GAS SENSOR COMPRISING A PULSED LIGHT SOURCE
20220011222 · 2022-01-13
Inventors
Cpc classification
International classification
Abstract
A method for measuring an amount of a gaseous species present in a gas, the gaseous species absorbing light in an absorption spectral band, comprises placing the gas between a light source and a measuring photodetector. The light source is configured to emit a light wave that propagates through the gas to the measuring photodetector. The light source is activated so as to illuminate the gas, so that the light source emits a light pulse. The method also includes measuring, with the measuring photodetector, a measurement intensity of a light wave transmitted by the gas during the illumination, in a measurement spectral band. The measurement spectral band comprises the absorption spectral band. The light source is activated using a pulsed activation signal, each pulse having a specific form, notably to reduce aging of the source.
Claims
1. A method for measuring an amount of a gaseous species present in a gas, the gaseous species absorbing light in an absorption spectral band, the method comprising: a) placing the gas between a light source and a measuring photodetector, the light source being configured to emit a light wave, which propagates through the gas to the measuring photodetector; b) activating the light source so as to illuminate the gas, so that the light source emits a light pulse; c) measuring, with the measuring photodetector, a measurement intensity of a light wave transmitted by the gas during the illumination, in a measurement spectral band, the measurement spectral band comprising the absorption spectral band; wherein step b) comprises supplying the light source with a pulsed activation signal, the activation signal comprising electrical pulses, each electrical pulse extending between an initial time and a final time, and each electrical pulse comprising: an initial period, extending an initial duration from the initial time, in the course of which the activation signal is at an initial level; a nominal period, after the initial period, in the course of which the activation signal is maintained at a nominal level strictly lower than the initial level, the nominal period having a nominal duration longer than the initial duration.
2. The method of claim 1, wherein the initial duration is comprised between 2 ms and 20 ms, and preferably between 5 ms and 15 ms.
3. The method of claim 1, wherein the nominal duration is comprised between 20 ms and 150 ms and preferably between 50 ms and 100 ms.
4. The method of claim 1, wherein, during the initial period, the activation signal is maintained at the initial level during the initial duration.
5. The method of claim 1, wherein the nominal period extends to the final time.
6. The method of claim 1, wherein the nominal period is followed by a final period, in the course of which the activation signal decreases, below the nominal level, during a final duration, until the final time.
7. The method of claim 6, wherein the final duration is longer than the initial duration.
8. The method of claim 6, wherein the final duration is shorter than the nominal duration.
9. The method of claim 6, wherein, in the course of the final period, the activation signal gradually decreases until the final time.
10. The method of claim 6, wherein the final duration is comprised between 10 ms and 100 ms, and preferably between 20 ms and 50 ms.
11. A sensor for determining an amount of a gaseous species in a gas, the sensor comprising: a light source, configured to emit a light wave that propagates to the gas, the light wave lying in an absorption spectral band of the gaseous species; a measuring photodetector, configured to detect a light wave transmitted by the gas, at various measurement times, in a measurement spectral band, and to measure a measurement intensity thereof; a pulse generator, configured to send an activation signal to the light source, the activation signal being formed from pulses, each pulse comprising: an initial period, extending an initial duration from the initial time, in the course of which the activation signal is at an initial level; a nominal period, after the initial period, in the course of which the activation signal is maintained at a nominal level strictly lower than the initial level, the nominal period having a nominal duration longer than the initial duration.
12. The sensor of claim 11, further comprising: a reference photodetector, configured to measure a reference intensity of a reference light wave emitted by the light source, in a reference spectral band, at the various measurement times.
13. The sensor of claim 11, wherein: the initial duration is comprised between 2 ms and 20 ms, and preferably between 5 ms and 15 ms; and/or the nominal duration is comprised between 20 ms and 150 ms and preferably between 50 ms and 100 ms.
14. The sensor of claim 11, wherein the pulse generator is configured such that each pulse comprises a final period, in the course of which the activation signal decreases, below the nominal level, during a final duration, until the final time.
15. The sensor of claim 14, wherein the final duration is comprised between 10 ms and 100 ms, and preferably between 20 ms and 50 ms.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION
[0050]
[0054] The gas G comprises a gaseous species G.sub.x an amount c.sub.x(k), a concentration, for example, of which it is desired to determine at a measurement time k. This gaseous species absorbs a measurable portion of the light in an absorption spectral band Δ.sub.x.
[0055] The light source 11 is able to emit the incident light wave 12, in the illumination spectral band Δ.sub.12, the latter possibly extending between the near ultraviolet and the mid infrared, for example between 200 nm and 10 μm, and most often between 1 μm and 10 μm. The absorption spectral band Δ.sub.x of the analyzed gaseous species G.sub.x is comprised in the illumination spectral band Δ.sub.12. The light source 11 is a pulsed source, the incident light wave 12 being a pulse of duration generally within a range from 100 ms to 1 s. The light source 11 may notably be a filament light source the filament of which is suspended and heated to a temperature within a range from 400° C. to 800° C. Its emission spectrum, in the emission spectral band Δ.sub.12, corresponds to the emission spectrum of a black body.
[0056] The measuring photodetector 20 is preferably associated with an optical filter 18, defining the measurement spectral band Δ.sub.20 encompassing all or part of the absorption spectral band Δ.sub.x of the gaseous species.
[0057] In the example in question, the measuring photodetector 20 is a thermopile, able to deliver a signal depending on the intensity of the detected light wave. Alternatively, the measuring photodetector may be a photodiode or another type of photodetector.
[0058] The reference photodetector 20.sub.ref is placed beside the measuring photodetector 20 and is of the same type as the latter. It is associated with an optical filter, referred to as the reference optical filter 18.sub.ref. The reference optical filter 18.sub.ref defines the reference spectral band Δ.sub.ref, which corresponds to a range of wavelengths that are not absorbed by the gaseous species in question. The reference bandwidth Δ.sub.ref is, for example, centered on the wavelength 3.91 μm.
[0059] The intensity I.sub.20(k) of the light wave 14 detected by the measuring photodetector 20, which is referred to as the measurement intensity, at a measurement time k, depends on the amount c.sub.x(k) at the measurement time, according to the Beer-Lambert law:
where: [0060] μ(c.sub.x(k)) is an absorption coefficient dependent on the amount c.sub.x(k) at the time k; [0061] l is the thickness of gas passed through by the light wave in the enclosure 5; and [0062] I.sub.0(k) is the intensity of the incident light wave, at the time k, which corresponds to the intensity of the light wave, in the measurement spectral band Δ.sub.20, reaching the measuring photodetector 20 in the absence of absorbent gas in the enclosure 5.
[0063] The comparison between I.sub.20(k) and I.sub.0(k), taking the form of a ratio
allows the absorption abs(k) generated by the gaseous species in question at the time k to be defined.
[0064] The device comprises a processing unit 30, a microprocessor for example, connected to a memory 32. To determine the amount of analyte c.sub.x(k) at each measurement time k, the processing unit receives the signals detected by the measuring photodetector 20 and the reference photodetector 20.sub.ref, respectively.
[0065] During each pulse from the light source 11, it is thus possible to determine μ(c.sub.x(k)), this allowing c.sub.x(k) to be estimated given that the relationship between c.sub.x(k) and μ(c.sub.x(k)) is known.
[0066] Expression (1) assumes the intensity I.sub.0(k) of the incident light wave 12 is known at the measurement time k. This intensity is determined from the light intensity detected by the reference photodetector.
[0067] As indicated above, the light source is pulsed. The measurement time k is a time corresponding to a light pulse. Thus, various measurement times correspond, respectively, to various light pulses.
[0068]
where [0069] L(λ, Temp) is luminance, which is dependent on the wavelength λ and on the surface temperature Temp of the black body, [0070] h is Planck's constant, [0071] B is Boltzmann's constant, and [0072] c is the speed of light in air.
[0073] The illumination spectrum S of the light source 11 corresponds to the variation in the luminance L(λ, Temp) as a function of λ, when the light source is at a temperature Temp. Generally, the temperature is within a range from 400° C. to 800° C.
[0074] The light source 11 is controlled by an electrical pulse generator 10, which delivers an activation signal in order to activate the light source. The activation signal V is an electrical signal with which the light source 11 is supplied. It is formed from electrical pulses imp.sub.V, each electrical pulse generating an emission of a light pulse imps by the light source. The level of the activation signal sets the amplitude of each light pulse delivered by the light source. By “level,” what is meant is a current or voltage level of the activation signal. In the remainder of the text, the activation signal is considered to set a voltage across the terminals of the light source. Alternatively, it could be a question of a current of the activation signal with which the light source is supplied.
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[0076] The inventors have supplied a light source 11, such as described above, with an activation signal V formed from regular rectangular pulses, such as shown in
[0077] The duration Δt of the electrical pulses of the activation signal V of the light source 11 was 260 ms. The nominal level V.sub.N was 1100 mV. The variation V as a function of time in the activation signal normalized by its maximum value has been schematically shown by black dotted lines.
[0078] It may be seen that the intensity I of the light wave emitted by the light source takes the form of a light pulse imp.sub.I, as was expected. However, it may also be seen that the light pulse imp.sub.I has a latency with respect to the electrical pulse imp.sub.V. This results in a time lag between the electrical pulse of the activation signal, and the light pulse of the light source 11. The time lag manifests itself: [0079] at the start of each electrical pulse imp.sub.V, as a rise time t.sub.r of the light pulse imp.sub.I inducing a delay, during the rise, of the light pulse with respect to the electrical pulse imp.sub.V. The rise time is, in this example, longer than 40 ms. [0080] at the end of each electrical pulse, as a fall time t.sub.d of the light pulse imp.sub.I inducing a delay, during the fall, of the light pulse with respect to the electrical pulse. The fall time is in this example of the order of 40 ms.
[0081] Due to the existence of the rise time and fall time, each light pulse imp.sub.I has a shape such as those schematically shown in
[0082] As may be seen in
[0083] The objective of the disclosure is to modify the shape of each electrical pulse of the activation signal, in order to adjust the shape of each light pulse emitted by the light source so as to avoid the need for an analog filter.
[0084] According to a first embodiment, it is sought to reduce the rise time t.sub.r of each light pulse, so that the duration of each light pulse may be reduced. According to a second embodiment, it is sought to adapt the shape of the light wave during its fall, so as to facilitate processing of the signal generated by the measuring photodetector 20, and by the optional reference photodetector 20.sub.ref.
[0085] As mentioned above, each measurement time k is preferably chosen so as to correspond to a maximum intensity I.sub.max of each light pulse. The longer the rise time t.sub.r, the more the measurement time must be offset with respect to the start of an electrical pulse of the activation signal V. The offset makes it possible for the measurement time to correspond to a time at which the light pulse is at its highest.
[0086] In order to reduce the rise time t.sub.r of the light pulse, it is proposed to modulate the amplitude of each electrical pulse of the activation signal V used to control the light source 11. This is the first embodiment of the disclosure, which embodiment will now be described with reference to
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[0088] At the end of the initial period T.sub.i, the activation signal is brought to a nominal level V.sub.N where it remains for a nominal period T.sub.N lasting a nominal duration Δt.sub.N. The nominal level corresponds to a conventional supply level of the light source. The nominal period T.sub.N extends between the first time t.sub.1 and a second time t.sub.2. In the embodiment shown in
[0089] Generally, the initial duration Δt.sub.i is shorter than the nominal duration Δt.sub.N.
[0090] The initial duration Δt.sub.i is preferably within a range from 2 ms to 20 ms, and preferably within a range from 5 ms to 15 ms. The nominal duration Δt.sub.N is preferably within a range from 20 ms to 150 ms, and preferably within a range from 50 ms to 100 ms.
[0091] In the example shown in
[0092] In
[0093] It will be recalled that, because of the negligible response time of a photodiode, the pulses shown in
[0094] The value of 1000 mV corresponds to the maximum intensity I.sub.max of the light wave emitted in the prior-art configuration.
[0095] It is within the ability of those skilled in the art to test various values of V.sub.i, Δt.sub.i, or even V.sub.N, to obtain, at the photodetector, a pulse shape considered to be optimal. The fact that excessively high values of V.sub.i may significantly increase power consumption will possibly be taken into account. Considering such an initial duration Δt.sub.i, the maximum level I.sub.max is reached more rapidly than in the prior art. This allows the duration of each light pulse to be reduced, because each measurement time k may be brought closer to the initial time of each pulse. Specifically, the measurement time is a time at which the light pulse has reached the maximum intensity I.sub.max. By reducing the rise time t.sub.r of the light pulse, the maximum intensity I.sub.max is reached more rapidly. The final time t.sub.f of the pulse may be chosen to lie a few ms or tens of ms after the maximum intensity I.sub.max. This results in a reduction in the total duration of the light pulse. By reducing the duration of the light pulse, aging of the light source 11 is delayed. In the example shown in
[0096] According to another embodiment, which may be implemented simultaneously with the first embodiment or independently of the latter, the main objective is to optimize the shape of the light pulse during its fall. According to this second embodiment, it is also possible to seek to reduce the rise time t.sub.r. According to this embodiment, as shown in
[0097] Preferably, the duration Δt.sub.f of the final period T.sub.f is shorter than the duration Δt.sub.N of the nominal period T.sub.N, it, for example, being at least 1.5 times shorter or at least 2 times shorter than the duration Δt.sub.N of the nominal period T.sub.N. Preferably, the duration of the final period Δt.sub.f is longer than the duration of the initial period Δt.sub.i. The duration Δt.sub.f of the final period T.sub.f may be within a range from 10 ms to 100 ms, and preferably within a range from 20 ms to 50 ms. During the final period T.sub.f, the activation signal is lower than the nominal level V.sub.N, and a fortiori lower than the initial level V.sub.i.
[0098] In the example shown in
[0099] Preferably, in the course of the final period T.sub.f, the fall of the activation signal follows a monotonic decreasing function, for example, and advantageously, a sinusoidal function.
[0100] According to this embodiment, the light pulse imp.sub.I decreases in a substantially sinusoidal fashion, as shown in
[0101] The electrical pulse imp.sub.V shown in
[0102] According to one variant, the pulse does not comprise an initial period T.sub.i. The initial time t.sub.i is then the same as the first time t.sub.1 of the nominal period T.sub.N.
[0103] Whatever the embodiment, each electrical pulse of the activation signal V may have the following parameters: [0104] duration Δt.sub.i of the initial period T.sub.i; [0105] level V.sub.i of the activation signal during the initial period T.sub.i; [0106] duration Δt.sub.N of the nominal period T.sub.N; [0107] level V.sub.N of the activation signal during the nominal period T.sub.N; [0108] duration Δt.sub.f of the final period T.sub.f; and [0109] function followed by the activation signal during the final period T.sub.f.
[0110] These parameters may be determined on a case-by-case basis, depending on the sought-after technical effect: decrease in rise time t.sub.r of the light pulse and/or optimization of the fall of the light wave. The parameters may, for example, be determined by actuating the light source and observing the variation in the signal detected by a photodetector. The latter may be the measuring photodetector 20 used by the sensor, or a specific photodetector, for example a photodiode, used for the purpose of adjusting the parameters of the shape of the electrical pulses from which the activation signal is formed. The power consumption of the light source may also be taken into account.
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[0120] The signal generated by the measuring photodetector 20 contains three pulses, corresponding to three light pulses generated by the light source.
[0121] The signal generated by the photodetector underwent a frequency analysis, after application of a fast Fourier transform, so as to obtain a spectral power corresponding to various frequencies.
[0122] This embodiment allows aging of the source to be limited, because it allows the duration Δt.sub.N of the nominal period T.sub.N to be reduced. It is estimated that this embodiment allows the duration of the nominal period to be reduced from 260 ms to 45 ms.
[0123] Tests were carried out over one week, using a sensor implementing the disclosure (second embodiment) and a prior-art sensor in which the light source was powered at regular intervals such as shown in
[0124] Thus, parameterization of the activation signal V according to the disclosure may: [0125] favor a rapid light-wave rise time, as explained with reference to
[0127] Embodiments of the disclosure will possibly be employed to control light sources with which gas sensors are equipped, for uses such as monitoring air pollution, food processing, monitoring industrial processes, monitoring combustion gases, etc.