METHOD(S) FOR CHANGING CONCENTRATION OF A SOLUTE WITHIN A SOLUTION
20220018554 · 2022-01-20
Inventors
Cpc classification
F24F2003/1458
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F24F11/0008
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F24F11/30
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
International classification
F24F3/14
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F24F11/00
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Abstract
A method(s) (600, 1100) for changing concentration of a solute within a solution is disclosed. The method (600) includes receiving a first stream of the solution at a state D.sub.in by a first heat and mass exchanger HMX1 and a second stream of the solution by a second heat and 5 mass exchanger HMX2. The method (600) includes processing the first stream of the solution by the HMX1 to generate a first dilute stream of the solution at a state D.sub.out. Further, the method (600) includes processing the second stream of the solution by the HMX2 to generate a first concentrate stream of the solution at a state Rout. The method (600) includes directing, at the initial phase, the first dilute stream of the solution from the processing unit to a first heat and mass exchanger 0 HMX1-n of a successive processing unit. The method (600) also includes receiving a first stream of the solution at a state D.sub.in-n by a second heat and mass exchanger HMX2-n.
Claims
1. The method for changing concentration of a solute within a solution, the method comprising: receiving a first stream of the solution at a state D.sub.in by a first heat and mass exchanger HMX1 of a processing unit from among a plurality of processing units and a second stream of the solution at the state R.sub.in by a second heat and mass exchanger HMX2 of the processing unit; processing the first stream of the solution by the HMX1 to generate a first dilute stream of the solution at a state D.sub.out, wherein the HMX1 includes a first desiccant which absorbs a first amount of the solute from the first stream of the solution at an initial phase; to processing, at the initial phase, the second stream of the solution by the HMX2 to generate a first concentrate stream of the solution at a state R.sub.out, wherein the HMX2 includes a second desiccant which releases a second amount of the solute within the second stream of the solution at the initial phase; directing, at the initial phase, the first dilute stream of the solution at the state D.sub.out from the processing unit to a first heat and mass exchanger HMX1-n of a successive processing unit from among the plurality of processing units; processing, at the initial phase, the first dilute stream of the solution by the HMX1-n of the successive processing unit to generate a concentrate stream of the solution at a state R.sub.out-n; receiving a first stream of the solution at a state D.sub.in-n by a second heat and mass exchanger HMX2-n of the successive processing unit; and processing, at the initial phase, the first stream of the solution by the HMX2-n of the successive processing unit to generate a second dilute stream of the solution at a state D.sub.out-n, wherein an amount of the solute within the second dilute stream of the solution at the state D.sub.out-n is less than an amount of the solute within the first stream of the solution at the state D.sub.in.
2. The method as claimed in claim 1, wherein at the subsequent phase, interchanging of operation of the HMX1-n and HMX2-n comprising: directing the first dilute stream of the solution at the state D.sub.out to the HMX2-n of the successive processing unit; processing the first dilute stream of the solution by the HMX2-n to generate the concentrate stream of the solution at the state R.sub.out-n, wherein the HMX2-n includes a desiccant adapted to release at least a portion from the solute which is being absorbed/adsorbed during the initial phase; receiving the first stream of the solution at the state D.sub.in-n by the HMX1-n of the successive processing unit; and processing the second concentrate stream of the solution by the HMX1-n to generate the second dilute stream of the solution at the state D.sub.out-n, wherein the HMX1-n includes a desiccant adapted to re-absorb an amount the solute to generate the second dilute stream of the solution.
3. The method as claimed in claim 1 further comprising: directing, at the initial phase, at least a portion of the first dilute stream of the solution from the HMX1 of the processing unit to the HMX2-n of the successive processing unit; and processing at least the portion of the first dilute stream by the HMX2-n to generate the second dilute stream at the state D.sub.out-n.
4. The method as claimed in claim 1 further comprising: directing at least a portion of the first dilute stream at the state D.sub.out of the solution to a third heat and mass exchanger HMX3 of the processing unit; and processing the at least the portion of the first dilute stream of the solution by the HMX3 of the processing unit to generate a concentrate stream of the solution at a state R.sub.out.
5. The method as claimed in claim 1 further comprising: directing a first stream of fluid at a state W.sub.c,in,1 to the HMX1, wherein the first stream of fluid absorbs heat generated during absorption of the first amount of the solute from the first stream of the solution by the first desiccant; and directing a second stream of fluid at a state W.sub.h,in,1 to the HMX2, wherein the second stream of fluid releases heat to increase temperature of the second desiccant which releases the second amount of the solute within the solvent.
6. The method as claimed in claim 1 further comprising: directing a first stream of water at a state W.sub.c,in,n to the HMX1-n, wherein the first stream of water absorbs heat generated during absorption of the first amount of the solute from the first stream of the solution; and directing a second stream of water at a state W.sub.h,in,n to the HMX2-n, wherein the second stream of water releases heat to increase temperature of the second desiccant which releases the second amount of the solute within the solvent.
7. The method as claimed in claim 1, wherein each of the first desiccant and the second desiccant is one of a liquid desiccant, a solid desiccant, and pellets of solid desiccant.
8. A method for changing concentration of a solute within a solvent, the method comprising: receiving a first stream of the solution at a state D.sub.in by a first heat and mass exchanger HMX1 of a processing unit; processing the first stream of the solution by the HMX1 to generate a first dilute stream of the solution at a state D.sub.out, wherein the HMX1 includes a first desiccant which absorbs a first amount of the solute from the first stream of the solution at an initial phase; directing, at the initial phase, at least a portion of the first dilute stream of the solution from the HMX1 to a second heat and mass exchanger HMX2 of the processing unit; and processing, by the HMX2, at least the portion of the first dilute stream to generate a concentrate stream of the solution at a state R.sub.out.
9. The method as claimed in claim 8 further comprising: directing, for a first time duration, the first stream of the solution at the state D.sub.in to the HMX2; processing the first stream of the solution at the state D.sub.in to generate a first concentrate stream of the solution at the state R.sub.out; directing, for a second time duration subsequent to the first time duration, at least a portion of the first dilute stream of the solution at the state D.sub.out from the HMX1 to the HMX2; and processing at least the portion of the first dilute stream of the solution by the HMX2 to generate a concentrate stream of the solution at a state R.sub.out.
10. The method as claimed in claim 9 further comprising: directing the concentrate stream of the solution at the state R.sub.out from the HMX2 to the HMX1; and processing the concentrate stream of the solution by the HMX1 to generate the first dilute stream of the solution at the state D.sub.out.
11. The method for changing concentration of a solute within a solution, the method comprising: receiving a first stream of the solution at a state D.sub.in by a first heat and mass exchanger HMX1 of a processing unit from among a plurality of processing units and a second stream of the solution at the state R.sub.in by a second heat and mass exchanger HMX2 of the processing unit; processing the first stream of the solution by the HMX1 to generate a first dilute stream of the solution at a state D.sub.out, wherein the HMX1 includes a first desiccant which absorbs a first amount of the solute from the first stream of the solution at an initial phase; processing, at the initial phase, the second stream of the solution by the HMX2 to generate a first concentrate stream of the solution at a state R.sub.out, wherein the HMX2 includes a second desiccant which releases a second amount of the solute within the second stream of the solution at the initial phase; directing, at the initial phase, the first concentrate stream of the solution at the state R.sub.out from the processing unit to a second heat and mass exchanger HMX2-n of a successive processing unit from among the plurality of processing units; processing, at the initial phase, the first concentrate stream of the solution by the HMX2-n of the successive processing unit to generate a dilute stream of the solution at a state D.sub.out-n; receiving a first stream of the solution at a state R.sub.in-n by a first heat and mass exchanger HMX1-n of the successive processing unit; and processing, at the initial phase, the concentrate stream of the solution by the HMX2-n of the successive processing unit to generate the second concentrate stream of the solution at a state R.sub.out-n, wherein an amount of the solute within the second concentrate stream of the solution at the state R.sub.out-n is higher than an amount of the solute within the second stream of the solution at the state R.sub.out.
12. The method as claimed in claim 11, wherein, at a subsequent phase, operation of the HMX1-n and the HXM2-n of the subsequent processing unit is interchanged with each other.
13. The method as claimed in claim 11, wherein each of the first desiccant and the second desiccant is one of a liquid desiccant, a solid desiccant, and pellets of solid desiccant.
14. The method as claimed in claim 11 further comprising: directing, at the initial phase, a first concentrate stream of the solution at the state R.sub.in to the HMX2 of the processing unit; processing the first concentrate stream of the solution at the state R.sub.in by the HMX2 to generate a second concentrate stream of the solution at the state R.sub.out; directing at least a portion of the second concentrate stream of the solution to the HMX1 of the processing unit; and processing at least the portion of the second concentrate stream of the solution by the HMX1 to generate a dilute stream of the solution at the state D.sub.out.
15. The method as claimed in claim 11 further comprising: directing, at the initial phase, at least a portion of the first concentrate stream of the solvent at the state R.sub.out from the HMX2 to the HMX1-n; and processing at least the portion of the first concentrate stream of the solvent to generate a concentrate stream of the solvent at a state R.sub.out-n.
16. The method for changing concentration of a solute within a solution, the method comprising: receiving a first stream of the solution at a state D.sub.in by a first heat and mass exchanger unit HMX1 of a processing unit from among a plurality of processing units; processing the first stream of the solution by the HMX1 of the processing unit to generate a first dilute stream of the solution at a state D.sub.out, wherein the HMX1 includes a desiccant which absorbs a first predefined amount of the solute from the first stream of the solution; directing the desiccant from the HMX1 to a second heat and mass exchanger HMX2 of the processing unit and a concentrate stream of the solution at a state R.sub.in1 to the HMX2; processing the first concentrate stream of the solution by the HMX2 to generate a first concentrate stream of the solution, wherein the desiccant received by the HMX2 releases at least the first predefined amount of the solute which is being absorbed/adsorbed from the first stream of the solution in the HMX1; directing the desiccant from the HMX2 to a third heat and mass exchanger HMX3 of the processing unit and at least a portion of the first dilute stream of the solution at the state D.sub.out from the HMX1 to the HMX3; processing at least the portion of the first dilute stream of the solution by the HMX3 to generate a second concentrate stream of the solution, wherein the desiccant received by the HMX3 from the HMX2 releases at least a second predefined amount of the solute which is being absorbed/adsorbed from the first stream of the solution in the HMX1; and directing the desiccant from the HMX3 to the HMX1 of the processing unit, wherein the desiccant re-absorbs a second amount of the solute from another stream directed in the HMX1.
17. The method as claimed in claim 16, wherein the desiccant is one of a liquid desiccant and pellets of solid desiccant
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0008] These and other features, aspects, and advantages of the present invention will become better understood when the following detailed description is read with reference to the accompanying drawings in which like characters represent like parts throughout the drawings, wherein:
[0009]
[0010]
[0011]
[0012]
[0013]
[0014]
[0015]
[0016]
[0017]
[0018]
[0019]
[0020]
[0021]
[0022]
[0023]
[0024]
[0025]
[0026]
[0027]
[0028]
[0029]
[0030]
[0031] Further, skilled artisans will appreciate that elements in the drawings are illustrated for simplicity and may not have been necessarily been drawn to scale. For example, the flow charts illustrate the method in terms of the most prominent steps involved to help to improve understanding of aspects of the present invention. Furthermore, in terms of the construction of the device, one or more components of the device may have been represented in the drawings by conventional symbols, and the drawings may show only those specific details that are pertinent to understanding the embodiments of the present invention so as not to obscure the drawings with details that will be readily apparent to those of ordinary skill in the art having benefit of the description herein.
DETAILED DESCRIPTION OF FIGURES
[0032] For the purpose of promoting an understanding of the principles of the invention, reference will now be made to the embodiment illustrated in the drawings and specific language will be used to describe the same. It will nevertheless be understood that no limitation of the scope of the invention is thereby intended, such alterations and further modifications in the illustrated system, and such further applications of the principles of the invention as illustrated therein being contemplated as would normally occur to one skilled in the art to which the invention relates.
[0033] Embodiments of the present invention will be described below in detail with reference to the accompanying drawings.
[0034]
[0035] Referring to
[0036] In the illustrated embodiment, each of the processing unit 102 may include a plurality of heat and mass exchangers HMXs in fluid communication with each other. In an embodiment, the plurality of heat and mass exchangers HMXs may individually referred to as a first heat and mass exchanger HMX1, a second heat and mass exchanger HMX2, third heat and mass exchanger HMX3, . . . , and a nth heat and mass exchanger HMXn, without departing from the scope of the present disclosure. Each of the HMXs may be embodied as (but not limited to) one of the following:
[0037] (a) Desiccant coated fin-tube heat exchangers;
[0038] (b) Desiccant coated banks of tubes (DCBT);
[0039] (c) Heat and mass exchangers found in adsorption/absorption chillers;
[0040] (d) Internally cooled desiccant wheel;
[0041] (e) Liquids-desiccant based internally cooled/heated mass exchangers;
[0042] (f) Fluidized bed reactors;
[0043] (g) Fixed-bed reactors;
[0044] (h) Spray tower (spray column/spray chamber).
[0045] In the illustrated embodiment, the HMX1 and the HMX2 may be configured to change concentration of the solute within the solution. In the present embodiment, the solution and the solute may be embodied as air and moisture, respectively, without departing from the scope of the present disclosure. In such an embodiment, each of the HMXs may be configured to perform humidification process and dehumidification process to change concentration of the solute within the solution. In one embodiment, each of the HMXs may be embodied as one of (a), (b), and (c) units as mentioned above. In such an embodiment, the HMX 1 and the HMX 2 may alternate between dehumidification and regeneration processes periodically. Thus, after some time, air to be dehumidified enters HMX 2 of the processing unit 102-1 at state Din,1 and regeneration air-stream enters HMX 1 of the processing unit 102-1 at state Rin,1 and so on. For instance, at an initial phase, the HMX1 and the HMX2 may perform dehumidification process and humidification process, respectfully. Further, at a subsequent phase, the HMX1 may perform humidification process and the HMX2 may perform dehumidfication process.
[0046] In another embodiment, each of the HMXs may be embodied as unit (d) as mentioned earlier. In such an embodiment, the HMX 1 and HMX 2 of the processing unit 102-1 are regions which respectively dehumidify (by absorbing/adsorbing moisture) and humidify (by releasing moisture during regeneration process) air. The HMX1 and the HMX2 of the processing unit 102-2 are sections which respectively humidify and dehumidify air and so on. In yet another embodiment, each of the HMXs may be embodied as unit (e) as mentioned earlier. In such an embodiment, the HMX 1 of the processing unit 102-1 is the conditioner wherein a liquid desiccant absorbs moisture. While, the HMX 2 of the processing unit 102-1 is the regenerator in which a liquid desiccant releases moisture. The HMX 1 and the HMX 2 of the processing unit 102-2 are regenerator and conditioner, respectively, and so on.
[0047] Some of the variations possible (but not limited to), as far as the relative directions, magnitude and duration of air and water flow and the number of HMXs are concerned, are:
[0048] (a) The air-streams may either be in parallel-flow, cross-flow or counter-flow arrangement.
[0049] (b) The pair of air-stream and water-stream may either be in parallel-flow, cross-flow or counter-flow arrangement.
[0050] (c) Instead of just HMX1 (read as ‘heat and mass exchanger’) and HMX2, there may be multiple HMXs used to achieve the said purpose (dehumidification of air). Moreover, the number of units undergoing dehumidification and regeneration need not be the same.
[0051] (d) The flow rate of air-streams need neither be steady nor does it need not be equal among HMXs. The air-flow rate may vary from one cycle to the next and may vary from one process (dehumidification or regeneration) to the next.
[0052]
[0053]
[0054] In essence, the dehumidification process proposed herein is that the dehumidified air stream, after undergoing dehumidification process (that also involves simultaneous cooling or full/partial heat-rejection), is fully or partly used as the inlet air-stream for regeneration process (which involves simultaneous internal heating). While this air-stream, after regenerating/drying a desiccant matrix may be discarded off, either the part of the dehumidified air stream not utilized for regeneration or the dehumidified air-stream after two or more stages of the aforementioned process is utilized as the useful product. Such product may either be considered as a final product or as an intermediate product, depending on the application.
[0055] Referring to
[0056] Upon receiving the first stream, the HMX1 may process, at an initial phase, the first stream of the solution to generate a first dilute stream of the solution at a state D.sub.out, interchangeably referred to as D.sub.out-1. The HMX1 may include a first desiccant which absorbs a first amount of the solute from the first stream of the solution at the initial phase. The first desiccant may perform sorption, such as absorption and adsorption, of the solute from the first dilute stream, when a first 15 stream of fluid at state W.sub.c,in,1 is directed to the HMX1. In an embodiment, the fluid may be embodied as one of water and any other suitable fluid know in the art, without departing from the scope of the present disclosure. The first stream of fluid may absorb heat generated during sorption of the first amount of the solute from the first stream of the solution by the first desiccant. This ensures that the first dilute stream of the solution may not become hot at an outlet of the HMX1.
[0057] Subsequently, upon receiving the second stream, the HMX2 may process the second stream of the solution at the state R.sub.in-1 to generate a first concentrate stream of the solution at a state R.sub.out, interchangeably referred to as R.sub.out-1. The HMX2 may include a second desiccant which releases a second amount of the solute within the second stream of the solution at the initial phase. In particular, the second stream of the solution may takes up the solute from the second desiccant, when a second stream of fluid at a state W.sub.h,in,1 is directed to the HMX2.
[0058] The second stream of fluid releases heat to increase temperature of the second desiccant which releases the second amount of the solute within the solvent. The second desiccant may perform sorption, such as absorption and adsorption, of the solute from the first dilute stream, when a first stream of fluid at state W.sub.c,in,1 is directed to the HMX1. The first stream of fluid may absorb heat generated during sorption of the first amount of the solute from the first stream of the solution by the first desiccant. Each of the first desiccant and the second desiccant may be embodied as one of a liquid desiccant, a solid desiccant, and pellets of solid desiccant.
[0059] During dehumidification process, the first concentrate stream at the state R.sub.out-1 generated by the HMX2 may be discarded from the system 100. At the initial phase, the HMX1 of the processing unit 102-1 may be configured to supply the first dilute stream of the solution at the state D.sub.out-1 to a first heat and mass exchanger HMX1-n of a successive processing unit 102-n from among the plurality of the processing units 102. In the illustrated embodiment, the HMX1 may be configured to supply the first dilute stream of the solution at the state D.sub.out,1 to the HMX1-n, where n=2, of a successive processing unit 102-2, interchangeably referred as the processing unit 102-2. The first dilute stream at the state D.sub.out-1 supplied to the HMX1-2 may interchangeably be referred to as the first dilute stream at the state R.sub.in-2.
[0060] Subsequently, at the initial phase, the HMX1-2 may process the first dilute stream of the solution at the state R.sub.in-2 to generate a concentrate stream of the solution at a state R.sub.out-2. In the illustrated embodiment, the concentrate stream at the state R.sub.out-2 generated by the HMX1-2 may be discarded from the system 100. Further, a second heat and mass exchanger HMX2-2 of the processing unit 102-2 may be configured to receive another stream, i.e., a first stream of the solution at a state D.sub.in-2. Upon receiving the first stream at the state D.sub.in-2, the HMX2-2, at the initial phase, may process the first stream of the solution at the state D.sub.in-n to generate a second dilute stream of the solution at a state D.sub.out-n. In the illustrated embodiment, the amount of the solute within the second dilute stream of the solution at the state D.sub.out-2 may be less than an amount of the solute within the first dilute stream of the solution at the state D.sub.in-1. Further, an air stream received from a last processing unit, i.e., the processing unit 102-n, may have a minimum value of specific humidity, and thereby may be used as a final product.
[0061] Further, at the subsequent phase, operation of the HMX1-n and the HXM2-n of the subsequent processing unit may be interchanged with each other. In the illustrated embodiment, operation of the HMX1-2 and the HMX2-2 of the processing unit 102-2 may be interchanged with each other. At the subsequent phase, the HMX2-2 of the processing unit 102-2 may receive the first dilute stream of the solution at the state D.sub.out. Further, the HMX2-2 may process the first dilute stream of the solution to generate the concentrate stream of the solution at the state R.sub.out-2. The HMX2-2 includes a desiccant adapted to release at least a portion from the solute which is being absorbed/adsorbed during the initial phase. Further, the HMX1-2 may receive the first stream of the solution at the state D.sub.in-2 by the HMX1-2 of the processing unit 102-2. Subsequently, the HMX1-2 may process the second concentrate stream of the solution to generate the second dilute stream of the solution at the state D.sub.out-2. The HMX1-2 includes a desiccant adapted to re-absorb an amount the solute to generate the second dilute stream of the solution. The desiccant of each of the HMX1-2 and the HMX2-2 may be embodied as one of a liquid desiccant, a solid desiccant, and pellets of solid desiccant.
[0062] Similarly, at a subsequent phase, operation of the HMX1 and the HMX2 of the processing unit 102 may be interchanged with each other. At the subsequent phase, the first desiccant of the HMX1 releases at least a portion from the first amount of the solute which is being absorbed/adsorbed by the first desiccant, the second desiccant of the HMX2 absorbs an amount of the solute to generate the first dilute stream of the solution.
[0063]
[0064] Referring to
[0065]
[0066] However, it should be appreciated by a person skilled in the art that the present embodiment can equally be implemented with respect to other processing units 102 of the system 100, without departing from the scope of the present disclosure. For the sake of brevity, features of the system 100 that are already explained in detail in the description of
[0067] Referring to
[0068] In another embodiment, the first dilute stream at the state D.sub.out may fully be used as the regeneration stream, i.e., R.sub.in. In such an embodiment, the first dilute stream at the state D.sub.out may fully be used as the regeneration stream, until a periodically steady-state is achieved. However, when the periodically steady-state is achieved, the first dilute stream at the state D.sub.out may partially be used as the regeneration stream and remaining portion of the first dilute stream may be used as the final product.
[0069]
[0070] However, it should be appreciated by a person skilled in the art that the present embodiment can equally be implemented with respect to other processing units 102 of the system 100, without departing from the scope of the present disclosure. For the sake of brevity, features of the system 100 that are already explained in detail in the description of
[0071] Referring to
[0072] In particular, the HMX2 may receive at least the portion of the first dilute stream at the state D.sub.out for a second time duration (for example say 40 seconds), subsequent to the first time duration. Thereafter, the HMX2 may process the received portion of the first dilute stream at the state D.sub.out to generate the concentrate stream of the solution at the state R.sub.out. The second desiccant may increase concentration of the solute in the received portion of the first dilute stream to generate the concentrate stream at the state R.sub.out. In an embodiment, each of the first time duration and the second time duration may selected based on dilution required in the first dilute stream and required flow-rate of the first dilute stream.
[0073] The advantage of the present embodiment is that in initial few seconds, highly dry air (with low RH) is not necessarily required for generating concentrate stream of the solution. However, as time proceeds and desiccant in the HMX becomes drier, much drier air (with low RH) is required, and then dehumidified air, such as the first dilute stream at the state D.sub.out must be partly redirected towards drying desiccant of the HMX2.
[0074]
[0075] However, it should be appreciated by a person skilled in the art that the present embodiment can equally be implemented with respect to other processing units 102 of the system 100, without departing from the scope of the present disclosure. For the sake of brevity, features of the system 100 that are already explained in detail in the description of
[0076] Referring to
[0077]
[0078] However, it should be appreciated by a person skilled in the art that the present embodiment can equally be implemented with respect to other processing units 102 of the system 100, without departing from the scope of the present disclosure. For the sake of brevity, features of the system 100 that are already explained in detail in the description of
[0079] Referring to
[0080] Further, upon generation of the first dilute stream, the desiccant from the HMX1 may be directed to the HMX2 of the processing unit 102-2, as shown by arrow 402. Subsequently, the HMX2 may receive a concentrate stream of the solution at a state R.sub.in,1. The HMX2 may process the concentrate stream of the solution at the state R.sub.in,1 to generate a first concentrate stream of the solution. The desiccant received by the HMX2 may release at least a first predefined amount of the solute which is being absorbed/adsorbed from the first stream of the solution in the HMX1.
[0081] Upon generation of the first concentrate stream, the desiccant may be directed to the HMX3 from the HMX2, as shown by arrow 404. Subsequently, the HMX3 may receive at least a portion of the first dilute stream of the solution at the state D.sub.out from the HMX1 to the HMX3. The HMX3 may process the at least portion of the first dilute stream of the solution to generate a second concentrate stream of the solution. The desiccant received by the HMX3 from the HMX2 may release at least a second predefined amount of the solute which is being absorbed/adsorbed from the first stream of the solution in the HMX 1. Subsequently, the desiccant may be directed from the HMX3 to the HMX 1 of the processing unit 102-1. Further, the desiccant may re-absorb a second amount of the solute from another stream directed in the HMX1.
[0082]
[0083] However, it should be appreciated by a person skilled in the art that the present embodiment can equally be implemented with respect to other processing units 102 of the system 100, without departing from the scope of the present disclosure. For the sake of brevity, features of the system 100 that are already explained in detail in the description of
[0084] Referring to
[0085] It may be noted that details regarding system and method for dilution of the solute within the solution is explained with respect to configurations as depicted in
[0086]
[0087] Referring to
[0088] At block 606, the method 600 includes processing, at the initial phase, the second stream of the solution by the HMX2 to generate the first concentrate stream of the solution at the state R.sub.out. The HMX2 includes the second desiccant which releases the second amount of the solute within the second stream of the solution at the initial phase. Further, at block 604, the method 600 includes directing, at the initial phase, the first dilute stream of the solution at the state D.sub.out from the processing unit to the HMX1-n of the successive processing unit 102-n from among the plurality of processing units 102. At block 608, the method 600 includes processing, at the initial phase, the first dilute stream of the solution by the HMX1-n of the successive processing unit to generate the concentrate stream of the solution at the state R.sub.out-n.
[0089] Referring to
[0090]
[0091] Referring to
[0092] At block 706, the method 700 includes directing the desiccant from the HMX1 to the HMX2 of the processing unit 102-1 and the concentrate stream of the solution at the state R.sub.in1 to the HMX2. Further, at block 708, the method includes processing the first concentrate stream of the solution by the HMX2 to generate the first concentrate stream of the solution. The desiccant received by the HMX2 releases at least the first predefined amount of the solute which is being absorbed/adsorbed from the first stream of the solution in the HMX1.
[0093] Referring to
[0094]
[0095]
[0096] The regeneration air-stream, after drying/regenerating the desiccant (while simultaneously getting heated in the process) during regeneration process, itself becomes humid. This humid air-stream is then used as the inlet air-stream for dehumidification process (which also involves simultaneous cooling or full/partial heat-rejection) during which the desiccant is charged/impregnated with moisture by adsorption/absorption process. While the dehumidified air-stream may be discarded off, the humid air-stream after two or more such cycles of the two processes (regeneration and dehumidification) in a single unit may be bled out and utilized as the useful product (either as the final product or intermediate product depending on the application) or else after two or more stages of the aforementioned process, is utilized as the useful product.
[0097] Referring to
[0098] The HMX1 may include the first desiccant which absorbs the first amount of the solute from the first stream of the solution at the initial phase. The first desiccant may perform sorption, such as absorption and adsorption, of the solute from the first dilute stream, when the first stream of fluid at state W.sub.c,in,1 is directed to the HMX1. The first stream of fluid may absorb heat generated during sorption of the first amount of the solute from the first stream of the solution by the first desiccant. This ensures that the first dilute stream of the solution may not become hot at an outlet of the HMX1.
[0099] Subsequently, upon receiving the second stream, the HMX2 may process the second stream of the solution at the state R.sub.in to generate the first concentrate stream of the solution at the state R.sub.out. The HMX2 may include the second desiccant which releases the second amount of the solute within the second stream of the solution at the initial phase. In particular, the second stream of the solution may takes up the solute from the second desiccant, when the second stream of fluid at the state W.sub.h,in,1 is directed to the HMX2.
[0100] The second stream of fluid releases heat to increase temperature of the second desiccant which releases the second amount of the solute within the solvent. The second desiccant may perform sorption, such as absorption and adsorption, of the solute from the first dilute stream, when the first stream of fluid at state W.sub.c,in,1 is directed to the HMX1. The first stream of fluid may absorb heat generated during sorption of the first amount of the solute from the first stream of the solution by the first desiccant.
[0101] During humidification process, the first dilute stream at the state D.sub.out generated by the HMX1 may be discarded from the system 100. At the initial phase, the HMX2 of the processing unit 102-1 may be configured to supply the first concentrate stream of the solution at the state R.sub.out to the HMX2-n of a successive processing unit 102-n from among the plurality of the processing units 102. In the illustrated embodiment, the HMX2 may be configured to supply the first concentrate stream of the solution at the state R.sub.out to the HMX2-n, where n=2, of a successive processing unit 102-2, interchangeably referred as the processing unit 102-2. The first concentrate stream at the state R.sub.out may be directed to the HMX2-2 for using such stream as dehumidification stream, i.e., D.sub.in-2.
[0102] Subsequently, at the initial phase, the HMX2-2 may process the first concentrate stream of the solution at the state D.sub.in-2 to generate a dilute stream of the solution at a state D.sub.out-2. In the illustrated embodiment, the dilute stream at the state D.sub.out-2 generated by the HMX2-2 may be discarded from the system 100. Further, the first heat and mass exchanger HMX1-2 of the processing unit 102-2 may be configured to receive another stream, i.e., a second stream of the solution at a state R.sub.in-2.
[0103] Upon receiving the second stream at the state R.sub.in-2, the HMX1-2, at the initial phase, may process the second stream of the solution at the state R.sub.in-2 to generate a second concentrate stream of the solution at a state R.sub.out-2. In one embodiment, the second concentrate stream of the solution may be used as a final product of the system. In another embodiment, the second concentrate stream of the solution at state R.sub.out-2 may be directed to HMX of the subsequent processing unit 102-n, where n=3.
[0104] In the illustrated embodiment, the amount of the solute within the second concentrate stream of the solution at the state R.sub.out-2 may be higher than an amount of the solute within the second stream of the solution at the state R.sub.in-1. Also, the amount of solute within the second concentrate stream of the solution at the state R.sub.out-2 may be higher than an amount of the solute within the first concentrate stream of the solution at the state R.sub.out-1.
[0105]
[0106] Referring to
[0107]
[0108] However, it should be appreciated by a person skilled in the art that the present embodiment can equally be implemented with respect to other processing units 102 of the system 100, without departing from the scope of the present disclosure. For the sake of brevity, features of the system 100 that are already explained in detail in the description of
[0109] Referring to
[0110] In another embodiment, the first concentrate stream at the state R.sub.out may fully be used as the dehumidification stream, i.e., D.sub.in. In such an embodiment, the first concentrate stream at the state R.sub.out may fully be used as the dehumidification stream, until a periodically steady-state is achieved. However, when the periodically steady-state is achieved, the first concentrate stream at the state R.sub.out may partially be used as the dehumidification stream and remaining portion of the first concentrate stream may be used as the final product.
[0111] It may be noted that details regarding system and method for concentrating the solute within the solution are explained with respect to configurations as depicted in
[0112] Needless to say, all the possibilities regarding different configurations, details of the units, relative directions, magnitude and duration of air and water flow and a number of HMXs discussed with respect to dehumidification process also exist for humidification process.
[0113]
[0114] Referring to
[0115] Further, at block 1106, the method includes processing, at the initial phase, the second stream of the solution by the HMX2 to generate the first concentrate stream of the solution at the state R.sub.out. The HMX2 includes the second desiccant which releases the second amount of the solute within the second stream of the solution at the initial phase. At block 1108, the method includes directing, at the initial phase, the first concentrate stream of the solution at the state R.sub.out from the processing unit to the HMX2-n of the successive processing unit from among the plurality of processing units.
[0116] Referring to
Mathematical Model
[0117] The mathematical model used herein is for simulating the performance of a DCFTHX (desiccant coated fin tube heat exchanger) for counter-flow arrangement of air-streams. It is similar to that presented in the Journal: Jagirdar M and Lee P S, Mathematical modeling and performance evaluation of a desiccant coated fin-tube heat exchanger. Applied Energy, 2018). The mathematical model as disclosed in the aforementioned journal is slightly altered in cognizance of the method(s) as explained in the present disclosure. The mathematical model implemented herein uses the inlet boundary condition (of air) to a unit, such as the HMX, undergoing regeneration for a case of the dehumidification process as given by equation (1). Note that this condition is applied to configuration similar to that of
While for the unit, such as the HMX, undergoing dehumidification for the regeneration process is given by equation (2). Note that this condition is applied to configuration similar to that of
[0118] Here, Ya(Lx,z,t) is the specific-humidity of air at the inlet (x=Lx) of the DCFTHX that regenerates air, at location ‘z’ in the direction transverse to the air-flow (along the height of the air channel) at time ‘t’. t1 and t2 are the durations of dehumidification and regeneration processes respectively. Hf, Hd and Ha are respectively the thickness of the fins, the desiccant layer thickness and height of the air channel.
Experimental Data
[0119] The variables selected to conduct the simulations are as presented in Table 1 for dehumidification process and humidification process, unless otherwise stated. It should be appreciated by a person skilled in the art that Table 1 is included to provide a better understanding of the present disclosure and therefore, should not be construed as limiting.
TABLE-US-00001 TABLE 1 Input data for simulations Desiccant properties Desiccant 800 kg/m.sup.3 mass fraction 0.9 specific heat 921 J/(Kg-K) density of sorbent of desiccant Desiccant 0.3 Pore diameter 10 nm porosity Geometrical parameters of DCFTHX longitudinal 22 mm tube length 600 mm Desiccant thickness 0.15 mm tube pitch (height of HX) transverse 25.4 mm Inner tube 8.5 mm Fin thickness 0.1 mm tube pitch diameter length of 44 mm Outer tube 9.5 mm the fin diameter width of 304.8 mm Fin pitch 2 mm the fin Fluid flow conditions for dehumidification cases dehumidification 120 s Inlet temperature 30° C. Inlet specific 0.0197 kg/kg time period of (cool) water humidity of working d.a. during air during dehumidification dehumidification regeneration 120 s Inlet temperature 40° C. Inlet specific 0.0197 kg/kg time period of (hot) water humidity of working d.a. during air during regeneration regeneration Mass flow rate 4 kg/s Inlet temperature 32° C. of hot water of working air during dehumidification Mass flow rate 4 kg/s Inlet temperature 32° C. of cool water of working air during regeneration Fluid flow conditions for simulations of humidification cases dehumidification Variable Inlet temperature 15° C. Inlet specific 0.0032 kg/kg time period of (cool) water humidity of working d.a. during air during dehumidification dehumidification regeneration Variable Inlet temperature 25° C. Inlet specific 0.0032 kg/kg time period of (hot) water humidity of working d.a. during air during regeneration regeneration Mass flow rate 4 kg/s Inlet temperature 15° C. of hot water of working air during dehumidification Mass flow rate 4 kg/s Inlet temperature 15° C. of cool water of working air during dehumidification
[0120]
[0121] It may be clearly observed in
[0122]
[0123] It may be clearly observed in
[0124]
[0125]
[0126]
[0127] It may be clearly observed in
[0128]
[0129]
[0130]
[0131] The method(s) implemented in configurations depicted in
[0132] The method(s) implemented in configurations depicted in
[0133] The method(s) which are explained in the present disclosure can be employed in various applications including, but not limited to, desalination, water-distillation as well as for humidifiers that may also be used in power-plants, industries etc, Therefore, the method(s) of the present disclosure has a wide range of applications.
[0134] While specific language has been used to describe the present subject matter, any limitations arising on account thereto, are not intended. As would be apparent to a person in the art, various working modifications may be made to the method in order to implement the inventive concept as taught herein. The drawings and the foregoing description give examples of embodiments. Those skilled in the art will appreciate that one or more of the described elements may well be combined into a single functional element. Alternatively, certain elements may be split into multiple functional elements. Elements from one embodiment may be added to another embodiment.