Determination of fluid parameters
11226300 · 2022-01-18
Assignee
Inventors
Cpc classification
G01N25/20
PHYSICS
International classification
G01N25/20
PHYSICS
Abstract
A method for determining fluid parameters, such as a heat capacity c.sub.Pρ, a calorific value Hp, a methane number MN, and/or a Wobbe index WI, of an unknown fluid (g). An unknown flow (55) of the fluid (g) is set in a sensor device (10), the sensor device (10) comprising a thermal flow sensor (1) and a pressure sensor device (15) for measuring at least one temperature value T.sub.1, T.sub.2, a further parameter, and differential pressure value Δρ over a flow restrictor (14). Using these measurement parameters T.sub.1, T.sub.2, Δρ and calibration data, the calorific value Hp, and/or the Wobbe index WI, or parameters indicative thereof, of an unknown fluid (g) are calculated. The invention also relates to such a sensor device (10) and to a computer program product for carrying out such a method.
Claims
1. A method for determining a characteristic parameter of a fluid, said fluid flowing in a fluid flow through a sensor device, the sensor device comprising: a thermal flow sensor device with a heater element and at least one temperature sensor, a flow restrictor arranged between first and second positions in said fluid flow, and a pressure sensor device for determining a pressure difference in the fluid between said first and second positions, the method comprising: (i) establishing the fluid flow with an unknown value through said sensor device with at least part of the fluid overflowing said thermal flow sensor; (ii) activating the heating element of said thermal flow sensor and measuring at least one first temperature with said at least one temperature sensor and at least one second temperature; (iii) measuring first and second absolute pressures in the fluid at the first and second positions, respectively, or measuring a differential pressure in the fluid between the first and second positions with said pressure sensor device; and (iv) determining from the measured first and second temperatures and calibration data a heat conductivity of said fluid of the fluid; (v) determining from the measured first and second temperatures, the measured pressure value(s) and calibration data a microscopic force of the fluid; (vi) determining from said heat conductivity and microscopic force said characteristic parameter of the fluid with correlation functions, the characteristic parameter being selected from the group consisting of the heat capacity, the calorific value and a parameter indicative thereof, the methane number, and the Wobbe index and a parameter indicative thereof.
2. The method according to claim 1, wherein the thermal flow sensor device comprises first and second temperature sensors for determining the first and second temperatures, wherein the heater element is arranged between said first and second temperature sensors.
3. The method according to claim 2, wherein the microscopic force is determined by rescaling at least part of the relevant calibration data prior to interpolation or wherein the measurement of the fluid is performed at several fluid flow values and the determined fluid parameter averaged.
4. The method according to claim 1, wherein the calibration data comprises first calibration data and second calibration data, the first and second calibration data comprising first and second temperatures and the pressure value(s) for at least one calibration fluid, wherein the first and second calibration data is stored in at least one lookup table, and wherein said heat conductivity and said microscopic force are determined by interpolation of the respective calibration data.
5. The method according to claim 4, wherein the first calibration data comprise the heat conductivity of the at least one calibration fluid and the second calibration data comprise the microscopic force of the at least one calibration fluid.
6. The method according to claim 1, wherein the correlation functions are based on a quadratic Ansatz.
7. The method according to claim 1, further comprising: (vii) determining a volume flow of the fluid flow of the fluid from the heat capacity and the heat conductivity determined previously.
8. The method according to claim 7, further comprising: (viii) determining an energy transfer per time unit from the volume flow and the calorific value of the fluid.
9. The method according to claim 1, further comprising: (ix) outputting the heat capacity, the calorific value, the Wobbe index, the methane number, an energy transfer determined from the volume fluid and the calorific value of the fluid, or a parameter indicative of any one thereof.
10. The method according to claim 1, wherein the fluid or the at least one calibration fluid is a burnable gas or a mixture thereof, or a natural gas or a mixture thereof.
11. The method according to claim 1, wherein first calibration data and second calibration data comprise first and second temperatures and the pressure value(s) for at two calibration fluids, wherein the first and second calibration data is stored in at least one lookup table, and wherein said heat conductivity and said microscopic force are determined by interpolation of the respective calibration data.
12. A sensor device for measuring a characteristic parameter selected from the group consisting of a heat capacity, a calorific value, a methane number, and a Wobbe index of a fluid, or a parameter indicative of any one thereof, the sensor device comprising: a flow channel for the fluid, the flow channel having an inlet and an outlet for the fluid, a thermal flow sensor device with a heater element and two temperature sensors and the heater element arranged therebetween, a flow restrictor arranged between first and second positions in said flow channel, at least one pressure sensor device for determining a pressure difference in the fluid between said first and second positions, and a digital control circuit comprising a memory, wherein the digital control circuit is configured to carry out a method comprising: (i) establishing the fluid flow with an unknown value through said sensor device with at least part of the fluid overflowing said thermal flow sensor; (ii) activating the heating element of said thermal flow sensor and measuring at least one first temperature with said at least one temperature sensor and at least one second temperature; (iii) measuring first and second absolute pressures in the fluid at the first and second positions, respectively, or measuring a differential pressure in the fluid between the first and second positions with said pressure sensor device; and (iv) determining from the measured first and second temperatures and calibration data a heat conductivity of said fluid of the fluid; (v) determining from the measured first and second temperatures, the measured pressure value(s) and calibration data a microscopic force of the fluid; (vi) determining from said heat conductivity and microscopic force said characteristic parameter of the fluid with correlation functions, the characteristic parameter being selected from the group consisting of the heat capacity, the calorific value and a parameter indicative thereof, the methane number, and the Wobbe index and a parameter indicative thereof.
13. The sensor device according to claim 12, wherein a memory is configured to store first and second calibration data, and wherein the digital control circuit is configured to retrieve the first and second calibration data from said memory and to determine the characteristic parameter.
14. The sensor device according to the claim 12, wherein the thermal flow sensor device is a CMOS flow sensor device.
15. The sensor device according to claim 13, wherein the correlations functions are stored in said memory.
16. The sensor device according to claim 13, wherein the digital control circuit is configured to determine the heat capacity, the calorific value or the parameter indicative thereof, the methane number or the parameter indicative thereof, or a Wobbe index or the parameter indicative thereof, of the fluid with said correlation functions.
17. A non-transitory computer usable memory medium having a computer readable program code embodied therein for execution by a digital control circuit of a sensor device, said sensor device comprising: a flow channel for the fluid, the flow channel having an inlet and an outlet for the fluid, a thermal flow sensor device with a heater element and two temperature sensors and the heater element arranged therebetween, a flow restrictor arranged between first and second positions in said flow channel, at least one pressure sensor device for determining a pressure difference in the fluid between said first and second positions, wherein, when executed by the digital control circuit, the program code implements a method comprising: (i) establishing the fluid flow with an unknown value through said sensor device with at least part of the fluid overflowing said thermal flow sensor; (ii) activating the heating element of said thermal flow sensor and measuring at least one first temperature with said at least one temperature sensor and at least one second temperature; (iii) measuring first and second absolute pressures in the fluid at the first and second positions, respectively, or measuring a differential pressure in the fluid between the first and second positions with said pressure sensor device; and (iv) determining from the measured first and second temperatures and calibration data a heat conductivity of said fluid of the fluid; (v) determining from the measured first and second temperatures, the measured pressure value(s) and calibration data a microscopic force of the fluid; (vi) determining from said heat conductivity and microscopic force said characteristic parameter of the fluid with correlation functions, the characteristic parameter being selected from the group consisting of the heat capacity, the calorific value and a parameter indicative thereof, the methane number, and the Wobbe index and a parameter indicative thereof.
18. A method for determining a characteristic parameter of a fluid, said fluid flowing in a fluid flow through a sensor device, the sensor device comprising: a thermal flow sensor device with a heater element and at least one temperature sensor, a flow restrictor arranged between first and second positions in said fluid flow, and a pressure sensor device for determining a pressure difference in the fluid between said first and second positions, the method comprising: (i) establishing the fluid flow with an unknown value through said sensor device with at least part of the fluid overflowing said thermal flow sensor; (ii) activating the heating element of said thermal flow sensor and measuring at least one first temperature with said at least one temperature sensor and at least one second temperature; (iii) measuring first and second absolute pressures in the fluid at the first and second positions, respectively, or measuring a differential pressure in the fluid between the first and second positions with said pressure sensor device; and (iv) determining from the measured first and second temperatures and calibration data a heat conductivity of said fluid of the fluid; (v) determining from the measured first and second temperatures, the measured pressure value(s) and calibration data a microscopic force of the fluid, wherein the microscopic force of the fluid is given by
ξ=η.sup.2/(ρPr.sup.2α), with η being the dynamic viscosity, ρ the density, and Pr the Prandtl number Pr=c.sub.Pη/λ, where c.sub.P is the specific heat and λ the heat conductivity of the fluid, and parameter α being a real number in the range fluid 0≤α≤1; (vi) determining from said heat conductivity and microscopic force said characteristic parameter of the fluid with correlation functions, the characteristic parameter being selected from the group consisting of the heat capacity, the calorific value and a parameter indicative thereof, the methane number, and the Wobbe index and a parameter indicative thereof.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) Preferred embodiments of the invention are described in the following with reference to the drawings, which are for the purpose of illustrating the present preferred embodiments of the invention and not for the purpose of limiting the same. In the drawings,
(2)
(3)
(4)
(5)
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(7)
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(9)
DESCRIPTION OF PREFERRED EMBODIMENTS
(10)
(11) The first temperature sensor 2 measures a first temperature T.sub.1, the second temperature sensor 4 a second temperature T.sub.2. In the present embodiment, the temperature sensors 2, 4 are thermopiles; in other embodiments, the temperature sensors 2, 4 may be of a different type, e.g. resistive temperature sensors. Typically, the heater element 3's working principle is based on the Joule heating effect, i.e. the heater element 3 is a resistive heater.
(12) The temperature of the heater element 3 is generally stabilized above a temperature of the substrate 6. As a fluid g overflows the heater 3, heat energy is transported from the heater element 3 to the second temperature sensor 4. Accordingly, the second T.sub.2 is higher than the first T.sub.1. The temperature difference T.sub.2−T.sub.1 (or, equivalently, the ratio of these temperatures) depends, inter alia, on the fluid flow 5 and on the heat transfer properties of the fluid g, in particular, on its heat conductivity and heat capacity.
(13) This type of flow sensor 1 is described, e.g., in WO 01/98736 A1 and U.S. Pat. No. 7,188,519 B2; the disclosure of these documents is incorporated herein by reference in its entirety for teaching the setup of the flow sensor device 1.
(14)
(15) The first by-pass channel 11 carries a by-pass flow 5. In the first by-pass channel 11, said thermal flow sensor 1 is arranged for measuring the fluid g conveyed through the sensor device 10. Flow meter 1 is preferably a wall-mounted sensor device. The thermal flow sensor 1 is integrated to the sensor device 10, e.g., with conventional circuitry 209 (e.g. analog amplifiers, an A/D-converter, and/or digital signal processors).
(16) A second by-pass channel 13 is provided between the first and second positions 18, 19. In said second by-pass channel 13, a differential pressure sensor device 15 is arranged. No fluid flow is established in said second by-pass channel 13, wherein, in the first by-pass channel 11, fluid g may flow without being noticeably disturbed by the thermal flow sensor 1.
(17) In the main-pass channel 12 is arranged, between the first and second positions 18, 19, a laminar flow restrictor 14. The flow restrictor 14 established a pressure drop Δp in the fluid g between the first and the second positions 18, 19.
(18) Accordingly, with the differential pressure sensor device 15, the pressure difference Δp in the fluid g between positions 18, 19 and the two fluid temperatures T.sub.1 and T.sub.2 at positions 18 and 19, respectively, may be measured.
(19) An alternative embodiment of the sensor device 10 is depicted in
(20) It is to be understood that other designs of the sensor device 10 may be used. For example, the flow meter device 1 may be arranged directly in the main flow 55.
(21) In the following, a preferred method of determining a calorific value of the unknown fluid g, in particular a natural gas (or a mixture of such gases), based on the data set Δp, T.sub.1 and T.sub.2 and calibration data LTU1-LUT4 is described.
(22) The heat conductivity λ and the microscopic force ξ of the fluid g may be determined experimentally. Generally, the microscopic force ξ of the fluid g is given by
ξ=η.sup.2/(ρPr.sup.2α).
Here, the parameters of the fluid g are the following: η is the dynamic viscosity, ρ denotes the density, and Pr is the so-called Prandtl number Pr=c.sub.Pη/λ, where c.sub.P is the specific heat and λ heat conductivity of the fluid g. Parameter α is a real number in the range fluid 0≤α≤1. Typically, the sensor device 10 is operated at temperature of −40° C. to 150° C. and at pressures of 0.01 MPa to 1 MPa.
(23) Now, in a first step, the heat conductivity λ of the fluid g may be determined from the two independent temperature T.sub.1 and T.sub.2 signals obtained by means of the thermal flow sensor 1. The T.sub.1 and T.sub.2 signals depend on the flow velocity ν of the fluid g and on physical parameters of the fluid g as follows:
T.sub.i=F.sub.i(c.sub.Pρν/λ,λ,Pr) with i=1,2. (1)
(24) The functions F.sub.i(c.sub.Pρξ/λ, λ, Pr) in Eq. (1) depend on the details of the measurement setup (e.g. the geometry of the main-pass/by-pass channel system, flow restrictors . . . ) as well as on the design and location of thermal flow sensor 1 in the by-pass channel 11. The functional dependence of Eq. (1) follows from the heat equation.
(25) Generally, the heat conductivity λ of the fluid g is given as:
λ=f(T.sub.1,T.sub.2). (2)
(26) The function f(T.sub.1, T.sub.2) in Eq. (2) can be determined, for example, through calibration measurements.
(27) Let Θ.sub.1=T.sub.2−T.sub.1 and Θ.sub.2=T.sub.1+T.sub.2. It is noted that, in other embodiments, other linear combinations of T.sub.1 and T.sub.2 signals may be used.
(28) Two calibration gases g.sub.1 and g.sub.2 with known heat conductivities λ.sup.g1 and λ.sup.g2, respectively, may be measured in calibration measurements. One sends both fluids g.sub.1 and g.sub.2, one at a time, through the sensor device 10 and varies the volume flow Q in the relevant flow range to determine the curves or sets of value pairs Θ.sub.2.sup.g1(Θ.sub.1.sup.g1) for fluid g.sub.1 and Θ.sub.2.sup.g2(Θ.sub.1.sup.g2) for fluid g.sub.2.
(29) By measurement of the fluid g, one determines its heat conductivity λ by means of linear interpolation of the Θ.sub.2 signal while keeping the Θ.sub.1 signal constant:
λ=xλ.sup.g1+(1−x)λ.sup.g2, (3)
with
x=[Θ.sub.2−Θ.sub.2.sup.g2(Θ.sub.1)]/[Θ.sub.2.sup.g1(Θ.sub.1)−Θ.sub.2.sup.g2(Θ.sub.1)]. (4)
(30) Instead of using two calibration fluids g.sub.1 and g.sub.2 one may also use master data and calibration data from only one calibration fluid. In this case, the thermal conductivity is determined from the relation λ=λ.sup.g1+m(Θ.sub.1)[Θ.sub.2−Θ.sub.2.sup.g1(Θ.sub.1)], where the slope m(Θ.sub.1) was determined beforehand by averaging calibration data (with two calibration gases) of many sensors. Said slope may be the master data.
(31) Preferably, the data is averaged over a plurality of single measurements. The single measurements may be performed at different values for the fluid flow Q.
(32)
ξ=g(Θ.sub.1,Θ.sub.2,Δp). (5)
(33) By means of the pressure sensor device 15 or 16, 17 the differential pressure Δp is measured. The differential pressure Δp depends on the flow velocity ξ as well as on the physical parameter η and ρ of the flowing fluid g as follows:
ξ=η.sup.2/ρ*H(ρν/η), (6)
wherein the function H(ρξ/η) depends on the details of the measurement setup (e.g. the geometry of the main-pass/by-pass channel system, flow restrictors . . . ). The functional dependence of Eq. (6) on the fluid parameters follows from the similarity transformation of the Navier-Stokes equations for incompressible fluids.
(34) The function g(Θ.sub.1, Θ.sub.2, Δp) may be determined by means of calibration measurements. Let Θ.sub.1=T.sub.2−T.sub.1 and Θ.sub.2=T.sub.1+T.sub.2. Again, it is possible to use other linear combinations of the T.sub.1 and T.sub.2 signals.
(35) For the calibration measurements, the two calibration gases g.sub.1 and g.sub.2 are used again, wherein the microscopic force parameters ξ.sup.g1 and ξ.sup.g2 of both gases g.sub.1 and g.sub.2 are known. During the calibration measurements, the fluid flow Q is varied in the relevant flow range, i.e. in the range the sensor device 10 shall operate with fluid g, and the two independent T.sub.1 and T.sub.2 signals obtained by means of the thermal flow sensor 1 and the differential pressure Δp is obtained by means of the pressure sensor device 15 or 16, 17. From these data, the two curves or sets of value pairs Δp.sup.g1(Θ.sub.1.sup.g1) for the first calibration gas g.sub.1 and Δp.sup.g2(Θ.sub.1.sup.g2) for the second calibration gas g.sub.2 are determined.
(36) During use, the gas g is measured by means of the thermal flow sensor 1 and the pressure sensor device 15 or 16, 17. From the thermal flow sensor Θ.sub.1 and Θ.sub.2 are obtained. On the basis of the Θ.sub.1 and Θ.sub.2 data, rescaled parameters Θ.sub.1′ and Θ.sub.1″ are calculated.
(37) Θ.sub.1′ and Θ.sub.1″ are the rescaled Θ.sub.1 parameters which are chosen such that the heat conductivity value λ corresponds to the heat conductivity values λ.sup.g1 and λ.sup.g2 of the calibration gases g.sub.1 and g.sub.2, respectively. Accordingly, Θ.sub.1=F.sub.1(c.sub.Pρξ/λ, λPr).fwdarw.Θ.sub.1′=F.sub.1(c.sub.Pρξ/λ, λ.sup.g1, Pr) and Θ.sub.1=F.sub.1(c.sub.Pρξ/λ, λ, Pr).fwdarw.Θ.sub.1″=F.sub.1(c.sub.Pρξ/λ, λ.sup.g2, Pr). In this way, the explicit dependency of the Θ.sub.1 and Θ.sub.2 data on λ is removed.
(38) Then, the microscopic force ξ is given by the linear interpolation formula:
ξ=wξ.sup.g1+(1−w)ξ.sup.g2 (7)
with
w=[Δp−Δp.sup.g2(Θ.sub.1″)]/[Δp.sup.g1(Θ.sub.1′)−Δp.sup.g2(Θ.sub.1″)]. (8)
(39) The rescaled sensor signals Θ.sub.1′ and Θ.sub.1″ in Eq. (8) may be determined as follows. By means of Eqs. (3, 4), one first determines the heat conductivity λ of the unknown gas g as outlined above. If said heat conductivity λ is close enough to λ.sup.g1 and λ.sup.g2 the Θ.sub.1 sensor signal may be linearized in parameter λ as follows:
Θ.sub.1=uΘ.sub.1.sup.g1(ϕ)+(1−u)Θ.sub.1.sup.g2(ϕ) (9)
with
u=(λ−λ.sup.g2)/(λ.sup.g1−λ.sup.g2). (10)
Here, ϕ=c.sub.Pρξ/λ. Said heat conductivity λ being “close enough” to λ.sup.g1 and λ.sup.g2 means that λ is in the range with a lower bound of 50% to 125%, preferably 80% to 100% of the smaller of λ.sup.g1 and with an upper bound of 100% to 150%, preferably 125% of the larger of λ.sup.g1 and λ.sup.g2, preferably it means that λ.sup.g1≤λ≤λ.sup.g2, wherein λ.sup.g1 and λ.sup.g2 differ by not more than 20% of the larger one of both.
(40) For given sensor signals Θ.sub.1 and Θ.sub.2, Eq. (9) implicitly defines the parameter ϕ=ϕ(Θ.sub.1, Θ.sub.2). From said parameter ϕ one can calculate the rescaled sensor signals Θ.sub.1′=Θ.sub.1.sup.g1(ϕ(Θ.sub.1, Θ.sub.2)) and Θ.sub.1″=Θ.sub.1.sup.g2(ϕ(Θ.sub.1, Θ.sub.2)).
(41) Preferably, the data is averaged over a plurality of single measurements. The single measurements may be performed at different values for the fluid flow Q.
(42)
(43) If one uses master data, ϕ(Θ.sub.1, Θ.sub.2) may be determined by measurement of one calibration gas only. In this case, Eq. (9) may be replaced by Θ.sub.1=[1+q(ϕ)(λ−λ.sup.g1)]Θ.sub.1.sup.g1(ϕ) where the slope q(ϕ) has been determined beforehand by averaging over the calibration data (with at least two calibration gases) of many sensors. Said slope may be used as master data.
(44) This method may be used for providing, e.g., an energy meter, e.g., for burnable gases such as natural gases. Generally, an energy meter determines a volume flow and the energy specific parameters such as calorific value Hρ or Wobbe index WI (in energy per volume) of an unknown burnable gas.
(45) Accordingly, the sensor device 10 may be configured for measuring T.sub.1, T.sub.2 and Δp of the fluid g. Moreover, fluid measurement device may comprise a digital control circuit 20 configured for carrying out the method as outlined above.
(46)
(47) Via a data interface 207, the processor 201 communicates with various peripherals, including the thermal flow sensor 1, the differential pressure sensor device 15 (or, in the embodiment according to
(48)
(49) Moreover, by means of the heat capacity c.sub.Pρ and heat conductivity λ the volume flow Q of the unknown gas g may be determined using the equation above. In combination with the calorific value Hρ one can obtain the energy transport per time unit.
(50) The correlation functions between the fluid parameters may be found by regression analysis. One may analyze e.g. a large data set containing physical properties of burnable gases or mixtures thereof. Such data sets are publicly available, e.g. in the report “Report on gas composition range in Europe” (available under http://www.ingas-eu.org/docs/DB0.1.pdf).
(51) Moreover, if the composition of the burnable gas, in particular the natural gas is known, physical parameters relevant here may be calculated by means of commercially available programs such as Refprop NIST (available under http://www.nist.gov/srd/nist23.cfm) or PPDS (available under http://www.tuv-sud.co.uk/uk-en/about-tuev-sued/tuev-sued-in-the-uk/nel/ppds-thermodynamic-properties-suite).
(52) The correlations functions for a quadratic Ansatz may be written as:
c.sub.Pρ=A.sub.1+B.sub.1λ+C.sub.1λ.sup.2+D.sub.1ξ+E.sub.1ξ.sup.2+F.sub.1λξ
Hρ=A.sub.2+B.sub.2λ+C.sub.2λ.sup.2+D.sub.2ξ+E.sub.2ξ.sup.2+F.sub.2λξ
WI=A.sub.3+B.sub.3λ+C.sub.3λ.sup.2+D.sub.3ξ+E.sub.3ξ.sup.2+F.sub.3λξ (11)
Using the least squares method, one may obtain the coefficients A.sub.i to F.sub.i, i=1 to 3. The following set of coefficients was found (Tab. 1):
(53) TABLE-US-00001 α = 0.7 A.sub.i B.sub.i C.sub.i D.sub.i E.sub.i F.sub.i c.sub.Pρ [kJ/(Km.sup.3)], 2.792 −0.156 0.026 −1.869 0.616 0.047 i = 1 Hρ [MJ/m.sup.3], −59.26 352.80 −188.44 −162.98 28.51 65.34 i = 2 WI [MJ/Sm.sup.3], −142.46 528.28 −223.47 −190.63 44.90 36.71 i = 3
Here, the coefficients A.sub.i to F.sub.i, i=1 to 3 are normalized such that the heat conductivity λ an the microscopic force ξ are given with reference to the heat conductivity λ an the microscopic force ξ of methane. For the calculation of ξ the value α=0.7 was used.
(54) The standard deviation of the relative error of the fit using the coefficients A.sub.i to F.sub.i, i=1 to 3 of Tab. 1 was found to be 0.28% for c.sub.Pρ, 0.15% for Hρ, and 0.43% for WI.
(55) An illustrative set of exemplary values is given in Tabs. 2, 3, 4, wherein all values are calculated at temperature T=25° C. and pressured p=0.1 MPa.
(56) Theoretical values as calculated by said commercially available programs (Tab. 2):
(57) TABLE-US-00002 λ ξ (α = 0.7) c.sub.Pρ Hρ WI [mW/(Km)] [nN] [kJ/(Km.sup.3)] [MJ/m.sup.3] [MJ/(Sm.sup.3)] methane 34.82 306.0 1.452 35.99 53.45 gas 1 32.04 260.1 1.557 39.08 53.82 gas 2 32.76 302.9 1.465 33.36 46.29
wherein gas 1 and gas 2 have the following compositions (Tab. 3):
(58) TABLE-US-00003 methane nitrogen ethane propane carbon dioxide gas 1 85.9% 1.0% 8.5% 3.1% 1.5% gas 2 84.4% 10.4% 2.6% 1.5% 1.1%
Values calculated by means of correlation function, i.e. Eqs. (11) (Tab. 4):
(59) TABLE-US-00004 c.sub.Pρ corr Hρ corr WI corr [kJ/(Km.sup.3)] [MJ/m.sup.3] [MJ/(Sm.sup.3)] methane 1.456 35.97 53.33 gas 1 1.563 38.99 53.55 gas 2 1.466 33.32 46.24
(60) From the Wobbe index one may determine the methane number MN.
(61) Accordingly, the present invention provides a small, inexpensive sensor element 10 and an inexpensive method which may be used for determining fluid parameters, wherein a pressure drop over the flow restrictor of maximum 2 millibars, as required by the relevant norm, is complied with.
(62) TABLE-US-00005 LIST OF REFERENCE SIGNS 1 thermal flow sensor device 2 first temperature sensor on 1 3 heater element on 1 4 second temperature sensor on 1 5 by-pass flow of fluid g 6 substrate of 1 7 membrane on 6 8 recess in 6 10 sensor device 11 first by-pass channel 12 main-pass channel 13 second by-pass channel 14 flow restrictor in 12 15 differential pressure sensor device 16, 17 absolute pressure sensor device 18 first position 19 second position 20 control circuit 201 processor unit 202 non-volatile memory 203, 204 sets of calibration data 205 machine-executable program 206 volatile memory 207 data interface 208 user interface 209 conventional circuitry 51 inlet for fluid g 52 outlet for fluid g 55 total fluid flow fluid g 701 flow establishing step 702 operating step 703 determining step 704, 705 retrieving step 706 calculating step 707 outputting step