LOW DIALECTRIC, HIGH HEAT-DISSIPATION LIQUID CRYSTAL POLYMER COMPOSITION FOR MILLIMETER WAVE BAND, AND METHOD FOR PRODUCING SAME

Abstract

Proposed is a dielectric material of a liquid-crystal polymer composition including a low-dielectric and high-heat-dissipating liquid-crystal-material monomer for a millimeter wave band and a polymer thereof, and more particularly, a liquid-crystal polymer composition including a low-dielectric and high-heat-dissipating liquid-crystal-material monomer for a millimeter wave band and a polymer thereof, the liquid-crystal-material monomer including a mesogen core, a silane-based group, and a polymerization reactive group.

Claims

1. A low-dielectric and high-heat-dissipating liquid-crystal-material monomer for a millimeter wave band, comprising one or more of a rod-shaped or plate-shaped mesogen core (C), a silane-based group (S), and a polymerization reactive group (F).

2. The low-dielectric and high-heat-dissipating liquid-crystal-material monomer for the millimeter wave band of claim 1, wherein the one or more of the rod-shaped or plate-shaped mesogen core (C), the silane-based group (S), and the polymerization reactive group (F) is one of types i) to v): i) a type including the mesogen core (C) and the silane-based group (S); ii) a type including the mesogen core (C), the silane-based group (S), and the polymerization reactive group (F); iii) a type including the mesogen core (C) and the polymerization reactive group (F); iv) a type including the silane-based group (S); and v) a type including the silane-based group (S) and the polymerization reactive group (F).

3. The low-dielectric and high-heat-dissipating liquid-crystal-material monomer for the millimeter wave band of claim 1, wherein the rod-shaped or plate-shaped mesogen core (C) is one or more of structures of Formulae 1 to 27, and the silane-based group (S) and/or the polymerization reactive group (F) are bonded to one or more of bondable positions of the rod-shaped or plate-shaped mesogen core (C): ##STR00015## ##STR00016## ##STR00017## ##STR00018##

4. The low-dielectric and high-heat-dissipating liquid-crystal-material monomer for the millimeter wave band of claim 1, wherein the silane-based group (S) is one or more of structures of Formulae 28 to 33, and the mesogen core (C) and/or the polymerization reactive group (F) are bonded to position of one or more substituents (“-”) represented in the silane-based group (S): ##STR00019##

5. The low-dielectric and high-heat-dissipating liquid-crystal-material monomer for the millimeter wave band of claim 1, wherein the polymerization reactive group (F) is one or more of structures of Formulae 34 to 43, and the mesogen core (C) and/or the silane-based group (S) are bonded to position of substituent R represented in the polymerization reactive group (F): ##STR00020##

6. The low-dielectric and high-heat-dissipating liquid-crystal-material monomer for the millimeter wave band of claim 1, wherein each of the mesogen core (C), the silane-based group (S), and the polymerization reactive group (F) comprises a linking group (A) of hydrocarbon including a heteroatom, the linking group (A) has a structure of “—(CH2)n-X—”, where n is an integer from 1 to 12, X is one or more of groups consisting of —O—, —S—, —SO2-, —NH—, —NHC(O)—, and —OC(O)—, and when the heteroatom of the linking group (A) is identical to a heteroatom included in the polymerization reactive group (F), both identical heteroatoms are positioned so as not to be linked consecutively.

7. A liquid-crystal polymer composition for a millimeter wave band, comprising a polymer of the low-dielectric and high-heat-dissipating liquid-crystal-material monomer for the millimeter wave band of claim 1.

8. The liquid-crystal polymer composition for the millimeter wave band of claim 7, wherein the polymer is a homopolymer of the monomer including one or more of a rod-shaped or plate-shaped mesogen core (C), a silane-based group (S), and a polymerization reactive group (F), a copolymer including two or more types of the monomer, or a mixture of the homopolymer and the copolymer.

9. A liquid-crystal polymer composition for a millimeter wave band, comprising a polymer of the low-dielectric and high-heat-dissipating liquid-crystal-material monomer for the millimeter wave band of claim 2.

10. The liquid-crystal polymer composition for the millimeter wave band of claim 9, wherein the polymer is {circle around (1)} a copolymer of two or more liquid-crystal-material monomers among liquid-crystal-material monomers of the types i) to v), {circle around (2)} a homopolymer in which the liquid-crystal-material monomers of the types i) to v) are independently polymerized, or {circle around (3)} a mixture of the copolymer and the homopolymer.

11. The liquid-crystal polymer composition for the millimeter wave band of claim 7, wherein the polymer has a weight-average molecular weight of 1,000 to 100,000.

12. A low-dielectric material produced by using the liquid-crystal polymer composition for the millimeter wave band of claim 7.

13. A low-dielectric material produced by using the liquid-crystal polymer composition for the millimeter wave band of claim 8.

14. A low-dielectric material produced by using the liquid-crystal polymer composition for the millimeter wave band of claim 9.

15. A low-dielectric material produced by using the liquid-crystal polymer composition for the millimeter wave band of claim 10.

16. A low-dielectric material produced by using the liquid-crystal polymer composition for the millimeter wave band of claim 11.

Description

DESCRIPTION OF DRAWINGS

[0025] FIG. 1 shows a structure of a liquid-crystal-material monomer of the present invention.

[0026] FIG. 2 shows NMR of a liquid-crystal-material monomer synthesized according to an embodiment of the present invention.

[0027] FIG. 3 is a graph showing permittivity and dielectric loss, which are dielectric characteristics, of a liquid-crystal-material monomer synthesized according to an embodiment of the present invention.

[0028] FIG. 4 shows NMR of a liquid-crystal-material monomer synthesized according to an embodiment of the present invention.

[0029] FIG. 5 shows NMR of a liquid-crystal-material monomer synthesized according to an embodiment of the present invention.

[0030] FIG. 6 shows NMR of a liquid-crystal-material monomer synthesized according to another embodiment of the present invention.

[0031] FIG. 7 shows NMR of a liquid-crystal-material monomer synthesized according to an embodiment of the present invention.

[0032] FIG. 8 shows dielectric characteristics of a low-dielectric and high-heat-dissipating film made of a liquid-crystal polymer composition including a liquid-crystal-material monomer synthesized according to an embodiment of the present invention.

MODE FOR INVENTION

[0033] Hereinafter, preferred embodiments of the present invention will be described in detail. In describing the present invention, in a case where it is determined that a detailed description of the related known art may obscure the gist of the present invention, the detailed description will be omitted. Throughout the specification, when a portion “includes” an element, another element may be further included, rather than excluding the existence of the other element, unless otherwise described. In addition, certain features presented in the drawings are enlarged, reduced, or simplified for ease of explanation, and the drawings and their elements are not necessarily drawn to scale. However, those skilled in the art will readily understand these details.

[0034] In addition, embodiments of the present invention are not intended to be limited to specific embodiments, and should be understood to include all transformations, equivalents, or substitutes included in the spirit and scope of the present invention.

[0035] The present invention relates to a liquid-crystal-material monomers including one or more of a rod-shaped or plate-shaped mesogen core (C), a silane-based group (S), and a polymerization reactive group (F), and a liquid-crystal polymer composition including a polymer of liquid-crystal-material monomers.

[0036] The liquid-crystal-material monomer including one or more of the rod-shaped or plate-shaped mesogen core (C), the silane-based group (S), and the polymerization reactive group (F) may specifically be of: [0037] i) a type including the mesogen core (C) and the silane-based group (S) (Type 1 below); [0038] ii) a type including the mesogen core (C), the silane-based group (S), and the polymerization reactive group (F) (Type 2 below); [0039] iii) a type including the mesogen core (C) and the polymerization reactive group (F) (Type 3 below); [0040] iv) a type including the silane-based group (S) (Type 4 below); or [0041] v) a type including the silane-based group (S) and the polymerization reactive group (F) (Type 5 below).

##STR00002##

[0042] In addition, the polymer of the liquid-crystal-material monomers may be [0043] {circle around (1)} a copolymer of two or more liquid-crystal-material monomers among liquid-crystal-material monomers of the types i) to v), [0044] {circle around (2)} a homopolymer in which the liquid-crystal-material monomers of the types i) to v) are each independently polymerized, or [0045] {circle around (3)} a mixture of the copolymer and the homopolymer.

[0046] Polymerization of the polymer is carried out by heat, ultraviolet rays, chemicals, or the like by using a reaction, such as radical polymerization, condensation polymerization, cyclopolymerization, or ionic polymerization, and in the types of i) to v), the silane-based group (S) and the polymerization reactive group (F) may undergo a polymerization reaction at each position.

[0047] In addition, the copolymer and the homopolymer may form a polymer network by connecting polymerization reactive groups (F) of the liquid-crystal-material monomers of i) to v) together in the form of a chain derivative.

[0048] In addition, the homopolymer or the copolymer has a weight-average molecular weight of 1,000 to 100,000, preferably, 2,000 to 30,000.

[0049] Specifically, the rod-shaped or plate-shaped mesogen core (C) may be one or more of structures of Formulae 1 to 27, and the silane-based group (S) and/or the polymerization reactive group (F) may be bonded to one or more of bondable positions of the rod-shaped or plate-shaped mesogen core (C).

##STR00003## ##STR00004## ##STR00005## ##STR00006##

[0050] The silane-based group (S) may specifically be one or more of structures of Formulae of 28 to 33, and the mesogen core (C) and/or the polymerization reactive group (F) may be bonded to position of one or more substituents (“-”) represented in the silane-based group (S).

##STR00007##

[0051] The polymerization reactive group (F) may specifically be one or more of structures of Formulae 34 to 43, and the mesogen core (C) and/or the silane-based group (S) may be bonded to position of substituent R represented in the polymerization reactive group (F).

##STR00008##

[0052] In addition, each of the mesogen core (C), the silane-based group (S), and the polymerization reactive group (F) may include a linking group (A) of hydrocarbon including a heteroatom, and structures of the mesogen core (C), the silane-based group (S), and the polymerization reactive group (F) of the liquid-crystal-material monomer of the liquid-crystal-material monomers of the types i) to v) may be connected to each other by using the linking group (A) of the hydrocarbon including the heteroatom.

[0053] The linking group (A) has a structure of “—(CH2)n-X—”, n is an integer from 1 to 12, X is one or more of groups consisting of —O—, —S—, —SO2-, —NH—, —NHC(O)—, and —OC(O)—, and when the heteroatom of the linking group (A) is identical to a heteroatom of the polymerization reactive group (F), both identical heteroatoms are positioned so as not to be linked consecutively.

[0054] Examples of the liquid-crystal-material monomers of the types i) to v) are Formulae 44, 45, 46, and 47, the following structures are merely examples of the liquid-crystal-material monomers of the types i) to v), and the liquid-crystal-material monomers of the types i) to v) of the present invention are not limited to the following structures.

##STR00009##

[0055] Hereinafter, dielectric characteristics of a low-dielectric and heat-dissipating film as a low-dielectric material using a liquid-crystal-material monomer according to an embodiment of the present invention, synthesis of a polymer including the same, and a liquid-crystal polymer composition including the polymer will be described.

EXAMPLE 1

1. Synthesis of Liquid-Crystal-Material Monomer: Compound 1

[0056] In order to produce a low-dielectric and heat-dissipating film as a dielectric material, Compound 1 as a liquid-crystal-material monomer including a polymerization reactive group in a rod-shaped mesogen core was synthesized by the following method.

##STR00010##

[0057] 8-(4-(6-((8-hydroxyoctyl)oxy)naphthalen-2-yl) phenoxy)octan-1-ol (4.3 mmol) and 30 ml of DCM were placed in a round flask and then stirred. Methacryloyl chloride (8.6 mmol) and 1.2 ml of trimethylamine were added to a reactor and then stirred at room temperature for 12 hours. After completion of the reaction, impurities were removed by using 5% sodium chloride (400 ml), followed by recrystallization by using methanol. After the recrystallization, a precipitate was filtered by using a filter, followed by column chromatography by using ethyl acetate and hexane at a ratio of 1:3. Afterwards, a solvent was removed, followed by recrystallization by using ethanol, and then a precipitate was filtered through a filter to synthesize 6-(4-(6-((6-(methacyloyloxy)hexyl)oxy) naphthalen-2-yl) phenoxy)hexyl methacrylate (Compound 1).

[0058] As a result of analyzing Compound 1 by nuclear magnetic resonance spectroscopy, it was found that the synthesis was successful without impurities (see FIG. 2).

2. Permittivity and Dielectric Loss of Low-Dielectric Material 1 Produced by Using Liquid-Crystal-Material Monomer of Formula 1

[0059] In order to produce low-dielectric and heat-dissipating film by using Compound 1, Compound 1 was placed on a glass substrate, and a temperature was raised to an isotropic-phase temperature of 200° C. to induce a liquid phase. Afterwards, another glass substrate was placed thereon as a cover, followed by curing for 1 hour at a liquid-crystal-phase temperature of 160° C. Afterwards, the glass substrate was etched by using hydrofluoric acid to obtain a polymer film (low-dielectric material 1).

[0060] FIG. 3 shows a result of measuring permittivity and dielectric loss of the polymer film from the 1.0 GHz band to the 9.4 GHz band. As a result of measuring the permittivity, the permittivity was about 2.3, showing excellent low-permittivity characteristics, and as a result of measuring the dielectric loss, the dielectric loss was about 0.028. In particular, it was found that the permittivity was significantly lower than the highest level (permittivity of 2.9 by liquid-crystal polymers of the related art) currently commercialized.

EXAMPLE 2

1. Synthesis of Liquid-Crystal-Material Monomer: Compound 2

[0061] Compound 2 as a liquid-crystal-material monomer including a silane-based group in a rod-shaped mesogen core was synthesized by the following method.

##STR00011##

[0062] 1.9 ml of 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane, 2,6-bis(allyloxyl)naphthalene (2.08 mmol), and 2,2-dimethoxy-2-phenylacetophenone (0.06 mmol) as a photoinitiator was placed in a round flask, and then a trace of tetrahydrofuran was added thereto to such an extent as to dissolve a reactant, followed by exposure to light for 1 hour under nitrogen. After completion of the reaction, 10 ml of tetrahydrofuran and potassium tert-butoxide (0.86 mmol) were further added thereto, followed by stirring for 24 hours at room temperature. Next, after titration in a beaker containing 2N HCl (125 ml), impurities were removed by using ethyl acetate and water. Column chromatography was carried out by using chloroform to synthesize Compound 2.

[0063] As a result of analyzing Compound 2 by nuclear magnetic resonance spectroscopy, it was found that the synthesis was successful without impurities (see FIG. 4).

EXAMPLE 3

1. Synthesis of Liquid-Crystal-Material Monomer: Compound 3

[0064] Compound 3 as a liquid-crystal-material monomer including a polymerization reactive group in a rod-shaped mesogen core was synthesized by the following method.

##STR00012##

[0065] Naphthalene-2,6-diol (2 g), allyl bromide (4.3 ml), potassium carbonate (10.4 g), and dimethylformamide (30 ml) were placed in a round flask and then stirred for 24 hours. After completion of the reaction, impurities were removed by using ethyl acetate and water. Recrystallization was carried out by using hexane to synthesize Compound 3.

[0066] As a result of analyzing Compound 3 by nuclear magnetic resonance spectroscopy, it was found that the synthesis was successful without impurities (see FIG. 5).

EXAMPLE 4

1. Synthesis of Liquid-Crystal-Material Monomer: Compound 4

[0067] Compound 4 as a liquid-crystal-material monomer including a silane-based group in a rod-shaped mesogen core was synthesized by the following method.

##STR00013##

[0068] 30 ml of tetrahydrofuran was added to 1,4-dibromobenzene (6.9 g) and magnesium (1.3 g) in a round flask. After 0° C. condition was formed, dimethylsilyl chloride (5.1 g) was dissolved in 20 ml of tetrahydrofuran, then slowly placed in a flask to be stirred for 14 hours. Next, an extraction process was carried out by using hexane, and synthesis was completed through distillation.

[0069] As a result of analyzing Compound 4 by nuclear magnetic resonance spectroscopy, it was found that the synthesis was successful without impurities (see FIG. 6).

EXAMPLE 5

1. Polymer 1 of Liquid-Crystal-Material Monomer

[0070] In order to produce a low-dielectric and heat-dissipating film as a dielectric material using a liquid-crystal polymer composition, polymer 1 including a rod-shaped mesogen core, a silane-based group, and a polymerization reactive group, as a polymer included in the liquid-crystal polymer composition, was synthesized by the following method.

##STR00014##

[0071] A mixture of Compound 3 (5 g), karstedt's catalyst in xylene (0.13 ml), Compound 4 (4.4 ml), and 100 ml of toluene in a round flask was stirred at 100° C. for 24 hours. After completion of the reaction, a celite filter was carried out, and a precipitate was collected by using methanol. The precipitate was filtered and dried to obtain Compound 5. In Compound 5, n was 35, and a weight-average molecular weight was about 15,000.

[0072] As a result of analyzing Compound 5 by nuclear magnetic resonance spectroscopy, it was found that the synthesis was successful without impurities (see FIG. 7).

2. Permittivity and Dielectric Loss of Low-Dielectric Material 2 Produced by Using Liquid-Crystal Polymer Composition Including Polymer 1

[0073] In order to produce a low-dielectric and heat-dissipating film by using polymer 1, a PDMS mold was manufactured to obtain a rectangular polymer film (low-dielectric material 2) at 150° C.

[0074] FIG. 8 shows a result of measuring permittivity and dielectric loss of the polymer film from the 1.0 GHz band to the 9.4 GHz band. As a result of measuring the permittivity, the permittivity was about 2.4, showing excellent low-permittivity characteristics, and as a result of measuring the dielectric loss, the dielectric loss was about 0.0-5. In particular, it was found that the permittivity was significantly lower than the highest level (permittivity of 2.9 by liquid-crystal polymers of the related art) currently commercialized.

[0075] As described above, by using a low-dielectric and high-heat-dissipating liquid-crystal-material monomer and a liquid-crystal polymer composition including a polymer thereof, it is possible to develop low-dielectric materials that may be used not only for next-generation high-speed communication antennas and millimeter wave radars for 5G and 6G, but also for communication convergence services, such as self-driving cars, healthcare, and smart cities.

[0076] Hereinbefore, specific parts of the present invention is described in detail, and for those skilled in the art, it will be clear that these specific descriptions are merely preferred embodiments, and the scope of the present invention is not limited thereby. Accordingly, the substantial scope of the present invention will be defined by the appended claims and their equivalents.

[0077] The present invention is filed with the support of the following project described in Table 1.

TABLE-US-00001 TABLE 1 National Research and Development Program Supporting This Invention Serial Number 2020M3D1A2100779 Department Name Ministry of Science and ICT Research Managing National Research Foundation of Korea (NRF) Organization Title of Research Innovative Technology Development Program for Material Fusion Title of Research Development of low-dielectric and high-heat- Project dissipating liquid-crystal polymer film for 5G FCCL Host Organization Jeonbuk National University Research Period Jul. 23, 2020-Dec. 31, 2023