Multi-junction solar cell with back-contacted front side

Abstract

A stacked multi-junction solar cell with a back-contacted front side, having a germanium substrate that forms a rear side of the multi-junction solar cell, a germanium sub-cell and at least two III-V sub-cells, successively in the named order, and at least one passage contact opening that extends from the front side of the multi-junction solar cell through the sub-cells to the rear side and a metallic connection contact that is guided through the passage contact opening. A diameter of the passage contact opening decreases in steps from the front side to the rear side of the multi-junction solar cell. The front side of the germanium sub-cell forms a first step having a first tread depth that circumferentially projects into the passage contact opening. The second step with a second tread depth circumferentially projects into the passage contact opening.

Claims

1. A stacked multi-junction solar cell, comprising: a germanium substrate; a germanium sub-cell over the germanium substrate; at least two III-V sub-cells over the germanium sub-cell; and a passage contact opening that extends along a longitudinal direction from a front side of the multi-junction solar cell to a rear side of the multi-junction solar cell, through the at least two III-V sub-cells, the germanium sub-cell, and the germanium substrate, the passage contact opening having a contiguous side surface and an oval circumference in cross section, the front side being opposite the rear side, wherein the contiguous side surface of the passage contact opening includes a first step that circumferentially projects into the passage contact opening and has a first tread depth, and a second step that circumferentially projects into the passage contact opening and has a second tread depth, a tread of the second step is located below a p/n junction of the germanium sub-cell, wherein the passage contact opening has a first area from the front side to a tread of the first step, a second area from the tread of the first step to the tread of the second step, and a third area from the tread of the second step to the rear side, wherein a diameter of the passage contact opening in the first area is greater than a diameter of the passage contact opening in the second area, and the diameter of the passage contact opening in the second area is greater than a diameter of the passage contact opening in the third area, and wherein the stacked multi-junction solar cell further comprises: a dielectric insulating layer disposed on the contiguous side surface of the passage contact opening along side walls of the at least two III-V sub-cells, the germanium sub-cell, and the germanium substrate, the dielectric insulating layer extending from the front side of the multi-junction solar cell to the rear side of the multi-junction solar cell; and a metallic contact layer disposed on the dielectric insulating layer, the metallic contact layer extending from the front side of the multi-junction solar cell to the rear side of the multi-junction solar cell, physically contacting an upper surface of the at least two III-V sub-cells, and separated from the side walls by the dielectric insulating layer.

2. The stacked multi-junction solar cell according to claim 1, wherein the III-V sub-cells have a common layer thickness of 5-15 μm.

3. The stacked multi-junction solar cell according to claim 1, wherein a diameter of the passage contact opening on the front side of the multi-junction solar cell is at least 400 μm, and is not greater than 1 mm.

4. The stacked multi-junction solar cell according to claim 1, wherein between the steps and/or above the first step and/or below the second step, the side surface of the passage contact opening forms an angle of at most 10° with respect to a longitudinal axis of the passage contact opening.

5. The stacked multi-junction solar cell according to claim 1, wherein the first tread depth of the first step is at least 200 μm.

6. The stacked multi-junction solar cell according to claim 1, wherein the second tread depth of the second step is at least 10 μm.

7. The stacked multi-junction solar cell according to claim 1, wherein a thickness of the germanium sub-cell, together with the germanium substrate, is 140-160 μm or 80-120 μm.

8. The stacked multi-junction solar cell according to claim 1, wherein a distance from the second step to the first step along the longitudinal direction is 1-4 μm.

9. The stacked multi junction solar cell according to claim 1, wherein the multi-junction solar cell comprises a III-V cover layer that forms the front side and has a thickness of 150-500 nm and a band gap of at least 1.86 eV.

10. The stacked multi-junction solar cell according to claim 1, wherein a diameter of the passage contact opening decreases in steps from the front side to the rear side of the multi-junction solar cell.

11. The stacked multi-junction solar cell according to claim 1, wherein the passage contact opening on the front side of the multi-junction solar cell has a diameter of at least 300 μm, wherein a tread depth of the first step is at least 100 μm, and wherein a tread depth of the second step is at least 5 μm.

12. The stacked multi-junction solar cell according to claim 1, wherein the germanium sub-cell, together with the germanium substrate, has a layer thickness of 80-300 μm.

13. The stacked multi-junction solar cell according to claim 1, wherein the dielectric insulating layer is disposed directly on sidewalls of the at least two III-V sub-cells, the germanium sub-cell, and the germanium substrate, and wherein the metallic contact layer is disposed directly on the dielectric insulating layer.

14. The stacked multi-junction solar cell according to claim 1, wherein the diameter of the passage contact opening in the first area is constant or decreases in the longitudinal direction, wherein the diameter of the passage contact opening in the second area is constant or decreases in the longitudinal direction, and wherein the diameter of the passage contact opening in the third area is constant or decreases in the longitudinal direction.

15. The stacked multi-junction solar cell according to claim 2, wherein the III-V sub-cells have the common layer thickness of 6-8 μm.

16. The stacked multi-junction solar cell according to claim 3, wherein the diameter of the passage contact opening on the front side of the multi-junction solar cell is at least 450 μm.

17. The stacked multi-junction solar cell according to claim 4, wherein between the steps and/or above the first step and/or below the second step, the side surface of the passage contact opening forms the angle of at most 2° with respect to the longitudinal axis of the passage contact opening.

18. The stacked multi-junction solar cell according to claim 4, wherein between the steps and/or above the first step and/or below the second step, the side surface of the passage contact opening forms the angle of at most 1° with respect to the longitudinal axis of the passage contact opening.

19. The stacked multi-junction solar cell according to claim 8, wherein the distance from the second step to the first step along the longitudinal direction is 1-3 μm.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) The present invention will become more fully understood from the detailed description given hereinbelow and the accompanying drawings which are given by way of illustration only, and thus, are not limitive of the present invention, and wherein:

(2) FIG. 1 is a cross section of an exemplary embodiment of a passage contact opening of a stacked multi-junction solar cell with a back-contacted front side,

(3) FIG. 2 is a plan view of an exemplary embodiment of the multi-junction solar cell,

(4) FIG. 3 is a rear side of an exemplary embodiment of the multi-junction solar cell, and

(5) FIG. 4 is a cross section of an exemplary embodiment of the passage contact opening.

DETAILED DESCRIPTION

(6) The illustration in FIG. 1 shows a section of a stacked multi-junction solar cell 10 with a back-contacted front side in a cross section. The multi-junction solar cell has a top 10.1 and a bottom 10.2 and a passage opening 12 that extends from the top 10.1 to the bottom 10.2.

(7) The bottom 10.2 is formed by a germanium substrate 14. On the germanium substrate there are, in the named order, a germanium sub-cell 16, a first III-V sub-cell 18 and a second III-V sub-cell 20 which forms the top 10.2.

(8) Together, the two III-V sub-cells 18 and 20 have a first layer thickness H1. The germanium substrate 13, together with the germanium sub-cell, has a second layer thickness H2.

(9) The passage opening 12 has a side surface 12.1, wherein the side surface 12.1 is formed to be contiguous as an outer surface of a cylinder and has an oval shape, for example circular or elliptical, in cross section.

(10) The passage opening 12 also has two steps 24 and 26. The first step 24 is formed by a front side 16.1 of the germanium sub-cell 16, wherein the top 16.1 forms a circumferential tread surface with a tread depth S1 that is constant in the radial direction.

(11) The second step 26 is located in an area of the germanium sub-cell 16 below a p/n junction 16.2 of the germanium sub-cell 16 and has a circumferential tread surface with a tread depth S2.

(12) The side surface 12.1 of the passage contact opening 12 and an area of the top 10.1 and the bottom 10.2 that adjoins the passage opening 12 is covered with a dielectric insulating layer 28.

(13) A metallic connection contact 22 is formed as a metallic contact layer, which extends from an area of the top 10.1 of the multi-junction solar cell 10 adjoining the dielectric insulating layer 28 on the dielectric insulating layer 28 through the passage contact opening to the area of the bottom 10.2 of the multi-junction solar cell that is covered by the dielectric insulating layer 28.

(14) The metallic contact layer 22 is integrally bonded both with the top 10.1 of the multi-junction solar cell 10 and with the dielectric insulating layer 28.

(15) In the illustration of FIG. 2, another embodiment of the multi-junction solar cell is shown in a plan view of the front side 10.1. Only what is different from the illustration in FIG. 1 is explained below.

(16) The multi-junction solar cell 10 has exactly two passage contact openings 12, wherein the two passage contact openings 12 are each arranged at an end of a busbar and the metallic contact layers 22 are each electrically conductively connected to the contact rail.

(17) In regular intervals, contact fingers extend perpendicularly to the busbar across the top 10.1 of the multi-junction solar cell, wherein each contact finger is electroconductively connected to the busbar and/or one of the contact layers 22.

(18) In the illustration of FIG. 3, another embodiment of the multi-junction solar cell is shown in a plan view of the rear side 10.2. Only what is different to the illustration in FIG. 1 is explained below.

(19) The multi-junction solar cell 10 has exactly two passage contact openings 12. The two passage contact openings are surrounded by a contiguous dielectric insulating layer 28.

(20) The illustration in FIG. 4 shows a cross section in the area of the passage opening of a further embodiment of the multi-junction solar cell, wherein only what is different from the illustration in FIG. 1 is explained.

(21) The dielectric layer 28 and the metallic contact layer 22 are not shown for the sake of clarity.

(22) The multi-junction solar cell 10 comprises a III-V cover layer 30, for example an InGaP layer, on the second III-V sub-cell 20, which forms the top 10.1 of the multi-junction solar cell 10.

(23) The passage opening created by, for example, two etching processes and a laser ablation process has three areas that are in each case separated by one of the steps S1 or S2.

(24) The first area extends from the top 10.1 of the multi-junction solar cell 10 to the top 16.2 of the germanium sub-cell, wherein the first area has a diameter D1 that is constant or only slightly decreases in the direction of the germanium sub-cell.

(25) The second area extends from the top 16.1 of the germanium sub-cell 16 into the germanium sub-cell 16 and has a diameter D2 that is constant or decreases in the direction of the germanium substrate 14.

(26) The third area extends from the second step S2 to the bottom 10.2 of the multi-junction solar cell and has a diameter D3 that is constant or slightly decreases in the direction of the bottom 10.2.

(27) The invention being thus described, it will be obvious that the same may be varied in many ways. Such variations are not to be regarded as a departure from the spirit and scope of the invention, and all such modifications as would be obvious to one skilled in the art are to be included within the scope of the following claims.