METHOD OF INCREASING THE STRENGTH AND/OR HARDNESS OF A GLASS ARTICLE

Abstract

The invention relates to methods of increasing the strength, especially the flexural strength, of a glass article produced from a glass material. The method includes the step of heating the glass article to a first temperature above the transformation temperature of the glass material, the step of shock cooling the glass article to a second temperature below the transformation temperature of the glass material, and the step of performing an ion exchange process at the second temperature.

Claims

1. A method for increasing the strength, more particularly the bending fracture strength, of a glass article produced from a glass material, specifically alkali metal-alkaline earth metal silicate glass or borosilicate glass, characterized by steps as follows: a. heating of the glass article to a first temperature which lies above the transition temperature of the glass material, b. shock cooling of the glass article to a second temperature which lies below the transition temperature of the glass material, the shock cooling taking place by contacting of the glass article with a cooling agent which has the second temperature, c. performing an ion exchange process at the second temperature for a period in the range from 15 minutes to 45 minutes.

2. The method as claimed in claim 1, characterized in that the first temperature lies in a range from 100 kelvins to 300 kelvins above the transition temperature.

3. The method as claimed in claim 1, characterized in that the first temperature lies in a range from 50 kelvins below to 30 kelvins above the Littleton softening point of the glass material.

4. The method as claimed in claim 1, characterized in that the glass article is heated in such a way that the initial heating rate is 100 kelvins per minute, more particularly more than 250 kelvins per minute.

5. The method as claimed in claim 1, characterized in that the shock cooling is performed without delay as soon as the glass article has reached the first temperature, or in that the shock cooling is performed with a delay of not more than one minute after the glass article has reached the first temperature.

6. The method as claimed in claim 1, characterized in that the glass article for heating is transferred into a kiln.

7. The method as claimed in claim 6, characterized in that the kiln has a kiln temperature which lies above the first temperature or in that the kiln has a kiln temperature which lies in a range from 10 kelvins to 40 kelvins above the first temperature.

8. The method as claimed in claim 1, characterized in that the glass article has a thickness and in that the glass article remains in the kiln for a heating time in the range from 35 seconds to 45 seconds per millimeter of thickness, more particularly for a heating time of 40 seconds per millimeter of thickness.

9. The method as claimed in claim 1, characterized in that the glass article is a hollow body with walls which have a wall thickness, and in that the glass article remains in the kiln for a heating time in the range from 35 seconds to 45 seconds per millimeter of wall thickness, more particularly for a heating time of 40 seconds per millimeter of wall thickness.

10. The method as claimed in claim 1, characterized in that the second temperature lies in a range from 50 kelvins to 200 kelvins below the transition temperature.

11. The method as claimed in claim 1, characterized in that the cooling agent is a liquid or a suspension.

12. The method as claimed in claim 1, characterized in that the shock cooling takes place by immersion of the glass article in a cooling bath which contains the cooling agent, or by spraying or by sprinkling with the cooling agent.

13. The method as claimed in claim 1, characterized in that the first temperature and the cooling agent temperature of the cooling agent are selected in such a way that the initial cooling rate is in the range from 80 kelvins to 120 kelvins per second, more particularly in the range from 90 kelvins to 110 kelvins per second, or is 100 kelvins per second.

14. The method as claimed in claim 1, characterized in that the ion exchange process comprises removing ions, more particularly alkali metal ions, very particularly sodium ions, from the glass article and replacing them by spatially larger ions, more particularly alkali metal ions, very particularly potassium ions.

15. The method as claimed in claim 1, characterized in that the ion exchange process comprises contacting the glass article with an exchange agent, more particularly with an exchange agent which has the second temperature.

16. The method as claimed in claim 15, characterized in that the exchange agent is used in the form of an exchange salt melt or in the form of a suspension or paste containing an exchange salt.

17. The method as claimed in claim 16, characterized in that the exchange salt is potassium nitrate or comprises potassium nitrate.

18. The method as claimed in claim 16, characterized in that contacting of the glass article with the exchange agent takes place by immersion or by spraying or by sprinkling.

19. The method as claimed in claim 15, characterized in that the cooling agent is at the same time also the exchange agent.

20. The method as claimed in claim 1, characterized in that the ion exchange process is performed for a period in the range from 20 minutes to 40 minutes.

21. The method as claimed in claim 1, characterized in that the glass material is not aluminosilicate glass.

22. The method as claimed in claim 1, characterized in that the glass material has an aluminum oxide fraction of less than 5% (percent by mass), more particularly of less than 4.5% (percent by mass).

23. The method as claimed in claim 1, characterized in that the glass material has a silicon dioxide fraction of more than 58% (percent by mass) and of less than 85% (percent by mass), more particularly of more than 70% (percent by mass) and of less than 74% (percent by mass).

24. The method as claimed in claim 1, characterized in that the glass material has an alkali metal oxide fraction, more particularly sodium oxide fraction and/or lithium oxide fraction, in the range from 5% (percent by mass) to 20% (percent by mass), more particularly in the range from 10% (percent by mass) to 14.5% (percent by mass) or in the range from 12% (percent by mass) to 13.5% (percent by mass).

25. The method as claimed in claim 1, characterized in that the glass material has a potassium oxide fraction of at most 7% (percent by mass), more particularly of at most 3% (percent by mass) or of at most 1% (percent by mass), or in that the glass material has a potassium oxide fraction in the range from 0.5% (percent by mass) to 0.9% (percent by mass).

26. The method as claimed in claim 1, characterized in that the glass material has a boron trioxide fraction of less than 15% (percent by mass), more particularly of at most 5% (percent by mass).

27. A glass article produced by means of a method as claimed in claim 1.

28. The glass article as claimed in claim 27, characterized in that the glass article is embodied as a hollow body, more particularly a drinking glass, a vase, a tumbler, a bowl or a bottle.

29. The glass article as claimed in claim 27, characterized in that the glass article is embodied as a dishware article, more particularly as a plate.

30. The glass article as claimed in claim 27, characterized in that the glass article is embodied as a flat glass sheet.

Description

BRIEF DESCRIPTION OF THE DRAWING VIEWS

[0054] In the drawing, the subject matter of the disclosure is represented illustratively and schematically and is described below with reference to the figures, where elements that are the same or have the same effect, even in different exemplary embodiments, are usually provided with the same reference signs. In the figures,

[0055] FIG. 1 shows a representation of the method of the disclosure in relation to the different temperatures during its implementation, and

[0056] FIG. 2 shows a representation of the temperature conditions during the implementation of an exemplary embodiment of a method of the disclosure.

DETAILED DESCRIPTION

[0057] FIG. 1 shows schematically a representation, which not true to scale, of the temperature conditions when the method of the disclosure is performed for increasing the strength, more particularly the bending fracture strength, of a glass article produced from a glass material.

[0058] In a first step, there is heating 1 of the glass article from a starting temperature T.sub.A, which may for example be the room temperature, to a first temperature T.sub.1, which lies above the transition temperature T.sub.g of the glass material of the glass article. The first temperature T.sub.1 preferably lies in a first range 3 from 100 kelvins to 300 kelvins above the transition temperature T.sub.g of the glass material.

[0059] In a second step, there is shock cooling 2 of the glass article to a second temperature T.sub.2, which lies below the transition temperature T.sub.g of the glass material. The second temperature lies preferably in a second range 4 from 50 kelvins to 200 kelvins below the transition temperature T.sub.g.

[0060] The shock cooling 2 is accomplished preferably by contacting with a cooling agent which has the second temperature T.sub.2 and which at the same time is also an exchange agent for the third step (not represented) of the performance of an ion exchange process at the second temperature T.sub.2.

[0061] The ion exchange process is preferably performed for a period in the range from 15 minutes to 300 minutes, more particularly in the range from 20 minutes to 40 minutes, more particularly for around 30 minutes.

[0062] FIG. 2 shows schematically a representation, which is not true to scale, of the temperature conditions when performing an exemplary embodiment of a method of the disclosure for increasing the strength, more particularly the bending fracture strength, of a glass article produced from soda-lime glass.

[0063] In a first step, there is heating 1 of the glass article from a starting temperature T.sub.A, which may for example be 20° C., in a kiln (not represented), to a first temperature T.sub.1 of 745° C., which lies above the transition temperature T.sub.g of 530° C. of the glass material of the glass article.

[0064] In a second step there follows directly shock cooling 2 of the glass article to a second temperature T2, which is 420° C. The shock cooling 2 is accomplished by immersing the glass article in a cooling bath (not represented), which as cooling agent comprises a salt melt of potassium nitrate. The salt melt has a temperature of 420° C.

[0065] At the same time the salt melt is also the exchange agent for the third step (not represented), of performing an ion exchange process, which is performed at the second temperature T.sub.2 of 420° C. For this, the glass article is left in the salt melt for a period in the range from 15 minutes to 300 minutes, more particularly in the range from 20 minutes to 40 minutes, more particularly for around 30 minutes.

[0066] Thereafter the glass article is removed from the cooling bath and cooled further to room temperature in a cooling position outside the cooling bath, and is finally cleaned.

LIST OF REFERENCE SIGNS

[0067] 1 Heating [0068] 2 Shock cooling [0069] 3 First region [0070] 4 Second region [0071] T.sub.1 First temperature [0072] T.sub.2 Second temperature [0073] T.sub.A Starting temperature [0074] T.sub.g Transition temperature