recycled aggregate sieved in step (1) was washed by clean water to clean the mud or incompletely stripped mortar attached to the surface of the aggregate. The recycled aggregate was loaded into the recycled aggregate container 9 after the cleaning. The recycled aggregate container 9 was then put into the third chamber. All the valves were closed.

(23) (3) The blast drier 7 in the third chamber 3 was switched on to dry the recycled aggregate in the third chamber 3.

(24) (4) The blast drier 7 was switched off. The third chamber being sealed was ensured. The vacuum device 1 was switched on to render the third chamber 3 under a vacuum negative pressure state. Afterwards, the vacuum device 1 was switched off.

(25) (5) Preparation of saturated calcium hydroxide solution:

(26) An appropriate amount of clean water was added into the first chamber 11. Afterwards, calcium oxide powder was slowly added and constant stirring was performed until the solution became turbid and precipitates occurred. Then a small amount of calcium oxide was excessively added.

(27) (6) Preparation of mixed solution of anhydrous ethanol, water and TEOS:

(28) All the materials were weighed according to the proportion listed in table 1. All the materials were sequentially added into the second chamber 6 and gentle stirring was performed to mix the solution uniformly. The second chamber 6 was sealed to prevent the volatilization of ethanol.

(29) (7) The valve B5 was opened to convey the mixed solution of anhydrous ethanol, water and TEOS in the second chamber 6 to the solution spray device 4 in the third chamber 3. The mixed solution was then evenly sprayed onto the aggregate at a constant speed. After the aggregate fully absorbed the mixed solution, the redundant mixed solution flowed to the bottom of the third chamber 3. The valve D8 was opened. The gathered mixed solution was pumped back into the second chamber 6 using the pump placed between valve D8 and the second chamber 6. In this way, the mixed solution could be recycled continuously. The process of spraying the mixed solution of anhydrous ethanol, water and TEOS lasted for 12 h.

(30) Vessels must be sealed to prevent ethanol volatizing, which affects the test result significantly.

(31) (8) After the mixed solution for synthesizing nano-silica based on a sol-gel method was sprayed for the last time, the mixed solution was recovered into the second chamber 6, and the valve B5 and the valve D8 were then closed. The blast drier 7 in the third chamber 3 was switched on to dry the recycled aggregate treated in step (8).

(32) (9) The blast drier 7 was switched off. The third chamber 3 being sealed was ensured. The vacuum device 1 was switched on to render the third chamber 3 under a vacuum negative pressure state. The vacuum device 1 was switched off.

(33) (10) The valve A2 was opened to convey the calcium hydroxide solution in the first chamber 11 to the solution spray device 4 in the third chamber 3, the calcium hydroxide solution is then evenly sprayed onto the aggregate at a constant speed, and after the aggregate fully absorbed the calcium hydroxide solution, the redundant calcium hydroxide solution flowed the bottom of the third chamber 3. The valve C10 was opened. The gathered calcium hydroxide solution was pumped back into the first chamber 11 using the pump placed between the valve C10 and the first chamber 11. In this way, the calcium hydroxide solution could be recycled continuously. The process of spraying the calcium hydroxide solution lasted for 12 h.

(34) (11) After the last time calcium hydroxide solution spraying, the calcium hydroxide solution completely flowed back into the first chamber 1. The valve A2 and the valve C10 were closed. The blast drier 7 in the third chamber 3 was switched on to dry the recycled aggregate treated in step (11).

(35) (12) Test steps (7)-(11) could be repeated according to requirements.

(36) (13) The treated recycled aggregate in the third chamber 3 was collected. Their water absorption and crushing values were measured according to Chinese standard JTG E42—2005.

(37) The treated recycled aggregate is shown in FIG. 2. Products in voids of the treated recycled aggregate are shown in FIG. 3. Set-up of crushing value test is shown in FIG. 4. Water absorption rate and crushing value test results are respectively shown in FIG. 5 and FIG. 6. The crushed aggregate is shown in FIG. 7.

(38) TABLE-US-00001 TABLE 1 Mixture proportion of the mixed solution for synthesizing nano-silica based on the sol-gel method. Material name Anhydrous ethanol Distilled water TEOS Proportion 4 1 3

(39) The aforementioned pictures and test data indicate that the recycled aggregate treatment method provided by the present invention can remarkably decrease the water absorption of the recycled aggregate, increase the strength of the recycled aggregate and decrease the crushing value of the recycled aggregate. It can be seen in FIG. 4 that the water absorption rate of the recycled aggregate decreases from 17% to 10%. It decreased by 41% in comparison with the water absorption rate of untreated recycled aggregate. It can be seen from FIG. 5 that the crushing value of the recycled aggregate decreases from 41% before treatment to 33% after treatment using the method provided by the present invention. Crushing value of the recycled aggregate decreases by 20%. It can be concluded that, by using the novel recycled aggregate reinforcing method, the solutions can effectively permeate into the aggregate. The C—S—H produced by reaction can fill micro-cracks and voids in the recycled aggregate so that the compactness of the surface of the recycled aggregate is increased and the porosity of the recycled aggregate is decreased. Therefore, the objectives of decreasing the water absorption rate of the recycled aggregate and increasing the strength of the recycled aggregate are achieved.

(40) The technological progress achieved by the process and the device for reinforcing recycled aggregate based on in-situ C—S—H production using the present invention are remarkable. Through the simple and easy-to-implement process, the properties of recycled aggregate can be improved effectively with low economic investment. Consequently, the working performance, mechanical properties and durability of recycled aggregate concrete are improved, and the utilization rate of recycled aggregate is increased.

(41) The aforementioned embodiment is merely a preferred case of the present application and is not used to limit the present application. For those skilled in the art, the present application may have various changes and variations. Any modification, equivalent replacement, improvement and so on which are made within the spirit and principle of the present application shall fall within the protection scope of the present application.