Method for Controlling Humidity in a Fuel Cell

Abstract

A method for controlling humidity in a fuel cell, wherein hydrogen is fed at a nominal pressure to the inlet of the cell, characterized in that at predetermined periodicity the following steps are repeated: instruction is given to open a hydrogen purge valve arranged on the outlet of the anode circuit; the pressure of hydrogen is measured at the inlet to the anode circuit of the cell, and the measured value is compared with a threshold pressure value; the purge valve is closed when the measured pressure is equal to or lower than the predetermined threshold pressure value; the opening time of the purge valve is measured; and the humidity level prevailing at the cathode of the cell is inferred therefrom.

Claims

1. A method for controlling humidity in a fuel cell, wherein hydrogen is fed at a nominal pressure to the inlet of the cell and wherein, at predetermined periodicity, the following steps are repeated: instruction is given to open a hydrogen purge valve arranged on the outlet of the anode circuit; the pressure of hydrogen is measured at the inlet to the anode circuit of the cell, and the measured value is compared with a predetermined threshold pressure value; the purge valve is closed when the measured pressure is equal to or lower than the predetermined threshold pressure value; the opening time of the purge valve is measured; and the humidity level prevailing at the cathode of the cell is inferred therefrom.

2. The method according to claim 1, wherein operation of the cell is adjusted when the opening time of the purge valve exceeds a pre-set value.

3. The method according to claim 1, wherein a mean is computed of several successive values of the opening time of the purge valve to infer the humidity level therefrom.

4. The method according to claim 1, wherein feeding of hydrogen to the cell is obtained from a tank by means of a proportional solenoid valve driven by a pressure regulator connected to a pressure sensor.

5. The method according to claim 4, wherein that said pressure regulator is deactivated during the opening time of the purge valve.

6. The method according to claim 1, wherein the predetermined threshold pressure value is between 70 and 95% of the nominal pressure.

7. The method according to claim 1, wherein the nominal pressure value is between 1.2 and 2 bars.

8. The method according to claim 1, wherein said periodicity is adapted as a function of the opening time of the purge valve at a previous purge.

9. The method according to claim 1, wherein said periodicity is between 2 s and 20 s for an opening time of the purge valve of between 500 ms and 100 ms.

10. The method according to claim 1, wherein, when the purge valve is opened, the time is measured after which the predetermined threshold value is reached starting from nominal pressure, in that it is compared with a maximum value and in that it is inferred that the purge valve is jammed in the closed position if this time exceeds this maximum value.

11. The method according to claim 1, wherein, when the purge valve is closed, the time is measured after which the nominal pressure is reached starting from the predetermined threshold value and it is compared with a time interval, and in that it is inferred that the purge valve is jammed in the open position if this time exceeds this time interval.

12. The method according to claim 1, wherein when the opening time of the purge valve is below a threshold value, it is inferred that the humidity level prevailing at the cathode is within a range lower than a threshold value.

13. The method according to claim 1, wherein when the opening time of the purge valve is above a threshold value, it is inferred that the humidity level prevailing at the cathode is within a range higher than a threshold value, and the value of the humidity level is determined on the basis of an unambiguous relationship between opening time and humidity level.

14. A device comprising a purge valve, a pressure sensor, and a control unit of a fuel cell, wherein the electronic control unit is configured for implementing the method of claim 1.

Description

BRIEF DESCRIPTION OF THE FIGURES

[0033] The invention will be better understood on reading the remainder of the description given in connection with the following figures.

[0034] FIG. 1 is a schematic view of the device for implementing the method of the invention;

[0035] FIG. 2 is a graph illustrating changes in pressure as a function of time;

[0036] FIG. 3 is a graph illustrating the relationship between opening time of the purge valve and periodicity of purges;

[0037] FIG. 4 is a graph illustrating the relationship between the amount of liquid water at the anode and the humidity prevailing at the cathode of a fuel cell;

[0038] FIG. 5 is a graph illustrating the variation in purge time as a function of the humidity prevailing at the cathode of a fuel cell.

[0039] In the different figures, same or similar elements carry the same reference. The description thereof is therefore not systematically reproduced.

DETAILED DESCRIPTION OF PARTICULAR EMBODIMENTS

[0040] FIG. 1 schematically illustrates a device 100 for implementing the method of the invention, installed on the anode circuit 10 of a fuel cell 1. More specifically, FIG. 1 illustrates the topology of the anode circuit 10 of the cell between an inlet E for hydrogen, derived for example from a pressurized hydrogen tank (not illustrated) and an outlet S of the cell under atmospheric pressure. The fuel cell 1 is fed with hydrogen via a proportional solenoid valve 4. This solenoid valve is driven by a regulator 5 to maintain the pressure at the inlet 6 to the cell at a predetermined value. For this purpose, a pressure sensor 3 is installed on the anode circuit just before the hydrogen inlet 6 into the fuel cell 1, and it is connected to the input of the regulator 5. The regulator 5 is of the type generally known and operates by means of a pseudo-analogue signal of Pulse Width Modulation (PWM). More specifically, the measurement signal sent by the sensor 3 arrives at a comparator 50 of the regulator which receives a set value. The output value of the comparator 50 is transmitted to a control unit 51 of the regulator which actuates the proportional solenoid valve 4. The set pressure value P.sub.nom is generated by the fuel cell controller. It can be constant or adapted to operating conditions, for example as a function of the current produced by the fuel cell.

[0041] As can be seen in FIG. 1, on the anode circuit 10 after the cell outlet 7, there is arranged a purge solenoid valve 2 of «On/Off» type driven by a control unit of the cell (not illustrated). The purge 2 is preferably positioned at a low point of the outlet collector of the anode circuit so that it is able to drain the liquid water.

[0042] In one variant, not illustrated, means are added to the anode circuit 10 for the recirculation of hydrogen, for example comprising a Venturi ejector arranged between the proportional solenoid valve 4 and the pressure sensor 3, so as to recirculate part of the gas at the outlet 7 before the purge valve 2.

[0043] FIG. 2 is a graph illustrating the principle for measuring the opening time of the purge valve 2, the time values in seconds being given along the X-axis and the pressure values in bars along the Y-axis. Anodic pressure at the inlet 6 to the cell is regulated at a set pressure value P.sub.nom via the proportional valve 4 and the regulator 5. The cell control unit controls opening of the purge valve 2. As soon as the purge valve is opened at time to, a rapid decrease is observed in hydrogen pressure measured by the pressure sensor 3. When the pressure reaches the threshold P.sub.low, the purge valve 2 is closed. The opening time T of the purge valve, equalling t1−t0, is used by the computer as indicator of the presence of water at the anode. It is observed that the greater the amount of liquid water at the anode outlet the longer the time needed to reach pressure P.sub.low due to the very high viscosity or density of water and the time it takes to escape via the purge valve, compared with the situation in which only gas needs to be evacuated by this same purge valve. During the opening time of the purge valve 2, the instruction given by the pressure regulator 5 remains fixed at the value at the instant preceding the purge so that counter-reaction of the proportional valve 4 does not perturb pressure change during the purge. Immediately after the purge, the pressure regulator is released and again activates the proportional valve 4 for return to the target pressure P.sub.nom.

[0044] The purge time T is therefore automatically adapted to the amount of liquid water at the anode. The more water there is, the longer the time needed to reach pressure P.sub.low. The purge time will be automatically lengthened in the event of the presence of water, to tend towards compensating for the purge time during which the purge valve 2 was employed for the evacuation of water and not gas.

[0045] In the invention, the opening time of the purge valve T=t1−t0 is used to determine the humidity level at the cathode of the cell.

[0046] The water produced by a fuel cell normally occurs at the cathode. It is experimentally shown however that liquid water occurs at the anode outlet when the humidity at the cathode outlet is increased due to a back-diffusion phenomenon. In FIG. 4 the amount of water present at the anode is shown along the Y-axis by its volume flow rate D, measured in I/h, and the level of relative humidity (RH) is given along the X-axis, as measured in a laboratory at the cathode outlet of a proton-exchange membrane fuel cell (PEMFC) comprising 256 cells of 300 A. It is therefore noted that, on and after a certain threshold, the water flow rate at the anode outlet increases with the humidity present at the cathode. Up to 75% RH (relative humidity), there is little or no liquid water at the anode outlet, liquid water at the anode outlet starts to occur on and after this threshold and the amount of liquid water present at the anode is thereafter strongly increased. It is therefore ascertained that liquid water is not present at the anode outlet when the relative humidity measured at the cathode is equal to or lower than 75%. Yet this threshold of 75% RH is the level which corresponds to the recommended operation of a fuel cell.

[0047] As explained above, periodic purges are carried out at the anode outlet using the device in FIG. 1. According to the functioning of this device, the opening time of the purge valve 2 at the anode outlet is automatically adapted as a function of the amount of liquid water at the anode outlet. In the invention, the opening time of the purge valve 2 is measured and this is used as indicator of the presence of liquid water at the anode outlet. Next, according to the measured values of purge valve opening time, the amount of liquid water at the anode outlet can be inferred therefrom and the humidity level at the cathode of the fuel cell is determined.

[0048] For the same cell as the one used to plot the graph in FIG. 4, laboratory measurements were used to plot the values of the graph in FIG. 5. The Y-axis indicates the opening time in seconds of the purge valve 2 at the anode outlet, and the X-axis gives % relative humidity measured at the cathode outlet of the cell. It is observed that the opening time of the purge valve 2 is constant and less than 0.3 s when the relative humidity measured at the cathode is lower than 75%, i.e. for recommended cell operation. Therefore, when the opening time of the purge valve is less than 0.3 s, it can be inferred that the level of relative humidity prevailing at the cathode is less than 75%.

[0049] When the opening time of the purge valve 2 is longer than 0.3 s, the level of relative humidity prevailing at the cathode can be inferred from the graph in FIG. 5, to the right of the value of 75%. In this case, the information obtained is more precise than when the level of relative humidity is lower than 75%. From the opening time of the purge valve 2, not only can it be inferred that the relative humidity prevailing at the cathode is higher than 75%, but the value of this humidity level is also known.

[0050] The value of 75% indicated above is an example and may vary as a function of the structure and operating conditions of the fuel cell 1, in particular as a function of the number of cells in the stack. This value is a first threshold value S1.

[0051] Similarly, the value of 0.3 s is an example and may vary as a function of the structure and operating conditions of the fuel cell 1, in particular as a function of the number of cells in the stack. This value is a second pre-set threshold value S2.

[0052] In the event that the opening time is less than the threshold value S2, the deducing or determining of the humidity level lies within a range, namely between 0 and the threshold value S1, between 0 and 75% in the example.

[0053] In the event that the opening time is longer than the threshold value S2, the measured opening time of the purge valve 2 is between 0.3 and 0.5 s, the level of relative humidity at the cathode increases to reach about 90% RH and the humidity level is inferred or determined both within a range, namely above this threshold value S1, and precisely by means of the unambiguous relationship between RH level and opening time T as represented by the curve seen on the right of the threshold value S1=75% in FIG. 5.

[0054] In this case also, the opening time of the purge valve on the anode side is sent to the control unit of the cell which acts on the operating parameters thereof such as: humidification (when actively managed), pressure, stoichiometry or temperature or any other parameter able to modify the humidity level to obtain optimum operation. For example, in the event that the opening time of the purge valve is longer than the second purge value S2, the operating parameters of the fuel cell are adjusted.

[0055] In one variant, the control unit of the cell records the measured values of the opening time of the purge valve 2 over several successive measurements and then computes a mean of these values before taking a decision determined by the presence of liquid water at the anode. This allows the preventing of measurement noise on purge valve opening time.

[0056] In another advantageous aspect of the invention, in addition to automatic adapting of purge time, in the event of the presence of water, the time or period between two successive purges is also reduced for better compensation. FIG. 3 shows the relationship between the purge time T in seconds measured by the control unit of the cell and periodicity fin seconds applied between purges. It can be seen that the longer the purge time revealing the presence of increasing amounts of water, the shorter the intervals between successive purges to promote the evacuation of excess water and to ensure sufficient purging despite the presence of water. This mapping is predetermined by means of prior fine-tuned calibration to guarantee that the liquid water at the anode is sufficiently drained to prevent degradation of the cell, but without causing excess evacuation to prevent hydrogen wastage, under all the operating conditions of the fuel cell.

[0057] For example, the periodicity of purges may vary from 2 s to 20 s for an opening time respectively varying from 500 ms to 100 ms. The first purge is triggered by the control unit of the cell after a pre-set operating time, for example after a cell operating time of a few seconds. An output value (opening time of the purge valve) is then used to determine the periodicity of the following purges.

[0058] In one variant, a minimum opening time and a maximum opening time of the purge valve 2 can be defined, and these values can be stored in the memory of the cell control unit to detect faults (jamming of the purge valve 2 in the open or closed position, or a possible anomaly on the hydrogen circuit).

[0059] Alternatively, the coherency of pressure changes can be monitored at the inlet to the anode circuit. To detect jamming of the purge valve in the closed position, it can be verified whether or not the pressure value P.sub.low is reached after the maximum opening time. To detect jamming of the purge valve in the open position, the return to pressure P.sub.nom can be verified after closing the purge valve. Therefore, if during operation, the time measured to reach the pressure value P.sub.low after opening of the purge valve instructed by the control unit exceeds a pre-set maximum value, it can be inferred that there is jamming of the purge valve in the closed position. If the control unit gives instruction for closing of the purge valve starting from P.sub.low and the measured pressure does not reach P.sub.nom sufficiently quickly, within a pre-set time interval, it can be inferred that there is jamming of the purge valve in the open position. In this case, the control unit can display error messages corresponding to the detected anomaly.