Composition comprising a combination of an acrylic polymer, a silicone copolymer and an amino acid or amino acid derivative

Abstract

The present invention relates to a composition for treating keratin fibres, comprising at least an aqueous dispersion of hybrid hydrophobic film-forming acrylic polymer particles, at least one linear block silicone copolymer and at least one amino acid or amino acid derivative.

Claims

1. A process for dyeing a head of hair, comprising: applying to the head of hair a hair dyeing composition comprising: an aqueous dispersion of hybrid hydrophobic film-forming acrylic polymer particles, present in an amount ranging from 1% to 15% by weight, relative to the total weight of the composition; at least one linear block silicone copolymer present in an amount ranging from 1% to 15% by weight, relative to the total weight of the composition; at least one amino acid present in an amount ranging from 0.05% to 5% by weight relative to the total weight of the composition, wherein the at least one amino acid is chosen from alanine, glycine, isoleucine, leucine, proline, tyrosine, valine, phenylalanine, tryptophan, mixtures thereof, or salts thereof; and at least one pigment, present in an effective amount to dye the head of hair; wherein the hybrid hydrophobic film-forming acrylic polymer particles are prepared from: (i) at least one compound (i) chosen from: monomers bearing at least one (meth)acrylic acid group, esters of monomers bearing at least one (meth)acrylic acid group, or amides of monomers bearing at least one (meth)acrylic acid group; and (ii) at least one compound (ii) chosen from styrene compounds; and wherein the hybrid hydrophobic film-forming acrylic polymer particles and the at least one linear block silicone copolymer are present in a weight ratio ranging from 1 to 3.

2. The process according to claim 1, wherein the at least one linear block silicone copolymer is in the form of an aqueous dispersion of particles in an aqueous medium.

3. The process according to claim 1, wherein the at least one linear block silicone copolymer is obtained by a chain-extension reaction, in the presence of a catalyst, using at least: a polysiloxane (i) bearing at least one reactive group; and an organosilicon compound (ii) which reacts with the polysiloxane (i) via a chain-extension reaction.

4. The process according to claim 3, wherein the polysiloxane (i) is chosen from the following polymers of formula (I): ##STR00005## wherein: R.sub.1 and R.sub.2 each independently represent a hydrocarbon-based group containing from 1 to 20 carbon atoms, an aryl group, or a reactive group; and n is an integer greater than 1, wherein each polymer contains an average of between one and two reactive groups.

5. The process according to claim 4, wherein the reactive groups in the polysiloxane are independently chosen from hydrogen, aliphatically unsaturated groups, a hydroxyl group, alkoxy groups, alkoxyalkoxy groups, an acetoxy group, amine groups, and mixtures thereof.

6. The process according to claim 4, wherein R.sub.1 represents a methyl group and R.sub.2 at the at least one end of a chain represents a vinyl group.

7. The process according to claim 3, wherein the organosilicon compound (ii) is chosen from the polysiloxanes of formula (I) and compounds acting as chain extenders.

8. The process according to the claim 7, wherein the organosilicon compound (ii) is a liquid organohydrogenpolysiloxane chosen from those of formula (II) below: ##STR00006## wherein n is an integer greater than 1.

9. The process according to claim 2, wherein the aqueous dispersion of linear block silicone copolymer particles comprises an aqueous dispersion of divinyl dimethicone/dimethicone copolymer particles.

10. The process according to claim 1, wherein the at least one amino acid is chosen from L-alanine, L-glycine, L-isoleucine, L-leucine, L-proline, L-tyrosine, L-valine, L-phenylalanine, D-tryptophan, mixtures thereof, or salts thereof.

11. The process according to claim 1, wherein the at least one pigment is present in an amount ranging from 0.1 to 30% by weight relative to the total weight of the composition.

Description

EXAMPLES

(1) TABLE-US-00001 Composition A Styrene/acrylate copolymer in aqueous dispersion, sold by 21.2 g, BASF under the name Joncryl 77 i.e. 10 g of AM Divinyl dimethicone/dimethicone copolymer as an aqueous 8.3 g, i.e. emulsion, sold by Dow Corning under the reference HMW 5 g of AM 2220 Nonionic Emulsion Glycine sold by Ajinomoto 2 g Black 2 as an aqueous dispersion, from Daito Kasei Kogyo 10 g, i.e. under the name WD-CB2 2.5 g of AM Water qs 100 g
0.6 g of composition A is applied to a 1 g lock of grey hair.
After a few seconds, the lock of hair is dried, the hair is dyed, and the colour is uniform and persistent on shampooing a few times. The hair is soft and the hairs may be individualized with the fingers or by using a comb and/or a brush.

(2) TABLE-US-00002 Composition B Styrene/acrylate copolymer in aqueous dispersion, sold by 21.2 g, i.e. BASF under the name Joncryl 77 10 g of AM Divinyl dimethicone/dimethicone copolymer as an aqueous 8.3 g, i.e. emulsion, sold by Dow Corning under the reference HMW 5 g of AM 2220 Nonionic Emulsion Nacre of mica coated with brown iron oxide, sold by Eckart 6 g under the name Prestige Soft Bronze L-Alanine (Ajinomoto) 1.5 g Water qs 100 g
0.7 g of composition B is applied to a 1 g lock of hair with a tone depth of 4.
The lock dries after a few seconds, and is shaped into a curl using a straightening iron. When the treated lock is placed in a beaker containing water, the shape of the curl is retained when the hair is wet and after drying in the open air.

(3) TABLE-US-00003 Composition C Styrene/acrylate copolymer in aqueous dispersion, 20 g of AM, i.e. sold by BASF under the name Joncryl 77 9.4 g of AM Divinyl dimethicone/dimethicone copolymer as an 7.9 g, i.e. 4.75 g aqueous emulsion, sold by Dow Corning under the of AM reference HMW 2220 Nonionic Emulsion N-Lauroyl L-lysine (Mihope LL from Ajinomoto) 2.5 g Black 2 as an aqueous dispersion, from Daito Kasei 9 g, i.e. 2.25 g Kogyo under the name WD-CB2 of AM Water qs 100 g
0.6 g of composition C is applied to a 1 g lock of grey hair.
After a few seconds, the lock of hair is dried, the hair is dyed, and the colour is uniform and persistent on shampooing a few times. The hair is soft and the hairs may be individualized with the fingers or by using a comb and/or a brush.

(4) TABLE-US-00004 Composition D Styrene/acrylate copolymer in aqueous dispersion, 20 g, i.e. 9.4 g sold by BASF under the name Joncryl 77 of AM Divinyl dimethicone/dimethicone copolymer as an 7.9 g, i.e. 4.75 g aqueous emulsion, sold by Dow Corning under the of AM reference HMW 2220 Nonionic Emulsion Silk protein powder (Crosilk Powder from Croda) 2 g Black 2 as an aqueous dispersion, from Daito Kasei 10 g, i.e. 2.5 g Kogyo under the name WD-CB2 of AM Water qs 100 g
0.6 g of composition D is applied to a 1 g lock of grey hair. After a few seconds, the lock of hair is dried, the hair is dyed, and the colour is uniform and persistent on shampooing a few times. The hairs may be individualized with the fingers or by using a comb and/or a brush.

(5) TABLE-US-00005 Composition E Styrene/acrylate copolymer in aqueous dispersion, sold by 21.2 g, i.e. BASF under the name Joncryl 77 10 g of AM Divinyl dimethicone/dimethicone copolymer as an aqueous 8.3 g, emulsion, sold by Dow Corning under the reference HMW i.e. 5 g 2220 Nonionic Emulsion of AM Glycine soya protein dispersion containing 6% active material 3 g (Eleseryl HGP LS 9874 from Laboratoires Sérobiologiques) Nacre of mica coated with brown iron oxide, sold by Eckart 5 g under the name Prestige Soft Bronze Water qs 100 g
0.6 g of composition E is applied to a 1 g lock of grey hair. After a few seconds, the lock of hair is dried, the hair is dyed, and the colour is uniform and persistent on shampooing a few times. The hairs may be individualized with the fingers or by using a comb and/or a brush.