HAIR CONDITIONING COMPOSITION

Abstract

Processes treat hair with aqueous compositions comprising one or more cationic polymers having certain cationic change densities and one or more aminated silicones. The novel processes provide long lasting conditioning to the hair and improve combability and suppleness of the hair which is maintainable up to twenty subsequent hair washes.

Claims

1. A process for long lasting conditioning of human hair, the process comprising: applying an aqueous composition onto hair; optionally leaving the aqueous composition on the hair for a period ranging from 1 to 15 min; optionally rinsed the aqueous composition off the hair; and increasing the hair temperature of the hair to an increased temperature ranging from 90 to 140° C., wherein the aqueous composition comprises one or more cationic quaternary ammonium polymers having a cationic charge density of 3.0 mEq/g or more and one or more aminated silicone selected from compounds according to general structure ##STR00003## wherein R is the same or different OH or CH.sub.3 or OCH.sub.3 and X represents butyl, propyl, isopropyl or isobutyl.

2. The process of claim 1, further comprising: heating up the hair to the increased temperature with a digital hair heating device.

3. The process of claim 1, further comprising: heating up the hair to the increased temperature with a flat iron or a round shaped iron.

4. The process of claim 1, wherein the one or more cationic quaternary ammonium polymers has a charge density of 3.5 to 8 mEq/g.

5. The process of claim 1, wherein the one or more cationic quaternary ammonium polymers is selected from Polyquaternium-37, Polyquaternium-6, Polyquaternium-7, and Polyquaternium-16.

6. The process of claim 1, wherein the one or more cationic quaternary ammonium polymers are present at a total concentration of 0.1 to 5% by weight, calculated to a total weight of the aqueous composition.

7. The process of claim 1, wherein the one or more aminated silicone is Bis(Hydroxy/Methoxy) Amodimethcone.

8. The process of claim 1, wherein the one or more aminated silicone is present at a total concentration of 0.1 to 5% by weight, calculated to a total weight of the aqueous composition.

9. The process of claim 1, wherein the aqueous composition further comprises one or more nonionic surfactants.

10. The process of claim 9, wherein the one or more nonionic surfactants are selected from a— fatty alcohol ethoxylates of the following general structure: R1 (OCH2CH2)n OH, wherein R1 is straight or branched, saturated or unsaturated alkyl chain which may be synthetic or natural with a C chain length in the range of 8 to 40, preferably 9 to 30 and more preferably 9 to 24 and n is a number in the range of 5 to 40, preferably 9 to 30, b— polypropylene glycol ether of fatty alcohols according to general structure: R2 (OCH2 (CH3) CH2)n OH, wherein R2 is straight or branched, saturated or unsaturated fatty alcohol which may be synthetic or natural with a C chain length in the range of 8 to 40, preferably 9 to 30 and more preferably 9 to 24 and n is a number in the range of 1 to 40, preferably 3 to 30, c— polyethylene glycol fatty acid esters of the following general structure: R3 C(O) (OCH2CH2)n OH, wherein R3 is straight or branched, saturated or unsaturated alkyl group which may be synthetic or natural with a C chain length in the range of 7 to 39, preferably 9 to 29 and more preferably 9 to 23 and n is a number in the range of 5 to 40, preferably 9 to 30, d— polypropylene glycol fatty acid esters of the following general structure: R4 C(O) (OCH2(CH3) CH2)n OH, wherein R4 is straight or branched, saturated or unsaturated alkyl group which may be synthetic or natural with a C chain length in the range of 7 to 39, preferably 9 to 29 and more preferably 9 to 23 and n is a number in the range of 1 to 40, preferably 9 to 30, e— polyethylene glycol and polypropylene glycol ether of fatty alcohols of the following general structure: R5 (OCH2 (CH3) CH2)n1 (OCH2CH2)n2 OH, wherein R5 is straight or branched, saturated or unsaturated alkyl group which may be synthetic or natural with a C chain length in the range of 7 to 39, preferably 9 to 29 and more preferably 9 to 23 and n1 and n2 may be the same or different and are a number in the range of 1 to 40; and f— ethoxylated triglycerides.

11. The process of claim 9, wherein the one or more nonionic surfactants are present at a total concentration of 0.1 to 5%, calculated to a total weight of the aqueous composition.

12. The process of claim 1, wherein the aqueous composition does not comprise quaternary ammonium surfactant at a concentration more than 5% by weight, calculated to a total weight of the aqueous composition.

13. The process of claim 1, wherein the aqueous composition further comprises one or more of the following compounds: Organic solvent; Fatty alcohol of the general structure: R6-OH, wherein R6 is straight or branched, saturated or unsaturated alkyl chain which may be synthetic or natural with a C chain length in the range of 12 to 24 which may as well be substituted with one or more groups on the alkyl chain; UV filter; Hair direct dye selected from cationic and neutral nitro dyes; Natural plant extract; Protein hydrolysate; Ubiquinone; Nonionic polymer; and Oil and/or oily substances selected from silicone oils, natural and synthetic oily, fatty alcohol dialkyl ethers and fatty acid fatty alcohol esters.

14. The process of claim 1, wherein the aqueous composition has a pH in the range of 3.0 to 8.0.

Description

DETAILED DESCRIPTION OF THE DISCLOSURE

[0042] Specifically, the aqueous composition of the present invention does not comprise quaternary ammonium surfactant of the general structure below at a concentration more than 10%, preferably 5% by weight of the total concentration of one or more cationic quaternary ammonium polymers having the cationic charge density as defined above. The general structure of cationic quaternary ammonium surfactant is

[0043] R.sub.11 R.sub.12 R.sub.13 R.sub.14 N

[0044] wherein R.sub.11 is an alky chain having C length of 8 to 30 which may be saturated or unsaturated, straight or branched, R.sub.12 an alky chain having C length of 1 to 30 which may be saturated or unsaturated, straight or branched, R.sub.11 and R.sub.12 additionally may take the structures of

[0045] R.sub.15 C(O) O (CH2)n or R.sub.15 C(O) NH(CH2)n

[0046] wherein R15 is an alkyl chain with a C length of 7 to 29 which may be saturated or unsaturated, straight or branched and n is a number between 1 and 4, R.sub.13 and R.sub.14 is an alkyl chain with a C length of 1 to 4 which may be straight or branched (only for C3 and C4), wherein all alkyl chains may include one or more substituents such as hydroxyl or (poly)ethoxy groups.

[0047] The composition of the present invention may comprise one or more fatty alcohols and may be in a form of emulsion. Suitable non-limiting examples are according to general structure

[0048] R.sub.6—OH

[0049] wherein R.sub.6 is straight or branched, saturated or unsaturated alkyl chain which may be synthetic or natural with a C chain length in the range of 12 to 24 which may as well be substituted with one or more groups on the alkyl chain.

[0050] Non limiting suitable examples are lauryl alcohol, myristyl alcohol, cetyl alcohol, oleyl alcohol, stearyl alcohol, behenyl alcohol and their mixtures. As a mixed fatty alcohol the mostly used one is the cetearyl alcohol as well the preferred fatty alcohol in the compositions of the present invention.

[0051] The total concentration of one or more fatty alcohols is in the range of 0.1 to 20%, preferably 0.5 to 15%, more preferably 1 to 10% and the most preferably 2 to 7.5% by weight calculated to the total composition.

[0052] The aqueous composition of the present invention may comprise one or more organic solvents. Suitable ones are ethanol, propanol, isopropanol, benzyl alcohol, benzyloxyethanol, ethoxydiglycol, alkylene carbonates such as ethylene carbonate and propylene carbonate, phenoxyethanol, butanol, isobutanol, cyclohexane, cyclohexanol, hexyleneglycol, ethylenecarbonate, propyleneglycol, poypropyleneglycols, ethyleneglycol monoethylether, ethylene glycol monobutyl ether, ethylene glycol monophenyl ether, 1-phenylethylalcohol, 2-phenylethylalcohol, o-methoxyphenol. The most preferred ones are ethanol, isopropanol, benzylalcohol and polypropylene glycols. Concentration of organic solvents should not exceed 20% by weight, preferably in the range of 0.1 to 15%, more preferably 0.1 to 10% by weight and most preferably 0.1 to 7.5% by weight calculated to total composition. It should be noted that concentration of one or more organic solvents is very much dependent on the type of preparation i.e. a solution can contain higher concentration of organic solvent than a gel or emulsion composition.

[0053] Further in an embodiment of the present invention, the aqueous composition of the present invention comprises at least one hair direct dye selected from cationic and neutral nitro dyes.

[0054] Any cationic direct dye is in principal suitable for the compositions. Non-limiting suitable examples are Basic Blue 6, Basic Blue 7, Basic Blue 9, Basic Blue 26, Basic Blue 41, Basic Blue 99, Basic Blue 124, Basic Brown 4, Basic Brown 7, Basic Brown 16, Basic Brown 17, Basic Green 1, Basic Orange 31, Basic Red 2, Basic Red 12, Basic Red 22, Basic Red 51, Basic Red 76, Basic Violet 2, Basic Violet 3, Basic Violet 10, Basic Violet 14, Basic Violet 57 and Basic Yellow 87.

[0055] Neutral dyes, so called nitro dyes for shading purposes are also optionally contained in the compositions. Suitable ones are HO Blue No. 2, HO Blue No. 4, HO Blue No. 5, HO Blue No. 6, HO Blue No. 7, HO Blue No. 8, HO Blue No. 9, HO Blue No. 10, HO Blue No. 11, HO Blue No. 12, HO Blue No. 13, HO Brown No. 1, HO Brown No. 2, HO Green No. 1, HO Orange No. 1, HO Orange No. 2, HO Orange No. 3, HO Orange No. 5, HO Red BN, HO Red No. 1, HO Red No. 3, HO Red No. 7, HO Red No. 8, HO Red No. 9, HO Red No. 10, HO Red No. 11, HO Red No. 13, HO Red No. 54, HO Red No. 14, HO Violet BS, HO Violet No. 1, HO Violet No. 2, HO Yellow No. 2, HO Yellow No. 4, HO Yellow No. 5, HO Yellow No. 6, HO Yellow No. 7, HO Yellow No. 8, HO Yellow No. 9, HO Yellow No. 10, HO Yellow No. 11, HO Yellow No. 12, HO Yellow No. 13, HO Yellow No. 14, HO Yellow No. 15, 2-Amino-6-chloro-4-nitrophenol, picramic acid, 1,2-Diamino-4-nitrobenzol, 1,4-Diamino-2-nitrobenzol, 3-Nitro-4-aminophenol, 1-Hydroxy-2-amino-3-nitrobenzol and 2-hydroxyethylpicramic acid.

[0056] Total concentration of one or more direct dyes in total is in the range of 0.001 to 1.0% by weight, preferably 0.01 to 0.8% more preferably 0.05 to 0.75% and most preferably 0.1 to 0.5% by weight calculated to total composition.

[0057] The aqueous composition of the present invention may further comprise one or more UV filters which may be selected from water soluble ones as well as oils soluble ones. The oil soluble UV filter are more preferred ones as they show no interaction with the cationic quaternary ammonium polymers. Non-limiting examples are 4-Aminobenzoic acid and the esters and salts thereof, 2-phenyl benzimidazole-5-sulfonic acid and the alkali and amine salts thereof, 4-dimethyl aminobenzoic acid and the esters and salts thereof, cinnamic acid and the esters and salts thereof, 4-methoxycinnamic acid and the esters and salts thereof, salicylic acid and the esters and salts thereof, 2.4-dihydroxybenzophenone, 2.2′.4.4′-tetrahydroxy-benzophenone, 2-hydroxy-4-methoxybenzophenone and its 5-sulfonic acid or the sodium salt thereof, 2.2′-dihydroxy-4.4′-dimethoxybenzophenone, 2-hydroxy-5-chlorobenzophenone, 2.2′-dihydroxy-4-methoxybenzophenone, 2.2′-dihydroxy-4.4′-dimethoxy-5.5′-disulfobenzo-phenone or the sodium salt thereof, 2-hydroxy-4-octyloxybenzophenone, 2-hydroxy-4-methoxy-4′-methylbenzophenone, 3-benzyl-idenecampher, 3-(4′-sulfo)-benzyl-idenebornane-2-one and the salts thereof, 3-(4′-methyl benzylidene)-DL-campher, and/or polysilicone-15.

[0058] The total UV filter concentration may be in the range of 0.01 to 1% by weight calculated to the total composition.

[0059] The composition used in the process of the present invention may comprise oil and/or oily substances which are suitably selected from silicone oils, either volatile or non-volatile, natural and synthetic oils, fatty alcohol ethers (dialkyl ethers) and fatty acid fatty alcohol esters. Among silicone oils those can be added to the compositions include, dimethicone, dimethiconol, polydimethylsiloxane (DC fluid ranges from Dow Corning), arylated silicones such as phenyl methicone, phenyl trimethicone, diphenyl dimethicone, diphenylsiloxy phenyl trimethicone, tetramethyl tetraphenyl trisiloxane, triphenyl trimethicone, and trimethyl pentaphenyl trisiloxane, aqueous emulsion of divinyldimethicone/dimethicone copolymer, preferably with a viscosity of higher than 1×10.sup.8 mm.sup.2/s, more preferably higher than 1.1×10.sup.8 mm.sup.2/s measured at 0.01 Hz and at approximately 25° C.

[0060] Suitable non-limiting examples to natural plant oils are such as olive oil, almond oil, avocado oil, wheatgerm oil and ricinus oil.

[0061] Suitable non-limiting examples to fatty alcohol fatty acid esters are such as isopropyl myristate, palmitate, stearate and isostearate, oleyl oleate, isocetyl stearate, hexyl laurate, dibutyl adipate, dioctyl adipate, myristyl myristate and oleyl erucate.

[0062] Suitable non-limiting examples to fatty alcohol ethers (dialkyl ethers) are such as dimyristyl ether, dicetyl ether and dicaprylyl ether.

[0063] The compositions comprise oil and/or oily substances at a total concentration in the range of 0.01 to 10%, preferably 0.05 to 7.5%, more preferably 0.1 to 5 and most preferably 0.1 to 3% by weight calculated to total composition.

[0064] The compositions according to the invention may also comprise further conditioning substances such as protein hydrolyzates and polypeptides, e.g., keratin hydrolyzates, collagen hydrolyzates of the type “Nutrilan®” or elastin hydrolyzates, as well as also in particular plant protein hydrolyzates, optionally, cationized protein hydrolyzates, e.g., “Gluadin®”.

[0065] The composition of the present invention may further comprise natural plant extracts. Within the meaning of the present invention the extracts are liquid extracts and prepared by mixing plant parts such as leaves, fruits, blossoms and roots with a solvent such as water, alcohol, propyleneglycol or mixture of more than one solvent and incubating for certain period of time and filtrating the undissolved plant parts. Suitable aqueous (e.g. steam-distilled) alcoholic or hydro-alcoholic plant extracts known per se are in particular aloe, pineapple, artichoke, arnica, avocado, valerian, bamboo, henbane, birch, stinging nettle, echinacea, ivy, wild angelica, gentian, ferns, pine needles, silver weed, ginseng, broom, oat, rose hip, hamamelis, hay flowers, elderberry, hop, coltsfoot, currants, chamomile, carrots, chestnuts, clover, burr root, cocoanut, cornflower, lime blossom, lily of the valley, marine algae, balm, mistletoe, passion flower, ratanhia, marigold, rosemary, horse chestnut, pink hawthorn, sage, horsetail, yarrow, primrose, nettle, thyme, walnut, wine leaves, white hawthorn, etc. Suitable trade products are, for example, the various “Extrapon®” products, “Herbasol®”, “Sedaplant®” and “Hexaplant®”. Extracts and the preparation thereof are also described in “Hagers Handbuch der pharmazeutischen Praxis”, 4.sup.th Ed. Preferred plant extracts are prepared from Vitis vinifera, Malus domestica, Camelia sinensis, Juglans regia Ribes Uva-Crispa, Ribes nigrum, Ribes rubrum and Punica granatum. The above mentioned extracts may also be available in the powder form and such are also suitable within the meaning of the present invention.

[0066] The natural plant extracts are included into the compositions at a concentration of 0.001 to 1.0%, preferably 0.005 to 0.75%, more preferably 0.01 to 0.6% and most preferably 0.05 to 0.5% by weight, calculated to total composition based on dry matter of the extract.

[0067] Further in an embodiment of the present invention, compositions comprise one or more ubiquinone of the following general structure

##STR00002##

[0068] where n is a number between 1 and 10. It should be noted that the compositions of the present invention can certainly comprise more than one ubiquinone. Preferred ubiquinones are the ones where n is a number between 6 and 10 and especially preferred is Ubiquinone 50 where n is 10, also known as Coenzyme Q10.

[0069] Concentration ubiquinone of the above formula in the compositions is from 0.0001 to 1%, preferably from 0.0002 to 0.75%, more preferably from 0.0002 to 0.5% and most preferably from 0.0005 to 0.5% by weight, calculated to total composition.

[0070] The pH of the compositions according to the present invention is suitably between 3.0 and 8.0 and preferably in the range of 3.5 to 6.5, more preferably 4.0 to 5.5 and most preferably 4.0 to 5.

[0071] In principal pH of the compositions can be adjusted with any organic and/or inorganic acids or their mixture. Some of them to mention are phosphoric acid, hydrochloric acid as the inorganic ones and to the organic acids the well-known citric acid and lactic acid, glycolic acid, glyoxylic acid, hydroxyacrylic acid, glyceric acid, malic acid and tartaric acid and of the dicarboxylic acids are malonic acid, succinic acid, glutaric acid, adipic acid, maleic acid, fumaric acid and phtalic acid.

[0072] Conditioning compositions of the present invention can comprise additionally any compound customarily found in conditioning compositions such as chelating agents, preservatives and fragrance.

[0073] The sequestering agents are selected from polycarboxy acids. The preferred one is ethylene diamine tetraacetic acid, EDTA. Typical useful concentration range for sequestering agents is of 0.01-2.5% by weight calculated to the total composition.

[0074] Viscosity of the conditioning composition may be adjusted according to the application form and generally should not be more than 50,000 mPa.Math.s at 20° C. measured with Brookfield Rheometer at a shear rate of 5 sec.sup.−1.

[0075] Thickening agents especially the nonionic thickening polymers may be comprised into the compositions of the present invention. Suitable non-limiting examples are cellulose derivatives such as hydroxyethyl cellulose, methyl cellulose, hydroxymethyl cellulose, hydroxypropyl cellulose, guar gum and its derivatives, and cognac mannan and derivatives. Thickeners may be included at a concentration of 0.05 to 2.5% by weight calculated to total composition. Concentration of thickener is very much dependent on the thickener itself and also the preparation such as pH value of the composition etc. and therefore should be selected depending on the desired viscosity of the composition.

[0076] The aqueous composition of the present invention may be in the form of solution, gel, dispersion and emulsion. These preparations may be provided to the consumers as they are confectioned in a suitable packaging which allows easy release of the products and distribution onto hair as well as they may be provided in a pressurized container. In case pressurized container is used as the vessel carrying the composition, it additionally comprises a pressurizing gas which may be selected form the any known ones such as alkanes, butane, isobutene, dimethyl ether, pressurized air, nitrogen and carbon dioxide.

[0077] The compositions of the present invention is used in a process for long lasting conditioning hair wherein the hair temperature is increased to the range of 40 to 140° C., preferably 60 to 140° C., more preferably 70 to 130° C., most preferably 80 to 120° C. and in particular 90 to 110° C. The heating of the hair is achieved with a hair dryer, with digital hair heating devices, with an iron which may be either flat or having certain surface structures or a round shaped iron. The operation of such kind of devices is commonly known by the skilled in the art or by the users who may be seen as average users of such devices.

[0078] In a preferred embodiment of the process the aqueous composition is not rinsed off from the hair prior to increasing the temperature of the hair.

[0079] The following examples are to illustrate the invention but not to limit it.

Example 1

[0080] The following compositions were prepared for the comparative tests.

TABLE-US-00001 % active matter A B C Polyquatemium 37 0.8 0.8 0.8 C12-13 Pareth-9 — 0.5 0.5 PPG-3 Caprylyl ether — — 1.0 Bis(Hydroxy/Methoxy) — — 0.5 Amodimethicone Citric acid q.s. to pH 4.0 Water to100

[0081] The composition C is within the scope of the claim 1.

[0082] Human hair streaks having approximately 25 cm length and weighing approximately 3.5 g was used for the comparative tests. The streaks were damaged prior to the tests by means of double bleaching with a bleaching composition commercially available under the brand name Goldwell.

[0083] The streaks, always in duplicate, were treated with the above compositions. Therefore, each streak was applied approximately 1 g of the product and left on the streak for 15 min and the streaks were rinsed off with water. Afterwards only one of the streaks of each pair was dried with a hair drier. Hair temperature reached was approximately 95° C. The temperature measurement was carried out using an infrared measuring device from a distance of approximately 5 cm.

[0084] Additionally two hair streaks were treated with composition C and the one was heated using hair drier to a temperature of 95° C. without rinsing off the composition (C+* in the Table below) and the other was treated with an hot iron operated at 130° C. for 5 times which resulted in approximate hair temperature of 100° C. (C+** in the Table below).

[0085] The suppleness of the hair was measured with a zwick machine and expressed as the force (in milliNewton—mN) to pull off a streak through the rods of the machine. The machine is commercially available from Zwick/Roell Company and includes a manual. It was used according to its manual. Briefly, the streak was placed among 5 metal rods which are placed offset in a given distance horizontally (2 cm) and vertically (8 cm) 5 in total and the force needed to pull the streaks through the metal rods at a given rate (5 cm/min) was measured. All values reported in the Table below are average of at least 6 readings.

[0086] In order to test the long lastingness of hair suppleness, the hair streaks were washed 5 times first and the suppleness was measured again as described above and after additional 5 washes the measurements were repeated. For washing hair streaks, 5% by weight Sodium lauryl ether sulfate solution in water at pH 5.0 was used.

[0087] The following results were obtained.

TABLE-US-00002 Suppleness (mN) Composition Heat Start 5 Wash 10 Wash Water − 1741 2072 1938 A + 756 873 1023 A − 791 1145 1578 B + 697 809 798 B − 715 1046 1311 C + 450 515 659 C − 525 1020 1280 C +* 348 518 629 C +** 388 489 572

[0088] It should be noted that the lower the value, the higher the suppleness of the hair.

[0089] From the above results it is clear that the aqueous composition according to the present invention improves hair suppleness and this effect is long lasting especially when hair temperature is increased after application of the composition. It is beyond any doubt that the addition of aminated silicone to Polyquaternium-37 comprising composition improved the suppleness of the hair. It was observed that the suppleness was affected by the presence of additional substances but the streaks treated with the composition of the present invention were judged to have enough suppleness.

[0090] The above results prove beyond any doubt the improved suppleness of the hair treated with the aqueous composition of the present invention.

[0091] The following examples fall within the scope of the present invention.

Example 2

[0092]

TABLE-US-00003 % by weight Polyquatemium-37 0.80 C12-13 Pareth-9 0.50 Bis(Hydroxy/Methoxy) 0.50 Amodimethicone Hydroxyethylcellulose 0.50 Lactic acid q.s. to pH 4.2 Water to 100

Example 3

[0093]

TABLE-US-00004 % by weight Polyquatemium-37 0.80 C12-13 Pareth-9 0.50 Bis(Hydroxy/Methoxy) 0.50 Amodimethicone Hydroxypropyl guar 0.50 Lactic acid q.s. to pH 4.2 Water to 100

Example 4

[0094]

TABLE-US-00005 % by weight Polyquatemium-37 0.80 C12-13 Pareth-9 0.50 Bis(Hydroxy/Methoxy) 0.50 Amodimethicone Basic Red 51 0.20 Basic Orange 31 0.02 Basic Yellow 87 0.08 Citric acid q.s. to pH 3.8 Water to 100

Example 5

[0095]

TABLE-US-00006 % by weight Polyquatemium-37 0.80 C12-13 Pareth-9 0.85 Bis(Hydroxy/Methoxy) 0.50 Amodimethicone Benzophenone-3 0.25 Basic Red 51 0.20 Basic Orange 31 0.02 Basic Yellow 87 0.08 Citric acid q.s. to pH 3.8 Water to 100

Example 6

[0096]

TABLE-US-00007 % by weight Polyquatemium-37 0.80 C12-13 Pareth-9 0.85 Bis(Hydroxy/Methoxy) 0.50 Amodimethicone Benzophenone-3 0.25 Ethylhexyl methoxy cinnamon 0.10 Basic Red 51 0.20 Basic Orange 31 0.02 HC red no 3 0.08 Citric acid q.s. to pH 3.8 Water to 100

Example 7

[0097]

TABLE-US-00008 % by weight Polyquatemium-37 0.80 C12-13 Pareth-9 0.85 Bis(Hydroxy/Methoxy) 0.50 Amodimethicone Benzophenone-3 0.25 Ethylhexyl methoxy cinnamate 0.10 Hydroxypropyl guar gum 0.25 Basic Red 51 0.20 Basic Orange 31 0.02 HC red no 3 0.08 Citric acid q.s. to pH 3.8 Water to 100

Example 8

[0098]

TABLE-US-00009 % by weight Polyquatemium-37 0.80 Ceteareth 20 1.25 Cetearyl alcohol 5.00 Bis(Hydroxy/Methoxy) 0.50 Amodimethicone Dimethicone 100 cSt 0.85 Ethylhexyl methoxy cinnamate 0.10 Lactic acid q.s. to pH 3.8 Water to 100

Example 9

[0099]

TABLE-US-00010 % by weight Polyquatemium-37 0.80 Ceteareth 30 1.25 Cetearyl alcohol 2.00 Behenyl alcohol 2.80 Dimethicone 50 cSt 0.85 Almond oil 0.10 Vitis vinifera extract 0.10 (dry matter) Lactic acid q.s. to pH 4.5 Water to 100

Example 10

[0100]

TABLE-US-00011 % by weight Polyquatemium-37 0.80 Ceteareth 30 1.25 Cetearyl alcohol 2.00 Behenyl alcohol 2.80 Basic Red 51 0.20 Basic Orange 37 0.02 HC red no 3 0.08 Basic yellow 87 0.03 HC Yellow 2 0.03 Bis(Hydroxy/Methoxy) 0.85 Amodimethicone Almond oil 0.10 Vitis vinifera extract 0.10 (dry matter) Lactic acid q.s. to pH 4.5 Water to 100