METHOD FOR IMPLEMENTING ATOMIC CLOCK BASED ON NV-15N COUPLING SPIN SYSTEM IN DIAMOND AND DEVICE

Abstract

A method for implementing an atomic clock based on NV-.sup.15N coupling spin system in diamond and a device are provided. The method includes: applying a pulse sequence to jointly initialize NV electron spins and .sup.15N nuclear spins; performing a Ramsey interferometry to compare a RF frequency and a .sup.15N hyperfine coupling; entangling the NV electron spin and the nuclear spin, reading out a state of nuclear spins by collecting a fluorescence signal; calculating a frequency difference between the RF frequency and the .sup.15N hyperfine coupling according to the fluorescence signal, thereby locking the RF frequency to the .sup.15N hyperfine coupling; and outputting the RF frequency as a frequency standard. This system is located in a stable solid environment and is not affected by environmental conditions such as an external magnetic field, electric field, and temperature, and therefore it has an excellent robustness. Various components of the device may be integrated into several chips to miniaturize a diamond atomic clock.

Claims

1. A method for implementing an atomic clock based on NV-.sup.15N coupling spin system in diamond, the method comprising: comparing a RF frequency with a .sup.15N hyperfine coupling through Ramsey interferometry; reading out a difference value between the RF frequency and the .sup.15N hyperfine coupling by collecting a fluorescence signal at NV centers so as to feedback and lock the RF frequency, and outputting the RF frequency as a frequency standard.

2. The method according to claim 1, comprising: initialization: applying a laser pulse to initialize NV electron spins in a preceding initialization process, simultaneously applying a DC bias square wave and a selective π first-microwave pulse and applying a π radiofrequency pulse to initialize .sup.15N nuclear spins, applying the laser pulse to reinitialize the NV electron spins, and finally applying a selective π second-microwave pulse to complete an overall initialization process; Ramsey interference: performing a Ramsey interference sequence using π/2 radiofrequency pulses; readout: applying the selective π second-microwave pulse to entangle the nuclear spin and the electron spin, applying the laser pulse, simultaneously collecting the fluorescence signal from the NV centers, and converting the fluorescence signal into an electrical signal; frequency feedback and locking: calculating a frequency difference between the RF frequency and the .sup.15N hyperfine coupling according to the electrical signal, and adjusting the RF frequency according to a calculation result until the RF frequency is locked to the .sup.15N hyperfine coupling; output: using a locked RF frequency as a frequency standard to output a clock signal of the atomic clock.

3. The method according to claim 2, wherein the initialization comprises: applying the laser pulse to initialize the NV electron spins to |m.sub.S=0>, simultaneously applying the DC bias square wave and the selective π first-microwave pulse and applying the π radiofrequency pulse to initialize the nuclear spins to |m.sub.I=−½>; applying the laser pulse to reinitialize the electron spins; and applying the selective π second-microwave pulse, so as to prepare the NV electron spins and the .sup.15N nuclear spins to a state |m.sub.S=+1, m.sub.I=−½>.

4. The method according to claim 2, wherein the preceding initialization process is performed multiple times to obtain an optimal polarization.

5. The method according to claim 2, wherein two states used for the Ramsey interference are |m.sub.I=−½> and |m.sub.I=+½>.

6. The method according to claim 2, wherein the RF frequency is calibrated through a proportional-integral-differential algorithm.

7. An atomic clock device based on NV-.sup.15N coupling spin system in diamond, comprising: a light source configured to emit a laser for exciting NV centers and causing the NV centers to emit a fluorescence; an optical filter configured to filter out a stray light outside a fluorescence spectrum; a microwave signal generator configured to generate a selective π first-microwave pulse and a selective π first-microwave pulse; a radiofrequency signal generator configured to generate a radiofrequency; a DC signal generator configured to generate a DC bias; power amplifiers configured to boost a power of the microwave and a power of the radiofrequency, respectively; a double split-ring resonator configured to transmit the selective π first-microwave pulse and the selective π first-microwave pulse to a spatial range of the laser-excited NV centers in diamond and form a uniform microwave field to manipulate electron spin states of NVs; a low frequency coil configured to transmit the radiofrequency to the spatial range of the laser-excited NV centers in diamond and form a uniform radiofrequency field to manipulate nuclear spin states of .sup.15Ns, and configured to transmit the DC bias to the spatial range of the laser-excited NV centers in diamond and form a uniform magnetic field to split energy levels of NV electron spins; a magnetic shield configured to shield a disturbance of an external magnetic field and improve stability and accuracy of the device; a photoelectric detector configured to collect a fluorescence signal radiated from the NV centers and convert the fluorescence signal into an electrical signal; a frequency feedback and locking module configured to receive the electrical signal transmitted by the photoelectric detector, calculate a frequency difference between a RF frequency and a .sup.15N hyperfine coupling based on the electrical signal, feedback and control the RF frequency in real time according to the frequency difference, and lock the RF frequency to the .sup.15N hyperfine coupling; and a sample module configured to provide NV-.sup.15N coupling spin systems, wherein a coherence time T.sub.2* of the NV centers in the sample module is greater than 1 μs.

8. The atomic clock device according to claim 7, comprising: a fluorescence waveguide configured to collect and transmit the fluorescence emitted by the NV centers.

9. The atomic clock device according to claim 7, comprising: a Bragg reflector configured to be arranged around the diamond for forming an optical cavity, so as to improve an excitation efficiency of the NV centers and reduce a requirement of a laser power.

10. The atomic clock device according to claim 7, wherein the number of NV centers of the sample module is greater than 10.sup.12.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0040] The drawings are used to better understand the solution and do not constitute a limitation to the present disclosure.

[0041] FIG. 1 shows an energy level structure diagram of an NV-.sup.15N coupling spin system according to the present disclosure.

[0042] FIG. 2 shows a flow chart of a method for implementing an atomic clock according to the present disclosure.

[0043] FIG. 3 shows an energy level structure diagram of an NV-.sup.15N coupling spin system after a DC bias is applied according to the present disclosure.

[0044] FIG. 4 shows a schematic diagram of a sequence of laser pulses, DC bias, selective π first-microwave pulses, selective π second-microwave pulses and radiofrequency pulses according to the present disclosure.

[0045] FIG. 5 shows a flow chart of a specific solution of an embodiment according the present disclosure.

[0046] FIG. 6 shows a comparison diagram of a frequency instability between an embodiment according to the present disclosure and a commercial atomic clock.

[0047] FIG. 7 shows a diagram of a diamond atomic clock device according to an embodiment of the present disclosure.

[0048] In the drawings:

[0049] 1. laser pulse; 2. selective π second-microwave pulse; 3. radiofrequency pulse; 4. selective π first microwave pulse; 5. DC bias

DETAILED DESCRIPTION

[0050] In order to make the objectives, technical solutions and advantages of the present disclosure more explicit, the principles and usage methods of the technical solutions of the present disclosure are described in detail as follows in combination with the specific embodiments and with reference to the accompanying drawings.

[0051] Nitrogen-vacancy defect (NV center) in diamond consists of a Nitrogen atom substituted for a Carbon atom and an adjacent vacancy, and a ground state .sup.3A.sub.2 of the negatively charged NV center is an electron spin with a spin number S=1. The electron spin has many excellent properties: the electron spin may be initialized with a laser, spin states of the electron spin may be read out by a fluorescence counting, a coherence manipulation may be performed by means of a microwave and a radiofrequency, and the electron spin has a long coherence time at a room temperature. Additionally, the electron spin of the NV center has a strong coupling with its own nitrogen nuclear spin, and may be used as a quantum resource to perform a task of quantum information processing. Such an NV-.sup.15N coupling spin system is used in the present disclosure, and a measurement environment is a room temperature atmosphere.

[0052] The physical effects considered in the present disclosure include zero-field splitting of an NV center, Zeeman effect of an NV electron spin, and hyperfine interaction between an NV electron spin and a .sup.15N nuclear spin. An NV electron wave function has C.sub.3v symmetry along the NV axis, defined as the z-axis. According to the C.sub.3v symmetry, a Hamiltonian of the hyperfine interaction between the NV electron spin and the .sup.15N nuclear spin may be simplified in a form described by a longitudinal component A.sub.∥ and a transverse component A.sub.⊥, as shown in equation (1):

[00001]$\begin{array}{cc}\begin{array}{c}{H}_{\mathrm{hyper}}=-\frac{{\mu }_o{\gamma }_e{\gamma }_n{\hslash }^2}{4}\left[.Math.\frac{3\left(S.Math.\hat{n}\right)\left(I.Math.\hat{n}\right)-S.Math.I}{{.Math.r-r_N.Math.}^3}.Math.+\frac{8\pi {.Math.{\Phi }_e\left(r_N\right).Math.}^2}{3}S.Math.I\right]\\ =A_{.Math.}{S}_z{I}_z+A_{\perp }\left(S_x{I}_x+S_y{I}_y\right)\end{array}& \left(1\right)\end{array}$

[0053] wherein μ.sub.0 is a vacuum permeability, ℏ is a reduced Planck constant, γ.sub.e and γ.sub.n are gyromagnetic ratios of the electron spin and the .sup.15N nuclear spin, S=(S.sub.x,S.sub.y,S.sub.z), I=(I.sub.x,I.sub.y,I.sub.z) are spin operators, {circumflex over (n)} is a unit vector along a |r−r.sub.N| direction, and |ϕ.sub.e(r.sub.N)|.sup.2 is an electron spin density at a .sup.15N position. A hyperfine coupling does not depend on environmental quantities such as a magnetic field, electric field and temperature, and has an extremely high stability, and therefore it is suitable as a frequency standard. With the zero-field splitting of the NV center and the Zeeman effect of the NV electron spin being added, a complete Hamiltonian of an NV-.sup.15N coupling quantum system is:

H.sub.0=H.sub.∥+H.sub.⊥  (2)

H.sub.∥=DS.sub.z.sup.2+γ.sub.eB.sub.0S.sub.z+A.sub.∥S.sub.zI.sub.z  (3)

H.sub.⊥=A.sub.⊥(S.sub.xI.sub.x+S.sub.yI.sub.y)  (4)

[0054] wherein D≈2870 MHz is the zero-field splitting of NV. H.sub.∥ is a principal term of the Hamiltonian, and H.sub.⊥ is a perturbative term, which is noncommutable with the principal term. and basically does not affect the energy level structure. Therefore, the frequency standard used by the atomic clock mainly comes from the longitudinal component A.sub.∥ of the hyperfine coupling. In order to split an energy level of the NV electron spin to initialize the nuclear spin, the Zeeman effect of the NV electron spin occurs only when a DC bias is applied.

[0055] In the case of absence of an external magnetic field and ignoring a strain, the energy level structure of the NV-.sup.15N coupling spin system is as shown in FIG. 1. A ground state .sup.3A.sub.2 thereof is a coupling spin system of the NV electron spin (S=1) and the .sup.15N nuclear spin (I=½), which has 6 energy levels in total. Two energy levels within an electron spin subspace m.sub.S=+1 (or two energy levels within a subspace m.sub.S=−1) may be used as atomic clock states, and the other energy levels may be used to initialize and read out the nuclear spin. The system may be excited from the ground state .sup.3A.sub.2 to an excited state .sup.3E by applying a 532 nm laser pulse, thereafter the spin state m.sub.S=±1 will reach an intermediate energy level with a high probability of non-radiation transition, and continue to return to the spin state m.sub.S=0 from the intermediate energy level through the non-radiation process. Therefore, an NV electron spin initialization may be achieved by a laser pulse irradiation. Moreover, due to the non-radiation transition, a fluorescence intensity of the spin state m.sub.S=±1 is lower than that of m.sub.S=0 (by about 30%). Therefore, the spin state of NV may be read out by a fluorescence collection. In the present disclosure, a photoelectric detector is used to record a fluorescence intensity of NV centers so as to read out the NV electron spins. Since the .sup.15N nuclear spin may not be directly initialized by a laser, the .sup.15N nuclear spin may initialized by means of simultaneously applying a DC bias square wave and a selective π first-microwave pulse and then applying a π radiofrequency pulse. Since the .sup.15N nuclear spin may also not be directly read out by a fluorescence, the .sup.15N nuclear spin and the NV electron spin may be entangled by applying a selective π second-microwave pulse and a π radiofrequency pulse, so as to implement the readout of .sup.15N nuclear spin.

[0056] The diamond used in the present disclosure is Ib or IIa type diamond, and the diamond may be prepared by a method of high temperature and high pressure (HPHT) or chemical vapor deposition (CVD). After an electron irradiation is performed on diamond, uniform vacancies are generated in diamond, then annealing is performed at above 600° C. to move the vacancies, and when the vacancies are captured by Nitrogen atoms, NV centers are formed. At present, an ideal productivity may exceed 50%, that is, more than half of the Nitrogen atoms may be combined with the vacancies to form the NV centers.

[0057] In the technical solution of the present disclosure, an ensemble of NV centers is used to reduce a statistical error of a frequency measurement, and simultaneously an external magnetic field is shielded, and a measurement is performed under a zero-field so as to eliminate the noise and line broadening resulting from problems such as the uniformity and stability of the magnetic field, and improve the stability and precision of the diamond atomic clock. A total measurement time is considered as T, in the case that NV centers of the number N are used, a relative frequency instability may be obtained by calculation as follows:

[00002]$\begin{array}{cc}\frac{\delta f}{f_0}=\frac{1}{2\pi f_{0}F\sqrt{T_2^{*}T}\sqrt{N}}\sim \frac{4\times 10^{-5}}{\sqrt{T}\sqrt{N}}& \left(5\right)\end{array}$

[0058] Wherein f.sub.0 is a center frequency, and is estimated to be about 3 MHz according to the longitudinal component A.sub.∥ of the hyperfine coupling, F is an NV center readout fidelity, and is about 1.5%, and T.sub.2* is a coherence time of the nuclear spin, and is about 10 m.sub.S. However, the impurities around the NV centers may change the longitudinal component A.sub.∥ of the .sup.15N hyperfine interaction and shorten the coherence time T.sub.2* of the nuclear spin through a strain or an electric field effect. Considering the influence exerted by impurity Nitrogen atoms which are the most in diamond, as far as diamond having a Nitrogen concentration of about 1 ppm is concerned, a single quantum coherence time of the NV ensemble in diamond may reach about 10 μs. This means that the zero-field splitting of the NV centers has a Gaussian distribution, which has a standard deviation of about 20 kHz, and is generated from a strain gradient of a lattice. When a zero-field splitting deviation of two NV centers is about 300 kHz, the longitudinal components A.sub.∥ of the NV-.sup.15N hyperfine coupling have a difference of several tens of Hertz. It may be supposed that for diamond having a Nitrogen concentration of about 1 ppm, a difference between the longitudinal components A.sub.∥ should be only several Hertz. This will not shorten the coherence time T.sub.2* of the nuclear spin. Therefore, theoretically a diamond atomic clock may be constructed using diamond having a Nitrogen concentration of about 10 ppm to achieve an optimal performance.

[0059] As shown in FIG. 2, the method for implementing an atomic clock according to the present disclosure includes: [0060] S201, initialization: applying a laser pulse to initialize NV electron spins in a preceding initialization process, simultaneously applying a DC bias square wave and a selective π first-microwave pulse and applying a π radiofrequency pulse to initialize .sup.15N nuclear spins, applying the laser pulse to reinitialize the NV electron spins, and finally applying a selective π second-microwave pulse to complete an overall initialization process; [0061] S202, Ramsey interference: performing a Ramsey interference sequence using π/2 radiofrequency pulses; [0062] S203, readout: applying the selective π second-microwave pulse to entangle the nuclear spin and the electron spin, applying the laser pulse, simultaneously collecting the fluorescence signal from the NV centers, and converting the fluorescence signal into an electrical signal; [0063] S204, frequency feedback and locking: calculating a frequency difference between the RF frequency and the .sup.15N hyperfine coupling according to the electrical signal, and adjusting the RF frequency according to a calculation result until the RF frequency is locked to the .sup.15N hyperfine coupling; [0064] S205, output: using a locked RF frequency as a frequency standard to output a clock signal of the atomic clock.

[0065] FIG. 3 shows an energy level structure of the NV-.sup.15N coupling spin system during application of a DC bias. The DC bias is configured to generate a small magnetic field, generally 1-10 Gauss, to split energy level structures of the NV centers, and perform a selective excitation for applying a selective π first-microwave pulse. The selective π first-microwave pulse is configured to flip a state |m.sub.S=0, m.sub.I=+½> to a state |m.sub.S=+1, m.sub.I=+½>. Subsequently, a r radiofrequency pulse is applied to initialize the .sup.15N nuclear spins to a state |m.sub.I=−½>. In some embodiments, a frequency of the selective π first-microwave pulse may be changed to flip a state |m.sub.S=0, m.sub.I=+½> to a state |m.sub.S=−1, m.sub.I=+½>. In some embodiments, the frequency of the selective π first-microwave pulse may be changed to flip a state |m.sub.S=0, m.sub.I=−½> to a state |m.sub.S=−1, m.sub.I=−½> or |m.sub.S=+1, m.sub.I=−½>, and then the π radiofrequency pulse is applied, so that the .sup.15N nuclear spins may be initialized to a state |m.sub.I=+½>.

[0066] FIG. 4 shows a schematic diagram of a sequence of laser pulses, selective π second-microwave pulses, radiofrequency pulses, selective π first-microwave pulse, and DC bias according to the present disclosure. The laser pulse is configured to initialize and read out NV electron spins. A laser pulse of 520-550 nm, preferably 532 nm is used in the present disclosure. The selective π second-microwave pulse is configured to flip a state |m.sub.S=0,m.sub.I=−½> to a state |m.sub.S=+1,m.sub.I=−½>, and a selective π pulse is used in the present disclosure. The radiofrequency pulse is configured for a coherence manipulation of a nuclear spin, so that the nuclear spins are flipped between a state |m.sub.I=−½> and a state |m.sub.I=+½>, and a π pulse and a π/2 pulse are included in the present disclosure. The selective π first-microwave pulse is configured to flip a state |m.sub.S=0, m.sub.I=+½> to a state |m.sub.S=+1, m.sub.I=+½>. The DC bias is configured to generate a small magnetic field to split energy level structures of NV centers, and perform a selective excitation for applying the selective r first-microwave pulse. Corresponding manipulations of the pulses in FIG. 4 may be found in FIG. 1 and FIG. 3 according to the correspondence of reference signs 1, 2, 3, and 4.

[0067] In some embodiments, a frequency of the selective r second-microwave pulse may be changed to flip a state |m.sub.S=0,m.sub.I=−½> to a state |m.sub.S=−1, =−½>. In some embodiments, if the nuclear spins are initialized to |m.sub.I=+½>, then the selective π second-microwave pulse is applied to flip a state |m.sub.S=0, m.sub.I=+½> to a state |m.sub.S=−1, m.sub.I=+½> or |m.sub.S=+1, m.sub.I=+½>. If it is excited to m.sub.S=+1, then the two states of the Ramsey interference are |m.sub.S=+1, =−½> and |m.sub.S=+1, m.sub.I=+½>. If it is excited to m.sub.S=−1, then the two states of the Ramsey interference are |m.sub.S=−1, m.sub.I=−½> and |m.sub.S=−1, m.sub.I=+½>.

[0068] Referring to FIG. 5, a specific solution of an embodiment of the present disclosure is described as follows.

[0069] In initialization step, a laser pulse of 532 nm is first applied to initialize NV electron spins to |m.sub.S=0> in a preceding initialization process. A DC bias square wave and a selective π first-microwave pulse are simultaneously applied and then a π radiofrequency pulse is applied to initialize .sup.15N nuclear spins to |m.sub.I=−½>. The laser pulse of 532 nm is applied to initialize the electron spins again. In this way, the NV electron spins and the .sup.15N nuclear spins are jointly initialized to a state |m.sub.S=0, m.sub.I=−½>. Due to an imperfect manipulation and an existence of an NV neutral charge state, a single preceding initialization process may not achieve a maximum polarization of the nuclear spins. Therefore, the above preceding initialization process may be performed multiple times to achieve an optimal polarization. Finally, a selective π second-microwave pulse is applied to prepare the NV electron spins and .sup.15N nuclear spins to a state |m.sub.S=+1, m.sub.I=−½>, so as to complete an overall initialization process.

[0070] In Ramsey interference step, similar to a method for a conventional atomic clock, a Ramsey interference sequence is performed using π/2 radiofrequency pulses. In the present embodiment, two states used in the Ramsey interference are |m.sub.S=+1, m.sub.I=−½> and |m.sub.S=+1, m.sub.I=+½>, and an energy level difference between the energy levels is a hyperfine coupling A.sub.∥ of the .sup.15N nuclear spin. A time r between two π/2 pulses is a coherence evolution time for comparing the RF frequency with the hyperfine coupling A.sub.∥. In a specific embodiment, an optimal value of r should be selected to enable a highest sensitivity the device. Therefore, the coherence time of the nuclear spin T.sub.2*˜10 m.sub.S is taken as τ in the present embodiment.

[0071] In readout step, a state of the nuclear spins is a result of the Ramsey interferometry. As the state of nuclear spins may not be directly read out by a fluorescence, the selective π second-microwave pulse is applied to entangle the nuclear spin and the electron spin. Then, the laser pulse is applied and simultaneously a photoelectric detector is turned on to collect a fluorescence signal from the NV centers to read out the state of electron spins, that is, the state of nuclear spins is read out. The photoelectric detector converts the fluorescence signal into an electrical signal, and the electrical signal is further used for a real-time feedback to calibrate the RF frequency.

[0072] In frequency feedback and locking step, the RF signal is fed back and controlled according to the electrical signal, which is converted from the fluorescence signal and may also be referred to as a measurement signal of Ramsay interferometry, and the RF frequency is locked to the .sup.15N hyperfine coupling in real time. Specifically, a frequency difference value between the RF frequency and the .sup.15N hyperfine coupling is calculated according to the electrical signal converted from the fluorescence signal. If the frequency difference value obtained by calculation is within an error range, a frequency of a RF generator is not adjusted. If the frequency difference value obtained by calculation is not within the error range, this means that the RF frequency is offset, the frequency of the RF generator is adjusted, and the step is turned back to the initialization for a new start until the frequency difference value is within the error range, so that the RF frequency is locked to the .sup.15N hyperfine coupling in real time. The error range may be set as a standard deviation obtained by testing an output RF frequency of the atomic clock before working of the atomic clock. A difference value between the .sup.15N hyperfine coupling and the RF frequency is calculated using the electrical signal. The specific calculation method is as follows: the RF frequency is set to be .sup.15N hyperfine coupling before working of the atomic clock work, a measurement of Ramsey interferometry is performed, a frequency sweeping is performed in a small range to obtain corresponding measurement signal of Ramsey interferometry and a ratio between a frequency difference value and an intensity change value of the electrical signal, and thereby a difference value between the .sup.15N hyperfine coupling and the RF frequency may be calculated by multiplying the intensity change value of the electrical signal during working of the atomic clock by the ratio. In some embodiments, better algorithms may be used for feedback. For example, a RF frequency is calibrated through a proportional-integral-derivative algorithm (PID algorithm) using a currently measured frequency difference value with multiple previously measured data. Specifically, a frequency control parameter is formed in a proportional-integral-derivative control process according to an estimated frequency difference value, and the frequency control parameter is fed back to a frequency feedback and locking module as the feedback input so as to lock the RF frequency.

[0073] FIG. 6 is a comparison diagram of a frequency instability between an embodiment of the present disclosure and a commercial atomic clock, and shows relative frequency instability δf√{square root over (R)}/f.sub.0, of an ensemble NV centers at an integration time of 1 second and a comparison with three commercial atomic clocks. The solid line is obtained by calculation according to equation (5), where a horizontal axis thereof is the number of NV centers (bottom) and a corresponding density of the NV centers (for diamond having a volume of 1 mm.sup.3) (top). By comparison, relative frequency instability of a Cesium chip clock (Cs Chip Clock) is 2.5×10.sup.−10, that of a commercial Rubidium atomic clock (Commercial Rb) is 2×10.sup.−11, and that of a commercial Cesium atomic clock (Commercial Cs) is 1.2×10.sup.−11. It may be seen from FIG. 6 that a diamond atomic clock having 10.sup.12-10.sup.13 NV centers may reach a level of a commercial atomic clock.

[0074] FIG. 7 shows a diamond atomic clock device according to an embodiment of the present disclosure, and the device includes an optical path module, a microwave and radiofrequency module, a signal collecting module, a frequency feedback and locking module and a sample module.

[0075] The optical path module includes a light source that is quickly switchable, a fluorescence waveguide, and an optical filter.

[0076] The light source is configured to emit a laser for exciting NV centers and causing the NV centers to emit a fluorescence. In the present embodiment, the light source is configured to be a fiber laser of 532 nm. In some embodiments, it may also be configured to be a laser light source for generating a laser of 520-550 nm. In some embodiments where compact structures are considered, the light source may also be a vertical cavity surface emitting laser of 520 nm.

[0077] The fluorescence waveguide is configured to collect and transmit a fluorescence emitted by the NV centers. For some embodiments where compact structures are provided, a fluorescence waveguide may not be configured.

[0078] The optical filter is configured to filter out a stray light outside a fluorescence spectrum. In the present embodiment, the optical filter is configured to be a band-pass filter set of 590-800 nm.

[0079] In some embodiments, the optical path module may further include a distributed Bragg reflector of 532 nm, and the Bragg reflector is configured to be arranged around the diamond for forming an optical cavity, so as to improve excitation efficiency of the NV centers and reduce requirements of a laser power.

[0080] The microwave and radiofrequency module includes a microwave signal generator, a RF signal generator, a DC signal generator, power amplifiers, a double split-ring resonator loaded with a diamond sample, a low frequency coil, and a magnetic shield.

[0081] The microwave signal generator, the RF signal generator, and the DC signal generator are respectively configured to generate a microwave, a radiofrequency, and a DC bias.

[0082] The power amplifiers are configured to boost a power of the microwave and a power of the radiofrequency, respectively.

[0083] The double split-ring resonator transmits the microwave to a spatial range of the laser-excited diamond NV centers and forms a uniform microwave field to manipulate electron spin states of NVs.

[0084] The low frequency coil has two functions: 1. to transmit the radiofrequency to the spatial range of the laser-excited NV centers in diamond and forms a uniform radiofrequency field to manipulate nuclear spin states of .sup.15Ns; and 2. to transmit the DC bias to the spatial range of the laser-excited NV centers in diamond and forms a uniform magnetic field to split energy levels of NV electron spins.

[0085] The magnetic shield is configured to shield a disturbance of an external magnetic field and improve stability and accuracy of the device. An influence of a spin Zeeman effect may be eliminated by constructing a diamond atomic clock in a zero-field with the external magnetic field shielding.

[0086] The signal collecting module includes a photoelectric detector, and the photoelectric detector is configured to collect a fluorescence signal radiated from the NV centers and convert the fluorescence signal into an electrical signal. The fluorescence signal corresponds to a result of the Ramsey interferometry. In the present embodiment, the photoelectric detector is configured to be a combination of a photodiode (PD) and an amplifying circuit.

[0087] The frequency feedback and locking module is configured to receive the electrical signal transmitted by the photoelectric detector, calculate a frequency difference between a RF frequency and a .sup.15N hyperfine coupling based on the electrical signal, feedback and control the RF frequency in real time according to the frequency difference, and lock the RF frequency to the .sup.15N hyperfine coupling, thereby calibrating the RF frequency in real time.

[0088] In some embodiments, the frequency feedback and locking module further includes a proportional-integral-derivative controller (PID controller) configured to form a frequency control parameter in a proportional-integral-derivative control process according to an estimated frequency difference value, and feedback the frequency control parameter to the frequency feedback and locking module as a feedback input.

[0089] The sample module of the present disclosure is configured to provide the NV-.sup.15N coupling spin systems. In the sample module of the present embodiment, a diamond sample grown by CVD (Chemical Vapor Deposition) is used. After an electron irradiation is performed on the diamond, annealing is performed at a high temperature to generate NV centers, and the NV centers are located in a bulk diamond. More generally, a coherence time T.sub.2* of the NV centers in the sample module in the technical solution of the present disclosure needs to be greater than 1 μs to implement the selective π first-microwave pulse and the selective π second-microwave pulse in FIG. 2. Additionally, the number of the NV centers inside the diamond should be greater than 10.sup.12 so as to improve precision and obtain a comparable performance to a commercial atomic clock. Therefore, in the present embodiment, for diamond having a volume of 1 mm.sup.3, an NV concentration should be greater than 6 ppb. Considering factors such as excitation efficiency and uniformity of a radiation field of the optical path module, a diamond sample having a dimension of about 1×1×0.1 mm.sup.3 and an NV concentration of about 1 ppm is selected in the present embodiment, and the number of the NVs is about 10.sup.13, corresponding to the number of the NVs indicated by asterisks in FIG. 6.

[0090] The NV-.sup.15N coupling spin system in diamond of the present disclosure is located in a stable solid environment and is not affected by environmental conditions such as an external magnetic field, electric field, and temperature, and therefore the system has an excellent robustness and a diamond atomic clock having a long-term high stability is expected to be implemented in such a system.

[0091] In the atomic clock device based on the above system, various components may be integrated into several chips, and a miniaturized diamond atomic clock is expected to be implemented.

[0092] The specific embodiments described above further illustrate the objects, technical solutions and beneficial effects of the present disclosure in detail. It should be understood that the above descriptions are only specific embodiments of the present disclosure and are not construed as limiting the present disclosure. Any modifications, equivalent replacements and improvements made within the spirit and principles of the present disclosure shall be contained in the scope of protection of the present disclosure.