1. Patent Search
  2. Details

Organic electroluminescent materials and devices

11189805 · 2021-11-30

Assignee

Inventors

Cpc classification

International classification

Abstract

Heteroleptic iridium complexes having the formula ##STR00001##
are disclosed. In this formula, R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, and R.sub.6, are selected from hydrogen, deuterium, cycloalkyl, deuterated cycloalkyl, alkyl, and deuterated alkyl, and can optionally be linked together to form a ring; at least one of R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, and R.sub.6 is cycloalkyl, deuterated cycloalkyl, alkyl, or deuterated alkyl; ring A is attached to the 4- or 5-position of ring B; and R and R′ can represent any of a variety of subsitutents. These iridium compounds contain alkyl substituted phenylpyridine ligands, which provide these compounds with beneficial properties when the iridium complexes are incorporated into OLED devices.

Claims

1. A compound comprising a heteroleptic iridium complex having the formula; ##STR00236## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, and R.sub.6, are independently selected from the group consisting of hydrogen, deuterium, cycloalkyl, deuterated cycloalkyl, alkyl, and deuterated alkyl; wherein any two adjacent R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, and R.sub.6 are optionally linked together to form a ring; wherein ring A is attached to the 4- or 5-position of ring B; wherein R and R′ represent mono-, di-, tri- or tetra-substitution and are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; and wherein at least one of the following is true: (i) at least one of R.sup.1 to R.sup.3 is alkyl or cycloalkyl, and at least one of R.sup.1 to R.sup.3 is deuterated alkyl or deuterated cycloalkyl; (ii) at least one of R.sup.4 to R.sup.6 is alkyl or cycloalkyl, and at least one of R.sup.4 to R.sup.6 is deuterated alkyl or deuterated cycloalkyl; (iii) R.sub.1 and R.sub.3 are both independently selected from cycloalkyl, deuterated cycloalkyl, alkyl and deuterated alkyl; (iv) each of R.sub.1, R.sub.2, and R.sub.3 is independently selected from selected from cycloalkyl, deuterated cycloalkyl, alkyl and deuterated alkyl; (v) at least one of R.sub.1, R.sub.2, and R.sub.3 is cycloalkyl or deuterated cycloalkyl; or (vi) at least one pair of adjacent substituents of R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, and R.sub.6 are linked together to form a ring.

2. The compound of claim 1, wherein the compound has a structure of formula: ##STR00237##

3. The compound of claim 1, wherein the compound has a structure formula: ##STR00238##

4. The compound of claim 1, wherein condition (i) is true.

5. The compound of claim 1, wherein condition (ii) is true.

6. The compound of claim 1, wherein any alkyl contains at least 2 carbons.

7. The compound of claim 1, wherein at least one alkyl contains greater than 10 carbons.

8. The compound of claim 1, wherein the compound is selected from the group consisting of: ##STR00239## ##STR00240## ##STR00241## ##STR00242## ##STR00243##

9. The compound of claim 1, having the formula IrL.sub.A(L.sub.B).sub.2, wherein the heteroleptic iridium complex is selected from the compounds listed in the following table: TABLE-US-00006 Compound Number L.sub.A L.sub.B II-20 L.sub.A46 L.sub.B1 II-21 L.sub.A47 L.sub.B1 II-22 L.sub.A48 L.sub.B1 II-23 L.sub.A49 L.sub.B1 II-24 L.sub.A50 L.sub.B1 II-25 L.sub.A51 L.sub.B1 II-31 L.sub.A57 L.sub.B1 II-32 L.sub.A58 L.sub.B1 II-37 L.sub.A63 L.sub.B1 II-38 L.sub.A64 L.sub.B1 II-39 L.sub.A65 L.sub.B1 II-40 L.sub.A66 L.sub.B1 II-41 L.sub.A67 L.sub.B1 II-42 L.sub.A68 L.sub.B1 II-43 L.sub.A69 L.sub.B1 II-73 L.sub.A46 L.sub.B2 II-74 L.sub.A47 L.sub.B2 II-76 L.sub.A49 L.sub.B2 II-77 L.sub.A50 L.sub.B2 II-78 L.sub.A51 L.sub.B2 II-84 L.sub.A57 L.sub.B2 II-85 L.sub.A58 L.sub.B2 II-90 L.sub.A63 L.sub.B2 II-91 L.sub.A64 L.sub.B2 II-93 L.sub.A66 L.sub.B2 II-94 L.sub.A67 L.sub.B2 II-95 L.sub.A68 L.sub.B2 II-96 L.sub.A69 L.sub.B2 II-140 L.sub.A46 L.sub.B3 II-141 L.sub.A47 L.sub.B3 II-143 L.sub.A49 L.sub.B3 II-144 L.sub.A50 L.sub.B3 II-145 L.sub.A51 L.sub.B3 II-151 L.sub.A57 L.sub.B3 II-152 L.sub.A58 L.sub.B3 II-157 L.sub.A63 L.sub.B3 II-158 L.sub.A64 L.sub.B3 II-160 L.sub.A66 L.sub.B3 II-161 L.sub.A67 L.sub.B3 II-162 L.sub.A68 L.sub.B3 II-163 L.sub.A69 L.sub.B3 II-207 L.sub.A46 L.sub.B4 II-208 L.sub.A47 L.sub.B4 II-210 L.sub.A49 L.sub.B4 II-211 L.sub.A50 L.sub.B4 II-212 L.sub.A51 L.sub.B4 II-218 L.sub.A57 L.sub.B4 II-219 L.sub.A58 L.sub.B4 II-224 L.sub.A63 L.sub.B4 II-225 L.sub.A64 L.sub.B4 II-227 L.sub.A66 L.sub.B4 II-228 L.sub.A67 L.sub.B4 II-229 L.sub.A68 L.sub.B4 II-230 L.sub.A69 L.sub.B4 II-267 L.sub.A40 L.sub.B5 II-268 L.sub.A41 L.sub.B5 II-273 L.sub.A46 L.sub.B5 II-274 L.sub.A47 L.sub.B5 II-276 L.sub.A49 L.sub.B5 II-277 L.sub.A50 L.sub.B5 II-278 L.sub.A51 L.sub.B5 II-284 L.sub.A57 L.sub.B5 II-285 L.sub.A58 L.sub.B5 II-290 L.sub.A63 L.sub.B5 II-291 L.sub.A64 L.sub.B5 II-292 L.sub.A65 L.sub.B5 II-293 L.sub.A66 L.sub.B5 II-294 L.sub.A67 L.sub.B5 II-295 L.sub.A68 L.sub.B5 II-296 L.sub.A69 L.sub.B5 II-340 L.sub.A46 L.sub.B6 II-341 L.sub.A47 L.sub.B6 II-343 L.sub.A49 L.sub.B6 II-344 L.sub.A50 L.sub.B6 II-345 L.sub.A51 L.sub.B6 II-346 L.sub.A52 L.sub.B6 II-351 L.sub.A57 L.sub.B6 II-352 L.sub.A58 L.sub.B6 II-357 L.sub.A63 L.sub.B6 II-358 L.sub.A64 L.sub.B6 II-359 L.sub.A65 L.sub.B6 II-360 L.sub.A66 L.sub.B6 II-361 L.sub.A67 L.sub.B6 II-362 L.sub.A68 L.sub.B6 II-363 L.sub.A69 L.sub.B6 II-407 L.sub.A46 L.sub.B7 II-408 L.sub.A47 L.sub.B7 II-410 L.sub.A49 L.sub.B7 II-411 L.sub.A50 L.sub.B7 II-412 L.sub.A51 L.sub.B7 II-413 L.sub.A52 L.sub.B7 II-418 L.sub.A57 L.sub.B7 II-419 L.sub.A58 L.sub.B7 II-424 L.sub.A63 L.sub.B7 II-425 L.sub.A64 L.sub.B7 II-426 L.sub.A65 L.sub.B7 II-427 L.sub.A66 L.sub.B7 II-428 L.sub.A67 L.sub.B7 II-429 L.sub.A68 L.sub.B7 II-430 L.sub.A69 L.sub.B7 II-463 L.sub.A35 L.sub.B8 II-468 L.sub.A40 L.sub.B8 II-469 L.sub.A41 L.sub.B8 II-474 L.sub.A46 L.sub.B8 II-475 L.sub.A47 L.sub.B8 II-477 L.sub.A49 L.sub.B8 II-478 L.sub.A50 L.sub.B8 II-479 L.sub.A51 L.sub.B8 II-480 L.sub.A52 L.sub.B8 II-485 L.sub.A57 L.sub.B8 II-486 L.sub.A58 L.sub.B8 II-491 L.sub.A63 L.sub.B8 II-492 L.sub.A64 L.sub.B8 II-493 L.sub.A65 L.sub.B8 II-494 L.sub.A66 L.sub.B8 II-495 L.sub.A67 L.sub.B8 II-496 L.sub.A68 L.sub.B8 II-497 L.sub.A69 L.sub.B8 II-501 L.sub.A6 L.sub.B9 II-502 L.sub.A7 L.sub.B9 II-507 L.sub.A12 L.sub.B9 II-508 L.sub.A13 L.sub.B9 II-510 L.sub.A15 L.sub.B9 II-511 L.sub.A16 L.sub.B9 II-512 L.sub.A17 L.sub.B9 II-513 L.sub.A18 L.sub.B9 II-517 L.sub.A24 L.sub.B9 II-518 L.sub.A25 L.sub.B9 II-523 L.sub.A30 L.sub.B9 II-524 L.sub.A31 L.sub.B9 II-526 L.sub.A33 L.sub.B9 II-527 L.sub.A34 L.sub.B9 II-528 L.sub.A35 L.sub.B9 II-538 L.sub.A46 L.sub.B9 II-539 L.sub.A47 L.sub.B9 II-541 L.sub.A49 L.sub.B9 II-542 L.sub.A50 L.sub.B9 II-543 L.sub.A51 L.sub.B9 II-548 L.sub.A57 L.sub.B9 II-549 L.sub.A58 L.sub.B9 II-554 L.sub.A63 L.sub.B9 II-555 L.sub.A64 L.sub.B9 II-556 L.sub.A65 L.sub.B9 II-557 L.sub.A66 L.sub.B9 II-558 L.sub.A67 L.sub.B9 II-559 L.sub.A68 L.sub.B9 II-560 L.sub.A69 L.sub.B9 II-566 L.sub.A6 L.sub.B10 II-567 L.sub.A7 L.sub.B10 II-572 L.sub.A12 L.sub.B10 II-573 L.sub.A13 L.sub.B10 II-574 L.sub.A14 L.sub.B10 II-575 L.sub.A15 L.sub.B10 II-576 L.sub.A16 L.sub.B10 II-577 L.sub.A17 L.sub.B10 II-578 L.sub.A18 L.sub.B10 II-584 L.sub.A24 L.sub.B10 II-585 L.sub.A25 L.sub.B10 II-590 L.sub.A30 L.sub.B10 II-591 L.sub.A31 L.sub.B10 II-592 L.sub.A32 L.sub.B10 II-593 L.sub.A33 L.sub.B10 II-594 L.sub.A34 L.sub.B10 II-595 L.sub.A35 L.sub.B10 II-606 L.sub.A46 L.sub.B10 II-607 L.sub.A47 L.sub.B10 II-609 L.sub.A49 L.sub.B10 II-610 L.sub.A50 L.sub.B10 II-611 L.sub.A51 L.sub.B10 II-617 L.sub.A57 L.sub.B10 II-618 L.sub.A58 L.sub.B10 II-623 L.sub.A63 L.sub.B10 II-624 L.sub.A64 L.sub.B10 II-626 L.sub.A66 L.sub.B10 II-627 L.sub.A67 L.sub.B10 II-628 L.sub.A68 L.sub.B10 II-629 L.sub.A69 L.sub.B10 II-635 L.sub.A6 L.sub.B11 II-636 L.sub.A7 L.sub.B11 II-641 L.sub.A12 L.sub.B11 II-642 L.sub.A13 L.sub.B11 II-644 L.sub.A15 L.sub.B11 II-645 L.sub.A16 L.sub.B11 II-646 L.sub.A17 L.sub.B11 II-647 L.sub.A18 L.sub.B11 II-653 L.sub.A24 L.sub.B11 II-654 L.sub.A25 L.sub.B11 II-659 L.sub.A30 L.sub.B11 II-660 L.sub.A31 L.sub.B11 II-661 L.sub.A32 L.sub.B11 II-662 L.sub.A33 L.sub.B11 II-663 L.sub.A34 L.sub.B11 II-664 L.sub.A35 L.sub.B11 II-675 L.sub.A46 L.sub.B11 II-676 L.sub.A47 L.sub.B11 II-677 L.sub.A48 L.sub.B11 II-678 L.sub.A49 L.sub.B11 II-679 L.sub.A50 L.sub.B11 II-680 L.sub.A51 L.sub.B11 II-686 L.sub.A57 L.sub.B11 II-687 L.sub.A58 L.sub.B11 II-692 L.sub.A63 L.sub.B11 II-693 L.sub.A64 L.sub.B11 II-695 L.sub.A66 L.sub.B11 II-696 L.sub.A67 L.sub.B11 II-697 L.sub.A68 L.sub.B11 II-698 L.sub.A69 L.sub.B11 II-702 L.sub.A6 L.sub.B12 II-703 L.sub.A7 L.sub.B12 II-708 L.sub.A12 L.sub.B12 II-709 L.sub.A13 L.sub.B12 II-711 L.sub.A15 L.sub.B12 II-712 L.sub.A16 L.sub.B12 II-713 L.sub.A17 L.sub.B12 II-714 L.sub.A18 L.sub.B12 II-718 L.sub.A24 L.sub.B12 II-719 L.sub.A25 L.sub.B12 II-724 L.sub.A30 L.sub.B12 II-725 L.sub.A31 L.sub.B12 II-727 L.sub.A33 L.sub.B12 II-728 L.sub.A34 L.sub.B12 II-729 L.sub.A35 L.sub.B12 II-733 L.sub.A40 L.sub.B12 II-734 L.sub.A41 L.sub.B12 II-739 L.sub.A46 L.sub.B12 II-740 L.sub.A47 L.sub.B12 II-742 L.sub.A49 L.sub.B12 II-743 L.sub.A50 L.sub.B12 II-744 L.sub.A51 L.sub.B12 II-749 L.sub.A57 L.sub.B12 II-750 L.sub.A58 L.sub.B12 II-755 L.sub.A63 L.sub.B12 II-756 L.sub.A64 L.sub.B12 II-758 L.sub.A66 L.sub.B12 II-759 L.sub.A67 L.sub.B12 II-760 L.sub.A68 L.sub.B12 II-761 L.sub.A69 L.sub.B12 II-767 L.sub.A6 L.sub.B13 II-768 L.sub.A7 L.sub.B13 II-773 L.sub.A12 L.sub.B13 II-774 L.sub.A13 L.sub.B13 II-775 L.sub.A14 L.sub.B13 II-776 L.sub.A15 L.sub.B13 II-777 L.sub.A16 L.sub.B13 II-778 L.sub.A17 L.sub.B13 II-779 L.sub.A18 L.sub.B13 II-785 L.sub.A24 L.sub.B13 II-786 L.sub.A25 L.sub.B13 II-791 L.sub.A30 L.sub.B13 II-792 L.sub.A31 L.sub.B13 II-794 L.sub.A33 L.sub.B13 II-795 L.sub.A34 L.sub.B13 II-796 L.sub.A35 L.sub.B13 II-807 L.sub.A46 L.sub.B13 II-808 L.sub.A47 L.sub.B13 II-810 L.sub.A49 L.sub.B13 II-811 L.sub.A50 L.sub.B13 II-812 L.sub.A51 L.sub.B13 II-813 L.sub.A52 L.sub.B13 II-818 L.sub.A57 L.sub.B13 II-819 L.sub.A58 L.sub.B13 II-824 L.sub.A63 L.sub.B13 II-825 L.sub.A64 L.sub.B13 II-827 L.sub.A66 L.sub.B13 II-828 L.sub.A67 L.sub.B13 II-829 L.sub.A68 L.sub.B13 II-830 L.sub.A69 L.sub.B13 II-836 L.sub.A6 L.sub.B14 II-837 L.sub.A7 L.sub.B14 II-842 L.sub.A12 L.sub.B14 II-843 L.sub.A13 L.sub.B14 II-845 L.sub.A15 L.sub.B14 II-846 L.sub.A16 L.sub.B14 II-847 L.sub.A17 L.sub.B14 II-848 L.sub.A18 L.sub.B14 II-854 L.sub.A24 L.sub.B14 II-855 L.sub.A25 L.sub.B14 II-860 L.sub.A30 L.sub.B14 II-861 L.sub.A31 L.sub.B14 II-863 L.sub.A33 L.sub.B14 II-864 L.sub.A34 L.sub.B14 II-865 L.sub.A35 L.sub.B14 II-876 L.sub.A46 L.sub.B14 II-877 L.sub.A47 L.sub.B14 II-878 L.sub.A48 L.sub.B14 II-879 L.sub.A49 L.sub.B14 II-880 L.sub.A50 L.sub.B14 II-881 L.sub.A51 L.sub.B14 II-882 L.sub.A52 L.sub.B14 II-887 L.sub.A57 L.sub.B14 II-888 L.sub.A58 L.sub.B14 II-893 L.sub.A63 L.sub.B14 II-894 L.sub.A64 L.sub.B14 II-896 L.sub.A66 L.sub.B14 II-897 L.sub.A67 L.sub.B14 II-898 L.sub.A68 L.sub.B14 II-899 L.sub.A69 L.sub.B14 II-905 L.sub.A6 L.sub.B15 II-906 L.sub.A7 L.sub.B15 II-911 L.sub.A12 L.sub.B15 II-912 L.sub.A13 L.sub.B15 II-914 L.sub.A15 L.sub.B15 II-915 L.sub.A16 L.sub.B15 II-916 L.sub.A17 L.sub.B15 II-917 L.sub.A18 L.sub.B15 II-923 L.sub.A24 L.sub.B15 II-924 L.sub.A25 L.sub.B15 II-929 L.sub.A30 L.sub.B15 II-930 L.sub.A31 L.sub.B15 II-932 L.sub.A33 L.sub.B15 II-933 L.sub.A34 L.sub.B15 II-934 L.sub.A35 L.sub.B15 II-939 L.sub.A40 L.sub.B15 II-940 L.sub.A41 L.sub.B15 II-945 L.sub.A46 L.sub.B15 II-946 L.sub.A47 L.sub.B15 II-948 L.sub.A49 L.sub.B15 II-949 L.sub.A50 L.sub.B15 II-950 L.sub.A51 L.sub.B15 II-956 L.sub.A57 L.sub.B15 II-957 L.sub.A58 L.sub.B15 II-962 L.sub.A63 L.sub.B15 II-963 L.sub.A64 L.sub.B15 II-965 L.sub.A66 L.sub.B15 II-966 L.sub.A67 L.sub.B15 II-967 L.sub.A68 L.sub.B15 II-968 L.sub.A69 L.sub.B15 II-972 L.sub.A6 L.sub.B16 II-973 L.sub.A7 L.sub.B16 II-978 L.sub.A12 L.sub.B16 II-979 L.sub.A13 L.sub.B16 II-981 L.sub.A15 L.sub.B16 II-982 L.sub.A16 L.sub.B16 II-983 L.sub.A17 L.sub.B16 II-984 L.sub.A18 L.sub.B16 II-988 L.sub.A24 L.sub.B16 II-989 L.sub.A25 L.sub.B16 II-994 L.sub.A30 L.sub.B16 II-995 L.sub.A31 L.sub.B16 II-997 L.sub.A33 L.sub.B16 II-998 L.sub.A34 L.sub.B16 II-999 L.sub.A35 L.sub.B16 II-1003 L.sub.A40 L.sub.B16 II-1004 L.sub.A41 L.sub.B16 II-1009 L.sub.A46 L.sub.B16 II-1010 L.sub.A47 L.sub.B16 II-1012 L.sub.A49 L.sub.B16 II-1013 L.sub.A50 L.sub.B16 II-1014 L.sub.A51 L.sub.B16 II-1019 L.sub.A57 L.sub.B16 II-1020 L.sub.A58 L.sub.B16 II-1025 L.sub.A63 L.sub.B16 II-1026 L.sub.A64 L.sub.B16 II-1028 L.sub.A66 L.sub.B16 II-1029 L.sub.A67 L.sub.B16 II-1030 L.sub.A68 L.sub.B16 II-1031 L.sub.A69 L.sub.B16 II-1036 L.sub.A6 L.sub.B17 II-1037 L.sub.A7 L.sub.B17 II-1042 L.sub.A12 L.sub.B17 II-1043 L.sub.A13 L.sub.B17 II-1045 L.sub.A15 L.sub.B17 II-1046 L.sub.A16 L.sub.B17 II-1047 L.sub.A17 L.sub.B17 II-1048 L.sub.A18 L.sub.B17 II-1053 L.sub.A24 L.sub.B17 II-1054 L.sub.A25 L.sub.B17 II-1059 L.sub.A30 L.sub.B17 II-1060 L.sub.A31 L.sub.B17 II-1062 L.sub.A33 L.sub.B17 II-1063 L.sub.A34 L.sub.B17 II-1064 L.sub.A35 L.sub.B17 II-1075 L.sub.A46 L.sub.B17 II-1076 L.sub.A47 L.sub.B17 II-1077 L.sub.A48 L.sub.B17 II-1078 L.sub.A49 L.sub.B17 II-1079 L.sub.A50 L.sub.B17 II-1080 L.sub.A51 L.sub.B17 II-1086 L.sub.A57 L.sub.B17 II-1087 L.sub.A58 L.sub.B17 II-1093 L.sub.A64 L.sub.B17 II-1095 L.sub.A66 L.sub.B17 II-1096 L.sub.A67 L.sub.B17 II-1097 L.sub.A68 L.sub.B17 II-1098 L.sub.A69 L.sub.B17 II-1103 L.sub.A6 L.sub.B18 II-1104 L.sub.A7 L.sub.B18 II-1109 L.sub.A12 L.sub.B18 II-1110 L.sub.A13 L.sub.B18 II-1112 L.sub.A15 L.sub.B18 II-1113 L.sub.A16 L.sub.B18 II-1114 L.sub.A17 L.sub.B18 II-1115 L.sub.A18 L.sub.B18 II-1120 L.sub.A24 L.sub.B18 II-1121 L.sub.A25 L.sub.B18 II-1126 L.sub.A30 L.sub.B18 II-1127 L.sub.A31 L.sub.B18 II-1129 L.sub.A33 L.sub.B18 II-1130 L.sub.A34 L.sub.B18 II-1131 L.sub.A35 L.sub.B18 II-1142 L.sub.A46 L.sub.B18 II-1143 L.sub.A47 L.sub.B18 II-1145 L.sub.A49 L.sub.B18 II-1146 L.sub.A50 L.sub.B18 II-1147 L.sub.A31 L.sub.B18 II-1153 L.sub.A57 L.sub.B18 II-1154 L.sub.A58 L.sub.B18 II-1159 L.sub.A63 L.sub.B18 II-1160 L.sub.A64 L.sub.B18 II-1162 L.sub.A66 L.sub.B18 II-1163 L.sub.A67 L.sub.B18 II-1164 L.sub.A68 L.sub.B18 II-1165 L.sub.A69 L.sub.B18 II-1170 L.sub.A6 L.sub.B19 II-1171 L.sub.A7 L.sub.B19 II-1176 L.sub.A12 L.sub.B19 II-1177 L.sub.A13 L.sub.B19 II-1179 L.sub.A15 L.sub.B19 II-1180 L.sub.A16 L.sub.B19 II-1181 L.sub.A17 L.sub.B19 II-1182 L.sub.A18 L.sub.B19 II-1187 L.sub.A24 L.sub.B19 II-1188 L.sub.A25 L.sub.B19 II-1193 L.sub.A30 L.sub.B19 II-1194 L.sub.A31 L.sub.B19 II-1196 L.sub.A33 L.sub.B19 II-1197 L.sub.A34 L.sub.B19 II-1198 L.sub.A35 L.sub.B19 II-1209 L.sub.A46 L.sub.B19 II-1210 L.sub.A47 L.sub.B19 II-1212 L.sub.A49 L.sub.B19 II-1213 L.sub.A50 L.sub.B19 II-1214 L.sub.A51 L.sub.B19 II-1220 L.sub.A57 L.sub.B19 II-1221 L.sub.A58 L.sub.B19 II-1226 L.sub.A63 L.sub.B19 II-1227 L.sub.A64 L.sub.B19 II-1229 L.sub.A66 L.sub.B19 II-1230 L.sub.A67 L.sub.B19 II-1231 L.sub.A68 L.sub.B19 II-1232 L.sub.A69 L.sub.B19 II-1237 L.sub.A6 L.sub.B20 II-1238 L.sub.A7 L.sub.B20 II-1243 L.sub.A12 L.sub.B20 II-1244 L.sub.A13 L.sub.B20 II-1246 L.sub.A15 L.sub.B20 II-1247 L.sub.A16 L.sub.B20 II-1248 L.sub.A17 L.sub.B20 II-1249 L.sub.A18 L.sub.B20 II-1254 L.sub.A24 L.sub.B20 II-1255 L.sub.A25 L.sub.B20 II-1260 L.sub.A30 L.sub.B20 II-1261 L.sub.A31 L.sub.B20 II-1263 L.sub.A33 L.sub.B20 II-1264 L.sub.A34 L.sub.B20 II-1265 L.sub.A35 L.sub.B20 II-1276 L.sub.A46 L.sub.B20 II-1277 L.sub.A47 L.sub.B20 II-1279 L.sub.A49 L.sub.B20 II-1280 L.sub.A50 L.sub.B20 II-1281 L.sub.A51 L.sub.B20 II-1287 L.sub.A57 L.sub.B20 II-1288 L.sub.A58 L.sub.B20 II-1293 L.sub.A63 L.sub.B20 II-1294 L.sub.A64 L.sub.B20 II-1296 L.sub.A66 L.sub.B20 II-1297 L.sub.A67 L.sub.B20 II-1298 L.sub.A68 L.sub.B20 II-1299 L.sub.A69 L.sub.B20 II-1304 L.sub.A6 L.sub.B21 II-1305 L.sub.A7 L.sub.B21 II-1310 L.sub.A12 L.sub.B21 II-1311 L.sub.A13 L.sub.B21 II-1313 L.sub.A15 L.sub.B21 II-1314 L.sub.A16 L.sub.B21 II-1315 L.sub.A17 L.sub.B21 II-1316 L.sub.A18 L.sub.B21 II-1321 L.sub.A24 L.sub.B21 II-1322 L.sub.A25 L.sub.B21 II-1327 L.sub.A30 L.sub.B21 II-1328 L.sub.A31 L.sub.B21 II-1330 L.sub.A33 L.sub.B21 II-1331 L.sub.A34 L.sub.B21 II-1332 L.sub.A35 L.sub.B21 II-1343 L.sub.A46 L.sub.B21 II-1344 L.sub.A47 L.sub.B21 II-1346 L.sub.A49 L.sub.B21 II-1347 L.sub.A50 L.sub.B21 II-1348 L.sub.A51 L.sub.B21 II-1354 L.sub.A57 L.sub.B21 II-1355 L.sub.A58 L.sub.B21 II-1360 L.sub.A63 L.sub.B21 II-1361 L.sub.A64 L.sub.B21 II-1363 L.sub.A66 L.sub.B21 II-1364 L.sub.A67 L.sub.B21 II-1365 L.sub.A68 L.sub.B21 II-1366 L.sub.A69 L.sub.B21 II-1371 L.sub.A6 L.sub.B22 II-1372 L.sub.A7 L.sub.B22 II-1377 L.sub.A12 L.sub.B22 II-1378 L.sub.A13 L.sub.B22 II-1380 L.sub.A15 L.sub.B22 II-1381 L.sub.A16 L.sub.B22 II-1382 L.sub.A17 L.sub.B22 II-1383 L.sub.A18 L.sub.B22 II-1368 L.sub.A24 L.sub.B22 II-1369 L.sub.A25 L.sub.B22 II-1374 L.sub.A30 L.sub.B22 II-1375 L.sub.A31 L.sub.B22 II-1377 L.sub.A33 L.sub.B22 II-1378 L.sub.A34 L.sub.B22 II-1379 L.sub.A35 L.sub.B22 II-1390 L.sub.A46 L.sub.B22 II-1391 L.sub.A47 L.sub.B22 II-1393 L.sub.A49 L.sub.B22 II-1394 L.sub.A50 L.sub.B22 II-1395 L.sub.A51 L.sub.B22 II-1401 L.sub.A57 L.sub.B22 II-1402 L.sub.A58 L.sub.B22 II-1407 L.sub.A63 L.sub.B22 II-1408 L.sub.A64 L.sub.B22 II-1410 L.sub.A66 L.sub.B22 II-1411 L.sub.A67 L.sub.B22 II-1412 L.sub.A68 L.sub.B22 II-1413 L.sub.A69 L.sub.B22 II-1419 L.sub.A6 L.sub.B23 II-1420 L.sub.A7 L.sub.B23 II-1425 L.sub.A12 L.sub.B23 II-1426 L.sub.A13 L.sub.B23 II-1428 L.sub.A15 L.sub.B23 II-1429 L.sub.A16 L.sub.B23 II-1430 L.sub.A17 L.sub.B23 II-1431 L.sub.A18 L.sub.B23 II-1437 L.sub.A24 L.sub.B23 II-1438 L.sub.A25 L.sub.B23 II-1443 L.sub.A30 L.sub.B23 II-1444 L.sub.A31 L.sub.B23 II-1446 L.sub.A33 L.sub.B23 II-1447 L.sub.A34 L.sub.B23 II-1448 L.sub.A35 L.sub.B23 II-1459 L.sub.A46 L.sub.B23 II-1460 L.sub.A47 L.sub.B23 II-1462 L.sub.A49 L.sub.B23 II-1463 L.sub.A50 L.sub.B23 II-1464 L.sub.A51 L.sub.B23 II-1470 L.sub.A57 L.sub.B23 II-1471 L.sub.A58 L.sub.B23 II-1476 L.sub.A63 L.sub.B23 II-1477 L.sub.A64 L.sub.B23 II-1479 L.sub.A66 L.sub.B23 II-1480 L.sub.A67 L.sub.B23 II-1481 L.sub.A68 L.sub.B23 II-1482 L.sub.A69 L.sub.B23 II-1488 L.sub.A6 L.sub.B24 II-1489 L.sub.A7 L.sub.B24 II-1494 L.sub.A12 L.sub.B24 II-1495 L.sub.A13 L.sub.B24 II-1497 L.sub.A15 L.sub.B24 II-1498 L.sub.A16 L.sub.B24 II-1499 L.sub.A17 L.sub.B24 II-1500 L.sub.A18 L.sub.B24 II-1506 L.sub.A24 L.sub.B24 II-1507 L.sub.A25 L.sub.B24 II-1512 L.sub.A30 L.sub.B24 II-1513 L.sub.A31 L.sub.B24 II-1515 L.sub.A33 L.sub.B24 II-1516 L.sub.A34 L.sub.B24 II-1517 L.sub.A35 L.sub.B24 II-1528 L.sub.A46 L.sub.B24 II-1529 L.sub.A47 L.sub.B24 II-1531 L.sub.A49 L.sub.B24 II-1532 L.sub.A50 L.sub.B24 II-1533 L.sub.A51 L.sub.B24 II-1539 L.sub.A57 L.sub.B24 II-1540 L.sub.A58 L.sub.B24 II-1545 L.sub.A63 L.sub.B24 II-1546 L.sub.A64 L.sub.B24 II-1548 L.sub.A66 L.sub.B24 II-1549 L.sub.A67 L.sub.B24 II-1550 L.sub.A68 L.sub.B24 II-1551 L.sub.A69 L.sub.B24 II-1557 L.sub.A6 L.sub.B25 II-1558 L.sub.A7 L.sub.B25 II-1563 L.sub.A12 L.sub.B25 II-1564 L.sub.A13 L.sub.B25 II-1566 L.sub.A15 L.sub.B25 II-1567 L.sub.A16 L.sub.B25 II-1568 L.sub.A17 L.sub.B25 II-1569 L.sub.A18 L.sub.B25 II-1575 L.sub.A24 L.sub.B25 II-1576 L.sub.A25 L.sub.B25 II-1581 L.sub.A30 L.sub.B25 II-1582 L.sub.A31 L.sub.B25 II-1584 L.sub.A33 L.sub.B25 II-1585 L.sub.A34 L.sub.B25 II-1586 L.sub.A35 L.sub.B25 II-1597 L.sub.A46 L.sub.B25 II-1598 L.sub.A47 L.sub.B25 II-1600 L.sub.A49 L.sub.B25 II-1601 L.sub.A50 L.sub.B25 II-1602 L.sub.A51 L.sub.B25 II-1608 L.sub.A57 L.sub.B25 II-1609 L.sub.A58 L.sub.B25 II-1614 L.sub.A63 L.sub.B25 II-1615 L.sub.A64 L.sub.B25 II-1617 L.sub.A66 L.sub.B25 II-1618 L.sub.A67 L.sub.B25 II-1619 L.sub.A68 L.sub.B25 II-1620 L.sub.A69 L.sub.B25 II-1626 L.sub.A6 L.sub.B26 II-1627 L.sub.A7 L.sub.B26 II-1632 L.sub.A12 L.sub.B26 II-1633 L.sub.A13 L.sub.B26 II-1635 L.sub.A15 L.sub.B26 II-1636 L.sub.A16 L.sub.B26 II-1637 L.sub.A17 L.sub.B26 II-1638 L.sub.A18 L.sub.B26 II-1644 L.sub.A24 L.sub.B26 II-1645 L.sub.A25 L.sub.B26 II-1650 L.sub.A30 L.sub.B26 II-1651 L.sub.A31 L.sub.B26 II-1653 L.sub.A33 L.sub.B26 II-1654 L.sub.A34 L.sub.B26 II-1655 L.sub.A35 L.sub.B26 II-1666 L.sub.A46 L.sub.B26 II-1667 L.sub.A47 L.sub.B26 II-1669 L.sub.A49 L.sub.B26 II-1670 L.sub.A50 L.sub.B26 II-1671 L.sub.A51 L.sub.B26 II-1677 L.sub.A57 L.sub.B26 II-1678 L.sub.A58 L.sub.B26 II-1683 L.sub.A63 L.sub.B26 II-1684 L.sub.A64 L.sub.B26 II-1686 L.sub.A66 L.sub.B26 II-1687 L.sub.A67 L.sub.B26 II-1688 L.sub.A68 L.sub.B26 II-1689 L.sub.A69 L.sub.B26 II-1695 L.sub.A6 L.sub.B27 II-1696 L.sub.A7 L.sub.B27 II-1701 L.sub.A12 L.sub.B27 II-1702 L.sub.A13 L.sub.B27 II-1704 L.sub.A15 L.sub.B27 II-1705 L.sub.A16 L.sub.B27 II-1706 L.sub.A17 L.sub.B27 II-1707 L.sub.A18 L.sub.B27 II-1713 L.sub.A24 L.sub.B27 II-1714 L.sub.A25 L.sub.B27 II-1719 L.sub.A30 L.sub.B27 II-1720 L.sub.A31 L.sub.B27 II-1722 L.sub.A33 L.sub.B27 II-1723 L.sub.A34 L.sub.B27 II-1724 L.sub.A35 L.sub.B27 II-1735 L.sub.A46 L.sub.B27 II-1736 L.sub.A47 L.sub.B27 II-1738 L.sub.A49 L.sub.B27 II-1739 L.sub.A50 L.sub.B27 II-1740 L.sub.A51 L.sub.B27 II-1746 L.sub.A57 L.sub.B27 II-1747 L.sub.A58 L.sub.B27 II-1752 L.sub.A63 L.sub.B27 II-1753 L.sub.A64 L.sub.B27 II-1755 L.sub.A66 L.sub.B27 II-1756 L.sub.A67 L.sub.B27 II-1757 L.sub.A68 L.sub.B27 II-1758 L.sub.A69 L.sub.B27 II-1764 L.sub.A6 L.sub.B28 II-1765 L.sub.A7 L.sub.B28 II-1770 L.sub.A12 L.sub.B28 II-1771 L.sub.A13 L.sub.B28 II-1773 L.sub.A15 L.sub.B28 II-1774 L.sub.A16 L.sub.B28 II-1775 L.sub.A17 L.sub.B28 II-1776 L.sub.A18 L.sub.B28 II-1782 L.sub.A24 L.sub.B28 II-1783 L.sub.A25 L.sub.B28 II-1788 L.sub.A30 L.sub.B28 II-1789 L.sub.A31 L.sub.B28 II-1791 L.sub.A33 L.sub.B28 II-1792 L.sub.A34 L.sub.B28 II-1793 L.sub.A35 L.sub.B28 II-1804 L.sub.A46 L.sub.B28 II-1805 L.sub.A47 L.sub.B28 II-1807 L.sub.A49 L.sub.B28 II-1808 L.sub.A50 L.sub.B28 II-1809 L.sub.A51 L.sub.B28 II-1815 L.sub.A57 L.sub.B28 II-1816 L.sub.A58 L.sub.B28 II-1821 L.sub.A63 L.sub.B28 II-1822 L.sub.A64 L.sub.B28 II-1824 L.sub.A66 L.sub.B28 II-1825 L.sub.A67 L.sub.B28 II-1826 L.sub.A68 L.sub.B28 II-1827 L.sub.A69 L.sub.B28, wherein each L.sub.A is defined as follows: ##STR00244## ##STR00245## ##STR00246## ##STR00247## ##STR00248## ##STR00249## ##STR00250## ##STR00251## wherein each L.sub.B is defined as follows: ##STR00252## ##STR00253## ##STR00254## ##STR00255## ##STR00256##

10. The compound of claim 1, having the formula IrL.sub.A(L.sub.B).sub.2, wherein the heteroleptic iridium complex is selected from the compounds in the following table: TABLE-US-00007 Compound Number L.sub.A L.sub.B II-1 L.sub.A6 L.sub.B1 II-2 L.sub.A12 L.sub.B1 II-3 L.sub.A13 L.sub.B1 II-4 L.sub.A16 L.sub.B1 II-5 L.sub.A17 L.sub.B1 II-6 L.sub.A24 L.sub.B1 II-7 L.sub.A30 L.sub.B1 II-8 L.sub.A31 L.sub.B1 II-9 L.sub.A34 L.sub.B1 II-10 L.sub.A35 L.sub.B1 II-20 L.sub.A46 L.sub.B1 II-21 L.sub.A47 L.sub.B1 II-23 L.sub.A49 L.sub.B1 II-24 L.sub.A50 L.sub.B1 II-25 L.sub.A51 L.sub.B1 II-31 L.sub.A57 L.sub.B1 II-32 L.sub.A58 L.sub.B1 II-37 L.sub.A63 L.sub.B1 II-38 L.sub.A64 L.sub.B1 II-40 L.sub.A66 L.sub.B1 II-41 L.sub.A67 L.sub.B1 II-42 L.sub.A68 L.sub.B1 II-43 L.sub.A69 L.sub.B1 II-44 L.sub.A6 L.sub.B2 II-45 L.sub.A7 L.sub.B2 II-49 L.sub.A12 L.sub.B2 II-50 L.sub.A13 L.sub.B2 II-51 L.sub.A16 L.sub.B2 II-52 L.sub.A17 L.sub.B2 II-56 L.sub.A24 L.sub.B2 II-60 L.sub.A30 L.sub.B2 II-61 L.sub.A31 L.sub.B2 II-62 L.sub.A34 L.sub.B2 II-63 L.sub.A35 L.sub.B2 II-73 L.sub.A46 L.sub.B2 II-74 L.sub.A47 L.sub.B2 II-76 L.sub.A49 L.sub.B2 II-77 L.sub.A50 L.sub.B2 II-78 L.sub.A51 L.sub.B2 II-84 L.sub.A57 L.sub.B2 II-85 L.sub.A58 L.sub.B2 II-90 L.sub.A63 L.sub.B2 II-91 L.sub.A64 L.sub.B2 II-93 L.sub.A66 L.sub.B2 II-94 L.sub.A67 L.sub.B2 II-95 L.sub.A68 L.sub.B2 II-96 L.sub.A69 L.sub.B2 II-101 L.sub.A6 L.sub.B3 II-102 L.sub.A7 L.sub.B3 II-107 L.sub.A12 L.sub.B3 II-108 L.sub.A13 L.sub.B3 II-110 L.sub.A15 L.sub.B3 II-111 L.sub.A16 L.sub.B3 II-112 L.sub.A17 L.sub.B3 II-113 L.sub.A18 L.sub.B3 II-118 L.sub.A24 L.sub.B3 II-119 L.sub.A25 L.sub.B3 II-124 L.sub.A30 L.sub.B3 II-125 L.sub.A31 L.sub.B3 II-127 L.sub.A33 L.sub.B3 II-128 L.sub.A34 L.sub.B3 II-129 L.sub.A35 L.sub.B3 II-140 L.sub.A46 L.sub.B3 II-141 L.sub.A47 L.sub.B3 II-143 L.sub.A49 L.sub.B3 II-144 L.sub.A50 L.sub.B3 II-145 L.sub.A51 L.sub.B3 II-146 L.sub.A52 L.sub.B3 II-151 L.sub.A57 L.sub.B3 II-152 L.sub.A58 L.sub.B3 II-157 L.sub.A63 L.sub.B3 II-158 L.sub.A64 L.sub.B3 II-160 L.sub.A66 L.sub.B3 II-161 L.sub.A67 L.sub.B3 II-162 L.sub.A68 L.sub.B3 II-163 L.sub.A69 L.sub.B3 II-168 L.sub.A6 L.sub.B3 II-169 L.sub.A7 L.sub.B3 II-174 L.sub.A12 L.sub.B4 II-175 L.sub.A13 L.sub.B4 II-177 L.sub.A15 L.sub.B4 II-178 L.sub.A16 L.sub.B4 II-179 L.sub.A17 L.sub.B4 II-180 L.sub.A18 L.sub.B4 II-185 L.sub.A24 L.sub.B4 II-186 L.sub.A25 L.sub.B4 II-191 L.sub.A30 L.sub.B4 II-192 L.sub.A31 L.sub.B4 II-194 L.sub.A33 L.sub.B4 II-195 L.sub.A34 L.sub.B4 II-196 L.sub.A35 L.sub.B4 II-207 L.sub.A46 L.sub.B4 II-208 L.sub.A47 L.sub.B4 II-210 L.sub.A49 L.sub.B4 II-211 L.sub.A50 L.sub.B4 II-212 L.sub.A51 L.sub.B4 II-218 L.sub.A57 L.sub.B4 II-219 L.sub.A58 L.sub.B4 II-224 L.sub.A63 L.sub.B4 II-225 L.sub.A64 L.sub.B4 II-227 L.sub.A66 L.sub.B4 II-228 L.sub.A67 L.sub.B4 II-229 L.sub.A68 L.sub.B4 II-230 L.sub.A69 L.sub.B4 II-234 L.sub.A6 L.sub.B5 II-235 L.sub.A7 L.sub.B5 II-240 L.sub.A12 L.sub.B5 II-241 L.sub.A13 L.sub.B5 II-243 L.sub.A15 L.sub.B5 II-244 L.sub.A16 L.sub.B5 II-245 L.sub.A17 L.sub.B5 II-246 L.sub.A18 L.sub.B5 II-251 L.sub.A24 L.sub.B5 II-252 L.sub.A25 L.sub.B5 II-257 L.sub.A30 L.sub.B5 II-258 L.sub.A31 L.sub.B5 II-260 L.sub.A33 L.sub.B5 II-261 L.sub.A34 L.sub.B5 II-262 L.sub.A35 L.sub.B5 II-267 L.sub.A40 L.sub.B5 II-268 L.sub.A41 L.sub.B5 II-273 L.sub.A46 L.sub.B5 II-274 L.sub.A47 L.sub.B5 II-276 L.sub.A49 L.sub.B5 II-277 L.sub.A50 L.sub.B5 II-278 L.sub.A51 L.sub.B5 II-284 L.sub.A57 L.sub.B5 II-285 L.sub.A58 L.sub.B5 II-290 L.sub.A63 L.sub.B5 II-291 L.sub.A64 L.sub.B5 II-293 L.sub.A66 L.sub.B5 II-294 L.sub.A67 L.sub.B5 II-295 L.sub.A68 L.sub.B5 II-296 L.sub.A69 L.sub.B5 II-301 L.sub.A6 L.sub.B6 II-302 L.sub.A7 L.sub.B6 II-307 L.sub.A12 L.sub.B6 II-308 L.sub.A13 L.sub.B6 II-310 L.sub.A15 L.sub.B6 II-311 L.sub.A16 L.sub.B6 II-312 L.sub.A17 L.sub.B6 II-313 L.sub.A18 L.sub.B6 II-318 L.sub.A24 L.sub.B6 II-319 L.sub.A25 L.sub.B6 II-324 L.sub.A30 L.sub.B6 II-325 L.sub.A31 L.sub.B6 II-327 L.sub.A33 L.sub.B6 II-328 L.sub.A34 L.sub.B6 II-329 L.sub.A35 L.sub.B6 II-340 L.sub.A46 L.sub.B6 II-341 L.sub.A47 L.sub.B6 II-343 L.sub.A49 L.sub.B6 II-344 L.sub.A50 L.sub.B6 II-345 L.sub.A51 L.sub.B6 II-346 L.sub.A52 L.sub.B6 II-351 L.sub.A57 L.sub.B6 II-352 L.sub.A58 L.sub.B6 II-357 L.sub.A63 L.sub.B6 II-358 L.sub.A64 L.sub.B6 II-360 L.sub.A66 L.sub.B6 II-361 L.sub.A67 L.sub.B6 II-362 L.sub.A68 L.sub.B6 II-363 L.sub.A69 L.sub.B6 II-368 L.sub.A6 L.sub.B7 II-369 L.sub.A7 L.sub.B7 II-374 L.sub.A12 L.sub.B7 II-375 L.sub.A13 L.sub.B7 II-377 L.sub.A15 L.sub.B7 II-378 L.sub.A16 L.sub.B7 II-379 L.sub.A17 L.sub.B7 II-380 L.sub.A18 L.sub.B7 II-385 L.sub.A24 L.sub.B7 II-386 L.sub.A25 L.sub.B7 II-391 L.sub.A30 L.sub.B7 II-392 L.sub.A31 L.sub.B7 II-394 L.sub.A33 L.sub.B7 II-395 L.sub.A34 L.sub.B7 II-396 L.sub.A35 L.sub.B7 II-407 L.sub.A46 L.sub.B7 II-408 L.sub.A47 L.sub.B7 II-410 L.sub.A49 L.sub.B7 II-411 L.sub.A50 L.sub.B7 II-412 L.sub.A51 L.sub.B7 II-413 L.sub.A52 L.sub.B7 II-418 L.sub.A57 L.sub.B7 II-419 L.sub.A58 L.sub.B7 II-424 L.sub.A63 L.sub.B7 II-425 L.sub.A64 L.sub.B7 II-427 L.sub.A66 L.sub.B7 II-428 L.sub.A67 L.sub.B7 II-429 L.sub.A68 L.sub.B7 II-430 L.sub.A69 L.sub.B7 II-435 L.sub.A6 L.sub.B8 II-436 L.sub.A7 L.sub.B8 II-441 L.sub.A12 L.sub.B8 II-442 L.sub.13 L.sub.B8 II-444 L.sub.A15 L.sub.B8 II-445 L.sub.A16 L.sub.B8 II-446 L.sub.A17 L.sub.B8 II-447 L.sub.A18 L.sub.B8 II-452 L.sub.A24 L.sub.B8 II-453 L.sub.A25 L.sub.B8 II-458 L.sub.A30 L.sub.B8 II-459 L.sub.A31 L.sub.B8 II-461 L.sub.A33 L.sub.B8 II-462 L.sub.A34 L.sub.B8 II-468 L.sub.A40 L.sub.B8 II-469 L.sub.A41 L.sub.B8 II-474 L.sub.A46 L.sub.B8 II-475 L.sub.A47 L.sub.B8 II-477 L.sub.A49 L.sub.B8 II-478 L.sub.A50 L.sub.B8 II-479 L.sub.A51 L.sub.B8 II-480 L.sub.A52 L.sub.B8 II-485 L.sub.A57 L.sub.B8 II-486 L.sub.A58 L.sub.B8 II-491 L.sub.A63 L.sub.B8 II-492 L.sub.A64 L.sub.B8 II-494 L.sub.A66 L.sub.B8 II-495 L.sub.A67 L.sub.B8 II-496 L.sub.A68 L.sub.B8 II-497 L.sub.A69 L.sub.B8 II-501 L.sub.A6 L.sub.B9 II-502 L.sub.A7 L.sub.B9 II-507 L.sub.A12 L.sub.B9 II-508 L.sub.A13 L.sub.B9 II-510 L.sub.A15 L.sub.B9 II-511 L.sub.A16 L.sub.B9 II-512 L.sub.A17 L.sub.B9 II-513 L.sub.A18 L.sub.B9 II-517 L.sub.A24 L.sub.B9 II-518 L.sub.A25 L.sub.B9 II-523 L.sub.A30 L.sub.B9 II-524 L.sub.A31 L.sub.B9 II-526 L.sub.A33 L.sub.B9 II-527 L.sub.A34 L.sub.B9 II-528 L.sub.A35 L.sub.B9 II-538 L.sub.A46 L.sub.B9 II-539 L.sub.A47 L.sub.B9 II-541 L.sub.A49 L.sub.B9 II-542 L.sub.A50 L.sub.B9 II-543 L.sub.A51 L.sub.B9 II-548 L.sub.A57 L.sub.B9 II-549 L.sub.A58 L.sub.B9 II-554 L.sub.A63 L.sub.B9 II-555 L.sub.A64 L.sub.B9 II-557 L.sub.A66 L.sub.B9 II-558 L.sub.A67 L.sub.B9 II-559 L.sub.A68 L.sub.B9 II-560 L.sub.A69 L.sub.B9 II-566 L.sub.A6 L.sub.B10 II-567 L.sub.A7 L.sub.B10 II-572 L.sub.A12 L.sub.B10 II-573 L.sub.A13 L.sub.B10 II-575 L.sub.A15 L.sub.B10 II-576 L.sub.A16 L.sub.B10 II-577 L.sub.A17 L.sub.B10 II-578 L.sub.A18 L.sub.B10 II-584 L.sub.A24 L.sub.B10 II-585 L.sub.A25 L.sub.B10 II-590 L.sub.A30 L.sub.B10 II-591 L.sub.A31 L.sub.B10 II-593 L.sub.A33 L.sub.B10 II-594 L.sub.A34 L.sub.B10 II-595 L.sub.A35 L.sub.B10 II-606 L.sub.A46 L.sub.B10 II-607 L.sub.A47 L.sub.B10 II-609 L.sub.A49 L.sub.B10 II-610 L.sub.A50 L.sub.B10 II-611 L.sub.A51 L.sub.B10 II-617 L.sub.A57 L.sub.B10 II-618 L.sub.A58 L.sub.B10 II-623 L.sub.A63 L.sub.B10 II-624 L.sub.A64 L.sub.B10 II-626 L.sub.A66 L.sub.B10 II-627 L.sub.A67 L.sub.B10 II-628 L.sub.A68 L.sub.B10 II-629 L.sub.A69 L.sub.B10 II-635 L.sub.A6 L.sub.B11 II-636 L.sub.A7 L.sub.B11 II-641 L.sub.A12 L.sub.B11 II-642 L.sub.A13 L.sub.B11 II-644 L.sub.A15 L.sub.B11 II-645 L.sub.A16 L.sub.B11 II-646 L.sub.A17 L.sub.B11 II-647 L.sub.A18 L.sub.B11 II-653 L.sub.A24 L.sub.B11 II-654 L.sub.A25 L.sub.B11 II-659 L.sub.A30 L.sub.B11 II-660 L.sub.A31 L.sub.B11 II-662 L.sub.A33 L.sub.B11 II-663 L.sub.A34 L.sub.B11 II-664 L.sub.A35 L.sub.B11 II-675 L.sub.A46 L.sub.B11 II-676 L.sub.A47 L.sub.B11 II-678 L.sub.A49 L.sub.B11 II-679 L.sub.A50 L.sub.B11 II-680 L.sub.A51 L.sub.B11 II-686 L.sub.A57 L.sub.B11 II-687 L.sub.A58 L.sub.B11 II-692 L.sub.A63 L.sub.B11 II-693 L.sub.A64 L.sub.B11 II-695 L.sub.A66 L.sub.B11 II-696 L.sub.A67 L.sub.B11 II-697 L.sub.A68 L.sub.B11 II-698 L.sub.A69 L.sub.B11 II-702 L.sub.A6 L.sub.B12 II-703 L.sub.A7 L.sub.B12 II-708 L.sub.A12 L.sub.B12 II-709 L.sub.A13 L.sub.B12 II-711 L.sub.A15 L.sub.B12 II-712 L.sub.A16 L.sub.B12 II-713 L.sub.A17 L.sub.B12 II-714 L.sub.A18 L.sub.B12 II-718 L.sub.A24 L.sub.B12 II-719 L.sub.A25 L.sub.B12 II-724 L.sub.A30 L.sub.B12 II-725 L.sub.A31 L.sub.B12 II-727 L.sub.A33 L.sub.B12 II-728 L.sub.A34 L.sub.B12 II-729 L.sub.A35 L.sub.B12 II-733 L.sub.A40 L.sub.B12 II-734 L.sub.A41 L.sub.B12 II-739 L.sub.A46 L.sub.B12 II-740 L.sub.A47 L.sub.B12 II-742 L.sub.A49 L.sub.B12 II-743 L.sub.A50 L.sub.B12 II-744 L.sub.A51 L.sub.B12 II-749 L.sub.A57 L.sub.B12 II-750 L.sub.A58 L.sub.B12 II-755 L.sub.A63 L.sub.B12 II-756 L.sub.A64 L.sub.B12 II-758 L.sub.A66 L.sub.B12 II-759 L.sub.A67 L.sub.B12 II-760 L.sub.A68 L.sub.B12 II-761 L.sub.A69 L.sub.B12 II-767 L.sub.A6 L.sub.B13 II-768 L.sub.A7 L.sub.B13 II-773 L.sub.A12 L.sub.B13 II-774 L.sub.A13 L.sub.B13 II-776 L.sub.A15 L.sub.B13 II-777 L.sub.A16 L.sub.B13 II-778 L.sub.A17 L.sub.B13 II-779 L.sub.A18 L.sub.B13 II-785 L.sub.A24 L.sub.B13 II-786 L.sub.A25 L.sub.B13 II-791 L.sub.A30 L.sub.B13 II-792 L.sub.A31 L.sub.B13 II-794 L.sub.A33 L.sub.B13 II-795 L.sub.A34 L.sub.B13 II-796 L.sub.A35 L.sub.B13 II-807 L.sub.A46 L.sub.B13 II-808 L.sub.A47 L.sub.B13 II-810 L.sub.A49 L.sub.B13 II-811 L.sub.A50 L.sub.B13 II-812 L.sub.A51 L.sub.B13 II-813 L.sub.A52 L.sub.B13 II-818 L.sub.A57 L.sub.B13 II-819 L.sub.A58 L.sub.B13 II-824 L.sub.A63 L.sub.B13 II-825 L.sub.A64 L.sub.B13 II-827 L.sub.A66 L.sub.B13 II-828 L.sub.A67 L.sub.B13 II-829 L.sub.A68 L.sub.B13 II-830 L.sub.A69 L.sub.B13 II-836 L.sub.A6 L.sub.B14 II-837 L.sub.A7 L.sub.B14 II-842 L.sub.A12 L.sub.B14 II-843 L.sub.A13 L.sub.B14 II-845 L.sub.A15 L.sub.B14 II-846 L.sub.A16 L.sub.B14 II-847 L.sub.A17 L.sub.B14 II-848 L.sub.A18 L.sub.B14 II-854 L.sub.A24 L.sub.B14 II-855 L.sub.A25 L.sub.B14 II-860 L.sub.A30 L.sub.B14 II-861 L.sub.A31 L.sub.B14 II-863 L.sub.A33 L.sub.B14 II-864 L.sub.A34 L.sub.B14 II-865 L.sub.A35 L.sub.B14 II-876 L.sub.A46 L.sub.B14 II-877 L.sub.A47 L.sub.B14 II-879 L.sub.A49 L.sub.B14 II-880 L.sub.A50 L.sub.B14 II-881 L.sub.A51 L.sub.B14 II-882 L.sub.A52 L.sub.B14 II-887 L.sub.A57 L.sub.B14 II-888 L.sub.A58 L.sub.B14 II-893 L.sub.A63 L.sub.B14 II-894 L.sub.A64 L.sub.B14 II-896 L.sub.A66 L.sub.B14 II-897 L.sub.A67 L.sub.B14 II-898 L.sub.A68 L.sub.B14 II-899 L.sub.A69 L.sub.B14 II-905 L.sub.A6 L.sub.B15 II-906 L.sub.A7 L.sub.B15 II-911 L.sub.A12 L.sub.B15 II-912 L.sub.A13 L.sub.B15 II-914 L.sub.A15 L.sub.B15 II-915 L.sub.A16 L.sub.B15 II-916 L.sub.A17 L.sub.B15 II-917 L.sub.A18 L.sub.B15 II-923 L.sub.A24 L.sub.B15 II-924 L.sub.A25 L.sub.B15 II-929 L.sub.A30 L.sub.B15 II-930 L.sub.A31 L.sub.B15 II-932 L.sub.A33 L.sub.B15 II-933 L.sub.A34 L.sub.B15 II-934 L.sub.A35 L.sub.B15 II-939 L.sub.A40 L.sub.B15 II-940 L.sub.A41 L.sub.B15 II-945 L.sub.A46 L.sub.B15 II-946 L.sub.A47 L.sub.B15 II-948 L.sub.A49 L.sub.B15 II-949 L.sub.A50 L.sub.B15 II-950 L.sub.A51 L.sub.B15 II-951 L.sub.A52 L.sub.B15 II-956 L.sub.A57 L.sub.B15 II-957 L.sub.A58 L.sub.B15 II-962 L.sub.A63 L.sub.B15 II-963 L.sub.A64 L.sub.B15 II-965 L.sub.A66 L.sub.B15 II-966 L.sub.A67 L.sub.B15 II-967 L.sub.A68 L.sub.B15 II-968 L.sub.A69 L.sub.B15 II-972 L.sub.A6 L.sub.B16 II-973 L.sub.A7 L.sub.B16 II-978 L.sub.A12 L.sub.B16 II-979 L.sub.A13 L.sub.B16 II-981 L.sub.A15 L.sub.B16 II-982 L.sub.A16 L.sub.B16 II-983 L.sub.A17 L.sub.B16 II-984 L.sub.A18 L.sub.B16 II-988 L.sub.A24 L.sub.B16 II-989 L.sub.A25 L.sub.B16 II-994 L.sub.A30 L.sub.B16 II-995 L.sub.A31 L.sub.B16 II-997 L.sub.A33 L.sub.B16 II-998 L.sub.A34 L.sub.B16 II-999 L.sub.A35 L.sub.B16 II-1003 L.sub.A40 L.sub.B16 II-1004 L.sub.A41 L.sub.B16 II-1009 L.sub.A46 L.sub.B16 II-1010 L.sub.A47 L.sub.B16 II-1012 L.sub.A49 L.sub.B16 II-1013 L.sub.A50 L.sub.B16 II-1014 L.sub.A51 L.sub.B16 II-1019 L.sub.A57 L.sub.B16 II-1020 L.sub.A58 L.sub.B16 II-1025 L.sub.A63 L.sub.B16 II-1026 L.sub.A64 L.sub.B16 II-1028 L.sub.A66 L.sub.B16 II-1029 L.sub.A67 L.sub.B16 II-1030 L.sub.A68 L.sub.B16 II-1031 L.sub.A69 L.sub.B16 II-1075 L.sub.A46 L.sub.B17 II-1076 L.sub.A47 L.sub.B17 II-1078 L.sub.A49 L.sub.B17 II-1079 L.sub.A50 L.sub.B17 II-1080 L.sub.A51 L.sub.B17 II-1086 L.sub.A57 L.sub.B17 II-1087 L.sub.A58 L.sub.B17 II-1093 L.sub.A64 L.sub.B17 II-1095 L.sub.A66 L.sub.B17 II-1096 L.sub.A67 L.sub.B17 II-1097 L.sub.A68 L.sub.B17 II-1098 L.sub.A69 L.sub.B17 II-1142 L.sub.A46 L.sub.B18 II-1143 L.sub.A47 L.sub.B18 II-1145 L.sub.A49 L.sub.B18 II-1146 L.sub.A50 L.sub.B18 II-1147 L.sub.A51 L.sub.B18 II-1153 L.sub.A57 L.sub.B18 II-1154 L.sub.A58 L.sub.B18 II-1159 L.sub.A63 L.sub.B18 II-1160 L.sub.A64 L.sub.B18 II-1162 L.sub.A66 L.sub.B18 II-1163 L.sub.A67 L.sub.B18 II-1164 L.sub.A68 L.sub.B18 II-1165 L.sub.A69 L.sub.B18 II-1209 L.sub.A46 L.sub.B19 II-1210 L.sub.A47 L.sub.B19 II-1212 L.sub.A49 L.sub.B19 II-1213 L.sub.A50 L.sub.B19 II-1214 L.sub.A51 L.sub.B19 II-1220 L.sub.A57 L.sub.B19 II-1221 L.sub.A58 L.sub.B19 II-1226 L.sub.A63 L.sub.B19 II-1227 L.sub.A64 L.sub.B19 II-1229 L.sub.A66 L.sub.B19 II-1230 L.sub.A67 L.sub.B19 II-1231 L.sub.A68 L.sub.B19 II-1232 L.sub.A69 L.sub.B19 II-1276 L.sub.A46 L.sub.B20 II-1277 L.sub.A47 L.sub.B20 II-1279 L.sub.A49 L.sub.B20 II-1280 L.sub.A50 L.sub.B20 II-1281 L.sub.A51 L.sub.B20 II-1287 L.sub.A57 L.sub.B20 II-1288 L.sub.A58 L.sub.B20 II-1293 L.sub.A63 L.sub.B20 II-1294 L.sub.A64 L.sub.B20 II-1296 L.sub.A66 L.sub.B20 II-1297 L.sub.A67 L.sub.B20 II-1298 L.sub.A68 L.sub.B20 II-1299 L.sub.A69 L.sub.B20 II-1343 L.sub.A46 L.sub.B21 II-1344 L.sub.A47 L.sub.B21 II-1346 L.sub.A49 L.sub.B21 II-1347 L.sub.A50 L.sub.B21 II-1348 L.sub.A51 L.sub.B21 II-1354 L.sub.A57 L.sub.B21 II-1355 L.sub.A58 L.sub.B21 II-1360 L.sub.A63 L.sub.B21 II-1361 L.sub.A64 L.sub.B21 II-1363 L.sub.A66 L.sub.B21 II-1364 L.sub.A67 L.sub.B21 II-1365 L.sub.A68 L.sub.B21 II-1366 L.sub.A69 L.sub.B21 II-1401 L.sub.A57 L.sub.B22 II-1402 L.sub.A58 L.sub.B22 II-1407 L.sub.A63 L.sub.B22 II-1408 L.sub.A64 L.sub.B22 II-1410 L.sub.A66 L.sub.B22 II-1411 L.sub.A67 L.sub.B22 II-1412 L.sub.A68 L.sub.B22 II-1413 L.sub.A69 L.sub.B22 II-1419 L.sub.A6 L.sub.B23 II-1420 L.sub.A7 L.sub.B23 II-1425 L.sub.A12 L.sub.B23 II-1426 L.sub.A13 L.sub.B23 II-1428 L.sub.A15 L.sub.B23 II-1429 L.sub.A16 L.sub.B23 II-1430 L.sub.A17 L.sub.B23 II-1431 L.sub.A18 L.sub.B23 II-1437 L.sub.A24 L.sub.B23 II-1438 L.sub.A25 L.sub.B23 II-1443 L.sub.A30 L.sub.B23 II-1444 L.sub.A31 L.sub.B23 II-1446 L.sub.A33 L.sub.B23 II-1447 L.sub.A34 L.sub.B23 II-1448 L.sub.A35 L.sub.B23 II-1459 L.sub.A46 L.sub.B23 II-1460 L.sub.A47 L.sub.B23 II-1462 L.sub.A49 L.sub.B23 II-1463 L.sub.A50 L.sub.B23 II-1464 L.sub.A51 L.sub.B23 II-1470 L.sub.A57 L.sub.B23 II-1471 L.sub.A58 L.sub.B23 II-1476 L.sub.A63 L.sub.B23 II-1477 L.sub.A64 L.sub.B23 II-1479 L.sub.A66 L.sub.B23 II-1480 L.sub.A67 L.sub.B23 II-1481 L.sub.A68 L.sub.B23 II-1482 L.sub.A69 L.sub.B23 II-1488 L.sub.A6 L.sub.B24 II-1489 L.sub.A7 L.sub.B24 II-1494 L.sub.A12 L.sub.B24 II-1495 L.sub.A13 L.sub.B24 II-1497 L.sub.A15 L.sub.B24 II-1498 L.sub.A16 L.sub.B24 II-1499 L.sub.A17 L.sub.B24 II-1500 L.sub.A18 L.sub.B24 II-1506 L.sub.A24 L.sub.B24 II-1507 L.sub.A25 L.sub.B24 II-1512 L.sub.A30 L.sub.B24 II-1513 L.sub.A31 L.sub.B24 II-1515 L.sub.A33 L.sub.B24 II-1516 L.sub.A34 L.sub.B24 II-1517 L.sub.A35 L.sub.B24 II-1528 L.sub.A46 L.sub.B24 II-1529 L.sub.A47 L.sub.B24 II-1531 L.sub.A49 L.sub.B24 II-1532 L.sub.A50 L.sub.B24 II-1533 L.sub.A51 L.sub.B24 II-1539 L.sub.A57 L.sub.B24 II-1540 L.sub.A58 L.sub.B24 II-1545 L.sub.A63 L.sub.B24 II-1546 L.sub.A64 L.sub.B24 II-1548 L.sub.A66 L.sub.B24 II-1549 L.sub.A67 L.sub.B24 II-1550 L.sub.A68 L.sub.B24 II-1551 L.sub.A69 L.sub.B24 II-1557 L.sub.A6 L.sub.B25 II-1558 L.sub.A7 L.sub.B25 II-1563 L.sub.A12 L.sub.B25 II-1564 L.sub.A13 L.sub.B25 II-1566 L.sub.A15 L.sub.B25 II-1567 L.sub.A16 L.sub.B25 II-1568 L.sub.A17 L.sub.B25 II-1569 L.sub.A18 L.sub.B25 II-1575 L.sub.A24 L.sub.B25 II-1576 L.sub.A25 L.sub.B25 II-1581 L.sub.A30 L.sub.B25 II-1582 L.sub.A31 L.sub.B25 II-1584 L.sub.A33 L.sub.B25 II-1585 L.sub.A34 L.sub.B25 II-1586 L.sub.A35 L.sub.B25 II-1597 L.sub.A46 L.sub.B25 II-1598 L.sub.A47 L.sub.B25 II-1600 L.sub.A49 L.sub.B25 II-1601 L.sub.A50 L.sub.B25 II-1602 L.sub.A51 L.sub.B25 II-1608 L.sub.A57 L.sub.B25 II-1609 L.sub.A58 L.sub.B25 II-1614 L.sub.A63 L.sub.B25 II-1615 L.sub.A64 L.sub.B25 II-1617 L.sub.A66 L.sub.B25 II-1618 L.sub.A67 L.sub.B25 II-1619 L.sub.A68 L.sub.B25 II-1620 L.sub.A69 L.sub.B25 II-1626 L.sub.A6 L.sub.B26 II-1627 L.sub.A7 L.sub.B26 II-1632 L.sub.A12 L.sub.B26 II-1633 L.sub.A13 L.sub.B26 II-1635 L.sub.A15 L.sub.B26 II-1636 L.sub.A16 L.sub.B26 II-1637 L.sub.A17 L.sub.B26 II-1638 L.sub.A18 L.sub.B26 II-1644 L.sub.A24 L.sub.B26 II-1645 L.sub.A25 L.sub.B26 II-1650 L.sub.A30 L.sub.B26 II-1651 L.sub.A31 L.sub.B26 II-1653 L.sub.A33 L.sub.B26 II-1654 L.sub.A34 L.sub.B26 II-1655 L.sub.A35 L.sub.B26 II-1666 L.sub.A46 L.sub.B26 II-1667 L.sub.A47 L.sub.B26 II-1669 L.sub.A49 L.sub.B26 II-1670 L.sub.A50 L.sub.B26 II-1671 L.sub.A51 L.sub.B26 II-1677 L.sub.A57 L.sub.B26 II-1678 L.sub.A58 L.sub.B26 II-1683 L.sub.A63 L.sub.B26 II-1684 L.sub.A64 L.sub.B26 II-1686 L.sub.A66 L.sub.B26 II-1687 L.sub.A67 L.sub.B26 II-1688 L.sub.A68 L.sub.B26 II-1689 L.sub.A69 L.sub.B26 II-1695 L.sub.A6 L.sub.B27 II-1696 L.sub.A7 L.sub.B27 II-1701 L.sub.A12 L.sub.B27 II-1702 L.sub.A13 L.sub.B27 II-1704 L.sub.A15 L.sub.B27 II-1705 L.sub.A16 L.sub.B27 II-1706 L.sub.A17 L.sub.B27 II-1707 L.sub.A18 L.sub.B27 II-1713 L.sub.A24 L.sub.B27 II-1714 L.sub.A25 L.sub.B27 II-1719 L.sub.A30 L.sub.B27 II-1720 L.sub.A31 L.sub.B27 II-1722 L.sub.A33 L.sub.B27 II-1723 L.sub.A34 L.sub.B27 II-1724 L.sub.A35 L.sub.B27 II-1735 L.sub.A46 L.sub.B27 II-1736 L.sub.A47 L.sub.B27 II-1738 L.sub.A49 L.sub.B27 II-1739 L.sub.A50 L.sub.B27 II-1740 L.sub.A51 L.sub.B27 II-1746 L.sub.A57 L.sub.B27 II-1747 L.sub.A58 L.sub.B27 II-1752 L.sub.A63 L.sub.B27 II-1753 L.sub.A64 L.sub.B27 II-1755 L.sub.A66 L.sub.B27 II-1756 L.sub.A67 L.sub.B27 II-1757 L.sub.A68 L.sub.B27 II-1758 L.sub.A69 L.sub.B27 II-1764 L.sub.A6 L.sub.B28 II-1765 L.sub.A7 L.sub.B28 II-1770 L.sub.A12 L.sub.B28 II-1771 L.sub.A13 L.sub.B28 II-1773 L.sub.A15 L.sub.B28 II-1774 L.sub.A16 L.sub.B28 II-1775 L.sub.A17 L.sub.B28 II-1776 L.sub.A18 L.sub.B28 II-1782 L.sub.A24 L.sub.B28 II-1783 L.sub.A25 L.sub.B28 II-1788 L.sub.A30 L.sub.B28 II-1789 L.sub.A31 L.sub.B28 II-1791 L.sub.A33 L.sub.B28 II-1792 L.sub.A34 L.sub.B28 II-1793 L.sub.A35 L.sub.B28 II-1804 L.sub.A46 L.sub.B28 II-1805 L.sub.A47 L.sub.B28 II-1807 L.sub.A49 L.sub.B28 II-1808 L.sub.A50 L.sub.B28 II-1809 L.sub.A51 L.sub.B28 II-1815 L.sub.A57 L.sub.B28 II-1816 L.sub.A58 L.sub.B28 II-1821 L.sub.A63 L.sub.B28 II-1822 L.sub.A64 L.sub.B28 II-1824 L.sub.A66 L.sub.B28 II-1825 L.sub.A67 L.sub.B28 II-1826 L.sub.A68 L.sub.B28 II-1827 L.sub.A69 L.sub.B28, wherein each L.sub.A is defined as follows: ##STR00257## ##STR00258## ##STR00259## ##STR00260## ##STR00261## ##STR00262## ##STR00263## ##STR00264## wherein each L.sub.B is defined as follows: ##STR00265## ##STR00266## ##STR00267## ##STR00268## ##STR00269##

11. A heteroleptic iridium complex having a formula IrL.sub.A(L.sub.B).sub.2 selected from the group consisting of Compound II-263 (L.sub.A36, L.sub.B5, Compound II-264 (L.sub.A37, L.sub.B5), Compound II-265 (L.sub.A38, L.sub.B5), Compound II-266 (L.sub.A39, L.sub.B5), Compound II-269 (L.sub.A42, L.sub.B5), Compound II-270 (L.sub.A43, L.sub.B5), Compound II-271 (L.sub.A44, L.sub.B5), Compound II-272 (L.sub.A45, L.sub.B5), Compound II-280 (L.sub.A53, L.sub.B5, Compound II-281 (L.sub.A54, L.sub.B5), Compound II-282 (L.sub.A55, L.sub.B5), Compound II-283 (L.sub.A56, L.sub.B5), Compound II-286 (L.sub.A59, L.sub.B5), Compound II-287 (L.sub.A60, L.sub.B5), Compound II-288 (L.sub.A61, L.sub.B5), Compound II-289 (L.sub.A62, L.sub.B5), Compound II-730 (L.sub.A37, L.sub.B12), Compound II-731 (L.sub.A38, L.sub.B12), Compound II-732 (L.sub.A39, L.sub.B12), Compound II-735 (L.sub.A42, L.sub.B12), Compound II-736 (L.sub.A43, L.sub.B12), Compound II-737 (L.sub.A44, L.sub.B12), Compound II-738 (L.sub.A45, L.sub.B12), Compound II-746 (L.sub.A54, L.sub.B12), Compound II-747 (L.sub.A55, L.sub.B12), Compound II-748 (L.sub.A56, L.sub.B12), Compound II-751 (L.sub.A59, L.sub.B12), Compound II-752 (L.sub.A60, L.sub.B12), Compound II-753 (L.sub.A61, L.sub.B12), Compound II-754 (L.sub.A62, L.sub.B12), Compound II-1470 (L.sub.A57, L.sub.B23), Compound II-1471 (L.sub.A58, L.sub.B23), Compound II-1476 (L.sub.A63, L.sub.B23), Compound II-1477 (L.sub.A64, L.sub.B23), Compound II-1478 (L.sub.A65, L.sub.B23), Compound II-1488 (L.sub.A6, L.sub.B24), Compound II-1489 (L.sub.A7, L.sub.B24), Compound II-1494 (L.sub.A12, L.sub.B24), Compound II-1495 (L.sub.A13, L.sub.B24), Compound II-1539 (L.sub.A57, L.sub.B24), Compound II-1540 (L.sub.A58, L.sub.B24), Compound II-1545 (L.sub.A63, L.sub.B24), Compound II-1546 (L.sub.A64, L.sub.B24), Compound II-1547 (L.sub.A65, L.sub.B24), Compound II-1557 (L.sub.A6, L.sub.B25), Compound II-1558 (L.sub.A7, L.sub.B25), Compound II-1563 (L.sub.A12, L.sub.B25), Compound II-1564 (L.sub.A13, L.sub.B25), Compound II-1677 (L.sub.A57, L.sub.B26), Compound II-1678 (L.sub.A58, L.sub.B26), Compound II-1683 (L.sub.A63, L.sub.B26), Compound II-1684 (L.sub.A64, L.sub.B26), Compound II-1685 (L.sub.A65, L.sub.B26), Compound II-1695 (L.sub.A6, L.sub.B27), Compound II-1696 (L.sub.A7, L.sub.B27), Compound II-1701 (L.sub.A12, L.sub.B27), and Compound II-1702 (L.sub.A13, L.sub.B27), wherein L.sub.A6, L.sub.A7, L.sub.A12, L.sub.A13, L.sub.A36, L.sub.A37, L.sub.A38, L.sub.A39, L.sub.A42, L.sub.A43, L.sub.A44, L.sub.A45, L.sub.A53, L.sub.A54, L.sub.A55, L.sub.A56, L.sub.A57, L.sub.A58, L.sub.A59, L.sub.A60, L.sub.A61, L.sub.A62, L.sub.A63, L.sub.A64, L.sub.A65, are defined as follows: ##STR00270## ##STR00271## ##STR00272## ##STR00273## ##STR00274## ##STR00275## ##STR00276## ##STR00277## ##STR00278## wherein L.sub.B5, L.sub.B12, L.sub.B23, L.sub.B24, L.sub.B25, L.sub.B26, and L.sub.B27 are defined as follows: ##STR00279## ##STR00280## ##STR00281## ##STR00282## and wherein the dashed lines represent bonds to the central iridium atom.

12. A first device comprising a first organic light emitting device, the first organic light emitting device comprising: an anode; a cathode; and an organic layer, disposed between the anode and the cathode, comprising a compound having the formula: ##STR00283## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, and R.sub.6, are independently selected from the group consisting of hydrogen, deuterium, cycloalkyl, deuterated cycloalkyl, alkyl, and deuterated alkyl; wherein any two adjacent R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, and R.sub.6 are optionally linked together to form a ring; wherein ring A is attached to the 4- or 5-position of ring B; wherein R and R′ represent mono-, di-, tri- or tetra-substitution and are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; and wherein at least one of the following is true: (i) at least one of R.sup.1 to R.sup.3 is alkyl or cycloalkyl, and at least one of R.sup.1 to R.sup.3 is deuterated alkyl or deuterated cycloalkyl; (ii) at least one of R.sup.4 to R.sup.6 is alkyl or cycloalkyl, and at least one of R.sup.4 to R.sup.6 is deuterated alkyl or deuterated cycloalkyl; (iii) R.sub.1 and R.sub.3 are both independently selected from cycloalkyl, deuterated cycloalkyl, alkyl and deuterated alkyl; (iv) each of R.sub.1, R.sub.2, and R.sub.3 is independently selected from selected from cycloalkyl, deuterated cycloalkyl, alkyl and deuterated alkyl; (v) at least one of R.sub.1, R.sub.2, and R.sub.3 is cycloalkyl or deuterated cycloalkyl; (vi) at least one pair of adjacent substituents of R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, and R.sub.6 are linked together to form a ring.

13. The first device of claim 12, wherein the organic layer is an emissive layer and the compound is an emissive dopant, or the organic layer is an emissive layer and the compound is a non-emissive dopant.

14. The first device of claim 12, wherein the organic layer further comprises a host, and the host comprises a triphenylene containing benzo-fused thiophene or benzo-fused furan; wherein any substituent in the host is an unfused substituent independently selected from the group consisting of C.sub.nH.sub.2n+1, OC.sub.nH.sub.2n+1, OAr.sub.1, N(C.sub.nH.sub.2n+1).sub.2, N(Ar.sub.1)(Ar.sub.2), CH═CH—C.sub.nH.sub.2n+1, C≡CC.sub.nH.sub.2n+1, Ar.sub.1, Ar.sub.1—Ar.sub.2, C.sub.nH.sub.2n—Ar.sub.1, wherein n is from 1 to 10; and wherein Ar.sub.1 and Ar.sub.2 are independently selected from the group consisting of benzene, biphenyl, naphthalene, triphenylene, carbazole, and heteroaromatic analogs thereof.

15. The first device of claim 12, wherein the first device further comprises a second emissive dopant having a peak wavelength of between 400 to 500 nanometers, and the second emissive dopant is a fluorescent emitter.

16. The first device of claim 12, wherein the first device further comprises a second emissive dopant having a peak wavelength of between 400 to 500 nanometers, and the second emissive dopant is a phosphorescent emitter.

17. A formulation comprising a compound of claim 1.

18. A consumer product comprising a first organic light emitting device, the first organic light emitting device comprising: an anode; a cathode; and an organic layer, disposed between the anode and the cathode, comprising a compound of claim 1.

19. The consumer product of claim 18, wherein the consumer product is selected from the group consisting of a flat panel display, a computer monitor, a television, a billboard, lights for interior or exterior illumination and/or signaling, a heads up display, a fully transparent display, a flexible display, a laser printer, a telephone, a cell phone, a personal digital assistant (PDA), a laptop computer, a digital camera, a camcorder, a viewfinder, a micro-display, a vehicle, a wall, theater or stadium screen, and a sign.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) FIG. 1 shows an organic light emitting device.

(2) FIG. 2 shows an inverted organic light emitting device that does not have a separate electron transport layer.

(3) FIG. 3 shows a compound of Formula I.

DETAILED DESCRIPTION

(4) Generally, an OLED comprises at least one organic layer disposed between and electrically connected to an anode and a cathode. When a current is applied, the anode injects holes and the cathode injects electrons into the organic layer(s). The injected holes and electrons each migrate toward the oppositely charged electrode. When an electron and hole localize on the same molecule, an “exciton,” which is a localized electron-hole pair having an excited energy state, is formed. Light is emitted when the exciton relaxes via a photoemissive mechanism. In some cases, the exciton may be localized on an excimer or an exciplex. Non-radiative mechanisms, such as thermal relaxation, may also occur, but are generally considered undesirable.

(5) The initial OLEDs used emissive molecules that emitted light from their singlet states (“fluorescence”) as disclosed, for example, in U.S. Pat. No. 4,769,292, which is incorporated by reference in its entirety. Fluorescent emission generally occurs in a time frame of less than 10 nanoseconds.

(6) More recently, OLEDs having emissive materials that emit light from triplet states (“phosphorescence”) have been demonstrated. Baldo et al., “Highly Efficient Phosphorescent Emission from Organic Electroluminescent Devices,” Nature, vol. 395, 151-154, 1998; (“Baldo-I”) and Baldo et al., “Very high-efficiency green organic light-emitting devices based on electrophosphorescence,” Appl. Phys. Lett., vol. 75, No. 3, 4-6 (1999) (“Baldo-II”), which are incorporated by reference in their entireties. Phosphorescence is described in more detail in U.S. Pat. No. 7,279,704 at cols. 5-6, which are incorporated by reference.

(7) FIG. 1 shows an organic light emitting device 100. The figures are not necessarily drawn to scale. Device 100 may include a substrate 110, an anode 115, a hole injection layer 120, a hole transport layer 125, an electron blocking layer 130, an emissive layer 135, a hole blocking layer 140, an electron transport layer 145, an electron injection layer 150, a protective layer 155, and a cathode 160. Cathode 160 is a compound cathode having a first conductive layer 162 and a second conductive layer 164. Device 100 may be fabricated by depositing the layers described, in order. The properties and functions of these various layers, as well as example materials, are described in more detail in U.S. Pat. No. 7,279,704 at cols. 6-10, which are incorporated by reference.

(8) More examples for each of these layers are available. For example, a flexible and transparent substrate-anode combination is disclosed in U.S. Pat. No. 5,844,363, which is incorporated by reference in its entirety. An example of a p-doped hole transport layer is m-MTDATA doped with F.sub.4-TCNQ at a molar ratio of 50:1, as disclosed in U.S. Patent Application Publication No. 2003/0230980, which is incorporated by reference in its entirety. Examples of emissive and host materials are disclosed in U.S. Pat. No. 6,303,238 to Thompson et al., which is incorporated by reference in its entirety. An example of an n-doped electron transport layer is BPhen doped with Li at a molar ratio of 1:1, as disclosed in U.S. Patent Application Publication No. 2003/0230980, which is incorporated by reference in its entirety. U.S. Pat. Nos. 5,703,436 and 5,707,745, which are incorporated by reference in their entireties, disclose examples of cathodes including compound cathodes having a thin layer of metal such as Mg:Ag with an overlying transparent, electrically-conductive, sputter-deposited ITO layer. The theory and use of blocking layers is described in more detail in U.S. Pat. No. 6,097,147 and U.S. Patent Application Publication No. 2003/0230980, which are incorporated by reference in their entireties. Examples of injection layers are provided in U.S. Patent Application Publication No. 2004/0174116, which is incorporated by reference in its entirety. A description of protective layers may be found in U.S. Patent Application Publication No. 2004/0174116, which is incorporated by reference in its entirety.

(9) FIG. 2 shows an inverted OLED 200. The device includes a substrate 210, a cathode 215, an emissive layer 220, a hole transport layer 225, and an anode 230. Device 200 may be fabricated by depositing the layers described, in order. Because the most common OLED configuration has a cathode disposed over the anode, and device 200 has cathode 215 disposed under anode 230, device 200 may be referred to as an “inverted” OLED. Materials similar to those described with respect to device 100 may be used in the corresponding layers of device 200. FIG. 2 provides one example of how some layers may be omitted from the structure of device 100.

(10) The simple layered structure illustrated in FIGS. 1 and 2 is provided by way of non-limiting example, and it is understood that embodiments of the invention may be used in connection with a wide variety of other structures. The specific materials and structures described are exemplary in nature, and other materials and structures may be used. Functional OLEDs may be achieved by combining the various layers described in different ways, or layers may be omitted entirely, based on design, performance, and cost factors. Other layers not specifically described may also be included. Materials other than those specifically described may be used. Although many of the examples provided herein describe various layers as comprising a single material, it is understood that combinations of materials, such as a mixture of host and dopant, or more generally a mixture, may be used. Also, the layers may have various sublayers. The names given to the various layers herein are not intended to be strictly limiting. For example, in device 200, hole transport layer 225 transports holes and injects holes into emissive layer 220, and may be described as a hole transport layer or a hole injection layer. In one embodiment, an OLED may be described as having an “organic layer” disposed between a cathode and an anode. This organic layer may comprise a single layer, or may further comprise multiple layers of different organic materials as described, for example, with respect to FIGS. 1 and 2.

(11) Structures and materials not specifically described may also be used, such as OLEDs comprised of polymeric materials (PLEDs) such as disclosed in U.S. Pat. No. 5,247,190 to Friend et al., which is incorporated by reference in its entirety. By way of further example, OLEDs having a single organic layer may be used. OLEDs may be stacked, for example as described in U.S. Pat. No. 5,707,745 to Forrest et al, which is incorporated by reference in its entirety. The OLED structure may deviate from the simple layered structure illustrated in FIGS. 1 and 2. For example, the substrate may include an angled reflective surface to improve out-coupling, such as a mesa structure as described in U.S. Pat. No. 6,091,195 to Forrest et al., and/or a pit structure as described in U.S. Pat. No. 5,834,893 to Bulovic et al., which are incorporated by reference in their entireties.

(12) Unless otherwise specified, any of the layers of the various embodiments may be deposited by any suitable method. For the organic layers, preferred methods include thermal evaporation, ink-jet, such as described in U.S. Pat. Nos. 6,013,982 and 6,087,196, which are incorporated by reference in their entireties, organic vapor phase deposition (OVPD), such as described in U.S. Pat. No. 6,337,102 to Forrest et al., which is incorporated by reference in its entirety, and deposition by organic vapor jet printing (OVJP), such as described in U.S. patent application Ser. No. 10/233,470, which is incorporated by reference in its entirety. Other suitable deposition methods include spin coating and other solution based processes. Solution based processes are preferably carried out in nitrogen or an inert atmosphere. For the other layers, preferred methods include thermal evaporation. Preferred patterning methods include deposition through a mask, cold welding such as described in U.S. Pat. Nos. 6,294,398 and 6,468,819, which are incorporated by reference in their entireties, and patterning associated with some of the deposition methods such as ink-jet and OVJD. Other methods may also be used. The materials to be deposited may be modified to make them compatible with a particular deposition method. For example, substituents such as alkyl and aryl groups, branched or unbranched, and preferably containing at least 3 carbons, may be used in small molecules to enhance their ability to undergo solution processing. Substituents having 20 carbons or more may be used, and 3-20 carbons is a preferred range. Materials with asymmetric structures may have better solution processibility than those having symmetric structures, because asymmetric materials may have a lower tendency to recrystallize. Dendrimer substituents may be used to enhance the ability of small molecules to undergo solution processing.

(13) Devices fabricated in accordance with embodiments of the invention may be incorporated into a wide variety of consumer products, including flat panel displays, computer monitors, televisions, billboards, lights for interior or exterior illumination and/or signaling, heads up displays, fully transparent displays, flexible displays, laser printers, telephones, cell phones, personal digital assistants (PDAs), laptop computers, digital cameras, camcorders, viewfinders, micro-displays, vehicles, a large area wall, theater or stadium screen, or a sign. Various control mechanisms may be used to control devices fabricated in accordance with the present invention, including passive matrix and active matrix. Many of the devices are intended for use in a temperature range comfortable to humans, such as 18 degrees C. to 30 degrees C., and more preferably at room temperature (20-25 degrees C.).

(14) The materials and structures described herein may have applications in devices other than OLEDs. For example, other optoelectronic devices such as organic solar cells and organic photodetectors may employ the materials and structures. More generally, organic devices, such as organic transistors, may employ the materials and structures.

(15) The terms halo, halogen, alkyl, cycloalkyl, alkenyl, alkynyl, arylkyl, heterocyclic group, aryl, aromatic group, and heteroaryl are known to the art, and are defined in U.S. Pat. No. 7,279,704 at cols. 31-32, which are incorporated herein by reference.

(16) A compound comprising a heteroleptic iridium complex is provided. In one embodiment, the compound is a compound of Formula I.

(17) ##STR00018##

(18) In the compound of Formula I, R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, and R.sub.6, are independently selected from the group consisting of hydrogen, deuterium, cycloalkyl, deuterated cycloalkyl, alkyl, and deuterated alkyl. At least one of R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, and R.sub.6 is cycloalkyl, deuterated cycloalkyl, alkyl or deuterated alkyl, and any two adjacent R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, and R.sub.6 are optionally linked together to form a ring. Thus, any of R.sub.1 and R.sub.2, R.sub.2 and R.sub.3, R.sub.3 and R.sub.4, R.sub.4 and R.sub.5, or R.sub.5 and R.sub.6 can be linked to form a ring. Ring A is attached to the 4- or 5-position of ring B. R and R′ represent mono-, di-, tri- or tetra-substitution and are independently selected from the group consisting of: hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.

(19) Ring B is numbered according to the following scheme:

(20) ##STR00019##
Thus, the 4-position is para to the pyridine nitrogen in ring B, and the 5-position is para to the phenyl ring attached to ring B.

(21) In one embodiment, the compound is a compound of Formula II.

(22) ##STR00020##

(23) In another embodiment, the compound is a compound of Formula III.

(24) ##STR00021##

(25) In one embodiment, R.sub.1 is alkyl. In one embodiment, R.sub.2 is alkyl. In one embodiment, R.sub.3 is alkyl. In one embodiment, R.sub.4 is alkyl. In one embodiment, R.sub.5 is alkyl. In one embodiment, R.sub.6 is alkyl. In one embodiment, at least one of R.sub.1, R.sub.2, and R.sub.3 is alkyl. In one embodiment, at least one of R.sub.4, R.sub.5, and R.sub.6 is alkyl. In another embodiment, at least one of R.sub.1, R.sub.2, and R.sub.3 is alkyl and at least one of R.sub.4, R.sub.5, and R.sub.6 is alkyl. In any of the foregoing embodiments, the alkyl may be replaced with a partially or fully deuterated alkyl.

(26) In one embodiment, the alkyl contains at least 2 carbons, at least 3 carbons, or at most 6 carbons. Having at least 2 carbons, at least 3 carbons, or at most 6 carbons allows the compounds of Formula I to efficiently emit in the yellow portion of the spectrum, without increasing the sublimation temperature of the compounds. Increased sublimation temperatures can make it difficult to purify compounds. In another embodiment, the alkyl contains greater than 10 carbons. Having an alkyl with greater than 10 carbons is useful in the solution processing of compounds of Formula I, which leads to inexpensive manufacture of OLED devices.

(27) In one embodiment, the compound emits yellow light with a full width at half maximum between about 70 nm to about 110 nm when the light has a peak wavelength between about 530 nm to about 580 nm. When compounds of Formula I have the above range of full width at half maximum (FWHM) with the accompanying range of peak wavelengths, they are efficient yellow emitters with broad line shapes, which is desirable in white light applications.

(28) Specific non-limiting compounds are provided. In one embodiment, the compound is selected from the group consisting of:

(29) ##STR00022## ##STR00023## ##STR00024## ##STR00025## ##STR00026## ##STR00027## ##STR00028## ##STR00029## ##STR00030## ##STR00031##

(30) In one aspect, the compound comprising a heteroleptic iridium complex has the formula IrL.sub.A(L.sub.B).sub.2, wherein L.sub.A is selected from the group consisting of

(31) ##STR00032## ##STR00033## ##STR00034## ##STR00035## ##STR00036## ##STR00037## ##STR00038## ##STR00039##

(32) L.sub.B is selected from the group consisting of

(33) ##STR00040## ##STR00041## ##STR00042## ##STR00043## ##STR00044##
and the heteroleptic iridium complex is selected from the group consisting of Compound II-1 through Compound II-1846, and Compound II-1847 listed in the following table:

(34) TABLE-US-00002 Compound Number L.sub.A L.sub.B II-1. L.sub.A6 L.sub.B1 II-2. L.sub.A12 L.sub.B1 II-3. L.sub.A13 L.sub.B1 II-4. L.sub.A16 L.sub.B1 II-5. L.sub.A17 L.sub.B1 II-6. L.sub.A24 L.sub.B1 II-7. L.sub.A30 L.sub.B1 II-8. L.sub.A31 L.sub.B1 II-9. L.sub.A34 L.sub.B1 II-10. L.sub.A35 L.sub.B1 II-11. L.sub.A36 L.sub.B1 II-12. L.sub.A38 L.sub.B1 II-13. L.sub.A39 L.sub.B1 II-14. L.sub.A40 L.sub.B1 II-15. L.sub.A41 L.sub.B1 II-16. L.sub.A42 L.sub.B1 II-17. L.sub.A43 L.sub.B1 II-18. L.sub.A44 L.sub.B1 II-19. L.sub.A45 L.sub.B1 II-20. L.sub.A46 L.sub.B1 II-21. L.sub.A47 L.sub.B1 II-22. L.sub.A48 L.sub.B1 II-23. L.sub.A49 L.sub.B1 II-24. L.sub.A50 L.sub.B1 II-25. L.sub.A51 L.sub.B1 II-26. L.sub.A52 L.sub.B1 II-27. L.sub.A53 L.sub.B1 II-28. L.sub.A54 L.sub.B1 II-29. L.sub.A55 L.sub.B1 II-30. L.sub.A56 L.sub.B1 II-31. L.sub.A57 L.sub.B1 II-32. L.sub.A58 L.sub.B1 II-33. L.sub.A59 L.sub.B1 II-34. L.sub.A60 L.sub.B1 II-35. L.sub.A61 L.sub.B1 II-36. L.sub.A62 L.sub.B1 II-37. L.sub.A63 L.sub.B1 II-38. L.sub.A64 L.sub.B1 II-39. L.sub.A65 L.sub.B1 II-40. L.sub.A66 L.sub.B1 II-41. L.sub.A67 L.sub.B1 II-42. L.sub.A68 L.sub.B1 II-43. L.sub.A69 L.sub.B1 II-44. L.sub.A6 L.sub.B2 II-45. L.sub.A7 L.sub.B2 II-46. L.sub.A9 L.sub.B2 II-47. L.sub.A10 L.sub.B2 II-48. L.sub.A11 L.sub.B2 II-49. L.sub.A12 L.sub.B2 II-50. L.sub.A13 L.sub.B2 II-51. L.sub.A16 L.sub.B2 II-52. L.sub.A17 L.sub.B2 II-53. L.sub.A21 L.sub.B2 II-54. L.sub.A22 L.sub.B2 II-55. L.sub.A23 L.sub.B2 II-56. L.sub.A24 L.sub.B2 II-57. L.sub.A27 L.sub.B2 II-58. L.sub.A28 L.sub.B2 II-59. L.sub.A29 L.sub.B2 II-60. L.sub.A30 L.sub.B2 II-61. L.sub.A31 L.sub.B2 II-62. L.sub.A34 L.sub.B2 II-63. L.sub.A35 L.sub.B2 II-64. L.sub.A36 L.sub.B2 II-65. L.sub.A38 L.sub.B2 II-66. L.sub.A39 L.sub.B2 II-67. L.sub.A40 L.sub.B2 II-68. L.sub.A41 L.sub.B2 II-69. L.sub.A42 L.sub.B2 II-70. L.sub.A43 L.sub.B2 II-71. L.sub.A44 L.sub.B2 II-72. L.sub.A45 L.sub.B2 II-73. L.sub.A46 L.sub.B2 II-74. L.sub.A47 L.sub.B2 II-75. L.sub.A48 L.sub.B2 II-76. L.sub.A49 L.sub.B2 II-77. L.sub.A50 L.sub.B2 II-78. L.sub.A51 L.sub.B2 II-79. L.sub.A52 L.sub.B2 II-80. L.sub.A53 L.sub.B2 II-81. L.sub.A54 L.sub.B2 II-82. L.sub.A55 L.sub.B2 II-83. L.sub.A56 L.sub.B2 II-84. L.sub.A57 L.sub.B2 II-85. L.sub.A58 L.sub.B2 II-86. L.sub.A59 L.sub.B2 II-87. L.sub.A60 L.sub.B2 II-88. L.sub.A61 L.sub.B2 II-89. L.sub.A62 L.sub.B2 II-90. L.sub.A63 L.sub.B2 II-91. L.sub.A64 L.sub.B2 II-92. L.sub.A65 L.sub.B2 II-93. L.sub.A66 L.sub.B2 II-94. L.sub.A67 L.sub.B2 II-95. L.sub.A68 L.sub.B2 II-96. L.sub.A69 L.sub.B2 II-97. L.sub.A2 L.sub.B3 II-98. L.sub.A3 L.sub.B3 II-99. L.sub.A4 L.sub.B3 II-100. L.sub.A5 L.sub.B3 II-101. L.sub.A6 L.sub.B3 II-102. L.sub.A7 L.sub.B3 II-103. L.sub.A8 L.sub.B3 II-104. L.sub.A9 L.sub.B3 II-105. L.sub.A10 L.sub.B3 II-106. L.sub.A11 L.sub.B3 II-107. L.sub.A12 L.sub.B3 II-108. L.sub.A13 L.sub.B3 II-109. L.sub.A14 L.sub.B3 II-110. L.sub.A15 L.sub.B3 II-111. L.sub.A16 L.sub.B3 II-112. L.sub.A17 L.sub.B3 II-113. L.sub.A18 L.sub.B3 II-114. L.sub.A20 L.sub.B3 II-115. L.sub.A21 L.sub.B3 II-116. L.sub.A22 L.sub.B3 II-117. L.sub.A23 L.sub.B3 II-118. L.sub.A24 L.sub.B3 II-119. L.sub.A25 L.sub.B3 II-120. L.sub.A26 L.sub.B3 II-121. L.sub.A27 L.sub.B3 II-122. L.sub.A28 L.sub.B3 II-123. L.sub.A29 L.sub.B3 II-124. L.sub.A30 L.sub.B3 II-125. L.sub.A31 L.sub.B3 II-126. L.sub.A32 L.sub.B3 II-127. L.sub.A33 L.sub.B3 II-128. L.sub.A34 L.sub.B3 II-129. L.sub.A35 L.sub.B3 II-130. L.sub.A36 L.sub.B3 II-131. L.sub.A37 L.sub.B3 II-132. L.sub.A38 L.sub.B3 II-133. L.sub.A39 L.sub.B3 II-134. L.sub.A40 L.sub.B3 II-135. L.sub.A41 L.sub.B3 II-136. L.sub.A42 L.sub.B3 II-137. L.sub.A43 L.sub.B3 II-138. L.sub.A44 L.sub.B3 II-139. L.sub.A45 L.sub.B3 II-140. L.sub.A46 L.sub.B3 II-141. L.sub.A47 L.sub.B3 II-142. L.sub.A48 L.sub.B3 II-143. L.sub.A49 L.sub.B3 II-144. L.sub.A50 L.sub.B3 II-145. L.sub.A51 L.sub.B3 II-146. L.sub.A52 L.sub.B3 II-147. L.sub.A53 L.sub.B3 II-148. L.sub.A54 L.sub.B3 II-149. L.sub.A55 L.sub.B3 II-150. L.sub.A56 L.sub.B3 II-151. L.sub.A57 L.sub.B3 II-152. L.sub.A58 L.sub.B3 II-153. L.sub.A59 L.sub.B3 II-154. L.sub.A60 L.sub.B3 II-155. L.sub.A61 L.sub.B3 II-156. L.sub.A62 L.sub.B3 II-157. L.sub.A63 L.sub.B3 II-158. L.sub.A64 L.sub.B3 II-159. L.sub.A65 L.sub.B3 II-160. L.sub.A66 L.sub.B3 II-161. L.sub.A67 L.sub.B3 II-162. L.sub.A68 L.sub.B3 II-163. L.sub.A69 L.sub.B3 II-164. L.sub.A2 L.sub.B4 II-165. L.sub.A3 L.sub.B4 II-166. L.sub.A4 L.sub.B4 II-167. L.sub.A5 L.sub.B4 II-168. L.sub.A6 L.sub.B4 II-169. L.sub.A7 L.sub.B4 II-170. L.sub.A8 L.sub.B4 II-171. L.sub.A9 L.sub.B4 II-172. L.sub.A10 L.sub.B4 II-173. L.sub.A11 L.sub.B4 II-174. L.sub.A12 L.sub.B4 II-175. L.sub.A13 L.sub.B4 II-176. L.sub.A14 L.sub.B4 II-177. L.sub.A15 L.sub.B4 II-178. L.sub.A16 L.sub.B4 II-179. L.sub.A17 L.sub.B4 II-180. L.sub.A18 L.sub.B4 II-181. L.sub.A20 L.sub.B4 II-182. L.sub.A21 L.sub.B4 II-183. L.sub.A22 L.sub.B4 II-184. L.sub.A23 L.sub.B4 II-185. L.sub.A24 L.sub.B4 II-186. L.sub.A25 L.sub.B4 II-187. L.sub.A26 L.sub.B4 II-188. L.sub.A27 L.sub.B4 II-189. L.sub.A28 L.sub.B4 II-190. L.sub.A29 L.sub.B4 II-191. L.sub.A30 L.sub.B4 II-192. L.sub.A31 L.sub.B4 II-193. L.sub.A32 L.sub.B4 II-194. L.sub.A33 L.sub.B4 II-195. L.sub.A34 L.sub.B4 II-196. L.sub.A35 L.sub.B4 II-197. L.sub.A36 L.sub.B4 II-198. L.sub.A37 L.sub.B4 II-199. L.sub.A38 L.sub.B4 II-200. L.sub.A39 L.sub.B4 II-201. L.sub.A40 L.sub.B4 II-202. L.sub.A41 L.sub.B4 II-203. L.sub.A42 L.sub.B4 II-204. L.sub.A43 L.sub.B4 II-205. L.sub.A44 L.sub.B4 II-206. L.sub.A45 L.sub.B4 II-207. L.sub.A46 L.sub.B4 II-208. L.sub.A47 L.sub.B4 II-209. L.sub.A48 L.sub.B4 II-210. L.sub.A49 L.sub.B4 II-211. L.sub.A50 L.sub.B4 II-212. L.sub.A51 L.sub.B4 II-213. L.sub.A52 L.sub.B4 II-214. L.sub.A53 L.sub.B4 II-215. L.sub.A54 L.sub.B4 II-216. L.sub.A55 L.sub.B4 II-217. L.sub.A56 L.sub.B4 II-218. L.sub.A57 L.sub.B4 II-219. L.sub.A58 L.sub.B4 II-220. L.sub.A59 L.sub.B4 II-221. L.sub.A60 L.sub.B4 II-222. L.sub.A61 L.sub.B4 II-223. L.sub.A62 L.sub.B4 II-224. L.sub.A63 L.sub.B4 II-225. L.sub.A64 L.sub.B4 II-226. L.sub.A65 L.sub.B4 II-227. L.sub.A66 L.sub.B4 II-228. L.sub.A67 L.sub.B4 II-229. L.sub.A68 L.sub.B4 II-230. L.sub.A69 L.sub.B4 II-231. L.sub.A3 L.sub.B5 II-232. L.sub.A4 L.sub.B5 II-233. L.sub.A5 L.sub.B5 II-234. L.sub.A6 L.sub.B5 II-235. L.sub.A7 L.sub.B5 II-236. L.sub.A8 L.sub.B5 II-237. L.sub.A9 L.sub.B5 II-238. L.sub.A10 L.sub.B5 II-239. L.sub.A11 L.sub.B5 II-240. L.sub.A12 L.sub.B5 II-241. L.sub.A13 L.sub.B5 II-242. L.sub.A14 L.sub.B5 II-243. L.sub.A15 L.sub.B5 II-244. L.sub.A16 L.sub.B5 II-245. L.sub.A17 L.sub.B5 II-246. L.sub.A18 L.sub.B5 II-247. L.sub.A20 L.sub.B5 II-248. L.sub.A21 L.sub.B5 II-249. L.sub.A22 L.sub.B5 II-250. L.sub.A23 L.sub.B5 II-251. L.sub.A24 L.sub.B5 II-252. L.sub.A25 L.sub.B5 II-253. L.sub.A26 L.sub.B5 II-254. L.sub.A27 L.sub.B5 II-255. L.sub.A28 L.sub.B5 II-256. L.sub.A29 L.sub.B5 II-257. L.sub.A30 L.sub.B5 II-258. L.sub.A31 L.sub.B5 II-259. L.sub.A32 L.sub.B5 II-260. L.sub.A33 L.sub.B5 II-261. L.sub.A34 L.sub.B5 II-262. L.sub.A35 L.sub.B5 II-263. L.sub.A36 L.sub.B5 II-264. L.sub.A37 L.sub.B5 II-265. L.sub.A38 L.sub.B5 II-266. L.sub.A39 L.sub.B5 II-267. L.sub.A40 L.sub.B5 II-268. L.sub.A41 L.sub.B5 II-269. L.sub.A42 L.sub.B5 II-270. L.sub.A43 L.sub.B5 II-271. L.sub.A44 L.sub.B5 II-272. L.sub.A45 L.sub.B5 II-273. L.sub.A46 L.sub.B5 II-274. L.sub.A47 L.sub.B5 II-275. L.sub.A48 L.sub.B5 II-276. L.sub.A49 L.sub.B5 II-277. L.sub.A50 L.sub.B5 II-278. L.sub.A51 L.sub.B5 II-279. L.sub.A52 L.sub.B5 II-280. L.sub.A53 L.sub.B5 II-281. L.sub.A54 L.sub.B5 II-282. L.sub.A55 L.sub.B5 II-283. L.sub.A56 L.sub.B5 II-284. L.sub.A57 L.sub.B5 II-285. L.sub.A58 L.sub.B5 II-286. L.sub.A59 L.sub.B5 II-287. L.sub.A60 L.sub.B5 II-288. L.sub.A61 L.sub.B5 II-289. L.sub.A62 L.sub.B5 II-290. L.sub.A63 L.sub.B5 II-291. L.sub.A64 L.sub.B5 II-292. L.sub.A65 L.sub.B5 II-293. L.sub.A66 L.sub.B5 II-294. L.sub.A67 L.sub.B5 II-295. L.sub.A68 L.sub.B5 II-296. L.sub.A69 L.sub.B5 II-297. L.sub.A2 L.sub.B6 II-298. L.sub.A3 L.sub.B6 II-299. L.sub.A4 L.sub.B6 II-300. L.sub.A5 L.sub.B6 II-301. L.sub.A6 L.sub.B6 II-302. L.sub.A7 L.sub.B6 II-303. L.sub.A8 L.sub.B6 II-304. L.sub.A9 L.sub.B6 II-305. L.sub.A10 L.sub.B6 II-306. L.sub.A11 L.sub.B6 II-307. L.sub.A12 L.sub.B6 II-308. L.sub.A13 L.sub.B6 II-309. L.sub.A14 L.sub.B6 II-310. L.sub.A15 L.sub.B6 II-311. L.sub.A16 L.sub.B6 II-312. L.sub.A17 L.sub.B6 II-313. L.sub.A18 L.sub.B6 II-314. L.sub.A20 L.sub.B6 II-315. L.sub.A21 L.sub.B6 II-316. L.sub.A22 L.sub.B6 II-317. L.sub.A23 L.sub.B6 II-318. L.sub.A24 L.sub.B6 II-319. L.sub.A25 L.sub.B6 II-320. L.sub.A26 L.sub.B6 II-321. L.sub.A27 L.sub.B6 II-322. L.sub.A28 L.sub.B6 II-323. L.sub.A29 L.sub.B6 II-324. L.sub.A30 L.sub.B6 II-325. L.sub.A31 L.sub.B6 II-326. L.sub.A32 L.sub.B6 II-327. L.sub.A33 L.sub.B6 II-328. L.sub.A34 L.sub.B6 II-329. L.sub.A35 L.sub.B6 II-330. L.sub.A36 L.sub.B6 II-331. L.sub.A37 L.sub.B6 II-332. L.sub.A38 L.sub.B6 II-333. L.sub.A39 L.sub.B6 II-334. L.sub.A40 L.sub.B6 II-335. L.sub.A41 L.sub.B6 II-336. L.sub.A42 L.sub.B6 II-337. L.sub.A43 L.sub.B6 II-338. L.sub.A44 L.sub.B6 II-339. L.sub.A45 L.sub.B6 II-340. L.sub.A46 L.sub.B6 II-341. L.sub.A47 L.sub.B6 II-342. L.sub.A48 L.sub.B6 II-343. L.sub.A49 L.sub.B6 II-344. L.sub.A50 L.sub.B6 II-345. L.sub.A51 L.sub.B6 II-346. L.sub.A52 L.sub.B6 II-347. L.sub.A53 L.sub.B6 II-348. L.sub.A54 L.sub.B6 II-349. L.sub.A55 L.sub.B6 II-350. L.sub.A56 L.sub.B6 II-351. L.sub.A57 L.sub.B6 II-352. L.sub.A58 L.sub.B6 II-353. L.sub.A59 L.sub.B6 II-354. L.sub.A60 L.sub.B6 II-355. L.sub.A61 L.sub.B6 II-356. L.sub.A62 L.sub.B6 II-357. L.sub.A63 L.sub.B6 II-358. L.sub.A64 L.sub.B6 II-359. L.sub.A65 L.sub.B6 II-360. L.sub.A66 L.sub.B6 II-361. L.sub.A67 L.sub.B6 II-362. L.sub.A68 L.sub.B6 II-363. L.sub.A69 L.sub.B6 II-364. L.sub.A2 L.sub.B7 II-365. L.sub.A3 L.sub.B7 II-366. L.sub.A4 L.sub.B7 II-367. L.sub.A5 L.sub.B7 II-368. L.sub.A6 L.sub.B7 II-369. L.sub.A7 L.sub.B7 II-370. L.sub.A8 L.sub.B7 II-371. L.sub.A9 L.sub.B7 II-372. L.sub.A10 L.sub.B7 II-373. L.sub.A11 L.sub.B7 II-374. L.sub.A12 L.sub.B7 II-375. L.sub.A13 L.sub.B7 II-376. L.sub.A14 L.sub.B7 II-377. L.sub.A15 L.sub.B7 II-378. L.sub.A16 L.sub.B7 II-379. L.sub.A17 L.sub.B7 II-380. L.sub.A18 L.sub.B7 II-381. L.sub.A20 L.sub.B7 II-382. L.sub.A21 L.sub.B7 II-383. L.sub.A22 L.sub.B7 II-384. L.sub.A23 L.sub.B7 II-385. L.sub.A24 L.sub.B7 II-386. L.sub.A25 L.sub.B7 II-387. L.sub.A26 L.sub.B7 II-388. L.sub.A27 L.sub.B7 II-389. L.sub.A28 L.sub.B7 II-390. L.sub.A29 L.sub.B7 II-391. L.sub.A30 L.sub.B7 II-392. L.sub.A31 L.sub.B7 II-393. L.sub.A32 L.sub.B7 II-394. L.sub.A33 L.sub.B7 II-395. L.sub.A34 L.sub.B7 II-396. L.sub.A35 L.sub.B7 II-397. L.sub.A36 L.sub.B7 II-398. L.sub.A37 L.sub.B7 II-399. L.sub.A38 L.sub.B7 II-400. L.sub.A39 L.sub.B7 II-401. L.sub.A40 L.sub.B7 II-402. L.sub.A41 L.sub.B7 II-403. L.sub.A42 L.sub.B7 II-404. L.sub.A43 L.sub.B7 II-405. L.sub.A44 L.sub.B7 II-406. L.sub.A45 L.sub.B7 II-407. L.sub.A46 L.sub.B7 II-408. L.sub.A47 L.sub.B7 II-409. L.sub.A48 L.sub.B7 II-410. L.sub.A49 L.sub.B7 II-411. L.sub.A50 L.sub.B7 II-412. L.sub.A51 L.sub.B7 II-413. L.sub.A52 L.sub.B7 II-414. L.sub.A53 L.sub.B7 II-415. L.sub.A54 L.sub.B7 II-416. L.sub.A55 L.sub.B7 II-417. L.sub.A56 L.sub.B7 II-418. L.sub.A57 L.sub.B7 II-419. L.sub.A58 L.sub.B7 II-420. L.sub.A59 L.sub.B7 II-421. L.sub.A60 L.sub.B7 II-422. L.sub.A61 L.sub.B7 II-423. L.sub.A62 L.sub.B7 II-424. L.sub.A63 L.sub.B7 II-425. L.sub.A64 L.sub.B7 II-426. L.sub.A65 L.sub.B7 II-427. L.sub.A66 L.sub.B7 II-428. L.sub.A67 L.sub.B7 II-429. L.sub.A68 L.sub.B7 II-430. L.sub.A69 L.sub.B7 II-431. L.sub.A2 L.sub.B8 II-432. L.sub.A3 L.sub.B8 II-433. L.sub.A4 L.sub.B8 II-434. L.sub.A5 L.sub.B8 II-435. L.sub.A6 L.sub.B8 II-436. L.sub.A7 L.sub.B8 II-437. L.sub.A8 L.sub.B8 II-438. L.sub.A9 L.sub.B8 II-439. L.sub.A10 L.sub.B8 II-440. L.sub.A11 L.sub.B8 II-441. L.sub.A12 L.sub.B8 II-442. L.sub.A13 L.sub.B8 II-443. L.sub.A14 L.sub.B8 II-444. L.sub.A15 L.sub.B8 II-445. L.sub.A16 L.sub.B8 II-446. L.sub.A17 L.sub.B8 II-447. L.sub.A18 L.sub.B8 II-448. L.sub.A20 L.sub.B8 II-449. L.sub.A21 L.sub.B8 II-450. L.sub.A22 L.sub.B8 II-451. L.sub.A23 L.sub.B8 II-452. L.sub.A24 L.sub.B8 II-453. L.sub.A25 L.sub.B8 II-454. L.sub.A26 L.sub.B8 II-455. L.sub.A27 L.sub.B8 II-456. L.sub.A28 L.sub.B8 II-457. L.sub.A29 L.sub.B8 II-458. L.sub.A30 L.sub.B8 II-459. L.sub.A31 L.sub.B8 II-460. L.sub.A32 L.sub.B8 II-461. L.sub.A33 L.sub.B8 II-462. L.sub.A34 L.sub.B8 II-463. L.sub.A35 L.sub.B8 II-464. L.sub.A36 L.sub.B8 II-465. L.sub.A37 L.sub.B8 II-466. L.sub.A38 L.sub.B8 II-467. L.sub.A39 L.sub.B8 II-468. L.sub.A40 L.sub.B8 II-469. L.sub.A41 L.sub.B8 II-470. L.sub.A42 L.sub.B8 II-471. L.sub.A43 L.sub.B8 II-472. L.sub.A44 L.sub.B8 II-473. L.sub.A45 L.sub.B8 II-474. L.sub.A46 L.sub.B8 II-475. L.sub.A47 L.sub.B8 II-476. L.sub.A48 L.sub.B8 II-477. L.sub.A49 L.sub.B8 II-478. L.sub.A50 L.sub.B8 II-479. L.sub.A51 L.sub.B8 II-480. L.sub.A52 L.sub.B8 II-481. L.sub.A53 L.sub.B8 II-482. L.sub.A54 L.sub.B8 II-483. L.sub.A55 L.sub.B8 II-484. L.sub.A56 L.sub.B8 II-485. L.sub.A57 L.sub.B8 II-486. L.sub.A58 L.sub.B8 II-487. L.sub.A59 L.sub.B8 II-488. L.sub.A60 L.sub.B8 II-489. L.sub.A61 L.sub.B8 II-490. L.sub.A62 L.sub.B8 II-491. L.sub.A63 L.sub.B8 II-492. L.sub.A64 L.sub.B8 II-493. L.sub.A65 L.sub.B8 II-494. L.sub.A66 L.sub.B8 II-495. L.sub.A67 L.sub.B8 II-496. L.sub.A68 L.sub.B8 II-497. L.sub.A69 L.sub.B8 II-498. L.sub.A3 L.sub.B9 II-499. L.sub.A4 L.sub.B9 II-500. L.sub.A5 L.sub.B9 II-501. L.sub.A6 L.sub.B9 II-502. L.sub.A7 L.sub.B9 II-503. L.sub.A8 L.sub.B9 II-504. L.sub.A9 L.sub.B9 II-505. L.sub.A10 L.sub.B9 II-506. L.sub.A11 L.sub.B9 II-507. L.sub.A12 L.sub.B9 II-508. L.sub.A13 L.sub.B9 II-509. L.sub.A14 L.sub.B9 II-510. L.sub.A15 L.sub.B9 II-511. L.sub.A16 L.sub.B9 II-512. L.sub.A17 L.sub.B9 II-513. L.sub.A18 L.sub.B9 II-514. L.sub.A21 L.sub.B9 II-515. L.sub.A22 L.sub.B9 II-516. L.sub.A23 L.sub.B9 II-517. L.sub.A24 L.sub.B9 II-518. L.sub.A25 L.sub.B9 II-519. L.sub.A26 L.sub.B9 II-520. L.sub.A27 L.sub.B9 II-521. L.sub.A28 L.sub.B9 II-522. L.sub.A29 L.sub.B9 II-523. L.sub.A30 L.sub.B9 II-524. L.sub.A31 L.sub.B9 II-525. L.sub.A32 L.sub.B9 II-526. L.sub.A33 L.sub.B9 II-527. L.sub.A34 L.sub.B9 II-528. L.sub.A35 L.sub.B9 II-529. L.sub.A36 L.sub.B9 II-530. L.sub.A38 L.sub.B9 II-531. L.sub.A39 L.sub.B9 II-532. L.sub.A40 L.sub.B9 II-533. L.sub.A41 L.sub.B9 II-534. L.sub.A42 L.sub.B9 II-535. L.sub.A43 L.sub.B9 II-536. L.sub.A44 L.sub.B9 II-537. L.sub.A45 L.sub.B9 II-538. L.sub.A46 L.sub.B9 II-539. L.sub.A47 L.sub.B9 II-540. L.sub.A48 L.sub.B9 II-541. L.sub.A49 L.sub.B9 II-542. L.sub.A50 L.sub.B9 II-543. L.sub.A51 L.sub.B9 II-544. L.sub.A52 L.sub.B9 II-545. L.sub.A54 L.sub.B9 II-546. L.sub.A55 L.sub.B9 II-547. L.sub.A56 L.sub.B9 II-548. L.sub.A57 L.sub.B9 II-549. L.sub.A58 L.sub.B9 II-550. L.sub.A59 L.sub.B9 II-551. L.sub.A60 L.sub.B9 II-552. L.sub.A61 L.sub.B9 II-553. L.sub.A62 L.sub.B9 II-554. L.sub.A63 L.sub.B9 II-555. L.sub.A64 L.sub.B9 II-556. L.sub.A65 L.sub.B9 II-557. L.sub.A66 L.sub.B9 II-558. L.sub.A67 L.sub.B9 II-559. L.sub.A68 L.sub.B9 II-560. L.sub.A69 L.sub.B9 II-561. L.sub.A1 L.sub.B10 II-562. L.sub.A2 L.sub.B10 II-563. L.sub.A3 L.sub.B10 II-564. L.sub.A4 L.sub.B10 II-565. L.sub.A5 L.sub.B10 II-566. L.sub.A6 L.sub.B10 II-567. L.sub.A7 L.sub.B10 II-568. L.sub.A8 L.sub.B10 II-569. L.sub.A9 L.sub.B10 II-570. L.sub.A10 L.sub.B10 II-571. L.sub.A11 L.sub.B10 II-572. L.sub.A12 L.sub.B10 II-573. L.sub.A13 L.sub.B10 II-574. L.sub.A14 L.sub.B10 II-575. L.sub.A15 L.sub.B10 II-576. L.sub.A16 L.sub.B10 II-577. L.sub.A17 L.sub.B10 II-578. L.sub.A18 L.sub.B10 II-579. L.sub.A19 L.sub.B10 II-580. L.sub.A20 L.sub.B10 II-581. L.sub.A21 L.sub.B10 II-582. L.sub.A22 L.sub.B10 II-583. L.sub.A23 L.sub.B10 II-584. L.sub.A24 L.sub.B10 II-585. L.sub.A25 L.sub.B10 II-586. L.sub.A26 L.sub.B10 II-587. L.sub.A27 L.sub.B10 II-588. L.sub.A28 L.sub.B10 II-589. L.sub.A29 L.sub.B10 II-590. L.sub.A30 L.sub.B10 II-591. L.sub.A31 L.sub.B10 II-592. L.sub.A32 L.sub.B10 II-593. L.sub.A33 L.sub.B10 II-594. L.sub.A34 L.sub.B10 II-595. L.sub.A35 L.sub.B10 II-596. L.sub.A36 L.sub.B10 II-597. L.sub.A37 L.sub.B10 II-598. L.sub.A38 L.sub.B10 II-599. L.sub.A39 L.sub.B10 II-600. L.sub.A40 L.sub.B10 II-601. L.sub.A41 L.sub.B10 II-602. L.sub.A42 L.sub.B10 II-603. L.sub.A43 L.sub.B10 II-604. L.sub.A44 L.sub.B10 II-605. L.sub.A45 L.sub.B10 II-606. L.sub.A46 L.sub.B10 II-607. L.sub.A47 L.sub.B10 II-608. L.sub.A48 L.sub.B10 II-609. L.sub.A49 L.sub.B10 II-610. L.sub.A50 L.sub.B10 II-611. L.sub.A51 L.sub.B10 II-612. L.sub.A52 L.sub.B10 II-613. L.sub.A53 L.sub.B10 II-614. L.sub.A54 L.sub.B10 II-615. L.sub.A55 L.sub.B10 II-616. L.sub.A56 L.sub.B10 II-617. L.sub.A57 L.sub.B10 II-618. L.sub.A58 L.sub.B10 II-619. L.sub.A59 L.sub.B10 II-620. L.sub.A60 L.sub.B10 II-621. L.sub.A61 L.sub.B10 II-622. L.sub.A62 L.sub.B10 II-623. L.sub.A63 L.sub.B10 II-624. L.sub.A64 L.sub.B10 II-625. L.sub.A65 L.sub.B10 II-626. L.sub.A66 L.sub.B10 II-627. L.sub.A67 L.sub.B10 II-628. L.sub.A68 L.sub.B10 II-629. L.sub.A69 L.sub.B10 II-630. L.sub.A1 L.sub.B11 II-631. L.sub.A2 L.sub.B11 II-632. L.sub.A3 L.sub.B11 II-633. L.sub.A4 L.sub.B11 II-634. L.sub.A5 L.sub.B11 II-635. L.sub.A6 L.sub.B11 II-636. L.sub.A7 L.sub.B11 II-637. L.sub.A8 L.sub.B11 II-638. L.sub.A9 L.sub.B11 II-639. L.sub.A10 L.sub.B11 II-640. L.sub.A11 L.sub.B11 II-641. L.sub.A12 L.sub.B11 II-642. L.sub.A13 L.sub.B11 II-643. L.sub.A14 L.sub.B11 II-644. L.sub.A15 L.sub.B11 II-645. L.sub.A16 L.sub.B11 II-646. L.sub.A17 L.sub.B11 II-647. L.sub.A18 L.sub.B11 II-648. L.sub.A19 L.sub.B11 II-649. L.sub.A20 L.sub.B11 II-650. L.sub.A21 L.sub.B11 II-651. L.sub.A22 L.sub.B11 II-652. L.sub.A23 L.sub.B11 II-653. L.sub.A24 L.sub.B11 II-654. L.sub.A25 L.sub.B11 II-655. L.sub.A26 L.sub.B11 II-656. L.sub.A27 L.sub.B11 II-657. L.sub.A28 L.sub.B11 II-658. L.sub.A29 L.sub.B11 II-659. L.sub.A30 L.sub.B11 II-660. L.sub.A31 L.sub.B11 II-661. L.sub.A32 L.sub.B11 II-662. L.sub.A33 L.sub.B11 II-663. L.sub.A34 L.sub.B11 II-664. L.sub.A35 L.sub.B11 II-665. L.sub.A36 L.sub.B11 II-666. L.sub.A37 L.sub.B11 II-667. L.sub.A38 L.sub.B11 II-668. L.sub.A39 L.sub.B11 II-669. L.sub.A40 L.sub.B11 II-670. L.sub.A41 L.sub.B11 II-671. L.sub.A42 L.sub.B11 II-672. L.sub.A43 L.sub.B11 II-673. L.sub.A44 L.sub.B11 II-674. L.sub.A45 L.sub.B11 II-675. L.sub.A46 L.sub.B11 II-676. L.sub.A47 L.sub.B11 II-677. L.sub.A48 L.sub.B11 II-678. L.sub.A49 L.sub.B11 II-679. L.sub.A50 L.sub.B11 II-680. L.sub.A51 L.sub.B11 II-681. L.sub.A52 L.sub.B11 II-682. L.sub.A53 L.sub.B11 II-683. L.sub.A54 L.sub.B11 II-684. L.sub.A55 L.sub.B11 II-685. L.sub.A56 L.sub.B11 II-686. L.sub.A57 L.sub.B11 II-687. L.sub.A58 L.sub.B11 II-688. L.sub.A59 L.sub.B11 II-689. L.sub.A60 L.sub.B11 II-690. L.sub.A61 L.sub.B11 II-691. L.sub.A62 L.sub.B11 II-692. L.sub.A63 L.sub.B11 II-693. L.sub.A64 L.sub.B11 II-694. L.sub.A65 L.sub.B11 II-695. L.sub.A66 L.sub.B11 II-696. L.sub.A67 L.sub.B11 II-697. L.sub.A68 L.sub.B11 II-698. L.sub.A69 L.sub.B11 II-699. L.sub.A3 L.sub.B12 II-700. L.sub.A4 L.sub.B12 II-701. L.sub.A5 L.sub.B12 II-702. L.sub.A6 L.sub.B12 II-703. L.sub.A7 L.sub.B12 II-704. L.sub.A8 L.sub.B12 II-705. L.sub.A9 L.sub.B12 II-706. L.sub.A10 L.sub.B12 II-707. L.sub.A11 L.sub.B12 II-708. L.sub.A12 L.sub.B12 II-709. L.sub.A13 L.sub.B12 II-710. L.sub.A14 L.sub.B12 II-711. L.sub.A15 L.sub.B12 II-712. L.sub.A16 L.sub.B12 II-713. L.sub.A17 L.sub.B12 II-714. L.sub.A18 L.sub.B12 II-715. L.sub.A21 L.sub.B12 II-716. L.sub.A22 L.sub.B12 II-717. L.sub.A23 L.sub.B12 II-718. L.sub.A24 L.sub.B12 II-719. L.sub.A25 L.sub.B12 II-720. L.sub.A26 L.sub.B12 II-721. L.sub.A27 L.sub.B12 II-722. L.sub.A28 L.sub.B12 II-723. L.sub.A29 L.sub.B12 II-724. L.sub.A30 L.sub.B12 II-725. L.sub.A31 L.sub.B12 II-726. L.sub.A32 L.sub.B12 II-727. L.sub.A33 L.sub.B12 II-728. L.sub.A34 L.sub.B12 II-729. L.sub.A35 L.sub.B12 II-730. L.sub.A37 L.sub.B12 II-731. L.sub.A38 L.sub.B12 II-732. L.sub.A39 L.sub.B12 II-733. L.sub.A40 L.sub.B12 II-734. L.sub.A41 L.sub.B12 II-735. L.sub.A42 L.sub.B12 II-736. L.sub.A43 L.sub.B12 II-737. L.sub.A44 L.sub.B12 II-738. L.sub.A45 L.sub.B12 II-739. L.sub.A46 L.sub.B12 II-740. L.sub.A47 L.sub.B12 II-741. L.sub.A48 L.sub.B12 II-742. L.sub.A49 L.sub.B12 II-743. L.sub.A50 L.sub.B12 II-744. L.sub.A51 L.sub.B12 II-745. L.sub.A52 L.sub.B12 II-746. L.sub.A54 L.sub.B12 II-747. L.sub.A55 L.sub.B12 II-748. L.sub.A56 L.sub.B12 II-749. L.sub.A57 L.sub.B12 II-750. L.sub.A58 L.sub.B12 II-751. L.sub.A59 L.sub.B12 II-752. L.sub.A60 L.sub.B12 II-753. L.sub.A61 L.sub.B12 II-754. L.sub.A62 L.sub.B12 II-755. L.sub.A63 L.sub.B12 II-756. L.sub.A64 L.sub.B12 II-757. L.sub.A65 L.sub.B12 II-758. L.sub.A66 L.sub.B12 II-759. L.sub.A67 L.sub.B12 II-760. L.sub.A68 L.sub.B12 II-761. L.sub.A69 L.sub.B12 II-762. L.sub.A1 L.sub.B13 II-763. L.sub.A2 L.sub.B13 II-764. L.sub.A3 L.sub.B13 II-765. L.sub.A4 L.sub.B13 II-766. L.sub.A5 L.sub.B13 II-767. L.sub.A6 L.sub.B13 II-768. L.sub.A7 L.sub.B13 II-769. L.sub.A8 L.sub.B13 II-770. L.sub.A9 L.sub.B13 II-771. L.sub.A10 L.sub.B13 II-772. L.sub.A11 L.sub.B13 II-773. L.sub.A12 L.sub.B13 II-774. L.sub.A13 L.sub.B13 II-775. L.sub.A14 L.sub.B13 II-776. L.sub.A15 L.sub.B13 II-777. L.sub.A16 L.sub.B13 II-778. L.sub.A17 L.sub.B13 II-779. L.sub.A18 L.sub.B13 II-780. L.sub.A19 L.sub.B13 II-781. L.sub.A20 L.sub.B13 II-782. L.sub.A21 L.sub.B13 II-783. L.sub.A22 L.sub.B13 II-784. L.sub.A23 L.sub.B13 II-785. L.sub.A24 L.sub.B13 II-786. L.sub.A25 L.sub.B13 II-787. L.sub.A26 L.sub.B13 II-788. L.sub.A27 L.sub.B13 II-789. L.sub.A28 L.sub.B13 II-790. L.sub.A29 L.sub.B13 II-791. L.sub.A30 L.sub.B13 II-792. L.sub.A31 L.sub.B13 II-793. L.sub.A32 L.sub.B13 II-794. L.sub.A33 L.sub.B13 II-795. L.sub.A34 L.sub.B13 II-796. L.sub.A35 L.sub.B13 II-797. L.sub.A36 L.sub.B13 II-798. L.sub.A37 L.sub.B13 II-799. L.sub.A38 L.sub.B13 II-800. L.sub.A39 L.sub.B13 II-801. L.sub.A40 L.sub.B13 II-802. L.sub.A41 L.sub.B13 II-803. L.sub.A42 L.sub.B13 II-804. L.sub.A43 L.sub.B13 II-805. L.sub.A44 L.sub.B13 II-806. L.sub.A45 L.sub.B13 II-807. L.sub.A46 L.sub.B13 II-808. L.sub.A47 L.sub.B13 II-809. L.sub.A48 L.sub.B13 II-810. L.sub.A49 L.sub.B13 II-811. L.sub.A50 L.sub.B13 II-812. L.sub.A51 L.sub.B13 II-813. L.sub.A52 L.sub.B13 II-814. L.sub.A53 L.sub.B13 II-815. L.sub.A54 L.sub.B13 II-816. L.sub.A55 L.sub.B13 II-817. L.sub.A56 L.sub.B13 II-818. L.sub.A57 L.sub.B13 II-819. L.sub.A58 L.sub.B13 II-820. L.sub.A59 L.sub.B13 II-821. L.sub.A60 L.sub.B13 II-822. L.sub.A61 L.sub.B13 II-823. L.sub.A62 L.sub.B13 II-824. L.sub.A63 L.sub.B13 II-825. L.sub.A64 L.sub.B13 II-826. L.sub.A65 L.sub.B13 II-827. L.sub.A66 L.sub.B13 II-828. L.sub.A67 L.sub.B13 II-829. L.sub.A68 L.sub.B13 II-830. L.sub.A69 L.sub.B13 II-831. L.sub.A1 L.sub.B14 II-832. L.sub.A2 L.sub.B14 II-833. L.sub.A3 L.sub.B14 II-834. L.sub.A4 L.sub.B14 II-835. L.sub.A5 L.sub.B14 II-836. L.sub.A6 L.sub.B14 II-837. L.sub.A7 L.sub.B14 II-838. L.sub.A8 L.sub.B14 II-839. L.sub.A9 L.sub.B14 II-840. L.sub.A10 L.sub.B14 II-841. L.sub.A11 L.sub.B14 II-842. L.sub.A12 L.sub.B14 II-843. L.sub.A13 L.sub.B14 II-844. L.sub.A14 L.sub.B14 II-845. L.sub.A15 L.sub.B14 II-846. L.sub.A16 L.sub.B14 II-847. L.sub.A17 L.sub.B14 II-848. L.sub.A18 L.sub.B14 II-849. L.sub.A19 L.sub.B14 II-850. L.sub.A20 L.sub.B14 II-851. L.sub.A21 L.sub.B14 II-852. L.sub.A22 L.sub.B14 II-853. L.sub.A23 L.sub.B14 II-854. L.sub.A24 L.sub.B14 II-855. L.sub.A25 L.sub.B14 II-856. L.sub.A26 L.sub.B14 II-857. L.sub.A27 L.sub.B14 II-858. L.sub.A28 L.sub.B14 II-859. L.sub.A29 L.sub.B14 II-860. L.sub.A30 L.sub.B14 II-861. L.sub.A31 L.sub.B14 II-862. L.sub.A32 L.sub.B14 II-863. L.sub.A33 L.sub.B14 II-864. L.sub.A34 L.sub.B14 II-865. L.sub.A35 L.sub.B14 II-866. L.sub.A36 L.sub.B14 II-867. L.sub.A37 L.sub.B14 II-868. L.sub.A38 L.sub.B14 II-869. L.sub.A39 L.sub.B14 II-870. L.sub.A40 L.sub.B14 II-871. L.sub.A41 L.sub.B14 II-872. L.sub.A42 L.sub.B14 II-873. L.sub.A43 L.sub.B14 II-874. L.sub.A44 L.sub.B14 II-875. L.sub.A45 L.sub.B14 II-876. L.sub.A46 L.sub.B14 II-877. L.sub.A47 L.sub.B14 II-878. L.sub.A48 L.sub.B14 II-879. L.sub.A49 L.sub.B14 II-880. L.sub.A50 L.sub.B14 II-881. L.sub.A51 L.sub.B14 II-882. L.sub.A52 L.sub.B14 II-883. L.sub.A53 L.sub.B14 II-884. L.sub.A54 L.sub.B14 II-885. L.sub.A55 L.sub.B14 II-886. L.sub.A56 L.sub.B14 II-887. L.sub.A57 L.sub.B14 II-888. L.sub.A58 L.sub.B14 II-889. L.sub.A59 L.sub.B14 II-890. L.sub.A60 L.sub.B14 II-891. L.sub.A61 L.sub.B14 II-892. L.sub.A62 L.sub.B14 II-893. L.sub.A63 L.sub.B14 II-894. L.sub.A64 L.sub.B14 II-895. L.sub.A65 L.sub.B14 II-896. L.sub.A66 L.sub.B14 II-897. L.sub.A67 L.sub.B14 II-898. L.sub.A68 L.sub.B14 II-899. L.sub.A69 L.sub.B14 II-900. L.sub.A1 L.sub.B15 II-901. L.sub.A2 L.sub.B15 II-902. L.sub.A3 L.sub.B15 II-903. L.sub.A4 L.sub.B15 II-904. L.sub.A5 L.sub.B15 II-905. L.sub.A6 L.sub.B15 II-906. L.sub.A7 L.sub.B15 II-907. L.sub.A8 L.sub.B15 II-908. L.sub.A9 L.sub.B15 II-909. L.sub.A10 L.sub.B15 II-910. L.sub.A11 L.sub.B15 II-911. L.sub.A12 L.sub.B15 II-912. L.sub.A13 L.sub.B15 II-913. L.sub.A14 L.sub.B15 II-914. L.sub.A15 L.sub.B15 II-915. L.sub.A16 L.sub.B15 II-916. L.sub.A17 L.sub.B15 II-917. L.sub.A18 L.sub.B15 II-918. L.sub.A19 L.sub.B15 II-919. L.sub.A20 L.sub.B15 II-920. L.sub.A21 L.sub.B15 II-921. L.sub.A22 L.sub.B15 II-922. L.sub.A23 L.sub.B15 II-923. L.sub.A24 L.sub.B15 II-924. L.sub.A25 L.sub.B15 II-1387. L.sub.A26 L.sub.B15 II-1388. L.sub.A27 L.sub.B15 II-1389. L.sub.A28 L.sub.B15 II-1390. L.sub.A29 L.sub.B15 II-1391. L.sub.A30 L.sub.B15 II-1392. L.sub.A31 L.sub.B15 II-1393. L.sub.A32 L.sub.B15 II-1394. L.sub.A33 L.sub.B15 II-1395. L.sub.A34 L.sub.B15 II-1396. L.sub.A35 L.sub.B15 II-1397. L.sub.A36 L.sub.B15 II-1398. L.sub.A37 L.sub.B15 II-1399. L.sub.A38 L.sub.B15 II-1400. L.sub.A39 L.sub.B15 II-1401. L.sub.A40 L.sub.B15 II-1402. L.sub.A41 L.sub.B15 II-1403. L.sub.A42 L.sub.B15 II-1404. L.sub.A43 L.sub.B15 II-1405. L.sub.A44 L.sub.B15 II-1406. L.sub.A45 L.sub.B15 II-1407. L.sub.A46 L.sub.B15 II-1408. L.sub.A47 L.sub.B15 II-1409. L.sub.A48 L.sub.B15 II-1410. L.sub.A49 L.sub.B15 II-1411. L.sub.A50 L.sub.B15 II-1412. L.sub.A51 L.sub.B15 II-1413. L.sub.A52 L.sub.B15 II-1414. L.sub.A53 L.sub.B15 II-1415. L.sub.A54 L.sub.B15 II-1416. L.sub.A55 L.sub.B15 II-1417. L.sub.A56 L.sub.B15 II-1418. L.sub.A57 L.sub.B15 II-1419. L.sub.A58 L.sub.B15 II-1420. L.sub.A59 L.sub.B15 II-1421. L.sub.A60 L.sub.B15 II-1422. L.sub.A61 L.sub.B15 II-1423. L.sub.A62 L.sub.B15 II-1424. L.sub.A63 L.sub.B15 II-1425. L.sub.A64 L.sub.B15 II-1426. L.sub.A65 L.sub.B15 II-1427. L.sub.A66 L.sub.B15 II-1428. L.sub.A67 L.sub.B15 II-1429. L.sub.A68 L.sub.B15 II-1430. L.sub.A69 L.sub.B15 II-1431. L.sub.A3 L.sub.B16 II-1432. L.sub.A4 L.sub.B16 II-1433. L.sub.A5 L.sub.B16 II-1434. L.sub.A6 L.sub.B16 II-1435. L.sub.A7 L.sub.B16 II-1436. L.sub.A8 L.sub.B16 II-1437. L.sub.A9 L.sub.B16 II-1438. L.sub.A10 L.sub.B16 II-1439. L.sub.A11 L.sub.B16 II-1440. L.sub.A12 L.sub.B16 II-1441. L.sub.A13 L.sub.B16 II-1442. L.sub.A14 L.sub.B16 II-1443. L.sub.A15 L.sub.B16 II-1444. L.sub.A16 L.sub.B16 II-1445. L.sub.A17 L.sub.B16 II-1446. L.sub.A18 L.sub.B16 II-1447. L.sub.A21 L.sub.B16 II-1448. L.sub.A22 L.sub.B16 II-1449. L.sub.A23 L.sub.B16 II-1450. L.sub.A24 L.sub.B16 II-1451. L.sub.A25 L.sub.B16 II-1452. L.sub.A26 L.sub.B16 II-1453. L.sub.A27 L.sub.B16 II-1454. L.sub.A28 L.sub.B16 II-1455. L.sub.A29 L.sub.B16 II-1456. L.sub.A30 L.sub.B16 II-1457. L.sub.A31 L.sub.B16 II-1458. L.sub.A32 L.sub.B16 II-1459. L.sub.A33 L.sub.B16 II-1460. L.sub.A34 L.sub.B16 II-1461. L.sub.A35 L.sub.B16 II-1462. L.sub.A36 L.sub.B16 II-1463. L.sub.A38 L.sub.B16 II-1464. L.sub.A39 L.sub.B16 II-1465. L.sub.A40 L.sub.B16 II-1466. L.sub.A41 L.sub.B16 II-1467. L.sub.A42 L.sub.B16 II-1468. L.sub.A43 L.sub.B16 II-1469. L.sub.A44 L.sub.B16 II-1470. L.sub.A45 L.sub.B16 II-1471. L.sub.A46 L.sub.B16 II-1472. L.sub.A47 L.sub.B16 II-1473. L.sub.A48 L.sub.B16 II-1474. L.sub.A49 L.sub.B16 II-1475. L.sub.A50 L.sub.B16 II-1476. L.sub.A51 L.sub.B16 II-1477. L.sub.A52 L.sub.B16 II-1478. L.sub.A54 L.sub.B16 II-1479. L.sub.A55 L.sub.B16 II-1480. L.sub.A56 L.sub.B16 II-1481. L.sub.A57 L.sub.B16 II-1482. L.sub.A58 L.sub.B16 II-1483. L.sub.A59 L.sub.B16 II-1484. L.sub.A60 L.sub.B16 II-1485. L.sub.A61 L.sub.B16 II-1486. L.sub.A62 L.sub.B16 II-1487. L.sub.A63 L.sub.B16 II-1488. L.sub.A64 L.sub.B16 II-1489. L.sub.A65 L.sub.B16 II-1490. L.sub.A66 L.sub.B16 II-1491. L.sub.A67 L.sub.B16 II-1492. L.sub.A68 L.sub.B16 II-1493. L.sub.A69 L.sub.B16 II-1494. L.sub.A2 L.sub.B17 II-1495. L.sub.A3 L.sub.B17 II-1496. L.sub.A4 L.sub.B17 II-1497. L.sub.A5 L.sub.B17 II-1498. L.sub.A6 L.sub.B17 II-1499. L.sub.A7 L.sub.B17 II-1500. L.sub.A8 L.sub.B17 II-1501. L.sub.A9 L.sub.B17 II-1502. L.sub.A10 L.sub.B17 II-1503. L.sub.A11 L.sub.B17 II-1504. L.sub.A12 L.sub.B17 II-1505. L.sub.A13 L.sub.B17 II-1506. L.sub.A14 L.sub.B17 II-1507. L.sub.A15 L.sub.B17 II-1508. L.sub.A16 L.sub.B17 II-1509. L.sub.A17 L.sub.B17 II-1510. L.sub.A18 L.sub.B17 II-1511. L.sub.A20 L.sub.B17 II-1512. L.sub.A21 L.sub.B17 II-1513. L.sub.A22 L.sub.B17 II-1514. L.sub.A23 L.sub.B17 II-1515. L.sub.A24 L.sub.B17 II-1516. L.sub.A25 L.sub.B17 II-1517. L.sub.A26 L.sub.B17 II-1518. L.sub.A27 L.sub.B17 II-1519. L.sub.A28 L.sub.B17 II-1520. L.sub.A29 L.sub.B17 II-1521. L.sub.A30 L.sub.B17 II-1522. L.sub.A31 L.sub.B17 II-1523. L.sub.A32 L.sub.B17 II-1524. L.sub.A33 L.sub.B17 II-1525. L.sub.A34 L.sub.B17 II-1526. L.sub.A35 L.sub.B17 II-1527. L.sub.A36 L.sub.B17 II-1528. L.sub.A37 L.sub.B17 II-1529. L.sub.A38 L.sub.B17 II-1530. L.sub.A39 L.sub.B17 II-1531. L.sub.A40 L.sub.B17 II-1532. L.sub.A41 L.sub.B17 II-1533. L.sub.A42 L.sub.B17 II-1534. L.sub.A43 L.sub.B17 II-1535. L.sub.A44 L.sub.B17 II-1536. L.sub.A45 L.sub.B17 II-1537. L.sub.A46 L.sub.B17 II-1538. L.sub.A47 L.sub.B17 II-1539. L.sub.A48 L.sub.B17 II-1540. L.sub.A49 L.sub.B17 II-1541. L.sub.A50 L.sub.B17 II-1542. L.sub.A51 L.sub.B17 II-1543. L.sub.A52 L.sub.B17 II-1544. L.sub.A53 L.sub.B17 II-1545. L.sub.A54 L.sub.B17 II-1546. L.sub.A55 L.sub.B17 II-1547. L.sub.A56 L.sub.B17 II-1548. L.sub.A57 L.sub.B17 II-1549. L.sub.A58 L.sub.B17 II-1550. L.sub.A59 L.sub.B17 II-1551. L.sub.A60 L.sub.B17 II-1552. L.sub.A61 L.sub.B17 II-1553. L.sub.A62 L.sub.B17 II-1554. L.sub.A63 L.sub.B17 II-1555. L.sub.A64 L.sub.B17 II-1556. L.sub.A65 L.sub.B17 II-1557. L.sub.A66 L.sub.B17 II-1558. L.sub.A67 L.sub.B17 II-1559. L.sub.A68 L.sub.B17 II-1560. L.sub.A69 L.sub.B17 II-1561. L.sub.A2 L.sub.B18 II-1562. L.sub.A3 L.sub.B18 II-1563. L.sub.A4 L.sub.B18 II-1564. L.sub.A5 L.sub.B18 II-1565. L.sub.A6 L.sub.B18 II-1566. L.sub.A7 L.sub.B18 II-1567. L.sub.A8 L.sub.B18 II-1568. L.sub.A9 L.sub.B18 II-1569. L.sub.A10 L.sub.B18 II-1570. L.sub.A11 L.sub.B18 II-1571. L.sub.A12 L.sub.B18 II-1572. L.sub.A13 L.sub.B18 II-1573. L.sub.A14 L.sub.B18 II-1574. L.sub.A15 L.sub.B18 II-1575. L.sub.A16 L.sub.B18 II-1576. L.sub.A17 L.sub.B18 II-1577. L.sub.A18 L.sub.B18 II-1578. L.sub.A20 L.sub.B18 II-1579. L.sub.A21 L.sub.B18 II-1580. L.sub.A22 L.sub.B18 II-1581. L.sub.A23 L.sub.B18 II-1582. L.sub.A24 L.sub.B18 II-1583. L.sub.A25 L.sub.B18 II-1584. L.sub.A26 L.sub.B18 II-1585. L.sub.A27 L.sub.B18 II-1586. L.sub.A28 L.sub.B18 II-1587. L.sub.A29 L.sub.B18 II-1588. L.sub.A30 L.sub.B18 II-1589. L.sub.A31 L.sub.B18 II-1590. L.sub.A32 L.sub.B18 II-1591. L.sub.A33 L.sub.B18 II-1592. L.sub.A34 L.sub.B18 II-1593. L.sub.A35 L.sub.B18 II-1594. L.sub.A36 L.sub.B18 II-1595. L.sub.A37 L.sub.B18 II-1596. L.sub.A38 L.sub.B18 II-1597. L.sub.A39 L.sub.B18 II-1598. L.sub.A40 L.sub.B18 II-1599. L.sub.A41 L.sub.B18 II-1600. L.sub.A42 L.sub.B18 II-1601. L.sub.A43 L.sub.B18 II-1602. L.sub.A44 L.sub.B18 II-1603. L.sub.A45 L.sub.B18 II-1604. L.sub.A46 L.sub.B18 II-1605. L.sub.A47 L.sub.B18 II-1606. L.sub.A48 L.sub.B18 II-1607. L.sub.A49 L.sub.B18 II-1608. L.sub.A50 L.sub.B18 II-1609. L.sub.A51 L.sub.B18 II-1610. L.sub.A52 L.sub.B18 II-1611. L.sub.A53 L.sub.B18 II-1612. L.sub.A54 L.sub.B18 II-1613. L.sub.A55 L.sub.B18 II-1614. L.sub.A56 L.sub.B18 II-1615. L.sub.A57 L.sub.B18 II-1616. L.sub.A58 L.sub.B18 II-1617. L.sub.A59 L.sub.B18 II-1618. L.sub.A60 L.sub.B18 II-1619. L.sub.A61 L.sub.B18 II-1620. L.sub.A62 L.sub.B18 II-1621. L.sub.A63 L.sub.B18 II-1622. L.sub.A64 L.sub.B18 II-1623. L.sub.A65 L.sub.B18 II-1624. L.sub.A66 L.sub.B18 II-1625. L.sub.A67 L.sub.B18 II-1626. L.sub.A68 L.sub.B18 II-1627. L.sub.A69 L.sub.B18 II-1628. L.sub.A2 L.sub.B19 II-1629. L.sub.A3 L.sub.B19 II-1630. L.sub.A4 L.sub.B19 II-1631. L.sub.A5 L.sub.B19 II-1632. L.sub.A6 L.sub.B19 II-1633. L.sub.A7 L.sub.B19 II-1634. L.sub.A8 L.sub.B19 II-1635. L.sub.A9 L.sub.B19 II-1636. L.sub.A10 L.sub.B19 II-1637. L.sub.A11 L.sub.B19 II-1638. L.sub.A12 L.sub.B19 II-1639. L.sub.A13 L.sub.B19 II-1640. L.sub.A14 L.sub.B19 II-1641. L.sub.A15 L.sub.B19 II-1642. L.sub.A16 L.sub.B19 II-1643. L.sub.A17 L.sub.B19 II-1644. L.sub.A18 L.sub.B19 II-1645. L.sub.A20 L.sub.B19 II-1646. L.sub.A21 L.sub.B19 II-1647. L.sub.A22 L.sub.B19 II-1648. L.sub.A23 L.sub.B19 II-1649. L.sub.A24 L.sub.B19 II-1650. L.sub.A25 L.sub.B19 II-1651. L.sub.A26 L.sub.B19 II-1652. L.sub.A27 L.sub.B19 II-1653. L.sub.A28 L.sub.B19 II-1654. L.sub.A29 L.sub.B19 II-1655. L.sub.A30 L.sub.B19 II-1656. L.sub.A31 L.sub.B19 II-1657. L.sub.A32 L.sub.B19 II-1658. L.sub.A33 L.sub.B19 II-1659. L.sub.A34 L.sub.B19 II-1660. L.sub.A35 L.sub.B19 II-1661. L.sub.A36 L.sub.B19 II-1662. L.sub.A37 L.sub.B19 II-1663. L.sub.A38 L.sub.B19 II-1664. L.sub.A39 L.sub.B19 II-1665. L.sub.A40 L.sub.B19 II-1666. L.sub.A41 L.sub.B19 II-1667. L.sub.A42 L.sub.B19 II-1668. L.sub.A43 L.sub.B19 II-1669. L.sub.A44 L.sub.B19 II-1670. L.sub.A45 L.sub.B19 II-1671. L.sub.A46 L.sub.B19 II-1672. L.sub.A47 L.sub.B19 II-1673. L.sub.A48 L.sub.B19 II-1674. L.sub.A49 L.sub.B19 II-1675. L.sub.A50 L.sub.B19 II-1676. L.sub.A51 L.sub.B19 II-1677. L.sub.A52 L.sub.B19 II-1678. L.sub.A53 L.sub.B19 II-1679. L.sub.A54 L.sub.B19 II-1680. L.sub.A55 L.sub.B19 II-1681. L.sub.A56 L.sub.B19 II-1682. L.sub.A57 L.sub.B19 II-1683. L.sub.A58 L.sub.B19 II-1684. L.sub.A59 L.sub.B19 II-1685. L.sub.A60 L.sub.B19 II-1686. L.sub.A61 L.sub.B19 II-1687. L.sub.A62 L.sub.B19 II-1688. L.sub.A63 L.sub.B19 II-1689. L.sub.A64 L.sub.B19 II-1690. L.sub.A65 L.sub.B19 II-1691. L.sub.A66 L.sub.B19 II-1692. L.sub.A67 L.sub.B19 II-1693. L.sub.A68 L.sub.B19 II-1694. L.sub.A69 L.sub.B19 II-1695. L.sub.A2 L.sub.B20 II-1696. L.sub.A3 L.sub.B20 II-1697. L.sub.A4 L.sub.B20 II-1698. L.sub.A5 L.sub.B20 II-1699. L.sub.A6 L.sub.B20 II-1700. L.sub.A7 L.sub.B20 II-1701. L.sub.A8 L.sub.B20 II-1702. L.sub.A9 L.sub.B20 II-1703. L.sub.A10 L.sub.B20 II-1704. L.sub.A11 L.sub.B20 II-1705. L.sub.A12 L.sub.B20 II-1706. L.sub.A13 L.sub.B20 II-1707. L.sub.A14 L.sub.B20 II-1708. L.sub.A15 L.sub.B20 II-1709. L.sub.A16 L.sub.B20 II-1710. L.sub.A17 L.sub.B20 II-1711. L.sub.A18 L.sub.B20 II-1712. L.sub.A20 L.sub.B20 II-1713. L.sub.A21 L.sub.B20 II-1714. L.sub.A22 L.sub.B20 II-1715. L.sub.A23 L.sub.B20 II-1716. L.sub.A24 L.sub.B20 II-1717. L.sub.A25 L.sub.B20 II-1718. L.sub.A26 L.sub.B20 II-1719. L.sub.A27 L.sub.B20 II-1720. L.sub.A28 L.sub.B20 II-1721. L.sub.A29 L.sub.B20 II-1722. L.sub.A30 L.sub.B20 II-1723. L.sub.A31 L.sub.B20 II-1724. L.sub.A32 L.sub.B20 II-1725. L.sub.A33 L.sub.B20 II-1726. L.sub.A34 L.sub.B20 II-1727. L.sub.A35 L.sub.B20 II-1728. L.sub.A36 L.sub.B20 II-1729. L.sub.A37 L.sub.B20 II-1730. L.sub.A38 L.sub.B20 II-1731. L.sub.A39 L.sub.B20 II-1732. L.sub.A40 L.sub.B20 II-1733. L.sub.A41 L.sub.B20 II-1734. L.sub.A42 L.sub.B20 II-1735. L.sub.A43 L.sub.B20 II-1736. L.sub.A44 L.sub.B20 II-1737. L.sub.A45 L.sub.B20 II-1738. L.sub.A46 L.sub.B20 II-1739. L.sub.A47 L.sub.B20 II-1740. L.sub.A48 L.sub.B20 II-1741. L.sub.A49 L.sub.B20 II-1742. L.sub.A50 L.sub.B20 II-1743. L.sub.A51 L.sub.B20 II-1744. L.sub.A52 L.sub.B20 II-1745. L.sub.A53 L.sub.B20 II-1746. L.sub.A54 L.sub.B20 II-1747. L.sub.A55 L.sub.B20 II-1748. L.sub.A56 L.sub.B20 II-1749. L.sub.A57 L.sub.B20 II-1750. L.sub.A58 L.sub.B20 II-1751. L.sub.A59 L.sub.B20 II-1752. L.sub.A60 L.sub.B20 II-1753. L.sub.A61 L.sub.B20 II-1754. L.sub.A62 L.sub.B20 II-1755. L.sub.A63 L.sub.B20 II-1756. L.sub.A64 L.sub.B20 II-1757. L.sub.A65 L.sub.B20 II-1758. L.sub.A66 L.sub.B20 II-1759. L.sub.A67 L.sub.B20 II-1760. L.sub.A68 L.sub.B20 II-1761. L.sub.A69 L.sub.B20 II-1762. L.sub.A2 L.sub.B21 II-1763. L.sub.A3 L.sub.B21 II-1764. L.sub.A4 L.sub.B21 II-1765. L.sub.A5 L.sub.B21 II-1766. L.sub.A6 L.sub.B21 II-1767. L.sub.A7 L.sub.B21 II-1768. L.sub.A8 L.sub.B21 II-1769. L.sub.A9 L.sub.B21 II-1770. L.sub.A10 L.sub.B21 II-1771. L.sub.A11 L.sub.B21 II-1772. L.sub.A12 L.sub.B21 II-1773. L.sub.A13 L.sub.B21 II-1774. L.sub.A14 L.sub.B21 II-1775. L.sub.A15 L.sub.B21 II-1776. L.sub.A16 L.sub.B21 II-1777. L.sub.A17 L.sub.B21 II-1778. L.sub.A18 L.sub.B21 II-1779. L.sub.A20 L.sub.B21 II-1780. L.sub.A21 L.sub.B21 II-1781. L.sub.A22 L.sub.B21 II-1782. L.sub.A23 L.sub.B21 II-1783. L.sub.A24 L.sub.B21 II-1784. L.sub.A25 L.sub.B21 II-1785. L.sub.A26 L.sub.B21 II-1786. L.sub.A27 L.sub.B21 II-1787. L.sub.A28 L.sub.B21 II-1788. L.sub.A29 L.sub.B21 II-1789. L.sub.A30 L.sub.B21 II-1790. L.sub.A31 L.sub.B21 II-1791. L.sub.A32 L.sub.B21 II-1792. L.sub.A33 L.sub.B21 II-1793. L.sub.A34 L.sub.B21 II-1794. L.sub.A35 L.sub.B21 II-1795. L.sub.A36 L.sub.B21 II-1796. L.sub.A37 L.sub.B21 II-1797. L.sub.A38 L.sub.B21 II-1798. L.sub.A39 L.sub.B21 II-1799. L.sub.A40 L.sub.B21 II-1800. L.sub.A41 L.sub.B21 II-1801. L.sub.A42 L.sub.B21 II-1802. L.sub.A43 L.sub.B21 II-1803. L.sub.A44 L.sub.B21 II-1804. L.sub.A45 L.sub.B21 II-1805. L.sub.A46 L.sub.B21 II-1806. L.sub.A47 L.sub.B21 II-1807. L.sub.A48 L.sub.B21 II-1808. L.sub.A49 L.sub.B21 II-1809. L.sub.A50 L.sub.B21 II-1810. L.sub.A51 L.sub.B21 II-1811. L.sub.A52 L.sub.B21 II-1812. L.sub.A53 L.sub.B21 II-1813. L.sub.A54 L.sub.B21 II-1814. L.sub.A55 L.sub.B21 II-1815. L.sub.A56 L.sub.B21 II-1816. L.sub.A57 L.sub.B21 II-1817. L.sub.A58 L.sub.B21 II-1818. L.sub.A59 L.sub.B21 II-1819. L.sub.A60 L.sub.B21 II-1820. L.sub.A61 L.sub.B21 II-1821. L.sub.A62 L.sub.B21 II-1822. L.sub.A63 L.sub.B21 II-1823. L.sub.A64 L.sub.B21 II-1824. L.sub.A65 L.sub.B21 II-1825. L.sub.A66 L.sub.B21 II-1826. L.sub.A67 L.sub.B21 II-1827. L.sub.A68 L.sub.B21 II-1828. L.sub.A69 L.sub.B21 II-1829. L.sub.A2 L.sub.B22 II-1830. L.sub.A3 L.sub.B22 II-1831. L.sub.A4 L.sub.B22 II-1832. L.sub.A5 L.sub.B22 II-1833. L.sub.A6 L.sub.B22 II-1834. L.sub.A7 L.sub.B22 II-1835. L.sub.A8 L.sub.B22 II-1836. L.sub.A9 L.sub.B22 II-1837. L.sub.A10 L.sub.B22 II-1838. L.sub.A11 L.sub.B22 II-1839. L.sub.A12 L.sub.B22 II-1840. L.sub.A13 L.sub.B22 II-1841. L.sub.A14 L.sub.B22 II-1842. L.sub.A15 L.sub.B22 II-1843. L.sub.A16 L.sub.B22 II-1844. L.sub.A17 L.sub.B22 II-1845. L.sub.A18 L.sub.B22 II-1846. L.sub.A20 L.sub.B22 II-1847. L.sub.A21 L.sub.B22 II-1848. L.sub.A22 L.sub.B22 II-1387. L.sub.A23 L.sub.B22 II-1388. L.sub.A24 L.sub.B22 II-1389. L.sub.A25 L.sub.B22 II-1390. L.sub.A26 L.sub.B22 II-1391. L.sub.A27 L.sub.B22 II-1392. L.sub.A28 L.sub.B22 II-1393. L.sub.A29 L.sub.B22 II-1394. L.sub.A30 L.sub.B22 II-1395. L.sub.A31 L.sub.B22 II-1396. L.sub.A32 L.sub.B22 II-1397. L.sub.A33 L.sub.B22 II-1398. L.sub.A34 L.sub.B22 II-1399. L.sub.A35 L.sub.B22 II-1400. L.sub.A36 L.sub.B22 II-1401. L.sub.A37 L.sub.B22 II-1402. L.sub.A38 L.sub.B22 II-1403. L.sub.A39 L.sub.B22 II-1404. L.sub.A40 L.sub.B22 II-1405. L.sub.A41 L.sub.B22 II-1406. L.sub.A42 L.sub.B22 II-1407. L.sub.A43 L.sub.B22 II-1408. L.sub.A44 L.sub.B22 II-1409. L.sub.A45 L.sub.B22 II-1410. L.sub.A46 L.sub.B22 II-1411. L.sub.A47 L.sub.B22 II-1412. L.sub.A48 L.sub.B22 II-1413. L.sub.A49 L.sub.B22 II-1414. L.sub.A50 L.sub.B22 II-1415. L.sub.A51 L.sub.B22 II-1416. L.sub.A52 L.sub.B22 II-1417. L.sub.A53 L.sub.B22 II-1418. L.sub.A54 L.sub.B22 II-1419. L.sub.A55 L.sub.B22 II-1420. L.sub.A56 L.sub.B22 II-1421. L.sub.A57 L.sub.B22 II-1422. L.sub.A58 L.sub.B22 II-1423. L.sub.A59 L.sub.B22 II-1424. L.sub.A60 L.sub.B22 II-1425. L.sub.A61 L.sub.B22 II-1426. L.sub.A62 L.sub.B22 II-1427. L.sub.A63 L.sub.B22 II-1428. L.sub.A64 L.sub.B22 II-1429. L.sub.A65 L.sub.B22 II-1430. L.sub.A66 L.sub.B22 II-1431. L.sub.A67 L.sub.B22 II-1432. L.sub.A68 L.sub.B22 II-1433. L.sub.A69 L.sub.B22 II-1434. L.sub.A1 L.sub.B23 II-1435. L.sub.A2 L.sub.B23 II-1436. L.sub.A3 L.sub.B23 II-1437. L.sub.A4 L.sub.B23 II-1438. L.sub.A5 L.sub.B23 II-1439. L.sub.A6 L.sub.B23 II-1440. L.sub.A7 L.sub.B23 II-1441. L.sub.A8 L.sub.B23 II-1442. L.sub.A9 L.sub.B23 II-1443. L.sub.A10 L.sub.B23 II-1444. L.sub.A11 L.sub.B23 II-1445. L.sub.A12 L.sub.B23 II-1446. L.sub.A13 L.sub.B23 II-1447. L.sub.A14 L.sub.B23 II-1448. L.sub.A15 L.sub.B23 II-1449. L.sub.A16 L.sub.B23 II-1450. L.sub.A17 L.sub.B23 II-1451. L.sub.A18 L.sub.B23 II-1452. L.sub.A19 L.sub.B23 II-1453. L.sub.A20 L.sub.B23 II-1454. L.sub.A21 L.sub.B23 II-1455. L.sub.A22 L.sub.B23 II-1456. L.sub.A23 L.sub.B23 II-1457. L.sub.A24 L.sub.B23 II-1458. L.sub.A25 L.sub.B23 II-1459. L.sub.A26 L.sub.B23 II-1460. L.sub.A27 L.sub.B23 II-1461. L.sub.A28 L.sub.B23 II-1462. L.sub.A29 L.sub.B23 II-1463. L.sub.A30 L.sub.B23 II-1464. L.sub.A31 L.sub.B23 II-1465. L.sub.A32 L.sub.B23 II-1466. L.sub.A33 L.sub.B23 II-1467. L.sub.A34 L.sub.B23 II-1468. L.sub.A35 L.sub.B23 II-1469. L.sub.A36 L.sub.B23 II-1470. L.sub.A37 L.sub.B23 II-1471. L.sub.A38 L.sub.B23 II-1472. L.sub.A39 L.sub.B23 II-1473. L.sub.A40 L.sub.B23 II-1474. L.sub.A41 L.sub.B23 II-1475. L.sub.A42 L.sub.B23 II-1476. L.sub.A43 L.sub.B23 II-1477. L.sub.A44 L.sub.B23 II-1478. L.sub.A45 L.sub.B23 II-1479. L.sub.A46 L.sub.B23 II-1480. L.sub.A47 L.sub.B23 II-1481. L.sub.A48 L.sub.B23 II-1482. L.sub.A49 L.sub.B23 II-1483. L.sub.A50 L.sub.B23 II-1484. L.sub.A51 L.sub.B23 II-1485. L.sub.A52 L.sub.B23 II-1486. L.sub.A53 L.sub.B23 II-1487. L.sub.A54 L.sub.B23 II-1488. L.sub.A55 L.sub.B23 II-1489. L.sub.A56 L.sub.B23 II-1490. L.sub.A57 L.sub.B23 II-1491. L.sub.A58 L.sub.B23 II-1492. L.sub.A59 L.sub.B23 II-1493. L.sub.A60 L.sub.B23 II-1494. L.sub.A61 L.sub.B23 II-1495. L.sub.A62 L.sub.B23 II-1496. L.sub.A63 L.sub.B23 II-1497. L.sub.A64 L.sub.B23 II-1498. L.sub.A65 L.sub.B23 II-1499. L.sub.A66 L.sub.B23 II-1500. L.sub.A67 L.sub.B23 II-1501. L.sub.A68 L.sub.B23 II-1502. L.sub.A69 L.sub.B23 II-1503. L.sub.A1 L.sub.B24 II-1504. L.sub.A2 L.sub.B24 II-1505. L.sub.A3 L.sub.B24 II-1506. L.sub.A4 L.sub.B24 II-1507. L.sub.A5 L.sub.B24 II-1508. L.sub.A6 L.sub.B24 II-1509. L.sub.A7 L.sub.B24 II-1510. L.sub.A8 L.sub.B24 II-1511. L.sub.A9 L.sub.B24 II-1512. L.sub.A10 L.sub.B24 II-1513. L.sub.A11 L.sub.B24 II-1514. L.sub.A12 L.sub.B24 II-1515. L.sub.A13 L.sub.B24 II-1516. L.sub.A14 L.sub.B24 II-1517. L.sub.A15 L.sub.B24 II-1518. L.sub.A16 L.sub.B24 II-1519. L.sub.A17 L.sub.B24 II-1520. L.sub.A18 L.sub.B24 II-1521. L.sub.A19 L.sub.B24 II-1522. L.sub.A20 L.sub.B24 II-1523. L.sub.A21 L.sub.B24 II-1524. L.sub.A22 L.sub.B24 II-1525. L.sub.A23 L.sub.B24 II-1526. L.sub.A24 L.sub.B24 II-1527. L.sub.A25 L.sub.B24 II-1528. L.sub.A26 L.sub.B24 II-1529. L.sub.A27 L.sub.B24 II-1530. L.sub.A28 L.sub.B24 II-1531. L.sub.A29 L.sub.B24 II-1532. L.sub.A30 L.sub.B24 II-1533. L.sub.A31 L.sub.B24 II-1534. L.sub.A32 L.sub.B24 II-1535. L.sub.A33 L.sub.B24 II-1536. L.sub.A34 L.sub.B24 II-1537. L.sub.A35 L.sub.B24 II-1538. L.sub.A36 L.sub.B24 II-1539. L.sub.A37 L.sub.B24 II-1540. L.sub.A38 L.sub.B24 II-1541. L.sub.A39 L.sub.B24 II-1542. L.sub.A40 L.sub.B24 II-1543. L.sub.A41 L.sub.B24 II-1544. L.sub.A42 L.sub.B24 II-1545. L.sub.A43 L.sub.B24 II-1546. L.sub.A44 L.sub.B24 II-1547. L.sub.A45 L.sub.B24 II-1548. L.sub.A46 L.sub.B24 II-1549. L.sub.A47 L.sub.B24 II-1550. L.sub.A48 L.sub.B24 II-1551. L.sub.A49 L.sub.B24 II-1552. L.sub.A50 L.sub.B24 II-1553. L.sub.A51 L.sub.B24 II-1554. L.sub.A52 L.sub.B24 II-1555. L.sub.A53 L.sub.B24 II-1556. L.sub.A54 L.sub.B24 II-1557. L.sub.A55 L.sub.B24 II-1558. L.sub.A56 L.sub.B24 II-1559. L.sub.A57 L.sub.B24 II-1560. L.sub.A58 L.sub.B24 II-1561. L.sub.A59 L.sub.B24 II-1562. L.sub.A60 L.sub.B24 II-1563. L.sub.A61 L.sub.B24 II-1564. L.sub.A62 L.sub.B24 II-1565. L.sub.A63 L.sub.B24 II-1566. L.sub.A64 L.sub.B24 II-1567. L.sub.A65 L.sub.B24 II-1568. L.sub.A66 L.sub.B24 II-1569. L.sub.A67 L.sub.B24 II-1570. L.sub.A68 L.sub.B24 II-1571. L.sub.A69 L.sub.B24 II-1572. L.sub.A1 L.sub.B25 II-1573. L.sub.A2 L.sub.B25 II-1574. L.sub.A3 L.sub.B25 II-1575. L.sub.A4 L.sub.B25 II-1576. L.sub.A5 L.sub.B25 II-1577. L.sub.A6 L.sub.B25 II-1578. L.sub.A7 L.sub.B25 II-1579. L.sub.A8 L.sub.B25 II-1580. L.sub.A9 L.sub.B25 II-1581. L.sub.A10 L.sub.B25 II-1582. L.sub.A11 L.sub.B25 II-1583. L.sub.A12 L.sub.B25 II-1584. L.sub.A13 L.sub.B25 II-1585. L.sub.A14 L.sub.B25 II-1586. L.sub.A15 L.sub.B25 II-1587. L.sub.A16 L.sub.B25 II-1588. L.sub.A17 L.sub.B25 II-1589. L.sub.A18 L.sub.B25 II-1590. L.sub.A19 L.sub.B25 II-1591. L.sub.A20 L.sub.B25 II-1592. L.sub.A21 L.sub.B25 II-1593. L.sub.A22 L.sub.B25 II-1594. L.sub.A23 L.sub.B25 II-1595. L.sub.A24 L.sub.B25 II-1596. L.sub.A25 L.sub.B25 II-1597. L.sub.A26 L.sub.B25 II-1598. L.sub.A27 L.sub.B25 II-1599. L.sub.A28 L.sub.B25 II-1600. L.sub.A29 L.sub.B25 II-1601. L.sub.A30 L.sub.B25 II-1602. L.sub.A31 L.sub.B25 II-1603. L.sub.A32 L.sub.B25 II-1604. L.sub.A33 L.sub.B25 II-1605. L.sub.A34 L.sub.B25 II-1606. L.sub.A35 L.sub.B25 II-1607. L.sub.A36 L.sub.B25 II-1608. L.sub.A37 L.sub.B25 II-1609. L.sub.A38 L.sub.B25 II-1610. L.sub.A39 L.sub.B25 II-1611. L.sub.A40 L.sub.B25 II-1612. L.sub.A41 L.sub.B25 II-1613. L.sub.A42 L.sub.B25 II-1614. L.sub.A43 L.sub.B25 II-1615. L.sub.A44 L.sub.B25 II-1616. L.sub.A45 L.sub.B25 II-1617. L.sub.A46 L.sub.B25 II-1618. L.sub.A47 L.sub.B25 II-1619. L.sub.A48 L.sub.B25 II-1620. L.sub.A49 L.sub.B25 II-1621. L.sub.A50 L.sub.B25 II-1622. L.sub.A51 L.sub.B25 II-1623. L.sub.A52 L.sub.B25 II-1624. L.sub.A53 L.sub.B25 II-1625. L.sub.A54 L.sub.B25 II-1626. L.sub.A55 L.sub.B25 II-1627. L.sub.A56 L.sub.B25 II-1628. L.sub.A57 L.sub.B25 II-1629. L.sub.A58 L.sub.B25 II-1630. L.sub.A59 L.sub.B25 II-1631. L.sub.A60 L.sub.B25 II-1632. L.sub.A61 L.sub.B25 II-1633. L.sub.A62 L.sub.B25 II-1634. L.sub.A63 L.sub.B25 II-1635. L.sub.A64 L.sub.B25 II-1636. L.sub.A65 L.sub.B25 II-1637. L.sub.A66 L.sub.B25 II-1638. L.sub.A67 L.sub.B25 II-1639. L.sub.A68 L.sub.B25 II-1640. L.sub.A69 L.sub.B25 II-1641. L.sub.A1 L.sub.B26 II-1642. L.sub.A2 L.sub.B26 II-1643. L.sub.A3 L.sub.B26 II-1644. L.sub.A4 L.sub.B26 II-1645. L.sub.A5 L.sub.B26 II-1646 L.sub.A6 L.sub.B26 II-1647. L.sub.A7 L.sub.B26 II-1648. L.sub.A8 L.sub.B26 II-1649. L.sub.A9 L.sub.B26 II-1650. L.sub.A10 L.sub.B26 II-1651. L.sub.A11 L.sub.B26 II-1652. L.sub.A12 L.sub.B26 II-1653. L.sub.A13 L.sub.B26 II-1654. L.sub.A14 L.sub.B26 II-1655. L.sub.A15 L.sub.B26 II-1656. L.sub.A16 L.sub.B26 II-1657. L.sub.A17 L.sub.B26 II-1658. L.sub.A18 L.sub.B26 II-1659. L.sub.A19 L.sub.B26 II-1660. L.sub.A20 L.sub.B26 II-1661. L.sub.A21 L.sub.B26 II-1662. L.sub.A22 L.sub.B26 II-1663. L.sub.A23 L.sub.B26 II-1664. L.sub.A24 L.sub.B26 II-1665. L.sub.A25 L.sub.B26 II-1666. L.sub.A26 L.sub.B26 II-1667. L.sub.A27 L.sub.B26 II-1668. L.sub.A28 L.sub.B26 II-1669. L.sub.A29 L.sub.B26 II-1670. L.sub.A30 L.sub.B26 II-1671. L.sub.A31 L.sub.B26 II-1672. L.sub.A32 L.sub.B26 II-1673. L.sub.A33 L.sub.B26 II-1674. L.sub.A34 L.sub.B26 II-1675. L.sub.A35 L.sub.B26 II-1676. L.sub.A36 L.sub.B26 II-1677. L.sub.A37 L.sub.B26 II-1678. L.sub.A38 L.sub.B26 II-1679. L.sub.A39 L.sub.B26 II-1680. L.sub.A40 L.sub.B26 II-1681. L.sub.A41 L.sub.B26 II-1682. L.sub.A42 L.sub.B26 II-1683. L.sub.A43 L.sub.B26 II-1684. L.sub.A44 L.sub.B26 II-1685. L.sub.A45 L.sub.B26 II-1686. L.sub.A46 L.sub.B26 II-1687. L.sub.A47 L.sub.B26 II-1688. L.sub.A48 L.sub.B26 II-1689. L.sub.A49 L.sub.B26 II-1690. L.sub.A50 L.sub.B26 II-1691. L.sub.A51 L.sub.B26 II-1692. L.sub.A52 L.sub.B26 II-1693. L.sub.A53 L.sub.B26 II-1694. L.sub.A54 L.sub.B26 II-1695. L.sub.A55 L.sub.B26 II-1696. L.sub.A56 L.sub.B26 II-1697. L.sub.A57 L.sub.B26 II-1698. L.sub.A58 L.sub.B26 II-1699. L.sub.A59 L.sub.B26 II-1700. L.sub.A60 L.sub.B26 II-1701. L.sub.A61 L.sub.B26 II-1702. L.sub.A62 L.sub.B26 II-1703. L.sub.A63 L.sub.B26 II-1704. L.sub.A64 L.sub.B26 II-1705. L.sub.A65 L.sub.B26 II-1706. L.sub.A66 L.sub.B26 II-1707. L.sub.A67 L.sub.B26 II-1708. L.sub.A68 L.sub.B26 II-1709. L.sub.A69 L.sub.B26 II-1710. L.sub.A1 L.sub.B27 II-1711. L.sub.A2 L.sub.B27 II-1712. L.sub.A3 L.sub.B27 II-1713. L.sub.A4 L.sub.B27 II-1714. L.sub.A5 L.sub.B27 II-1715. L.sub.A6 L.sub.B27 II-1716. L.sub.A7 L.sub.B27 II-1717. L.sub.A8 L.sub.B27 II-1718. L.sub.A9 L.sub.B27 II-1719. L.sub.A10 L.sub.B27 II-1720. L.sub.A11 L.sub.B27 II-1721. L.sub.A12 L.sub.B27 II-1722. L.sub.A13 L.sub.B27 II-1723. L.sub.A14 L.sub.B27 II-1724. L.sub.A15 L.sub.B27 II-1725. L.sub.A16 L.sub.B27 II-1726. L.sub.A17 L.sub.B27 II-1727. L.sub.A18 L.sub.B27 II-1728. L.sub.A19 L.sub.B27 II-1729. L.sub.A20 L.sub.B27 II-1730. L.sub.A21 L.sub.B27 II-1731. L.sub.A22 L.sub.B27 II-1732. L.sub.A23 L.sub.B27 II-1733. L.sub.A24 L.sub.B27 II-1734. L.sub.A25 L.sub.B27 II-1735. L.sub.A26 L.sub.B27 II-1736. L.sub.A27 L.sub.B27 II-1737. L.sub.A28 L.sub.B27 II-1738. L.sub.A29 L.sub.B27 II-1739. L.sub.A30 L.sub.B27 II-1740. L.sub.A31 L.sub.B27 II-1741. L.sub.A32 L.sub.B27 II-1742. L.sub.A33 L.sub.B27 II-1743. L.sub.A34 L.sub.B27 II-1744. L.sub.A35 L.sub.B27 II-1745. L.sub.A36 L.sub.B27 II-1746. L.sub.A37 L.sub.B27 II-1747. L.sub.A38 L.sub.B27 II-1748. L.sub.A39 L.sub.B27 II-1749. L.sub.A40 L.sub.B27 II-1750. L.sub.A41 L.sub.B27 II-1751. L.sub.A42 L.sub.B27 II-1752. L.sub.A43 L.sub.B27 II-1753. L.sub.A44 L.sub.B27 II-1754. L.sub.A45 L.sub.B27 II-1755. L.sub.A46 L.sub.B27 II-1756. L.sub.A47 L.sub.B27 II-1757. L.sub.A48 L.sub.B27 II-1758. L.sub.A49 L.sub.B27 II-1759. L.sub.A50 L.sub.B27 II-1760. L.sub.A51 L.sub.B27 II-1761. L.sub.A52 L.sub.B27 II-1762. L.sub.A53 L.sub.B27 II-1763. L.sub.A54 L.sub.B27 II-1764. L.sub.A55 L.sub.B27 II-1765. L.sub.A56 L.sub.B27 II-1766. L.sub.A57 L.sub.B27 II-1767. L.sub.A58 L.sub.B27 II-1768. L.sub.A59 L.sub.B27 II-1769. L.sub.A60 L.sub.B27 II-1770. L.sub.A61 L.sub.B27 II-1771. L.sub.A62 L.sub.B27 II-1772. L.sub.A63 L.sub.B27 II-1773. L.sub.A64 L.sub.B27 II-1774. L.sub.A65 L.sub.B27 II-1775. L.sub.A66 L.sub.B27 II-1776. L.sub.A67 L.sub.B27 II-1777. L.sub.A68 L.sub.B27 II-1778. L.sub.A69 L.sub.B27 II-1779. L.sub.A1 L.sub.B28 II-1780. L.sub.A2 L.sub.B28 II-1781. L.sub.A3 L.sub.B28 II-1782. L.sub.A4 L.sub.B28 II-1783. L.sub.A5 L.sub.B28 II-1784. L.sub.A6 L.sub.B28 II-1785. L.sub.A7 L.sub.B28 II-1786. L.sub.A8 L.sub.B28 II-1787. L.sub.A9 L.sub.B28 II-1788. L.sub.A10 L.sub.B28 II-1789. L.sub.A11 L.sub.B28 II-1790. L.sub.A12 L.sub.B28 II-1791. L.sub.A13 L.sub.B28 II-1792. L.sub.A14 L.sub.B28 II-1793. L.sub.A15 L.sub.B28 II-1794. L.sub.A16 L.sub.B28 II-1795. L.sub.A17 L.sub.B28 II-1796. L.sub.A18 L.sub.B28 II-1797. L.sub.A19 L.sub.B28 II-1798. L.sub.A20 L.sub.B28 II-1799. L.sub.A21 L.sub.B28 II-1800. L.sub.A22 L.sub.B28 II-1801. L.sub.A23 L.sub.B28 II-1802. L.sub.A24 L.sub.B28 II-1803. L.sub.A25 L.sub.B28 II-1804. L.sub.A26 L.sub.B28 II-1805. L.sub.A27 L.sub.B28 II-1806. L.sub.A28 L.sub.B28 II-1807. L.sub.A29 L.sub.B28 II-1808. L.sub.A30 L.sub.B28 II-1809. L.sub.A31 L.sub.B28 II-1810. L.sub.A32 L.sub.B28 II-1811. L.sub.A33 L.sub.B28 II-1812. L.sub.A34 L.sub.B28 II-1813. L.sub.A35 L.sub.B28 II-1814. L.sub.A36 L.sub.B28 II-1815. L.sub.A37 L.sub.B28 II-1816. L.sub.A38 L.sub.B28 II-1817. L.sub.A39 L.sub.B28 II-1818. L.sub.A40 L.sub.B28 II-1819. L.sub.A41 L.sub.B28 II-1820. L.sub.A42 L.sub.B28 II-1821. L.sub.A43 L.sub.B28 II-1822. L.sub.A44 L.sub.B28 II-1823. L.sub.A45 L.sub.B28 II-1824. L.sub.A46 L.sub.B28 II-1825. L.sub.A47 L.sub.B28 II-1826. L.sub.A48 L.sub.B28 II-1827. L.sub.A49 L.sub.B28 II-1828. L.sub.A50 L.sub.B28 II-1829. L.sub.A51 L.sub.B28 II-1830. L.sub.A52 L.sub.B28 II-1831. L.sub.A53 L.sub.B28 II-1832. L.sub.A54 L.sub.B28 II-1833. L.sub.A55 L.sub.B28 II-1834. L.sub.A56 L.sub.B28 II-1835. L.sub.A57 L.sub.B28 II-1836. L.sub.A58 L.sub.B28 II-1837. L.sub.A59 L.sub.B28 II-1838. L.sub.A60 L.sub.B28 II-1839. L.sub.A61 L.sub.B28 II-1840. L.sub.A62 L.sub.B28 II-1841. L.sub.A63 L.sub.B28 II-1842. L.sub.A64 L.sub.B28 II-1843. L.sub.A65 L.sub.B28 II-1844. L.sub.A66 L.sub.B28 II-1845. L.sub.A67 L.sub.B28 II-1846. L.sub.A68 L.sub.B28 II-1847. L.sub.A69 L.sub.B28,

(35) In one preferred embodiment, the heteroleptic iridium complex is selected from the group of compounds that have one or more deuterated ligands. The group consists of Compound II-11 through Compound II-43, Compound II-64 through Compound II-96, Compound II-130 through Compound II-163, Compound II-197 through Compound II-230, Compound II-263 through Compound II-296, Compound II-330 through Compound II-363, Compound II-397 through Compound II-430, Compound II-464 through Compound II-1031, Compound II-1065 through Compound II-1098, Compound II-1132 through Compound II-1165, Compound II-1199 through Compound II-1232, Compound II-1266 through Compound II-1299, Compound II-1333 through Compound II-1366, Compound II-1400 through Compound II-1846, and Compound II-1847.

(36) In a more preferred embodiment, the heteroleptic iridium complex is selected from the group of compounds having one or more deuterated ligands, wherein the group consisting of Compound II-11, Compound II-12, Compound II-13, Compound II-16, Compound II-17, Compound II-18, Compound II-19, Compound II-27, Compound II-28, Compound II-29, Compound II-30, Compound II-33, Compound II-34, Compound II-35, Compound II-36, Compound II-263, Compound II-264, Compound II-265, Compound II-266, Compound II-269, Compound II-270, Compound II-271, Compound II-272, Compound II-280, Compound II-281, Compound II-282, Compound II-283, Compound II-286, Compound II-287, Compound II-288, Compound II-289, Compound II-529, Compound II-530, Compound II-531, Compound II-534, Compound II-535, Compound II-536, Compound II-537, Compound II-545, Compound II-546, Compound II-547, Compound II-550, Compound II-551, Compound II-552, Compound II-553, Compound II-730, Compound II-731, Compound II-732, Compound II-735, Compound II-736, Compound II-737, Compound II-738, Compound II-746, Compound II-747, Compound II-748, Compound II-751, Compound II-752, Compound II-753, Compound II-754, Compound II-1132, Compound II-1133, Compound II-1134, Compound II-1135, Compound II-1138, Compound II-1139, Compound II-1140, Compound II-1141, Compound II-1149, Compound II-1150, Compound II-1151, Compound II-1152, Compound II-1155, Compound II-1156, Compound II-1157, Compound II-1158, Compound II-1469, Compound II-1470, Compound II-1471, Compound II-1472, Compound II-1475, Compound II-1476, Compound II-1477, Compound II-1478, Compound II-1486, Compound II-1487, Compound II-1488, Compound II-1489, Compound II-1492, Compound II-1493, Compound II-1494, Compound II-1495, Compound II-1538, Compound II-1539, Compound II-1540, Compound II-1541, Compound II-1544, Compound II-1545, Compound II-1546, Compound II-1547, Compound II-1555, Compound II-1556, Compound II-1557, Compound II-1558, Compound II-1561, Compound II-1562, Compound II-1563, Compound II-1564, Compound II-1676, Compound II-1677, Compound II-1678, Compound II-1679, Compound II-1682, Compound II-1683, Compound II-1684, Compound II-1685, Compound II-1693, Compound II-1694, Compound II-1695, Compound II-1696, Compound II-1699, Compound II-1700, Compound II-1701, and Compound II-1702.

(37) In one aspect, a formulation comprising the compound of the present invention is disclosed. The forumlation comprises a heteroleptic iridium complex having the formula IrL.sub.A(L.sub.B).sub.2, wherein L.sub.A is selected from the group consisting of ligands L.sub.A1 through L.sub.A69, L.sub.B is selected from the group consisting of ligands L.sub.B1 through L.sub.B28, and the heteroleptic iridium complex is selected from the group consisting of Compound II-1 through Compound II-1847 as defined herein.

(38) In one aspect, a first device is provided. The first device comprises a first organic light emitting device, and contains an anode, a cathode, and an organic layer, disposed between the anode and the cathode. The organic layer comprises a heteroleptic iridium complex having the formula IrL.sub.A(L.sub.B).sub.2, wherein L.sub.A is selected from the group consisting of the ligands L.sub.A1 through L.sub.A69 defined herein, L.sub.B is selected from the group consisting of the ligands L.sub.B1 through L.sub.B28, and the heteroleptic iridium complex is selected from the group consisting of Compound II-1 through Compound II-1846, and Compound II-1847 as defined herein.

(39) In one preferred embodiment, the heteroleptic iridium complex in the organic layer of the first device is selected from a group of compounds having one or more deuterated ligands. Such group consists of Compound II-11 through Compound II-43, Compound II-64 through Compound II-96, Compound II-130 through Compound II-163, Compound II-197 through Compound II-230, Compound II-263 through Compound II-296, Compound II-330 through Compound II-363, Compound II-397 through Compound II-430, Compound II-464 through Compound II-1031, Compound II-1065 through Compound II-1098, Compound II-1132 through Compound II-1165, Compound II-1199 through Compound II-1232, Compound II-1266 through Compound II-1299, Compound II-1333 through Compound II-1366, Compound II-1400 through Compound II-1846, and Compound II-1847, as defined herein.

(40) In one embodiment, the organic layer is an emissive layer and the compound is an emissive dopant. In another embodiment, the organic layer is an emissive layer and the compound is a non-emissive dopant.

(41) In another embodiment, the organic layer further comprises a host. In one embodiment, the host comprises a triphenylene containing benzo-fused thiophene or benzo-fused furan, wherein any substituent in the host is an unfused substituent independently selected from the group consisting of C.sub.nH.sub.2n+1, OC.sub.nH.sub.2n−1, OAr.sub.1, N(C.sub.nH.sub.2n+1).sub.2, N(Ar.sub.1)(Ar.sub.2), CH═CH—C.sub.nH.sub.2n+1, C≡CHC.sub.nH.sub.2n+1, Ar.sub.1, Ar.sub.1—Ar.sub.2, C.sub.nH.sub.2n−Ar.sub.1, or no substitution. Ar.sub.1 and Ar.sub.2 are independently selected from the group consisting of benzene, biphenyl, naphthalene, triphenylene, carbazole, and heteroaromatic analogs thereof, and n is from 1 to 10. In one embodiment, the host has the formula:

(42) ##STR00045##

(43) In one embodiment, the host is a metal complex. Any of the metal complexes described herein are suitable hosts.

(44) OLEDs that incorporate compounds of Formula I have broad yellow emission profiles, as well as high quantum efficiencies and long commercial lifetimes. A device capable of broad yellow emission is particularly desirable in white illumination sources.

(45) The quality of white illumination sources can be fully described by a simple set of parameters. The color of the light source is given by its CIE chromaticity coordinates x and y (1931 2-degree standard observer CIE chromaticity). The CIE coordinates are typically represented on a two dimensional plot. Monochromatic colors fall on the perimeter of the horseshoe shaped curve starting with blue in the lower left, running through the colors of the spectrum in a clockwise direction to red in the lower right. The CIE coordinates of a light source of given energy and spectral shape will fall within the area of the curve. Summing light at all wavelengths uniformly gives the white or neutral point, found at the center of the diagram (CIE x,y-coordinates, 0.33, 0.33). Mixing light from two or more sources gives light whose color is represented by the intensity weighted average of the CIE coordinates of the independent sources.

(46) Thus, mixing light from two or more sources can be used to generate white light.

(47) When considering the use of these white light sources for illumination, the CIE color rendering index (CRI) may be considered in addition to the CIE coordinates of the source. The CRI gives an indication of how well the light source will render colors of objects it illuminates. A perfect match of a given source to the standard illuminant gives a CRI of 100. Though a CRI value of at least 70 may be acceptable for certain applications, a preferred white light source may have a CRI of about 80 or higher.

(48) The compounds of Formula I have yellow emission profiles with significant red and green components. The addition of a blue emitter, i.e. an emitter with a peak wavelength of between 400 to 500 nanometers, together with appropriate filters on OLEDs incorporating the compound of Formula I allows for the reproduction of the RGB spectrum. In some embodiments, OLEDs that incorporate compounds of Formula I are used for color displays (or lighting applications) using only two types of emissive compounds: a yellow emitter of Formula I and a blue emitter. A color display using only two emissive compounds: a broad yellow emitter of Formula I and a blue emitter, may employ a color filter to selectively pass the red, green, and blue color components of a display. The red and green components can both come from a broad yellow emitter of Formula I.

(49) In one embodiment, the first device is a consumer product. In another embodiment, the first device is an organic light-emitting device. In another aspect, the first device comprises a lighting panel.

(50) In one embodiment, the first device further comprises a second emissive dopant having a peak wavelength of between 400 to 500 nanometers. In one embodiment, the second emissive dopant is a fluorescent emitter. In another embodiment, the second emissive dopant is a phosphorescent emitter.

(51) In one embodiment, the first device further comprises a first organic light-emitting device comprising a compound of Formula I and a second light emitting device separate from the first organic light-emitting device comprising an emissive dopant having a peak wavelength of between 400 to 500 nanometers. The first and second light-emitting devices can be placed in any suitable spatial arrangement, depending on the needs of the desired display or lighting application.

(52) In another embodiment, the first device comprises an organic-light emitting device having a first emissive layer comprising a compound of Formula I and a second emissive layer comprising an emissive dopant having a peak wavelength of between 400 to 500 nanometers. The first emissive layer and the second emissive layer may have one or more other layers in between them.

Device Examples

(53) All device examples were fabricated by high vacuum (<10.sup.−7 Torr) thermal evaporation (VTE). The anode electrode is 800 Å of indium tin oxide (ITO). The cathode consisted of 10 Å of LiF followed by 1000 Å of Al. All devices were encapsulated with a glass lid sealed with an epoxy resin in a nitrogen glove box (<1 ppm of H.sub.2O and O.sub.2) immediately after fabrication, and a moisture getter was incorporated inside the package.

(54) The organic stack of the device examples consisted of sequentially, from the ITO surface, 100 Å of Compound A as the hole injection layer (HIL), 300 Å of 4,4′-bis[N-(1-naphthyl)-N-phenylamino]biphenyl(alpha-NPD) as the hole transporting layer (HTL), 300 Å of 7-15 wt % of a compound of Formula I doped in with Compound H (as host) as the emissive layer (EML), 50 Å or 100 Å of Compound H as blocking layer (BL), 450 Å or 500 of Å Alq (tris-8-hydroxyquinoline aluminum) as the electron transport layer (ETL). The comparative example used 8 weight percent of Compound X in the EML. The device results and data are summarized in Table 1 and Table 2 from those devices. As used herein, NPD, Alq, Compound A, Compound H, and Compound X have the following structures:

(55) ##STR00046##

(56) TABLE-US-00003 TABLE 2 VTE Phosphorescent OLEDs Example HIL HTL EML (300 Å, doping %) BL ETL Comparative Compound A NPD 300 Å Compound Compound X Compound H Alq 450 Å Example 1 100 Å H  8% 50 Å Example 1 Compound A NPD 300 Å Compound Compound 3 Compound H Alq 450 Å 100 Å H 12% 50 Å Example 2 Compound A NPD 300 Å Compound Compound 4 Compound H Alq 450 Å 100 Å H 12% 50 Å Example 3 Compound A NPD 300 Å Compound Compound 5 Compound H Alq 450 Å 100 Å H 10% 50 Å Example 4 Compound A NPD 300 Å Compound Compound 6 Compound H Alq 450 Å 100 Å H  7% 50 Å Example 5 Compound A NPD 300 Å Compound Compound 7 Compound H Alq 500 Å 100 Å H 10% 50 Å Example 6 Compound A NPD 300 Å Compound Compound 8 Compound H Alq 450 Å 100 Å H  7% 50 Å

(57) TABLE-US-00004 TABLE 3 VTE Device Data FWHM Voltage LE EQE PE LT80% Example x y λ.sub.max (nm) (V) (Cd/A) (%) (lm/W) (h) Comparative 0435 0550 556 84 59 583 173 313 510 Example 1 Example 1 0458 0532 562 82 50 668 205 422 900 Example 2 0460 0530 562 82 51 616 190 382 1250 Example 3 0428 0556 552 84 56 772 226 430 630 Example 4 0461 0528 566 86 62 615 193 310 540 Example 5 0485 0508 570 84 50 646 212 404 4300 Example 6 0462 0528 564 82 57 524 162 289 830

(58) The device data show that compounds of Formula I are effective yellow emitters with broad line shape (desirable for use in white light devices), with high efficiency and commercially useful lifetimes. Devices made with compounds of Formula I (Examples 1-6) generally show higher luminous efficiencies (LE), external quantum efficiencies (EQE) and power efficiencies (PE) than the Comparative Example. Without being bound by theory, it is believed that the alkyl substitutions reduce the aggregation of the dopant in the device, change the charge transport properties, and lead to higher efficiencies versus the Comparative Example, which lacks alkyl groups. Additionally, Compounds 3-5, Compound 7, and Compound 8 all show lower turn-on voltages in the device than Comparative Compound X. Finally, the compounds of Formula I in Examples 1-6 show longer device lifetimes than the Comparative Example. For example, Compound 4 and Compound 7 had device lifetimes about 2.5 and 8 fold higher, respectively, than Comparative Compound X.

(59) Combination with other Materials

(60) The materials described herein as useful for a particular layer in an organic light emitting device may be used in combination with a wide variety of other materials present in the device. For example, emissive dopants disclosed herein may be used in conjunction with a wide variety of hosts, transport layers, blocking layers, injection layers, electrodes and other layers that may be present. The materials described or referred to below are non-limiting examples of materials that may be useful in combination with the compounds disclosed herein, and one of skill in the art can readily consult the literature to identify other materials that may be useful in combination.

(61) HIL/HTL:

(62) A hole injecting/transporting material to be used in the present invention is not particularly limited, and any compound may be used as long as the compound is typically used as a hole injecting/transporting material. Examples of the material include, but not limit to: a phthalocyanine or porphryin derivative; an aromatic amine derivative; an indolocarbazole derivative; a polymer containing fluorohydrocarbon; a polymer with conductivity dopants; a conducting polymer, such as PEDOT/PSS; a self-assembly monomer derived from compounds such as phosphonic acid and sliane derivatives; a metal oxide derivative, such as MoO.sub.x; a p-type semiconducting organic compound, such as 1,4,5,8,9,12-Hexaazatriphenylenehexacarbonitrile; a metal complex, and a cross-linkable compounds.

(63) Examples of aromatic amine derivatives used in HIL or HTL include, but not limit to the following general structures:

(64) ##STR00047##

(65) Each of Ar.sup.1 to Ar.sup.9 is selected from the group consisting aromatic hydrocarbon cyclic compounds such as benzene, biphenyl, triphenyl, triphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, azulene; group consisting aromatic heterocyclic compounds such as dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine, thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine; and group consisting 2 to 10 cyclic structural units which are groups of the same type or different types selected from the aromatic hydrocarbon cyclic group and the aromatic heterocyclic group and are bonded to each other directly or via at least one of oxygen atom, nitrogen atom, sulfur atom, silicon atom, phosphorus atom, boron atom, chain structural unit and the aliphatic cyclic group. Wherein each Ar is further substituted by a substituent selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.

(66) In one aspect, Ar.sup.1 to Ar.sup.9 is independently selected from the group consisting of:

(67) ##STR00048##

(68) k is an integer from 1 to 20; X.sup.1 to X.sup.8 is C (including CH) or N; Ar.sup.1 has the same group defined above.

(69) Examples of metal complexes used in HIL or HTL include, but not limit to the following general formula:

(70) ##STR00049##

(71) M is a metal, having an atomic weight greater than 40; (Y.sup.1—Y.sup.2) is a bidentate ligand, Y.sup.1 and Y.sup.2 are independently selected from C, N, O, P, and S; L is an ancillary ligand; m is an integer value from 1 to the maximum number of ligands that may be attached to the metal; and m+n is the maximum number of ligands that may be attached to the metal.

(72) In one aspect, (Y.sup.1—Y.sup.2) is a 2-phenylpyridine derivative.

(73) In another aspect, (Y.sup.1—Y.sup.2) is a carbene ligand.

(74) In another aspect, M is selected from Ir, Pt, Os, and Zn.

(75) In a further aspect, the metal complex has a smallest oxidation potential in solution vs. Fc.sup.+/Fc couple less than about 0.6 V.

(76) Host:

(77) The light emitting layer of the organic EL device of the present invention preferably contains at least a metal complex as light emitting material, and may contain a host material using the metal complex as a dopant material. Examples of the host material are not particularly limited, and any metal complexes or organic compounds may be used as long as the triplet energy of the host is larger than that of the dopant.

(78) Examples of metal complexes used as host are preferred to have the following general formula:

(79) ##STR00050##

(80) M is a metal; (Y.sup.3—Y.sup.4) is a bidentate ligand, Y.sup.3 and Y.sup.4 are independently selected from C, N, O, P, and S; L is an ancillary ligand; m is an integer value from 1 to the maximum number of ligands that may be attached to the metal; and m+n is the maximum number of ligands that may be attached to the metal.

(81) In one aspect, the metal complexes are:

(82) ##STR00051##

(83) (O—N) is a bidentate ligand, having metal coordinated to atoms O and N.

(84) In another aspect, M is selected from Ir and Pt.

(85) In a further aspect, (Y.sup.3—Y.sup.4) is a carbene ligand.

(86) Examples of organic compounds used as host are selected from the group consisting aromatic hydrocarbon cyclic compounds such as benzene, biphenyl, triphenyl, triphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, azulene; group consisting aromatic heterocyclic compounds such as dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine, thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine; and group consisting 2 to 10 cyclic structural units which are groups of the same type or different types selected from the aromatic hydrocarbon cyclic group and the aromatic heterocyclic group and are bonded to each other directly or via at least one of oxygen atom, nitrogen atome, sulfur atom, silicon atom, phosphorus atom, boron atom, chain structural unit and the aliphatic cyclic group. Wherein each group is further substituted by a substituent selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.

(87) In one aspect, host compound contains at least one of the following groups in the molecule:

(88) ##STR00052## ##STR00053##

(89) R.sup.1 to R.sup.7 is independently selected from the group consisting of hydrogen, alkyl, alkoxy, amino, alkenyl, alkynyl, arylalkyl, heteroalkyl, aryl and heteroaryl, when it is aryl or heteroaryl, it has the similar definition as Ar's mentioned above.

(90) k is an integer from 0 to 20.

(91) X.sup.1 to X.sup.8 is selected from C (including CH) or N.

(92) HBL:

(93) A hole blocking layer (HBL) may be used to reduce the number of holes and/or excitons that leave the emissive layer. The presence of such a blocking layer in a device may result in substantially higher efficiencies as compared to a similar device lacking a blocking layer. Also, a blocking layer may be used to confine emission to a desired region of an OLED.

(94) In one aspect, compound used in HBL contains the same molecule used as host described above.

(95) In another aspect, compound used in HBL contains at least one of the following groups in the molecule:

(96) ##STR00054##

(97) k is an integer from 0 to 20; L is an ancillary ligand, m is an integer from 1 to 3.

(98) ETL:

(99) Electron transport layer (ETL) may include a material capable of transporting electrons. Electron transport layer may be intrinsic (undoped), or doped. Doping may be used to enhance conductivity. Examples of the ETL material are not particularly limited, and any metal complexes or organic compounds may be used as long as they are typically used to transport electrons.

(100) In one aspect, compound used in ETL contains at least one of the following groups in the molecule:

(101) ##STR00055##

(102) R.sup.1 is selected from the group consisting of hydrogen, alkyl, alkoxy, amino, alkenyl, alkynyl, arylalkyl, heteroalkyl, aryl and heteroaryl, when it is aryl or heteroaryl, it has the similar definition as Ar's mentioned above.

(103) Ar.sup.1 to Ar.sup.3 has the similar definition as Ar's mentioned above.

(104) k is an integer from 0 to 20.

(105) X.sup.1 to X.sup.8 is selected from C (including CH) or N.

(106) In another aspect, the metal complexes used in ETL contains, but not limit to the following general formula:

(107) ##STR00056##

(108) (O—N) or (N—N) is a bidentate ligand, having metal coordinated to atoms O, N or N, N; L is an ancillary ligand; m is an integer value from 1 to the maximum number of ligands that may be attached to the metal.

(109) In any above-mentioned compounds used in each layer of the OLED device, the hydrogen atoms can be partially or fully deuterated.

(110) In addition to and/or in combination with the materials disclosed herein, many hole injection materials, hole transporting materials, host materials, dopant materials, exiton/hole blocking layer materials, electron transporting and electron injecting materials may be used in an OLED. Non-limiting examples of the materials that may be used in an OLED in combination with materials disclosed herein are listed in Table 3 below. Table 3 lists non-limiting classes of materials, non-limiting examples of compounds for each class, and references that disclose the materials.

(111) TABLE-US-00005 TABLE 3 MATERIAL EXAMPLES OF MATERIAL PUBLICATIONS Hole injection materials Phthalocyanine and porphryin compounds embedded image Appl. Phys. Lett. 69, 2160 (1996) Starburst triarylamines embedded image J. Lumin. 72-74, 985 (1997) CF.sub.x embedded image Appl. Phys. Lett. Fluorohydrocarbon 78, 673 (2001) polymer Conducting polymers (e.g., PEDOT:PSS, polyaniline, polypthiophene) 0embedded image Synth. Met. 87, 171 (1997) WO2007002683 Phosphonic acid and sliane SAMs embedded image US20030162053 Triarylamine or polythiophene polymers with conductivity dopants embedded image EP1725079A1 embedded image embedded image Arylamines complexed with metal oxides such as molybdenum and tungsten oxides embedded image SID Symposium Digest, 37, 923 (2006) WO2009018009 p-type semiconducting organic complexes embedded image US20020158242 Metal organometallic complexes embedded image US20060240279 Cross-linkable compounds embedded image US20080220265 Hole transporting materials Triarylamines (e.g., TPD, α-NPD) embedded image Appl. Phys. Lett. 51, 913 (1987) 0embedded image U.S. Pat. No. 5,061,569 embedded image EP650955 embedded image J. Mater. Chem. 3, 319 (1993) embedded image Appl. Phys. Lett. 90, 183503 (2007) embedded image Appl. Phys. Lett. 90, 183503 (2007) Triaylamine on spirofluorene core embedded image Synth. Met. 91, 209 (1997) Arylamine carbazole compounds embedded image Adv. Mater. 6, 677 (1994), US20080124572 Triarylamine with (di)benzothiophene/ (di)benzofuran embedded image US20070278938, US20080106190 Indolocarbazoles embedded image Synth. Met. 111, 421 (2000) Isoindole compounds embedded image Chem. Mater. 15, 3148 (2003) Metal carbene complexes 0embedded image US20080018221 Phosphorescent OLED hosts materials Red hosts Arylcarbazoles embedded image Appl. Phys. Lett. 78, 1622 (2001) Metal 8- hydroxyquinolates (e.g., Alq.sub.3, BAlq) embedded image Nature 395, 151 (1998) embedded image US20060202194 embedded image WO2005014551 embedded image WO2006072002 Metal phenoxy- benzothiazole compounds embedded image Appl. Phys. Lett. 90, 123509 (2007) Conjugated oligomers and polymers (e.g., polyfluorene) embedded image Org. Electron. 1, 15 (2000) Aromatic fused rings embedded image WO2009066779, WO2009066778. WO2009063833, US20090045731, US20090045730. WO2009008311, US20090008605, US20090009065 Zinc complexes embedded image WO2009062578 Green hosts Arylcarbazoles 0embedded image Appl. Phys. Lett. 78, 1622 (2001) embedded image US20030175553 embedded image WO2001039234 Aryltriphenylene compounds embedded image US20060280965 embedded image US20060280965 embedded image WO2009021126 Donor acceptor type molecules embedded image WO2008056746 Aza-carbazole/ DBT/DBF embedded image JP2008074939 Polymers (e.g., PVK) embedded image Appl. Phys. Lett. 77, 2280 (2000) Spirofluorene compounds embedded image WO2004093207 Metal phenoxy- benzooxazole compounds 00embedded image WO2005089025 01embedded image WO2006132173 02embedded image JP200511610 Spirofluorene- carbazole compounds 03embedded image JP2007254297 04embedded image JP2007254297 Indolocarbazoles 05embedded image WO2007063796 06embedded image WO2007063754 5-member ring electron deficient heterocycles (e.g., triazole, oxadiazole) 07embedded image J. Appl. Phys. 90, 5048 (2001) 08embedded image WO2004107822 Tetraphenylene complexes 09embedded image US20050112407 Metal phenoxypyridine compounds 0embedded image WO2005030900 Metal coordination complexes (e.g., Zn, Al with N{circumflex over ( )}N ligands) embedded image US20040137268, US20040137267 Blue hosts Arylcarbazoles embedded image Appl. Phys. Lett, 82, 2422 (2003) embedded image US20070190359 Dibenzothiophene/ Dibenzofuran- carbazole compounds embedded image WO2006114966, US20090167162 embedded image US20090167162 embedded image WO2009086028 embedded image US20090030202, US20090017330 Silicon aryl compounds embedded image US20050238919 embedded image WO2009003898 Silicon/Germanium aryl compounds 0embedded image EP2034538A Aryl benzoyl ester embedded image WO2006100298 High triplet metal organometallic complex embedded image U.S. Pat. No. 7,154,114 Phosphorescent dopants Red dopants Heavy metal porphyrins (e.g., PtOEP) embedded image Nature 395, 151 (1998) Iridium(III) organometallic complexes embedded image Appl. Phys. Lett. 78, 1622 (2001) embedded image US2006835469 embedded image US2006835469 embedded image US20060202194 embedded image US20060202194 embedded image US20070087321 0embedded image US20070087321 embedded image Adv. Mater. 19, 739 (2007) embedded image WO2009100991 embedded image WO2008101842 Platinum(II) organometallic complexes embedded image WO2003040257 Osmium(III) complexes embedded image Chem. Mater. 17, 3532 (2005) Ruthenium(II) complexes embedded image Adv. Mater. 17, 1059 (2005) Rhenium (I), (II), and (III) complexes embedded image US20050244673 Green dopants Iridium(III) organometallic complexes embedded image Inorg. Chem. 40, 1704 (2001) and its derivatives embedded image US20020034656 0embedded image U.S. Pat. No. 7,332,232 embedded image US20090108737 embedded image US20090039776 embedded image U.S. Pat. No. 6,921,915 embedded image U.S. Pat. No. 6,687,266 embedded image Chem. Mater. 16, 2480 (2004) embedded image US20076190359 embedded image US 20060008670 JP2007123392 embedded image Adv. Mater. 16, 2003 (2004) embedded image Angew. Chem. Int. Ed. 2006, 45, 7800 0embedded image WO2009050290 embedded image US20090165846 embedded image US20080015355 Monomer for polymeric metal organometallic compounds embedded image U.S. Pat. No. 7,250,226, U.S. Pat. No. 7,396,598 Pt(II) organometallic complexes, including polydentated ligands embedded image Appl. Phys. Lett. 86, 153505 (2005) embedded image Appl. Phys. Lett. 86, 153505 (2005) embedded image Chem. Lett. 34, 592 (2005) embedded image WO2002015645 embedded image US20060263635 Cu complexes embedded image WO2009000673 Gold complexes 0embedded image Chem. Commun. 2906 (2005) Rhenium(III) complexes embedded image Inorg. Chem. 42, 1248 (2003) Deuterated organometallic complexes embedded image US20030138657 Organometallic complexes with two or more metal centers embedded image US20030152802 embedded image U.S. Pat. No. 7,090,928 Blue dopants Iridium(III) organometallic complexes embedded image WO2002002714 embedded image WO2006009024 embedded image US20060251923 embedded image U.S. Pat. No. 7,393,599, WO2006056418, US20050260441, WO2005019373 embedded image U.S. Pat. No. 7,534,505 0embedded image U.S. Pat. No. 7,445,855 embedded image US20070190359, US20080297033 embedded image U.S. Pat. No. 7,338,722 embedded image US20020134984 embedded image Angew. Chem. Int. Ed. 47, 1 (2008) embedded image Chem. Mater. 18, 5119 (2006) embedded image Inorg. Chem. 46, 4308 (2007) embedded image WO2005123873 embedded image WO2005123873 embedded image WO2007004380 0embedded image WO2006082742 Osmium(II) complexes embedded image U.S. Pat. No. 7,279,704 embedded image Organometallics 23, 3745 (2004) Gold complexes embedded image Appl. Phys. Lett. 74, 1361 (1999) Platinum(II) complexes embedded image WO2006098120, WO2006103874 Exciton/hole blocking layer materials Bathocuprine compounds (e.g., BCP, BPhen) embedded image Appl. Phys. Lett. 75, 4 (1999) embedded image Appl. Phys. Lett. 79, 449 (2001) Metal 8- hydroxyquinolates (e.g., BAlq) embedded image Appl. Phys. Lett. 81, 162 (2002) 5-member ring electron deficient heterocycles such as triazole, oxadiazole, imidazole, benzoimidazole embedded image Appl. Phys. Lett. 81, 162 (2002) Triphenylene compounds embedded image US20050025993 Fluorinated aromatic compounds 0embedded image Appl. Phys. Lett. 79, 156 (2001) Phenothiazine- S-oxide embedded image WO2008132085 Electron transporting materials Anthracene- benzoimidazole compounds embedded image WO2003060956 embedded image US20090179554 Aza triphenylene derivatives embedded image US20090115316 Anthracene- benzothiazole compounds embedded image Appl. Phys. Lett. 89, 063504 (2006) Metal 8- hydroxyquinolates (e.g., Alq.sub.3, Zrq.sub.4) embedded image Appl. Phys. Lett. 51, 913 (1987) U.S. Pat. No. 7,230,107 Metal hydroxy- benoquinolates embedded image Chem. Lett. 5, 905 (1993) Bathocuprine compounds such as BCP, BPhen, etc embedded image Appl. Phys. Lett. 91, 263503 (2007) embedded image Appl. Phys. Lett. 79, 449 (2001) 5-member ring electron deficient heterocycles (e.g., triazole, oxadiazole, imidazole, benzoimidazole) 00embedded image Appl. Phys. Lett. 74, 865 (1999) 01embedded image Appl. Phys. Lett. 55, 1489 (1989) 02embedded image Jpn. J. Apply. Phys. 32, L917 (1993) Silole compounds 03embedded image Org. Electron. 4, 113 (2003) Arylborane compounds 04embedded image J. Am. Chem. Soc. 120, 9714 (1998) Fluorinated aromatic compounds 05embedded image J. Am. Chem. Soc. 122, 1832 (2000) Fullerene (e.g. C60) 06embedded image US20090101870 Triazine complexes 07embedded image US20040036077 Zn (N{circumflex over ( )}N) complexes 08embedded image U.S. Pat. No. 6,528,187

EXPERIMENTAL

(112) Chemical abbreviations used throughout this document are as follows: Cy is cyclohexyl, dba is dibenzylideneacetone, EtOAc is ethyl acetate, S-Phos is dicyclohexyl(2′,6′-dimethoxy-[1,1′-biphenyl]-3-yl)phosphine, THF is tetrahydrofuran, DCM is dichloromethane, PPh.sub.3 is triphenylphosphine.

(113) Synthesis of Compound 3

(114) Step 1

(115) Synthesis of 5-Methyl-2-phenylpyridine

(116) ##STR00209##
In a 1 L round bottom flask was added 2-bromo-5-methylpyridine (30 g, 174 mmol), phenylboronic acid (25.5 g, 209 mmol), dicyclohexyl(2′,6′-dimethoxy-[1,1′-biphenyl]-2-yl)phosphine (2.86 g, 6.98 mmol) and potassium phosphate tribasic monohydrate (120 g, 523 mmol) with toluene (600 mL) and water (60 mL). The reaction mixture was degassed with N.sub.2 for 20 min. Pd.sub.2(dba).sub.3 (3.19 g, 3.49 mmol) was added and the reaction mixture was refluxed for 18 h. The reaction mixture was cooled, the aqueous layer was removed and the organic layer was concentrated to dryness to leave a residue. The residue was dissolved in EtOAc:hexane (1:3) and passed through a small silica gel plug and eluted with EtOAc:hexane (1:3). The solvent was removed and the crude product was purified by Kugelrohr at 150° C. to yield 26 g of 5-methyl-2-phenylpyridine, which was obtained as a white solid (HPLC purity: 99.2%).
Step 2

(117) Synthesis of Iridium Chloro-Bridged Dimer:

(118) ##STR00210##
In a 500 mL round bottom flask was added 5-methyl-2-phenylpyridine (12 g, 70.9 mmol) and iridium(III) chloride hydrate (7.14 g, 20.2 mmol) with 2-ethoxyethanol (100 mL) and water (33.3 mL) under a nitrogen atmosphere. The resulting reaction mixture was refluxed at 130° C. for 18 h. The resulting precipitate was filtered and washed with methanol (3-4 times) and hexane (3-4 times). The product obtained was dried to give 11.0 g (96% yield) of the desired product.

(119) Synthesis of Iridium Trifluoromethanesulfonate Salt:

(120) ##STR00211##
The iridium dimer (11 g, 9.75 mmol), as obtained in Step 2 above, was suspended in 600 mL of dichloromethane. In a separate flask, silver(I) trifluoromethanesulfonate (5.26 g, 20.48 mmol) was dissolved in MeOH (300 mL) and added slowly to the dichloromethane suspension with continuous stirring at room temperature. The reaction mixture was stirred overnight in the dark. The reaction mixture was filtered through a tightly packed Celite® bed and the solvent was removed under vacuum to give 15 g (100% yield) of product as a brownish green solid. The product was used without further purification.
Step 3

(121) Synthesis of Compound 3:

(122) ##STR00212##

(123) A mixture of iridium trifluormethanesulfonate complex (3.0 g, 4.04 mmol), as obtained from Step 2 above, and 2,4-diphenylpyridine (3.11 g, 13.45 mmol) in EtOH (30 mL) and MeOH (30 mL) was refluxed for 20 h under inert atmosphere. The reaction mixture was cooled to room temperature, diluted with ethanol, Celite® was added and the mixture stirred for 10 min. The mixture was filtered on a small silica gel plug on a frit and washed with ethanol (3-4 times) and hexane (3-4 times). The filtrate was discarded. The Celite®/silica plug was then washed with dichloromethane to elute the crude product. The crude product was chromatographed on silica gel with 1/1 (v/v) dichloromethane/hexane and later 4/1 (v/v) dichloromethane/hexane to yield 0.9 g of Compound 3 (28% yield), which was confirmed by HPLC (99.9% pure) and LC/MS.

(124) Synthesis of Compound 4

(125) Step 1

(126) Synthesis of 4-chloro-2-phenylpyridine:

(127) ##STR00213##

(128) A 1 L round bottom flask was charged with 2,4-dichloropyridine (30 g, 203 mmol), phenylboronic acid (24.7 g, 203 mmol), potassium carbonate (84 g, 608 mmol), Pd(PPh.sub.3).sub.4 (2.3 g, 2.0 mmol), dimethoxyethane (500 mL) and water (150 mL). The reaction mixture was degassed and heated to reflux for 20 h. After cooling and separation of the layers, the aqueous layer was extracted with EtOAc (2×100 mL). After removal of the solvent, the crude product was subjected to column chromatography (SiO.sub.2, 5% EtOAc in hexane to 10% EtOAc in hexane) to get 34 g (88% yield) of pure product.

(129) Step 2

(130) Synthesis of 2-phenyl-4-(prop-1-en-2yl)pyridine:

(131) ##STR00214##
4-Chloro-2-phenylpyridine (14.0 g, 73.8 mmol) and potassium phosphate (51.0 g, 221 mmol) were dissolved in 300 mL of toluene and 30 mL of water. The reaction was purged with nitrogen for 20 minutes and then 4,4,5,5-tetramethyl-2-(prop-1-en-2-yl)-1,3,2-dioxaborolane (16.65 mL, 89 mmol), Pd.sub.2(dba).sub.3 (1.35 g, 1.48 mmol) and S-Phos (2.42 g, 5.91 mmol) were added. The reaction was refluxed for 18 h. After cooling, 100 mL of water was added, the layers were separated, and the aqueous layer extracted twice with 100 mL of ethyl acetate. The organic layers were passed through a plug of silica gel, eluting with DCM. After evaporation of the solvent, the crude product was subjected to column chromatography (SiO.sub.2, 5% EtOAc in hexane to 10% EtOAc in hexane) to get 13.5 g of pure product (90% yield).
Step 3

(132) Synthesis of 2-phenyl-4-propylpyridine:

(133) ##STR00215##
2-Phenyl-4-(prop-1-en-2-yl) pyridine (13.5 g, 69.1 mmol) was added to a hydrogenator bottle with EtOH (150 mL). The reaction mixture was degassed by bubbling N.sub.2 for 10 min. Pd/C (0.736 g, 6.91 mmol) and Pt/C (0.674 g, 3.46 mmol) were added. The reaction mixture was placed on a Parr hydrogenator for 2 h (H.sub.2˜84 psi, according to theoretical calculations). The reaction mixture was filtered on a tightly packed Celite® bed and washed with dichloromethane. The solvent was evaporated and GC/MS confirmed complete hydrogenation. The crude product was adsorbed on Celite® for column chromatography. The crude product was chromatographed on silica gel with 10% EtOAc in hexane to yield 10 g (75% yield) of the desired product (HPLC purity: 99.8%). The product was confirmed by GC/MS.
Step 4

(134) Synthesis of Iridium Chloro-Bridged Dimer:

(135) ##STR00216##
To a 500 mL round-bottom flask was added 4-isopropyl-2-phenylpyridine (8.0 g, 40.6 mmol) and iridium(III) chloride hydrate (7.4 g, 20.28 mmol) with 2-ethoxyethanol (90 mL) and water (30 mL) under a nitrogen atmosphere. The resulting reaction mixture was refluxed at 130° C. for 18 h. The resulting precipitate was filtered and washed with methanol (3-4 times) and hexane (3-4 times). The product obtained was dried to give 6.1 g (95% yield) of the desired product.
Step 5

(136) Synthesis of Iridium Trifluoromethanesulfonate Salt:

(137) ##STR00217##
The iridium dimer (6.2 g, 4.94 mmol), obtained as in Step 4 above, was dissolved in 500 mL of dichloromethane. In a separate flask, silver(I) trifluoromethanesulfonate (2.66 g, 10.37 mmol) was dissolved in MeOH (250 mL) and added slowly to the dichloromethane solution with continuous stirring at room temperature. The reaction mixture was stirred overnight in the dark. The reaction mixture was filtered through a tightly packed Celite® bed and the solvent was removed under vacuum to give 7.8 g (100% yield) of product as a brownish green solid. The product was used without further purification.
Step 6

(138) Synthesis of Compound 4:

(139) ##STR00218##
A mixture of iridium trifluormethanesulfonate complex (2.4 g, 3.01 mmol), obtained as in Step 5 above, and 2,4-diphenylpyridine(2.4 g, 10.38 mmol) in EtOH (30 mL) and MeOH (30 mL) was refluxed for 20 h under N.sub.2 atmosphere. The reaction mixture was cooled to room temperature, diluted with ethanol, Celite® was added, and the mixture was stirred for 10 min. The mixture was filtered on a small silica gel plug and washed with ethanol (3-4 times) and with hexane (3-4 times). The filtrate was discarded. The Celite®/silica plug was then washed with dichloromethane to elute the product. The crude product was chromatographed on silica gel with 30% THF in hexanes to yield 1.24 g (51% yield) of Compound 4 as a yellow solid. The product was confirmed by HPLC (99.9% pure) and LC/MS.

(140) Synthesis of Compound 5

(141) Step 1

(142) Synthesis of 4-(4-isobutylphenyl)-2-phenylpyridine:

(143) ##STR00219##
A 250 mL round-bottomed flask was charged with 4-chloro-2-phenylpyridine (5 g, 26.4 mmol), (4-isobutylphenyl)boronic acid (7.04 g, 39.5 mmol), Pd.sub.2(dba).sub.3(0.483 g, 0.527 mmol), dicyclohexyl(2′,6′-dimethoxy-[1,1′-biphenyl]-3-yl)phosphine (S-Phos) (0.866 g, 2.109 mmol), K.sub.3PO.sub.4(16.79 g, 79 mmol), toluene (100 mL) and water (10 mL) to give a yellow suspension. The suspension was heated to reflux for 21 hrs. The reaction mixture was poured into water and extracted with EtOAc. The organic layers were combined and subjected to column chromatography (SiO.sub.2, 10% EtOAc in hexane) to yield 4-(4-isobutylphenyl)-2-phenylpyridine (6 g, 20.9 mmol, 79% yield).
Step 2

(144) Synthesis of Compound 5:

(145) ##STR00220##
A mixture of iridium trifluormethanesulfonate complex (3.0 g, 3.76 mmol) and 4-(4-isobutylphenyl)-2-phenylpyridine (3.0 g, 10.44 mmol) in EtOH (30 mL) and MeOH (30 mL) was refluxed for 20 h under inert atmosphere. The reaction mixture was cooled to room temperature, diluted with ethanol, Celite® was added and the mixture stirred for 10 min. The mixture was filtered on a small silica gel plug on a frit and washed with ethanol (3-4 times) and with hexane (3-4 times). The filtrate was discarded. Celite®/silica plug was then washed with dichloromethane to elute the product. The crude product was chromatographed on silica gel with 1/1 dichloromethane/hexane to yield 2.0 g (65% yield) of Compound 5 as a yellow solid. Compound 5 was confirmed by HPLC (99.8% pure) and LC/MS.

(146) Synthesis of Compound 6

(147) Step 1

(148) Synthesis of Iridium Chloro-Bridged Dimer:

(149) ##STR00221##
To a 500 mL round-bottom flask was added 3-methyl-2-phenylpyridine (5.7 g, 33.7 mmol) and iridium(III) chloride hydrate (5.94 g, 16.84 mmol), 2-ethoxyethanol (100 mL) and water (33.3 mL). The resulting reaction mixture was refluxed at 130° C. for 18 h under a nitrogen atmosphere. The resulting precipitate was filtered and washed with methanol (3-4 times) and hexane (3-4 times). The product obtained was dried to give 6.35 g (66% yield) of the desired product.
Step 2

(150) Synthesis of Irdium Trifluoromethanesulfonate Salt:

(151) ##STR00222##
The iridium dimer (4.33 g, 3.84 mmol) was dissolved in 500 mL of dichloromethane. In a separate flask, silver(I) trifluoromethanesulfonate (2.07 g, 8.06 mmol) was dissolved in MeOH (250 mL) and was added slowly to the dichloromethane solution with continuous stirring at room temperature. The reaction mixture was stirred overnight in the dark. The reaction mixture was filtered through a tightly packed Celite® bed and the solvent was removed under vacuum to give 5.86 g (100% yield) of product as a brownish solid. The product was used without further purification.
Step 3

(152) Synthesis of Compound 6:

(153) ##STR00223##
A mixture of iridium trifluormethanesulfonate complex (2.85 g, 3.84 mmol) and 2-(dibenzo[b,d]furan-4-yl)-4,5-dimethylpyridine (2.85 g, 12.33 mmol) in EtOH (30 mL) and MeOH (30 mL) was refluxed for 20 h under inert atmosphere. The reaction mixture was cooled to room temperature, diluted with ethanol, Celite® was added and the mixture stirred for 10 min. The mixture was filtered on a small silica gel plug on a frit and washed with ethanol (3-4 times) and with hexane (3-4 times). The filtrate was discarded. The Celite®/silica plug was then washed with dichloromethane to elute the product. The crude product was chromatographed on silica gel with 1/1 (v/v) dichloromethane/hexane to yield 0.5 g (17% yield) of Compound 6 as a yellow solid. Compound 6 was confirmed by HPLC (99.8% pure) and LC/MS.

(154) Synthesis of Compound 7

(155) ##STR00224##
A mixture of iridium trifluormethanesulfonate complex (3.0 g, 3.76 mmol) and 4-(4-isobutylphenyl)-2-phenylpyridine (3.0 g, 10.44 mmol) in EtOH (30 mL) and MeOH (30 mL) was refluxed for 20 h under inert atmosphere. The reaction mixture was cooled to room temperature, diluted with ethanol, Celite® was added and the mixture stirred for 10 min. The mixture was filtered on a small silica gel plug on a frit and washed with ethanol (3-4 times) and with hexane (3-4 times). The filtrate was discarded. The Celite®/silica plug was then washed with dichloromethane to elute the product. The crude product was chromatographed on silica gel with toluene to yield 1.35 g (44% yield) of Compound 7 as a yellow solid. Compound 7 was confirmed by HPLC (99.9% pure) and LC/MS.

(156) Synthesis of Compound 8

(157) Step 1

(158) Synthesis of 2-phenyl-5-(prop-1-en-2-yl)pyridine:

(159) ##STR00225##
To a 1 L round bottom flask was added 5-chloro-2-phenylpyridine (10.15 g, 53.5 mmol), dicyclohexyl(2′,6′-dimethoxy-[1,1′-biphenyl]-2-yl)phosphine (1.8 g, 4.3 mmol), potassium phosphate tribasic monohydrate (37.0 g, 161 mmol) with toluene (200 mL) and water (20 mL). The reaction mixture was degassed with N.sub.2 for 20 minutes, then 4,4,5,5-tetramethyl-2-(prop-1-en-2-yl)-1,3,2-dioxaborolane (12.07 mL, 64.2 mmol) and Pd.sub.2(dba).sub.3 (0.980 g, 1.070 mmol) were added and the reaction mixture was refluxed for 18 h. The aqueous layer was removed and the organic layer was concentrated to dryness. The crude product was chromatographed on silica gel with 0-20% EtOAc in hexane to yield 11 g of the desired product (HPLC purity: 95%). The product was confirmed by GC/MS.
Step 2

(160) Synthesis of 2-phenyl-5-isopropylpyridine:

(161) ##STR00226##
2-Phenyl-5-(prop-1-en-2-yl)pyridine (11 g, 56.3 mmol) was added to a hydrogenator bottle with EtOH (150 mL). The reaction mixture was degassed by bubbling N.sub.2 for 10 min, after which, Pd/C (0.60 g, 5.63 mmol) and Pt/C (0.55 g, 2.82 mmol) were added. The reaction mixture was placed on the Parr hydrogenator for 1.5 h (H.sub.2˜70 psi, according to theoretical calculations). The reaction mixture was filtered on a tightly packed Celite® bed and washed with dichloromethane. The solvent was removed on a rotoevaporator and GC/MS confirmed complete conversion. The crude product was adsorbed on Celite® for column chromatography. The crude product was chromatographed on silica gel with 10% EtOAc in hexane to yield 6 g (54% yield) of the desired product (HPLC purity: 100%). The product was confirmed by GC/MS.
Step 3

(162) Synthesis of Iridium Chloro-Bridged Dimer:

(163) ##STR00227##
To a 500 mL round-bottom flask was added 5-isopropyl-2-phenylpyridine (6.0 g, 30.4 mmol) and iridium(III) chloride hydrate (3.57 g, 10.14 mmol) with 2-ethoxyethanol (100 mL) and water (33.3 mL) under a nitrogen atmosphere. The resulting reaction mixture was refluxed at 130° C. for 18 h. The resulting precipitate was filtered and washed with methanol (3-4 times) and hexane (3-4 times). The product obtained was dried to give 7 g (100% yield) of the desired product.
Step 4

(164) Synthesis of Irdium Trifluoromethanesulfonate Salt:

(165) ##STR00228##
The iridium dimer (5.3 g, 4.27 mmol) was dissolved in 500 mL of dichloromethane. In a separate flask, silver(I) trifluoromethanesulfonate (2.3 g, 8.97 mmol) was dissolved in MeOH (250 mL) and added slowly to the dichloromethane solution with continuous stirring at room temperature. The reaction mixture was stirred overnight in the dark. The reaction mixture was filtered through a tightly packed Celite® bed and the solvent was removed under vacuum to give 6.9 g (100% yield) of product as a brownish solid. The product was used without further purification.
Step 5

(166) Synthesis of Compound 8

(167) ##STR00229##
A mixture of iridium trifluoromethanesulfonate complex (3.0 g, 3.76 mmol) and 2-(dibenzo[b,d]furan-4-yl)-4,5-dimethylpyridine (3.0 g, 10.98 mmol) in EtOH (30 mL) and MeOH (30 mL) was refluxed for 20 h under inert atmosphere. The reaction mixture was cooled to room temperature, diluted with ethanol, Celite® was added and the mixture stirred for 10 min. The mixture was filtered on a small silica gel plug on a frit and washed with ethanol (3-4 times) and with hexane (3-4 times). The filtrate was discarded. The Celite®/silica plug was then washed with dichloromethane to elute the product. The crude product was chromatographed on silica gel with 1/1 dichloromethane/hexane to yield 2.1 g (65% yield) of Compound 8 as a yellow solid. The product was confirmed by HPLC (99.8% pure) and LC/MS.

(168) Synthesis of Compound II-11.

(169) ##STR00230##
Iridium intermediate (11.5 g, 17.6 mmol) and 2-phenyl-4-(4-methyl-d.sub.3-phenyl)pyridine (13 g, 52.2 mmol) were suspended/dissolved in 1:1 methanol:ethanol (440 mL). The reaction was heated at reflux for 24 hours then cooled to room temperature. Celite® was added and the reaction was stirred for 10 minutes. The suspension was filtered through a pad of silica gel via vacuum filtration and the silica gel/Celite® pad was washed with ethanol. The receiving flask was changed and the Celite®/silica gel pad was washed with dichloromethane. The dichloromethane extracts were concentrated to give˜10 g of crude product of ˜92% purity. The crude was purified by column chromatography to give desired product (4.7 g, 35% yield).

(170) Synthesis of Compound II-232.

(171) ##STR00231##
A mixture of the iridium intermediate (3.01 g, 4.03 mmol), 4-(4-isopropylphenyl)-2-phenylpyridine (3.3 g, 12.08 mmol), methanol (100 mL) and ethanol (100 mL) was heated up at 65° C. (oil bath temperature) for 72 hours. The reaction was cooled down and filtered. The solid was washed thoroughly with methanol. The crude was run through a silica gel plug with dichloromethane, then purified by reverse phase column (C18) with 5% water in acetonitrile to obtain 1.2 g pure product (yield 36%).

(172) Synthesis of Compound II-263.

(173) ##STR00232##
A mixture of the iridium intermediate (2.5 g, 3.25 mmol), 2-phenyl-4-(4-methyl-d.sub.3-phenyl)pyridine (2.41 g, 9.74 mmol), methanol (100 mL) and ethanol (100 mL) was heated up at 65° C. (oil bath T) for 72 hours. The reaction was cooled down and filtered. The solid was washed thoroughly with methanol. The solid was run through a silica plug with dichloromethane, then purified with reverse phase column (C18) with 10% water in Macetonitrile to obtain 0.670 g (26% yield) of pure product.

(174) Synthesis of Compound II-242

(175) ##STR00233##

(176) A mixture of the iridium intermediate (3.2 g, 4.16 mmol), 4-(3,4-dimethylphenyl)-2-phenylpyridine (3.23 g, 12.47 mmol), methanol (100 mL) and ethanol (100 mL) was heated up at 65° C. (oil bath temperature) for 72 hours. The reaction was cooled down and filtered. The solid was washed thoroughly with methanol. The solid was run through a silica gel plug with dichloromethane, then purified with reverse phase column (C18) with 5% water in acetonitrile to obtain 2.2 g pure product (yield 64.9%).

(177) Synthesis of Compound II-536

(178) ##STR00234##
A mixture of the iridium intermediate (1.6 g, 2.14 mmol), 4-(3-isopropyl-d7-phenyl)-2-phenylpyridine (1.8 g, 6.42 mmol), ethanol (60 mL) and methanol (60 mL) was heated at 65° C. for 72 hours. The reaction was cooled down and filtered through a small plug of silica gel and washed with dichloromethane. The solution was concentrated and chromatographed (1:1 heptane:DCM) to give desired product (0.4 g, 23% yield).

(179) Synthesis of Compound II-737

(180) ##STR00235##
A mixture of the iridium intermediate (1.6 g, 2.05 mmol), 4-(3-isopropyl-d7-phenyl)-2-phenylpyridine (1.72 g, 6.14 mmol), ethanol (60 mL) and methanol (60 mL) was heated at 65° C. for 72 hours. The reaction was cooled down and filtered through a small plug of silica gel and washed with dichloromethane. The dichloromethane solution was concentrated and chromatographed with C18 reverse phase column 90-95% acetonitrile in water to give desired product (0.48 g, 28% yield).

(181) It is understood that the various embodiments described herein are by way of example only, and are not intended to limit the scope of the invention. For example, many of the materials and structures described herein may be substituted with other materials and structures without deviating from the spirit of the invention. The present invention as claimed may therefore include variations from the particular examples and preferred embodiments described herein, as will be apparent to one of skill in the art. It is understood that various theories as to why the invention works are not intended to be limiting.