Long thin glass body
11220088 · 2022-01-11
Assignee
Inventors
- Takeshi Murashige (Ibaraki, JP)
- Junichi Inagaki (Ibaraki, JP)
- Seong Jin Ryu (Ibaraki, JP)
- Hiroyuki Takemoto (Ibaraki, JP)
Cpc classification
B32B3/266
PERFORMING OPERATIONS; TRANSPORTING
B32B37/14
PERFORMING OPERATIONS; TRANSPORTING
B32B2457/20
PERFORMING OPERATIONS; TRANSPORTING
Y10T428/24314
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10T428/24331
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
B32B7/12
PERFORMING OPERATIONS; TRANSPORTING
B32B17/06
PERFORMING OPERATIONS; TRANSPORTING
International classification
B32B7/12
PERFORMING OPERATIONS; TRANSPORTING
B32B38/00
PERFORMING OPERATIONS; TRANSPORTING
B32B37/14
PERFORMING OPERATIONS; TRANSPORTING
Abstract
There is provided a thin glass elongated body having a small amount of air bubbles between a thin glass and a resin film. A thin glass elongated body of the present invention includes: a thin glass having an elongated shape; and a resin film bonded onto at least part of the thin glass, wherein the resin film has, in a portion in which the thin glass and the resin film are laminated, a plurality of cutting lines and/or holes each penetrating through the resin film.
Claims
1. A thin glass elongated body, comprising: a thin glass having an elongated shape; and a resin film bonded onto at least part of the thin glass, wherein the resin film has, in a portion in which the thin glass and the resin film are laminated, a plurality of cutting lines each penetrating through the resin film, and wherein when the plurality of cutting lines are projected onto one imaginary line that is perpendicular to a longitudinal direction of the resin film, the plurality of cutting lines define a plurality of projection lines, and at least one end of each projection line corresponding to one of the plurality of cutting lines contacts an end of the project line corresponding to an adjacent one of the plurality of cutting lines, so that the plurality of projection lines form one continuous line, wherein a length of each of the plurality of cutting lines is less than 30% with respect to a width of the resin film, and wherein at least a portion of the plurality of cutting lines are formed at an angle of 30-60° relative to the longitudinal direction of the resin film.
2. The thin glass elongated body according to claim 1, wherein a length of the continuous line or the discontinuous line is 60% or more with respect to a width of the resin film.
3. The thin glass elongated body according to claim 1, wherein the thin glass has a thickness of from 10 μm to 150 μm.
4. The thin glass elongated body according to claim 1, wherein the thin glass and the resin film are bonded onto each other through intermediation of a pressure-sensitive adhesive layer.
5. A thin glass rolled body, which is formed by taking up the thin glass elongated body of claim 1.
6. A method of manufacturing the thin glass elongated body of claim 1, the method comprising: subjecting the thin glass and the resin film to preliminary bonding by laminating the resin film onto the thin glass; and subjecting, after the preliminary bonding, the thin glass and the resin film to final bonding through use of a pressure roll, the method further comprising, before the final bonding, forming a plurality of cutting lines and/or holes each penetrating through the resin film in the resin film.
7. The thin glass elongated body according to claim 1, wherein the plurality of cutting lines are formed in groups at intervals of 2 to 30 m in the longitudinal direction of the resin film, and wherein each group of cutting lines occupies an area of the resin film having a width of from 300 mm to 1,000 mm and a length of from 100 mm to 1,000 mm.
Description
BRIEF DESCRIPTION OF DRAWINGS
(1)
(2)
(3)
(4)
(5)
(6)
(7)
(8)
DESCRIPTION OF EMBODIMENTS
A. Thin Glass Elongated Body
(9)
(10)
(11) In one embodiment, the cutting lines 21 are inclined with respect to the longitudinal direction of the thin glass elongated body 100. When the cutting lines 21 are formed so as to be inclined, air trapped between the thin glass and the resin film is released during manufacturing by the roll-to-roll process, and the opening of the cutting lines can be prevented. When the opening of the cutting lines is prevented, a thin glass elongated body in which troubles during conveyance are suppressed and the resin film can effectively protect the thin glass can be obtained. An inclined angle a of each cutting line with respect to the longitudinal direction of the resin film is preferably from 10° to 80°, more preferably from 30° to 60°.
(12) The length of each cutting line may be set to any appropriate length as long as the effect of the present invention is obtained. For example, in the case where the width of the resin film is from 300 mm to 1,000 mm, the length of each cutting line is preferably from 10 mm to 500 mm, more preferably from 20 mm to 150 mm, still more preferably from 30 mm to 60 mm. Further, in the case where the cutting lines are inclined, the length of each cutting line is preferably less than 50%, more preferably 40% or less, still more preferably from 3% to 35%, particularly preferably from 3% to 20% with respect to the width of the resin film. In the case where the length of each cutting line is 50% or more with respect to the width of the resin film, the stiffness of the resin film decreases, and there is a risk in that the resin film may not serve as the protective film. Further, during manufacturing of the thin glass elongated body or during conveyance in the roll-to-roll process to which the obtained thin glass elongated body is subjected, there is a risk in that troubles such as the breakage of the thin glass may occur.
(13) It is preferred to form the plurality of cutting lines 21 in both the longitudinal direction and the width direction. The cutting lines may be formed at a uniform density (that is, over the entire resin film at a substantially constant interval) or may be formed at a non-uniform density in plan view. As illustrated in
(14) The cutting lines are not limited to the configuration illustrated in
(15) Further, as illustrated in
(16) It is preferred that, when the plurality of cutting lines or holes are projected onto the width direction of the resin film, a set of projection lines projected onto one imaginary line b parallel to the width direction of the resin film form one continuous line c, c′ or one discontinuous line having a disconnected portion of 5 mm or less (
(17) As described above, in the case where the set of the projection lines of the plurality of cutting lines or holes may form one continuous line, air trapped over an entire region of the thin glass elongated body in the width direction can be released easily by the roll-to-roll process, and thus the thin glass elongated body having a small amount of a few air bubbles can be obtained. Further, in the case where the set of the projection lines on the basis of one group of cutting lines may form one continuous line, the trapped air is released in each group of cutting lines by the roll-to-roll process, and hence the thin glass elongated body having a small amount of air bubbles can be obtained. In addition, the state in which the trapped air (air bubbles) accumulates is less liable to continue during manufacturing, and hence the thin glass elongated body capable of being manufactured with less trouble during processing can be obtained. Also in the case where the set of the projection lines of the cutting lines or holes may forma discontinuous line having a disconnected portion of 5 mm or less, the above-mentioned effect can be obtained. The length of the disconnected portion is preferably 3 mm or less, more preferably 1 mm or less, still more preferably 0 mm (that is, a continuous line).
(18) The length of the continuous line c, c′ is preferably 60% or more, more preferably 80% or more, still more preferably 90% or more with respect to the width of the resin film. In such a range, the trapped air is released more reliably. In the case where the set of the projection lines of the cutting lines or holes may form the discontinuous line having a disconnected portion of 5 mm or less, the length of the discontinuous line is preferably 60% or more, more preferably 80% or more, still more preferably 90% or more with respect to the width of the resin film. It is preferred that the cutting lines be formed so that the continuous line and the discontinuous line are formed in a center portion of the resin film in the width direction.
(19)
(20) The thin glass elongated body 200 illustrated in
(21)
(22) Practically, the thin glass elongated body may be provided as a thin glass rolled body into a state in which the thin glass elongated body is taken up into a roll shape. In the thin glass elongated body of the present invention, air is not trapped between the thin glass and the resin film when the thin glass and the resin film are bonded onto each other, or air can be released in the roll-to-roll process even in the case where air is trapped. Therefore, the breakage of the thin glass caused by the trapped air (air bubbles) can be prevented also in the case where the thin glass elongated body is taken up as the thin glass rolled body.
(23) <Thin Glass>
(24) As the thin glass, any appropriate thin glass may be adopted as long as the thin glass has a plate shape. As the thin glass, according to the classification based on a composition, there are given, for example, soda-lime glass, borate glass, aluminosilicate glass, and quartz glass. Further, according to the classification based on an alkaline component, there are given alkali-free glass and low-alkali glass. The alkali-free glass is preferably used. This is because the alkali-free glass is excellent in strength and chemical durability. In the case where the thin glass elongated body includes a plurality of thin glasses, the plurality of thin glasses may be those belonging to the same classification or those belonging to different classifications.
(25) As a method of forming the thin glass, any appropriate method may be adopted. Typically, the thin glass is manufactured by melting a mixture containing main raw materials, such as silica and alumina, an antifoaming agent, such as a salt cake and antimony oxide, and a reducing agent, such as carbon, at temperature of from 1,400° C. to 1,600° C. so as to form the mixture into a thin plate shape, and cooling the resultant. As a method of forming the thin glass into a thin plate, there are given, for example, a slot down-draw method, a fusion method, a float method, and the like. The thin glass formed into a plate shape by those methods may be reduced in thickness or subjected to chemical polishing with a solvent, such as hydrofluoric acid, as necessary, in order to increase the smoothness of a surface and an end portion.
(26) The thickness of the thin glass is preferably from 10 μm to 150 μm, more preferably from 20 μm to 120 μm, still more preferably from 30 μm to 100 μm. In the case where the thickness of the thin glass is more than 150 μm, the thin glass does not have sufficient flexibility, and there is a risk in that the thin glass may be difficult to take up into a roll shape. Further, in the case where the thickness of the thin glass is less than 10 μm, there is a risk in that the handling may be difficult.
(27) The width of the thin glass is preferably 300 mm or more, more preferably 400 mm or more. In general, a wide thin glass is difficult to handle because a significant load is applied to the thin glass when the thin glass is twisted or deflected under the self weight. The present invention exhibits the effect markedly in the processing or treatment of the wide thin glass, which is usually difficult to handle. The upper limit of the width of the thin glass is preferably 2,000 mm or less, more preferably 1,500 mm or less, still more preferably 1,200 mm or less.
(28) The length of the thin glass may be set to any appropriate length depending on a desired treatment or processing amount. For example, the thin glass having a length of from 30 m to 1,000 m may be used.
(29) <Resin Film>
(30) The resin film preferably includes the base material layer and the pressure-sensitive adhesive layer. The pressure-sensitive adhesive layer may be formed on the entire surface of the base material layer, or may be formed on part of the surface thereof. As a material for forming the base material layer, any appropriate resin may be selected as long as effect of the present invention is obtained. As such resin for forming the resin film, there are given, for example, polyethylene, polyvinyl chloride, polyethylene terephthalate, polyvinylidene chloride, polypropylene, polyvinyl alcohol, polyester, polycarbonate, polystyrene, polyacrylonitrile, an ethylene vinyl acetate copolymer, an ethylene-vinyl alcohol copolymer, an ethylene-methacrylic acid copolymer, nylon, cellophane, and a silicone resin. Of those, a polyethylene terephthalate-based resin or polyethylene is preferably used.
(31) The base material layer has a thickness of preferably from 2 μm to 300 μm, more preferably from 10 μm to 200 μm.
(32) For example, a rubber-based pressure-sensitive adhesive, an acrylic pressure-sensitive adhesive, a silicone-based pressure-sensitive adhesive, and a urethane-based pressure-sensitive adhesive are given as the material for forming the pressure-sensitive adhesive layer.
(33) The thickness of the pressure-sensitive adhesive layer is preferably from 1 μm to 200 μm, more preferably from 4 μm to 100 μm, still more preferably from 5 μm to 50 μm.
(34) The resin film has a pressure-sensitive adhesive strength (substantially the pressure-sensitive adhesive strength of the pressure-sensitive adhesive layer) of preferably from 0.002 N/25 mm to 2.0 N/25 mm, more preferably from 0.002 N/25 mm to 1.0 N/25 mm, still more preferably from 0.005 N/25 mm to 0.9 N/25 mm, with respect to the thin glass. When the resin film has a pressure-sensitive adhesive strength falling within the above-mentioned range, the resin film can easily be peeled off from the thin glass in the case where the resin film needs to be peeled off from the thin glass. It should be noted that the pressure-sensitive adhesive strength may be measured as follows: the resin film is bonded onto the thin glass so that the pressure-sensitive adhesive layer side faces the thin glass; and after the lapse of 30 minutes, the pressure-sensitive adhesive strength is measured with a pressure-sensitive adhesive strength measurement device (for example, an instron-type tensile tester, manufactured by Shimadzu Corporation, autograph) under the conditions of a temperature of 23° C., a humidity of 50% RH, a peeling direction of 180°, and a peel rate of 300 mm/min.
(35) The thickness of the resin film is preferably from 3 μm to 320 μm, more preferably from 5 μm to 250 μm, still more preferably from 20 μm to 50 μm. In the case where the thickness of the resin film is less than 3 μm, there is a risk in that it may become difficult to laminate the resin film and the thin glass. In the case where the thickness of the resin film is more than 320 μm, the thin glass elongated body does not have sufficient flexibility, and there is a risk in that the thin glass elongated body may not be suitable for the roll-to-roll process.
(36) A product of the Young's modulus and the thickness of the resin film is preferably from 50 GPa.Math.μm to 1,000 GPa.Math.μm, more preferably from 50 GPa.Math.μm to 500 GPa.Math.μm. That is, in the case of using a thick resin film, it is preferred to select a material having a low Young's modulus as compared to the case of using a thin resin film. With this, the thin glass elongated body having a high protective effect on the thin glass can be obtained. The Young's modulus as used herein refers to a value calculated from a maximum tangent gradient in a stress-strain (S-S) curve obtained by stretching a strip sample having a width of 10 mm at 23° C., a chuck distance of 50 mm, and a speed of 300 mm/min.
(37) It is preferred that the product of the Young's modulus and the thickness of the resin film be smaller than a product of the Young's modulus and the thickness of the thin glass. The product (GPa.Math.μm) of the Young's modulus and the thickness of the resin film is preferably 90% or less, more preferably 80% or less, still more preferably 70% or less, particularly preferably 60% or less, most preferably 50% or less, with respect to the product (GPa.Math.μm) of the Young's modulus and the thickness of the thin glass. The resin film described above is preferred because a load caused by bending is less liable to be applied to the resin film than in the case of the thin glass. Further, when the resin film which is bent more easily than the thin glass is used, the thin glass elongated body excellent in flexibility can be obtained.
(38) The width of the resin film is preferably from 90% to 120%, more preferably from 100% to 110%, still more preferably 100% with respect to the width of the thin glass. In such a range, the resin film can effectively protect the thin glass, and the alignment is more easily adjusted at the time of processing or treatment.
(39) <Another Film>
(40) As a material for forming the other film, any appropriate material may be selected as long as the effect of the present invention is obtained. As the material for forming the other film, a material having higher toughness than that of the thin glass is used, and examples thereof include a resin and a metal. Examples of the resin include a polyethylene terephthalate-based resin, a polyimide-based resin, a polyamide-based resin, a polyethylene naphthalate-based resin, a polycarbonate-based resin, and a cycloolefin-based resin. Of those, a polyethylene terephthalate-based resin is preferably used. Examples of the metal include aluminum, stainless steel, copper, iron, and lead. Of those, aluminum or stainless steel is preferably used.
(41) A fracture toughness value of the other film is preferably from 2 MPa.Math.m.sup.1/2 to 20 MPa.Math.m.sup.1/2, more preferably from 5 MPa.Math.m.sup.1/2 to 20 MPa.Math.m.sup.1/2, particularly preferably from 10 MPa.Math.m.sup.1/2 to 20 MPa.Math.m.sup.1/2.
(42) The thickness of the other film is preferably from 5 μm to 500 μm. When the other film is formed of the resin, the thickness of the other film is more preferably from 10 μm to 200 μm, still more preferably from 30 μm to 100 μm. When the other film is formed of the metal, the thickness of the other film is more preferably from 5 μm to 200 μm, still more preferably from 30 μm to 50 μm.
(43) The width of the other film may be set to any appropriate width depending on the width of the thin glass. An absolute value of a difference between the width of the thin glass and the width of the other film is preferably 20 mm or less, more preferably 10 mm or less, most preferably 0 mm.
(44) It is preferred that the length of the other film be equal to or more than the length (length from feed to take-up) of a device in which the thin glass elongated body is set. The length of the other film is, for example, from 5 m to 200 m.
B. Method of Manufacturing Thin Glass Elongated Body
(45) The thin glass elongated body of the present invention may be manufactured by bonding the thin glass and the resin film onto each other by any appropriate method. For example, the thin glass elongated body of the present invention may be manufactured by the roll-to-roll process involving subjecting the thin glass and the resin film to preliminary bonding by laminating the resin film onto the thin glass, and subjecting, after the preliminary bonding, the thin glass and the resin film to final bonding through use of a pressure roll, such as a laminate roll or a nip roll.
(46) As described above, the cutting lines and/or holes are formed in the resin film. The cutting lines or holes may be formed before the preliminary bonding of the thin glass and the resin film or after the preliminary bonding, but it is preferred that the cutting lines or holes be formed before the final bonding. In the present invention, the cutting lines or holes are formed in the resin film before a laminate of the thin glass and the resin film passes through the pressure roll, and hence air trapped between the thin glass and the resin film can be released at an inlet of the roll. Therefore, troubles during the processing such as the breakage of the thin glass can be prevented.
(47) As a method of forming the cutting lines and holes, any appropriate method may be adopted. Examples of the method include a method involving using a blade and a method involving using laser light.
EXAMPLES
(48) The present invention is hereinafter specifically described by way of Example. However, the present invention is not limited to Example.
Example 1
(49) A resin film (PET film, total thickness: 25 μm) including a pressure-sensitive adhesive layer was laminated on the entire surface on one side of a thin glass (thickness: 50 μm) having a length of 20 m and a width of 300 mm to subject the thin glass and the resin film to preliminary bonding. Then, cutting lines were formed in the resin film as illustrated in
(50) Then, the laminate of the thin glass and the resin film was caused to pass through a nip roll, and hence the thin glass and the resin film were subjected to final bonding to form a thin glass elongated body. The thin glass elongated body was taken up to obtain a thin glass rolled body.
(51) As a result of obtaining the thin glass elongated body (thin glass rolled body) in the above-mentioned manner, the thin glass was not broken during manufacturing, air bubbles were not confirmed in the thin glass elongated body after being taken up, and the thin glass was not broken even after the take-up.
INDUSTRIAL APPLICABILITY
(52) The thin glass elongated body of the present invention can be suitably used as a thin glass material to be subjected to the roll-to-roll process, such as a display substrate, a sensor cover, or an element cover.
(53) TABLE-US-00001 Reference Signs List 10 thin glass 20 resin film 21 cutting line 22 hole 30 another film 100, 200, 300 thin glass elongated body