Hydrogen gas compression system
11761586 · 2023-09-19
Assignee
Inventors
Cpc classification
F17C2225/0123
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2223/0123
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2221/012
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C2227/0164
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F17C5/06
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
International classification
B01D53/02
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A system for compressing hydrogen gas may include a compression stage with a water lubricated and sealed compressor, a gas-liquid separation stage, and a drying stage with an adsorption-type gas dryer. The system receives hydrogen gas via an inlet and discharges dry compressed hydrogen gas via an outlet. The system has an encapsulating vessel defining a cavity within which the separation stage and drying stage are located.
Claims
1. A hydrogen gas compression system comprising: a primary gas inlet through which to receive hydrogen gas; a compression stage having: an intake that receives gas from the primary gas inlet, at least one rotary compressor that has: a working chamber, one or more rotating elements housed internally of the working chamber that are driven via an input shaft to compress gas passing through the working chamber, and a liquid water inlet through which liquid water is delivered into the working chamber to provide lubrication to the rotating elements, and sealing of the working chamber, and a compression stage discharge that is in communication with the working chamber, through which to discharge a fluid stream containing at least compressed hydrogen gas and water; a separation stage that is in communication with the compression stage discharge and includes at least one separator that is configured to separate a liquid component from the fluid stream and thereby discharge a gas stream; a drying stage that is in communication with the separation stage and includes at least one adsorption-type gas dryer that is configured to adsorb and thereby remove water vapour from the gas stream; a primary gas outlet that is in communication with the drying stage, and through which to discharge dry compressed hydrogen gas; and an encapsulating vessel defining a cavity within which the separation stage and drying stage are located, the encapsulating vessel having a port in communication with the primary gas outlet.
2. The hydrogen gas compression system of claim 1, wherein at least the compression stage discharge of the compression stage is located within the cavity.
3. The hydrogen gas compression system of claim 1, wherein the encapsulating vessel is substantially hermetically sealed so that the cavity is isolated from the atmosphere.
4. The hydrogen gas compression system of claim 1, wherein the at least one rotary compressor includes a housing, and the vessel is configured to mate with the housing, and wherein the cavity is defined by the housing and the vessel.
5. The hydrogen gas compression system of claim 1, wherein the encapsulating vessel is configured to form a sump within which to collect the liquid component separated from the fluid stream in the separation stage, and the system further comprises a water return circuit that receives liquid water collected in the sump, and supplies the liquid water to the liquid water inlet of the compression stage.
6. The hydrogen gas compression system of claim 1, wherein the one or more rotating elements of the rotary compressor can be any of: a vane, a screw, a complementary twin screw pair, or a scroll.
7. The hydrogen gas compression system of claim 1, wherein the compression stage includes two or more rotary compressors that are assembled for sequential compression of hydrogen gas.
8. The hydrogen gas compression system of claim 1, further comprising a drive motor having an output shaft, and a non-contact coupling mounted between the drive motor output shaft and the input shaft.
9. The hydrogen gas compression system of claim 1, wherein the gas dryer contains desiccant material to adsorb water vapour from the gas stream.
10. The hydrogen gas compression system of claim 1, wherein the gas dryer is a pressure swing adsorption unit that has dual chambers each containing a bed of desiccant material, and valves to control the flow of the gas stream through the chambers such that in operation of the system each chamber alternately adsorbs water vapour from the gas stream into the desiccant material, and regenerates the desiccant material.
11. The hydrogen gas compression system of claim 10, wherein each of the chambers is a generally elongate chamber, and wherein the system is arranged with the longitudinal axes of the chambers being substantially parallel with the rotational axis of the input shaft.
12. The hydrogen gas compression system of claim 10, wherein the gas dryer is configured to regenerate the desiccant material by diverting a portion of the dry compressed hydrogen gas that is discharged from the drying stage to form a purge gas stream, and wherein the purge gas stream of the pressure swing adsorption unit is expanded to be approximately at the pressure at the intake, and then passed through the desiccant material to be regenerated.
13. The hydrogen gas compression system of claim 12, wherein the purge gas stream of the pressure swing adsorption unit is returned to the intake of the compression stage after passing through the desiccant material to be regenerated.
14. The hydrogen gas compression system of claim 1, wherein the separation stage includes a first separator that removes a first portion of liquid water from the fluid stream, and a second separator that removes a second portion of liquid water from the fluid stream, and wherein the first portion of liquid water is in a form having a size that is larger than a droplet size of the second portion of liquid water.
15. The hydrogen gas compression system of claim 1, wherein the separation stage includes a centrifugal-type separator that induces a vortex in the incoming fluid stream, and wherein centrifugal force within the vortex at least substantially separates at least a first portion of liquid water out of the fluid stream.
16. The hydrogen gas compression system of claim 1, wherein the separation stage includes a coalescing-type separator with at least one screen element through which to pass the fluid stream, whereby liquid water within the fluid stream coalesces on the surface of the screen element to thereby separate the fluid stream into coalesced liquid water and the gas stream, and wherein the coalesced liquid water forms a part of the liquid component that is separated from the fluid stream.
17. The hydrogen gas compression system of claim 1, further comprising a pressure boost stage that acts on one of the gas stream or the fluid stream, wherein the pressure boost stage includes a gas driven pressure booster that is configured to increase the pressure of the gas stream or the fluid stream passing therethrough.
18. The hydrogen gas compression system of claim 17, wherein exhausted drive gas is directed to a lower pressure point within the system, the lower pressure point being between the primary gas inlet and the pressure boost stage.
19. The system of claim 17, wherein the gas driven pressure booster is a dual action single stage booster.
20. The hydrogen gas compression system of claim 1, further comprising a deoxidation stage that is arranged to remove oxygen from the fluid stream, the deoxidation stage including a deoxidation vessel having a chamber and a catalyst within the chamber, wherein the catalyst is to remove oxygen molecules from the fluid stream.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) In order that the disclosure may be more easily understood, embodiments will now be described, by way of example only, with reference to the accompanying drawings, in which:
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DETAILED DESCRIPTION
(12)
(13) In this particular example, the system 10 includes a compression stage 16, a separation stage 18, and a drying stage 20.
(14) The compression stage 16, which is illustrated schematically in
(15) Liquid water is delivered into the working chamber 28 via a liquid water inlet 34 (which is shown schematically in
(16) A compression stage discharge 36 is in communication with the working chamber 28. The fluid stream is discharged via the compression stage discharge 36 into a pipe 38a that interconnects the compression stage 16 with the separation stage 18.
(17) The separation stage 18 includes at least one separator (discussed in further detail below) that is configured to separate liquid water from the fluid stream and thereby discharge a gas stream. A pipe 38b interconnects the separation stage 18 with the drying stage 20. The drying stage 20 includes at least one adsorption-type gas dryer (also discussed in further detail below) that is configured to adsorb and thereby remove water vapour from the gas stream.
(18) The primary gas outlet 14 is in communication with the drying stage 20. Thus, in use of the system 10, dry compressed hydrogen gas is discharged at the primary gas outlet 14.
(19) The system 10 illustrated in
(20) The inclusion of the separation stage 18 and drying stage 20 within the system 10 removes the liquid water, and then the water vapour, from the fluid stream that is discharged from the rotary compressor 24. Thus, the system 10 is able to provide hydrogen gas compressed to pressures in excess of 2 MPa (20 bar), and free of contaminant water.
(21) The system 10 includes an encapsulating vessel 40 with a cavity 42 to contain the separation stage 18 and drying stage 20. The encapsulating vessel 40 is hermetically sealed so that the cavity 42 is isolated from the surrounding atmosphere. In this particular example, the encapsulating vessel 40 mates with the housing 26 of the rotary compressor 24, such that the compression stage discharge 36 is located within the cavity 42. The encapsulating vessel 40 includes a removable lid 44 that closes an access opening in the vessel 40. In the illustrated embodiment, the lid 44 has the form of a cover plate. In some alternative embodiments, the removable lid 44 can be a domed cap or head.
(22) The bottom part of the cavity 42 within the encapsulating vessel 40 defines a sump 46 to collect liquid water that is removed from the fluid stream in the separation stage 18. Collected liquid water is illustrated within the sump 46 of the cavity 42.
(23) In use of the system 10, the head space of the cavity 42 is to be filled with hydrogen gas. This provides benefit in that propagation of gas into either the fluid stream or the gas stream from the cavity does not introduce contaminating material. Further, in use of the system 10, the head space of the cavity 42 is to be pressurized to a level that is approximately equal to the pressure of the dried compressed hydrogen gas at the primary gas outlet 14.
(24) The system 10 includes a water return circuit 48 that receives liquid water collected in the sump 46, and supplies that collected water to the liquid water inlet 34. In this way, the collected liquid water is reused by the rotary compressor 24. The water return circuit 48 can include a heat exchanger 50 to reduce the temperature of the water that is returned to the liquid water inlet 34.
(25) An overflow valve 52 is provided to the encapsulating vessel 40 to limit the quantity of liquid water within the sump 46 to a predetermined volume. In some examples, the overflow valve 52 can be mechanically actuated, such as a float valve. In some alternative examples, the overflow valve 52 can include a sensor that communicates with a pump to actively draw liquid water out from the sump 46.
(26) It should be appreciated that
(27) The system 10 includes a drive motor 54 having an output shaft 56. A non-contact coupling is mounted between the output shaft 56 and the input shaft 32 of the rotary compressor 24. In this example, the non-contact coupling is in the form of a magnetic coupling with a driving rotor 58 mounted on the output shaft 56, and a driven rotor 60 mounted on the input shaft 32. The coupling enables contactless torque transmission between the drive motor 54 and the rotary compressor 24. In addition, part of the housing 26 forms a containment shroud between the rotors 58, 60 of the coupling.
(28) The use of the non-contact coupling has the benefit of eliminating an opening in the housing of the rotary compressor for a shaft to transfer rotational motion from the drive motor to the rotating element. Hence, the need for a stuffing box in the housing is also eliminated.
(29) The drive motor 54 has a cooling fan 62 that is also mounted on the output shaft 56. The cooling fan 62 is on the opposing side of the motor housing to the driving rotor 58. The cooling fan 62 and heat exchanger 50 are arranged such that rotation of the cooling fan 62 pushes air through the heat exchanger 50 to increase the heat transfer rate of the heat exchanger 50.
(30) The separation stage 18 of this particular example is illustrated schematically in
(31) As stated previously, the fluid stream containing at least compressed hydrogen gas and water is discharged via the compression stage discharge 36. It is understood that in at least some embodiments, the water component in the fluid stream that is discharged from the compression stage 16 will include liquid water in a range of particle sizes. A portion of that liquid water are “droplets”, and another portion of that liquid are “aerosols”. For the purposes of this specification, the term “aerosols” is to be understood to refer to liquid water of particle sizes that are capable of forming a microscopic suspension of liquid droplets within hydrogen gas flow. Further, the term “droplets” is to be understood to refer to liquid water of particle sizes that are larger than “aerosols”. Without being bound to a specific size delineation, the particle size of aerosols is up to approximately 1,000 nanometres.
(32) Within the separation stage 18, the centrifugal-type separator 64 operates to remove water in droplet form from the fluid stream, and the coalescing-type separator 66 operates to remove water in aerosol form from the fluid stream. Hence, the first portion of liquid water that is removed by the centrifugal-type separator 64 is in a form having a size that is larger than the droplet size of the second portion of liquid water (which is removed by the coalescing-type separator 66).
(33) As shown in
(34) The coalescing-type separator 66 includes a screen element 70 through which the fluid stream is passed. Water aerosols in the fluid stream coalesce and/or are filtered by the screen element 70. To this end, liquid water within the fluid stream coalesces on the surface of the screen element 70. The gas fraction in the fluid stream passes through the screen element 70 and is discharged into the pipe 38b. Gravity draws the coalesced liquid water downward for discharge via a liquid discharge 72 of the coalescing-type separator 66.
(35) The gas fraction that is discharged into the pipe 38c forms a gas stream that includes hydrogen gas and water vapour. That gas stream progresses to the drying stage 20 of the system 10.
(36) As indicated in
(37) The drying stage 20 is illustrated schematically in
(38) Each of the chambers 76a, 76b has a generally elongate form. In this example, each chamber 76a, 76b is cylindrical. As indicated in
(39) The sets of valves 78a, 78b are to be operated to control the flow of the gas stream through the chambers 76a, 76b, such that in operation of the system 10 each chamber is alternately “online” (and so is adsorbing water vapour from the gas stream into the desiccant material), and “offline” (and so to regenerate the desiccant material). As is known in this type of gas dryer, the two chambers are maintained in opposing states.
(40) The gas dryer 74 regenerates the desiccant material in the offline chamber by diverting a portion of the dry compressed hydrogen gas that is discharged from the drying stage 20 to form a purge gas stream. Prior to passing through the offline chamber, the purge gas stream is expanded to be approximately at the pressure at the intake 22 of the rotary compressor 24. As is known to those having ordinary skill in the art, the expansion of the purge gas stream lowers the dew point of the purge gas stream, such that water in the desiccant material is taken up by the purge gas. The purge gas stream is returned to the low pressure side of the compression stage compression stage 16, as indicated in
(41) Operation of the valves in the sets of valves 78a, 78b is achieved by a pressurized gas control subsystem (not shown) that is part of the system 10. The gas control subsystem operates on the principles of pneumatic valve control, but does not use air for the control gas. In an example, the gas control subsystem can use hydrogen gas for the control gas. This has the advantage that any leaks from the gas control subsystem within the encapsulating vessel 40 only introduce hydrogen gas.
(42) In some alternatives, the gas control subsystem can utilize a control gas that is at least substantially inert with respect to hydrogen, and/or has a sufficiently high ionisation energy such that within the system and process operating parameters a reaction between the control gas and hydrogen is unlikely. Examples of such control gases include argon gas, and nitrogen.
(43) In the example illustrated in
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(45) It should be appreciated that the form and components of the electrolyser 202 has relevance to the compression and drying of the produced hydrogen gas. However, for the purposes of this disclosure, it is sufficient to note that the electrolyser 202 has a water inlet 204, a hydrogen gas outlet 206, and an off gas discharge 208. The electrolyser 202 receives liquid water via the water inlet 204 from an appropriate supply, and separates out hydrogen gas by an electrolysis process. To this end, an electrical current is applied to the liquid water to separate the water molecules into hydrogen gas and oxygen gas. The off gases, including oxygen gas, is passed through the off gas discharge 208 for appropriate management.
(46) The hydrogen gas outlet 206 supplies hydrogen gas to the primary gas inlet 12 of the system 10.
(47) The water return circuit 48 returns liquid water from the sump 46, released via the overflow valve 52, to merge with the liquid water at the water inlet 204. A check valve 210 can be installed in the water return circuit 48 to ensure appropriate direction of flow.
(48) It should be appreciated that the hydrogen gas that is produced by the electrolyser 202 can contain a water vapour fraction, due to the nature of the electrolysis process. Consequently, the hydrogen gas production facility 200 has a net positive flow of water vapour into the system 10. Water that is extracted by the system 10, as previously described, is returned for reprocessing by the electrolyser 202 and then the system 10.
(49) It may be necessary to implement a start-up procedure for the hydrogen gas production facility 200 that may involve charging the encapsulating vessel 40 with liquid water to fill the sump 46. It may also be necessary to charge the encapsulating vessel 40 with hydrogen gas and pressurize the cavity 42 to the operating pressure of the compression stage 16 at the compression stage discharge 36.
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(51) A dry compressed hydrogen gas remains after water vapour is removed at step 308. It should be appreciated that the system 10 implements the method 300.
(52) Liquid water and water vapour that are removed in steps 306 and 308 respectively can then be directed for reprocessing, as described previously with respect to the system 10 and in reference to
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(54) The system 110 includes a deoxidation stage 190 that is arranged to remove oxygen from the fluid stream. As shown in
(55) A pipe 138c interconnects the centrifugal-type separator 164 with the deoxidation vessel 192, and another pipe 138d interconnects the deoxidation vessel 192 with the coalescing-type separator 166.
(56) As should be apparent from
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(58) The compression stage 416 of the system 410 provides for multi-stage compression. In this example, two rotary compressors 424a, 424b sequentially compress the gas received from the primary gas inlet 412 at the intake 422 to the first stage rotary compressor 424a. The first stage rotary compressor 424a compresses gas to a first nominal pressure, and the second stage rotary compressor 424b compresses gas to a second nominal pressure. By way of indicative example only, the first nominal pressure can be in the range of 0.8 to 1.6 MPa (8 to 16 bar), and the second nominal pressure can be in the range of 3 to 6 MPa (30 to 60 bar).
(59) The system 410 includes a pressure boost stage 482 that is between the separation and drying stages 418, 420. It should be appreciated that the pressure boost stage 482 acts to increase the pressure of the gas stream prior to passing into the drying stage 420.
(60) The pressure boost stage 482 is illustrated schematically in further detail in
(61) The gas driven pressure booster 484 has a pair of compression chambers 486a, 486b between which is a central drive chamber 488. Within the central drive chamber 488 is a master piston 490. Each compression chamber 486a, 486b has a primary piston 492a, 492b that is connected with the master piston 490 by a rod.
(62) The gas driven pressure booster 484 also includes an induction manifold, a high-pressure discharge manifold, and an exhaust return manifold. It should be appreciated that the induction manifold, high-pressure manifold, and an exhaust return are shown schematically in
(63) The induction manifold is to direct gas from the pipe 438b to intake ports of each of the compression chambers 486a, 486b via check valves 494a, and to the central drive chamber 488 via a spool valve 496a. It should be appreciated that in operation of the system 410 the induction manifold receives hydrogen gas via the pipe 438b at approximately the second nominal pressure.
(64) The high-pressure manifold receives gas from exhaust ports of each of the compression chambers 486a, 486b, and directs the gas to the pipe 438d via check valves 494b.
(65) The exhaust return receives exhaust gas from the central drive chamber 488, through spool valve 496b, and is then arranged to return the exhaust gas through a return pipe 438r to merge with the fluid stream. In this example, the exhaust return merges the exhaust gas between the first and second stage rotary compressors 424a, 424b, as shown in
(66) By way of brief explanation, the spool valves 496a, 496b are configured to alternately define a pressure differential within the central drive chamber 488 and across the master piston 490. Accordingly, the master piston 490 reciprocates within the central drive chamber 488. A charge of gas is drawn into each compression chamber 486a, 486b from the induction manifold as the working volume in the corresponding compression chamber 486a, 486b is increasing. Within the opposing compression chamber 486b, 486a, gas is compressed to a third nominal pressure as the working volume decreases. The check valves 494b open to release the compressed gas stream into the pipe 438d at the third nominal pressure.
(67) As is known to those having ordinary skill in the art, the ratio between the area of the master piston 490 and the primary pistons 492 is proportional to the maximum compression ratio of the gas driven pressure booster 484.
(68) In the illustrated example, the pressure boost stage 482 is positioned between the separation and drying stages 418, 420. This is beneficial in that the gas stream is to be free of liquid water. Hence, the operation of the gas driven pressure booster 484 is unlikely to be compromised by the presence of liquid in the gas stream. Some alternative examples may have a pressure boost stage that receives dried compressed hydrogen gas from the drying stage (and hence is positioned between the drying stage and the primary gas outlet).
(69) In one example, the maximum compression ratio of the gas driven pressure booster 484 is at least 2:1. Accordingly, the third nominal pressure at the pipe 438d can be in excess of 6 MPa. In another example, the maximum compression ratio of the gas driven pressure booster 484 is 2.5:1, such that system 410 operates with the third nominal pressure at the pipe 438d being in the range of approximately 7.5 to 15 MPa.
(70) It should be appreciated that the pressure of the compressed hydrogen gas at the primary gas outlet 414 of the system 410 can be further increased by including additional compression stages within the compression stage 416.
(71) Throughout this specification and the claims which follow, unless the context requires otherwise, the word “comprise”, and variations such as “comprises” and “comprising”, should be understood to imply the inclusion of a stated integer or step or group of integers or steps but not the exclusion of any other integer or step or group of integers or steps.
(72) The reference in this specification to any prior publication (or information derived from it), or to any matter which is known, is not, and should not be taken as an acknowledgment or admission or any form of suggestion that that prior publication (or information derived from it) or known matter forms part of the common general knowledge in the field of endeavour to which this specification relates.