Heater

Abstract

A heater comprising a ceramic heater element and at least two fins for dissipating heat from the ceramic heater element, wherein the ceramic heater element extends along a plane in one dimension and the at least two fins extend away from the plane, and wherein the at least two fins are connected to the ceramic heater element via discrete connecting portions.

Claims

1. A heater comprising a ceramic heater element that comprises a ceramic substrate and at least two fins for dissipating heat from the ceramic heater element, wherein the ceramic substrate extends along a plane in one dimension and the at least two fins extend away from the plane, and wherein each fin of the at least two fins is connected to the ceramic substrate along a length of the fin via discrete connecting portions of the fin such that the fin is not connected to the ceramic substrate along an entire length of the fin, wherein the discrete connecting portions are a plurality of uniform areas of contact between the ceramic substrate and the at least two fins.

2. The heater of claim 1, wherein the discrete connecting portions are each separated by a gap.

3. The heater of claim 2, wherein the fin has a thickness and the gap is between 0.8 and 1.2 times the fin thickness.

4. The heater of claim 1, wherein the at least two fins are disposed on each side of the ceramic heater element.

5. The heater of claim 1, wherein the heater comprises a plurality of fins extending from both sides of the ceramic heater element.

6. The heater of claim 5, wherein the plurality of fins vary in height from a first edge to a second edge of the plurality of fins.

7. A method of attaching a metal fin to a ceramic heater element, the method comprising: (a) applying a filler material to a ceramic surface of the ceramic heater element; (b) positioning a metal fin over the filler material to produce a heater template; and (c) brazing the heater template in a furnace at a temperature of between 750° C. and 900° C. to melt the filler and cause the filler and the ceramic surface of the ceramic heater element to react together.

8. The method of claim 7, wherein the fin is made from one of copper, stainless steel, and kovar.

9. The method of claim 7, further comprising: (i) coating the ceramic surface of the ceramic heater element with a metallisation paste; (ii) sintering the coated ceramic heater element; (iii) electroless plating of a nickel layer on the sintered coated ceramic heater element to produce a primary metallised surface; and (iv) applying a flux to the primary metallised surface, wherein steps (i) to (iv) are carried out prior to step (a) and wherein step (c) additionally melts the flux located between the metal fin and the primary metallised surface and is carried out at a temperature of around 600° C.

10. The method of claim 9, wherein the metallisation paste is a mixture of the ceramic material used to form the ceramic heater element and a refractory material.

11. The method of claim 10, wherein the metallisation paste is applied to the ceramic heater element at a thickness of 10 to 12 microns.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) The invention will now be described by way of example, with reference to the accompanying drawings, of which:

(2) FIG. 1 shows a side view of a brazed sample;

(3) FIG. 2 shows the surface profile of a standard sheet and a multi-sectioned sheet prior to brazing;

(4) FIG. 3a shows an example of a track layout on a rectangular heating element;

(5) FIG. 3b shows an example of a track layout on an arcuate heating element;

(6) FIG. 4a shows the base and fin geometry on a rectangular ceramic heater element;

(7) FIG. 4b shows the base and fin geometry on a arcuate ceramic heater element;

(8) FIG. 5a shows a multi-sectioned base;

(9) FIG. 5b is an expanded view of a portion of FIG. 5a;

(10) FIG. 6 shows a heat dispersing fin having discrete connecting portions;

(11) FIG. 7a shows an isometric view of a set of fins brazed to a rectangular ceramic heater element;

(12) FIG. 7b shows a different view of two sets of fins brazed to an arcuate ceramic heater element;

(13) FIG. 8a shows an isometric view of a set of varying height fins brazed to a rectangular a ceramic heater element;

(14) FIG. 8b shows a side view of a set of varying height fins brazed to a ceramic heater element;

(15) FIG. 9a shows an isometric view of a set of folded fins brazed to a ceramic heater element;

(16) FIG. 9b shows a side view of a set of folded fins brazed to a ceramic heater element;

(17) FIG. 10a shows a cross-section through a brazed fin;

(18) FIG. 10b shows a side view through a brazed fin;

(19) FIG. 11a shows an isometric view of an arcuate brazed heater;

(20) FIG. 11b shows an expanded view of a portion of the view of FIG. 11a;

(21) FIG. 12a shows a first side of a retaining structure for a heater prototype;

(22) FIG. 12b shows an assembled retaining structure for a heater template;

(23) FIG. 13a shows a side view of fins of varying spacing;

(24) FIG. 13b shows a side view of fins having staggered discrete connecting portions;

(25) FIG. 14a shows an end view of a heater in an enclosure;

(26) FIG. 14b shows an isometric view of a heater in an enclosure;

(27) FIG. 15a shows a cross-section through an appliance suitable for accommodating a heater according to some embodiments;

(28) FIG. 15b shows a partial isometric view of an appliance suitable for accommodating a heater according to some embodiments; and

(29) FIG. 16 shows a side view of an alternative appliance suitable for accommodating a heater according to some embodiments.

DETAILED DESCRIPTION OF THE INVENTION

(30) According to some embodiments, a method includes a first step of making an HTCC heater element. Three exemplary materials for the element include aluminium oxide, aluminium nitride and silicon nitride. Commercially available materials may be used. For example, materials commercially available from Precision Ceramics (e.g., with the grade of alumina being 99.6% alumina, product description AT 79, the grade of aluminium nitride available in 2015, and the silicon nitride, product description SL 200 BG). The ceramic heater elements may be formed initially from a rectangular substrate which when sintered forms 70 mm×30 mm×0.5 mm coupons. A first layer of the green state ceramic may have a tungsten track screen printed onto a surface. The tungsten may be formed into a slurry with material of the same composition as the ceramic used to form the heater element and then a second layer of the green state ceramic may be applied. This may be sintered at over 1000° C., for example, around 1800° C. The resulting embedded tungsten track may have a thickness of 18-20 microns. FIG. 3 shows an example of two tracks 300, 310. The skilled person will appreciate that different ceramic compositions and sizes of coupons will require different sintering conditions and that such information is widely available in a multitude of text books.

(31) Table 1 shows different exemplary combinations of ceramic and metal that were evaluated.

(32) TABLE-US-00001 TABLE 1 Copper C103 Stainless Steel S430 Kovar Single Single Multi- Single Multi- Ceramic sheet sheet section sheet section Al.sub.2O.sub.3 5 coupons 5 coupons 5 coupons 5 coupons 5 coupons Al.sub.3N.sub.4 5 coupons 5 coupons 5 coupons 5 coupons 5 coupons Si.sub.3N.sub.4 5 coupons 5 coupons 5 coupons 5 coupons 5 coupons

(33) The brazing process was carried out on coupons (rectangular portions) of 70 mm×30 mm×0.5 mm of the ceramic heater element 10 in a vacuum furnace at 850° C. using a braze filler 20. The braze filler was 0.05 mm thick foil of AgCuTi active brazing, the metal 30 was only applied to one side of the ceramic which resulted in post brazing warpage and could account for some of the failures. Table 2 details the post brazing survival rate for the different combinations. FIG. 1 shows a side view of the construction and FIG. 2 details the difference between the single sheet 40 of the metal and the multi sections sheet 50. The multi sectioned sheet 50 was a first attempt to relieve the stress by having a discontinuous bond between the ceramic and the metal material. Relief cuts 52 were made into the metal in two directions on the side to be bonded to the ceramic heater element 10.

(34) TABLE-US-00002 TABLE 2 Copper C103 Stainless Steel S430 Kovar Single Single Multi- Single Multi- Ceramic sheet sheet section sheet section Al.sub.2O.sub.3 100% (5/5) 0% (0/5) 0% (0/5) 100% (5/5) 80% (4/5) Al.sub.3N.sub.4 100% (5/5) 0% (0/5) 0% (0/5)  0% (0/5) 20% (1/5) Si.sub.3N.sub.4 100% (5/5) 0% (0/5) 0% (0/5)  60% (3/5) 40% (2/5)

(35) Without being bound by any theory, it is thought that the stainless steel samples failed as a result of the brazing process being below the temperature of plastic deformation for this alloy thus, the metal side of the joint can only deform elastically which introduces stress into the joint. Conversely, copper can yield to reduce the build-up of stresses.

(36) A further investigation used heat dissipating fins. The fins 44, 54 are planar sheets which extend orthogonally away from a base portion 42, 56 respectively. In FIG. 4a the base portion 42 is a single rectangular sheet with integral fins 44. The fins 44 and base 42 are formed from a block of copper which is machined to remove the material between the fins 60. In FIG. 4b the fins 54 and base 56 are also integral and formed from an arcuate block of copper which is machined to produce arcuate fins 54 integral to an arcuate base 56. FIGS. 5a and 5b show a multi sectioned sheet 50 with integral heat dissipating fins 54. These samples were formed from a block of Kovar which was machined to remove the material from between the fins 54 and to provide the relief cuts 52 in the base to provide discrete connecting portions 58. The same fin geometry was used on the straight or rectangular samples and the same brazing conditions. The brazing survival rates are shown in Table 3.

(37) TABLE-US-00003 TABLE 3 Copper C103 Kovar Ceramic Straight Curved Straight Al.sub.2O.sub.3  0% (0/3)  0% (0/1) 67% (2/3) Al.sub.3N.sub.4 67% (2/3) 100% (1/1) 33% (1/3)

(38) The surviving samples were tested by thermally cycling them but all failed by cracking at the metal ceramic joint due to a build-up of stress. For the copper samples this is believed to be via cold working which increases the strength of the copper over time along with a mismatch ion the coefficient of thermal expansion.

(39) A third trial was carried out using an aluminium heat dispersing fin 60 (FIG. 6). The specific alloy chosen was (Al 1050-O) as the material properties of this alloy are more conducive to making a successful heater as it has a lower yield strength and is less work hardening.

(40) Referring now to FIGS. 6 to 11b, the heat dispersing fins 60 in this trial had a much smaller footprint on the ceramic heater element. Individual fins made from aluminium 1050-O sheets having a thickness t of 0.3 mm and 0.5 mm included discrete contacting portions 62 at the base create a multi-sectioned interface with the ceramic. The fin assemblies 160 were identical on each side of the ceramic heater element to balance the momentum on the ceramic. The contact points 1 and d of the fins were 2 mm×2 mm but further tests were also carried out with 1.5 mm×1.4 mm (see FIGS. 10a and 10b). Each fin 60 is made from stamped metal sheet which reduces raw material costs and the manufacturing complexity from the previous complex 3-dimensional shape that required either milling or metal injection moulding.

(41) For straight fins, the metal sheet profiles were cut with EDM wire (FIG. 6); and the feet are bent with a 90° V-press tool. For curved profiles, there is a final curved stamping process.

(42) Having individual fins 60 may require a fixture to keep all fins in place during brazing; the material chosen was graphite due to the temperatures of the brazing process and as it would not react. A fixture was designed and is shown in FIGS. 12a and 12b. A first part 200 retains one side of the fins, the ceramic heating element 10 is aligned and then a second part 210 of the fixture containing the other side 160a of the fins 60 is attached.

(43) As the fins are aluminium, active brazing was not used (the temperature is too high).

(44) The process was carried out as follows. First the surfaces of the ceramic heater element 10 were first cleaned thoroughly then coated with a primary metallizing layer 100. This is a 10-12 micron tungsten layer which is screen printed onto each side of the ceramic heater element. The tungsten is applied as an element in a metallisation paste and then coated part is sintered. The same ceramic material is used as a component in the tungsten paste so the same sintering conditions are used.

(45) The secondary layer 110, on top of the tungsten, is a 3-5 micron electroless nickel coating. For this trial the nickel alloy used was Ni-11P coating (near the eutectic). The process is also known as an ‘electrolytic’ or ‘autocatalytic’ process. This nickel layer prevents surface oxidation of the tungsten layer in air and improves wetting of the braze filler. A heat treatment at approximately 800° C. in a reducing atmosphere is used to diffuse this layer into the tungsten primary layer.

(46) As an alternative to using electroless plating, other forms of electroplating can be used, for example brush electroplating or dip electroplating.

(47) A flux material is applied to each electroplated surface. One example of a flux is Harris Al braze-1070 flux which was applied using a brush applicator. On each side of the metallised ceramic heater element 100, 110 initially 0.082+/−0.003 g was used. In a further test 0.0808+/−0.002 g was added per side. The flux material contains both aluminium and silicon and melts during the brazing process, removing oxides and improving the wetting of the surfaces. The addition of silicon as an alloying element in the filler lowers the melting point and the viscosity of the molten metal, which improves the alloy's gap-filling capability. The eutectic composition allows the lowest melting point of the binary alloy, and lowest viscosity (a transition from a single solid phase to a single liquid phase).

(48) Finally, a braze filler material 120 is applied over the flux material. An example of a filler material is Prince and Izant Al-718. This is provided as a foil which is 590 microns thick. In a first example a single sheet of the foil was used providing 0.271+/−0.004 g of filler material per side. A second example used 0.527+/−0.006 g of filler material per side (two 50 micron foil layers per side).

(49) Another example of a suitable material is NOCOLOK® Sil Flux” from Solvay. This combines filler and flux in one paste so removes the need for two step application.

(50) The heat sink material chosen was Al1050-O grade which is a commercially pure grade that has undergone an annealing heat treatment process. The heat sink is a non-traditional ‘finned heat sink’ because the ‘heat sink base’ has been removed and only the fins are used. These fins are directly bonded to the heat generating surface using a ‘flanged tee’ joint.

(51) The fins 60 are created from rolled sheet through EDM wire cutting and bending processes. As part of the cutting process, small cuts are created at the bottom of the fins. This effectively produces a plurality of legs 64 and inbetween each adjacent pair of legs, parallel slots 66 that extend from one edge of the metal sheet towards the distal end. A second stage is to produce the discrete connecting portions; this is achieved by bending the metal sheet in a 90° V-press tool. This forms a plurality of “L-shaped” features having a leg 64 which forms part of the fin proper and a foot portion which forms the discrete connecting portion 62 for each leg.

(52) The brazing process is carried out in a furnace. Some samples were brazed in a vacuum furnace but this was found to be unnecessary and increased the dwell time required as only radiation was used to heat the sample. Further processes were carried out in a reducing atmosphere at approximately one atmosphere of pressure. The heater template is assembled within an enclosure 200, 210 and placed in the furnace at room temperature and then heated to around 610° C. in an atmosphere of 95% nitrogen and 5% hydrogen. The heating process took around an hour, in this case this was the highest for the furnace used and potentially higher rates could be used which would reduce the brazing time. The temperature was held for a pre-determined time and then cooled to room temperature. The pre-determined time was around 2 minutes, but this is dependent on the thermal mass of the enclosure 200, 210 and the heater so is subject to change dependent on these factors.

(53) After removal from the furnace, the heater was washed in an ultrasonic hot water bath at 40° C. to remove flux residue from between the discrete connecting portions.

(54) Theoretically, this joint should not work due to Coefficient of Thermal Expansion (CTE) mismatch between the ceramic and the metal. Also, if the two materials were joined without fracture of the ceramic, the joint would not survive many thermal cycles.

(55) By using individual fins 60, there is a reduction in the contact area between the heat sink and the ceramic heating element 10 this limits the problems caused by the mismatch is thermal expansion coefficient in one orientation—across the width of the ceramic heater element. In addition, by having the discrete points of contact 62 along each individual fin 60, the problem caused by the mismatch is thermal expansion coefficient in another orientation—along the length of the ceramic heater element 10. The discrete connecting portions act as stress relief cuts.

(56) A few variations in the form of the ceramic heater will now be discussed. The fins 60 may be all of the same height as shown in FIGS. 7a and 7b. This is the simplest embodiment of the brazed heater. As most hair care appliances have a tubular casing, the fins can be made of a varying height. FIGS. 8a and 8b show this. At least one fin 60 is at the maximum height. In this example two fins 60 are of the maximum height and to make the heater tubular these are located in the middle of the ceramic heater element. The ceramic heater element 10 is defined by a first edge 12 and a second edge 14 so the middle of the ceramic heater element 10 is between these edges. As we approach either of the first edge 12 and the second edge 14, the fins 60a, 60b, 60c get progressively shorter in height to form the tubular shape.

(57) As previously described, FIG. 3a shows an example of heater tracks 300, 310 in a rectangular ceramic heater element. In this example power to both tracks 300, 310 is provided at a first end 320 of the ceramic heater element via a first pair of connectors 324 and a second pair of connectors 326 is provided at a second end 322 of the ceramic heater element 10. As the skilled person will know, the connectors can be positioned at different locations along the ceramic heater element.

(58) FIG. 3b shows an arcuate ceramic heater element 150. In this example the two heater tracks 302, 312 are not adjacent as before, rather they are side by side and share a common connection 330 which is located centrally along the length of the ceramic heater element 150 between the first end 320 and the second end 322. This common connector can be either the live or neutral connector. For the first track 320 a second connector 332 is provided adjacent the first end 320 of the ceramic heater element 150 and for the second track 312 a second connector 334 is provided adjacent the second end 322 of the ceramic heater element 150. These second two connectors 332, 334 are the other of the live and neutral connectors.

(59) As an alternative to the connectors being provided along an edge of the ceramic heater element 150, FIGS. 13a and 13b show a different arrangement. In these examples the heater tracks are interlaced as with FIG. 3a but all the connectors 340, 342, 344 are provide at a first end 332 of the ceramic heater element 150. Again one of the connectors 344 is a shared connector and provided either the live or the neutral connector to the ceramic heater element 150 and the other two connectors 340, 344 are the other of the live and neutral connectors.

(60) FIGS. 11a and 11b show a brazed heater with fins of varying height 60, 60a, 60b, 60c and 60d as described with respect to FIGS. 8a and 8b but brazed onto an arcuate ceramic heater element 150.

(61) FIG. 13a shows a brazed heater with fins 60 having varying spacing. The arcuate ceramic heater element 150 has an inner radius ri and an outer radius ro each having a common centre c. At the inner radius ri there is a fin spacing of xi and at the outer radius ro there is a fin spacing of xo where xo is greater than xi thus the spacing between the fins gradually increase from the inner radius ri towards the outer radius ro. The variable spacing helps with thermal and flow management as fluid in the heater flows from the first end 322 to the second end 324. The flow restriction in each channel (space between fins) is changed. This is a design variable which allows flow to be redistributed. The outer radius of the heater has a longer channel length (longer fins). A given volume of air will spend more time these channels, heating up more as it through the channel. If the spacing between fins is increased in this area, the flow rate in these channels will increase. This reduces the dwell time, so there is less heating of the air. In this example the inner radius was around 29 mm and the outer radius around 59 mm. The centre path length, this being the mid line between the inner radius and the outer radius is 69 mm. The height of a fin 60 is around 13 mm.

(62) FIG. 13b illustrates that the fins 60 do not need necessarily to be aligned at the first end 322. Depending on the configuration of the inlet side 350 of the heater, it may not be possible to have the discrete connecting portions 62 starting at a common distance from this inlet side 350, thus a first fin 600 may be staggered with respect to an adjacent fin 602, 604.

(63) Referring now to FIGS. 14a and 14b, a heater 80 is shown in an enclosure 82. Traditionally such an enclosure would be made from an insulating material, such as mica. For the straight heater examples herein described mica would be acceptable. However, for the arcuate heaters, it is difficult to wind the mica sheets especially at the centre on the inner radius as the length on mica that would be required is less than on the outer radius. Due to this and the fact that the heat dissipating fins are not live, a metal enclosure can be used. With a more traditional wire heater this would not be possible as there would be a risk of the live heater element contacting the enclosure, perhaps after some damage is sustained. In theory, the enclosure 82 can be designed to contact the heater 80 however, it was found that having a small gap 90 between a fin tip 84 and both the first edge 86 and the second edge 86 of the ceramic heater element 150 is useful. A gap 90 of 0.5 mm to 2 mm was used as this gave a sufficient air gap to allow control of the flow around the curve and thermal management of the temperature of the enclosure. Thus, the outer surface of the enclosure 82 was 75° C. at an ambient temperature of 25° C.

(64) FIGS. 15a and 15b show an example of a hairdryer in which the heater described can be used. The hairdryer 700 has a fluid inlet 702 at one end of a handle 720, a fluid flow path 704 extending from the fluid inlet 702 through the handle 720 to a fluid outlet 706. Fluid is drawn into the fluid inlet 702 by a motor 710 located within the handle 720. In this example, the heater 80 is curved or arcuate and resides in a transition region from a first orientation of the handle 720 to a second orientation of the fluid outlet 706. In this example the second orientation is orthogonal to the first orientation, but that is a preferred feature as when a user holds the handle the fluid outlet can be easily turned with respect to the users' hair.

(65) The ceramic heater element herein described is designed to withstand 400° C. with a power input of 1500 W at a maximum fluid temperature at the outlet of 125° C. Table 4 shows a range of parameters that were achieved.

(66) TABLE-US-00004 TABLE 4 Max. exit Track 1 Track 2 Flow rate temp temp temp Power Heater_P   9 std l = s  76° C. 106° C. 124° C. 514 W 469 Pa 101° C. 161° C. 186° C. 766 W 506 Pa 124° C. 213° C. 244° C. 1003 W  541 Pa   11 std l = s  76° C. 110° C. 130° C. 584 W 617 Pa 101° C. 170° C. 198° C. 895 W 689 Pa 125° C. 229° C. 264° C. 1197 W  734 Pa 13.5 std l = s  75° C. 112° C. 132° C. 663 W 875 Pa 101° C. 178° C. 208° C. 1038 W  947 Pa 129° C. 260° C. 301° C. 1504 W  1050 Pa 

(67) Within the hairdryer shown in FIGS. 15a and 15b, the envelope for the heater 80 and enclosure 82—the heater assembly—has a maximum outer diameter of 35 mm. This heater 80 has been demonstrated to provide a heating element power of 1500 W at 13.5 l/s air flow through the hairdryer with a maximum heater assembly pressure drop of 1000 Pa at 13.5 l/s air and 1500 W input power. In addition with the varying fin spacing shown in FIG. 13a a maximum temperature difference of ±5 deg C. across the exiting air flow cross section.

(68) FIGS. 9a and 9b show an alternative embodiment where the fins 260 are not formed as separate stamped sheets instead a single sheet of metal is folded into a corrugated or castellated form with a base portion 262 which is adapted to be brazed to the ceramic heater element 62. The process of forming the discrete connecting areas 264 is carried out after the stamping process but in the same manner as before. However, each fin 260 shares a discrete connecting area 264 rather than having an individual one. This further minimises the contact area and so regions of thermal mismatch between the metal fin and the ceramic heater element. In addition, there is a top section 264 which is fed heat via two adjacent fins 260a, 260b so the thermal delivery towards the fin tip is increased.

(69) FIG. 16 shows a further example of a hot styling device 800 that is suitable for use with the straight heater as shown in FIG. 7b. The device is tubular in shape, has a fluid inlet 802 at one end and a fluid outlet 804 at the distal end with a fluid flow path in between. In use, a fan unit draws fluid into the fluid inlet and a heater optionally heats the fluid before it exits the device at the fluid outlet.

(70) The invention has been described in detail with respect to a hairdryer and a hot styling device however, it is applicable to any appliance that draws in a fluid and directs the outflow of that fluid from the appliance.

(71) The appliance can be used with or without a heater; the action of the outflow of fluid at high velocity has a drying effect.

(72) The fluid that flows through the appliance is generally air, but may be a different combination of gases or gas and can include additives to improve performance of the appliance or the impact the appliance has on an object the output is directed at for example, hair and the styling of that hair.

(73) The invention is not limited to the detailed description given above. Variations will be apparent to the person skilled in the art.