THIN-FILM HEAT INSULATION SHEET FOR MONOCRYSTALLINE SILICON GROWTH FURNACE AND MONOCRYSTALLINE SILICON GROWTH FURNACE
20220002900 · 2022-01-06
Inventors
- Xing WEI (Shanghai, CN)
- Tao WEI (Shanghai, CN)
- Minghao LI (Shanghai, CN)
- Zhan Li (Shanghai, CN)
- Yun Liu (Shanghai, CN)
- Zhongying XUE (Shanghai, CN)
Cpc classification
Y10T117/1068
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
C30B35/00
CHEMISTRY; METALLURGY
International classification
Abstract
Disclosed is a thin-film heat insulation sheet for a monocrystalline silicon growth furnace, which comprises one or more first refractive layers and one or more second refractive layers which have different refractivity and are laminated alternately to form a laminated structure. Also disclosed is a monocrystalline silicon growth furnace, in which the thin-film heat insulation sheet is arranged on a heat shield. The thin-film heat insulation sheet has good reflectivity in wavelength ranges of heat radiation. When disposed on a heat shield to be applied to the monocrystalline silicon growth furnace, the thin-film heat insulation sheet not only can improve ability of the heat shield to reflect heat energy, reduce heat dissipation of molten silicon melt, and improve heat energy utilization, but also is conducive to heat insulation performance of the heat field, thereby improving the quality of the heat field to improve the quality and yield of monocrystalline silicon.
Claims
1. A thin-film heat insulation sheet for a monocrystalline silicon growth furnace, wherein the thin-film heat insulation sheet for a monocrystalline silicon growth furnace comprises one or more first refractive layers (10) and one or more second refractive layers (20) which have different refractivity from that of the one or more first refractive layers (10), the one or more first refractive layers (10) and the one or more second refractive layers (20) are laminated alternately to form a laminated structure, and the first refractive layer (10) is attached to the second refractive layer (20) disposed adjacent thereto.
2. The thin-film heat insulation sheet for a monocrystalline silicon growth furnace of claim 1, wherein all the first refractive layers (10) are made of silicon, and each of the first refractive layers (10) has a thickness in a range from 0.1 mm to 0.8 mm and roughness of less than 1.4 A.
3. The thin-film heat insulation sheet for a monocrystalline silicon growth furnace of claim 2, wherein each of the first refractive layers (10) has a thickness in a range from 0.1 mm to 0.3 mm and roughness of less than 1 A.
4. The thin-film heat insulation sheet for a monocrystalline silicon growth furnace of claim 1, wherein all the first refractive layers (10) are made of molybdenum, and each of the first refractive layers (10) has a thickness in a range from 0.5 mm to 3 mm and roughness of less than 10 A.
5. The thin-film heat insulation sheet for a monocrystalline silicon growth furnace of claim 4, wherein each of the first refractive layers (10) has a thickness in a range from 1 mm to 2 mm and roughness of less than 3 A.
6. The thin-film heat insulation sheet for a monocrystalline silicon growth furnace of claim 1, wherein at least one of the first refractive layers (10) in the laminated structure is made of silicon, and at least one of the first refractive layers (10) in the laminated structure is made of molybdenum; the at least one of the first refractive layers (10) made of silicon has a thickness in a range from 0.1 mm to 0.8 mm, and the at least one of the first refractive layers (10) made of molybdenum has a thickness in a range from 0.5 mm to 3 mm.
7. The thin-film heat insulation sheet for a monocrystalline silicon growth furnace of claim 2, wherein the second refractive layers (20) are made of silicon dioxide, and each of the second refractive layers (20) has a thickness in a range from 0.1 mm to 1.5 mm and roughness of less than 2 A.
8. The thin-film heat insulation sheet for a monocrystalline silicon growth furnace of claim 4, wherein the second refractive layers (20) are made of silicon dioxide, and each of the second refractive layers (20) has a thickness in a range from 0.1 mm to 1.5 mm and roughness of less than 2 A.
9. The thin-film heat insulation sheet for a monocrystalline silicon growth furnace of claim 6, wherein the second refractive layers (20) are made of silicon dioxide, and each of the second refractive layers (20) has a thickness in a range from 0.1 mm to 1.5 mm and roughness of less than 2 A.
10. The thin-film heat insulation sheet for a monocrystalline silicon growth furnace of claim 7, wherein each of the second refractive layers (20) has a thickness in a range from 0.1 mm to 0.5 mm and roughness of less than 1 A.
11. The thin-film heat insulation sheet for a monocrystalline silicon growth furnace of claim 8, wherein each of the second refractive layers (20) has a thickness in a range from 0.1 mm to 0.5 mm and roughness of less than 1 A.
12. The thin-film heat insulation sheet for a monocrystalline silicon growth furnace of claim 9, wherein each of the second refractive layers (20) has a thickness in a range from 0.1 mm to 0.5 mm and roughness of less than 1 A.
13. The thin-film heat insulation sheet for a monocrystalline silicon growth furnace of claim 1, wherein the thin-film heat insulation sheet is further provided with an encapsulation layer which is suitable for encapsulating the laminated structure.
14. A monocrystalline silicon growth furnace, wherein the monocrystalline silicon growth furnace comprises a furnace body, a crucible, a heater unit, a heat shield, and a thin-film heat insulation sheet of claim 1; the thin-film heat insulation sheet is provided on the heat shield; a cavity is provided in the furnace body; the crucible is arranged in the cavity and is used to contain melt for growth of monocrystalline silicon; the heater unit is arranged between the crucible and the furnace body and is used to provide a heat field required for the growth of the monocrystalline silicon; and the heat shield is arranged in an upper portion of the crucible and is used to reflect heat energy emitted from the crucible, and the thin-film heat insulation sheet is arranged on a side of the heat shield close to the crucible and/or the thin-film heat insulation sheet is arranged on a side of the crucible close to the monocrystalline silicon grown.
15. A monocrystalline silicon growth furnace, wherein the monocrystalline silicon growth furnace comprises a furnace body, a crucible, a heater unit, a heat shield, and a thin-film heat insulation sheet of claim 2; the thin-film heat insulation sheet is provided on the heat shield; a cavity is provided in the furnace body; the crucible is arranged in the cavity and is used to contain melt for growth of monocrystalline silicon; the heater unit is arranged between the crucible and the furnace body and is used to provide a heat field required for the growth of the monocrystalline silicon; and the heat shield is arranged in an upper portion of the crucible and is used to reflect heat energy emitted from the crucible, and the thin-film heat insulation sheet is arranged on a side of the heat shield close to the crucible and/or the thin-film heat insulation sheet is arranged on a side of the crucible close to the monocrystalline silicon grown.
16. A monocrystalline silicon growth furnace, wherein the monocrystalline silicon growth furnace comprises a furnace body, a crucible, a heater unit, a heat shield, and a thin-film heat insulation sheet of claim 3; the thin-film heat insulation sheet is provided on the heat shield; a cavity is provided in the furnace body; the crucible is arranged in the cavity and is used to contain melt for growth of monocrystalline silicon; the heater unit is arranged between the crucible and the furnace body and is used to provide a heat field required for the growth of the monocrystalline silicon; and the heat shield is arranged in an upper portion of the crucible and is used to reflect heat energy emitted from the crucible, and the thin-film heat insulation sheet is arranged on a side of the heat shield close to the crucible and/or the thin-film heat insulation sheet is arranged on a side of the crucible close to the monocrystalline silicon grown.
17. A monocrystalline silicon growth furnace, wherein the monocrystalline silicon growth furnace comprises a furnace body, a crucible, a heater unit, a heat shield, and a thin-film heat insulation sheet of claim 4; the thin-film heat insulation sheet is provided on the heat shield; a cavity is provided in the furnace body; the crucible is arranged in the cavity and is used to contain melt for growth of monocrystalline silicon; the heater unit is arranged between the crucible and the furnace body and is used to provide a heat field required for the growth of the monocrystalline silicon; and the heat shield is arranged in an upper portion of the crucible and is used to reflect heat energy emitted from the crucible, and the thin-film heat insulation sheet is arranged on a side of the heat shield close to the crucible and/or the thin-film heat insulation sheet is arranged on a side of the crucible close to the monocrystalline silicon grown.
18. A monocrystalline silicon growth furnace, wherein the monocrystalline silicon growth furnace comprises a furnace body, a crucible, a heater unit, a heat shield, and a thin-film heat insulation sheet of claim 5; the thin-film heat insulation sheet is provided on the heat shield; a cavity is provided in the furnace body; the crucible is arranged in the cavity and is used to contain melt for growth of monocrystalline silicon; the heater unit is arranged between the crucible and the furnace body and is used to provide a heat field required for the growth of the monocrystalline silicon; and the heat shield is arranged in an upper portion of the crucible and is used to reflect heat energy emitted from the crucible, and the thin-film heat insulation sheet is arranged on a side of the heat shield close to the crucible and/or the thin-film heat insulation sheet is arranged on a side of the crucible close to the monocrystalline silicon grown.
19. A monocrystalline silicon growth furnace, wherein the monocrystalline silicon growth furnace comprises a furnace body, a crucible, a heater unit, a heat shield, and a thin-film heat insulation sheet of claim 6; the thin-film heat insulation sheet is provided on the heat shield; a cavity is provided in the furnace body; the crucible is arranged in the cavity and is used to contain melt for growth of monocrystalline silicon; the heater unit is arranged between the crucible and the furnace body and is used to provide a heat field required for the growth of the monocrystalline silicon; and the heat shield is arranged in an upper portion of the crucible and is used to reflect heat energy emitted from the crucible, and the thin-film heat insulation sheet is arranged on a side of the heat shield close to the crucible and/or the thin-film heat insulation sheet is arranged on a side of the crucible close to the monocrystalline silicon grown.
20. A monocrystalline silicon growth furnace, wherein the monocrystalline silicon growth furnace comprises a furnace body, a crucible, a heater unit, a heat shield, and a thin-film heat insulation sheet of claim 13; the thin-film heat insulation sheet is provided on the heat shield; a cavity is provided in the furnace body; the crucible is arranged in the cavity and is used to contain melt for growth of monocrystalline silicon; the heater unit is arranged between the crucible and the furnace body and is used to provide a heat field required for the growth of the monocrystalline silicon; and the heat shield is arranged in an upper portion of the crucible and is used to reflect heat energy emitted from the crucible, and the thin-film heat insulation sheet is arranged on a side of the heat shield close to the crucible and/or the thin-film heat insulation sheet is arranged on a side of the crucible close to the monocrystalline silicon grown.
Description
BRIEF DESCRIPTION OF DRAWINGS
[0024] In order to more clearly illustrate the technical solutions of the present invention, the drawings that are used in the description of the embodiments or the prior art will be briefly introduced hereafter. Obviously, the drawings in the following description are only some embodiments of the present invention, and other drawings can be obtained based on these drawings by those of ordinary skill in the art without creative work.
[0025]
[0026]
[0027]
[0028]
[0029]
[0030]
[0031]
[0032]
[0033] In the drawings: 10—first refractive layer, 10(I)—first refractive layer made of silicon, 10(II)—first refractive layer made of molybdenum, and 20—second refractive layer.
DETAILED DESCRIPTION
[0034] Hereafter, the technical solutions according to embodiments of the present invention will be described clearly and thoroughly with reference to drawings. Obviously, the described embodiments are only part of, not all of, the embodiments of the present invention. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without any creative work shall fall within the protection scope of the present invention.
[0035] It should be noted that the terms “first”, “second”, or the like as used in the specification and claims of the present invention and in the above-mentioned drawings are used to distinguish similar objects, and are not intended to define a particular order or a sequential order. It should be understood that data used with reference to the terms may be interchanged, where appropriate, so that the embodiments of the present invention described herein can be implemented in an order other than those illustrated or described herein. In addition, the terms “comprising”, “including”, “having”, and any variations thereof, are intended to encompass non-exclusive inclusions.
Embodiment 1
[0036] Refer to
[0037] In the embodiment of the present invention, all the first refractive layers 10 in the laminated structures are made of silicon. Each of the first refractive layers 10 has a thickness in a range from 0.1 mm to 0.8 mm and roughness of less than 1.4 A. It should be noted that in the embodiment, the roughness refers to a root-mean-square roughness.
[0038] In the laminated structures, all the second refractive layers 20 are made of silicon dioxide. Each of the second refractive layers 20 has a thickness in a range from 0.5 mm to 3 mm and roughness of less than 2 A. Both the first refractive layer 10 and the second refractive layer 20 have low surface roughness, which is beneficial for good interface contact between the first refractive layer 10 and the second refractive layer 20, thereby improving heat reflectivity of the entire laminated structures.
[0039] The thin-film heat insulation sheet is further provided with an encapsulation layer (not shown) for encapsulating the laminated structure. The encapsulated thin-film heat insulation sheet is used to be disposed in a monocrystalline silicon growth furnace.
[0040] It should be noted that in the embodiment of the present invention, preparation processes for the first refractive layer 10 and the second refractive layer 20 are not limited. However, it should be understand that the final laminated structures have identical heat reflection effect, regardless of processes used to obtain the first refractive layer and the second refractive layer that meet the above requirements for thickness and roughness.
[0041] It should be noted that in these thin-film heat insulation sheets shown in
[0042] In particular, in the thin-film heat insulation sheets provided in the embodiment as shown in
[0043] Refer to
[0044] In addition, as the number of the first refractive layer—second refractive layer pairs increases, the number of interfaces formed by alternate arrangement of the first refractive layers 10 and the second refractive layers 20 also increases. When the number of the first refractive layer-second refractive layer pairs increases from one to three, the heat reflectivity of the thin-film heat insulation sheet is improved. However, when the number of the first refractive layer-second refractive layer pairs is four or more, the heat reflectivity graphs of the thin-film heat insulation sheets fluctuate more drastically, and a situation occurs where the heat reflectivity of the thin-film heat insulation sheet is lower than that of a thin-film silicon sheet at a wavelength in a range from 800 nm to 1100 nm, which is very detrimental for the overall heat reflectivity of the thin-film heat insulation sheet. Thus, it can also be seen that when the number of the first refractive layer-second refractive layer pairs is in a range from 2 to 3 and the interface number in the laminated structure is in a range from 3 to 5, the thin-film heat insulation sheets have better heat reflectivity. That is to say, improved heat reflectivity of the thin-film heat insulation sheet cannot be achieved by blindly increasing the number of the first refractive layer-second refractive layer pairs.
[0045] A monocrystalline silicon growth furnace is also provided according the embodiment of the present invention, which comprises a furnace body, a crucible, a heater unit, a heat shield, and a thin-film heat insulation sheet provided in the above-mentioned technical solutions, wherein the thin-film heat insulation sheet is disposed on the heat shield.
[0046] A cavity is provided in the furnace body.
[0047] The crucible is disposed in the cavity and located in the center of the cavity, wherein the crucible is recessed in the central portion and is used for containing melt for growth of monocrystalline silicon.
[0048] The crucible may be prepared from quartz (silicon dioxide), or may be prepared from graphite. Alternatively, the crucible may comprise an inner wall made of quartz material and an outer wall made of graphite material such that the inner wall of the crucible can directly contact silicon melt, and the outer wall of the crucible made of graphite can play a supporting role.
[0049] The heater unit is positioned around the crucible and between the crucible and the furnace body, thereby providing a heat field required for the growth of the monocrystalline silicon.
[0050] There is a space between the heater unit and the crucible. The space may be adjusted depending on parameters such as the size of the cavity, the size of the crucible, the heating temperature, and so on.
[0051] The heater unit is preferably a graphite heater unit. Further, the heater unit may comprise one or more heaters disposed around the crucible to make the heat field in which the crucible is located uniform.
[0052] The heat shield is disposed in an upper portion of the crucible, and is used to reflect heat energy emitted from the melt contained in the crucible, thereby playing a heat preservation role.
[0053] The thin-film heat insulation sheet is disposed on a side of the heat shield close to the crucible, and/or the thin-film heat insulation sheet is disposed on a side of the crucible close to the monocrystalline silicon grown.
[0054] Furthermore, the monocrystalline silicon growth furnace may also comprise a cooler for cooling a monocrystalline silicon ingot grown.
[0055] The crucible may also connected with an elevator mechanism and a rotation mechanism. The elevator mechanism is used to raise and lower the crucible. The rotation mechanism is used to rotate the crucible. The crucible can be raised/lowered and rotated in the heat field provided by the heater unit, which is beneficial to provide a good heat field environment. Thus, the silicon melt inside the crucible can also be positioned in a uniform heat environment.
[0056] When the thin-film heat insulation sheet according to the embodiment of the present invention is disposed on a heat shield to be applied to the monocrystalline silicon growth furnace, it not only can improve ability of the heat shield to reflect heat energy, reduce heat dissipation of molten silicon melt, and improve heat energy utilization, but also is conducive to heat insulation performance of the heat field, thereby improving the quality of the heat field to improve the quality and yield of monocrystalline silicon.
Embodiment 2
[0057] In Embodiment 1, the first refractive layer 10 and the second refractive layer 20 exist in pairs. The thin-film heat insulation sheet provided according to Embodiment 2 differs from that of Embodiment 1 in that: in the thin-film heat insulation sheet provided in the embodiment, the number of the first refractive layers 10 is not equal to that of the second refractive layers 20.
[0058] Refer to
[0059] In the thin-film heat insulation sheet in
[0060] Refer to
[0061] In the thin-film heat insulation sheet in
[0062] It should be noted that in the embodiment, the numbers of the first refractive layers 10 and the second refractive layers 20 are merely illustrative, and the numbers of the first refractive layers 10 and the second refractive layers 20 other than those provided in the embodiment may be used.
[0063] Refer to
Embodiment 3
[0064] The thin-film heat insulation sheet according to the embodiment comprises first refractive layers 10 and second refractive layers 20 which have different refractivity from that of the first refractive layers 10, and the first refractive layers 10 and the second refractive layers 20 are disposed alternately. The thin-film heat insulation sheet of the embodiment differs from those of Embodiment 1 and Embodiment 2 in that:
[0065] There are at least two first refractive layers 10, wherein at least one of the first refractive layers 10 in the laminated structure is made of silicon, and at least one of the second refractive layers 20 in the laminated structure is made of molybdenum.
[0066] As an example, as shown in
[0067] As another example, as shown in
[0068] Refer to
[0069] The thin-film heat insulation sheet of
[0070] In summary, all the thin-film heat insulation sheets provided in the embodiments of the present invention have higher heat reflectivity than the heat insulation silicon sheet used in prior art. When the thin-film heat insulation sheets are disposed on heat shields to be applied in the monocrystalline silicon growth furnace, they not only can increase ability of the heat shields to reflect heat energy emitted from the silicon melt in the crucible, reduce heat dissipation of the molten silicon melt, and improve heat energy utilization, but also is conducive to heat insulation performance of the heat field, thereby improving the quality of the heat field to improve the quality and yield of monocrystalline silicon.
[0071] It should be noted that differences among the embodiments are described in the description of the present invention. In addition to the above embodiments, more thin-film heat insulation sheets other than those provided in the above embodiments can be obtained based on the features disclosed above by combining various layers in the thin-film heat insulation sheet.
[0072] The above-mentioned embodiments are preferred embodiments of the present invention, and are not intended to limit the present invention. It is apparent that to those skilled in the art that the present invention is not limited to the exemplary embodiments and can be implemented in other specific forms without departing from the spirit or essential features of the present invention. Therefore, from any point of view, the embodiments should be regarded as exemplary and non-limiting. All equivalent changes and modifications made in accordance with the present invention fall within the scope of the present invention defined by the attached claims. Any reference signs in the claims should not be regarded as limiting the claims involved.