MANUFACTURABLE HUMIDIFIER
20230299315 · 2023-09-21
Inventors
Cpc classification
Y02P70/50
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y02E60/50
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
B21D53/02
PERFORMING OPERATIONS; TRANSPORTING
International classification
Abstract
A method for assembling a fuel cell humidifier can include steps of providing a first humidifier plate and a humidifier membrane. The first humidifier plate can have a first top plate surface. The humidifier membrane can have a bottom membrane surface. The bottom membrane surface of the humidifier membrane can be disposed on the first top plate surface of the first humidifier plate. The first humidifier plate can be partially melted. This can permit the first top plate surface of the first humidifier plate to permeate into the bottom membrane surface of the humidifier membrane. The first humidifier plate can be cooled, which can fuse the first top plate surface of the first humidifier plate with the bottom membrane surface of the humidifier membrane.
Claims
1. A humidifier for humidifying a fuel cell stack, comprising: a first humidifier plate with a first top plate surface; and a humidifier membrane with a bottom membrane surface fused with the top plate surface of the humidifier plate.
2. The humidifier of claim 1, further including a second humidifier plate with a second bottom plate surface fused with a top membrane surface of the humidifier membrane.
3. The humidifier of claim 2, wherein the first humidifier plate has a first recess perimeter fused with a second recess perimeter of the second humidifier plate, a seal between the first humidifier plate and the second humidifier plate, the seal bounding the humidifier membrane.
4. The humidifier of claim 3, wherein each of the first humidifier plate and the second humidifier plate has a plate main body with a plurality of header apertures and a flow field circumscribed by a lip, the flow field including a plurality of lattice apertures with a plurality of connecting bridges, each of the lattice apertures separated by one of the connecting bridges.
5. The humidifier of claim 4, wherein the plate main body has a plurality of grooves, each of the grooves disposed adjacent to one of the header apertures and the flow field.
6. The humidifier of claim 4, wherein the connecting bridges has a plurality of spacers disposed thereon, each of the spacers configured to receive the humidifier membrane.
7. The humidifier of claim 1, wherein the humidifier does not include a substantial compression and retention system.
8. The humidifier of claim 1, wherein the humidifier plate is manufactured from a material that does not substantially melt at room temperature or a selected operating temperature.
9. The humidifier of claim 8, wherein the material is configured to partially melt at a temperature that is greater than the room temperature or the selected operating temperature, thereby allowing the bottom membrane surface of the humidifier membrane to permeate into the top plate surface of the humidifier plate.
10. A fuel cell system comprising: a fuel cell stack configured to output a wet fluid stream; a fluid source configured to output a dry fluid stream; and a humidifier according to claim 1, wherein the humidifier is configured to receive the wet fluid stream and the dry fluid stream and humidify the dry fluid stream with the wet fluid stream, thereby forming a humidified fluid stream to be provided to the fuel cell stack.
Description
DRAWINGS
[0013] The above, as well as other advantages of the present disclosure, will become readily apparent to those skilled in the art from the following detailed description, particularly when considered in the light of the drawings described herein.
[0014]
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[0020]
[0021]
DETAILED DESCRIPTION
[0022] The following description of technology is merely exemplary in nature of the subject matter, manufacture, and use of one or more inventions, and is not intended to limit the scope, application, or uses of any specific invention claimed in this application or in such other applications as can be filed claiming priority to this application, or patents issuing therefrom. Regarding methods disclosed, the order of the steps presented is exemplary in nature, and thus, the order of the steps can be different in various embodiments, including where certain steps can be simultaneously performed.
[0023] The terms “a” and “an” as used herein indicate “at least one” of the item is present; a plurality of such items can be present, when possible. Except where otherwise expressly indicated, all numerical quantities in this description are to be understood as modified by the word “about” and all geometric and spatial descriptors are to be understood as modified by the word “substantially” in describing the broadest scope of the technology. The term “about” when applied to numerical values indicates that the calculation or the measurement allows some slight imprecision in the value (with some approach to exactness in the value; approximately or reasonably close to the value; nearly). If, for some reason, the imprecision provided by “about” and/or “substantially” is not otherwise understood in the art with this ordinary meaning, then “about” and/or “substantially” as used herein indicates at least variations that can arise from ordinary methods of measuring or using such parameters.
[0024] Although the open-ended term “comprising,” as a synonym of non-restrictive terms such as including, containing, or having, is used herein to describe and claim embodiments of the present technology, embodiments can alternatively be described using more limiting terms such as “consisting of” or “consisting essentially of.” Thus, for any given embodiment reciting materials, components, or process steps, the present technology also specifically includes embodiments consisting of, or consisting essentially of, such materials, components, or process steps excluding additional materials, components or processes (for consisting of) and excluding additional materials, components or processes affecting the significant properties of the embodiment (for consisting essentially of), even though such additional materials, components or processes are not explicitly recited in this application.
[0025] Disclosures of ranges are, unless specified otherwise, inclusive of endpoints and include all distinct values and further divided ranges within the entire range. Thus, for example, a range of “from A to B” or “from about A to about B” is inclusive of A and of B. Disclosure of values and ranges of values for specific parameters (such as amounts, weight percentages, etc.) are not exclusive of other values and ranges of values useful herein. It is envisioned that two or more specific exemplified values for a given parameter can define endpoints for a range of values that can be claimed for the parameter. For example, if Parameter X is exemplified herein to have value A and also exemplified to have value Z, it is envisioned that Parameter X can have a range of values from about A to about Z. Similarly, it is envisioned that disclosure of two or more ranges of values for a parameter (whether such ranges are nested, overlapping, or distinct) subsume all possible combination of ranges for the value that might be claimed using endpoints of the disclosed ranges. For example, if Parameter X is exemplified herein to have values in the range of 1-10, or 2-9, or 3-8, it is also envisioned that Parameter X can have other ranges of values including 1-9, 1-8, 1-3, 1-2, 2-10, 2-8, 2-3, 3-10, 3-9, and so on.
[0026] When an element or layer is referred to as being “on,” “engaged to,” “connected to,” or “coupled to” another element or layer, it can be directly on, engaged, connected, or coupled to the other element or layer, or intervening elements or layers can be present. In contrast, when an element is referred to as being “directly on,” “directly engaged to,” “directly connected to” or “directly coupled to” another element or layer, there can be no intervening elements or layers present. Other words used to describe the relationship between elements should be interpreted in a like fashion (e.g., “between” versus “directly between,” “adjacent” versus “directly adjacent,” etc.). As used herein, the term “and/or” includes any and all combinations of one or more of the associated listed items.
[0027] Although the terms first, second, third, etc. can be used herein to describe various elements, components, regions, layers and/or sections, these elements, components, regions, layers and/or sections should not be limited by these terms. These terms can be only used to distinguish one element, component, region, layer or section from another region, layer, or section. Terms such as “first,” “second,” and other numerical terms when used herein do not imply a sequence or order unless clearly indicated by the context. Thus, a first element, component, region, layer, or section discussed below could be termed a second element, component, region, layer, or section without departing from the teachings of the example embodiments.
[0028] Spatially relative terms, such as “inner,” “outer,” “beneath,” “below,” “lower,” “above,” “upper,” and the like, can be used herein for ease of description to describe one element or feature’s relationship to another element(s) or feature(s) as illustrated in the figures. Spatially relative terms can be intended to encompass different orientations of the device in use or operation in addition to the orientation depicted in the figures. For example, if the device in the figures is turned over, elements described as “below”, or “beneath” other elements or features would then be oriented “above” the other elements or features. Thus, the example term “below” can encompass both an orientation of above and below. The device can be otherwise oriented (rotated 90 degrees or at other orientations) and the spatially relative descriptors used herein interpreted accordingly.
[0029] All documents, including patents, patent applications, and scientific literature cited in this detailed description are incorporated herein by reference, unless otherwise expressly indicated. Where any conflict or ambiguity can exist between a document incorporated by reference and this detailed description, the present detailed description controls.
[0030] With reference to
[0031] The humidifier 100 can include at least one humidifier plate 104 (shown in
[0032] An entirety of the plate main body 112, the top plate surface 114, and/or the bottom plate surface 116 can be formed from a meltable material. The meltable material can be configured to be pliable or moldable at a certain elevated temperature and solidify upon cooling. In particular, the meltable material can be configured to not substantially melt at room temperature or at a selected operating temperature of the humidifier. Desirably, this can allow the humidifier 100 to operate at room temperature or the selected temperature without melting. In certain examples, the room temperature can be about 68° to 72° degrees. In other examples, the selected operating temperature is the preferred ambient temperature that the humidifier 100 reaches while in operation. However, it should be appreciated that the room temperature or selected operating temperature may varying depending on different factors, such as the humidity, pressure, and/or other environmental factors.
[0033] The meltable material can be configured to partially melt at a predetermined temperature. The predetermined temperature can be a temperature that is not typically reached during normal operation of the humidifier 100. In certain examples, the predetermined temperature is greater than the room temperature or the selected operating temperature. When the meltable material partially melts and becomes at least partially liquid, the humidifier membrane 106 can be disposed on one of the humidifier plates 104, which can permit a portion of the meltable material of the humidifier plates 104 to permeate into the humidifier membrane 106. When the meltable material cools and solidifies, the humidifier membrane 106 can be trapped within the meltable material and sealed with one of the humidifier plates 104, as shown in
[0034] While still referring to
[0035] The meltable material of the humidifier plate 104 can include a thermoplastic material. The thermoplastic material can be configured to become pliable, moldable, and/or partially liquid at the predetermined temperature. Resistance of the meltable material to water and solvents is advantageous. The meltable material is further selected to be generally impermeable to gases, including water vapor. In certain examples, the thermoplastic material can include a hot melt adhesive. One of ordinary skill in the art may select suitable materials for the meltable material within the scope of the present disclosure.
[0036] Where the meltable material includes a hot melt adhesive, the hot melt adhesive can include one or more base materials along with one or more various additives. The composition can be formulated to have a glass transition temperature (onset of brittleness) below the lowest service temperature and a suitably high melt temperature as well. The degree of crystallization can be as high as possible but within limits of allowed shrinkage. The melt viscosity and the crystallization rate (and corresponding open time) can be tailored for the application. Faster crystallization rate usually implies higher bond strength. To reach the properties of semicrystalline polymers, amorphous polymers can require molecular weights too high and, therefore, unreasonably high melt viscosity; the use of amorphous polymers as the hot melt adhesive can be limited to function as one or more modifiers. Certain polymers can be selected that can form hydrogen bonds between their chains, forming pseudo-cross-links which strengthen the polymer.
[0037] The meltable material can be formulated using amounts of base materials and additives that are tailored to provide increased tackiness and influence the nature of mutual molecular interactions, as well as interactions with the humidifier membrane 106 substrate. In certain embodiments, one or more ethylene vinyl acetate (EVA) copolymers can be used as base materials with one or more terpene-phenol resins (TPR) as tackifier additives. Further examples include meltable materials including ethylene-vinyl acetate (EVA) copolymers with one or more tackifier resins, waxes, and stabilizers.
[0038] Certain embodiments of the meltable material can include one or more of: polyolefins (PO) including polyethylene (LDPE, HDPE), atactic polypropylene (PP or APP), polybutene-1, oxidized polyethylene; amorphous polyolefin (APO/APAO) polymers including amorphous (atactic) propylene (APP), amorphous propylene/ethylene (APE), amorphous propylene/butene (APB), amorphous propylene/hexene (APH), amorphous propylene/ethylene/butene; polyamides; polyesters; polyurethanes, including thermoplastic polyurethane (TPU); styrene block copolymers (SBC) including styrene-butadiene-styrene (SBS), styrene-isoprene-styrene (SIS), styrene-ethylene/butylene-styrene (SEBS), and styrene-ethylene/propylene (SEP); polycaprolactone with soy protein, using coconut oil as plasticizer; polycarbonates; fluoropolymers along with tackifiers and ethylene copolymer with polar groups; and silicone rubbers.
[0039] Certain embodiments of the meltable material can include one or more of the following additives: tackifying resins (e.g., rosins and their derivates, terpenes and modified terpenes, aliphatic, cycloaliphatic and aromatic resins (C5 aliphatic resins, C9 aromatic resins, and C5/C9 aliphatic/aromatic resins), hydrogenated hydrocarbon resins, and their mixtures, terpene-phenol resins (TPR, used often with EVAs)); waxes, e.g., microcrystalline waxes, fatty amide waxes or oxidized Fischer-Tropsch waxes; plasticizers (e.g., benzoates such as 1,4-cyclohexane dimethanol dibenzoate, glyceryl tribenzoate, or pentaerythritol tetrabenzoate, phthalates, paraffin oils, polyisobutylene, chlorinated paraffins, etc.); antioxidants and stabilizers (e.g., hindered phenols, BHT, phosphites, phosphates, hindered aromatic amines); added in small amounts (<1%), not influencing physical properties; biocide for hindering bacterial growth; flame retardants; antistatic agents; and fillers.
[0040] Now referencing
[0041] With reference to
[0042] With reference to
[0043] Now referencing
[0044] The lattice 136, due to the lattice apertures 140, can minimize an amount of material needed to form a humidifier plate 104. It is possible to forgo the lattice apertures 140 and connecting bridges 142 and have a solid and continuous support (not shown) for the spacers 144. Otherwise, with the lattice apertures 140, a solid layer or film (not shown) can be used to seal and enclose the plurality of lattice apertures 140 of the lattices 136 of the plates 104 on the outside thereof.
[0045] With reference to
[0046] While still referring to
[0047] The first humidifier plate 108 and the second humidifier plate 110, for example, can each be substantially identical, as per the first humidifier plate shown in
[0048] The humidifier membrane 106 can be configured to allow the wet fluid stream to humidify the dry fluid stream before the dry fluid stream is sent to the fuel cell stack 102. The humidifier membrane 106 can include a plurality of humidifier membranes 106. Each of the humidifier membranes 106 can have a membrane main body 150 with a top membrane surface 152 and a bottom membrane surface 154. Each of the humidifier membranes 106 can be configured to be disposed between one of the humidifier plates 104 and another one of the humidifier plates 104. For example, the bottom membrane surface 154 of the humidifier membrane 106 can be disposed on the top plate surface 114 of the first humidifier plate 108 and the top plate surface 114′ of the second humidifier plate 110 can be disposed on the top membrane surface 152 of the humidifier membrane 106, as shown in
[0049] In this manner, there can be one or more instances of a humidifier membrane 106 disposed between two humidifier plates 104. Each humidifier membrane 106 disposed between two humidifier plates 104 can be referred to as a plate-membrane-plate sandwich or humidifier unit 156. A stack (not shown) can be formed of such plate-membrane-plate sandwiches or humidifier units 156. Whether one humidifier unit 156 is formed, or a stack of plate-membrane-plate sandwiches are formed, solid layers or films (not shown) can be used to seal and enclose the plurality of lattice apertures 140 of the lattices 136 of the plates 104 on the outside of each sandwich.
[0050] The humidifier membrane 106 can be configured to be a water vapor permeable membrane. This can allow heat and/or water vapor from the wet fluid stream to pass through the humidifier membrane 106 to humidify the dry fluid stream before it can be sent to the fuel cell stack 102. For example, where the humidifier membrane 106 is disposed between the first humidifier plate 108 and the second humidifier plate 110 and between the wet fluid stream and the dry fluid stream, the humidifier membrane 106 can permit heat and/or water vapor from the wet fluid stream to pass through the humidifier membrane 106 to humidify the dry fluid stream. Desirably, this can allow the heat and/or water vapor from the wet fluid stream to humidify the dry fluid stream before it can be sent to the fuel cell stack 102. In certain examples, the humidifier membrane is similar and/or identical to the humidifier membrane 106 described in U.S. Pat. No. 8,091,868 to Robb et al., the entire disclosure of which is incorporated herein by reference. Certain embodiments of the humidifier membrane 106 can include expanded polytetrafluoroethylene (ePTFE). Other non-limiting examples can include humidifier membranes 106 formed from any conventional membrane including perfluorosulfonic acid (PFSA), such as the membrane sold under the trademark Nafion®, a hydrophilic polymer membrane, a hydrocarbon-based membrane, and a polymer composite membrane, for example. However, it should be appreciated that a skilled artisan can employ different technologies for the humidifier membrane 106, within the scope of this disclosure.
[0051] In certain examples, the header apertures 118 can all be aligned, and the dry fluid stream across each humidifier unit 156 in one direction and the wet fluid stream across each plate-membrane-plate sandwich in another direction, where the wet fluid stream and dry fluid stream exchange humidity. The stack of humidifier units 156 can therefore provide large surface area for humidity exchange (essentially the sum of all the membrane areas).
[0052] As shown in
[0053] With reference to
[0054] Now referring to
[0055] With reference to
[0056] Advantageously, the humidifier 100 and methods 200, 300 provided by the present technology may not require maintaining a sufficient compression force. For example, the meltable material can allow the humidifier plates 104 and the humidifier membrane 106 to be joined together without requiring a compression and retention system. Desirably, by not requiring a compression and retention system, the humidifier 100 and methods 200, 300 can reduce processing time, costs, and may not add additional thickness to the humidifier 100.
[0057] Example embodiments are provided so that this disclosure will be thorough, and will fully convey the scope to those who are skilled in the art. Numerous specific details are set forth such as examples of specific components, devices, and methods, to provide a thorough understanding of embodiments of the present disclosure. It will be apparent to those skilled in the art that specific details need not be employed, that example embodiments can be embodied in many different forms, and that neither should be construed to limit the scope of the disclosure. In some example embodiments, well-known processes, well-known device structures, and well-known technologies are not described in detail. Equivalent changes, modifications and variations of some embodiments, materials, compositions, and methods can be made within the scope of the present technology, with substantially similar results.