Method and apparatus for producing biofuel in an oscillating flow production line under supercritical fluid conditions
11773050 · 2023-10-03
Assignee
Inventors
- Ib Johannsen (Risskov, DK)
- Anders Peter Stubkjær ADAMSEN (Hobro, DK)
- Bjørn Sjøgren Kilsgaard (Aarhus, DK)
- Viktor MILKEVYCH (Randers, DK)
Cpc classification
C10G1/00
CHEMISTRY; METALLURGY
Y02E50/10
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
B01J2219/00159
PERFORMING OPERATIONS; TRANSPORTING
C10L2200/0476
CHEMISTRY; METALLURGY
B01J19/0013
PERFORMING OPERATIONS; TRANSPORTING
C07C37/004
CHEMISTRY; METALLURGY
C10L2270/026
CHEMISTRY; METALLURGY
B01J2219/00087
PERFORMING OPERATIONS; TRANSPORTING
C07C51/00
CHEMISTRY; METALLURGY
B01J3/008
PERFORMING OPERATIONS; TRANSPORTING
Y02P30/20
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
B01J3/02
PERFORMING OPERATIONS; TRANSPORTING
C10L1/02
CHEMISTRY; METALLURGY
B01J4/008
PERFORMING OPERATIONS; TRANSPORTING
C10L8/00
CHEMISTRY; METALLURGY
Y02P20/54
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
C07D307/34
CHEMISTRY; METALLURGY
C07C67/08
CHEMISTRY; METALLURGY
International classification
B01J3/00
PERFORMING OPERATIONS; TRANSPORTING
B01J19/00
PERFORMING OPERATIONS; TRANSPORTING
B01J19/24
PERFORMING OPERATIONS; TRANSPORTING
B01J3/02
PERFORMING OPERATIONS; TRANSPORTING
B01J3/04
PERFORMING OPERATIONS; TRANSPORTING
B01J4/00
PERFORMING OPERATIONS; TRANSPORTING
C07C37/00
CHEMISTRY; METALLURGY
C07C51/00
CHEMISTRY; METALLURGY
C07C67/08
CHEMISTRY; METALLURGY
C07D307/34
CHEMISTRY; METALLURGY
C10G1/00
CHEMISTRY; METALLURGY
C10G3/00
CHEMISTRY; METALLURGY
C10L1/02
CHEMISTRY; METALLURGY
Abstract
The invention discloses a method for producing bio-fuel (BF) from a high-viscosity biomass using thermo-chemical conversion of the biomass in a production line (10) with pumping means (PM), heating means (HM) and cooling means (CM). The method has the steps of 1) operating the pumping means, the heating means and the cooling means so that the production line is under supercritical fluid conditions (SCF) to induce biomass conversion in a conversion zone (CZ) within the production line, and 2) operating the pumping means so that at least part of the production line is in an oscillatory flow (OF) mode. The invention is advantageous for providing an improved method for producing biofuel from a high-viscosity biomass. This is performed by an advantageous combination of two operating modes: supercritical fluid (SCF) conditions and oscillatory flow (OF).
Claims
1. A production line for producing biofuel, or other bio-based chemicals, from biomass in a continuous flow, using thermo-chemical conversion of the biomass, comprising: a biomass inlet, a tubular reactor, two double piston based pumps each having associated valves for control of working pressure and each having associated hydraulic actuators situated upstream and downstream relative to the biomass inlet, heating means (HM) in thermal contact with a first part of the tubular reactor for controlling the temperature in the tubular reactor, and cooling means (CM) in thermal contact with a second part of the tubular reactor for cooling the biomass under conversion, wherein the tubular reactor is not equipped with internal baffles that influence mixing.
2. The production line of claim 1 further comprising a heat exchanger including heat clamps made from solid matrixes of heat conducting material that surround the tubular reactor.
3. A method for producing bio-fuel, or other bio-based chemicals, from biomass under continuous flow in the production line of claim 1 comprising: operating each of the two double piston-based pumps in a manner such that the two pistons of each double piston-based pump work in counter-phase relative to one another and controlling the corresponding working pressure of the pistons using the associated valves; and thermo-chemically converting the biomass in the tubular reactor.
4. A method for producing bio-fuel, or other bio-based chemicals, from biomass under continuous flow in the production line of claim 1 comprising: operating the production line in a manner such that the flow in at least part of the tubular reactor oscillates such that local flow has alternating direction between forward and backward, resulting in lower viscosity of the biomass and higher heat transfer; and thermo-chemically converting the biomass in the tubular reactor.
5. A method for producing bio-fuel, or other bio-based chemicals, from biomass under continuous flow in the production line of claim 1 comprising: maintaining a conversion zone situated between the first part of the tubular reactor in thermal contact with the heating means and the second part of the tubular reactor in thermal contact with the cooling means at a temperature between 500K and 650K; and thermo-chemically converting the biomass in the tubular reactor.
6. A method for producing bio-fuel or other bio-based chemicals, from biomass under continuous flow in the production line of claim 1 comprising: operating the two double piston-based pumps, the heating means, and the cooling means of the production line in a manner such that a conversion zone (CZ) situated between the first part of the tubular reactor in thermal contact with the heating means and the second part of the tubular reactor in thermal contact with the cooling means is maintained under supercritical or near-supercritical fluid conditions to induce biomass conversion; and thermo-chemically converting the biomass in the tubular reactor.
7. A method for producing bio-fuel or other bio-based chemicals, from biomass under continuous flow in the production line of claim 1 comprising: thermo-chemically converting the biomass in the tubular reactor in the presence of water or other polar solvents.
Description
BRIEF DESCRIPTION OF THE FIGURES
(1) The invention will now be described in more detail with regard to the accompanying figures. The figures show one way of implementing the present invention and are not to be construed as being limiting to other possible embodiments falling within the scope of the attached claim set.
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DETAILED DESCRIPTION OF AN EMBODIMENT
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(13) The method according to the invention particularly comprises operating the pumping means 20, the heating means 30 and the cooling means 40 so that, at least part of, the production line 10 is under supercritical fluid conditions (SCF), optionally at near-supercritical fluid conditions, so as to induce biomass conversion in a conversion zone CZ within the production line. In
(14) The method according to the invention further comprises operating the pumping means PM 20 so that, at least part of, the production line 10 is in an oscillatory flow OF mode, wherein a local oscillatory flow rate of the biomass under conversion is superimposed on the average flow rate through the production line 10.
(15) Thus, in some embodiments the whole production line 10 is operated in an oscillatory flow OF mode, including the supercritical fluid SCF zone and the conversion zone CZ. In other embodiments, only parts of the production line 10 is operated in an oscillatory flow OF mode, for example the part of the production line 10 from the pumping means PM 20 inducing the oscillatory flow and parts of the conversion zone CZ. In some embodiments, the oscillatory flow mode may extend into parts of the supercritical fluid SCF zone but not covering the conversion zone CZ due to the damping taking place of the oscillatory flow in the supercritical fluid SCF zone.
(16) In
(17) The production line 10 shown is schematically indicated in
(18) Within the context of the present invention, the pumping means PM 20 may comprise electrically driven, hydraulically driven, and/or pneumatically driven pumps. The pumps may be positive displacement pumps, e.g. piston based pumps, or velocity pumps, e.g. centrifugal type pumps. The pumping means may include extruders for feeding biomass under pressure, or eccentric screw pumps. Alternative pumping means include impulse pumps, gravity pumps, steam pumps, and valveless pumps.
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(20) According to the invention further the pumping means PM 20 are operated so that, at least part of, the production line 10 is in an oscillatory flow OF mode, the local oscillatory flow rate of the biomass under conversion is superimposed on the average flow rate through the production line as shown in the graph of
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(22) The oscillatory flow inducing means 50 is positioned in fluid contact with the production line 10 at, or near, the first part 1 of the production line and operated for inducing an oscillatory flow to at least in part of the conversion zone CZ. Similarly, the oscillatory flow inducing means 50′ is positioned in fluid contact with the production line at, or near, the second part 2 of the production line 10 and operated for inducing an oscillatory flow back stream through the production line 10 back to at least part of the conversion zone CZ. In embodiments of the invention, only one of the OFIM pumps may be used, i.e. either pump 50 or pump 50′.
(23) As seen in
(24) Within the context of the present invention, the oscillatory flow inducing means may comprise electrically driven, hydraulically driven, and/or pneumatically driven pumps. The pumps may be positive displacement pumps, e.g. piston based pumps or membrane based pumps, or velocity pumps, e.g. centrifugal type pumps. The oscillatory flow inducing means of
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(31) The production line comprises a depressurizing unit and take off unit (not shown in
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(33) The depressurizing unit may alternatively, or additionally, comprise one or more of the following depressurizing means; needle valves, capillary tubes etc. In particular, various pumps and combination thereof may be used, such as an electrically driven, hydraulically driven, and/or pneumatically driven pump. The pumps may be positive displacement pumps, e.g. piston based pumps, membrane (diaphragm) based pumps, gear pumps, progressing cavity pump, impeller based pumps, rotary lobe pumps, rotary vane pumps, or velocity pumps, e.g. centrifugal type pumps. Especially, they may have double action.
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(35) Pumping means 120 are capable of pumping the biomass 4 BM through the production line under a controlled pressure and flow. Initially, the biomass BM enters a heat exchanger 150 (from the left in
(36) Secondly, heating means HM 130 in thermal contact with the production line 10 facilitate control of the temperature and thereby resulting in further heating of the biomass. The heated biomass then enters the reactor part 104 REAC of the production line 10 under (near) supercritical fluid condition. In the reactor, the biomass will be converted to biofuel 5 BF. The drawing in
(37) Thus, the production line is operated so that the pumping means 120 and 150, the heating means and the cooling means so that, at least part of, the production line is under supercritical fluid conditions SCF, optionally at near-supercritical fluid conditions, so as to induce biomass conversion in a conversion zone CZ, here reactor 104 REAC, within the production line 10.
(38) Additionally, the production line 10 is operated so that the pumping means 120 and the oscillatory flow inducing means 150 are able to keep, at least at part of, the production line in an oscillatory flow OF mode, wherein a local oscillatory flow rate of the biomass under conversion is superimposed on the average flow rate through the production line 10.
(39) As shown in
(40) Suitable heating exchangers 150 and the combined heat exchanger of cooler 140 and heater 130 may include, but is not limited to, tube-by-tube configuration joined in a highly thermally conductive material, a segmented heat exchanger, heat exchanger using a cooling medium, such as oil, salt melting medium, hot water medium, etc., as the skilled person in thermodynamics would readily contemplate for use when designing, implementing and operating a production line for producing biofuel, or other bio-based chemicals, from biomass according to the present invention.
(41) It should be noted that even though the production line 10 shown in
(42) It may be mentioned that the depressurizing unit 170 may be functionally connected to the OFIM 150 and the pumping means 120 for optionally re-using the energy in the high pressure product of biofuel BF 5. Particularly, the depressurizing unit 170 can be fluid-wise connected to the OFIM 150 with an additional pressure accumulator for temporally storing the pressure energy, and later reuse the pressure energy for creating oscillatory flow in the production line, as explained in more detail in connection with
(43) In a production system for producing bio-fuel etc. according to the present invention as depicted in
(44) The heat transfer was performed through a large number of custom-made heat clamps made out of cast iron, cf.
(45) Furthermore, experiments with fibrous biomass (10% milled Miscantus Gigantus in water containing 1.5% potassium hydroxide) at the above temperature range showed that there was a 10-20% reduction in feed pressure needed to obtain a steady flow of 25 l/hr, indicating a significant reduction in dynamic viscosity of the feed as expected when implementing the present invention.
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(48) the method comprising:
(49) S1 operating the pumping means, the heating means and the cooling means so that, at least part of, the production line is under supercritical fluid conditions SCF, optionally at near-supercritical fluid conditions, so as to induce biomass conversion in a conversion zone CZ, e.g. reactor 104 REAC in
(50) S2 operating the pumping means so that, at least part of, the production line is in an oscillatory flow OF mode, wherein a local oscillatory flow rate of the biomass under conversion is superimposed on the average flow rate through the production line.
(51) In short, the present invention discloses a method for producing bio-fuel BF from a high-viscosity biomass using thermo-chemical conversion of the biomass in a production line 10 with pumping means PM, heating means HM and cooling means CM. The method has the steps of 1) operating the pumping means, the heating means and the cooling means so that the production line is under supercritical fluid conditions SCF to induce biomass conversion in a conversion zone CZ within the production line, and 2) operating the pumping means so that, at least part of, the production line is in an oscillatory flow OF mode. The invention is advantageous for providing an improved method for producing biofuel from a high-viscosity biomass. This is performed by an advantageous combination of two operating modes: supercritical fluid SCF conditions and oscillatory flow OF.
(52) The invention can be implemented by means of hardware, software, firmware or any combination of these. The invention or some of the features thereof can also be implemented as software running on one or more data processors and/or digital signal processors.
(53) The individual elements of an embodiment of the invention may be physically, functionally and logically implemented in any suitable way such as in a single unit, in a plurality of units or as part of separate functional units. The invention may be implemented in a single unit, or be both physically and functionally distributed between different units and processors.
(54) Although the present invention has been described in connection with the specified embodiments, it should not be construed as being in any way limited to the presented examples. The scope of the present invention is set out by the accompanying claim set. In the context of the claims, the terms “comprising” or “comprises” do not exclude other possible elements or steps. Also, the mentioning of references such as “a” or “an” etc. should not be construed as excluding a plurality. The use of reference signs in the claims with respect to elements indicated in the figures shall also not be construed as limiting the scope of the invention. Furthermore, individual features mentioned in different claims, may possibly be advantageously combined, and the mentioning of these features in different claims does not exclude that a combination of features is not possible and advantageous.