Tunable spectral filters
11226503 · 2022-01-18
Assignee
Inventors
- Marc Currie (Washington, DC, US)
- Virginia D. Wheeler (Alexandria, VA, US)
- Guy Beadie (Falls Church, VA, US)
Cpc classification
G02F1/0102
PHYSICS
International classification
Abstract
A tunable spectral filter comprising a phase change material is incorporated into a multilayered dielectric structure. The dielectric permittivity, and thus the filter properties, of the structure can be modified by producing a change in the phase change material, e.g., causing a metal-insulator transition. By controllably causing such a change in the dielectric permittivity of the phase change material, the spectral transmittance and reflectance of the structure, and thus its filter properties, can be modified to provide a predetermined transmittance or reflectance of electromagnetic radiation incident on the structure. In preferred embodiments, the phase change material layer is a vanadium dioxide (VO.sub.2) film formed by atomic layer deposition (ALD).
Claims
1. A tunable spectral filter, comprising: a plurality of repeating stacks of dielectric material layers on a substrate, the substrate having an index of refraction n.sub.s that is lower than the index of refraction of any of the materials in the stack; wherein each of the repeating stacks includes at least one phase change material layer integrated therein, the phase change material layer being thinner than the other material layers in the stack and having an index of refraction that is higher than an index of refraction of any of the other materials in the stack; wherein a dielectric permittivity of the phase change material layer can be controllably changed to tune the filter so as to provide a predetermined amount of spectral transmittance and/or reflectance of light incident on the filter.
2. The tunable spectral filter according to claim 1, wherein each dielectric material layer has a thickness of between 0.1 and 1.0 times a wavelength of light incident on the filter and the phase change material layer has a thickness of 0.01 to 0.10 times the thickness of a single static dielectric layer, wherein the thickness of the dielectric material layers is configured to obtain a desired spectral reflectance and transmittance of the filter.
3. The tunable spectral filter according to claim 2, wherein the phase change material comprises ALD-VO.sub.2.
4. The tunable spectral filter according to claim 1, wherein each dielectric material layer in the stack has a thickness of 5-50 nm and the phase change material layer has a thickness of 2-10 nm.
5. The tunable spectral filter according to claim 1, wherein the dielectric materials in the stack comprise silicon dioxide, titanium dioxide, and vanadium dioxide.
6. The tunable spectral filter according to claim 1, wherein the phase change material comprises NbO.sub.2, GeTe, SmNiO.sub.3, Ti.sub.4O.sub.7, or VO.sub.2.
7. The tunable spectral filter according to claim 1, further comprising a plurality of low-index dielectric material layers and a plurality of high-index dielectric material layers, wherein a thickness of each low-index dielectric material layer is about 190 nm and a thickness of each high-index dielectric material layer is about 150 nm, and further wherein a thickness of the phase change material layer is about 40 nm, wherein the thicknesses of the low-index dielectric material layer, the high-index dielectric material layer, and the phase change material layer are configured to cause the filter to function as a tunable bandpass filter when the phase change material layer is tuned to a metallic state.
8. The tunable spectral filter according to claim 1, further comprising a plurality of low-index dielectric material layers and a plurality of high-index dielectric material layers, wherein a thickness of each low-index dielectric material layer is about 185 nm and a thickness of each high-index dielectric material layer is about 195 nm, and further wherein a thickness of the phase change material layer is about 6 nm, wherein the thicknesses of the low-index dielectric material layer, the high-index dielectric material layer, and the phase change material layer are configured to cause the filter to function as a tunable notch filter when the phase change material layer is controllably tuned to an insulating or a metallic state.
9. The tunable spectral filter according to claim 1, wherein the substrate is diamond.
10. The tunable spectral filter according to claim 1, wherein the substrate further comprises a membrane adjacent the last stack in the filter, wherein the membrane has an index of refraction that of approximately 2 and a thickness of 500 nm to reduce the lateral conductivity and facilitate heating of the filter.
11. The tunable spectral filter according to claim 1, wherein each stack comprises two dielectric materials and a phase change material.
12. The tunable spectral filter according to claim 1, wherein each stack comprises one dielectric material and one phase change material.
13. The tunable spectral filter according to claim 1, wherein the filter includes at least one stack having at least one repeating layer of the phase change material integrated therein.
14. The tunable spectral filter according to claim 1, wherein the substrate has a non-planar surface adjacent to the final stack in the filter, wherein the final stack conforms to a shape of the non-planar surface.
15. The tunable spectral filter according to claim 1, wherein the filter is released from the substrate to create a free-standing, flexible-film filter.
16. A tunable gradient-index filter, comprising: a plurality of repeating stacks of dielectric material layers on a substrate, the substrate having an index of refraction n.sub.s that is lower than the index of refraction of any of the materials in the stack; wherein each of the repeating stacks includes a plurality of high-index dielectric material layers, a plurality of low-index dielectric material layers, and at least one phase change material layer; wherein each of the high-index dielectric material layers, low-index dielectric material layers, and phase change material layer has a corresponding thickness less than one-quarter of a wavelength of an incident radiation of interest, the high-index dielectric material layers, low-index dielectric material layers, the thickness of the high-index dielectric material layers, the low-index dielectric material layers, and the phase change material layer in a first stack varying in a non-periodic manner from the corresponding thicknesses in a second stack to enable an almost continuously varying refractive index in the filter.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION
(7) The aspects and features of the present invention summarized above can be embodied in various forms. The following description shows, by way of illustration, combinations and configurations in which the aspects and features can be put into practice. It is understood that the described aspects, features, and/or embodiments are merely examples, and that one skilled in the art may utilize other aspects, features, and/or embodiments or make structural and functional modifications without departing from the scope of the present disclosure.
(8) The present invention provides a tunable spectral filter comprising a phase change material incorporated into a multilayered dielectric structure. As described in more detail below, the dielectric permittivity, and thus the filter properties, of the structure can be modified by causing a metal-insulator transition in the phase change material. By controllably causing such a change in the dielectric permittivity of the phase change material, the transmittance and reflectance of the structure, and thus its filter properties, can be modified to provide a predetermined transmittance or reflectance of electromagnetic radiation incident on the structure.
(9) Some of these phase change materials are highly absorptive of light at most wavelengths, which has made them considered to be unsuitable for use in a multi-layered optical filter. However, while these phase change materials can be absorptive, these materials can also have a high refractive index whose magnitude can be modulated through their phase change. For example, as described above in the case of phase change materials such as VO.sub.2, the change in their dielectric properties, including their index of refraction, can be is very large when the materials undergo a phase change. Therefore, by embedding a very thin layer of these phase change materials within a period of a multilayer dielectric stack, a structure having negligible loss can be produced; by increasing the number of periods having an embedded phase change material in the stack, the total change in the refractive index of the stack upon a change in the material's phase can be amplified while maintaining the overall low absorption of the stack.
(10) The present invention therefore provides an improved multilayered filter structure which includes a phase change material as an integral part of the filter, wherein layers of the phase change material are distributed throughout the multilayered structure and wherein the filter properties of the multilayered structure can be tuned by tuning the dielectric permittivity of the phase change material, e.g., by changing the temperature of the filter, applying electric or magnetic fields, or by applying mechanical strain and/or pressure.
(11) Thus, in accordance with the present invention, a tunable spectral filter can be formed by modifying a conventional repeating high-index/low-index multilayered structure, wherein the high-index material layer is replaced by a layer of a lossless high-index material for the majority of the layer thickness coupled with an ultrathin layer of a phase change material having a refractive index similar to that of the high-index material. Since the phase change material is ultrathin, the loss due to absorption within the material is mitigated, while large changes in the optical properties of the stack can be produced by repeated layering of the high-index material/phase change material structure. Typical layer thicknesses are designed based upon the wavelength of light, such that a single material layer thickness is between 0.1 and 1.0 wavelengths thick, where the thickness is optimized for the desired spectral reflectance and transmittance of the filter. In our tunable filters, this allows the ultrathin phase change material to be approximately 0.01 to 0.10 times smaller than the thickness of a single static layer to achieve the desired tunability. Examples of static dielectric materials for use in optical filters are silicon, silicon oxides, silicon nitrides, calcium fluoride, magnesium fluoride, aluminum oxide, titanium oxide, zinc sulfide, zinc selenide, zinc telluride, etc. In other embodiments, if the phase change material has a low-enough refractive index, one could instead break the low-index layer into two parts (e.g., a thicker lossless part and an ultrathin phase change material part). This would allow integration with current design models, while enabling filter tunability of the filter through dynamic modifications of the phase change material.
(12) As noted above, vanadium oxide (VO.sub.2) is a phase change material that has been used in spectral filters, but due to its very high optical absorption has not previously been used as a layer in a repeating multilayer stack configuration such as that used in the present invention; instead, it has only been used as a single layer within a multilayered structure comprising other materials. See, e.g., Wang, supra, where a single VO.sub.2 layer serves as a defect layer in a Bragg filter formed by a stacked TiO.sub.2/SiO.sub.2 layered structure.
(13) Researchers at the U.S. Naval Research Laboratory (NRL), including some of the inventors of the present invention, have developed a growth technique that enables production of VO.sub.2 by atomic layer deposition (ALD) which produces higher quality ultrathin VO.sub.2 films (referred to herein as “ALD-VO.sub.2 films”) having lower loss than had been possible with VO.sub.2 films produced using conventional techniques. See Marc Currie et al., “Atomic Layer Deposition of Vanadium Dioxide and a Temperature-dependent Optical Model,” J. Vis. Exp. (135), e57103, doi:10.3791/57103 (2018).
(14) In addition, such ALD-VO.sub.2 films are more stable than those produced using conventional techniques, such that their metal-insulator transition can be gradually tuned so as to result in a gradual change in their dielectric properties. The dielectric properties of such ALD-VO.sub.2 films are stable even if the tuning is stopped at any point within the transition region. See M. Currie et al., “Characterizing the tunable refractive index of vanadium dioxide,” Opt. Mater. Express, vol. 7, no. 5, pp. 1697-1707 (2017). The transition temperature at which these ALD-VO.sub.2 films change between metal and insulator can be modified to occur anywhere between 20 and 80° C. by altering the material's crystallinity and strain (e.g., via doping) during the ALD process; this wide range of transition temperatures enables a wide variety of control over the phase change process.
(15) The low loss of these ALD-VO.sub.2 films enable a more significant change in dielectric properties upon phase transition, thereby, enabling a greater change in filter properties. This allows for either thinner layers of phase change materials (thereby reducing filter losses further) or layers with higher contrast (with lower-loss than other state of the art VO.sub.2 films).
(16) Thus, the present invention provides a tunable spectral filter that incorporates a phase change material into a layered dielectric structure. While at present it appears that ALD-VO.sub.2 films developed at NRL may be preferred because of their high-quality and low-loss one skilled in the art will recognize that high-quality, low-loss films made from other phase change materials using other techniques that may be developed will also be suitable for use in the tunable spectral filters described and claimed herein, and filters using all such phase change materials are deemed to be within the scope and spirit of the present disclosure.
(17) The dielectric properties of the phase change material in combination with a multilayer dielectric structure described above provide a unique avenue towards a wide array of applications.
(18) The block schematic in
(19) As illustrated in
(20) The transmittance and reflectance of these multilayered structures depends on the thickness and dielectric permittivity of each material. When the dielectric permittivity of the phase change material is changed, the index of refraction n.sub.3 of the phase change material will also be changed, and so the transmissive and reflective properties of the filter will be modified. Thus, by controllably modifying the dielectric permittivity of the phase change material in at least one of the layered stacks, e.g., by changing the temperature of the filter, applying electric or magnetic fields, or by applying mechanical strain and/or pressure to the phase change material, a spectral filter in accordance with the present invention can be tuned to provide predetermined filtering properties.
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(22) In the embodiment illustrated in
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(25) In still other embodiments, a tunable spectral filter in accordance with the present invention can include a multilayer structure on a non-planar substrate surface 240, as illustrated in
(26) A phase change material that undergoes a metal-insulator transition provides another unique capability for polarized optics. The change in the optical phase upon reflection are unequal for light polarized parallel and perpendicular to the plane of incidence with a metal. Thus, when changing from an insulator to a metal, these attributes enable difference passbands for different polarizations of light. This further enhances the capabilities of creating tunable optical filters from phase change materials with a metal-insulator transition.
(27) Other alternative designs could provide additional advantages for specific operations, and one skilled in the art will readily recognize that other configurations of multilayered dielectric structures including one or more phase change materials can be used to make spectral filters whose properties are tuned by controlling the phase change material in accordance with the present invention.
(28) To demonstrate the general concepts, devices having the design presented in
(29) In one case, a device having the structure according to
(30) The performance of this device is shown by the plot in
(31) As can be seen from the plot in
(32) The layered structure of
(33) The layered structure of
(34) To further examine the utility of using phase change materials for tunable filter elements, a tunable bandpass/bandstop filter near 2.8 μm wavelength was fabricated by incorporating a single 45 nm layer of VO.sub.2 into a dielectric layer structure disposed on a 500 nm-thick nanocrystalline diamond film. The performance of this structure is illustrated by the plots in
(35) In another case, a tunable short-pass reflecting filter (for use in separating reflected light in the visible range from transmitted light in the near-IR wavelength range) was fabricated from a single 30 nm-thick layer of VO.sub.2 on a 300 nm-thick SiO.sub.2 film, which in turn was on a Si substrate. The filter performance of this structure was examined, with the results being shown by the plots in
Alternatives
(36) Although a tunable spectral filter in accordance with the present invention has often been described in the context of using VO.sub.2 as the phase change material, one skilled in the art will readily understand that any volatile phase change material (e.g., NbO.sub.2, GeTe, SmNiO.sub.3, Ti.sub.4O.sub.7 etc.) can be used, so long the material's the dielectric properties change as the material changes phase.
(37) In some embodiments, a tunable spectral filter in accordance with the present invention can be configured to include high index layers, low index layers, and phase change layers with thinner-than-quarter-wavelength thickness increments, without a strict periodicity in thicknesses. Such a structure can enable an almost continuously varying refractive index (as a function of thickness) which can be used for creating a tunable gradient-index filter, also known as a rugate filter, i.e., an optical filter based on a dielectric coating, where the refractive index is varied continuously (rather than in steps) at least in some part of the structure. In some cases, the refractive index varies in a sinusoidal oscillation, leading to reflection in some narrow wavelength region, and transmission in another. In transmission, one obtains a notch filter, which blocks some limited wavelength range, while in reflection one obtains a bandpass filter. Such filters are used, for example, as laser blocking filters in Raman spectroscopy. In some cases, it may be possible to combine multiple reflection bands in order to obtain multiple notch filters.
(38) In some embodiments, one or more of the layered stacks can further include additional phase change materials, each having their own respective index of refraction and phase change behavior to enable further fine-tuning of the spectral properties of the filter.
(39) Many additional uses in both the military and commercial environments could be realized from this invention. Such tunable filters could be used for a wide variety of molecular sensing, communication, biomedical instruments, on-chip spectroscopy, etc.
Advantages and New Features
(40) Tunable filters are used in applications such as spectroscopy, sensing, communication, and imaging. One significant benefit of our proposed approach is the absence of mechanical tuning needed to vary the filter's spectral characteristics. This provides a reduction in system complexity by removing the mechanical elements, thereby resulting in a more compact and robust system.
(41) One significant benefit of our proposed approach is the absence of mechanical tuning.
(42) However, a combination of mechanical tuning with our tuning method would enable even broader capabilities.
(43) An additional feature is that the filter's spectral properties (e.g., bandwidth, selectivity, etc.) can be customized by modifying the properties of the layered materials. Knowledge of the optical properties of these materials, such as NRL's model of the optical properties of vanadium dioxide, are critical to creating custom filter designs.
(44) Another potential benefit is increased tuning speed, allowing more rapid tuning which is useful in applications such as modulation, gating, and switching.
(45) A further benefit is that using atomic-layer deposition fabrication techniques, these dielectric films can conformally coat arbitrary three dimensional surfaces, creating complex structures and/or allowing for more complex tunable filter systems.
(46) Finally, another advantage of this process is the ability to fabricate these multilayer structures for these tunable filters directly on a detector, sensor, or system.
SUMMARY
(47) Spectral filters that incorporate a phase change material to enable their tuning to obtain desired reflectance or transmittance properties have been described. Although particular embodiments, aspects, and features have been described and illustrated, one skilled in the art would readily appreciate that the invention described herein is not limited to only those embodiments, aspects, and features but also contemplates any and all modifications and alternative embodiments that are within the spirit and scope of the underlying invention described and claimed herein. The present application contemplates any and all modifications within the spirit and scope of the underlying invention described and claimed herein, and all such modifications and alternative embodiments are deemed to be within the scope and spirit of the present disclosure.