Mixtures of cosmetic UV absorbers

Abstract

Disclosed are cosmetic or pharmaceutical composition comprising a UV filter combination of (a) an aqueous dispersion of 5,6,5′,6′-tetraphenyl-3,3′-(1,4-Phenylene)bis(1,2,4-Triazine) corresponding to the formula ##STR00001## in particulate form; and (b) the UV filters selected from (b.sub.1) Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine; (b.sub.2) Butyl Methoxydibenzoylmethane; (b.sub.3) Diethylhexyl Butamido Triazone; (b.sub.4) Ethylhexyl Triazone; (b.sub.5) Diethylamino Hydroxy Benzoyl Hexyl Benzoate; (b.sub.6) Ethyhexyl Methoxycinnamate; (b.sub.7) Ethylhexyl Salicylate; (b.sub.8) Homosalate; (b.sub.9) Octocrylene; (b.sub.10) Methylene Bis-Benzotriazolyl Tetramethylbutylphenol; (b.sub.11) Phenylbenzimidazole Sulfonic Acid; (b.sub.12) Titanium Dioxide; (b.sub.13) Tris-Biphenyl Triazine; and (b.sub.14) (2-{4-[2-(4-Diethylamino-2-hydroxy-benzoyl)-benzoyl]-piperazine-1-carbonyl}-phenyl)-(4-diethylamino-2-hydroxy-phenyl)-methanone; (b.sub.15) BBDAPT; Benzoic acid, 4,4′-[[6-[[3-[1,3,3,3-tetramethyl-1-[(trimethylsilyl)oxy]-1 disiloxanyl]propyl]amino]-1,3,5-triazine-2,4-diyl]diimino]bis-, dibutyl ester; (b.sub.16) benzylidene malonates; and (b.sub.17) merocyanine derivatives; (b.sub.18) Bis(butylbenzoate) diaminotriazine aminopropylsiloxane; (b.sub.19) Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine) encapsulated in a polymer matrix; (b.sub.20) 2-(2H-Benzotriazol-2-yl)-6-[(2-ethylhexyloxy)methyl]-4-methylphenol; and (b.sub.21) 2-Propenoic acid, 3-(4-methoxyphenyl)-, 2-methylphenyl ester.

Claims

1. A cosmetic or pharmaceutical composition comprising a UV filter combination of (a) an aqueous dispersion of 5,6,5′,6′-tetraphenyl-3,3′-(1,4-Phenylene)bis(1,2,4-Triazine) corresponding to the formula ##STR00048## in particulate form; and (b) UV filters selected from the group consisting of (b.sub.1) Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine; (b.sub.2) Butyl Methoxydibenzoylmethane; (b.sub.3) Diethylhexyl Butamido Triazone; (b.sub.4) Ethylhexyl Triazone; (b.sub.5) Diethylamino Hydroxy Benzoyl Hexyl Benzoate; (b.sub.6) Ethylhexyl Methoxycinnamate; (b.sub.7) Ethylhexyl Salicylate; (b.sub.8) Homosalate; (b.sub.9) Octocrylene; (b.sub.10) Methylene Bis-Benzotriazolyl Tetramethylbutylphenol; (b.sub.11) Phenylbenzimidazole Sulfonic Acid; (b.sub.12) Titanium Dioxide; (b.sub.13) Tris-Biphenyl Triazine; (b.sub.14) (2-{4-[2-(4-Diethylamino-2-hydroxy-benzoyl)-benzoyl]-piperazine-1-carbonyl}-phenyl)-(4-diethylamino-2-hydroxy-phenyl)-methanone; (b.sub.15) BBDAPT; Benzoic acid, 4,4′-[[6-[[3-[1,3,3,3-tetramethyl-1-[(trimethylsilyl)oxy]-1 disiloxanyl]propyl]amino]-1,3,5-triazine-2,4-diyl]diimino]bis-, dibutyl ester; (b.sub.16) benzylidene malonates; (b.sub.17) merocyanine derivatives; (b.sub.18) Bis(butylbenzoate) diaminotriazine aminopropylsiloxane; (b.sub.19) Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine encapsulated in a polymer matrix; (b.sub.20) 2-(2H-Benzotriazol-2-yl)-6-[(2-ethylhexy loxy)methyl]-4-methylphenol; and (b.sub.21) 2-Propenoic acid, 3-(4-methoxyphenyl)-, 2-methylphenyl ester, wherein the average particle size of component (a) is in the range from 0.02 to 2 micrometres; and wherein said composition contains from 0.1 to 15% by weight, based on the total weight of the composition, of the UV filter combination of (a) and (b); and wherein said composition contains at least two of the UV filters (b.sub.1)-(b.sub.21); and wherein said composition also contains a pharmaceutically or cosmetically acceptable excipient and wherein the compound of formula (1) is present in the micronized state.

2. The cosmetic or pharmaceutical composition according to claim 1, wherein component (a) represents an aqueous dispersion comprising the UV filter of formula (1) in a concentration range from 40 to 50 b.w.

3. The cosmetic or pharmaceutical composition according to claim 2, wherein the aqueous dispersion according to component (a) contains a grinding aid that is PPG-1-PEG-9 Lauryl Glycol Ether and the average particle size of formula (1) is in the range from 0.1 to 1.0 micrometres.

4. The cosmetic or pharmaceutical composition according to claim 1, wherein the aqueous dispersion according to component (a) contains a dispersing agent which is PPG-1-PEG-9 Lauryl Glycol Ether.

5. The cosmetic or pharmaceutical composition according to claim 1, wherein component (a) represents an aqueous dispersion comprising the UV filter of formula (1) encapsulated in a polymer carrier in a concentration range from 20 to 50% b.w.

6. The cosmetic or pharmaceutical composition according to claim 1, comprising (UV1) 5,6,5′,6′-tetraphenyl-3,3′-(1,4-Phenylene)bis(1,2,4-Triazine) (a) of formula (1); (UV2) Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine (b.sub.1); and (UV3) filters selected from the group consisting of (UV3.sub.1) Diethylamino Hydroxy Benzoyl Hexyl Benzoate (b.sub.5); (UV3.sub.2) Butyl Methoxydibenzoylmethane (b.sub.2); and (UV3.sub.3) Benzoic acid, 4,4′-[[6-[[3-[1,3,3,3-tetramethyl-1-[(trimethylsilyl)oxy]-1 disiloxanyl]propyl]amino]-1,3,5-triazine-2,4-diyl]diimino]bis-, dibutyl ester (b.sub.15).

7. The cosmetic or pharmaceutical composition according to claim 1, comprising (UV1) 5,6,5′,6′-tetraphenyl-3,3′-(1,4-Phenylene)bis(1,2,4-Triazine) (a) of formula (1); (UV2) Methylene Bis-Benzotriazolyl Tetramethylbutylphenol (b.sub.10); and (UV3) filters selected from the group consisting of (UV3.sub.1) Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine (b.sub.1); (UV3.sub.2) Diethylamino Hydroxy Benzoyl Hexyl Benzoate (b.sub.5); (UV3.sub.3) Butyl Methoxydibenzoylmethane (b.sub.2); and (UV3.sub.4) Benzoic acid, 4,4′-[[6-[[3-[1,3,3,3-tetramethyl-1-[(trimethylsilyl)oxy]-1 disiloxanyl]propyl]amino]-1,3,5-triazine-2,4-diyl]diimino]bis-, dibutyl ester.

8. The cosmetic or pharmaceutical composition according to claim 1, comprising (UV1) Phenylene Bis-Diphenyltriazine (a) of formula (1); (UV2) Diethylamino Hydroxy Benzoyl Hexyl Benzoate (b.sub.5); and (UV3) Butyl Methoxydibenzoylmethane (b.sub.2).

9. The cosmetic or pharmaceutical composition according to claim 1, comprising (UV1) 5,6,5′,6′-tetraphenyl-3,3′-(1,4-Phenylene)bis(1,2,4-Triazine) (a) of formula (1); (UV2) Ethylhexyl Triazone (b.sub.4); and UV filters (UV3) selected from the group consisting of (UV3.sub.1) Methylene Bis-Benzotriazolyl Tetramethylbutylphenol (b.sub.10); (UV3.sub.2) Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine (b.sub.1); (UV3.sub.3) Diethylamino Hydroxy Benzoyl Hexyl Benzoate (b.sub.5); (UV3.sub.4) Butyl Methoxydibenzoylmethane (b.sub.2); and (UV3.sub.5) Benzoic acid, 4,4′-[[6-[[3-[1,3,3,3-tetramethyl-1-[(trimethylsilyl)oxy]-1 disiloxanyl]propyl]amino]-1,3,5-triazine-2,4-diyl]diimino]bis-, dibutyl ester (b.sub.15).

10. The cosmetic or pharmaceutical composition according to claim 1, comprising (UV1) 5,6,5′,6′-tetraphenyl-3,3′-(1,4-Phenylene)bis(1,2,4-Triazine) (a) of formula (1); (UV2) Benzoic acid, 4,4′-[[6-[[3-[1,3,3,3-tetramethyl-1-[(trimethylsilyl)oxy]-1 disiloxanyl]propyl]amino]-1,3,5-triazine-2,4-diyl]diimino]bis-, dibutyl ester (b.sub.15); and UV filters (UV3) selected from the group consisting of (UV3.sub.1) Methylene Bis-Benzotriazolyl Tetramethylbutylphenol (b.sub.10); (UV3.sub.2) Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine (b.sub.1); (UV3.sub.3) Diethylamino Hydroxy Benzoyl Hexyl Benzoate (b.sub.5); and (UV3.sub.4) Butyl Methoxydibenzoylmethane (b.sub.2).

11. The cosmetic or pharmaceutical composition according to claim 1, comprising (UV1) 5,6,5′,6′-tetraphenyl-3,3′-(1,4-Phenylene)bis(1,2,4-Triazine) (a) of formula (1); (UV2) Methylene Bis-Benzotriazolyl Tetramethylbutylphenol (b.sub.10); (UV3) Ethylhexyl Triazone (b.sub.4); and UV filters (UV4) selected from the group consisting of (UV4.sub.1) Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine (b.sub.1); (UV4.sub.2) Diethylamino Hydroxy Benzoyl Hexyl Benzoate (b.sub.5); (UV4.sub.3) Butyl Methoxydibenzoylmethane (b.sub.2); and (UV4.sub.4) Benzoic acid, 4,4′-[[6-[[3-[1,3,3,3-tetramethyl-1-[(trimethylsilyl)oxy]-1 disiloxanyl]propyl]amino]-1,3,5-triazine-2,4-diyl]diimino]bis-, dibutyl ester (b.sub.15).

12. The cosmetic or pharmaceutical composition according to claim 1, comprising (UV1) 5,6,5′,6′-tetraphenyl-3,3′-(1,4-Phenylene)bis(1,2,4-Triazine) (a) of formula (1); (UV2) Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine (b.sub.1); (UV3) Ethylhexyl Triazone (b.sub.4); and the UV filters (UV4) selected from the group consisting of (UV4.sub.1) Diethylamino Hydroxy Benzoyl Hexyl Benzoate (b.sub.5); (UV4.sub.2) Butyl Methoxydibenzoylmethane (b.sub.2); and (UV4.sub.3) Benzoic acid, 4,4′-[[6-[[3-[1,3,3,3-tetramethyl-1-[(trimethylsilyl)oxy]-1 disiloxanyl]propyl]amino]-1,3,5-triazine-2,4-diyl]diimino]bis-, dibutyl ester (b.sub.15).

13. The cosmetic or pharmaceutical composition according to claim 1, comprising (UV1) 5,6,5′,6′-tetraphenyl-3,3′-(1,4-Phenylene)bis(1,2,4-Triazine) (a) of formula (1); (UV2) Diethylamino Hydroxy Benzoyl Hexyl Benzoate (b.sub.5); (UV3) Butyl Methoxydibenzoylmethane (b.sub.2); and (UV4) Ethylhexyl Triazone (b4).

14. The cosmetic or pharmaceutical composition according to claim 1, comprising (UV1) 5,6,5′,6′-tetraphenyl-3,3′-(1,4-Phenylene)bis(1,2,4-Triazine) (a) of formula (1); (UV2) Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine (b.sub.1); (UV3) Ethylhexyl Triazone (b.sub.4); the UV filters (UV4) selected from the group consisting of (UV4.sub.1)) Methylene Bis-Benzotriazolyl Tatramethylbutylphenyl (b.sub.10 (UV4.sub.2) Diethylamino Hydroxy Benzoyl Hexyl Benzoate (b.sub.5); and (UV4.sub.3) Butyl Methoxydibenzoylmethane (b.sub.2); and the UV filters (UV5) selected from the group consisting of (UV5.sub.1) Ethylhexyl Salicylate (b.sub.7); (UV5.sub.2) Tris-Biphenyl Triazine (b.sub.13); (UV5.sub.3) Octocrylene (b.sub.9); (UV5.sub.4) Diethylhexyl Butamido Triazone (b.sub.3); (UV5.sub.5) Phenylbenzimidazole Sulfonic Acid (b.sub.11); (UV5.sub.6) Titanium Dioxide (b.sub.12) (UV5.sub.7) Homosalate (b.sub.8); (UV5.sub.8) (2-{4-[2-(4-Diethylamino-2-hydroxy-benzoyl)-benzoyl]-piperazine-1-carbonyl}-phenyl)-(4-diethylamino-2-hydroxy-phenyl)-methanone (b.sub.14); and (UV5.sub.9) Benzoic acid, 4,4′-[[6-[[3-[1,3,3,3-tetramethyl-1-[(trimethylsilyl)oxy]-1 disiloxanyl]propyl]amino]-1,3,5-triazine-2,4-diyl]diimino]bis-, dibutyl ester (b.sub.15).

15. The cosmetic or pharmaceutical composition according to claim 1, comprising (UV1) 5,6,5′,6′-tetraphenyl-3,3′-(1,4-Phenylene)bis(1,2,4-Triazine) (a) of formula (1); (UV2) Methylene Bis-Benzotriazolyl Tetramethylbutylphenol (b.sub.10); (UV3) Ethylhexyl Triazone (b.sub.4); the UV filters (UV4) selected from the group consisting of (UV4.sub.1) Diethylamino Hydroxy Benzoyl Hexyl Benzoate (b.sub.5) (UV4.sub.2) Butyl Methoxydibenzoylmethane (b.sub.2); and the UV filters (UV5) selected from the group consisting of (UV5.sub.1) Ethylhexyl Salicylate (b.sub.1) (UV5.sub.2) Tris-Biphenyl Triazine (b.sub.13) (UV5.sub.3) Octocrylene (b.sub.9) (UV5.sub.4) Diethylhexyl Butamido Triazone (b.sub.3) (UV5.sub.5) Phenylbenzimidazole Sulfonic Acid (b.sub.11) (UV5.sub.6) Titanium Dioxide (b.sub.12) (UV5.sub.7) Homosalate (b.sub.8) (UV5.sub.8) (2-{4-[2-(4-Diethylamino-2-hydroxy-benzoyl)-benzoyl]-piperazine-1-carbonyl}-phenyl)-(4-diethylamino-2-hydroxy-phenyl)-methanone (b.sub.14); and (UV5.sub.9) Benzoic acid, 4,4′-[[6-[[3-[1,3,3,3-tetramethyl-1-[(trimethylsilyl)oxy]-1 disiloxanyl]propyl]amino]-1,3,5-triazine-2,4-diyl]diimino]bis-, dibutyl ester (bis).

16. The cosmetic or pharmaceutical composition according to claim 1, wherein the UV filters (b.sub.10) Methylene Bis-Benzotriazolyl Tetramethylbutylphenol, (b.sub.13) Tris-Biphenyl Triazine and (b.sub.14) (2-{4-[2-(4-Diethylamino-2-hydroxy-benzoyl)-benzoyl]-piperazine-1-carbonyl}-phenyl)-(4-diethylamino-2-hydroxy-phenyl)-methanone are present in the cosmetic or pharmaceutical composition in their micronized state.

17. The cosmetic or pharmaceutical composition according to claim 1, wherein (b) is (b.sub.1), (b.sub.4) and (b.sub.5).

18. The cosmetic or pharmaceutical composition according to claim 1, wherein the micronized UV absorber of formula (I) has an average particle size from 0.1 to 1.0 μm.

19. The cosmetic or pharmaceutical composition according to claim 1, wherein the composition comprises A or B: A: 1. potassium cetyl phosphate, 2. glyceryl stearate, 3. stearyl alcohol, 4. dibutyl adipate, 5. ethylhexyl benzoate, 6. di-C12-13 alkyl tartrate, 7. ethylhexyl triazone, 8. bis-ethylhexyloxyphenol methoxyphenyl triazine, 9. water, 10. glycerin, 11. xanthan gum, 12. aqueous dispersion of 5,6,5′,6′-tetraphenyl-3,3′-(1,4-Phenylene)bis(1,2,4-Triazine) and 13. phenoxyethanol, methylparaben, ethyl-paraben, butylparaben, propylparaben, isobutylparaben; B: 1. potassium cetyl phosphate, 2. glyceryl stearate, 3. stearyl alcohol, 4. ethylhexyl benzoate, 5. phenoxyethyl caprylate, 6. diisopropyl sebacate, 7. diethylamino hydroxybenzoyl hexyl benzoate, 8. ethylhexyl triazone, 9. bis-ethylhexyloxyphenol methoxyphenyl triazine 10. water, 11. glycerin, 12. xanthan gum, 13. tromethamine, 14. phenylbenzimidazol sulfonic acid, 15. 5,6,5′,6′-tetraphenyl-3,3′-(1,4-Phenylene)bis(1,2,4-Triazine), and 16. phenoxyethanol, methylparaben, ethyl-paraben, butylparaben, propylparaben, isobutylparaben.

20. The cosmetic or pharmaceutical composition according to claim 1, wherein the composition comprises A or B: A: TABLE-US-00029 Compound Amount (% w/w) Potassium Cetyl Phosphate 1.80 Glyceryl Stearate 2.50 Stearyl Alcohol 2.50 Dibutyl Adipate 5.00 Ethylhexyl Benzoate 8.00 Di-C12-13 Alkyl Tartrate 5.00 Ethylhexyl Traizone 3.00 Bis-ethylhexyloxyphenol 2.00 methoxyphenyl triazine Aqua Qsp to 100% Glycerin 10.00 Xanthan Gum 0.30 5,6,5′,6′-tetraphenyl-3,3′-(1,4- 2.00 Phenylene)bis(1,2,4-Triazine) Phenoxyethanol, Methylparaben, Ethyl- 0.80 paraben, Butylparaben, Propylparaben, Isobutylparaben B: TABLE-US-00030 Compound Amount (% w/w) Potassium Cetyl Phosphate 1.80 Glyceryl Stearate 2.50 Stearyl Alcohol 2.50 Ethylhexyl Benzoate 7.00 Phenoxyethyl Caprylate 5.00 Diisopropyl Sebacate 11.00 Diethylamino Hydroxybenzoyl Hexyl 10.00 Benzoate Ethylhexyl Triazone 3.00 Bis-ethylhexyloxyphenol 3.00 methoxyphenyl triazine Aqua Qsp to 100% Glycerin 10.00 Xanthan Gum 0.30 Tromethamine 0.92 Phenylbenzimidazol sulfonic acid 2.00 5,6,5′,6′-tetraphenyl-3,3′-(1,4- 2.30 Phenylene)bis(1,2,4-Triazine) Phenoxyethanol, Methylparaben, Ethyl- 0.80 paraben, Butylparaben, Propylparaben, Isobutylparaben.

21. The cosmetic or pharmaceutical composition according to claim 1, wherein said composition contains from 0.5 to 10% by weight, based on the total weight of the composition, of the UV absorber mixture (a) and (b).

22. A cosmetic or pharmaceutical composition comprising a UV filter combination of (a) an aqueous dispersion of 5,6,5′,6′-tetraphenyl-3,3′-(1,4-Phenylene)bis(1,2,4-Triazine) corresponding to the formula ##STR00049## in particulate form; and (b) UV filters selected from the group consisting of (b.sub.1) Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine; (b.sub.2) Butyl Methoxydibenzoylmethane; (b.sub.4) Ethylhexyl Triazone; (b.sub.6) Ethylhexyl Methoxycinnamate; (b.sub.7) Ethylhexyl Salicylate; (b.sub.8) Homosalate; (b.sub.9) Octocrylene; (b.sub.10) Methylene Bis-Benzotriazolyl Tetramethylbutylphenol; (b.sub.11) Phenylbenzimidazole Sulfonic Acid; (b.sub.14) (2-{4-[2-(4-Diethylamino-2-hydroxy-benzoyl)-benzoyl]-piperazine-1-carbonyl}-phenyl)-(4-diethylamino-2-hydroxy-phenyl)-methanone; (b.sub.15) BBDAPT; Benzoic acid, 4,4′-[[6-[[3-[1,3,3,3-tetramethyl-1-[(trimethylsilyl)oxy]-1 disiloxanyl]propyl]amino]-1,3,5-triazine-2,4-diyl]diimino]bis-, dibutyl ester; (b.sub.16) benzylidene malonates; (b.sub.17) merocyanine derivatives; (b.sub.18) Bis(butylbenzoate) diaminotriazine aminopropylsiloxane; (b.sub.19) Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine encapsulated in a polymer matrix; (b.sub.20) 2-(2H-Benzotriazol-2-yl)-6-[(2-ethylhexy loxy)methyl]-4-methylphenol; and (b.sub.21) 2-Propenoic acid, 3-(4-methoxyphenyl)-, 2-methylphenyl ester, wherein the average particle size of component (a) is in the range from 0.02 to 2 micrometres; and wherein said composition contains from 0.1 to 15% by weight, based on the total weight of the composition, of the UV absorber mixture (a) and (b); and wherein said composition contains at least two of the UV filters selected from (b.sub.1), (b.sub.2), (b.sub.4), (b.sub.6)-(b.sub.11), (b.sub.14)-(b.sub.17); and wherein said composition also contains a pharmaceutically or cosmetically acceptable excipient and wherein the compound of formula (1) is present in the micronized state.

23. A cosmetic or pharmaceutical composition comprising a UV filter combination of (a) an aqueous dispersion of 5,6,5′,6′-tetraphenyl-3,3′-(1,4-Phenylene)bis(1,2,4-Triazine) corresponding to the formula ##STR00050## in particulate form; and (b) UV filters (b.sub.1) Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine and (b.sub.4) Ethylhexyl Triazone; wherein the average particle size of component (a) is in the range from 0.02 to 2 micrometres; and wherein said composition contains from 0.1 to 15% by weight, based on the total weight of the composition, of the UV absorber mixture (a) and (b); and and wherein said composition also contains a pharmaceutically or cosmetically acceptable excipient and wherein the compound of formula (1) is present in the micronized state.

Description

(1) A. Preparation Examples

(2) Preparation of a Micronized UV Absorber Dispersion

(3) 100 parts of the compound of formula (1) is milled together with zirconium silicate bells (diameter: 0.1 to 4 mm) as grinding aids, a dispersing agent (15 parts PPG-1-PEG-9 Lauryl Glycol Ether) and water (85 parts) in a ball mill to a mean particle size of d.sub.50=130 nm. Benzoic acid is then added to the dispersion as preservative. A thickener may be optionally used (Xanthan gum, PVP)

(4) According to this method a micropigment dispersion of a UV absorber of formula (1) is obtained.

(5) B. Formulation Examples

(6) In the following Examples percentages relate to weight. The amounts of the micronized Phenylene Bis-Diphenyltriazine compounds used correspond to the pure substance.

(7) Legend:

(8) * particulate organic filter 50-200 nm, aqueous dispersion, active ingredient 40-50 w/w % ** particulate organic filter 50-200 nm, encapsulated active ingredient 20 w/w % *** particulate inorganic filter 10-200 nm, active ingredient 80-100 w/w %
O/W Formulation
Anionic System Emulsifier

(9) TABLE-US-00003 Example B1: Emulsion high Protection 1A 1B 1C 1D 1E 1F 1G 1H 1I % % % % % % % % % INCI-Name w/w w/w w/w w/w w/w w/w w/w w/w w/w Part A Cyclomethicone 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 Dibutyl Adipate 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 Tridecyl Trimellitate 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 C12-15 Alkyl Benzoate 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Ethylhexyl Palmitate 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 Glyceryl Stearate 1.50 1.50 1.50 1.50 1.50 1.50 1.50 1.50 1.50 Potassium Cetyl Phosphate 1.80 1.80 1.80 1.80 1.80 1.80 1.80 1.80 1.80 VP/Eicosene Copolymer 0.60 0.60 0.60 0.60 0.60 0.60 0.60 0.60 0.60 Part B Aqua Qs Qs Qs Qs Qs Qs Qs Qs Qs to to to to to to to to to 100 100 100 100 100 100 100 100 100 Acrylates/Palmeth-25 Acrylate 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 Copolymer Glycerin 6.00 6.00 6.00 6.00 6.00 6.00 6.00 6.00 6.00 Disodium EDTA 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 Part C Phenoxyethanol (and) Methylparaben 0.70 0.70 0.70 0.70 0.70 0.70 0.70 0.70 0.70 (and) Ethylparaben (and) Butylparaben (and) Propylparaben (and) Isobutylparaben Tocopheryl Acetate 0.30 0.30 0.30 0.30 0.30 0.30 0.30 0.30 0.30 Diethylamino Hydroxy Benzoyl Hexyl 2.00 Benzoate Ethylhexyl Triazone 2.00 2.00 2.00 2.00 BBDAPT (CAS Nb: 207562-42-3) 2.00 Ethylhexyl Methoxycinnamate 4.00 2.00 7.00 7.00 MBM-09 6.00 14.00 10.00 Bis-Ethylhexyloxyphenol 2.00 2.00 2.00 2.00 2.00 Methoxyphenyl Triazine Methylene Bis-Benzotriazolyl 3.00 3.00 3.00 3.00 Tetramethylbutylphenol * Phenylene Bis-Diphenyltriazine * 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 2.00

(10) TABLE-US-00004 Example B2: Sun Milk 2A 2B 2C 2D 2E 2F 2G 2H 2I % % % % % % % % % INCI-Name w/w w/w w/w w/w w/w w/w w/w w/w w/w Part A C12-15 Alkyl Benzoate 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 Dicaprylyl Carbonate 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 Tridecyl Trimellitate 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 Coco-Caprylate 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Isohexadecane 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 Cyclopentasiloxane 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 Stearic Acid 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 PEG-100 Stearate (and) Glyceryl 0.80 0.80 0.80 0.80 0.80 0.80 0.80 0.80 0.80 Stearate Potassium Cetyl Phosphate 1.30 1.30 1.30 1.30 1.30 1.30 1.30 1.30 1.30 PVP/Eicosene Copolymer 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Part B Aqua Qs Qs Qs Qs Qs Qs Qs Qs Qs to to to to to to to to to 100 100 100 100 100 100 100 100 100 Propylene Glycol 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 Xanthan Gum 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 Acrylates/C10-30 Alkyl Methacrylate 0.15 0.15 0.15 0.15 0.15 0.15 0.15 0.15 0.15 Copolymer Disodium EDTA 0.15 0.15 0.15 0.15 0.15 0.15 0.15 0.15 0.15 Part C Triethanolamine Qs Qs Qs Qs Qs Qs Qs Qs Qs Dimethicone 0.40 0.40 0.40 0.40 0.40 0.40 0.40 0.40 0.40 Phenoxyethanol (and) Methylparaben 0.70 0.70 0.70 0.70 0.70 0.70 0.70 0.70 0.70 (and) Ethylparaben (and) Butylparaben (and) Propylparaben (and) Isobutylparaben Tocopheryl Acetate 0.90 0.90 0.90 0.90 0.90 0.90 0.90 0.90 0.90 Diethylamino Hydroxy Benzoyl Hexyl 2.00 Benzoate Ethylhexyl Triazone 2.00 1.00 2.00 2.00 2.00 BBDAPT (CAS Nb: 207562-42-3) 1.00 2.00 Ethylhexyl Methoxycinnamate 7.00 7.00 Bis-Ethylhexyloxyphenol 2.00 2.00 2.00 2.00 2.00 Methoxylphenyl Triazine Methylene Bis-Benzotriazolyl 3.00 3.00 3.00 3.00 3.00 3.00 Tetramethylbutylphenol * MBM-09 10.00 10.00 10.00 10.00 10.00 10.00 10.00 Micronized Phenylene Bis- 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 2.00 Diphenyltriazine
O/W Formulation
Nonionic System Emulsifier

(11) TABLE-US-00005 Example B3: Sun cream 3A 3B 3C 3D 3E 3F 3G 3H 3I % % % % % % % % % INCI-Name w/w w/w w/w w/w w/w w/w w/w w/w w/w Part A Cetearyl glucoside 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 C12-15 Alkyl Benzoate 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 Triisodecyl Trimellitate 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 Dibutyl Adipate 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 Dicaprylyl Carbonate 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 Part B Water Qs Qs Qs Qs Qs Qs Qs Qs Qs to to to to to to to to to 100 100 100 100 100 100 100 100 100 Disodium EDTA 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 Glycerin 6.00 6.00 6.00 6.00 6.00 6.00 6.00 6.00 6.00 PVP/dimethylconylacrylate/ 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 polycarbamyl/polyglycol ester Sodium polyacrylate 0.70 0.70 0.70 0.70 0.70 0.70 0.70 0.70 0.70 Part C Dimethicone 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 Corn Starch modified 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 Part D Phenoxyethanol (and) Methylparaben 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 (and) Ethylparaben (and) Butylparaben (and) Propylparaben (and) Isobutylparaben Diethylamino Hydroxy Benzoyl Hexyl 2.00 Benzoate Ethylhexyl Triazone 2.00 2.00 2.00 2.00 BBDAPT (CAS Nb: 207562-42-3) 2.00 Ethylhexyl Methoxycinnamate 7.00 2.00 2.00 MBM-09 14.00 14.00 10.00 10.00 Bis-Ethylhexyloxyphenol 2.00 2.00 2.00 2.00 2.00 Methoxyphenyl Triazine Methylene Bis-Benzotriazolyl 3.00 3.00 3.00 3.00 Tetramethylbutylphenol * Bis-Ethylhexyloxyphenol 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 Methoxyphenyl Triazine ** Phenylene Bis-Diphenyltriazine * 10.00 10.00 10.00 10.00 6.00 3.00 2.00 8.00 6.00

(12) TABLE-US-00006 Example B4: Sun Cream 4A 4B 4C 4D 4E 4F 4G 4H 4I % % % % % % % % % INCI-Name w/w w/w w/w w/w w/w w/w w/w w/w w/w Part A Tribehenin PEG-20 esters 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 C12-15 Alkyl Benzoate 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 Tridecyl Trimellitate 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 Coco-Caprylate 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Dibutyl adipate 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 PPG-2 Myristyl Ether Propionate 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 Part B Water Qs Qs Qs Qs Qs Qs Qs Qs Qs to to to to to to to to to 100 100 100 100 100 100 100 100 100 PVP/dimethylconylacrylate/ 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 polycarbamyl/polyglycol ester Disodium EDTA 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 Sclerotium Gum 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 Ammonium 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 Acryldimethyltaurate/Beneth-25 Methacrylate Crosspolymer. Part C Cyclopentasiloxane (and) 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 cyclohexasiloxane Phenoxyethanol (and) Methylparaben 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 (and) Ethylparaben (and) Butylparaben (and) Propylparaben (and) Isobutylparaben Sodium Hydroxide (and) Water Qsp Qsp Qsp Qsp Qsp Qsp Qsp Qsp Qsp Diethylamino Hydroxy Benzoyl Hexyl 2.00 Benzoate Ethylhexyl Triazone 2.00 2.00 2.00 2.00 BBDAPT (CAS Nb: 207562-42-3) 2.00 Ethylhexyl Methoxycinnamate 7.00 7.00 Bis-Ethylhexyloxyphenol 2.00 2.00 2.00 2.00 2.00 Methoxyphenyl Triazine Methylene Bis-Benzotriazolyl 3.00 3.00 3.00 3.00 3.00 3.00 Tetramethylbutylphenol * MBM-09 10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00 Bis-Ethylhexyloxyphenol 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 Methoxyphenyl Triazine ** Phenylene Bis-Diphenyltriazine * 6.00 3.00 4.00 5.00 2.00 3.00 5.00 6.00 2.00

(13) TABLE-US-00007 Example B5: Daily Care with UV Protection 5A 5B 5C 5D 5E 5F 5G 5H 5I % % % % % % % % % INCI-Name w/w w/w w/w w/w w/w w/w w/w w/w w/w Part A Glyceryl Stearate 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 Glyceryl Stearate (and) PEG-100 3.50 3.50 3.50 3.50 3.50 3.50 3.50 3.50 3.50 Stearate C12-15 Alkyl Benzoate 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 Triisodecyl Trimellitate 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 Dicaprylyl Carbonate 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Cetyl Alcohol 1.50 1.50 1.50 1.50 1.50 1.50 1.50 1.50 1.50 Myristyl Myristate 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 Isopropyl Palmitate 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 Part B Aqua qs qs qs qs qs qs qs qs qs to to to to to to to to to 100 100 100 100 100 100 100 100 100 Propylene Glycol 7.50 7.50 7.50 7.50 7.50 7.50 7.50 7.50 7.50 Part C Phenoxyethanol (and) Methylparaben 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 (and) Butylparaben (and) Ethylparaben (and) Propylparaben Sodium Acrylates Copolymer (and) 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 Paraffinium Liquidum (and) PPG-1 Trideceth-6 Part D Citric Acid Qsp Qsp Qsp Qsp Qsp Qsp Qsp Qsp Qsp Bis-Ethylhexyloxyphenol 2.00 2.00 2.00 Methoxyphenyl Triazine Methylene Bis-Benzotriazolyl 3.00 3.00 3.00 Tetramethylbutylphenol * Tris-Biphenyl Triazine * 2.00 2.00 2.00 Methanone, 1,1′-(1,4-piperazinediyl)- 2.00 2.00 2.00 bis[1-[2-[4-(diethylamino)-2-hydroxy- benzoyl]phenyl]- CAS number (919803-06-8) * Benzophenone-3 3.00 3.00 3.00 3.00 3.00 Homosalate 10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00 Octocrylene 4.00 8.00 2.00 8.00 8.00 8.00 MBM-09 6.00 4.00 6.00 6.00 Ethylhexyl Salicylate 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 Butyl Methoxydibenzoylmethane 1.00 BBDAPT (CAS Nb: 207562-42-3) 2.00 Phenylene Bis-Diphenyltriazine * 2.00 2.00 6.00 2.00 5.00 4.00 2.00 3.00 5.00
O/W Formulation
Gel

(14) TABLE-US-00008 Example B6: Sunscreen Gel 6A 6B 6C 6D 6E 6F 6G 6H 6I % % % % % % % % % INCI-Name w/w w/w w/w w/w w/w w/w w/w w/w w/w Alcohol Denatured Qs Qs Qs Qs Qs Qs Qs Qs Qs to to to to to to to to to 100 100 100 100 100 100 100 100 100 Dibutyl Adipate 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 Triisodecyl Trimellitate 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Dicaprylyl Carbonate 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 Hydroxpropyl Cellulose 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Acrylates/Octylacrylamide Copolymer 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 C12-15 Alkyl Benzoate 10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00 Cyclotetrasiloxane (and) 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 Cyclopentasiloxane PEG/PPG-4/12 Dimethicone 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Diethylamino Hydroxy Benzoyl Hexyl 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Benzoate Ethylhexyl Triazone 2.00 2.00 2.00 2.00 BBDAPT (CAS Nb: 207562-42-3) 2.00 Ethylhexyl Methoxycinnamate 7.00 7.00 4.00 2.00 MBM-09 14.00 6.00 10.00 Bis-Ethylhexyloxyphenol 2.00 2.00 2.00 2.00 2.00 Methoxyphenyl Triazine Methylene Bis-Benzotriazolyl 3.00 3.00 3.00 3.00 Tetramethylbutylphenol * Tris-Biphenyl Triazine * 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 Phenylene Bis-Diphenyltriazine * 2.00 2.00 8.00 3.00 5.00 2.00 1.00 8.00 6.00

(15) TABLE-US-00009 Example B7: Clear Sunscreen Gel 7A 7B 7C 7D 7E 7F 7G 7H 7I % % % % % % % % % INCI-Name w/w w/w w/w w/w w/w w/w w/w w/w w/w SD Alcohol 40 Qs Qs Qs Qs Qs Qs Qs Qs Qs to to to to to to to to to 100 100 100 100 100 100 100 100 100 Dibutyl Adipate 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 Tridecyl Trimellitate 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Dicaprylyl Carbonate 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Hydroxypropyl Cellulose 1.70 1.70 1.70 1.70 1.70 1.70 1.70 1.70 1.70 Isopropyl PPG-2 Isodeceth-7 9.70 9.70 9.70 9.70 9.70 9.70 9.70 9.70 9.70 Carboxylate SD Alcohol 40 24.00 24.00 24.00 24.00 24.00 24.00 24.00 24.00 24.00 Fragrance 0.60 0.60 0.60 0.60 0.60 0.60 0.60 0.60 0.60 Aqua 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 Diethylamino Hydroxy Benzoyl 1.00 1.00 1.00 1.00 1.00 1.00 1.00 2.00 3.00 Hexyl Benzoate Ethylhexyl Triazone 2.00 2.00 2.00 2.00 BBDAPT (CAS Nb: 207562-42-3) 2.00 Ethylhexyl Methoxycinnamate 7.00 7.00 Bis-Ethylhexyloxyphenol 2.00 2.00 2.00 2.00 2.00 Methoxyphenyl Triazine Methylene Bis-Benzotriazolyl 3.00 3.00 3.00 3.00 3.00 3.00 Tetramethylbutylphenol * MBM-09 10.00 10.00 10.00 10.00 10.00 10.00 10.00 Tris-Biphenyl Triazine * 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 Phenylene Bis-Diphenyltriazine * 5.00 1.00 2.00 3.00 1.00 8.00 6.00 3.00 3.00
O/W formulation
Emulsifier Free

(16) TABLE-US-00010 Example B8: Emulsifier free 8A 8B 8C 8D 8E 8F 8G 8H 8I % % % % % % % % % INCI-Name w/w w/w w/w w/w w/w w/w w/w w/w w/w Ceteareth-20 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Xanthan Gum 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 Dicaprylyl Carbonate 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 Triisodecyl Trimellitate 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 Tridecyl Trimellitate 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Dibutyl Adipate 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 C12-15 Alkyl Benzoate 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Butylene Glycol 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 Dicaprylate/Dicaprate Cyclomethicone 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 VP/Hexadecene Copolymer 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 Glycerin 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 Vitamin E Acetate 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 PETP 0.40 0.40 0.40 0.40 0.40 0.40 0.40 0.40 0.40 Butylene Glycol (and) Iodopropynyl 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 Butylcarbamate Methylparaben 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 Phenoxyethanol 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 Ethanol 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 Parfume 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 Aqua ad ad ad ad ad ad ad ad ad 100 100 100 100 100 100 100 100 100 Diethylamino Hydroxy Benzoyl 1.00 Hexyl Benzoate Ethylhexyl Triazone 2.00 2.00 2.00 2.00 BBDAPT (CAS Nb: 207562-42-3) 2.00 Ethylhexyl Methoxycinnamate 7.00 7.00 7.00 MBM-09 14.00 14.00 Bis-Ethylhexyloxyphenol 2.00 2.00 2.00 2.00 2.00 Methoxyphenyl Triazine Methylene Bis-Benzotriazolyl 3.00 3.00 3.00 3.00 Tetramethylbutylphenol * Methanone, 1,1′-(1,4-piperazine- 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 diyl)bis[1-[2-[4-(diethylamino)-2- hydroxybenzoyl]phenyl]- CAS number (919803-06-8) * Phenylene Bis-Diphenyltriazine * 3.00 3.00 3.00 2.00 4.00 6.00 8.00 1.00 3.00

(17) TABLE-US-00011 Example B9: Emulsifier free 9A 9B 9C 9D 9E 9F 9G 9H 9I % % % % % % % % % INCI-Name w/w w/w w/w w/w w/w w/w w/w w/w w/w Sodium Carbomer 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 Xanthan Gum 0.30 0.30 0.30 0.30 0.30 0.30 0.30 0.30 0.30 Dibutyl Adipate 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 Tridecyl Trimellitate 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 Coco-Caprylate 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 C12-15 Alkyl Benzoate 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Dicaprylyl Carbonate 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Dimethicone 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 Shea Butter 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 EthylhexyloxyGlycerin 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 Glycerin 7.50 7.50 7.50 7.50 7.50 7.50 7.50 7.50 7.50 Glycinc Soja 1.50 1.50 1.50 1.50 1.50 1.50 1.50 1.50 1.50 Vitamin E Acetate 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 α-Glycosil Rutin 0.30 0.30 0.30 0.30 0.30 0.30 0.30 0.30 0.30 PETP 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 Trisodium EDTA 0.30 0.30 0.30 0.30 0.30 0.30 0.30 0.30 0.30 Ethanol 7.00 7.00 7.00 7.00 7.00 7.00 7.00 7.00 7.00 Aqua ad ad ad ad ad ad ad ad ad 100 100 100 100 100 100 100 100 100 Diethylamino Hydroxy Benzoyl 2.00 2.00 2.00 2.00 2.00 1.00 2.00 2.00 Hexyl Benzoate Ethylhexyl Triazone 2.00 2.00 2.00 2.00 BBDAPT (Cas Nb: 207562-42-3) 2.00 Ethylhexyl Methoxycinnamate 7.00 7.00 Bis-Ethylhexyloxyphenol 2.00 2.00 2.00 2.00 2.00 Methoxyphenyl Triazine Methylene Bis-Benzotriazolyl 3.00 3.00 3.00 3.00 3.00 3.00 Tetramethylbutylphenol * MBM-09 10.00 10.00 10.00 10.00 10.00 10.00 10.00 Methanone, 1,1′-(1,4-piperazine- 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 diyl)bis[1-[2-[4-(diethylamino)-2-hy- droxybenzoyl]phenyl]- CAS number (919803-06-8) * Phenylene Bis-Diphenyltriazine * 1.00 3.00 5.00 7.00 4.00 2.00 2.00 1.00 5.00
Spray Formulation
Classic

(18) TABLE-US-00012 Example B10: Sun spray 10A 10B 10C 10D 10E 10F 10G 10H 10I % % % % % % % % % INCI-Name w/w w/w w/w w/w w/w w/w w/w w/w w/w Part A Butylene Glycol 10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00 Dicaprylate/Dicaprate C18-36 Acid Triglyceride 0.70 0.70 0.70 0.70 0.70 0.70 0.70 0.70 0.70 Ceteareth-20 0.60 0.60 0.60 0.60 0.60 0.60 0.60 0.60 0.60 Dibutyl Adipate 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 Triisodecyl Trimellitate 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 Dicaprylyl Carbonate 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 C12-15 Alkyl Benzoate 6.00 6.00 6.00 6.00 6.00 6.00 6.00 6.00 6.00 Taurine 0.40 0.40 0.40 0.40 0.40 0.40 0.40 0.40 0.40 VP/Hexadecene Copolymer 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 Part B Aqua Qs Qs Qs Qs Qs Qs Qs Qs Qs to to to to to to to to to 100 100 100 100 100 100 100 100 100 Glycerin 6.00 6.00 6.00 6.00 6.00 6.00 6.00 6.00 6.00 Methylpropanediol 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Acrylates/C10-30 Alkyl Acrylate 0.18 0.18 0.18 0.18 0.18 Crosspolymer Acrylates/10-30 Alkyl 0.18 0.18 0.18 0.18 Methacrylate Copolymer Trisodium EDTA 0.10 0.10 0.10 0.10 0.10 0.10 0.10 0.10 0.10 Part C Alcohol Denatured 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 Phenoxyethanol (and) Methyl- 0.70 0.70 0.70 0.70 0.70 0.70 0.70 0.70 0.70 paraben (and) Ethylparaben (and) Butylparaben (and) Propyl- paraben (and) Isobutylparaben Tocopheryl Acetate 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 Diethylamino Hydroxy Benzoyl 1.00 1.00 1.00 2.00 2.00 1.00 1.00 2.00 Hexyl Benzoate Ethylhexyl Triazone 1.00 2.00 2.00 2.00 BBDAPT (CAS Nb: 207562-42-3) 2.00 Ethylhexyl Methoxycinnamate 2.00 2.00 Bis-Ethylhexyloxyphenol 2.00 2.00 2.00 2.00 1.00 Methoxyphenyl Triazine Methylene Bis-Benzotriazolyl 2.00 2.00 3.00 3.00 3.00 2.00 Tetramethylbutylphenol * MBM-09 10.00 10.00 10.00 10.00 10.00 5.00 5.00 Bis-Ethylhexyloxyphenol 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 Methoxyphenyl Triazine ** Tris-Biphenyl Triazine * 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 Methanone, 1,1′-(1,4-pipera- 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 zinediyl)bis[1-[2-[4-(diethylamino)- 2-hydroxybenzoyl]phenyl]- CAS number (919803-06-8) * Phenylene Bis-Diphenyltriazine * 1.00 1.00 1.00 3.00 4.00 1.00 1.00 2.00 4.00
Spray Formulation
Foaming

(19) TABLE-US-00013 Example 11: Sun spray foaming 11A 11B 11C 11D 11E 11F 11G 11H 11I % % % % % % % % % INCI-Name w/w w/w w/w w/w w/w w/w w/w w/w w/w Part A Behenyl Alcohol (and) Glyceryl 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 Stearate (and) Glyceryl Stearate Citrate (and) Disodium Ethylene Dicocamide PEG-15 Disulfate Isotrideceth-12 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 Ethylhexyl Salicylate 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 Hydrogenated Coco-glycerides 1.50 1.50 1.50 1.50 1.50 1.50 1.50 1.50 1.50 C12-15 Alkyl Benzoate 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 Part B Aqua 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 Glycerin 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 Galactoarabinan 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 Part C Disodium Ethylene Dicocamide 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 PEG-15 Disulfate (and) Sodium Lauroyl Lactylate Water Qs Qs Qs Qs Qs Qs Qs Qs Qs to to to to to to to to to 100 100 100 100 100 100 100 100 100 Part D Phenoxyethanol (and) Methyl- 0.70 0.70 0.70 0.70 0.70 0.70 0.70 0.70 0.70 paraben (and) Ethylparaben (and) Butylparaben (and) Propylparaben (and) Isobutylparaben Tocopheryl Acetate 0.60 0.60 0.60 0.60 0.60 0.60 0.60 0.60 0.60 Diethylamino Hydroxy Benzoyl 2.00 2.00 0.00 0.00 0.00 0.00 0.00 2.00 0.00 Hexyl Benzoate Ethylhexyl Triazone 2.00 2.00 2.00 2.00 BBDAPT (CAS Nb: 207562-42-3) 2.00 Ethylhexyl Methoxycinnamate 7.00 7.00 7.00 MBM-09 14.00 14.00 Bis-Ethylhexyloxyphenol 2.00 2.00 2.00 2.00 2.00 Methoxyphenyl Triazine Methylene Bis-Benzotriazolyl 3.00 3.00 3.00 4.00 Tetramethylbutylphenol * Titanium Dioxide *** 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 Phenylene Bis-Diphenyltriazine * 2.00 1.00 2.00 6.00 1.00 3.00 2.00 8.00 2.00
Spray Formulation
Continuous

(20) TABLE-US-00014 Example B12: Continuous Spray Fresh Cooling 12A 12B 12C 12D 12E 12F 12G 12H 12I % % % % % % % % % INCI-Name w/w w/w w/w w/w w/w w/w w/w w/w w/w SD-Alcohol 40 58.00 58.00 58.00 58.00 58.00 58.00 58.00 58.00 58.00 Diethylhexyl 2,6-Naphthalate 6.00 6.00 6.00 6.00 6.00 6.00 6.00 6.00 6.00 Trisiloxane (and) Dimethicone 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 Acrylates/Octylacrylamide 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 Copolymer PPG-5-Ceteth-20 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 Tocopherol Acetate 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Ascorbyl Palmitate 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 Retinyl Palmitate 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 Cyclopentasiloxane (and) 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Acrylates/Dimethicone Copolymer Propylene Glycol (and) 1.50 1.50 1.50 1.50 1.50 1.50 1.50 1.50 1.50 Ethoxydiglycol (and) Menthyl PCA (and) Lauryl PCA Parfume q.s. q.s. q.s. q.s. q.s. q.s. q.s. q.s. q.s. Aqua ad ad ad ad ad ad ad ad ad 100 100 100 100 100 100 100 100 100 Propellent Qs Qs Qs Qs Qs Qs Qs Qs Qs Diethylamino Hydroxy Benzoyl 2.00 Hexyl Benzoate Ethylhexyl Triazone 2.00 2.00 2.00 2.00 BBDAPT (CAS Nb: 207562-42-3) 2.00 Ethylhexyl Methoxycinnamate 4.00 7.00 Bis-Ethylhexyloxyphenol 2.00 2.00 2.00 2.00 2.00 Methoxyphenyl Triazine Methylene Bis-Benzotriazolyl 3.00 3.00 3.00 3.00 3.00 3.00 Tetramethylbutylphenol * MBM-09 10.00 10.00 8.00 10.00 10.00 10.00 10.00 Titanium Dioxide *** 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 Phenylene Bis-Diphenyltriazine * 1.00 4.00 3.00 6.00 2.00 6.00 1.00 6.00 2.00
W/O Formulation

(21) TABLE-US-00015 Example B13: Sunmilk for highly sensitive skins 13A 13B 13C 13D 13E 13F 13G 13H 13I % % % % % % % % % INCI-Name w/w w/w w/w w/w w/w w/w w/w w/w w/w Part A C12-15 Alky Benzoate 3.50 3.50 3.50 3.50 3.50 3.50 3.50 3.50 3.50 Cyclopentasiloxane (and) 9.00 9.00 9.00 9.00 9.00 9.00 9.00 9.00 9.00 Cyclohexasiloxane Isododecane 4.50 4.50 4.50 4.50 4.50 4.50 4.50 4.50 4.50 PEG-30 Dipolyhydroxystearate 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 PEG-45/Dodecyl Glycol 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Copolymer Hydrogenated Castor Oil 1.50 1.50 1.50 1.50 1.50 1.50 1.50 1.50 1.50 Tribehenin 0.40 0.40 0.40 0.40 0.40 0.40 0.40 0.40 0.40 Disteardimonium Hectorite 0.60 0.60 0.60 0.60 0.60 0.60 0.60 0.60 0.60 Part B Aqua Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 Glycerin 10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00 Part C Phenoxyethanol (and) 0.70 0.70 0.70 0.70 0.70 0.70 0.70 0.70 0.70 Methylparaben (and) Ethylparaben (and) Butylparaben (and) Propylparaben (and) Isobutylparaben Tocopheryl Acetate 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 Silica Dimethyl Silylate 0.60 0.60 0.60 0.60 0.60 0.60 0.60 0.60 0.60 Ethylhexyl Triazone 1.00 2.00 2.00 2.00 BBDAPT 1.00 (CAS Nb: 207562-42-3) Bis-Ethylhexyloxyphenol 1.00 1.00 1.00 1.00 2.00 2.00 1.00 1.00 2.00 Methoxyphenyl Triazine Methylene Bis-Benzotriazolyl 3.00 3.00 4.00 3.00 3.00 3.00 3.00 3.00 3.00 Tetramethylbutylphenol * Bis-Ethylhexyloxyphenol 1.00 1.00 1.00 1.00 1.00 1.00 Methoxyphenyl Triazine ** Tris-Biphenyl Triazine * 1.00 1.00 2.00 Methanone, 1,1′-(1,4- 1.00 1.00 2.00 1.00 1.00 1.00 1.00 1.00 piperazinediyl)bis[1- [2-[4-(diethylamino)- 2-hydroxybenzoyl]phenyl]- CAS number (919803-06-8) * Butyl 1.00 1.00 1.00 1.00 2.00 3.00 Methoxydibenzoylmethane Octocrylene 8.00 8.00 8.00 3.00 MBM-09 6.00 Ethylhexyl Salicylate 5.00 5.00 5.00 Diethylhexyl Butamido Triazone 1.00 1.00 1.00 Phenylbenzimidazole 2.00 2.00 2.00 Sulfonic Acid Phenylene Bis- 2.00 2.00 5.00 1.00 2.00 2.00 1.00 1.00 6.00 Diphenyltriazine *

(22) TABLE-US-00016 Example B14: Sun Milk W/O 14A 14B 14C 14D 14E 14F 14G 14H 14I % % % % % % % % % INCI-Name w/w w/w w/w w/w w/w w/w w/w w/w w/w Part A Butylen Glycol 5.50 5.50 5.50 5.50 5.50 5.50 5.50 5.50 5.50 Dicaprylate/Dicaprate C18-36 Acid Triglyceride 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 Isopropyl Stearate 3.50 3.50 3.50 3.50 3.50 3.50 3.50 3.50 3.50 C12-15 Alkyl Benzoate 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 Polyglyceryl-2 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 Dipolyhydroxystearate Diethylhexyl Butamido Triazone 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 Cetyl Dimethicone 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 Part B Aqua Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 Butylene Glycol 3.50 3.50 3.50 3.50 3.50 3.50 3.50 3.50 3.50 Glycerin 3.50 3.50 3.50 3.50 3.50 3.50 3.50 3.50 3.50 Aluminum Starch 0.40 0.40 0.40 0.40 0.40 0.40 0.40 0.40 0.40 Octenylsuccinate Magnesium Sulfate 0.30 0.30 0.30 0.30 0.30 0.30 0.30 0.30 0.30 Heptahydrate Part C Alcohol Denatured 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 BHT 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 Phenoxyethanol (and) 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 Methylparaben (and) Ethylparaben (and) Butylparaben (and) Propylparaben (and) Isobutylparaben Tocopheryl Acetate 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Diethylamino Hydroxy Benzoyl 1.00 1.00 1.00 Hexyl Benzoate Ethylhexyl Triazone 1.50 1.00 2.00 2.00 2.00 BBDAPT 2.00 (CAS Nb: 207562-42-3) Ethylhexyl Methoxycinnamate 4.00 1.00 1.00 3.00 6.00 Bis-Ethylhexyloxyphenol 2.00 1.00 2.00 2.00 2.00 Methoxyphenyl Triazine Methylene Bis-Benzotriazolyl 2.00 Tetramethylbutylphenol * MBM-09 8.00 5.00 5.00 Tris-Biphenyl Triazine * 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Ethylhexyl Salicylate 5.00 5.00 Diethylhexyl Butamido Triazone 1.00 1.00 Phenylbenzimidazole 2.00 2.00 Sulfonic Acid Titanium Dioxide *** 2.00 Homosalate 10.00 5.00 Phenylene Bis- 4.00 3.00 2.00 3.00 3.00 1.00 3.00 4.00 4.00 Diphenyltriazine *
W/Si Formulation

(23) TABLE-US-00017 Example B15: W/Si sun cream 15A 15B 15C 15D 15E 15F 15G 15H 15I % % % % % % % % % INCI-Name w/w w/w w/w w/w w/w w/w w/w w/w w/w Part A Cyclopentasiloxane (and) 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 Dimethicone/Vinyl Dimethicone Crosspolymer PEG-10 Dimethicone 0.30 0.30 0.30 0.30 0.30 0.30 0.30 0.30 0.30 Dimethicone (and) 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 Dimethicone/PEG-10/15 Crosspolymer Dimethicone 10.70 10.70 10.70 10.70 10.70 10.70 10.70 10.70 10.70 Part B 1,3-Butylen Glycol 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 Sodium Citrate 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 Ethyl Alcohol 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 Sodium Chloride 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 Aqua Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 Diethylamino Hydroxy Benzoyl 2.00 Hexyl Benzoate Ethylhexyl Triazone 1.00 1.00 2.00 2.00 1.00 BBDAPT 2.00 (CAS Nb: 207562-42-3) Ethylhexyl Methoxycinnamate 3.00 2.00 1.00 MBM-09 2.00 8.00 2.00 Bis-Ethylhexyloxyphenol 2.00 2.00 2.00 2.00 2.00 Methoxyphenyl Triazine Methylene Bis-Benzotriazolyl 3.00 3.50 3.00 3.00 Tetramethylbutylphenol * Isoamyl p-Methoxycinnamate 3.00 1.00 1.00 1.00 1.00 1.00 3.50 1.00 1.00 4-Methylbenzylidene Camphor 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Polysilicone-15 2.00 1.00 1.00 1.00 1.00 1.00 2.00 1.00 1.00 Disodium Phenyl 1.00 3.00 3.00 1.00 2.00 2.00 3.50 1.00 1.00 Dibenzylmidazole Tetrasulfonate Phenylene Bis- 5.00 2.00 2.00 3.00 2.00 2.00 2.00 2.00 3.00 Diphenyltriazine *

(24) TABLE-US-00018 Example B16: W/Si sun cream 16A 16B 16C 16D 16E 16F 16G 16H 16I % % % % % % % % % INCI-Name w/w w/w w/w w/w w/w w/w w/w w/w w/w Part Cyclopentasiloxane (and) 10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00 A PEG/PPG-18/18 Dimethicone Cyclomethicone 9.00 9.00 9.00 9.00 9.00 9.00 9.00 9.00 9.00 Cyclomethicone (and) 3.50 3.50 3.50 3.50 3.50 3.50 3.50 3.50 3.50 Trimethylsiloxysilicate Cyclopentasiloxane (and) 7.00 7.00 7.00 7.00 7.00 7.00 7.00 7.00 7.00 Dimethicone Crosspolymer Part Divinyldimethicone/Dimethicone 2.30 2.30 2.30 2.30 2.30 2.30 2.30 2.30 2.30 B Copolymer (and) C12-13 Pareth-23 (and) C12-13 Pareth-3 Sodium Chloride 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 Aqua Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 Merocyanine 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Diethylamino Hydroxy Benzoyl 1.00 Hexyl Benzoate Ethylhexyl Triazone 2.50 2.50 2.00 2.00 1.00 BBDAPT (CAS Nb: 207562-42-3) 1.00 Ethylhexyl Methoxycinnamate 7.00 7.00 4.00 Bis-Ethylhexyloxyphenol 2.00 2.00 2.00 2.00 2.00 Methoxyphenyl Triazine MBM-09 14.00 8.00 10.00 Methylene Bis-Benzotriazolyl 3.00 3.00 3.00 3.00 Tetramethylbutylphenol * Phenylene Bis-Diphenyltriazine * 1.00 1.00 2.00 4.00 2.00 1.00 1.00 3.00 3.00
Lipstick Formulation

(25) TABLE-US-00019 Example B16: Lipstick 16A 16B 16C 16D 16E 16F 16G 16H 16I % % % % % % % % % INCI-Name w/w w/w w/w w/w w/w w/w w/w w/w w/w Microcristallina Wax 7.00 7.00 7.00 7.00 7.00 7.00 7.00 7.00 7.00 Cera Carnauba 2.50 2.50 2.50 2.50 2.50 2.50 2.50 2.50 2.50 Candelilla Cera 6.50 6.50 6.50 6.50 6.50 6.50 6.50 6.50 6.50 Cetyl Alcohol 1.50 1.50 1.50 1.50 1.50 1.50 1.50 1.50 1.50 Lanolin Oil 9.00 9.00 9.00 9.00 9.00 9.00 9.00 9.00 9.00 Bis-Diglyceryl Polyacyladipate-2 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 Avocado Oil 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 Pentaerythrityl Tetraisostearate 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 Myristyl Lactate 6.00 6.00 6.00 6.00 6.00 6.00 6.00 6.00 6.00 Jojoba Oil 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 Hydrogenated Polydecene 13.00 13.00 13.00 13.00 13.00 13.00 13.00 13.00 13.00 VP/Hexadecene Copolymer 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 PEG-45/Dodecyl Glycol Copolymer 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Interference Pigments 6.80 6.80 6.80 6.80 6.80 6.80 6.80 6.80 6.80 Tocopheryl Acetate 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 BHT 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 Preservatives q.s. q.s. q.s. q.s. q.s. q.s. q.s. q.s. q.s. Parfume. Aroma q.s. q.s. q.s. q.s. q.s. q.s. q.s. q.s. q.s. Water QS to 100 QS to 100 QS to 100 QS to 100 QS to 100 QS to 100 QS to 100 QS to 100 QS to 100 Merocyanine 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Diethylamino Hydroxy Benzoyl 3.00 Hexyl Benzoate Ethylhexyl Triazone 2.00 1.00 2.00 2.00 2.00 Ethylhexyl Methoxycinnamate 5.00 5.00 Bis-Ethylhexyloxyphenol 2.00 2.00 2.00 2.00 2.00 Methoxyphenyl Triazine Methylene Bis-Benzotriazolyl 3.00 3.00 3.00 3.00 3.00 3.00 Tetramethylbutylphenol * MBM-09 10.00 10.00 10.00 10.00 8.00 10.00 8.00 Phenylene Bis-Diphenyltriazine * 4.00 3.00 2.00 4.00 1.00 1.00 3.00 3.00 2.00
Aqueous Gel Formulation

(26) TABLE-US-00020 Example B17: Clear Gel 17A 17B 17C 17D 17E 17F 17G 17H 17I % % % % % % % % % INCI-Name w/w w/w w/w w/w w/w w/w w/w w/w w/w SD Alcohol 40 44.07 44.07 44.07 44.07 44.07 44.07 44.07 44.07 44.07 Hydroxypropyl Cellulose 1.67 1.67 1.67 1.67 1.67 1.67 1.67 1.67 1.67 Isopropyl PPG-2-Isodeceth-7 9.64 9.64 9.64 9.64 9.64 9.64 9.64 9.64 9.64 Carboxylate SD Alcohol 40 24.30 24.30 24.30 24.30 24.30 24.30 24.30 24.30 24.30 Fragrance 0.60 0.60 0.60 0.60 0.60 0.60 0.60 0.60 0.60 Deionized Water Qsp Qsp Qsp Qsp Qsp Qsp Qsp Qsp Qsp 100 100 100 100 100 100 100 100 100 Citric Acid (and) Silver Citrate 0.10 0.10 0.10 0.10 0.10 0.10 0.10 0.10 0.10 Sclerotium Gum 0.10 0.10 0.10 0.10 0.10 0.10 0.10 0.10 0.10 Merocyanine 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Diethylamino Hydroxy Benzoyl 1.00 Hexyl Benzoate Ethylhexyl Triazone 2.00 2.00 2.00 2.00 2.00 Ethylhexyl Methoxycinnamate 7.00 7.00 4.00 7.00 Bis-Ethylhexyloxyphenol Methoxy- 2.00 2.00 2.00 2.00 2.00 phenyl Triazine MBM-09 14.00 6.00 Methylene Bis-Benzotriazolyl Tetra- 3.00 3.00 3.00 3.00 methylbutylphenol * Bis-Ethylhexyloxyphenol 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 Methoxyphenyl Triazine ** Phenylene Bis-Diphenyltriazine * 4.00 4.00 1.00 2.00 4.00 5.00 2.00 2.00 2.00
Make-Up Formulation

(27) TABLE-US-00021 Example 18: Foundations; O/W forms 18A 18B 18C 18D 18E 18F 18G 18H 18I % % % % % % % % % INCI-Name w/w w/w w/w w/w w/w w/w w/w w/w w/w Butylene Glycol 6.50 6.50 6.50 6.50 6.50 6.50 6.50 6.50 6.50 Magnesium Aluminum Silicate 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 Sodium Carboxymethylcellulose 0.30 0.30 0.30 0.30 0.30 0.30 0.30 0.30 0.30 Xanthan Gum 0.10 0.10 0.10 0.10 0.10 0.10 0.10 0.10 0.10 Triethanolamine 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Polysorbate 20 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 Sericite 7.00 7.00 7.00 7.00 7.00 7.00 7.00 7.00 7.00 Iron oxides 1.10 1.10 1.10 1.10 1.10 1.10 1.10 1.10 1.10 Spherical Silica 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Cetearyl octanoate 10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00 Stearic Acid 2.50 2.50 2.50 2.50 2.50 2.50 2.50 2.50 2.50 Glyceryl stearate 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 Tridecyl trimellilate 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 Water qsp qsp qsp qsp qsp qsp qsp qsp qsp Preservative 0.55 0.55 0.55 0.55 0.55 0.55 0.55 0.55 0.55 Merocyanine 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Diethylamino Hydroxy Benzoyl 1.00 Hexyl Benzoate Ethylhexyl Triazone 2.00 2.00 2.00 2.00 2.00 Ethylhexyl Methoxycinnamate 7.00 7.00 Bis-Ethylhexyloxyphenol 2.00 2.00 2.00 2.00 2.00 Methoxyphenyl Triazine Methylene Bis-Benzotriazolyl 3.00 3.00 3.00 2.00 3.00 3.00 Tetramethylbutylphenol * MBM-09 10.00 10.00 10.00 10.00 10.00 10.00 10.00 Bis-Ethylhexyloxyphenol 2.00 2.00 3.00 2.00 2.00 2.00 2.00 2.00 2.00 Methoxyphenyl Triazine ** Phenylene Bis-Diphenyltriazine * 2.00 4.00 2.00 2.00 4.00 1.00 3.00 2.00 4.00
Pickering Formulation

(28) TABLE-US-00022 Example B19: Pickering Emulsions 19A 19B 19C 19D 19E 19F 19G 19H 19I % % % % % % % % % INCI-Name w/w w/w w/w w/w w/w w/w w/w w/w w/w Octyidodecanol 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 Butylen Glycol Caprylate/Caprate 4.50 4.50 4.50 4.50 4.50 4.50 4.50 4.50 4.50 Dicaprylyl Ether 2.50 2.50 2.50 2.50 2.50 2.50 2.50 2.50 2.50 Dicaprylyl Carbonate 6.00 6.00 6.00 6.00 6.00 6.00 6.00 6.00 6.00 Hydroxyoctacosanyl 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 Hydroxystearate Disteardimonium Hectorit 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Dimethicone 2.50 2.50 2.50 2.50 2.50 2.50 2.50 2.50 2.50 Distarch Phosphate 1.50 1.50 1.50 1.50 1.50 1.50 1.50 1.50 1.50 NaCl 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Glycerin 10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00 Trisodium EDTA 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Porpylene Carbonate 0.33 0.33 0.33 0.33 0.33 0.33 0.33 0.33 0.33 Phenoxyethanol 0.40 0.40 0.40 0.40 0.40 0.40 0.40 0.40 0.40 Diazolidinyl Urea 0.28 0.28 0.28 0.28 0.28 0.28 0.28 0.28 0.28 Parfume 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 Water ad ad ad ad ad ad ad ad ad 100 100 100 100 100 100 100 100 100 Merocyanine 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Diethylamino Hydroxy Benzoyl 2.00 Hexyl Benzoate Ethylhexyl Triazone 2.00 2.00 2.00 2.00 2.00 Ethylhexyl Methoxycinnamate 7.00 7.00 5.00 5.00 MBM-09 4.00 10.00 14.00 Bis-Ethylhexyloxyphenol 2.00 2.00 2.00 2.00 2.00 Methoxyphenyl Triazine Methylene Bis-Benzotriazolyl 3.00 3.00 2.00 4.00 Tetramethylbutylphenol * Tris-Biphenyl Triazine * 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 Phenylene Bis-Diphenyltriazine * 2.00 3.00 4.00 2.00 2.00 3.00 2.00 4.00 5.00
Microemulsion Formulation

(29) TABLE-US-00023 Example B20: MICROEMULSION LOTION 20A 20B 20C 20D 20E 20F 20G 20H 20I % % % % % % % % % INCI-Name w/w w/w w/w w/w w/w w/w w/w w/w w/w PPG-26-Buteth-26 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 Ceteareth 20 10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00 C12-15 Alkyl Benzoate 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 Oleth-5 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 PPG-11 Stearyl Ether 10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00 Aluminum Chlorohydrex PG 15.00 15.00 15.00 15.00 15.00 15.00 15.00 15.00 15.00 Water Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 Merocyanine 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Diethylamino Hydroxy Benzoyl 2.00 Hexyl Benzoate Ethylhexyl Triazone 2.00 2.00 2.00 2.00 2.00 Ethylhexyl Methoxycinnamate 7.00 7.00 Bis-Ethylhexyloxyphenol Methoxy- 2.00 2.00 2.00 2.00 2.00 phenyl Triazine Methylene Bis-Benzotriazolyl Tetra- 3.00 3.00 3.00 3.00 3.00 3.00 methylbutylphenol * MBM-09 10.00 10.00 10.00 10.00 5.00 5.00 10.00 Tris-Biphenyl Triazine * 2.00 2.00 2.00 2.00 1.00 2.00 2.00 2.00 2.00 Phenylene Bis-Diphenyltriazine * 4.00 3.00 1.00 2.00 2.00 1.00 1.00 2.00 4.00
Cationic Formulation

(30) TABLE-US-00024 Example B21: Cationic O/W sun cream 21A 21B 21C 21D 21E 21F 21G 21H 21I % % % % % % % % % INCI-Name w/w w/w w/w w/w w/w w/w w/w w/w w/w Part Distearyldimonium Chloride 3.50 3.50 3.50 3.50 3.50 3.50 3.50 3.50 3.50 A Glyceryl Stearate 1.50 1.50 1.50 1.50 1.50 1.50 1.50 1.50 1.50 Stearyl Alcohol 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 C12-15 Alkyl Benzoate 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 Diethylhexyl Carbonate 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 Cetyl Ricinoleate 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Triisostearin 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Part Aqua Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 B Glycerin 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 Trisodium EDTA 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 Part Phenoxyethanol (and) 0.70 0.70 0.70 0.70 0.70 0.70 0.70 0.70 0.70 C Methylparaben (and) Ethylparaben (and) Butylparaben (and) Propylparaben (and) Isobutylparaben Tocopheryl Acetate 0.80 0.80 0.80 0.80 0.80 0.80 0.80 0.80 0.80 Merocyanine 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Diethylamino Hydroxy Benzoyl 1.00 Hexyl Benzoate Ethylhexyl Triazone 2.00 2.00 2.00 2.00 2.00 Ethylhexyl Methoxycinnamate 1.00 6.00 7.00 7.00 MBM-09 6.00 14.00 8.00 Bis-Ethylhexyloxyphenol 2.00 2.00 2.00 2.00 2.00 Methoxyphenyl Triazine Methylene Bis-Benzotriazolyl 3.00 2.00 3.00 3.00 Tetramethylbutylphenol * Methanone, 1,1′-(1,4- 2.00 2.00 2.00 2.00 2.00 3.00 2.00 2.00 2.00 piperazinediyl)bis[1-[2-[4- (diethylamino)-2- hydroxybenzoyl]phenyl]- CAS number (919803-06-8) * Phenylene Bis-Diphenyltriazine * 3.00 4.00 3.00 3.00 1.00 2.00 3.00 4.00 3.00
Si/W Formulation

(31) TABLE-US-00025 Example B22: Si/W sun cream 22A 22B 22C 22D 22E 22F 22G 22H 22I % % % % % % % % % INCI-Name w/w w/w w/w w/w w/w w/w w/w w/w w/w Part Cyclopentasiloxane 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 A (and) Dimethicone/ Vinyl Dimethicone Cross- polymer Dimethicone (and) 30.00 30.00 30.00 30.00 30.00 30.00 30.00 30.00 30.00 Dimethicone/Vinyl Dimethicone Crosspolymer Cyclopentasiloxane 10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00 10.00 Part 1.3-Butylen Glycol 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 B Polyglyceryl-3 Disiloxane 0.60 0.60 0.60 0.60 0.60 0.60 0.60 0.60 0.60 Dimethicone Polyglyceryl-3 Polydimethylsiloxy- 0.30 0.30 0.30 0.30 0.30 0.30 0.30 0.30 0.30 ethyl Dimethicone Acrylamide/Sodium 0.60 0.60 0.60 0.60 0.60 0.60 0.60 0.60 0.60 Acryloyldimethyltaurate Copolymer (and) Isohexadecane (and) Polysorbate 80 Ammonium 0.65 0.65 0.65 0.65 0.65 0.65 0.65 0.65 0.65 Acryloyldimethyltaurate/VP Copolymer Sodium Chloride 0.10 0.10 0.10 0.10 0.10 0.10 0.10 0.10 0.10 Aqua Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 Merocyanine 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Diethylamino Hydroxy Benzoyl 2.00 Hexyl Benzoate Ethylhexyl Triazone 2.00 2.00 2.00 2.00 1.00 Ethylhexyl Methoxycinnamate 7.00 7.00 Bis-Ethylhexyloxyphenol 1.00 1.00 1.00 2.00 1.00 Methoxyphenyl Triazine Methylene Bis-Benzotriazolyl 3.00 2.00 2.00 3.00 3.00 1.00 Tetramethylbutylphenol * MBM-09 20.00 10.00 10.00 10.00 10.00 10.00 13.00 Methanone, 1,1′-(1,4-piperazine- 2.00 2.00 2.00 2.00 2.00 2.00 4.00 4.00 2.00 diyl)bis[1-[2-[4-(diethylamino)-2- hydroxybenzoyl]phenyl]- CAS number (919803-06-8) * Phenylene Bis-Diphenyltriazine * 2.00 2.00 2.00 1.00 3.00 2.00 2.00 1.00 2.00
O/W Formulation
Anionic System Emulsifier

(32) TABLE-US-00026 Example B23: Emulsion high Protection 23A 23B 23C 23D 23E 23F 23G 23H 23I % % % % % % % % % INCI-Name w/w w/w w/w w/w w/w w/w w/w w/w w/w Part A Cyclomethicone 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 Dibutyl Adipate 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 Tridecyl Trimellitate 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 C12-15 Alkyl Benzoate 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Ethylhexyl Palmitate 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 Glyceryl Stearate 1.50 1.50 1.50 1.50 1.50 1.50 1.50 1.50 1.50 Potassium Cetyl Phosphate 1.80 1.80 1.80 1.80 1.80 1.80 1.80 1.80 1.80 VP/Eicosene Copolymer 0.60 0.60 0.60 0.60 0.60 0.60 0.60 0.60 0.60 Part B Aqua Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 Acrylates/Palmeth-25 Acrylate 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 Copolymer Glycerin 6.00 6.00 6.00 6.00 6.00 6.00 6.00 6.00 6.00 Disodium EDTA 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 Part C Phenoxyethanol (and) 0.70 0.70 0.70 0.70 0.70 0.70 0.70 0.70 0.70 Methylparaben (and) Ethylparaben (and) Butylparaben (and) Propylparaben (and) Isobutylparaben Tocopheryl Acetate 0.30 0.30 0.30 0.30 0.30 0.30 0.30 0.30 0.30 Diethylamino Hydroxy Benzoyl 2.00 Hexyl Benzoate Ethylhexyl Triazone 2.00 2.00 2.00 2.00 BBDAPT (CAS Nb: 2.00 207562-42-3) Ethylhexyl Methoxycinnamate 7.00 7.00 7.00 7.00 7.00 Bis-Ethylhexyloxyphenol 2.00 2.00 2.00 2.00 2.00 Methoxyphenyl Triazine Methylene Bis-Benzotriazolyl 3.00 3.00 3.00 3.00 Tetramethylbutylphenol * Phenylene Bis- 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 2.00 Diphenyltriazine * MBM-09 4.00 4.00 4.00 4.00 4.00 4.00 4.00 10.00 2.00

(33) TABLE-US-00027 Example B24: Sun Milk 24A 24B 24C 24D 24E 24F 24G 24H 24I % % % % % % % % % INCI-Name w/w w/w w/w w/w w/w w/w w/w w/w w/w Part C12-15 Alkyl Benzoate 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 A Coco-Caprylate 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 Tridecyl Trimellitate 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 Dibutyl Adipate 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Isohexadecane 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 Cyclopentasiloxane 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 Stearic Acid 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 PEG-100 Stearate (and) Glyceryl 0.80 0.80 0.80 0.80 0.80 0.80 0.80 0.80 0.80 Stearate Potassium Cetyl Phosphate 1.30 1.30 1.30 1.30 1.30 1.30 1.30 1.30 1.30 PVP/Eicosene Copolymer 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Part Aqua Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 Qs to 100 B Propylene Glycol 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 Xanthan Gum 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 Acrylates/C10-30 Alkyl Acrylate 0.15 0.15 0.15 0.15 0.15 0.15 0.15 0.15 0.15 Crosspolymer Disodium EDTA 0.15 0.15 0.15 0.15 0.15 0.15 0.15 0.15 0.15 Part Triethanolamine Qs Qs Qs Qs Qs Qs Qs Qs Qs C Dimethicone 0.40 0.40 0.40 0.40 0.40 0.40 0.40 0.40 0.40 Phenoxyethanol (and) 0.70 0.70 0.70 0.70 0.70 0.70 0.70 0.70 0.70 Methylparaben (and) Ethylparaben (and) Butylparaben (and) Propylparaben (and) Isobutylparaben Tocopheryl Acetate 0.90 0.90 0.90 0.90 0.90 0.90 0.90 0.90 0.90 Diethylamino Hydroxy Benzoyl 2.00 Hexyl Benzoate Ethylhexyl Triazone 2.00 1.00 2.00 2.00 2.00 BBDAPT (CAS Nb: 207562-42-3) 1.00 2.00 Ethylhexyl Methoxycinnamate 7.00 7.00 Bis-Ethylhexyloxyphenol 2.00 2.00 2.00 2.00 2.00 Methoxyphenyl Triazine Methylene Bis-Benzotriazolyl 3.00 3.00 3.00 3.00 3.00 3.00 Tetrametylbutylphenol * Phenylene Bis-Diphenyltriazine * 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 MBM-09 4.00 4.00 10.00  4.00 4.00 4.00 4.00 4.00 2.00

(34) TABLE-US-00028 Example B25: Sun lotion 25A 25B 25C 25D 25E 25F 25G % % % % % % % INCI-Name w/w w/w w/w w/w w/w w/w w/w Part A Potassium Cetyl Phosphate 1.80 1.80 1.80 1.80 1.80 1.80 1.80 Glycery Stearate 2.5 2.5 2.5 2.5 2.5 2.5 2.5 Stearyl Alcohol 2.5 2.5 2.5 2.5 2.5 2.5 2.5 C12-15 Alkyl Benzoate 5.00 12.00 2.00 Dibutyl Adipate 15.00 5.00 15.00 5.00 Ethylhexyl Benzoate 5.00 8.00 10.00 8.00 7.00 Di C12-13 Alkyl Tartrate 5.00 5.00 5.00 Phenoxyethyl Ester 5.00 5.00 Diisopropyl Sebacate 11.00 Butyl Methoxydibenzoylmethane 3.00 Diethylamino Hydroxybenzoyl 2.00 5.00 10.00 Hexyl Benzoate Ethylhexyl Triazone 3.00 2.00 3.00 3.00 Bis-Ethylhexyloxyphenol 2.00 2.00 3.00 2.00 3.00 Methoxyphenyl Triazine Part B Aqua Qsp Qsp Qsp Qsp Qsp Qsp Qsp to to to to to to to 100 100 100 100 100 100 100 Glycerin 10.00 10.00 10.00 10.00 10.00 10.00 10.00 Xanthan Gum 0.30 0.30 0.30 0.30 0.30 0.30 0.30 Tromethamine 0.92 Phenylbenzimidazole Sulfonic 2.00 Acid Part C Phenylene Bis-Diphenyltriazine * 3.00 2.00 2.00 2.00 Phenylene Bis-Diphenyltriazine .sup.a) 2.00 1.70 2.30 Methanone, 1,1′-(1,4- 3.00 1.00 piperazinediyl)-bis[1-[2-[4- (diethylamino)-2-hydroxy- benzoyl]phenyl]- CAS number (919803-06-8) * Phenoxyethanol (and) 0.80 0.80 0.80 0.80 0.80 0.80 0.80 Methylparaben (and) Ethylparaben (and) Butylparaben (and) Propylparaben (and) Isobutylparaben In vitro SPF measured according 22 30 18 17 8 26 63 to the method described UVA PF measured according to 18 11.3 7.9 12.9 13 8.9 29.2 the method described Critical wavelength (nm) 381 376 377 382 386 381 378 Foodnote: .sup.a) particulate organic filter 50-200 nm, aqueous dispersion, active ingredient 20-30 w/w %
Method to Assess In Vitro Sun Protection Factor Measurement (SPF)

(35) End-product application rate 1.3 mg/cm.sup.2 on PMMA plates (Helioplates®)

(36) UV Transmittance analysis with Labsphere UV-1000S Transmittance Analyser

(37) $\mathrm{SPF}=\frac{\stackrel{400\mathrm{nm}}{\underset{290\mathrm{nm}}{\int }}{E}_{\lambda }.Math.S_{\lambda }.Math.d\lambda }{\stackrel{400\mathrm{nm}}{\underset{290\mathrm{nm}}{\int }}{E}_{\lambda }.Math.S_{\lambda }.Math.T_{\lambda }.Math.d\lambda }$
wherein E.sub.λ=erythema action spectrum; S.sub.λ=solar spectral irradiance and T.sub.λ=spectral transmittance of the sample.
Method to Assess In Vitro UVA Protection Factor (UVA PF)

(38) End-product application rate 1.3 mg/cm.sup.2 on PMMA plates (Helioplates®)

(39) UV Transmittance analysis with Labsphere UV-1000S Transmittance Analyser

(40) Pre-irradiation step (to take the sun care product photostability into account) via a solar simulator such as Atlas Suntest CPS+

(41) $\mathrm{PFUVA}=\frac{\stackrel{400}{\underset{320}{.Math.}}\mathrm{\Delta \lambda }}{\stackrel{400}{\underset{320}{.Math.}}{T}_{\lambda }.Math.\mathrm{\Delta \lambda }}=\frac{1}{T_m}$

(42) Wherein T.sub.λ=sunscreen product transmittance at wave length λ and T.sub.m=mean arithmetical value of Transmittance data in the UVA range.

(43) Critical Wavelength

(44) The critical wavelength is the wavelength at which the sunscreen allows 10% of the rays to penetrate. A sunscreen with a critical wavelength over 370 nm is considered by the FDA to provide excellent UV protection.