CU-CONTAINING NON-WOVEN FABRIC AND METHOD FOR PREPARING THE SAME

Abstract

This application provides a Cu-containing non-woven fabric with antibacterial and antiviral properties and application thereof. The preparation method includes the following steps: web-forming, pre-wetting, and spunlace bonding a fiber in sequence to obtain the spunlace non-woven base fabric; padding and sizing the spunlace non-woven base fabric in an organic copper complex solution to obtain a Cu-containing spunlace non-woven fabric, wherein the Cu-containing spunlace non-woven fabric contains copper of ≥500 ppm; and drying and winding the Cu-containing spunlace non-woven fabric after being padded and sized. The method is simple and easy to achieve industrialization. This application also provides a Cu-containing non-woven fabric with antibacterial and antiviral properties having excellent antibacterial and antivirus properties. This application also provides an application of the Cu-containing non-woven fabric with antibacterial and antiviral properties which has an advantage of being widely used.

Claims

1. A method for preparing a Cu-containing non-woven fabric, comprising the following steps: preparing a spunlace non-woven base fabric: forming a web from a fiber, pre-wetting the web, and spunlacing the web to obtain the spunlace non-woven base fabric; padding and sizing: padding and sizing the spunlace non-woven base fabric in an organic copper complex solution to obtain a Cu-containing spunlace non-woven fabric, wherein the Cu-containing spunlace non-woven fabric contains copper of ≥500 ppm; and drying and winding the Cu-containing spunlace non-woven fabric.

2. The method for preparing the Cu-containing non-woven fabric according to claim 1, wherein the fiber comprises at least one selected from a group consisting of a natural fiber, an artificial cellulose fiber, an artificial protein fiber, a polyacrylonitrile fiber, and a polyvinyl alcohol fiber.

3. The method for preparing the Cu-containing non-woven fabric according to claim 1, wherein the fabric obtained after forming the web contains any one selected from a group consisting of ≥5% by weight of a cotton fiber, 5-65% by weight of a cellulose fiber, 5-65% by weight of a protein fiber, 5-65% by weight of a polyacrylonitrile fiber, or 100% by weight of a polyvinyl alcohol fiber having a low temperature solubility; and the organic copper complex solution is obtained by adding water to a 5.5 wt % initial organic copper complex solution by a volume of 10-30 times more than that of the 5.5 wt % initial organic copper complex solution.

4. The method for preparing the Cu-containing non-woven fabric according to claim 3, wherein the 5.5 wt % initial organic copper complex solution is prepared by the following steps: preparing a coordination ionic liquid: mixing urea, caprolactam, and acetamide thoroughly, heating, and keeping a temperature until the caprolactam and the urea are melted and liquefied thoroughly to obtain the coordination ionic liquid; and preparing the organic copper complex solution: adding a coordination solid mixture containing sodium chloride, potassium permanganate, sodium peroxide, and copper powder into the coordination ionic liquid under stirring to cause a reaction, cooling, and pouring into pure water to obtain an initial organic copper complex solution containing 5.5 wt % copper.

5. The method for preparing the Cu-containing non-woven fabric according to claim 4, wherein in the step of preparing the coordination ionic liquid, a ratio of urea:caprolactam:acetamide is in a range of 1:(0.2-0.4):(0.2-0.4) by weight, a heating temperature after mixing urea, caprolactam, and acetamide is in a range of 100−120° C., and a time period of keeping the temperature is in a range of 0.5-1 h.

6. The method for preparing the Cu-containing non-woven fabric according to claim 4, wherein, in the step of preparing the organic copper complex solution, a ratio of sodium chloride:potassium permanganate:sodium peroxide:copper powder is in a range of 1:(1-2):(1-2):(2.5-2.9) by weight, and a ratio of coordination solid mixture:coordination ionic liquid is in a range of 1:(3-3.5) by weight.

7. The method for preparing the Cu-containing non-woven fabric according to claim 1, wherein when the fiber is one or more selected from a group consisting of a polyester fiber, a polyamide fiber, a polyvinyl chloride fiber, and a polypropylene fiber, the spunlace non-woven base fabric is subjected to a step of padding in a chitosan-ascorbic acid solution before being padded and sized.

8. The method for preparing the Cu-containing non-woven fabric according to claim 7, wherein the step of padding in the chitosan-ascorbic acid solution before being padded and sized comprises padding the spunlace non-woven base fabric in the chitosan-ascorbic acid solution and drying the spunlace non-woven base fabric at a temperature of 150-170° C. for 5-10 min, in which the chitosan-ascorbic acid solution is prepared by adding 5-10 parts by weight of chitosan powder into 25-30 parts by weight of acetic acid and 60-70 parts by weight of water under magnetic stirring until the chitosan powder is dissolved, and adding 3-5 parts by weight of ascorbic acid under stirring.

9. The method for preparing the Cu-containing non-woven fabric according to claim 7, the spunlace non-woven base fabric is subjected to a step of soaping after the step of padding in the chitosan-ascorbic acid solution, comprising soaping the dried spunlace non-woven base fabric in a 5 g/L soaping agent at a soaping temperature of 35-40° C. for 5-10 min, and drying at a drying temperature of 50-60° C.

10. A Cu-containing non-woven fabric prepared by the method according to claim 1.

Description

DESCRIPTION OF THE EMBODIMENTS

[0039] This application will be further explained in detail below in combination with examples. These examples are only an explanation of this application, and do not limit the protection scope of this application. It shall be carried out according to conventional conditions or the conditions recommended by the manufacturer if conditions are not specified in the examples.

[0040] It should be noted that the spunlace technology can process various kinds of fibers, such as a cotton fiber, a nylon fiber, a polypropylene fiber, a polyester fiber, a viscose fiber and other common fibers. Therefore, the material of the spunlace non-woven fabric obtained in the step of preparing the spunlace non-woven base fabric is not limited, which can be a cellulose fiber such as the viscose fiber, a protein fiber such as a peanut protein fiber, and can also be a fiber selected from a group consisting of a polyester fiber, a polyamide fiber, a polyacrylonitrile fiber, a polyvinyl chloride fiber, a polypropylene fiber, or a polyvinyl alcohol fiber. The Cu-containing spunlace non-woven fabric contains ≥500 ppm copper by controlling the copper content contained in the organic copper complex solution, preferably, 1000-8000 ppm.

[0041] For the purpose of forming a chemical chelation between complexed copper ions in an organic copper complex solution and the fiber of the spunlace non-woven fabric, making copper ions difficult to be separated, and making the spunlace non-woven fabric have excellent and long-lasting antibacterial property, in the step of preparing the spunlace non-woven base fabric, the fiber used for web-formation includes any one of a natural fiber or the fiber obtained by wet spinning. Specifically, the fiber includes at least one selected from a group consisting of a natural fiber, an artificial cellulose fiber, an artificial protein fiber, a polyacrylonitrile fiber, and a polyvinyl alcohol fiber. All the above-mentioned fibers contain hydroxyl groups, and the fabric obtained after web-formation contains free hydroxyl groups which can chemically chelate with complexed copper ions when the spunlace non-woven base fabric is padded in the organic copper complex solution, thus the two are firmly combined with each other. The fiber used for web-formation can be the viscose fiber or the peanut protein fiber, or the mixture of the viscose fiber and the protein fiber. Preferably, the fabric obtained after web-formation includes ≥5% by weight of a cotton fiber, or 5-65% by weight of the cellulose fiber, or 5-65% by weight of the protein fiber, or 5-65% by weight of the polyacrylonitrile fiber, or 100% by weight of the polyvinyl alcohol fiber being dissolved at a low temperature. Any one of the above-mentioned solutions can be adopted, but this application is not limited thereto. When the fiber is a mixture of the above-mentioned hydroxyl-containing fiber and non-hydroxyl-containing fiber, it is only necessary that the sum of the hydroxyl-containing fibers in the fabric after web-formation can reach the minimum amount. For example, if the cotton fiber, viscose fiber, and polyester fiber are adopted, it is only necessary to ensure that the sum of the cotton fiber and viscose fiber in the fabric is ≥5 wt %. If the viscose fiber, polyacrylonitrile fiber, and polyester fiber are adopted, it is only necessary to ensure that the sum of the viscose fiber and polyacrylonitrile fiber is in a range of 5-65 wt %. The copper content contained in the spunlace nonwoven fabric is finally controlled by controlling the amount of the fiber in the fabric and the copper content in the organic copper complex solution.

[0042] The above-mentioned polyvinyl alcohol fiber being dissolved at the low temperature can be directly dissolved in the water with a low temperature of 20-98° C.

[0043] When the fiber used for web-formation does not contain hydroxyl groups, for example, the fiber includes one or more selected from a group consisting of a polyester fiber, a polyamide fiber, a polyvinyl chloride fiber, and a polypropylene fiber, the spunlace nonwoven fabric is padded in a chitosan-ascorbic acid solution before being padded and sized so as to increase the bonding between the complexed copper ions and spunlace nonwoven fabric. Both the chitosan and ascorbic acid contain free hydroxyl groups, and by using the attachment property of the chitosan and adding acetic acid into the chitosan ascorbic acid solution, the chitosan and ascorbic acid are more firmly attached to the spunlace non-woven base fabric which is chemically chelated with copper ions in the organic copper complex solution, thereby enhancing the bonding between organic copper and spunlace non-woven fabric.

[0044] This application will be further explained in detail below in combination with preparation examples, examples, and comparation examples.

[0045] Preparation Examples 1-5 are examples for preparing the organic copper complex solution.

Preparation Example 1

[0046] A method for preparing an organic copper complex solution included the following steps:

[0047] Step S1. preparing a coordination ionic liquid: mixing urea, caprolactam, and acetamide thoroughly according to a ratio of 1:0.2:0.2 by weight, heating to a temperature of 100° C. and keeping the temperature for 1 h until the caprolactam and the urea were melted and liquefied thoroughly to obtain the coordination ionic liquid; and

[0048] Step S2. preparing an organic copper complex solution: weighting sodium chloride, potassium permanganate, sodium peroxide, and copper powder according to a ratio of 1:1:1:2.5 by weight, mixing them to obtain a coordination solid mixture, adding the coordination solid mixture into the coordination ionic liquid and stirring thoroughly, a ratio of the coordination solid mixture and the coordination ionic liquid being 1:3 by weight, the copper powder being fully oxidized into monovalent ions and forming coordination ions with organic compounds in the coordination ionic liquid, adding pure water after being cooled to obtain an initial organic copper complex solution containing 5.5 wt % copper with no precipitation or discoloration occurred after 3 days, and adding water into the initial organic copper complex solution by a volume of 10 times more than the initial organic copper complex solution so as to obtain the organic copper complex solution.

Preparation Example 2

[0049] A method for preparing an organic copper complex solution included the following steps:

[0050] Step S1. preparing a coordination ionic liquid: mixing urea, caprolactam, and acetamide thoroughly according to a ratio of 1:0.3:0.4 by weight, heating to a temperature of 110° C. and keeping the temperature for 0.5 h until the caprolactam and the urea were melted and liquefied thoroughly to obtain the coordination ionic liquid; and Step S2. preparing an organic copper complex solution: weighting sodium chloride, potassium permanganate, sodium peroxide, and copper powder according to a ratio of 1:2:1:2.9 by weight, mixing them to obtain a coordination solid mixture, adding the coordination solid mixture into the coordination ionic liquid and stirring thoroughly, a ratio of the coordination solid mixture and the coordination ionic liquid being 1:3.5 by weight, the copper powder being fully oxidized into monovalent ions and forming coordination ions with organic compounds in the coordination ionic liquid, adding pure water after being cooled to obtain an initial organic copper complex solution containing 5.5 wt % copper with no precipitation or discoloration occurred after 3 days, and adding water into the initial organic copper complex solution by a volume of 20 times more than the initial organic copper complex solution so as to obtain the organic copper complex solution.

Preparation Example 3

[0051] A method for preparing an organic copper complex solution included the following steps:

[0052] Step S1. preparing a coordination ionic liquid: mixing urea, caprolactam, and acetamide thoroughly according to a ratio of 1:0.4:0.4 by weight, heating to a temperature of 120° C. and keeping the temperature for 1 h until the caprolactam and the urea were melted and liquefied thoroughly to obtain the coordination ionic liquid; and

[0053] Step S2. preparing an organic copper complex solution: weighting sodium chloride, potassium permanganate, sodium peroxide, and copper powder according to a ratio of 1:2:2:2.9 by weight, mixing them to obtain a coordination solid mixture, adding the coordination solid mixture into the coordination ionic liquid and stirring thoroughly, a ratio of the coordination solid mixture and the coordination ionic liquid being 1:3.5 by weight, the copper powder being fully oxidized into monovalent ions and forming coordination ions with organic compounds in the coordination ionic liquid, adding pure water after being cooled to obtain an initial organic copper complex solution containing 5.5 wt % copper with no precipitation or discoloration occurred after 3 days, and adding water with a volume of 30 times than the initial organic copper complex solution into the initial organic copper complex solution so as to obtain the organic copper complex solution.

Preparation Example 4

[0054] A method for preparing an organic copper complex solution was carried out according to the method in Preparation Example 2, except that water with a volume of 15 times more than the initial organic copper complex solution was added so as to obtain the organic copper complex solution.

Preparation Example 5

[0055] A method for preparing an organic copper complex solution was carried out according to the method in Preparation Example 2, except that water with a volume of 25 times more than the initial organic copper complex solution was added so as to obtain the organic copper complex solution.

[0056] Preparation Examples 6-10 are examples for preparing the chitosan-ascorbic acid solution.

Preparation Example 6

[0057] A method for preparing a chitosan-ascorbic acid solution included the following steps:

[0058] adding 5 kg chitosan powder into 25 kg acetic acid and 60 kg water under magnetic stirring until the chitosan powder was dissolved, then adding 3 kg ascorbic acid, and stirring thoroughly.

Preparation Example 7

[0059] A method for preparing a chitosan-ascorbic acid solution included the following steps: adding 8 kg chitosan powder into 28 kg acetic acid and 65 kg water under magnetic stirring until the chitosan powder was dissolved, then adding 4 kg ascorbic acid, and stirring thoroughly.

Preparation Example 8

[0060] A method for preparing a chitosan-ascorbic acid solution included the following steps:

[0061] adding 10 kg chitosan powder into 30 kg acetic acid and 70 kg water under magnetic stirring until the chitosan powder was dissolved, then adding 5 kg ascorbic acid, and stirring thoroughly.

EXAMPLES

Example 1

[0062] A method for preparing a Cu-containing non-woven fabric with antibacterial and antiviral properties included the following steps:

[0063] preparing a spunlace non-woven base fabric: forming a web from a mixed fiber of a viscose fiber and a polyester fiber, pre-wetting the web, and spunlacing the web to obtain the spunlace non-woven base fabric, and the fabric obtained after forming the web containing 5 wt % viscose fiber;

[0064] padding and sizing: padding and sizing the spunlace non-woven base fabric in an organic copper complex solution through a sizing machine to obtain a Cu-containing spunlace non-woven fabric, wherein the organic copper complex solution in the sizing machine was prepared from Preparation Example 2; and

[0065] drying at a drying temperature of 90° C. and winding the Cu-containing spunlace non-woven fabric after being padded and sized.

Example 2

[0066] A method for preparing a Cu-containing non-woven fabric with antibacterial and antiviral properties included the following steps:

[0067] preparing a spunlace non-woven base fabric: forming a web from a mixed fiber of a viscose fiber, a polyacrylonitrile fiber, and a polyester fiber, pre-wetting the web, and spunlacing the web to obtain the spunlace non-woven base fabric, and the sum of the viscose fiber and the polyester fiber after web-forming being 65 wt %;

[0068] padding and sizing: padding and sizing the spunlace non-woven base fabric in an organic copper complex solution through a sizing machine to obtain a Cu-containing spunlace non-woven fabric, wherein the organic copper complex solution in the sizing machine was prepared from Preparation Example 1; and

[0069] drying at a drying temperature of 100° C. and winding the Cu-containing spunlace non-woven fabric after being padded and sized.

Example 3

[0070] A method for preparing a Cu-containing non-woven fabric with antibacterial and antiviral properties included the following steps:

[0071] preparing a spunlace non-woven base fabric: forming a web from a mixed fiber of a cotton fiber and a polyester fiber, pre-wetting the web, and spunlacing the web to obtain the spunlace non-woven base fabric, and the fabric obtained after web-forming containing 5 wt % cotton fiber;

[0072] padding and sizing: padding and sizing the spunlace non-woven base fabric in an organic copper complex solution through a sizing machine to obtain a Cu-containing spunlace non-woven fabric, wherein the organic copper complex solution in the sizing machine was prepared from Preparation Example 5; and

[0073] drying at a drying temperature of 100° C. and winding the Cu-containing spunlace non-woven fabric after being padded and sized.

Example 4

[0074] A method for preparing a Cu-containing non-woven fabric with antibacterial and antiviral properties was carried out according the method in Example 2 except that,

[0075] preparing the spunlace non-woven base fabric: web-forming a web from a mixed fiber of a soybean fiber and a polyester fiber, pre-wetting the web, and spunlacing the web to obtain the spunlace non-woven base fabric, and the fabric obtained after web-forming containing 20 wt % soybean fiber; and

[0076] the organic copper complex solution in the sizing machine was prepared from Preparation Example 3.

Example 5

[0077] A method for preparing a Cu-containing non-woven fabric with antibacterial and antiviral properties was carried out according the method in Example 2 except that,

[0078] preparing the spunlace non-woven base fabric: forming a web from a polyvinyl alcohol fiber having a low-temperature water solubility, pre-wetting the web, and spunlacing the web to obtain the spunlace non-woven base fabric, wherein the polyvinyl alcohol fiber having a low-temperature water solubility can be directly dissolved in water at a temperature of 20° C.; and

[0079] the organic copper complex solution in the sizing machine was prepared from Preparation Example 4.

Example 6

[0080] A method for preparing a Cu-containing non-woven fabric with antibacterial and antiviral properties included the following steps:

[0081] preparing a spunlace non-woven base fabric: forming a web from a polypropylene fiber, pre-wetting the web, and spunlacing the web to obtain the spunlace non-woven base fabric;

[0082] padding in an chitosan-ascorbic acid solution: padding the spunlace non-woven base fabric in the chitosan-ascorbic acid solution through a sizing machine, then drying at a temperature of 150° C. for 10 min, wherein the chitosan-ascorbic acid solution in the sizing machine was prepared from Preparation Example 6;

[0083] soaping: soaping the dried spunlace non-woven base fabricin a 5 g/L soaping agent at a soaping temperature of 35° C. for 10 min, and drying at a drying temperature of 50° C., wherein the soaping agent was purchased from Dongguan Chain Spinning New Material Technology Co. Ltd., the brand was chain spinning Texchain, and the model was 605;

[0084] padding and sizing: padding and sizing the soaped spunlace non-woven base fabric in an organic copper complex solution through a sizing machine to obtain a Cu-containing spunlace non-woven fabric, wherein the organic copper complex solution in the sizing machine was prepared from Preparation Example 1; and

[0085] drying at a drying temperature of 100° C. and winding the Cu-containing spunlace non-woven fabric after being padded and sized.

Example 7

[0086] A method for preparing a Cu-containing non-woven fabric with antibacterial and antiviral properties included the following steps:

[0087] preparing a spunlace non-woven base fabric: forming a web from a polyamide fiber, pre-wetting the web, and spunlacing the web to obtain the spunlace non-woven base fabric;

[0088] padding in an chitosan-ascorbic acid solution: padding the spunlace non-woven base fabric in the chitosan-ascorbic acid solution through a sizing machine, then drying at a temperature of 160° C. for 8 min, wherein the chitosan-ascorbic acid solution in the sizing machine was prepared from Preparation Example 7;

[0089] soaping: soaping the dried spunlace non-woven base fabric in a 5 g/L soaping agent at a soaping temperature of 40° C. for 5 min, and drying at a drying temperature of 55° C., wherein the soaping agent was purchased from Dongguan Chain Spinning New Material Technology Co. Ltd., the brand was chain spinning Texchain, and the model was 605;

[0090] padding and sizing: padding and sizing the soaped spunlace non-woven base fabric in an organic copper complex solution through a sizing machine to obtain a Cu-containing spunlace non-woven fabric, wherein the organic copper complex solution in the sizing machine was prepared from Preparation Example 2; and

[0091] drying at a drying temperature of 100° C. and winding the Cu-containing spunlace non-woven fabric after being padded and sized.

Example 8

[0092] A method for preparing a Cu-containing non-woven fabric with antibacterial and antiviral properties included the following steps:

[0093] preparing a spunlace non-woven base fabric: web-forming a web from a polyvinyl chloride fiber, pre-wetting the web, and spunlacing the web to obtain the spunlace non-woven base fabric;

[0094] padding in an chitosan-ascorbic acid solution: padding the spunlace non-woven base fabric in the chitosan-ascorbic acid solution through a sizing machine, then drying at a temperature of 170° C. for 5 min, wherein the chitosan-ascorbic acid solution in the sizing machine was prepared from Preparation Example 8;

[0095] soaping: soaping the dried spunlace non-woven base fabric after in a 5 g/L soaping agent at a soaping temperature of 40° C. for 5 min, and drying at a drying temperature of 60° C., wherein the soaping agent was purchased from Dongguan Chain Spinning New Material Technology Co. Ltd., the brand was chain spinning Texchain, and the model was 605;

[0096] padding and sizing: padding and sizing the soaped spunlace non-woven base fabric in an organic copper complex solution through a sizing machine to obtain a Cu-containing spunlace non-woven fabric, wherein the organic copper complex solution in the sizing machine was prepared from Preparation Example 3; and

[0097] drying at a drying temperature of 100° C. and winding the Cu-containing spunlace non-woven fabric after padded and sized.

COMPARATION EXAMPLES

Comparation Example 1

[0098] A method for preparing a Cu-containing non-woven fabric with antibacterial and antiviral properties was carried out according the method in Example 2 except that, in the step of padding and sizing, when preparing the organic copper complex solution in the sizing machine, the initial organic copper complex solution was added into pure water with a volume of 12 times more than the initial organic copper complex solution, and the rest was the same as Preparation Example 2.

Comparation Example 2

[0099] A method for preparing a Cu-containing non-woven fabric with antibacterial and antiviral properties was carried out according the method in Example 2 except that, in the step of padding and sizing, when preparing the organic copper complex solution in the sizing machine, the initial organic copper complex solution was added into pure water with a volume of 25 times more than the initial organic copper complex solution, and the rest was the same as Preparation Example 2.

Comparation Example 3

[0100] A method for preparing a Cu-containing non-woven fabric with antibacterial and antiviral properties was carried out according the method in Example 2 except that, in the step of padding and sizing, the solution in the sizing machine was not the organic copper complex solution but a 3 mol/L copper chloride solution.

[0101] Property Test

[0102] 1. Antibacterial Property Test

[0103] Antibacterial properties of spunlace non-woven base fabrics obtained from examples 1-8 were determined according to AATCC 100-2012. The test sample was a circular swatch with a diameter of 4.8 cm, and 4 parallel tests were carried out with an average value being taken. The test bacteria was Methicillin-resistant Staphylococcus aureus ATCC 33591, and the volume of the inoculum was 1 mL. Results of the test were shown as Table 1.

TABLE-US-00001 TABLE 1 Antibacterial property of examples The number of bacteria obtained by elution with different contact time Inoculum “0” h of “24” h of Percent Test concentration contact time contact time reduction of bacteria (cfu/mL) / (cfu/swatch) (cfu/swatch) bacteria Methicillin-resistant 1.1 × 10.sup.5 Example 1 1.0 × 10.sup.5 <1.0 × 10.sup.2 >99.9 Staphylococcus Example 2 1.0 × 10.sup.5 <1.0 × 10.sup.2 >99.9 aureus ATCC 33591 Example 3 1.0 × 10.sup.5 <1.0 × 10.sup.2 >99.9 Example 4 1.0 × 10.sup.5 <1.0 × 10.sup.2 >99.9 Example 5 1.0 × 10.sup.5 <1.0 × 10.sup.2 >99.9 Example 6 1.0 × 10.sup.5 <1.0 × 10.sup.2 >99.9 Example 7 1.0 × 10.sup.5 <1.0 × 10.sup.2 >99.9 Example 8 1.0 × 10.sup.5 <1.0 × 10.sup.2 >99.9

[0104] Similarly, the above-mentioned antibacterial property test was carried out for spunlace non-woven base fabrics obtained from comparation examples 1-3, and results were shown as table 2.

TABLE-US-00002 TABLE 2 Antibacterial property of comparation examples The number of bacteria obtained by elution with different contact time Inoculum “0” h of “24” h of Percent Test concentration contact time contact time reduction of bacteria (cfu/mL) / (cfu/swatch) (cfu/swatch) bacteria Methicillin-resistant 1.1 × 10.sup.5 Comparation 1.0 × 10.sup.5 5.0 × 10.sup.3 95 Staphylococcus example 1 aureus ATCC 33591 Comparation 1.0 × 10.sup.5 <1.0 × 10.sup.2  >99.9 example 2 Comparation 1.0 × 10.sup.5 1.2 × 10.sup.4 88 example 3

[0105] It can be seen from table 1 that antibacterial properties of spunlace non-woven fabrics prepared by the method of this application were excellent, especially for Methicillin-resistant Staphylococcus aureus with strong toxicity and drug resistance. In this application, adding water with a volume of 10-30 times than an initial organic copper complex solution into the initial organic copper complex solution with a weight percentage of 5.5 wt %, and controlling fiber materials used for web-formation, the concentration of copper ions on the spunlace non-woven fabric was controlled to be in a range of 500-8000 ppm, which played an excellent antibacterial effect. Combining with comparation example 3 and example 2, it can be seen that the antibacterial property was greatly improved by using organic copper complex ions in this application than by directly adding inorganic copper. Referring to comparation examples 1-2 and example 2, it can be seen that the antibacterial effect was greatly reduced when the concentration of copper ions in the organic copper complex solution was very low, and when the concentration of copper ions was very high, the antibacterial property kept unchanged while the cost was increased, meanwhile the copper with a high content was harmful for the human body.

[0106] In addition, when spunlace non-woven fabrics containing hydroxyl groups in examples 1-5 were directly padded in the organic copper complex solution, the antibacterial effect thereof was excellent. Meanwhile, because the raw material of the spunlace non-woven fabric was polyester which was the synthetic fiber and did not contain cellulose, it should be padded in the chitosan-ascorbic acid solution in advance and then padded in the organic complex copper solution, and the obtained spunlace non-woven fabric also had excellent antibacterial property.

[0107] 2. Persistence Property Test

[0108] After respectively washing spunlace non-woven base fabrics for 50, 100, and 200 times, antibacterial properties of spunlace non-woven base fabrics obtained from examples 1 and 7 and comparation examples 1 and 3 were determined according to AATCC 100-2012. The test sample was a circular swatch with a diameter of 4.8 cm, the test bacteria was Methicillin-resistant Staphylococcus aureus ATCC 33591, and the volume of the inoculum was 1 mL. Furthermore, the copper content on spunlace non-woven fabrics was tested to determine the loss of copper content. Results of the test were shown as Table 3.

TABLE-US-00003 TABLE 3 Persistence property test 50 times 100 times 200 times percent loss of percent loss of percent loss of reduction of copper reduction of copper reduction of copper Items bacteria content bacteria content bacteria content Example 2 >99 <0.1% >99 <0.1% >99 <0.1% Example7 >99 <0.1% >99 <0.1% >99 <0.1% Comparation 93.8 <0.1% 87.5 0.3% 80.1 0.7% example 1 Comparation 80.5 3.5% 76.5 8.6% 70.9 12.4% example 3

[0109] It can be seen from table 3 that after washing spunlace non-woven fabrics for 50, 100 and 200 times, the antibacterial effect of spunlace non-woven fabrics on methicillin-resistant Staphylococcus aureus in this application did not significantly change and had excellent persistence property.

[0110] 3. Antivirus Property Test

[0111] The antivirus property test was performed on the spunlace non-woven fabric prepared in example 2, specifically, Murine norovirus s99 was used in place of human norovirus in inactivation residual activity test on human skin, in which the skin was obtained as follow.

[0112] Skin substrate. Skin was obtained from Tissue Solutions Limited, UK. The sample was used under licence. Cat #T-SKN-CUSTOM. Lot #SKINMD10413C. Was delivered under dry ice, next day delivery and stored at 8° C. Caucasian, thigh/hip. Female 46 years. BMI 24. Freeze date: 01/04/13. The Skin was thawed and dissected to remove subcutaneous tissue immediately before use.

[0113] Test Steps:

[0114] i) Virus stock: MNV 260315.17, stored at −80° C. Thawed immediately before use.

[0115] ii) The action of the wet wipe on skin (approximately 1.0×1.0 cm patches, freshly prepared), N=5 in a separate sterile plastic petri dish at 3 minute intervals, was simulated by using a standard wipe motion: The skin was held in one corner by sterile forceps and three strokes of the wipe were made along one axis of the skin patch covering the surface of the skin and then three strokes performed at 90°. This was then repeated. The duration of this was 30 seconds.

[0116] iii) After 4 hours incubation at room temperature, 50 μl of virus suspension was inoculated onto the surface of the patch for 1 minute.

[0117] iv) The skin patch was transferred to 2.0 ml cold cell culture medium (Dulbecco's modified Eagle's medium (DMEM)+5.0% V/V Foetal bovine serum)+1.0 g sterile glass beads and vortexed for 20 seconds. The recovery medium was filtered through a 0.45 μm filter to remove contaminating bacteria and stored at −20° C. overnight. A 0.1 ml volume was neutralized by gel filtration (Microspin S-400 HR column) and the eluent (void volume) was serially 10-fold diluted for TCID.sub.50 assay. [0118] v) TCID.sub.50 assay performed for each replicate [0119] vi) Calculations were made for TCID.sub.50/ml according to Karberl.sup.1. [0120] vii) The virus in the washings was calculated by 10.sup.(Σn+0.5)*400 TCID.sub.50/ml

[0121] where Σn is the sum of the proportions of wells infected from the 10.sup.−1 to the 10.sup.−6 dilution of the virus.

[0122] Results of the test were shown as Table 4.

TABLE-US-00004 TABLE 4 Antivirus property test CONTROL TREATED Raw Mean Mean Raw Mean Mean Mean Mean % Time replicate date TCID.sub.50/ml TCID.sub.50/ml log.sub.10 log.sub.10 date TCID.sub.50/ml TCID.sub.50/ml log.sub.10 log.sub.10 LogR reduction Wipe 1 1.00 1.26E+04 4.10 1.00 1.26E+04 4.10 motion 30 2 1.33 2.70E+04 4.43 0.83 8.55E+03 3.93 seconds 3 1.33 2.70E+04 4.43 0.83 8.55E+03 3.93 4 1.00 1.26E+04 4.10 1.00 1.26E+04 4.10 5 1.50 4.00E+04 23876.97 4.60 4.33 0.83 8.55E+03 10190.75 3.93 4.00 0.33 57.32 Neutralisation control 1.00 1.26E+04 10190.75 4.10 *Raw data in the above table: is the sum of the proportions of wells infected from the 10.sup.−1 to the 10.sup.−.sup.6 dilution of the virus *CONTROL: Non-infused wet wipe; TREATED: Copper-infused wet wipe

CONCLUSION

[0123] According to the protocol described against Murine norovirus s99 Berlin strain/RAW cells a surrogate for human norovirus, Cu-containing non-woven fabric achieved the following performance in vitro when compared to a non-woven fabric control:

[0124] Cu-containing non-woven fabric upon contact with the virus for 60 seconds, 4 hours after application onto to human skin, achieved a mean percent reduction of 57.32% in virus bioactivity compared to the non-woven fabric control. This product when applied (as wiping) to skin therefore shows a residual affect after 4 hours.

[0125] In summary, the spunlace non-woven fabric prepared by the method in this application has antibacterial and antivirus properties, which can be widely used in medical and health, domestic decoration, clothing, industry, agriculture and other fields, especially in medical and health products such as masks and operating coats.

[0126] These embodiments are only an explanation of this invention, and do not limit the protection scope of this invention. Those skilled in the art can make modifications without creative contribution to this embodiment after reading this specification, and it is protected by the patent law as long as it is within the scope of the claims of this invention.