Method and apparatus for recovering fibers embedded in a composite material

Abstract

A method for recovering fibers embedded in a composite material including loading a furnace chamber with a volume of the composite material; thermolyzing the composite material in the furnace chamber, resulting in a gaseous fraction that is continuously evacuated from the furnace chamber, and a residue of fibers covered with char that is left in the furnace chamber; cracking the gaseous fraction from the thermolyzing operation, resulting in a mixture of condensable and non-condensable gases that can be recycled; injecting a stream of an oxygen-containing gas into the still hot furnace chamber after the thermolyzing is completed therein, to burn the char from the fibers in an exothermic combustion.

Claims

1. A method for recovering fibers embedded in a composite material including using two furnace chambers, the method comprising: loading a first furnace chamber with a volume of a composite material; thermolyzing the composite material in said first furnace chamber, resulting in a gaseous fraction that is continuously evacuated from the first furnace chamber, and a residue of fibers covered with char that is left in the first furnace chamber; cracking the gaseous fraction from the thermolyzing, resulting in a mixture of one or more condensable gases with one or more non-condensable gases; injecting a stream of an oxygen-containing gas into the still hot first furnace chamber after the thermolyzing is completed therein, to burn the char from the fibers in an exothermic combustion; loading a second furnace chamber with a volume of the composite material; thermolyzing the composite material in the second furnace chamber, with heat being contributed by the combustion that is taking or has taken place in the first furnace chamber, resulting in a gaseous fraction that is continuously evacuated from the second furnace chamber, and a residue of fibers covered with char that is left in the second furnace chamber; cracking the gaseous fraction from the thermolyzing in the second furnace chamber, resulting in a mixture of one or more condensable with one or more non-condensable gases; unloading clean fibers from the first furnace chamber and loading the first furnace chamber with a volume of the composite material; injecting a stream of an oxygen-containing gas into the still hot second furnace chamber after the thermolyzing is completed therein, in order to burn the char from the fibers in an exothermic combustion; thermolyzing the composite material in the first furnace chamber, with heat being contributed by the combustion that is taking or has taken place in the second furnace chamber, resulting in a gaseous fraction that is continuously evacuated from the first furnace chamber, and a residue of fibers covered with char that is left in the first furnace chamber; cracking the gaseous fraction from the thermolyzing in the first furnace chamber, resulting in a mixture of condensable and non-condensable gases; unloading clean fibers from the second furnace chamber and loading the second furnace chamber with a volume of the composite material; injecting a stream of an oxygen-containing gas into the still hot first furnace chamber after the thermolyzing is completed therein, to burn the char from the fibers in an exothermic combustion.

2. The method of claim 1, the thermolyzing being a pyrolysis.

3. The method of claim 2, the pyrolysis being performed with the first furnace chamber at a temperature of 350-600° C.

4. The method of claim 3, the oxygen-containing gas being air enriched with an additional 2-20% in volume of oxygen in comparison to normal air.

5. The method of claim 2, the cracking being performed by circulating the gaseous fraction through a reducing agent.

6. The method of claim 1, the cracking being performed by circulating the gaseous fraction through a reducing agent.

7. The method of claim 6, the reducing agent being kept at a temperature of 250-400° C.

8. The method of claim 1, further comprising using the one or more non-condensable gases for contributing heat to the first furnace chamber in the thermolyzing.

9. The method of claim 8, the thermolysis being performed under vacuum.

10. The method of claim 1, the thermolyzing being performed under vacuum.

11. The method of claim 1, the oxygen-containing gas being air enriched with an additional 2-20% in volume of oxygen in comparison to normal air.

12. The method of claim 1, the thermolyzing lasting between 1 and 4 hours.

13. The method of claim 1, the combustion lasting between 1 and 4 hours.

14. The method of claim 1, further comprising using the one or more non-condensable gases for contributing heat to one furnace chamber in the thermolyzing.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) Non-limiting examples of the present disclosure will be described in the following, with reference to the appended drawings, in which:

(2) FIG. 1 is a schematic view of an apparatus for recovering fibers embedded in a composite material;

(3) FIG. 2 is another schematic view of the apparatus of FIG. 1;

(4) FIG. 3 is schematic view that illustrates a use of the apparatus of FIG. 1;

(5) FIG. 4 is schematic view that illustrates another use of the apparatus of FIG. 1; and

(6) FIG. 5 is a schematic view of two furnace chambers of an apparatus for recovering fibers embedded in a composite material.

DETAILED DESCRIPTION OF EXAMPLES

(7) The apparatus of FIGS. 1 and 2 includes a furnace 1 provided with a furnace chamber 10, a burner 11 for the chamber 10, a first outlet 12 from the chamber 10, an inlet 13 to the chamber 10 and a second outlet 14 therefrom. The first outlet 12 leads (through a conduit) to a reducing member 20 including a reducing agent 21, for example zeolite or an SiC catalyst. Downstream from the catalyst is a condenser 31, from which non-condensable gases can be brought, through a filter 32, to the burner 11.

(8) The inlet 13 allows for injection of a stream of air (or other oxygen-containing gas) into the furnace chamber 10, and the second outlet 14 is to evacuate combustion gases from the furnace chamber 10 to a separator (e.g. a cyclone) 41 and some further filters 42. The apparatus also includes suitable valves in the conduits.

(9) The operation with the apparatus is as follows (the goal is to extract clean fibers from a discarded part made of a polymer-based composite material with embedded fibers, e.g. glass or carbon fibers, for example a removed wind turbine blade): A. Cut or pound the composite part into small pieces or fragments. B. Introduce a suitable volume of such fragments 18 (FIG. 3) into the furnace chamber 10. C. Pyrolyze (or, more generally, thermolize) the composite material 18 present in the furnace chamber 10 at a temperature of 350-600° C., preferably of about 550° C., until the matrix (for example, resin-made) of the composite material is completely decomposed. D. Continuously extract the gaseous fraction produced in the pyrolysis through the first outlet 12, and crack this gaseous fraction by passing it through the reducing agent 21, which is kept at a temperature of 250-400° C., preferably of about 350° C. E. Bring the gases produced in the cracking process into the condenser 31, where they are rapidly cooled down (to under 10° C.) in order to obtain two different fuels: a condensed gas (i.e. a liquid fuel to be sold or anyhow used) and a non-condensable gas which is separated and brought into the burner 11, after being filtered through filter 32.

(10) The reducing agent 21 is thermostated, i.e., its temperature is carefully controlled in order to optimize the cracking reactions. The non-condensable gas or gases brought into the burner 11 are burned therein and thus contribute thermal energy to the pyrolysis (at the beginning, when this recycled fuel is not available yet, an external fuel can be used, for example propane), or, alternatively, instead of bringing the non-condensable gas to the burner 11, the non-condensable gas can be used to drive a turbine (not shown) in a cogeneration process. The condensed gases can be collected in different containers depending on their condensation temperatures.

(11) Apart from the gaseous fraction, the other result of the pyrolysis is a heap of fibers covered with char 19 (FIG. 4), and the operation goes on as follows: F. Just after the pyrolysis has been completed, inject a stream of an oxygen-containing gas (for example air or oxygen-enriched air, e.g. air enriched with 6%-volume of O.sub.2) into the furnace chamber 10, which is still very hot from the pyrolysis (basically at the same temperature thereof), until the char is burned-out in an exothermic combustion, leaving the fibers clean. G. Continuously extract the combusted gaseous stream from the furnace chamber 10 through the second outlet 14 and bring said combustion gases into the separator 41, e.g. a cyclone, where they are suitably treated and filtered (at least a part of the combustion gases are carried through the filters 42).

(12) FIG. 3 shows the pyrolysis and cracking processes (operations C, D and E). The solid black valves represent open valves and the white valves represent closed valves. The straight arrows represent gas flows and the curved arrow at the bottom of the condenser 31 would represent a liquid flow (in case the corresponding bottom valve would be open).

(13) FIG. 4 shows the exothermic combustion (operations F and G); as before, the solid black valves represent open valves and the white valves represent closed valves, and the straight arrows represent gas flows. The multi-pointed arrow in chamber 10 represents the char combustion. Operation F can be termed ‘exothermic sweeping’.

(14) FIG. 5 shows another example in which the furnace 1 includes two furnace chambers, a first furnace chamber 10 and a second furnace chamber 15. This apparatus can be operated in batch mode as follows: I. Load furnace chambers 10 and 15 with respective volumes of a composite material. II. Pyrolyze the composite material present in first furnace chamber 10. III. Exothermically sweep the char-covered fibers in first furnace chamber 10. IV. Pyrolyze the composite material present in second furnace chamber 15 using heat from operation III; this pyrolysis and the exothermic sweeping of operation III can start simultaneously. V. Unload the clean fibers from first furnace chamber 10 and load a volume of composite material therein. VI. Exothermically sweep the char-covered fibers in second furnace chamber 15. VII. Pyrolyze the composite material present in first furnace chamber 10 using heat from operation VI; this pyrolysis and the exothermic sweeping of operation VI can start simultaneously. VIII. Unload the clean fibers from second furnace chamber 15 and, unless the current batch operation is finished, load a volume of composite material therein. IX. Continue from operation III.

(15) In experimental examples, the weight-ratio of recycled clean fibers to the fibers initially contained in the composite material was estimated to be of approximately 95%, which shows the effectiveness or the method described above. Besides, the method further produces energy (from the non-condensable gases) and fuel (the condensable gases).

(16) Although only a number of examples have been disclosed herein, other alternatives, modifications, uses and/or equivalents thereof are possible. Furthermore, all possible combinations of the described examples are also covered. Thus, the scope of the present disclosure should not be limited by particular examples, but should be determined only by a fair reading of the claims that follow. If reference signs related to drawings are placed in parentheses in a claim, they are solely for attempting to increase the intelligibility of the claim, and shall not be construed as limiting the scope of the claim.