A PLASMONIC DEVICE AND A METHOD FOR FABRICATING A PLASMONIC DEVICE
20230324725 · 2023-10-12
Inventors
Cpc classification
G02F1/015
PHYSICS
International classification
Abstract
The invention relates to a plasmonic device and a method for fabricating a plasmonic device. The plasmonic device comprises a substrate on which is arranged a plasmonic section which includes at least one inorganic confining structure adjacent to an organic optical material for providing a plasmonic waveguide. The organic optical material originates from one or more processes for arranging the organic optical material in a limited area. A protective layer is deposited for covering and/or enclosing the organic optical material for improved reliability of the plasmonic waveguide.
Claims
1. A plasmonic device comprising: a substrate on which is arranged a plasmonic section which includes at least one inorganic confining structure adjacent to an organic optical material for providing a plasmonic waveguide, wherein the organic optical material originates from one or more processes for arranging the organic optical material in a limited area, and wherein a protective layer is deposited for covering and/or enclosing the organic optical material for improved reliability of the plasmonic waveguide.
2. The device of claim 1, wherein the one or more processes for arranging the organic optical material in a limited area includes one or more of a local deposition process and a combination of a deposition process and a structuring process.
3. The device of claim 1, wherein the protective layer originates from one or more thin film deposition processes.
4. (canceled)
5. (canceled)
6. The device of claim 1, wherein one of the at least one inorganic confining structure includes a plasmonic material and other ones of the at least one inorganic confining structure include one or more of a plasmonic material, a conductor, a semiconductor, and a dielectric element.
7. The device of claim 1, wherein the protective layer has a structured design which originates at least partially from one or more of a lithographic process, a masking process, a structuring process, a local growth process, and a local deposition process, wherein the structured design enables in particular electrically respectively optically connecting the plasmonic section.
8. The device of claim 1, wherein the protective layer has a structured design which originates at least partially from connecting one or more of a further electrical component (31″, 32″) and a further optical component with the plasmonic section prior to depositing the protective layer.
9. The device of claim 1, wherein the protective layer has a structured design which originates at least partially from partially or fully penetrating the protective layer for connecting one or more of a further electrical component (31″, 32″) and a further optical component for electrically respectively optically connecting the plasmonic section.
10. The device of claim 1, wherein the protective layer includes one or more of an inorganic material, an organic material, and a combination thereof, in particular one or more of a mineral material, a material including micro-particles, nano-particles, a nano-laminate, an epoxy material, a sol-gel material, a 2D material, a polymer film, an organic material, a composite material, a metal, a semiconductor material, an insulating material, a ceramic, a glass, and a dielectric.
11. The device of claim 1, wherein the protective layer includes multiple sublayers.
12. The device of claim 1, wherein the structured design of the protective layer includes one or more openings (51, 52, 53) for providing access to one or more electrical and/or optical connection areas of the integrated optical device.
13. The device of claim 1, wherein the device is configured to enable modulation of an optical signal in accordance with an electrical signal, and/or to enable modulation of an electrical signal in accordance with an optical signal.
14. A method for fabricating a plasmonic device, the method comprising: providing a substrate, arranging on the substrate a plasmonic section which includes at least one inorganic confining structure adjacent to an organic optical material for providing a plasmonic waveguide, wherein the organic optical material is arranged in a limited area, and depositing a protective layer for covering and/or enclosing the organic optical material for improved reliability of the plasmonic waveguide.
15. The method of claim 14, wherein the organic optical material is arranged using one or more of a local deposition process and a combination of a deposition process and a structuring process.
16. The method of claim 14, wherein the protective layer is deposited using one or more thin film deposition processes.
17. A plasmonic device comprising a substrate, a plasmonic section arranged on the substrate, the plasmonic section including at least one inorganic confining structure adjacent to an organic optical material providing a plasmonic waveguide, wherein the organic optical material is arranged in a limited area, and a protective layer covering and/or enclosing the organic optical material.
18. The plasmonic device of claim 17 wherein the protective layer fully encloses the organic optical material.
19. The plasmonic device of claim 17 with more than one inorganic confining structure, wherein the organic optical material is an electro-optic material and the inorganic confining structures are electrodes or are electrically contacted to electrodes.
20. The plasmonic device of claim 17 wherein the organic optical material is an organic nonlinear optical material having second-order nonlinearity.
21. The plasmonic device of claim 17 wherein the protective layer has a water-vapor transmission rate below at least one of 1×10.sup.−1 g/(m.sup.2day), 1×10.sup.−3 g/(m.sup.2day), and 1×10.sup.−5 g/(m.sup.2day).
22. The plasmonic device of claim 17 wherein the protective layer has an oxygen permeation rate below at least one of 100 cm.sup.3/(m.sup.2day), 1×10.sup.−0 cm.sup.3/(m.sup.2day), 1×10.sup.−2 cm.sup.3/(m.sup.2day), and 1×10.sup.−4 cm.sup.3/(m.sup.2day).
23. The plasmonic device of claim 17 wherein the protective layer includes a combination of an inorganic material and an organic material.
24. The plasmonic device of claim 17 wherein the protective layer includes a nano-laminate.
25. The plasmonic device of claim 17 wherein the organic optical material partially covers the inorganic confining structures.
26. The plasmonic device of claim 17 wherein the limited area of the organic optical material is at least ten times smaller than an area of the substrate.
27. The plasmonic device of claim 17 having two inorganic confining structures with a gap between them, wherein the limited area of the organic optical material is at least ten times larger than an area of the gap.
28. The plasmonic device of claim 17 wherein the protective layer includes at least one of glass, aluminum nitride, Al2O3, HfO2, SiO2, ZrO2, ZnO, SiN, silicon oxynitride, TiO2, TiN, and organic materials.
29. The plasmonic device of claim 17 wherein the protective layer is structured to only partially extend over the inorganic confining structures.
30. The plasmonic device of claim 17 wherein the protective layer includes a first protective sublayer and a second protective sublayer, and wherein the protective sublayers include different materials.
31. The plasmonic device of claim 17 comprising more than one inorganic confining structure, wherein the confining structures comprise electrodes auxiliary electrical components, and further auxiliary components, wherein the auxiliary electrical components form electrical lines providing an electrical connection between the further auxiliary components and the inorganic confining structures, and wherein the electrodes are covered by the protective layer, and wherein the auxiliary electrical components are partially covered by the protective layer, thereby providing access to the auxiliary electrical components.
32. The method of claim 14 comprising the step of depositing the protective layer to fully enclose the organic optical material.
33. The method of claim 14 comprising the step of using a combination of a deposition process and a structuring process to arrange the organic optical material in the limited area.
34. The method of claim 33 wherein the combination of the deposition process and the structuring process comprises at least one of an ink-jet printing process, an aerosol printing process, a drop-casting process, a dispensing process, an etching process, a lift-off process, a local growth process, a mechanical or thermal structuring process, a masking process, and a lithographic process.
35. The method of claim 14 comprising the step of arranging the organic optical material in the limited area by means of spin-coating in combination with a lithographic process.
36. The method of claim 14 comprising the step of depositing the protective layer by means of one or more thin film deposition processes including include at least one of an atomic layer deposition process, a sputtering process, and a molecular layer deposition process.
37. The method of claim 14 comprising the step of manufacturing the protective layer with a structured design using at least one of a lithographic process and a masking process.
38. The method of claim 14 comprising the step of removing areas or sections of the protective layer where the protective layer is not required.
39. The method of claim 14 further comprising the step of depositing a first protective layer, followed by wire-bonding, and followed by depositing a second protective layer.
40. The method of claim 14 wherein the protective layer is deposited in a deposition process applied at temperatures of at least one of: below 200° C., below 140° C., and below 100° C.
41. The method of claim 14 further comprising the steps depositing a first and a second protective layer using different deposition processes.
42. The method of claim 14 comprising the steps of depositing a plurality of protective sublayers and using one or more of the protective sublayer as a mask for structuring the organic optical material in the limited area.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0045] In the following, advantageous embodiments of the invention will be described with reference to the enclosed drawings. However, neither the drawings nor the description shall be interpreted as limiting the invention.
[0046]
[0047]
[0048]
[0049] The figures are only schematic and not to scale. Same reference signs refer to same or similar features.
MODE(S) FOR CARRYING OUT THE INVENTION
[0050]
[0051] As shown in
[0052]
[0053] In some embodiments, as illustrated in
[0054] In some embodiments, the inorganic confining structures 31, 32 include a first portion arranged adjacent to the organic optical material 33, and a second portion arranged adjacent to the first portion, and a third portion arranged adjacent to the second portion. The first portion may include a plasmonic material, the second portion may include a conductive material, or a material for capacitive coupling such as BaTiO3, and the third portion may include a conductive material for contacting, providing a plasmonic device 1. T plasmonic material is provided for enabling the plasmonic waveguide 34, wherein the second and third portion allow electrically contacting the devices. In some embodiments, the inorganic confining structures 31, 32 include a first portion of a plasmonic material such as Au, Ag, Cu, Al, TiN, a material with a negative real part of the permittivity, etc., wherein electrical contacts are not required for applications such as frequency mixing. Thus, the plasmonic device may be configured as a modifier circuit for receiving one or more optical signals and for generating a modified signal, such as for receiving an optical input signal which includes one or more input frequencies and for generating an optical output signal which includes one or more output frequencies in accordance with predefined arithmetic operations on the input frequencies, such as a duplication of an input frequency, a difference between input frequencies, etc. The predefined arithmetic operations may be achieved with an organic optical material 33 having a second order nonlinearity and/or a third order nonlinearity. In some embodiments, the inorganic confining structures 31, 32 include a first portion, such plasmonic material, and a second portion, such as a conducting material, which is spaced apart from the first portion.
[0055]
[0056] In some embodiments of the invention, the organic optical material 33 originates from a local deposition technique. In some embodiments of the invention, the organic optical material 33 originates from an ink-jet printing process, drop-casting process, aerosol printing process or another local deposition technique resulting in a drop-like deposition. In some embodiments of the invention, the organic optical material 33 originates from a lithographic process. In some embodiments of the invention, the organic optical material 33 originates from a structuring process applied prior to or after deposition of the organic optical material 33, such as a lithographic step including etching, lift-off, etc. In some embodiments the organic optical material 33 may be structured by mechanically, thermally, etc. removing portions of the organic optical material 33 after deposition, such as mechanically scratching, burning away with a hot needle, a laser, etc.
[0057] For example,
[0058] In accordance with some embodiments of the invention, the limited area of the organic optical material 33 is at least ten times smaller than the area of the substrate 2.
[0059] In accordance with some embodiments of the invention, the limited area of the organic optical material 33 is at least ten times larger than the area of a gap between the inorganic confining structures 31, 32.
[0060] The present disclosure shows various embodiments of a plasmonic device 1 having a plasmonic section 3. The plasmonic section 3 includes a plasmonic waveguide 34 formed by inorganic confining structures 31, 32 and an organic optical material 33. In some embodiments of the plasmonic device 1, the inorganic confining structures 31, 32 are metals for forming a plasmonic slot waveguide that is filled with the organic optical material 33. An electrical signal may be connected to the inorganic confining structures 31, 32 for generating an electric field within the organic optical material 33.
[0061] The present disclosure shows various embodiments of a plasmonic device 1 comprising a substrate 2, inorganic confining structures 31, 32, an organic optical material 33 and a protective layer 4.
[0062] The substrate 2 may include a material such as Silicon, Silicon Oxide, Sapphire, Glass, Silicon Nitride, Silicon Oxynitride, III-V materials, Oxides, Nitrides, organic materials, dielectric, semiconductor, or insulating materials. The substrate 2 may be an silicon-on-insulator (SOI) substrate or an oxidized silicon wafer. The substrate 2 may be an electronic die or wafer containing CMOS circuits, bi-polar transistors, electronic circuits, etc.
[0063] The inorganic confining structures 31, 32 may include a plasmonic material including a metal such as Au (Au: Gold), Ag (Ag: Silver), Nickel (Ni), Cu (Cu: Copper), Al (Al: Aluminum), Ti (Ti: Titanium), or any other metal, or TiN (TiN: Titanium Nitride), or a material with a negative real part of the permittivity, or an alloy or a layer structure of them.
[0064] In some embodiments, a first inorganic confining structure 31 includes different materials than a second inorganic confining structure 32. The first inorganic confining structure 31 may include a plasmonic material as defined in the previous paragraph, and the second inorganic confining structure 32 may include a dielectric or semiconductor material such as Silicon, Silicon Oxide, Silicon Oxynitride, Silicon Nitride, Barium Titanate, Lithium Niobate, GaAs, III-V materials, etc.
[0065] The organic optical material 33 may include an organic non-linear optical material, in particular featuring a second-order (chi-2) or a third-order (chi-3) nonlinearity, such as an OEO material (OEO: organic electro-optic), an organic dye, organic crystals, organic electro-optic polymers, chromophores, composite materials, disperse red 1 (DR1), SEO100, SEO125, SEO250, GigOptix M3, JRD1, YLD124, HLD, AJCKL1 or any of the previous materials in a host material such as poly methyl methacrylate (PMMA) e.g. DR1 in PMMA or amorphous polycarbonate (APC) e.g. AJCKL1 in APC. The organic optical material may be a chromophore material. The organic optical material may haven a linear and/or a quadratic electro-optic effect. The organic optical material may have an electro-optic coefficient. The organic optical material may haven an electro-optic coefficient of r.sub.33>30 pm/V or r.sub.33>60 pm/V may, or r.sub.33>100 pm/V or ideally r.sub.33>140 pm/V. The optical material may have a glass transition temperature T.sub.g. The organic optical material may have a glass transition temperature T.sub.g>60° C., T.sub.g>80° C., T.sub.g>120° C., or T.sub.g>160° C.
[0066] The organic optical material 33 may include liquid crystals, organic nanoparticles, quantum dots, organic materials, etc.
[0067] The protective layer 4 may protect the organic optical material 33 from degradation, thereby improving reliability of the plasmonic waveguide respectively the plasmonic section. The protective layer 4 may provide protection from external influences such as O2, H2O, humidity, solvents, plasma processes, mechanical influences, stress, etc. The protective layer 4 may reduce, limit, and/or remove chemical degradation of the organic optical material 33. The protective layer 4 may reduce, limit, and/or remove oxidation of the organic optical material 33. The protective layer 4 may reduce, limit, and/or remove the reduction of functions such as the nonlinearity of the organic optical material 33. The protective layer 4 may act as a heat conductive layer in order to dissipate heat from the inorganic confining structures 31, 32, the organic optical material 33, the plasmonic waveguide 34, etc. The protective layer may be configured for providing water-vapor transmission rates of below 1×10.sup.−1 g/(m.sup.2 day), or below 1×10.sup.−3 g/(m.sup.2 day), or below 1×10.sup.−5 g/(m.sup.2 day). The protective layer may be configured for providing oxygen transmission rates in the range of below 100 cm.sup.3/(m.sup.2 day), or below 1×10.sup.0 cm.sup.3/(m.sup.2 day), or below 1×10.sup.−2 cm.sup.3/(m.sup.2 day), or below 1×10.sup.−4 cm.sup.3/(m.sup.2 day).
[0068] The protective layer 4 may originate from an atomic layer deposition process (ALD), a sputtering process, a plasma-enhanced chemical vapor deposition process (PECVD), a pulsed laser deposition process (PLD), a physical vapor deposition process (PVD), a molecular layer deposition process (MLD), a blade-casting process, a printing process, a spin-coating process and/or a sol-gel process. The protective layer 4 may include an inorganic material, an organic material, and/or a combination thereof. The protective layer 4 may have a multilayer design. The protective layer 4 may include a mineral material, a material including micro-particles, nano-particles, a 2D material, a polymer film, a composite material, a metal, a semiconductor material, and/or an insulating material. The protective layer 4 may include glass, aluminum nitride, Al2O3, HfO2, SiO2, ZrO2, ZnO, SiN, silicon oxynitride, TiO2, TiN, organic materials, etc. The protective layer 4 may originate from a deposition process applied at temperatures below 200° C., below 140° C. or below 100° C. in order to prevent degeneration or loss of performance of the organic optical material 33.
[0069] In some embodiments of the invention, the plasmonic device 1 includes inorganic confining structures 31, 32 in the form of electrodes and includes an organic optical material 33 in the form of an electro-optic material for providing the plasmonic waveguide 34, and wherein an optical signal may be coupled into the plasmonic waveguide and modulated in accordance with an electrical signal applied to the electrodes.
[0070] In accordance with some embodiments of the invention, the plasmonic section 3 includes the inorganic confining structures 31, 32, and the organic optical material 33. The inorganic confining structures 31, 32 may include metallic or dielectric or semiconductor or multilayer structures. The inorganic confining structures 31, 32 may make use of organic optical materials 33, such as organic nonlinear materials, etc.
[0071]
[0072]
[0073]
[0074]
[0075] In accordance with some embodiments of the invention, a plurality of protective sublayers 41, 42, . . . may be deposited, wherein different deposition processes and/or different materials may be involved. Thus, two or more protective sublayers 41, 42, . . . may be deposited. One or more of the protective sublayers 41, 42, . . . may have a structured design. One or more of the protective sublayers 41, 42, . . . may serve as a lithographic mask to locally open other protective sublayers 41, 42, . . . below. One or more of the protective sublayers 41, 42, . . . may serve as a mask for structuring the organic optical material 33, in particular for arranging the organic optical material 33 in a limited area.
[0076] In accordance with some embodiments of the invention, a first protective sublayer 41 may include an organic-inorganic multilayer (or an inorganic-organic multilayer). In accordance with some embodiments of the invention, the second protective sublayer 42 may include a (thick) organic or inorganic material for encapsulation. In accordance with some embodiments of the invention, the second protective sublayer 42 may include an epoxy, a photo resist, an electron-beam resist, a glue, etc.
[0077]
[0078]
[0079]
[0080] Contrary to the protective layer 4, the cladding 6 does not provide functions for protection from external influences such as O2, H2O, etc., because the cladding 6 is designed for improving operation of the auxiliary optical component 33′, for example in photonics for providing the low-refractive-index material that surrounds the core of an optical fiber or a photonic optical waveguide to contain core light and providing a refractive index contrast to the core (or confining structure) and reducing surface scattering. In all-glass fibers, the cladding is glass. A cladding 6 as illustrated in
[0081]
[0082]
[0083]
[0084]
[0085]
[0086] As illustrated in
[0087] As illustrated in
[0088] As illustrated in
[0089] As illustrated in
[0090] In accordance with some embodiments of the invention, areas or sections of the protective layer 4 may be removed using other techniques wherever the protective layer 4 is not required.
[0091] In accordance with some embodiments of the invention, depositing a protective layer 4 having a structured design allows for contacting electrodes, accessing optical interfaces, or post-process certain areas of chip.
[0092]
[0093]
[0094]
[0095]
[0096]
[0097]
[0098]
[0099] According to
[0100]
[0101]
[0102] In accordance with some embodiments of the invention, the first inorganic confining structure 31 or the second inorganic confining structure 32 is formed from a dielectric or semiconducting material for providing a hybrid plasmonic waveguide.
[0103]
[0104]
[0105]
[0106]
[0107]
[0108]
[0109] Finally, it should be noted that the term “comprising” does not exclude other elements or steps and the “a” or “an” does not exclude a plurality. Also, elements described in association with different embodiments may be combined. It should also be noted that reference signs in the claims should not be construed as limiting the scope of the claims.