METHOD FOR CONTINUOUS CLEANING OF PROCESS WATER IN WASTE PAPER TREATMENT WITH CONTROL OF THE CONTENT OF INORGANIC SOLIDS
20230322599 · 2023-10-12
Assignee
Inventors
- George TROUBOUNIS (Munich, DE)
- Henning LAUBROCK (Munich, DE)
- Lucas MENKE (Munich, DE)
- Luis DOMENE FIGUEROLA (Munich, DE)
Cpc classification
C02F2209/10
CHEMISTRY; METALLURGY
Y02W10/30
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
C02F3/2866
CHEMISTRY; METALLURGY
C02F3/2846
CHEMISTRY; METALLURGY
International classification
Abstract
The present invention relates to a method and to a device for continuous cleaning of process water circulating in a device for treating waste paper. The process water is supplied, from a unit of the device, to an anaerobic reactor comprising a gas separator, and the cleaned process water is returned back to a unit of the device, wherein this unit is selected from: a pulper; screening device; dewatering unit; oxidation/reduction unit; centrifugal screening device; fine screening device; paper-machine mould section; paper-machine press section; reject treatment unit; fibre recovery unit; and drying section; wherein the content of inorganic solids in the reactor is measured and, if this content exceeds a pre-set limit value, process water from the reactor is continuously fed to a solid-liquid separator for separation into a fraction that is depleted of inorganic solids and a fraction that is enriched with inorganic solids, wherein the fraction that is depleted of inorganic solids is returned to the anaerobic reactor and the fraction that is enriched with inorganic solids is conveyed away out of the device, until the content of inorganic solids in the process water is less than the limit value.
Claims
1. Method for continuous cleaning of process water circulating in a device for processing waste paper (100) and/or in the paper machine (200) of a machine for manufacturing paper from waste paper, in which process water to be cleaned is supplied, from at least one unit of the device (100) and/or the paper machine (200), to a process water processing unit having an anaerobic reactor (125a, 125b, 225) comprising one or more gas separators (504), the process water is contacted, in the anaerobic reactor (125a, 125b, 225), with anaerobic microorganisms in order to break down impurities contained in the process water, and the cleaned process water is conveyed away from the anaerobic reactor (125a, 125b, 225) and returned to at least one unit of the device (100) and/or the paper machine (200), wherein at least one unit is selected from one or more of a pulper (105), sorting device (110a, 110b), dewatering unit (115a, 115b), oxidation/reduction unit (112), centrifugal sorter (202), fine sorting device (204), paper-machine mold part (206), paper-machine press part (208), reject treatment unit (118a, 118b, 212), fiber recovery unit (214) and drying part (210), wherein, in the method, the content of inorganic solids in the process water contained in the anaerobic reactor (125a, 125b, 225) is measured continuously or discontinuously and, if the content of inorganic solids in the process water contained in the anaerobic reactor (125a, 125b, 225) exceeds a pre-set limit value, process water is continuously supplied, from the anaerobic reactor (125a, 125b, 225), to a solid-liquid separator (126a, 126b, 226) for separation into a fraction depleted of inorganic solids and a fraction enriched with inorganic solids, wherein the fraction depleted of inorganic solids is returned to the anaerobic reactor (125a, 125b, 225) at least in part and the fraction enriched with inorganic solids is conveyed away from the device (100) and/or the paper machine (200), until the content of inorganic solids in the process water contained in the anaerobic reactor (125a, 125b, 225) is less than the pre-set limit value.
2. Method according to claim 1, wherein the process water supplied continuously to the solid-liquid separator (126a, 126b, 226) from the anaerobic reactor (125a, 125b, 225) is removed from the lower region of the anaerobic reactor (125a, 125b, 225) .
3. Method according to claim 1, wherein the lower region of the anaerobic reactor (125a, 125b, 225), viewed in cross section, is designed in a zigzag shape, the zigzag-shaped region extending over 1 to 50% the height of the anaerobic reactor (125a, 125b, 225).
4. Method according to claim 1, wherein the lower region of the anaerobic reactor (125a, 125b, 225), viewed in cross section, is designed as a cone (514), the cone (514) extending over 1 to 20% of the height of the anaerobic reactor (125a, 125b, 225).
5. Method according to claim 1, wherein the limit value for the content of inorganic solids in the process water contained in the anaerobic reactor (125a, 125b, 225) is pre-set to a value between 30 and 45 wt.% .
6. Method according to claim 1, wherein process water from the anaerobic reactor (125a, 125b, 225) is supplied continuously to a solid-liquid separator (126a, 126b, 226), and the fraction depleted of inorganic solids is returned to the anaerobic reactor (125a, 125b, 225), at least in part, until the content of inorganic solids in the process water contained in the anaerobic reactor (125a, 125b, 225) is at least 1% less than than the pre-set limit value.
7. Method according to claim 1, wherein the process water is separated in the solid-liquid separator (126a, 126b, 226) such that the portion of the fraction depleted of inorganic solids is at least 70 vol.%, and the portion of the fraction enriched with inorganic solids amounts to the remainder up to 100%, with respect to the volume flow of the process water supplied to the solid-liquid separator (126a, 126b, 226).
8. Method according to claim 1, wherein the process water is separated in the solid-liquid separator (126a, 126b, 226) such that the content of inorganic solids in the fraction enriched with inorganic solids is at least 25% higher than the content of inorganic solids in the fraction depleted of inorganic solids.
9. Method according to claim 1, wherein the solid-liquid separator (126a, 126b, 226) comprises one or more centrifugal separators (126a, 126b, 226) .
10. Device for processing waste paper (100), and/or paper machine (200) of a machine for manufacturing paper from waste paper, the device (100) and/or the paper machine (200) comprising a process water processing unit (116a, 116b, 216) for cleaning process water circulating in the device (100) and/or the paper machine (200), and comprising at least one unit selected from one or more of a pulper (105), sorting device (110a, 110b), dewatering unit (115a, 115b), oxidation/reduction unit (112), centrifugal sorter (202), fine sorting device (204), paper-machine mold part (206), paper-machine press part (208), reject treatment unit (118a, 118b, 212), fiber recovery unit (214) and drying part (210), and the process water processing unit (116a, 116b, 216) comprising: i) an anaerobic reactor (125a, 125b, 225) comprising one or more gas separators (504), for anaerobic cleaning of process water, comprising at least one supply line (500) for supplying process water to be cleaned to the anaerobic reactor (125a, 125b, 225), and at least one discharge line (512) for conveying away cleaned process water out of the reactor (125a, 125b, 225), the process water processing unit (116a, 116b, 216) being connected to at least one of the at least one unit, such that, during operation of the device (100) and/or paper machine (200), process water to be cleaned is supplied from at least one unit to the process water processing unit (116a, 116b, 216) and, therein, the anaerobic reactor (125a, 125b, 225), and after the process water processing step cleaned process water is returned into the at least one unit, and ii) a solid-liquid separator (126a, 126b, 226) for separating process water conveyed away from the anaerobic reactor (125a, 125b, 225) into a fraction depleted of inorganic solids and a fraction enriched with inorganic solids, comprising a discharge line (127a, 127b, 227) for the fraction enriched with inorganic solids and comprising a return line (128a, 128b, 228) for returning the fraction depleted of inorganic solids into the anaerobic reactor (125a, 125b, 225), at least in part, a further line leading from the anaerobic reactor (125a, 125b, 225) to the solid-liquid separator (126a, 126b, 226) for supplying process water conveyed away from the anaerobic reactor (125a, 125b, 225), wherein this further comprises iii) a measuring device for measuring the content of inorganic solids in the process water contained in the anaerobic reactor (125a, 125b, 225), and in that this also comprises a control means which can receive measuring data regarding the content of inorganic solids in the process water contained in the anaerobic reactor (125a, 125b, 225) and into which a limit value and optionally a threshold value can be input, the control means being designed such that it automatically starts the continuous removal of process water from the anaerobic reactor (125a, 125b, 225) and the supply thereof into the solid-liquid separator (126a, 126b, 226), if an input limit value for the inorganic solids content in the process water contained in the anaerobic reactor (125a, 125b, 225) is exceeded, and automatically ends the continuous removal of process water from the anaerobic reactor (125a, 125b, 225), and the supply thereof into the solid-liquid separator (126a, 126b, 226), in the event of falling below the limit value or an input threshold value for the inorganic solids content in the process water contained in the anaerobic reactor (125a, 125b, 225).
11. Device (100) and/or paper machine (200) according to claim 10, wherein the lower region of the anaerobic reactor (125a, 125b, 225), viewed in cross section, is designed in a zigzag shape, the zigzag-shaped region extending over 1 to 50% of the height of the anaerobic reactor (125a, 125b, 225).
12. Device (100) and/or paper machine (200) according to claim 10, wherein the lower region of the anaerobic reactor (125a, 125b, 225), viewed in cross section, is designed as a cone (514), the cone (514) extending over 1 to 50% of the height of the anaerobic reactor (125a, 125b, 225).
13. Device (100) and/or paper machine (200) according to claim 10, wherein the solid-liquid separator (126a, 126b, 226) comprises one or more centrifugal separators (126a, 126b, 226) .
14. Device (100) and/or paper machine (200) according to claim 10, wherein the one or more gas separators (504) in the anaerobic reactor (125a, 125b, 225) are arranged at a height of between 30 and 90% respect to the height of the anaerobic reactor (125a, 125b, 225).
15. Device (100) and/or paper machine (200) according to claim 10, wherein the one or more gas separators (504) are designed such that they prevent anaerobic microorganism pellets (502) from flowing further up in the anaerobic reactor (125a, 125b, 225), and thus result in gas adhering to the surface of the anaerobic microorganism pellets (502) being released and the gas being conveyed away out of the anaerobic reactor (125a, 125b, 225) via the gas separator.
16. Machine for manufacturing paper from waste paper, comprising a device for processing waste paper (100) and a paper machine (200) according to claim 10, wherein the device (100) comprises one, two or more stages (101a, 101b), each stage (101a, 101b) comprising a dewatering unit (115a, 115b) and at least one further unit selected from one or more of pulper (105), sorting device (110a, 110b) and oxidation/reduction unit (112), each stage (101a, 101b) and the paper machine (200) in each case comprising a process water processing unit (116a, 116b, 216) having the features of claim 10 relating to the process water processing unit.
17. Machine according to claim 16, wherein the paper machine (200) comprises at least one unit selected from a centrifugal sorter (202), fine sorting device (204), paper-machine mold part (206), paper-machine press part (208), reject treatment unit (212), fiber recovery unit (214), and drying part (210).
Description
[0051] The present invention will be described in greater detail in the following, with reference to the accompanying drawings, in which:
[0052]
[0053]
[0054]
[0055] The system shown in
[0056] The first stage 101a of the paper processing device 100 comprises a raw material inlet 102, a pulper 105, a sorting means 110a, and a dewatering unit 115a, which are sequentially arranged and are interconnected in each case. Within the meaning of the present invention, a pulper 105 is understood to mean not only a means, as shown schematically in
[0057] The pulper 105 and the sorting means 110a are in each case connected to a reject treatment unit 118a by means of a line.
[0058] Furthermore, the first stage 101a of the waste paper processing device 100 comprises a process water processing unit 116a which is supplied, via corresponding lines from the reject treatment unit 118a, from the sorting device 110a and from the dewatering unit 115a, with the process water accumulating in said system parts. The process water processing unit 116a consists of a material recovery unit 120a, a pre-acidification reactor 121a, a system according to the invention for cleaning process water which comprises an anaerobic reactor 125a to which anaerobic microorganisms are added, and a solid-liquid separator 126a (for separating process water conveyed away from the anaerobic reactor 125a into a fraction depleted of inorganic solids and a fraction enriched with inorganic solids), comprising a discharge line 127a for the fraction enriched with inorganic solids and comprising a return line 128a for returning the fraction depleted of inorganic solids into the anaerobic reactor 125a, and a chalk elimination unit 130a and a filtration unit 140a. In this case, the chalk elimination unit 130a is designed as a pressure-relief flotation means. The system comprising the anaerobic reactor 125a and the solid-liquid separator 126a, for cleaning process water, is shown in more detail in
[0059] For the sake of completeness, it should be noted that the filtration unit 140a is optional and can also be omitted, i.e. the filtrate can be returned from the chalk elimination unit 130a directly into the return line 145a. Furthermore, a centrifugal sorter can be provided before or after the sorting device 110a. Furthermore, the material recovery unit 120a can be combined with a material removal unit, for example designed as a micro-flotation means.
[0060] In contrast with the first stage 101a, the second stage 101b of the waste paper processing device 100 comprises a sorting device 110b connected to the dewatering unit 115a, an oxidation unit or reduction unit 112, and a dewatering unit 115b, which are sequentially arranged and interconnected. Furthermore, the second stage 101b comprises a process water processing unit 116b which is designed in a manner analogous to the process water processing unit 116a of the first stage 101a, i.e. comprises a chalk elimination unit 130b designed as a pressure-relief flotation means, the filtration unit 140b of the second stage 101b of the waste paper processing device 100 being connected to the sorting device 110b via a return line 145b, and being connected to the return line 145a of the first stage 101a of the waste paper processing device 100, emerging from the filtration unit 140a, via a partial flow line 170a. While the sorting device 110b and the oxidation unit or reduction unit 112 are connected via corresponding lines to a reject treatment unit 118b, the dewatering unit 115b is connected directly to the material recovery unit 120b of the process water processing unit 116b. Furthermore, a line leads from the oxidation unit or reduction unit 112 to the material recovery unit 120b.
[0061] For the sake of completeness, it should be noted that the filtration unit 140b is optional and can also be omitted. Furthermore, a centrifugal sorter can be provided before or after the sorting device 110b. Furthermore, the material recovery unit 120b can be combined with a material removal unit, for example designed as a micro-flotation means.
[0062] The paper machine 200 comprises a centrifugal sorter 202, a fine sorting device 204, a paper-machine mold part 206, a paper-machine press part 208, and a drying part 210, which are sequentially arranged and interconnected. The centrifugal sorter 202 and the fine sorting device 204 are connected to a reject treatment unit 212, and the paper-machine mold part 206 and the paper-machine press part 208 are connected to a fiber recovery unit 214. Furthermore, the reject treatment unit 212 and the fiber recovery unit 214 are connected via corresponding lines to a process water processing unit 216, which consists of a material removal unit 220, a pre-acidification reactor 221, a system according to the invention for cleaning process water which comprises an anaerobic reactor 225 to which anaerobic microorganisms are added, and a solid-liquid separator 226 (for separating process water conveyed away from the anaerobic reactor 225 into a fraction depleted of inorganic solids and a fraction enriched with inorganic solids), comprising a discharge line 227 for the fraction enriched with inorganic solids and comprising a return line 228 for returning the fraction depleted of inorganic solids into the anaerobic reactor 225, and a chalk elimination unit 230 and a filtration unit 240. Furthermore, a return line 270 leads from the filtration unit 240 of the paper machine 200 into the line 170 of the second stage 101b of the waste paper processing device 100. The fiber recovery unit 214 and the material removal unit 220 can also be combined in a device part designed for example as micro-flotation.
[0063] Furthermore a fresh water supply line 280 is provided in the region of the paper machine 200, via which fresh water supply line fresh water can be supplied to the paper machine. In this case, the fresh water supply line 280 can open at various locations in the paper machine 200, for example in the supply line to the centrifugal sorter 202 and/or in the paper-machine mold part 206 and/or the paper-machine press part 208, and therefore the exact position of the fresh water supply line 280 is not shown in
[0064] The system according to the invention for cleaning process water, shown in more detail in
[0065] During operation of the system shown in
[0066] Furthermore, flotation for the purpose of elimination of pigments, ink and color particles (de-inking) can be carried out in the sorting device 110a. Furthermore, in the case of fabric washing, fine materials and ash can be separated. In the dewatering unit 115a arranged downstream of the sorting device 110a, which dewatering unit is preferably designed as a dewatering filter and/or as a screw press, the fiber suspension is compressed by removing process water, in order to travel from the dewatering unit 115a into the sorting device 110b of the second stage 101b of the waste paper processing device 100, as a compressed fiber suspension. A partial stream of the process water accumulating in the sorting device 110a is conveyed into the reject treatment unit 118a, whereas the other partial stream of the process water accumulating in the sorting device 110a, together with the process water accumulating in the dewatering unit 115a of the first stage 101a, is conveyed, via corresponding lines, directly into the material recovery unit 120a of the process water processing unit 116a of the first stage 101a of the waste paper processing device 100, in which fibrous materials contained in the process water are separated therefrom, which fibrous materials are supplied again to the processing process. Preferably, the material recovery unit 120a is designed as a pressure-relief flotation means.
[0067] In the case of the system shown in
[0068] The process water cleaned and descaled in the process processing unit 116a of the first stage 101a of the waste paper processing device 100 is returned to the pulper 105 via the return line 145a.
[0069] The compressed fiber suspension, conveyed away from the dewatering unit 115a of the first stage 101a of the waste paper processing device 100, reaches the sorting stage 110b, and from there an oxidation unit or reduction unit 112, before the fiber suspension is compressed in the dewatering unit 115b of the second stage 101b, in order to remove as much of the process water as possible from the fiber suspension. In a manner analogous to the first stage 101a of the waste paper processing device 100, the process water accumulating in the sorting device 110b, and a partial stream of the process water accumulating in the oxidation unit or reduction unit 112, are conducted into the reject treatment unit 118b, and the process water accumulating there is conducted into the material recovery unit 120b. The other partial stream of the process water accumulating in the oxidation unit or reduction unit 112, and the process water accumulating in the dewatering unit 115b, are conducted directly into the material recovery unit 120b of the process water processing unit 116b of the second stage 101b of the waste paper processing device 100, and cleaned and descaled in the process water processing unit 116b. The process water thus treated largely returns to the sorting device 110b from the filtration unit 140b, via the line 170 and the return line 145b, whereas a possible excess of process water is returned to the first stage 101a of the waste paper processing device 100 via the partial flow line 170a and into the return line 145a leading to the pulper 105.
[0070] In the paper machine 200, the compressed fibrous material suspension, continuously supplied from the dewatering unit 115b, is processed to form paper, by means of the centrifugal sorter 202, in which parts having a specific weight greater or less than water are separated, the fine sorting device 204, the paper-machine mold part 206, the paper-machine press part 208, and the drying part 210. While the process water accumulating in the system parts 202 and 204 is conducted into the reject treatment unit 212, the process water accumulating in the system parts 206 and 208 is conducted into the fiber recovery unit 214. While the rejects are dewatered in the reject treatment unit 212, in the fiber recovery unit 214 the process water originating from the paper-machine mold part 206 and the paper-machine press part 208 undergoes prior material removal, and fibers are separated therefrom. Process water accumulating in the reject treatment unit 212 and in the fiber recovery unit 214 is conducted continuously into the process water processing unit 216 of the paper machine 200, and there flows sequentially through the material removal unit 220, the pre-acidification reactor 221, the anaerobic reactor 225 and, if the limit value is exceeded, the solid-liquid separator, the chalk elimination unit 230 and the filtration unit 240, which are operated in the manner of the corresponding system parts of the process water processing units 116a, 116b of the waste paper processing device 100, described above. Alternatively thereto, the process water accumulating in the reject treatment unit 212 can be conveyed away from the system as waste water, and only the process water accumulating in the fiber recovery unit 214 can be conducted continuously through the process water processing unit 216 of the paper machine 200. The cleaned and descaled process water withdrawn from the filtration unit 240 is largely returned to the centrifugal sorter 202 of the paper machine 200 via the return line 270 and the partial flow line 270b, whereas a possible excess of process water is conveyed into the line 170 emerging from the filtration unit 140b of the second stage 101b of the waste paper processing device 100, via the partial flow line 270a.
[0071] A completely closed process water circuit is possible in principle, but would possibly lead, in the long term, to concentrations of impurities, which would ultimately impair the efficiency of the system. A relatively small portion of fresh water, with respect to the amount of water evaporated in the drying part, is supplied continuously to the process, preferably the paper machine 200, via the fresh water supply line 280. It is possible, in the case of productions having particular requirements for a low content of impurities, such as salts, to remove a corresponding amount of process water from the process, via the process water line 300, and to clean it further using the material removal unit 305, the cooling unit 310 and the biological treatment unit 315, before said stream is conducted away in the public sewerage system or watercourse 400. Furthermore, the process water optionally conveyed away from the reject treatment units 118a, 118b, 212, as mentioned above, can also be removed from the process via the process water line 300, and cleaned by the material removal unit 305, the cooling unit 310, and the biological treatment unit 315, and returned to the process.
[0072] In
[0073] The anaerobic reactor 125a shown in
TABLE-US-00001 List of reference signs 100 waste paper processing device 101a first stage of the waste paper processing device 101b second stage of the waste paper processing device 102 raw material inlet 105 pulper 110a, 110b sorting device 112 oxidation unit/reduction unit 115a, 115b dewatering unit 116a, 116b process water processing unit of the material/waste paper processing device 118a, 118b reject treatment unit 120a, 120b material recovery unit 121a, 121b pre-acidification reactor 125a, 125b anaerobic reactor 126a, 126b solid-liquid separator/cyclone 127a, 127b discharge line 128a, 128b return line 129 line for supplying process water into the solid-liquid separator 130a, 130b chalk elimination unit 140a, 140b filtration unit 145a, 145b return line 170 line 170a partial flow line 200 paper machine 202 centrifugal sorter 204 fine sorting device 206 paper-machine mold part 208 paper-machine press part 210 drying part 212 reject treatment unit 214 fiber recovery unit 216 process water processing unit of the paper machine 220 material removal unit 221 pre-acidification reactor 225 anaerobic reactor 226 solid-liquid separator/cyclone 227 discharge line 228 return line 230 chalk elimination unit 240 filtration unit 270 return line 270a, 270b partial flow line 280 fresh water supply line 300 process water line 305 mechanical material removal unit 310 cooling unit 315 biological treatment unit 400 public watercourse 500 supply line 502 microorganism pellets 504 gas separator 506 liquid level 508 clearwater overflows 510 gas discharge line 512 discharge line for cleaned process water 514 cone/conical region 516 valve