METHOD OF RECYCLING A STRUCTURE OR AT LEAST A PORTION THEREOF, AND COMPONENT FOR AN AIRCRAFT OR SPACECRAFT
20230311206 · 2023-10-05
Inventors
Cpc classification
B33Y70/00
PERFORMING OPERATIONS; TRANSPORTING
B22F9/04
PERFORMING OPERATIONS; TRANSPORTING
B22F1/12
PERFORMING OPERATIONS; TRANSPORTING
B22F2999/00
PERFORMING OPERATIONS; TRANSPORTING
C22B21/0069
CHEMISTRY; METALLURGY
B22F2998/10
PERFORMING OPERATIONS; TRANSPORTING
B33Y80/00
PERFORMING OPERATIONS; TRANSPORTING
B22F1/142
PERFORMING OPERATIONS; TRANSPORTING
B22F8/00
PERFORMING OPERATIONS; TRANSPORTING
B22F1/142
PERFORMING OPERATIONS; TRANSPORTING
C22B21/0092
CHEMISTRY; METALLURGY
B22F10/28
PERFORMING OPERATIONS; TRANSPORTING
B22F1/12
PERFORMING OPERATIONS; TRANSPORTING
B22F8/00
PERFORMING OPERATIONS; TRANSPORTING
B22F10/25
PERFORMING OPERATIONS; TRANSPORTING
B22F10/28
PERFORMING OPERATIONS; TRANSPORTING
B22F2998/10
PERFORMING OPERATIONS; TRANSPORTING
B22F10/25
PERFORMING OPERATIONS; TRANSPORTING
B22F2999/00
PERFORMING OPERATIONS; TRANSPORTING
International classification
B22F8/00
PERFORMING OPERATIONS; TRANSPORTING
B22F9/04
PERFORMING OPERATIONS; TRANSPORTING
B22F10/28
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A method of recycling a structure or at least a portion thereof, and component for an aircraft or spacecraft. The structure comprises components connected to each other and each made from a metal alloy. The method includes producing, at least from a plurality of the components, including components made from at least two different metal alloys, a powder adapted to being used as a starting material in an additive manufacturing process. Also, a component for an aircraft or spacecraft, made using additive manufacturing, the component being produced a powder obtained in accordance with the method.
Claims
1. A method of recycling a structure, or at least a portion thereof, wherein the structure comprises components connected to each other and each made from a metal alloy, wherein the method comprises: producing, at least from material of a plurality of components including components made from at least two different metal alloys, a powder configured to be utilized as a starting material in an additive manufacturing process.
2. The method according to claim 1, wherein producing the powder comprises melting the material of the plurality of components to form a melt and atomizing the melt.
3. The method according to claim 2, wherein the melt is formed by subjecting at least some of the components from the plurality of the components, or sections thereof, which are still connected to each other to melting, or mechanically reducing at least some of the components from the plurality of the components, or sections thereof, which are still connected to each other to smaller pieces and subjecting the smaller pieces to melting.
4. The method according to claim 1, wherein the producing comprises: mechanically reducing the material of the plurality of components to powder, by cutting, or chopping, or shredding, or chipping, or grinding, or a combination thereof.
5. The method according to claim 4, wherein the mechanically reducing the material to powder comprises subjecting at least some of the components from the plurality of the components, or sections thereof, which are still connected to each other to cutting, or chopping, or shredding, or chipping, or grinding, or a combination thereof.
6. The method according to claim 1, wherein producing the powder further comprises subjecting the powder to a plasma treatment.
7. The method according to claim 1, wherein producing the powder comprises nano-decorating the powder with at least one additive.
8. The method according to claim 7, wherein the at least one additive is selected from consisting of: titanium, silicon, a zirconium hydride, a titanium diboride, a calcium hexaboride, a lanthanum hexaboride, and mixtures thereof.
9. The method according to claim 1, wherein the additive manufacturing process is a powder bed process.
10. The method according to claim 1, wherein the components from the plurality of components includes components each made from an aluminum alloy.
11. The method according to claim 1, wherein the components from the plurality of components includes components made from alloys classified in at least two different alloy series, and the method further comprising: producing a new component with the additive manufacturing process, wherein the new component comprises a cross-over alloy can be additively made.
12. The method according to claim 1, wherein the components from the plurality of components comprises one or more of at least a portion of an outer fuselage skin, a wing cover, a fuselage stringer, a wing stringer, a fuselage frame, an internal structural element of a fuselage, a bracket or a fastening element.
13. The method according to claim 1, wherein the components from the plurality of components comprises components connected to each other using rivets or using a bolted connection or welded to each other or adhesively bonded to each other.
14. The method according to claim 1, wherein at least some of the components from the plurality of components are connected to each other via connecting elements, in particular rivets or bolts, the connecting elements being formed with a material different from an aluminum alloy, wherein during production of the powder, the connecting elements are processed together with the components from the plurality of components.
15. The method according to claim 1, wherein the method further comprises: selecting, based on documentation available of the structure to be recycled, components of the structure or sections thereof to be used for the production of a batch of a pre-defined powder.
16. The method according to claim 1, wherein the method further comprises: producing a new component for an aircraft or spacecraft, wherein the producing of the new component includes the additive manufacturing process and the powder is used as the starting material in the additive manufacturing process for producing the new component.
17. The method according to claim 1, wherein the component is an aircraft or spacecraft structure.
18. The method according to claim 1, wherein the additive manufacturing process comprises locally melting the powder to form a melt and cooling the melt resulting therefrom at a cooling rate of at least 10,000 Kelvin per second.
19. The method according to claim 1, wherein the components from the plurality of components includes components each made from an aluminum alloy classified in a 2xxx aluminum alloy series, a 5xxx aluminum alloy series, a 6xxx aluminum alloy series, and a 7xxx aluminum alloy series.
20. A component for an aircraft or spacecraft made using additive manufacturing, wherein the component is produced with the powder obtained in accordance with the method of claim 1.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0055] The invention will be explained in the following with reference to the schematic figures of the drawings which illustrate embodiments of the invention. Herein:
[0056]
[0057]
[0058]
[0059]
[0060]
[0061]
[0062] The enclosed drawings are intended to illustrate embodiments of the invention so that the invention may be further understood. The drawings, in conjunction with the description, are intended to explain principles and concepts of the invention. Other embodiments and many of the advantages described may be inferred from the drawings. Elements of the drawings are not necessarily drawn to scale.
[0063] Elements, features and components which are identical or which have the same function or effect have been labeled in the drawings using the same reference signs, except where explicitly stated otherwise.
DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS
[0064]
[0065] More specifically, the aircraft structure comprises a multitude of structural components, some of which are schematically shown in exemplary manner in
[0066] The structural components 4a-4h may each correspond, for example, to one of a fuselage skin 2a or pressure cabin skin, a fuselage stringer 2b, a fuselage frame 2c, an internal structural component 2d (not shown in detail in the FIGS.) of the fuselage 2, an upper wing cover 3a, a lower wing cover 3c, or a wing stringer such as a lower wing stringer 3b. Any of the structural components 4a-4h may alternatively correspond to another metal component or element of the aircraft structure not shown in more detail in
[0067] During production of the aircraft 1, each of the structural components 4a-4h, 2a-2d, 3a-3c was manufactured from a light metal alloy, more specifically an aluminum alloy. As the requirements for various structural components differ, e.g. regarding the required mechanical load-bearing capacity, capability of being cold or hot formed or being machined, resistance to fatigue or corrosion, etc, the components 4a-4h, 2a-2d, 3a-3c are made from different aerospace aluminum alloys, in particular from alloys classified in one of the 2xxx, 5xxx, 6xxx and 7xxx aluminum alloy series, wherein the alloys may for example be alloys commonly used in structural aircraft parts. More specifically, the alloys from the 2xxx series may be AlCuMg(Li) alloys, the alloys from the 5xxx series AlMg(Sc) or AlMg(Mn) alloys, the alloys from the 6xxx series AlMgSiCu alloys, the alloys from the 7xxx series AlZnMgCu alloys.
[0068] Within the aircraft or spacecraft 1, components may be present which are not made from aluminum alloys, but from other metals, or from non-metallic materials. The method as illustrated by the embodiment of
[0069] Accordingly, the methods according to the embodiments described herein are applicable to structures, in particular in the air or space industry, which are formed wholly or in part with components made from aluminum alloys. The aluminum alloy components may in particular form a significant or predominant fraction of the structure.
[0070] In the airplane 1 displayed in
[0071] The aircraft 1 of
[0072] The method of recycling the structure of the aircraft 1, or at least a part of that structure, in accordance with the embodiment of
[0073] The powder 101 produced is suitable for use as a starting material in an additive manufacturing process, for example a laser powder bed fusion process, to make a new component. Yet, the powder 101 could also be adapted for use in an additive thermal spraying process.
[0074] In accordance with the embodiment of
[0075]
[0076]
[0077] In the embodiment of
[0078] The mechanical reduction, in particular grinding, in step 20 can be facilitated by performing the step 20, or at least the grinding therein, at low temperature, in particular if the components to be processed become sufficiently brittle for proper grinding at lower temperature.
[0079] Irregular fragments, chips and flakes having edges result from the cutting, chopping or chipping and grinding in step 20. In order to improve the flowability of the powder, the powder obtained as an intermediate product in step 20 then undergoes plasma spheroidization in step 30. The powder is treated by a plasma in order to modify the particle shape and obtain a powder formed by rounded, spheroid or preferably essentially spherical particles, which exhibits good flowability.
[0080] During the plasma treatment in step 30, organic contaminations, for example from sealants or similar, may also be removed. In some cases, the plasma treatment may also be able to provide some deoxidation of the powder.
[0081] In step 40, the powder obtained as an intermediate product in step 30 undergoes nano-decoration with an additive capable of acting as a grain refiner and nucleating agent. The additive may e.g. be selected from, or may comprise at least one, of titanium (Ti), silicon (Si), a zirconium hydride, for example ZrH.sub.2, a titanium diboride (TiB.sub.2), a calcium hexaboride (CaB.sub.6) or a lanthanum hexaboride (LaB.sub.6). In variants, the use of other or further additives, e.g. higher-melting pure metals or alloys, is conceivable.
[0082] More particularly, in step 40, the intermediate powder obtained in step 30 may be nano-decorated with one or more of such additives. The additive(s) can in particular be fine powders, comprising particles considerably finer than those obtained in step 30, in particular having a particle size of <1,000 nm. For example, in step 40, the powder resulting from step 30 can be mixed with the fine powder nano-additive(s) and can be mechanically alloyed with the additive(s) using a ball mill or similar device or using an ultrasonic device, or other deposition methods may be used.
[0083] At the end of step 40, the powder 101 is obtained. The powder 101 is adapted for use as a starting material in an additive manufacturing process. Steps 20, 30, 40 form sub-steps of the powder production step 10.
[0084] In a step 80, additive manufacturing or 3D-printing of a new component 201 for an aircraft or spacecraft, e.g. a structural component 201, is carried out. More specifically, the new component 201 is manufactured in step 80 in accordance with a laser powder bed fusion method, in which the powder 101 is used as a starting material. The powder 101 is applied in layered manner on a platform and selectively melted by a laser to form a three-dimensional component, which e.g. may be of intricate shape.
[0085] In the method of the second embodiment, the powder 101 is a heterogeneous powder. The powder 101 comprises rounded, e.g. essentially spherical, particles 102, schematically displayed in
[0086] In step 80 of the second embodiment, a cross-over alloy of two or more aluminum alloys is formed in the local molten pool, as the powder 101 is subjected to selective melting at the laser focus. Further, in the powder bed fusion method, the local melt is able to rapidly cool. Cooling rates of at least 10,000 Kelvin per second (10.sup.4 K/s), even higher than 100,000 K/s (10.sup.5 K/s) or up to 1,000,000 K/s (10.sup.6 K/s), are achievable. The different aluminum alloys contributed by the particles 102 preferably mix to form an essentially homogeneous melt, which also contains the additive(s) introduced by nano-decoration in step 40. As the melt rapidly cools, the alloying elements can be maintained in solid solution, avoiding phase separation.
[0087] The additive(s) introduced in step 40 act as nucleating agent(s) and grain refiner(s), so that a very fine-grained internal microstructure is obtained as the material solidifies and cools, forming a cross-over alloy. More specifically, nano-particles formed from the additive(s) selected in exemplary manner from Ti, Si, ZrH.sub.2, TiB.sub.2, CaB.sub.6 or LaB.sub.6 are high temperature stable and will not be immediately diluted in the cross-over aluminum alloy melt. In the additive manufacturing process 80, the melt locally exists only for a brief time, and rapidly solidifies, and the additive(s) can act as so-called heterogeneous nuclei.
[0088] Consequently, hot cracking can be avoided safeguarding generated cross-over alloy integrity and quality, in particular as an important basic element of the additively generated new product.
[0089] Upon completion of step 80, a new component 201 of a cross-over alloy has been formed. The component 201 may undergo further treatment, machining etc. in order to form a finished, high-grade part ready for use in an aircraft or spacecraft, e.g. as a structural member or for another purpose.
[0090] In particular, after 3D printing in step 80, the new component 201 may undergo a heat treatment, as illustrated in
[0091]
[0092] The production 10′ of a powder 101 that can be used at a later stage in additive manufacturing further comprises, according to the third embodiment, a step 70 in which the melt, which preferably is homogeneous, is atomized in order to obtain a powder. The melt atomization 70 may be performed either by gas atomization, e.g. using an inert gas to atomize the melt, or by centrifugal atomization, which includes jetting the melt onto a rotating element, e.g. a rotating disk. After cooling of the droplets obtained by atomization, a homogeneous powder is obtained.
[0093] As in the method of
[0094] After the melt atomization step 70, the resulting powder is nano-decorated in a subsequent step 40, in the same manner as described above with reference to
[0095] The powder can then be used, in a manner analogous to the powder 101 of
[0096] In some implementations, additive manufacturing 80 using the homogeneous powder directly obtained from step 70 may already result in a fine-grained structure after solidification, and hence, in such cases step 40 might be omitted. Preferably, however, a nano-decoration step 40 is provided.
[0097] The recycling method of the third embodiment may be advantageous in particular if some or all of the components to be processed, out of the components 2a-2d, 3a-3c, 4a-4h of the structure of the aircraft 1 have high ductility even at low temperatures, and therefore cannot be mechanically ground or are difficult to be reduced to particles in mechanical manner, even at low temperature.
[0098] The particles of the powder obtained in step 70 each are formed of a cross-over alloy dependent on the composition of the components that underwent melting in step 50. As a result of the cooling rate during atomization, some phase separation may occur in some implementations within the particles of the powder resulting from step 70. Yet, the powder is then used, in step 80, e.g. in a laser powder bed fusion process, in which again a melt is formed which rapidly cools to retain the alloying elements in solid solution as described above. The additive(s) added via nano-decoration in step 40 help(s) to obtain a fine-grained microstructure of the material during additive manufacturing in step 80 and to avoid hot cracking. Precipitation of one or more desired phase(s) can be initiated or promoted by a targeted heat treatment in step 90, in a manner analogous to what has been described above with reference to
[0099] As may be seen from the description above, the composition of the cross-over alloy, which might also be termed a “secondary alloy” or even “dirty alloy”, as it is produced from a mixture of components having different compositions, depends on the selection of the plurality of components, out of the multitude of components, e.g. 2a-2d, 3a-3c, 4a-4h, from which the structure of the aircraft 1 is formed, which are processed to form the powder 101 to be used as starting material in additive manufacturing.
[0100]
[0101] Preparation of recycling of the structure of the aircraft 1 or a portion thereof includes, in accordance with the fourth embodiment, a step 410 of selecting components of the structure, or sections of such components, which should be used for the production of a batch of powder of pre-defined, desired type, having a target overall powder composition. For instance, step 410 may result in the definition of a portion 500 to be cut from the structure of the aircraft 1, or several such portions, which is or are to be processed to form a batch of powder. A component selection algorithm, capable of being executed by a data processing device such as a computer, may be used to implement step 410. The component selection algorithm may, in a variant, be additionally configured to partition the entire aircraft structure into portions 500 from which batches of powder of pre-defined composition, which may vary or be identical, can be made.
[0102] Furthermore, the method of the fourth embodiment illustrated in
[0103] A method according to a fifth embodiment is schematically shown in
[0104] In an analogous variant of the method of
[0105] Depending on the structure to be recycled, portions thereof may not contain such additional elements e.g. from Ti or a Ti alloy or from steel, or may not contain them in significant amount, so that in this case, a mixture essentially containing different aluminum alloys is subjected to a powder production process including mechanical reduction to powder and plasma treatment or melting and melt atomization, as described above.
[0106] With respect to the embodiments described above, it is conceivable that the new component, e.g. 201, may be subjected at least partially to machining if necessary or desired, e.g. at interface portions thereof.
[0107] Also, it is conceivable in variants of the embodiments above, if required in order to adjust the composition of the powder, that (an) additional alloying element(s) may be added during production of the powder. Preferably, however, such additional alloying element(s) would be added in small quantities only, so as to rely to a very large extent on the materials to be recycled.
[0108] The embodiments described above in particular provide advantages of: [0109] avoiding expensive separation and sorting, in particular Al-alloy composition respecting sorting, of components to be recycled; [0110] enabling cost effective and energy effective tailor-made powder production; [0111] exploiting the full potential of additive manufacturing by processing powders and material combinations not accessible by conventional processing routes; [0112] providing access to high-quality aluminum products obtained by cost-effective and efficient recycling of e.g. aircraft structures, and avoiding down-cycling or mere storage of end-of-life structures;
[0113] Although the invention has been completely described above with reference to preferred embodiments, the invention is not limited to these embodiments but may be modified in many ways.
[0114] For instance, the structure to be recycled is not necessarily an aircraft structure, but could instead be a spacecraft structure, or another structure, for instance formed with light metal components.
[0115] While at least one exemplary embodiment of the present invention(s) is disclosed herein, it should be understood that modifications, substitutions and alternatives may be apparent to one of ordinary skill in the art and can be made without departing from the scope of this disclosure. This disclosure is intended to cover any adaptations or variations of the exemplary embodiment(s). In addition, in this disclosure, the terms “comprise” or “comprising” do not exclude other elements or steps, the terms “a” or “one” do not exclude a plural number, and the term “or” means either or both. Furthermore, characteristics or steps which have been described may also be used in combination with other characteristics or steps and in any order unless the disclosure or context suggests otherwise. This disclosure hereby incorporates by reference the complete disclosure of any patent or application from which it claims benefit or priority.
LIST OF REFERENCE SIGNS
[0116] 1 aircraft [0117] 1a nose [0118] 1b empennage [0119] 2 fuselage [0120] 2a fuselage skin [0121] 2b fuselage stringer [0122] 2c fuselage frame [0123] 2d internal fuselage structures [0124] 3 wing [0125] 3a upper wing covers [0126] 3b lower wing stringers [0127] 3c lower wing covers [0128] 4a-4h component [0129] 5a riveted connection [0130] 5b bolted connection [0131] 5c welded connection [0132] 5d adhesively bonded connection [0133] 6 end-of-life “waste” [0134] 7 down-cycling [0135] 8 product resulting from down-cycling [0136] 9 recycling [0137] 10 powder production [0138] 10′ powder production [0139] 10″ powder production [0140] 20 mechanical reduction to powder step [0141] 30 plasma-spheroidization step [0142] 40 nano-decoration step [0143] 50 melting step [0144] 70 melt atomization step [0145] 80 additive manufacturing [0146] 90 heat treatment [0147] 101 powder [0148] 102 powder particle [0149] 103 nano-particle of additive [0150] 104 nano-particle of additive [0151] 201 additively manufactured new component [0152] 300 documentation [0153] 410 component selection step [0154] 420 heat treatment selection or definition step [0155] 500 selected portion of structure