LIQUID-CRYSTAL MEDIUM

Abstract

A liquid crystal medium containing a) one or more compounds of formula I

##STR00001## b) one or more compounds of the formula IIBa

##STR00002## and c) one or more compounds of the formula IIDa

##STR00003## and the use thereof for optical, electro-optical and/or electronic purposes, in particular in LC displays, especially in IPS, FFS, VA or PS-VA displays.

Claims

1. A liquid crystal medium comprising a) one or more compounds of formula I ##STR00292## in which R.sup.11, R.sup.12 identically or differently, denote H, straight chain alkyl or alkoxy having 1 to 15 C atoms, straight chain alkenyl or alkenyloxy having 2 to 15 C atoms or branched alkyl, alkoxy, alkenyl or alkenyloxy having 3 to 15 C atoms, where one or more CH.sub.2 groups in these radicals may each be replaced, independently of one another, by ##STR00293##  —C≡C—, —CF.sub.2O—, —OCF.sub.2—, —O—, —CO—O— or —O—CO— in such a way that O atoms are not linked directly to one another, and in which one or more H atoms may be replaced by halogen, L.sup.1, L.sup.2 identically or differently, denote F or Cl, and b) one or more compounds of formula IIBa ##STR00294## in which R.sup.2B denotes alkyl or alkoxy each having 1 to 7 C atoms or alkenyl having 2 to 7 C atoms, (O) denotes O or a single bond, and v is an integer from 1 to 5; and c) one or more compounds of formula IIDa ##STR00295## in which R.sup.2D denotes alkyl or alkoxy each having 1 to 7 C atoms or alkenyl having 2 to 7 C atoms, (O) denotes O or a single bond, and v is an integer from 1 to 5.

2. The liquid crystal medium according to claim 1, wherein the medium further comprises one or more compounds of formula III ##STR00296## in which R.sup.31 and R.sup.32 identically or differently, denote H, straight chain alkyl or alkoxy having 1 to 15 C atoms, straight chain alkenyl or alkenyloxy having 2 to 15 C atoms or branched alkyl, alkoxy, alkenyl or alkenyloxy having 3 to 15 C atoms, where one or more CH.sub.2 groups in these radicals may each be replaced, independently of one another, by ##STR00297##  —C≡C—, —CF.sub.2O—, —OCF.sub.2—, —CH═CH—, by —O—, —CO—O— or —O—CO— in such a way that O atoms are not linked directly to one another, and in which one or more H atoms may be replaced by halogen, Δ.sup.31 on each occurrence, independently of one another, denotes a) 1,4-cyclohexylene or 1,4-cyclohexenylene radical, in which one or two non-adjacent CH.sub.2 groups may be replaced by —O— or —S—, b) a 1,4-phenylene radical, in which one or two CH groups may be replaced by N, or c) a radical selected from the group consisting of spiro[3.3]heptane-2,6-diyl, 1,4-bicyclo[2.2.2]octylene, naphthalene-2,6-diyl, decahydronaphthalene-2,6-diyl, 1,2,3,4-tetrahydronaphthalene-2,6-diyl, phenanthrene-2,7-diyl and fluorene-2,7-diyl, where the radicals a), b) and c) may be mono- or polysubstituted by halogen atoms, Z.sup.31 on each occurrence independently of one another denotes —CO—O—, —O—CO—, —CF.sub.2O—, —OCF.sub.2—, —CH.sub.2O—, —OCH.sub.2—, —CH.sub.2—, —CH.sub.2CH.sub.2—, —(CH.sub.2).sub.4—, —CH═CH—CH.sub.2O—, —C.sub.2F.sub.4—, —CH.sub.2CF.sub.2—, —CF.sub.2CH.sub.2—, —CF═CF—, —CH═CF—, —CF═CH—, —CH═CH—, —C≡C— or a single bond, L.sup.31 and L.sup.32 each, independently of one another, denote F, Cl, CF.sub.3 or CHF.sub.2, and n is 0, 1 or 2.

3. The liquid crystal medium according to claim 1, wherein the medium further comprises one or more compounds of formulae IIA, IIB, IIC and/or IID, ##STR00298## in which R.sup.2A, R.sup.2B, R.sup.2C and R.sup.2D identically or differently, denote H, straight chain alkyl or alkoxy having 1 to 15 C atoms, straight chain alkenyl or alkenyloxy having 2 to 15 C atoms or branched alkyl, alkoxy, alkenyl or alkenyloxy having 3 to 15 C atoms, where one or more CH.sub.2 groups in these radicals may each be replaced, independently of one another, by ##STR00299##  —C≡C—, —CF.sub.2O—, —OCF.sub.2—, —CH═CH—, by —O—, —CO—O— or —O—CO— in such a way that O atoms are not linked directly to one another, and in which one or more H atoms may be replaced by halogen, (O) denotes O or a single bond, L.sup.1 to L.sup.4 each, independently of one another, denote F, Cl, CF.sub.3 or CHF.sub.2, Y denotes H, F, Cl, CF.sub.3, CHF.sub.2 or CH.sub.3, Z.sup.2, Z.sup.2B and Z.sup.2D each, independently of one another, denote a single bond, —CH.sub.2CH.sub.2—, —CH═CH—, —CF.sub.2O—, —OCF.sub.2—, —CH.sub.2O—, —OCH.sub.2—, —COO—, —OCO—, —C.sub.2F.sub.4—, —CF═CF— or —CH═CHCH.sub.2O—, p denotes 0, 1 or 2, q denotes 0 or 1, and v denotes an integer from 1 to 6, wherein the compounds of formulae IIBa and IIDa are excluded from formulae IIB and IID.

4. The liquid crystal medium according to claim 1, wherein the medium comprises one or more compounds of formulae I-1 and/or I-2 ##STR00300## in which R.sup.11 and R.sup.12 independently denote alkyl having 1 to 6 C atoms or alkenyl having 2 to 6 C atoms, where at least one of R.sup.11 and R.sup.12 denotes alkenyl having 2 to 6 C atoms.

5. The liquid crystal medium according to claim 1, wherein the medium further comprises one or more compounds of formula S ##STR00301## in which Ar denotes an aromatic or heteroaromatic hydrocarbon group having 4 to 40 C atoms; Sp denotes a spacer group; R.sup.S denotes H, alkyl having 1 to 12 C atoms or alkenyl having 2 to 12 C atoms; Z.sup.S denotes —O—, —C(O)O—, —(CH.sub.2).sub.2— or —(CH.sub.2).sub.2O—, or a single bond; HA denotes ##STR00302## R.sup.H denotes H, O*, CH.sub.3, OH or OR.sup.S; R.sup.S1, R.sup.S2, R.sup.S3 and R.sup.S4, identically or differently, denote alkyl having 1 to 6 C atoms; G denotes H or R.sup.S or a group Z.sup.S—HA; z is an integer from 1 to 6; and q is 3 or 4.

6. The medium according to claim 5, wherein the total concentration of the one or more compounds of the formula S is >1000 ppm to 5000 ppm.

7. The medium according to claim 1, wherein the medium further comprises one or more compounds of formula IV ##STR00303## in which R.sup.41 denotes alkyl having 1 to 7 C atoms or alkenyl having 2 to 7 C atoms, and R.sup.42 denotes alkyl having 1 to 7 C atoms or alkoxy having 1 to 6 C atoms or alkenyl having 2 to 7 C atoms.

8. The liquid crystal medium according to claim 1, wherein the medium further comprises one or more compounds of formula V ##STR00304## in which R.sup.51, R.sup.52 denote alkyl having 1 to 7 C atoms, alkoxy having 1 to 7 C atoms, or alkoxyalkyl, alkenyl or alkenyloxy having 2 to 7 C atoms, ##STR00305##  identically or differently, denote ##STR00306## Z.sup.51, Z.sup.52 each, independently of one another, denote —CH.sub.2—CH.sub.2—, —CH.sub.2—O—, —CH═CH—, —C≡C—, —COO— or a single bond, and n is 1 or 2.

9. The medium according to claim 1, wherein the medium further comprises a polymerisable compound of formula R
P-Sp-Δ.sup.1-(Z.sup.1-Δ.sup.2).sub.z-R  R in which P denotes a polymerisable group, Sp denotes a spacer group or a single bond, Δ.sup.1, Δ.sup.2 identically or differently, denote an aromatic, heteroaromatic, alicyclic or heterocyclic group, which may contain fused rings, and which is unsubstituted, or mono- or polysubstituted by L, Z.sup.1 is —O—, —S—, —CO—, —CO—O—, —O—CO—, —O—CO—O—, —OCH.sub.2—, —CH.sub.2O—, —SCH.sub.2—, —CH.sub.2S—, —CF.sub.2O—, —OCF.sub.2—, —CF.sub.2S—, —SCF.sub.2—, —(CH.sub.2).sub.n1—, —CF.sub.2CH.sub.2—, —CH.sub.2CF.sub.2—, —(CF.sub.2).sub.n1—, —CH═CH—, —CF═CF—, —CH═CF—, —CF═CH—, —C≡C—, —CH═CH—CO—O—, —O—CO—CH═CH—, —CH.sub.2—CH.sub.2—CO—O—, —O—CO—CH.sub.2—CH.sub.2—, —CR.sup.0R.sup.00—, or a single bond, R.sup.0, R.sup.00 are independently of one another H or alkyl having 1 to 12 C atoms, R is H, L, or P-Sp-, L is F, Cl, —CN, P-Sp- or a straight chain alkyl having 1 to 25 C atoms, or a branched or cyclic alkyl having 3 to 25 C atoms, wherein one or more non-adjacent CH.sub.2— groups are optionally replaced by —O—, —S—, —CO—, —CO—O—, —O—CO—, or —O—CO—O— in such a manner that O- and/or S-atoms are not directly connected with each other, and wherein one or more H atoms are each optionally replaced by P-Sp-, F or Cl, z is 0, 1, 2 or 3, and n1 is 1, 2, 3 or 4.

10. An LC display comprising the liquid crystal medium according to claim 1.

11. The display according to claim 10, wherein the display is a VA, IPS, FFS or UB-FFS display.

12. A PSA display comprising the liquid crystal medium according to claim 9, wherein the compound of formula R is polymerised.

13. The display according to claim 12, wherein the display is a PS-VA, PS-IPS, PS-FFS, PS-UB-FFS, SA-FFS or SA-VA display.

14. A process for the preparation of the liquid crystal medium according to claim 1 comprising mixing one or more compounds of formula I with one or more compounds of formula IIBa and one or more compounds of formula IIDa.

Description

EXAMPLES

[0435] The present invention is illustrated in detail by the following non-restrictive working examples.

[0436] The following abbreviations and symbols are used: [0437] V.sub.0 threshold voltage, capacitive [V] at 20° C., [0438] n.sub.e extraordinary refractive index at 20° C. and 589 nm, [0439] n.sub.0 ordinary refractive index at 20° C. and 589 nm, [0440] Δn optical anisotropy at 20° C. and 589 nm, [0441] ε.sub.⊥ dielectric permittivity perpendicular to the director at 20° C. and 1 kHz, [0442] ε.sub.∥ dielectric permittivity parallel to the director at 20° C. and 1 kHz, [0443] Δε dielectric anisotropy at 20° C. and 1 kHz, [0444] cl.p., T(N,I) clearing point [° C.], [0445] γ.sub.1 rotational viscosity at 20° C. [mPa.Math.s], [0446] K.sub.1 elastic constant, “splay” deformation at 20° C. [pN], [0447] K.sub.2 elastic constant, “twist” deformation at 20° C. [pN], [0448] K.sub.3 elastic constant, “bend” deformation at 20° C. [pN].

[0449] Unless explicitly noted otherwise, all concentrations in the present application are quoted in percent by weight and relate to the corresponding mixture as a whole, comprising all solid or liquid-crystalline components, without solvents.

[0450] Unless explicitly noted otherwise, all temperature values indicated in the present application, such as, for example, for the melting point T(C,N), the transition from the smectic (S) to the nematic (N) phase T(S,N) and the clearing point T(N,I), are quoted in degrees Celsius (° C.). M.p. denotes melting point, cl.p.=clearing point. Furthermore, C=crystalline state, N=nematic phase, S=smectic phase and I=isotropic phase. The data between these symbols represent the transition temperatures.

[0451] All physical properties are and have been determined in accordance with “Merck Liquid Crystals, Physical Properties of Liquid Crystals”, Status November 1997, Merck KGaA, Germany, and apply for a temperature of 20° C., and Δn is determined at 589 nm and Δε at 1 kHz, unless explicitly indicated otherwise in each case.

[0452] The term “threshold voltage” for the present invention relates to the capacitive threshold (V.sub.0), also known as the Freedericks threshold, unless explicitly indicated otherwise. In the examples, the optical threshold may also, as generally usual, be quoted for 10% relative contrast (V.sub.10).

[0453] Unless stated otherwise, the process of polymerising the polymerisable compounds in the PSA displays as described above and below is carried out at a temperature where the LC medium exhibits a liquid crystal phase, preferably a nematic phase, and most preferably is carried out at room temperature.

[0454] Unless stated otherwise, methods of preparing test cells and measuring their electrooptical and other properties are carried out by the methods as described hereinafter or in analogy thereto.

[0455] The display used for measurement of the capacitive threshold voltage consists of two plane-parallel glass outer plates with a distance of 25 μm, each of which has on the inside an electrode layer and an unrubbed polyimide alignment layer on top, which effect homeotropic alignment of the liquid-crystal molecules.

[0456] The display or test cell used for measurement of the tilt angles consists of two plane-parallel glass outer plates at a separation of 4 μm, each of which has on the inside an electrode layer and a polyimide alignment layer on top, where the two polyimide layers are rubbed antiparallel to one another and effect a homeotropic edge alignment of the liquid-crystal molecules.

[0457] The polymerisable compounds are polymerised in the display or test cell by irradiation with UV light of defined intensity for a prespecified time, with a voltage simultaneously being applied to the display (usually 10 V to 30 V alternating current, 1 kHz). In the examples, unless indicated otherwise, a fluorescent lamp and an intensity of 10 to 20 mW/cm.sup.2 is used for polymerisation. The intensity is measured using a standard meter (Ushio Accumulate UV meter with central wavelength of 313 nm).

Mixture Examples

[0458] The nematic LC host mixtures M1 to M73 have the compositions and properties given in the following tables.

TABLE-US-00005 Mixture M1 CPP-3-2 12.00 Clp. [° C.]: 74.5 CC-2-3 14.50 Δn [589 nm, 20° C.]: 0.1071 CC-3-4 6.00 ε.sub.∥ [1 kHz, 20° C.]: 3.4 CC-3-5 6.00 ε.sub.⊥ [1 kHz, 20° C.]: 5.4 CCP-3-1 12.75 Δε [1 kHz, 20° C.]: −2.0 CLY-3-O2 8.00 K.sub.1 [pN, 20° C.]: 14.5 CPY-3-O2 9.50 K.sub.3 [pN, 20° C.]: 14.1 CP-3-O2 10.00 V.sub.0 [V, 20° C.]: 2.79 PY-1-O4 5.75 γ.sub.1 [mPa s, 20° C.]: 88 PYP-2-3 5.75 LTS bulk [h, −25° C.]: 600 Y-4O-O4 9.75 LTS bulk [h, −30° C.]: 600 Σ 100.0

TABLE-US-00006 Mixture M2 CPP-3-2 12.00 Clp. [° C.]: 73 CC-2-3 14.50 Δn [589 nm, 20° C.]: 0.1072 CC-3-4 6.00 ε.sub.∥ [1 kHz, 20° C.]: 3.3 CC-3-5 6.00 ε.sub.⊥ [1 kHz, 20° C.]: 5.4 CCP-3-1 12.75 Δε [1 kHz, 20° C.]: −1.9 CLY-3-O2 8.00 K.sub.1 [pN, 20° C.]: 13.8 CPY-3-O2 9.50 K.sub.3 [pN, 20° C.]: 13.8 CP-3-O2 10.00 V.sub.0 [V, 20° C.]: 2.77 PY-1-O4 5.75 γ.sub.1 [mPa s, 20° C.]: 81 PYP-2-3 5.75 Y-2O-O1V 5.00 Y-3O-O1V 4.75 Σ 100.0

[0459] The mixture M2 additionally contains 200 ppm of the compound I-1-1a

##STR00285##

TABLE-US-00007 Mixture M3 CCY-3-O2 11.0 Clp. [° C.]: 81 CPY-3-O2 12.5 Δn [589 nm, 20° C.]: 0.1033 CLY-3-O2 10.0 ε.sub.∥ [1 kHz, 20° C.]: 3.7 PY-3-O2 8.5 ε.sub.⊥ [1 kHz, 20° C.]: 7.5 Y-4O-O4 6.5 Δε [1 kHz, 20° C.]: −3.8 CCY-3-O1 7.5 K.sub.1 [pN, 20° C.]: 14.6 CC-3-V 32.5 K.sub.3 [pN, 20° C.]: 16.5 CC-3-V1 6.5 V.sub.0 [V, 20° C.]: 2.20 PGIY-2-O4 5.0 γ.sub.1 [mPa s, 20° C.]: 100 Σ 100.0

TABLE-US-00008 Mixture M4 CCY-3-O2 11.0 Clp. [° C.]: 79.5 CPY-3-O2 12.5 Δn [589 nm, 20° C.]: 0.1032 CLY-3-O2 10.0 ε.sub.∥ [1 kHz, 20° C.]: 3.6 PY-3-O2 8.5 ε.sub.⊥ [1 kHz, 20° C.]: 7.5 Y-2O-O1V 6.5 Δε [1 kHz, 20° C.]: −3.7 CCY-3-O1 7.5 K.sub.1 [pN, 20° C.]: 14.1 CC-3-V 32.5 K.sub.3 [pN, 20° C.]: 16.3 CC-3-V1 6.5 V.sub.0 [V, 20° C.]: 2.19 PGIY-2-O4 5.0 γ.sub.1 [mPa s, 20° C.]: 94 Σ 100.0

[0460] The mixture M4 additionally contains 50 ppm of the compound I-2-1a

##STR00286##

TABLE-US-00009 Mixture M5 CLY-3-O2 8.0 Clp. [° C.]: 75.5 CPY-3-O2 9.5 Δn [589 nm, 20° C.]: 0.1197 CPY-3-O2 11.5 ε.sub.∥ [1 kHz, 20° C.]: 3.4 PY-3-O2 5.5 ε.sub.⊥ [1 kHz, 20° C.]: 5.8 Y-4O-O4 5.0 Δε [1 kHz, 20° C.]: −2.4 CC-3-V 31.5 K.sub.1 [pN, 20° C.]: 14.5 CC-3-V1 8.0 K.sub.3 [pN, 20° C.]: 15.1 CPP-3-2 8.0 V.sub.0 [V, 20° C.]: 2.66 PP-1-2V1 7.5 γ.sub.1 [mPa s, 20° C.]: 80 PGIY-2-O4 5.5 Σ 100.0

TABLE-US-00010 Mixture M6 CLY-3-O2 8.0 Clp. [° C.]: 74.5 CPY-3-O2 9.5 Δn [589 nm, 20° C.]: 0.1194 CPY-3-O2 11.5 ε.sub.∥ [1 kHz, 20° C.]: 3.3 PY-3-O2 5.5 ε.sub.⊥ [1 kHz, 20° C.]: 5.8 Y-2O-O1V 5.0 Δε [1 kHz, 20° C.]: −2.3 CC-3-V 31.5 K.sub.1 [pN, 20° C.]: 14.1 CC-3-V1 8.0 K.sub.3 [pN, 20° C.]: 15.0 CPP-3-2 8.0 V.sub.0 [V, 20° C.]: 2.64 PP-1-2V1 7.5 γ.sub.1 [mPa s, 20° C.]: 75 PGIY-2-O4 5.5 Σ 100.0

[0461] Mixture M6 additionally contains 80 ppm of the compound ST-12b-1

##STR00287##

TABLE-US-00011 Mixture M7 CC-3-V 34.0 Clp. [° C.]: 74.5 CC-3-V1 8.0 Δn [589 nm, 20° C.]: 0.1084 CCY-3-O1 6.5 ε.sub.∥ [1 kHz, 20° C.]: 3.6 CCY-3-O2 9.0 ε.sub.⊥ [1 kHz, 20° C.]: 6.8 CLY-3-O2 5.0 Δε [1 kHz, 20° C.]: −3.2 CPY-3-O2 11.5 K.sub.1 [pN, 20° C.]: 14.0 PGIY-2-O4 5.0 K.sub.3 [pN, 20° C.]: 15.4 PP-1-2V1 1.0 V.sub.0 [V, 20° C.]: 2.32 PY-3-O2 10.0 γ.sub.1 [mPa s, 20° C.]: 86 PY-4-O2 4.0 LTS bulk [h, −25° C.]: 216 PYP-2-3 3.0 LTS bulk [h, −30° C.]: 72 Y-4O-O4 3.0 Σ 100.0

TABLE-US-00012 Mixture M8 CC-3-V 34.0 Clp. [° C.]: 74 CC-3-V1 8.0 Δn [589 nm, 20° C.]: 0.1083 CCY-3-O1 6.5 ε.sub.∥ [1 kHz, 20° C.]: 3.6 CCY-3-O2 9.0 ε.sub.⊥ [1 kHz, 20° C.]: 6.8 CLY-3-O2 5.0 Δε [1 kHz, 20° C.]: −3.2 CPY-3-O2 11.5 K.sub.1 [pN, 20° C.]: 13.8 PGIY-2-O4 5.0 K.sub.3 [pN, 20° C.]: 15.4 PP-1-2V1 1.0 V.sub.0 [V, 20° C.]: 2.31 PY-3-O2 10.0 γ.sub.1 [mPa s, 20° C.]: 83 PY-4-O2 4.0 PYP-2-3 3.0 Y-2O-O1V 3.0 Σ 100.0

TABLE-US-00013 Mixture M9 Y-4O-O4 4.0 Clp. [° C.]: 69.7 CY-3-O2 14.0 Δn [589 nm, 20° C.]: 0.1104 PY-3-O2 12.0 ε.sub.∥ [1 kHz, 20° C.]: 4.5 CCY-3-O1 4.0 ε.sub.⊥ [1 kHz, 20° C.]: 10.5 CCY-3-O2 7.0 Δε [1 kHz, 20° C.]: −6.0 CCY-3-O3 4.0 K.sub.1 [pN, 20° C.]: 12.9 CCY-4-O2 4.0 K.sub.3 [pN, 20° C.]: 13.8 CLY-3-O2 6.0 V.sub.0 [V, 20° C.]: 1.59 CLY-3-O3 6.0 γ.sub.1 [mPa s, 20° C.]: 125 B(S)-2O-O4 4.0 B(S)-2O-O5 4.0 PGIY-2-O4 5.0 CC-3-V 21.5 CCP-V-1 4.5 Σ 100.0

TABLE-US-00014 Mixture M10 B(S)-2O-O5 3.0 Clp. [° C.]: 80.6 CC-3-V 35.0 Δn [589 nm, 20° C.]: 0.0932 CC-3-V1 8.0 ε.sub.∥ [1 kHz, 20° C.]: 3.5 CC-3-5 3.0 ε.sub.⊥ [1 kHz, 20° C.]: 6.7 CCP-3-1 3.0 Δε [1 kHz, 20° C.]: −3.2 CCY-3-O1 5.0 K.sub.1 [pN, 20° C.]: 15.8 CCY-3-O2 9.0 K.sub.3 [pN, 20° C.]: 17.2 CLY-3-O2 9.0 V.sub.0 [V, 20° C.]: 2.46 CLY-4-O2 5.0 γ.sub.1 [mPa s, 20° C.]: 89 CLY-5-O2 5.0 LTS bulk [h, −20° C.]: 1000 PY-1-O2 10.0 PY-3-O2 2.0 Y-4O-O4 3.0 Σ 100.0

TABLE-US-00015 Mixture M11 B(S)-2O-O4 3.0 Clp. [° C.]: 77.2 B(S)-2O-O5 4.0 Δn [589 nm, 20° C.]: 0.1296 B(S)-2O-O6 3.0 ε.sub.∥ [1 kHz, 20° C.]: 4.3 CC-3-V 30.0 ε.sub.⊥ [1 kHz, 20° C.]: 10.6 CLY-3-O2 7.0 Δε [1 kHz, 20° C.]: −6.2 CLY-3-O3 5.0 K.sub.1 [pN, 20° C.]: 14.6 CLY-4-O2 3.5 K.sub.3 [pN, 20° C.]: 14.6 COB(S)-2-O4 8.5 V.sub.0 [V, 20° C.]: 1.61 CPY-2-O2 8.0 γ.sub.1 [mPa s, 20° C.]: 133 CPY-3-O2 9.0 LTS bulk [h, −20° C.]: 1000 PY-1-O2 9.5 PY-2-O2 8.0 Y-4O-O4 1.5 Σ 100.0

TABLE-US-00016 Mixture M12 B(S)-2O-O4 3.0 Clp. [° C.]: 76.9 B(S)-2O-O5 4.0 Δn [589 nm, 20° C.]: 0.1288 B(S)-2O-O6 3.0 ε.sub.∥ [1 kHz, 20° C.]: 4.7 CC-3-V 25.0 ε.sub.⊥ [1 kHz, 20° C.]: 11.8 CLY-3-O2 7.0 Δε [1 kHz, 20° C.]: −7.2 CLY-3-O3 5.0 K.sub.1 [pN, 20° C.]: 14.7 CLY-4-O2 4.0 K.sub.3 [pN, 20° C.]: 14.2 COB(S)-2-O4 10.0 V.sub.0 [V, 20° C.]: 1.49 CPY-2-O2 10.0 γ.sub.1 [mPa s, 20° C.]: 147 CPY-3-O2 10.5 LTS bulk [h, −20° C.]: 1000 PY-1-O2 9.0 PY-2-O2 2.5 Y-4O-O4 7.0 Σ 100.0

TABLE-US-00017 Mixture M13 B(S)-2O-O4 3.0 Clp. [° C.]: 77.1 B(S)-2O-O5 4.0 Δn [589 nm, 20° C.]: 0.1299 B(S)-2O-O6 3.0 ε.sub.∥ [1 kHz, 20° C.]: 4.5 CC-3-V 27.5 ε.sub.⊥ [1 kHz, 20° C.]: 11.4 CLY-3-O2 7.0 Δε [1 kHz, 20° C.]: −6.8 CLY-3-O3 5.0 K.sub.1 [pN, 20° C.]: 14.4 CLY-4-O2 2.5 K.sub.3 [pN, 20° C.]: 14.4 COB(S)-2-O4 10.0 V.sub.0 [V, 20° C.]: 1.54 CPY-2-O2 10.0 γ.sub.1 [mPa s, 20° C.]: 147 CPY-3-O2 10.0 LTS bulk [h, −20° C.]: 1000 PY-1-O2 9.0 PY-2-O2 4.0 Y-4O-O4 5.0 Σ 100.0

TABLE-US-00018 Mixture M14 B(S)-2O-O4 4.0 Clp. [° C.]: 77.1 B(S)-2O-O5 5.0 Δn [589 nm, 20° C.]: 0.1317 B(S)-2O-O6 4.0 ε.sub.∥ [1 kHz, 20° C.]: 4.9 CC-3-V 22.0 ε.sub.⊥ [1 kHz, 20° C.]: 13.1 CLY-3-O2 7.0 Δε [1 kHz, 20° C.]: −8.1 CLY-3-O3 5.0 K.sub.1 [pN, 20° C.]: 14.8 CLY-4-O2 5.0 K.sub.3 [pN, 20° C.]: 14.3 COB(S)-2-O4 10.0 V.sub.0 [V, 20° C.]: 1.40 CPY-2-O2 9.0 γ.sub.1 [mPa s, 20° C.]: 167 CPY-3-O2 12.0 LTS bulk [h, −20° C.]: 1000 PY-1-O2 7.0 Y-4O-O4 10.0 Σ 100.0

TABLE-US-00019 Mixture M15 B(S)-2O-O4 4.0 Clp. [° C.]: 78.7 CC-3-V 35.0 Δn [589 nm, 20° C.]: 0.0935 CCP-V-1 15.0 ε.sub.∥ [1 kHz, 20° C.]: 3.6 CCY-3-O1 6.0 ε.sub.⊥ [1 kHz, 20° C.]: 6.9 CCY-3-O2 7.0 Δε [1 kHz, 20° C.]: −3.3 CCY-5-O2 7.0 K.sub.1 [pN, 20° C.]: 14.1 CLY-3-O2 6.0 K.sub.3 [pN, 20° C.]: 16.0 CLY-5-O2 2.0 γ.sub.1 [mPa s, 20° C.]: 90 CY-3-O2 3.0 PY-1-O2 6.0 PY-3-O2 4.0 Y-4O-O4 5.0 Σ 100.0

TABLE-US-00020 Mixture M16 B(S)-2O-O4 4.0 Clp. [° C.]: 75.9 CC-3-V 28.5 Δn [589 nm, 20° C.]: 0.0936 CC-3-V1 8.0 ε.sub.∥ [1 kHz, 20° C.]: 3.7 CCP-V-1 13.5 ε.sub.⊥ [1 kHz, 20° C.]: 7.0 CCY-3-O1 8.0 Δε [1 kHz, 20° C.]: −3.3 CCY-3-O2 10.0 K.sub.1 [pN, 20° C.]: 13.9 CLY-3-O2 6.0 K.sub.3 [pN, 20° C.]: 16.2 CLY-5-O2 2.0 γ.sub.1 [mPa s, 20° C.]: 86 CY-3-O2 5.0 PY-1-O2 6.0 PY-3-O2 4.0 Y-4O-O4 5.0 Σ 100.0

TABLE-US-00021 Mixture M17 B(S)-2O-O4 4.0 Clp. [° C.]: 74.6 B(S)-2O-O5 5.0 Δn [589 nm, 20° C.]: 0.1157 CC-3-V 22.0 ε.sub.∥ [1 kHz, 20° C.]: 4.5 CLY-2-O4 5.0 ε.sub.⊥ [1 kHz, 20° C.]: 11.1 CLY-3-O2 9.0 Δε [1 kHz, 20° C.]: −6.6 CLY-3-O3 6.0 K.sub.1 [pN, 20° C.]: 13.3 CLY-4-O2 5.0 K.sub.3 [pN, 20° C.]: 14.7 CLY-5-O2 5.0 V.sub.0 [V, 20° C.]: 1.57 COB(S)-2-O4 1.0 γ.sub.1 [mPa s, 20° C.]: 142 CPY-3-O2 10.0 LTS bulk [h, −20° C.]: 1000 CY-3-O2 15.0 PY-2-O2 10.0 Y-4O-O4 3.0 Σ 100.0

TABLE-US-00022 Mixture M18 B(S)-2O-O5 5.0 Clp. [° C.]: 74.3 CC-3-V 24.5 Δn [589 nm, 20° C.]: 0.1117 CLY-2-O4 5.0 ε.sub.∥ [1 kHz, 20° C.]: 4.4 CLY-3-O2 9.0 ε.sub.⊥ [1 kHz, 20° C.]: 10.5 CLY-3-O3 6.0 Δε [1 kHz, 20° C.]: −6.1 CLY-4-O2 5.0 K.sub.1 [pN, 20° C.]: 13.8 CLY-5-O2 3.5 K.sub.3 [pN, 20° C.]: 14.1 CPY-3-O2 10.0 V.sub.0 [V, 20° C.]: 1.60 CY-3-O2 15.0 γ.sub.1 [mPa s, 20° C.]: 131 Y-4O-O4 3.0 PY-2-O2 10.0 COB(S)-2-O4 4.0 Σ 100.0

TABLE-US-00023 Mixture M19 B(S)-2O-O4 2.0 Clp. [° C.]: 75 B(S)-2O-O5 3.0 Δn [589 nm, 20° C.]: 0.1035 B(S)-2O-O6 2.0 ε.sub.∥ [1 kHz, 20° C.]: 3.5 B-2O-O5 2.0 ε.sub.⊥ [1 kHz, 20° C.]: 6.6 CPP-3-2 4.0 Δε [1 kHz, 20° C.]: −3.1 CC-3-V 51.0 K.sub.1 [pN, 20° C.]: 14.4 CC-3-V1 1.0 K.sub.3 [pN, 20° C.]: 14.6 CLY-3-O2 9.0 V.sub.0 [V, 20° C.]: 2.29 COB(S)-2-O4 5.5 γ.sub.1 [mPa s, 20° C.]: 71 CPY-3-O2 12.0 LTS bulk [h, −20° C.]: 384 PY-1-O2 7.5 Y-4O-O4 1.0 Σ 100.0

TABLE-US-00024 Mixture M20 CC-3-V 50.0 Clp. [° C.]: 75 CC-5-V 6.31 Δn [589 nm, 20° C.]: 0.0940 CLY-3-O2 7.0 ε.sub.∥ [1 kHz, 20° C.]: 3.5 CLY-3-O3 6.0 ε.sub.⊥ [1 kHz, 20° C.]: 6.6 CLY-4-O2 5.0 Δε [1 kHz, 20° C.]: −3.2 CPY-3-O2 1.64 K.sub.1 [pN, 20° C.]: 14.5 B(S)-2O-O4 3.0 K.sub.3 [pN, 20° C.]: 13.8 B(S)-2O-O5 4.0 V.sub.0 [V, 20° C.]: 2.21 B(S)-2O-O6 2.0 γ.sub.1 [mPa s, 20° C.]: 70 COB(S)-2-O4 8.0 LTS bulk [h, −20° C.]: 1000 PY-1-O2 5.97 Y-4O-O4 1.08 Σ 100.0

TABLE-US-00025 Mixture M21 CC-3-V 48.26 Clp. [° C.]: 76.6 CLY-3-O2 7.0 Δn [589 nm, 20° C.]: 0.0945 CLY-3-O3 6.0 ε.sub.∥ [1 kHz, 20° C.]: 3.5 CLY-2-O4 5.0 ε.sub.⊥ [1 kHz, 20° C.]: 6.5 CLY-4-O2 5.0 Δε [1 kHz, 20° C.]: −3.0 CLY-5-O2 3.22 K.sub.1 [pN, 20° C.]: 14.0 CPY-3-O2 12.0 K.sub.3 [pN, 20° C.]: 14.9 B(S)-2O-O4 2.04 V.sub.0 [V, 20° C.]: 2.34 PY-1-O2 7.65 γ.sub.1 [mPa s, 20° C.]: 77 Y-4O-O4 3.83 Σ 100.0

TABLE-US-00026 Mixture M22 B(S)-2O-O4 3.0 Clp. [° C.]: 73.9 B(S)-2O-O5 4.0 Δn [589 nm, 20° C.]: 0.1097 B(S)-2O-O6 3.0 ε.sub.∥ [1 kHz, 20° C.]: 4.9 B-2O-O5 2.0 ε.sub.⊥ [1 kHz, 20° C.]: 12.7 CC-3-V 24.0 Δε [1 kHz, 20° C.]: −7.8 CCY-3-O1 4.0 K.sub.1 [pN, 20° C.]: 14.2 CCY-3-O2 4.0 K.sub.3 [pN, 20° C.]: 12.8 CCY-3-O3 3.0 V.sub.0 [V, 20° C.]: 1.36 CCY-4-O2 5.0 γ.sub.1 [mPa s, 20° C.]: 138 CLY-2-O4 4.0 LTS bulk [h, −20° C.]: 1000 CLY-3-O2 7.0 CLY-3-O3 5.0 CLY-4-O2 5.0 COB(S)-2-O4 8.5 CY-3-O2 1.5 PY-2-O2 7.0 Y-4O-O4 10.0 Σ 100.0

TABLE-US-00027 Mixture M23 CC-3-V 50.5 Clp. [° C.]: 75 CLY-3-O2 7.0 Δn [589 nm, 20° C.]: 0.0929 CLY-3-O3 5.0 ε.sub.∥ [1 kHz, 20° C.]: 3.5 CLY-2-O4 5.0 ε.sub.⊥ [1 kHz, 20° C.]: 6.4 CLY-4-O2 5.0 Δε [1 kHz, 20° C.]: −2.9 CLY-5-O2 1.5 K.sub.1 [pN, 20° C.]: 13.8 CPY-3-O2 10.5 K.sub.3 [pN, 20° C.]: 14.4 PY-1-O2 7.5 V.sub.0 [V, 20° C.]: 2.34 Y-4O-O4 4.0 γ.sub.1 [mPa s, 20° C.]: 74 COB(S)-2-O4 4.0 LTS bulk [h, −20° C.]: 336 Σ 100.0

TABLE-US-00028 Mixture M24 B(S)-2O-O5 3.0 Clp. [° C.]: 94.4 B(S)-2O-O6 2.0 Δn [589 nm, 20° C.]: 0.0899 CC-3-V 30.0 ε.sub.∥ [1 kHz, 20° C.]: 3.3 CC-3-V1 8.0 ε.sub.⊥ [1 kHz, 20° C.]: 7.2 CC-3-5 8.0 Δε [1 kHz, 20° C.]: −3.9 CCY-3-O2 9.0 K.sub.1 [pN, 20° C.]: 19.9 CLOY-3-O2 15.0 K.sub.3 [pN, 20° C.]: 21.2 CLY-3-O2 9.0 V.sub.0 [V, 20° C.]: 2.47 CLY-3-O3 3.0 γ.sub.1 [mPa s, 20° C.]: 141 CLY-4-O2 5.0 LTS bulk [h, −20° C.]: 672 CLY-5-O2 5.0 PY-1-O2 1.5 Y-4O-O4 1.5 Σ 100.0

TABLE-US-00029 Mixture M25 B(S)-2O-O4 7.0 Clp. [° C.]: 52.4 CC-3-V 43.0 Δn [589 nm, 20° C.]: 0.1033 CLY-3-O2 8.0 ε.sub.∥ [1 kHz, 20° C.]: 4.2 CPY-3-O2 8.0 ε.sub.⊥ [1 kHz, 20° C.]: 7.9 CY-3-O2 8.0 Δε [1 kHz, 20° C.]: −3.7 PGIY-2-O4 8.0 K.sub.1 [pN, 20° C.]: 10.0 PY-3-O2 6.0 K.sub.3 [pN, 20° C.]: 10.4 PYP-2-3 5.0 V.sub.0 [V, 20° C.]: 1.78 Y-4O-O4 7.0 γ.sub.1 [mPa s, 20° C.]: 61 Σ 100.0

TABLE-US-00030 Mixture M26 B(S)-2O-O4 7.0 Clp. [° C.]: 55.9 CC-3-V 42.5 Δn [589 nm, 20° C.]: 0.1038 CCY-3-O2 8.0 ε.sub.∥ [1 kHz, 20° C.]: 4.1 CLY-3-O2 8.0 ε.sub.⊥ [1 kHz, 20° C.]: 7.7 CY-3-O2 5.5 Δε [1 kHz, 20° C.]: −3.6 PGIY-2-O4 8.0 K.sub.1 [pN, 20° C.]: 10.7 PY-3-O2 6.0 K.sub.3 [pN, 20° C.]: 11.0 PYP-2-3 8.0 V.sub.0 [V, 20° C.]: 1.83 Y-4O-O4 7.0 γ.sub.1 [mPa s, 20° C.]: 63 Σ 100.0

TABLE-US-00031 Mixture M27 B(S)-2O-O4 7.0 Clp. [° C.]: 60.2 CC-3-V 44.5 Δn [589 nm, 20° C.]: 0.1044 CCY-3-O2 7.5 ε.sub.∥ [1 kHz, 20° C.]: 4.0 CLY-3-O2 7.0 ε.sub.⊥ [1 kHz, 20° C.]: 7.6 CPY-3-O2 7.0 Δε [1 kHz, 20° C.]: −3.6 PGIY-2-O4 7.0 K.sub.1 [pN, 20° C.]: 11.6 PY-3-O2 7.0 K.sub.3 [pN, 20° C.]: 11.8 PYP-2-3 5.0 V.sub.0 [V, 20° C.]: 1.91 Y-4O-O4 8.0 γ.sub.1 [mPa s, 20° C.]: 66 Σ 100.0

TABLE-US-00032 Mixture M28 B(S)-2O-O4 7.0 Clp. [° C.]: 55.1 CC-3-V 42.0 Δn [589 nm, 20° C.]: 0.1030 CCY-3-O2 6.0 ε.sub.∥ [1 kHz, 20° C.]: 4.1 CLY-3-O2 6.5 ε.sub.⊥ [1 kHz, 20° C.]: 7.6 CPY-3-O2 8.0 Δε [1 kHz, 20° C.]: −3.5 CY-3-O2 6.0 K.sub.1 [pN, 20° C.]: 10.7 PY-3-O2 7.5 K.sub.3 [pN, 20° C.]: 11.3 PYP-2-3 10.0 V.sub.0 [V, 20° C.]: 1.87 Y-4O-O4 7.0 γ.sub.1 [mPa s, 20° C.]: 63 Σ 100.0

TABLE-US-00033 Mixture M29 B(S)-2O-O4 7.0 Clp. [° C.]: 57.7 CC-3-V 44.0 Δn [589 nm, 20° C.]: 0.1039 CCY-3-O2 6.0 ε.sub.∥ [1 kHz, 20° C.]: 4.0 CLY-3-O2 6.0 ε.sub.⊥ [1 kHz, 20° C.]: 7.6 CPY-3-O2 6.0 Δε [1 kHz, 20° C.]: −3.5 CY-3-O2 6.0 K.sub.1 [pN, 20° C.]: 11.0 PGIY-2-O4 7.0 K.sub.3 [pN, 20° C.]: 11.5 PY-3-O2 6.0 V.sub.0 [V, 20° C.]: 1.89 PYP-2-3 6.0 γ.sub.1 [mPa s, 20° C.]: 64 Y-4O-O4 6.0 Σ 100.0

TABLE-US-00034 Mixture M30 B-2O-O5 4.0 Clp. [° C.]: 73.5 CC-3-V 32.0 Δn [589 nm, 20° C.]: 0.1020 CCP-3-1 4.0 ε.sub.∥ [1 kHz, 20° C.]: 4.1 CCY-3-O1 6.0 ε.sub.⊥ [1 kHz, 20° C.]: 9.2 CCY-3-O2 9.0 Δε [1 kHz, 20° C.]: −5.1 CLY-3-O2 6.5 K.sub.1 [pN, 20° C.]: 13.7 CLY-3-O3 5.0 K.sub.3 [pN, 20° C.]: 14.9 Y-4O-O4 3.0 V.sub.0 [V, 20° C.]: 1.81 CY-3-O2 15.5 γ.sub.1 [mPa s, 20° C.]: 102 B(S)-2O-O5 4.0 LTS bulk [h, −20° C.]: 504 B(S)-2O-O4 3.0 LTS bulk [h, −30° C.]: 144 CPYP-3-2 4.0 PY-3-O2 4.0 Σ 100.0

TABLE-US-00035 Mixture M31 CC-3-V 32.5 Clp. [° C.]: 74.5 CCP-3-1 5.0 Δn [589 nm, 20° C.]: 0.1012 CCY-3-O1 7.0 ε.sub.∥ [1 kHz, 20° C.]: 4.1 CCY-3-O2 7.0 ε.sub.⊥ [1 kHz, 20° C.]: 9.0 CLY-3-O2 6.5 Δε [1 kHz, 20° C.]: −4.9 CLY-3-O3 4.0 K.sub.1 [pN, 20° C.]: 13.7 Y-4O-O4 4.5 K.sub.3 [pN, 20° C.]: 14.8 CY-3-O2 14.0 V.sub.0 [V, 20° C.]: 1.83 B(S)-2O-O5 4.0 γ.sub.1 [mPa s, 20° C.]: 96 B(S)-2O-O4 4.0 LTS bulk [h, −20° C.]: 240 B(S)-2O-O6 4.0 CPYP-3-2 4.0 PY-3-O2 3.5 Σ 100.0

TABLE-US-00036 Mixture M32 CY-3-O2 8.5 Clp. [° C.]: 75 CLY-3-O2 8.0 Δn [589 nm, 20° C.]: 0.1023 CLY-3-O3 5.5 ε.sub.∥ [1 kHz, 20° C.]: 3.9 CLY-5-O2 5.0 ε.sub.⊥ [1 kHz, 20° C.]: 8.7 CLY-4-O2 5.0 Δε [1 kHz, 20° C.]: −4.8 CLY-2-O4 5.0 K.sub.1 [pN, 20° C.]: 14.4 CPY-3-O2 4.0 K.sub.3 [pN, 20° C.]: 14.3 CC-3-V 40.0 V.sub.0 [V, 20° C.]: 1.83 B(S)-2O-O5 3.0 γ.sub.1 [mPa s, 20° C.]: 92 B(S)-2O-O4 3.0 B(S)-2O-O6 3.0 B-2O-O5 4.0 Y-4O-O4 1.5 PY-3-O2 4.5 Σ 100.0

TABLE-US-00037 Mixture M33 CY-3-O2 5.0 Clp. [° C.]: 75 CLY-3-O2 8.0 Δn [589 nm, 20° C.]: 0.1024 CLY-3-O3 5.0 ε.sub.∥ [1 kHz, 20° C.]: 3.9 CLY-5-O2 5.0 ε.sub.⊥ [1 kHz, 20° C.]: 8.7 CLY-4-O2 5.0 Δε [1 kHz, 20° C.]: −4.8 CLY-2-O4 4.5 K.sub.1 [pN, 20° C.]: 15.1 CC-3-V 44.0 K.sub.3 [pN, 20° C.]: 14.1 B(S)-2O-O5 5.0 V.sub.0 [V, 20° C.]: 1.80 B(S)-2O-O4 5.0 γ.sub.1 [mPa s, 20° C.]: 85 B(S)-2O-O6 5.0 B-2O-O5 4.0 Y-4O-O4 1.0 PY-3-O2 3.5 Σ 100.0

TABLE-US-00038 Mixture M34 CY-3-O2 11.5 Clp. [° C.]: 75 CLY-3-O2 8.0 Δn [589 nm, 20° C.]: 0.1023 CLY-3-O3 5.0 ε.sub.∥ [1 kHz, 20° C.]: 3.9 CLY-5-O2 5.0 ε.sub.⊥ [1 kHz, 20° C.]: 8.9 CLY-4-O2 5.0 Δε [1 kHz, 20° C.]: −4.9 CLY-2-O4 5.0 K.sub.1 [pN, 20° C.]: 14.2 CPY-3-O2 4.5 K.sub.3 [pN, 20° C.]: 14.4 CC-3-V 37.5 V.sub.0 [V, 20° C.]: 1.81 B(S)-2O-O5 5.0 γ.sub.1 [mPa s, 20° C.]: 94 B(S)-2O-O4 4.0 LTS bulk [h, −20° C.]: 1000 B(S)-2O-O6 3.0 LTS bulk [h, −30° C.]: 120 Y-4O-O4 2.0 PY-3-O2 4.5 Σ 100.0

TABLE-US-00039 Mixture M35 CY-3-O2 11.5 Clp. [° C.]: 74.5 CLY-3-O2 8.0 Δn [589 nm, 20° C.]: 0.1026 CLY-3-O3 5.0 ε.sub.∥ [1 kHz, 20° C.]: 4.0 CLY-5-O2 5.0 ε.sub.⊥ [1 kHz, 20° C.]: 8.9 CLY-4-O2 5.0 Δε [1 kHz, 20° C.]: −5.0 CLY-2-O4 5.0 K.sub.1 [pN, 20° C.]: 14.6 CCP-3-1 3.5 K.sub.3 [pN, 20° C.]: 14.4 CC-3-V 36.0 V.sub.0 [V, 20° C.]: 1.80 B(S)-2O-O5 6.0 γ.sub.1 [mPa s, 20° C.]: 93 B(S)-2O-O4 5.0 LTS bulk [h, −20° C.]: 1000 B(S)-2O-O6 3.0 Y-4O-O4 2.0 PY-3-O2 5.0 Σ 100.0

TABLE-US-00040 Mixture M36 CCP-V-1 6.0 Clp. [° C.]: 75 CLY-3-O2 6.5 Δn [589 nm, 20° C.]: 0.1030 CLY-4-O2 2.0 ε.sub.∥ [1 kHz, 20° C.]: 3.4 CPY-3-O2 9.0 ε.sub.⊥ [1 kHz, 20° C.]: 6.1 PGIY-2-O4 6.0 Δε [1 kHz, 20° C.]: −2.6 PYP-2-3 1.5 K.sub.1 [pN, 20° C.]: 14.0 B(S)-2O-O4 4.0 K.sub.3 [pN, 20° C.]: 14.2 B(S)-2O-O5 5.0 V.sub.0 [V, 20° C.]: 2.45 B(S)-2O-O6 3.0 γ.sub.1 [mPa s, 20° C.]: 65 CC-3-V 53.0 LTS bulk [h, −20° C.]: 216 Y-4O-O4 2.0 PY-3-O2 2.0 Σ 100.0

TABLE-US-00041 Mixture M37 CLY-3-O2 7.5 Clp. [° C.]: 75.5 CLY-4-O2 5.0 Δn [589 nm, 20° C.]: 0.1032 CLY-5-O2 2.0 ε.sub.∥ [1 kHz, 20° C.]: 3.4 CPY-3-O2 9.0 ε.sub.⊥ [1 kHz, 20° C.]: 6.1 PGIY-2-O4 6.0 Δε [1 kHz, 20° C.]: −2.7 PYP-2-3 4.0 K.sub.1 [pN, 20° C.]: 14.0 B(S)-2O-O4 4.0 K.sub.3 [pN, 20° C.]: 14.2 B(S)-2O-O5 4.0 V.sub.0 [V, 20° C.]: 2.42 CC-3-V 54.0 γ.sub.1 [mPa s, 20° C.]: 69 Y-4O-O4 2.5 LTS bulk [h, −20° C.]: 192 PY-3-O2 2.0 Σ 100.0

TABLE-US-00042 Mixture M38 CY-3-O2 13.0 Clp. [° C.]: 80 CLY-3-O2 8.0 Δn [589 nm, 20° C.]: 0.1069 CLY-3-O3 6.0 ε.sub.∥ [1 kHz, 20° C.]: 4.2 CLY-5-O2 6.0 ε.sub.⊥ [1 kHz, 20° C.]: 10.3 CLY-4-O2 6.0 Δε [1 kHz, 20° C.]: −6.1 CLY-2-O4 6.0 K.sub.1 [pN, 20° C.]: 15.2 CPY-3-O2 8.5 K.sub.3 [pN, 20° C.]: 15.0 CC-3-V 29.0 V.sub.0 [V, 20° C.]: 1.66 B(S)-2O-O5 5.0 γ.sub.1 [mPa s, 20° C.]: 124 B(S)-2O-O4 4.0 LTS bulk [h, −20° C.]: 192 B(S)-2O-O6 3.0 LTS bulk [h, −30° C.]: 96 Y-4O-O4 5.0 PY-3-O2 0.5 Σ 100.0

TABLE-US-00043 Mixture M39 CY-3-O2 8.0 Clp. [° C.]: 79.5 CLY-3-O2 8.0 Δn [589 nm, 20° C.]: 0.1055 CLY-3-O3 5.0 ε.sub.∥ [1 kHz, 20° C.]: 4.0 CLY-5-O2 5.0 ε.sub.⊥ [1 kHz, 20° C.]: 9.3 CLY-4-O2 6.0 Δε [1 kHz, 20° C.]: −5.3 CLY-2-O4 6.0 K.sub.1 [pN, 20° C.]: 15.0 CPY-3-O2 8.0 K.sub.3 [pN, 20° C.]: 15.0 CC-3-V 35.0 V.sub.0 [V, 20° C.]: 1.78 B(S)-2O-O5 5.0 γ.sub.1 [mPa s, 20° C.]: 108 B(S)-2O-O4 4.0 LTS bulk [h, −20° C.]: 1000 B(S)-2O-O6 3.0 LTS bulk [h, −30° C.]: 312 Y-4O-O4 4.0 PY-3-O2 3.0 Σ 100.0

TABLE-US-00044 Mixture M40 CC-3-V 44.5 Clp. [° C.]: 81 CPY-3-O2 11.0 Δn [589 nm, 20° C.]: 0.1078 CLY-2-O4 4.0 ε.sub.∥ [1 kHz, 20° C.]: 3.5 CLY-3-O2 6.0 ε.sub.⊥ [1 kHz, 20° C.]: 7.2 CLY-3-O3 4.5 Δε [1 kHz, 20° C.]: −3.7 CLY-4-O2 4.0 K.sub.1 [pN, 20° C.]: 14.9 CLY-5-O2 4.0 K.sub.3 [pN, 20° C.]: 14.7 PYP-2-3 4.0 V.sub.0 [V, 20° C.]: 2.11 PY-3-O2 4.0 γ.sub.1 [mPa s, 20° C.]: 88 B(S)-2O-O5 4.0 B(S)-2O-O4 4.0 B(S)-2O-O6 3.0 Y-4O-O4 3.0 Σ 100.0

TABLE-US-00045 Mixture M41 CC-3-V 41.5 Clp. [° C.]: 81 CPY-3-O2 11.0 Δn [589 nm, 20° C.]: 0.1078 CLY-2-O4 4.0 ε.sub.∥ [1 kHz, 20° C.]: 3.7 CLY-3-O2 6.0 ε.sub.⊥ [1 kHz, 20° C.]: 7.5 CLY-3-O3 5.0 Δε [1 kHz, 20° C.]: −3.8 CLY-4-O2 4.0 K.sub.1 [pN, 20° C.]: 15.4 CLY-5-O2 4.0 K.sub.3 [pN, 20° C.]: 15.3 CCP-3-1 2.5 V.sub.0 [V, 20° C.]: 2.12 PYP-2-3 2.5 γ.sub.1 [mPa s, 20° C.]: 92 PY-3-O2 7.5 LTS bulk [h, −20° C.]: 1000 B(S)-2O-O5 4.0 B(S)-2O-O4 3.0 B(S)-2O-O6 2.0 Y-4O-O4 3.0 Σ 100.0

TABLE-US-00046 Mixture M42 CCP-3-1 2.0 Clp. [° C.]: 93 CCP-V-1 6.0 Δn [589 nm, 20° C.]: 0.1020 CCY-3-O2 0.5 ε.sub.∥ [1 kHz, 20° C.]: 3.5 CCY-3-O3 3.5 ε.sub.⊥ [1 kHz, 20° C.]: 7.6 CCY-5-O2 1.0 Δε [1 kHz, 20° C.]: −4.1 CLY-3-O2 14.0 K.sub.1 [pN, 20° C.]: 21.5 CLY-3-O3 4.5 K.sub.3 [pN, 20° C.]: 17.9 CLY-4-O2 5.0 V.sub.0 [V, 20° C.]: 2.20 PGIY-2-O4 3.5 γ.sub.1 [mPa s, 20° C.]: 121 B(S)-2O-O4 3.5 B(S)-2O-O5 4.5 B(S)-2O-O6 3.0 CC-3-V1 13.0 CC-2-3 9.0 CC-3-4 8.0 CC-3-5 11.0 PY-1-O2 2.0 Y-4O-O4 6.0 Σ 100.0

TABLE-US-00047 Mixture M43 B(S)-2O-O5 0.25 Clp. [° C.]: 72.5 CCP-3-1 16.0 Δn [589 nm, 20° C.]: 0.1036 CC-3-V 5.0 ε.sub.∥ [1 kHz, 20° C.]: 3.8 CC-3-V1 7.0 ε.sub.⊥ [1 kHz, 20° C.]: 6.9 CC-4-V1 9.0 Δε [1 kHz, 20° C.]: −3.1 CCY-3-O1 4.0 K.sub.1 [pN, 20° C.]: 13.5 CCY-3-O2 6.0 K.sub.3 [pN, 20° C.]: 15.1 CLY-3-O2 4.5 V.sub.0 [V, 20° C.]: 2.33 CPY-3-O2 5.0 γ.sub.1 [mPa s, 20° C.]: 96 CPY-2-O2 2.0 LTS bulk [h, −20° C.]: 1000 CY-3-O2 7.5 PY-1-O2 4.75 PYP-2-3 10.0 CC-3-O1 10.0 Y-4O-O4 9.0 Σ 100.0

TABLE-US-00048 Mixture M44 CCP-3-1 2.0 Clp. [° C.]: 89.5 CCP-V-1 8.0 Δn [589 nm, 20° C.]: 0.1040 CCY-3-O2 2.5 ε.sub.∥ [1 kHz, 20° C.]: 3.6 CCY-3-O3 2.5 ε.sub.⊥ [1 kHz, 20° C.]: 7.6 CCY-5-O2 2.0 Δε [1 kHz, 20° C.]: −4.0 CLY-3-O2 7.0 K.sub.1 [pN, 20° C.]: 20.7 CLY-3-O3 4.5 K.sub.3 [pN, 20° C.]: 16.9 CLY-4-O2 5.0 V.sub.0 [V, 20° C.]: 2.17 PGIY-2-O4 5.0 γ.sub.1 [mPa s, 20° C.]: 116 B(S)-2O-O4 4.0 B(S)-2O-O5 5.0 B(S)-2O-O6 3.5 CC-3-V1 12.5 CC-2-3 9.0 CC-3-4 8.0 CC-3-5 10.7 PY-1-O2 2.0 Y-4O-O4 6.5 CCQU-3-F 0.3 Σ 100.0

TABLE-US-00049 Mixture M45 CC-3-V 48.26 Clp. [° C.]: 76.5 CLY-3-O2 7.0 Δn [589 nm, 20° C.]: 0.0952 CLY-3-O3 6.0 ε.sub.∥ [1 kHz, 20° C.]: 3.5 CLY-2-O4 5.0 ε.sub.⊥ [1 kHz, 20° C.]: 6.6 CLY-4-O2 5.0 Δε [1 kHz, 20° C.]: −3.1 CLY-5-O2 3.22 K.sub.1 [pN, 20° C.]: 14.1 CPY-3-O2 12.0 K.sub.3 [pN, 20° C.]: 15.0 B(S)-2O-O4 2.04 V.sub.0 [V, 20° C.]: 2.33 PY-1-O2 7.65 γ.sub.1 [mPa s, 20° C.]: 77 Y-4O-O4 3.83 LTS bulk [h, −20° C.]: 384 Σ 100.0

TABLE-US-00050 Mixture M46 CC-3-V 50.0 Clp. [° C.]: 75.5 CC-5-V 6.31 Δn [589 nm, 20° C.]: 0.0947 CLY-3-O2 7.0 ε.sub.∥ [1 kHz, 20° C.]: 3.4 CLY-3-O3 6.0 ε.sub.⊥ [1 kHz, 20° C.]: 6.4 CLY-4-O2 5.0 Δε [1 kHz, 20° C.]: −3.1 CPY-3-O2 1.64 K.sub.1 [pN, 20° C.]: 14.1 B(S)-2O-O4 3.0 K.sub.3 [pN, 20° C.]: 13.4 B(S)-2O-O5 4.0 V.sub.0 [V, 20° C.]: 2.21 B(S)-2O-O6 2.0 γ.sub.1 [mPa s, 20° C.]: 68 COB(S)-2-O4 8.0 LTS bulk [h, −20° C.]: 480 PY-1-O2 5.97 Y-4O-O4 1.08 Σ 100.0

TABLE-US-00051 Mixture M47 CC-3-V 48.0 Clp. [° C.]: 76.5 CLY-3-O2 8.0 Δn [589 nm, 20° C.]: 0.0932 CLY-3-O3 6.0 ε.sub.∥ [1 kHz, 20° C.]: 3.5 CLY-2-O4 6.0 ε.sub.⊥ [1 kHz, 20° C.]: 6.7 CLY-4-O2 5.0 Δε [1 kHz, 20° C.]: −3.1 CLY-5-O2 5.0 K.sub.1 [pN, 20° C.]: 14.2 CPY-3-O2 8.0 K.sub.3 [pN, 20° C.]: 14.9 B(S)-2O-O4 2.0 V.sub.0 [V, 20° C.]: 2.31 PY-1-O2 8.0 γ.sub.1 [mPa s, 20° C.]: 79 Y-4O-O4 4.0 LTS bulk [h, −20° C.]: 672 Σ 100.0

TABLE-US-00052 Mixture M48 CC-3-V 49.5 Clp. [° C.]: 75 CLY-3-O2 8.0 Δn [589 nm, 20° C.]: 0.0935 CLY-3-O3 5.0 ε.sub.∥ [1 kHz, 20° C.]: 3.5 CLY-2-O4 5.0 ε.sub.⊥ [1 kHz, 20° C.]: 6.4 CPY-2-O2 10.5 Δε [1 kHz, 20° C.]: −2.9 CPY-3-O2 10.5 K.sub.1 [pN, 20° C.]: 13.3 B(S)-2O-O4 2.0 K.sub.3 [pN, 20° C.]: 14.3 CY-3-O2 3.5 V.sub.0 [V, 20° C.]: 2.33 PY-1-O2 2.0 γ.sub.1 [mPa s, 20° C.]: 75 Y-4O-O4 4.0 Σ 100.0

TABLE-US-00053 Mixture M49 B(S)-2O-O5 4.0 Clp. [° C.]: 75 CPP-3-2 8.0 Δn [589 nm, 20° C.]: 0.1022 CC-3-V1 10.0 ε.sub.∥ [1 kHz, 20° C.]: 3.8 CC-3-4 6.0 ε.sub.⊥ [1 kHz, 20° C.]: 7.1 CC-3-5 6.0 Δε [1 kHz, 20° C.]: −3.3 CCY-3-O1 12.0 K.sub.1 [pN, 20° C.]: 13.3 CCY-3-O2 7.0 K.sub.3 [pN, 20° C.]: 15.3 CLY-3-O2 1.0 V.sub.0 [V, 20° C.]: 2.26 CPY-2-O2 8.0 γ.sub.1 [mPa s, 20° C.]: 113 CVCP-V-1 8.0 CY-1-O2 8.5 PCH-302 13.0 PY-1-O2 2.5 Y-4O-O4 6.0 Σ 100.0

TABLE-US-00054 Mixture M50 B(S)-2O-O5 4.0 Clp. [° C.]: 89.5 CC-3-V 15.0 Δn [589 nm, 20° C.]: 0.0929 CC-3-V1 8.0 ε.sub.∥ [1 kHz, 20° C.]: 3.5 CC-4-V1 8.5 ε.sub.⊥ [1 kHz, 20° C.]: 7.4 CC-3-5 12.0 Δε [1 kHz, 20° C.]: −3.9 CCY-3-O2 11.0 K.sub.1 [pN, 20° C.]: 18.7 CCY-5-O2 3.5 K.sub.3 [pN, 20° C.]: 18.3 CLY-3-O2 9.0 V.sub.0 [V, 20° C.]: 2.29 CLY-3-O3 6.0 γ.sub.1 [mPa s, 20° C.]: 119 CLY-4-O2 5.0 CLY-5-O2 5.0 PY-1-O2 6.5 Y-4O-O4 6.5 Σ 100.0

TABLE-US-00055 Mixture M51 B(S)-2O-O4 5.0 Clp. [° C.]: 78 B(S)-2O-O5 5.0 Δn [589 nm, 20° C.]: 0.1146 B(S)-2O-O6 4.0 ε.sub.∥ [1 kHz, 20° C.]: 4.2 CC-3-V 32.0 ε.sub.⊥ [1 kHz, 20° C.]: 10.7 CLY-2-O4 4.5 Δε [1 kHz, 20° C.]: −6.4 CLY-3-O2 6.0 K.sub.1 [pN, 20° C.]: 15.7 CLY-3-O3 5.0 K.sub.3 [pN, 20° C.]: 14.1 CLY-4-O2 4.0 V.sub.0 [V, 20° C.]: 1.56 CLY-5-O2 5.0 γ.sub.1 [mPa s, 20° C.]: 123 COB(S)-2-O4 8.5 LTS bulk [h, −20° C.]: 1000 CCP-3-1 1.5 LTS bulk [h, −30° C.]: 480 CY-3-O2 8.5 PY-3-O2 7.0 B(S)-4O-O6 2.0 Y-4O-O4 2.0 Σ 100.0

TABLE-US-00056 Mixture M52 B(S)-2O-O4 5.0 Clp. [° C.]: 77.5 B(S)-2O-O5 5.0 Δn [589 nm, 20° C.]: 0.1146 B(S)-2O-O6 4.0 ε.sub.∥ [1 kHz, 20° C.]: 4.3 CC-3-V 31.5 ε.sub.⊥ [1 kHz, 20° C.]: 10.7 CLY-2-O4 4.5 Δε [1 kHz, 20° C.]: −6.4 CLY-3-O2 6.0 K.sub.1 [pN, 20° C.]: 15.7 CLY-3-O3 5.0 K.sub.3 [pN, 20° C.]: 14.0 CLY-4-O2 4.0 V.sub.0 [V, 20° C.]: 1.55 CLY-5-O2 5.0 γ.sub.1 [mPa s, 20° C.]: 123 COB(S)-2-O4 8.5 LTS bulk [h, −20° C.]: 1000 CCP-3-1 3.0 LTS bulk [h, −30° C.]: 336 CY-3-O2 5.0 PY-3-O2 7.5 B(S)-4O-O6 2.0 Y-4O-O4 4.0 Σ 100.0

TABLE-US-00057 Mixture M53 B(S)-2O-O4 5.0 Clp. [° C.]: 77.5 B(S)-2O-O5 5.0 Δn [589 nm, 20° C.]: 0.1150 B(S)-2O-O6 4.0 ε.sub.∥ [1 kHz, 20° C.]: 4.3 CC-3-V 30.5 ε.sub.⊥ [1 kHz, 20° C.]: 10.8 CLY-2-O4 4.5 Δε [1 kHz, 20° C.]: −6.4 CLY-3-O2 6.0 K.sub.1 [pN, 20° C.]: 15.8 CLY-3-O3 5.0 K.sub.3 [pN, 20° C.]: 14.0 CLY-4-O2 4.0 V.sub.0 [V, 20° C.]: 1.56 CLY-5-O2 5.0 γ.sub.1 [mPa s, 20° C.]: 118 COB(S)-2-O4 8.5 LTS bulk [h, −20° C.]: 1000 CCP-3-1 5.0 LTS bulk [h, −30° C.]: 744 CY-3-O2 2.0 PY-3-O2 7.5 B(S)-4O-O6 2.0 Y-4O-O4 6.0 Σ 100.0

TABLE-US-00058 Mixture M54 B(S)-2O-O4 5.0 Clp. [° C.]: 77 B(S)-2O-O5 5.0 Δn [589 nm, 20° C.]: 0.1145 B(S)-2O-O6 4.0 ε.sub.∥ [1 kHz, 20° C.]: 4.3 CC-3-V 32.5 ε.sub.⊥ [1 kHz, 20° C.]: 10.8 CLY-2-O4 4.5 Δε [1 kHz, 20° C.]: −6.5 CLY-3-O2 6.0 K.sub.1 [pN, 20° C.]: 15.6 CLY-3-O3 5.0 K.sub.3 [pN, 20° C.]: 14.0 CLY-4-O2 4.0 V.sub.0 [V, 20° C.]: 1.55 CLY-5-O2 5.0 γ.sub.1 [mPa s, 20° C.]: 122 COB(S)-2-O4 8.5 LTS bulk [h, −20° C.]: 1000 CCP-3-1 2.0 CY-3-O2 4.5 PY-3-O2 7.0 B(S)-4O-O6 3.0 Y-4O-O4 4.0 Σ 100.0

TABLE-US-00059 Mixture M55 B(S)-2O-O4 5.0 Clp. [° C.]: 77.5 B(S)-2O-O5 5.0 Δn [589 nm, 20° C.]: 0.1142 B(S)-2O-O6 4.0 ε.sub.∥ [1 kHz, 20° C.]: 4.3 CC-3-V 34.0 ε.sub.⊥ [1 kHz, 20° C.]: 10.7 CLY-2-O4 4.5 Δε [1 kHz, 20° C.]: −6.4 CLY-3-O2 6.0 K.sub.1 [pN, 20° C.]: 16.1 CLY-3-O3 5.0 K.sub.3 [pN, 20° C.]: 13.8 CLY-4-O2 4.0 V.sub.0 [V, 20° C.]: 1.55 CLY-5-O2 5.0 γ.sub.1 [mPa s, 20° C.]: 118 COB(S)-2-O4 8.5 LTS bulk [h, −20° C.]: 1000 CCP-3-1 1.5 LTS bulk [h, −30° C.]: 192 CY-3-O2 3.0 PY-3-O2 6.5 B(S)-4O-O6 4.0 Y-4O-O4 4.0 Σ 100.0

TABLE-US-00060 Mixture M56 B(S)-2O-O4 5.0 Clp. [° C.]: 77 B(S)-2O-O5 5.0 Δn [589 nm, 20° C.]: 0.1146 B(S)-2O-O6 4.0 ε.sub.∥ [1 kHz, 20° C.]: 4.3 CC-3-V 31.5 ε.sub.⊥ [1 kHz, 20° C.]: 10.7 CLY-2-O4 5.5 Δε [1 kHz, 20° C.]: −6.5 CLY-3-O2 5.5 K.sub.1 [pN, 20° C.]: 15.2 CLY-3-O3 4.5 K.sub.3 [pN, 20° C.]: 14.1 CLY-4-O2 4.5 V.sub.0 [V, 20° C.]: 1.56 CLY-5-O2 5.0 γ.sub.1 [mPa s, 20° C.]: 125 COB(S)-2-O4 8.0 LTS bulk [h, −20° C.]: 840 CPY-3-O2 2.5 LTS bulk [h, −30° C.]: 528 CY-3-O2 9.5 PY-3-O2 7.5 Y-4O-O4 2.0 Σ 100.0

TABLE-US-00061 Mixture M57 B(S)-2O-O4 5.0 Clp. [° C.]: 78 B(S)-2O-O5 5.0 Δn [589 nm, 20° C.]: 0.1148 B(S)-2O-O6 4.0 ε.sub.∥ [1 kHz, 20° C.]: 4.3 CC-3-V 32.0 ε.sub.⊥ [1 kHz, 20° C.]: 10.8 CLY-2-O4 5.5 Δε [1 kHz, 20° C.]: −6.5 CLY-3-O2 5.5 K.sub.1 [pN, 20° C.]: 15.3 CLY-3-O3 4.5 K.sub.3 [pN, 20° C.]: 14.1 CLY-4-O2 4.5 V.sub.0 [V, 20° C.]: 1.56 CLY-5-O2 5.0 γ.sub.1 [mPa s, 20° C.]: 125 COB(S)-2-O4 8.0 LTS bulk [h, −20° C.]: 840 CPY-3-O2 4.5 LTS bulk [h, −30° C.]: 144 CY-3-O2 6.5 PY-3-O2 6.0 Y-4O-O4 4.0 Σ 100.0

TABLE-US-00062 Mixture M58 B(S)-2O-O4 5.0 Clp. [° C.]: 78 B(S)-2O-O5 5.0 Δn [589 nm, 20° C.]: 0.1145 B(S)-2O-O6 4.0 ε.sub.∥ [1 kHz, 20° C.]: 4.3 CC-3-V 32.5 ε.sub.⊥ [1 kHz, 20° C.]: 10.8 CLY-2-O4 5.5 Δε [1 kHz, 20° C.]: −6.5 CLY-3-O2 5.5 K.sub.1 [pN, 20° C.]: 15.4 CLY-3-O3 4.5 K.sub.3 [pN, 20° C.]: 14.1 CLY-4-O2 4.5 V.sub.0 [V, 20° C.]: 1.56 CLY-5-O2 5.0 γ.sub.1 [mPa s, 20° C.]: 121 COB(S)-2-O4 8.0 LTS bulk [h, −20° C.]: 1000 CPY-3-O2 6.0 LTS bulk [h, −30° C.]: 792 CY-3-O2 3.0 PY-3-O2 5.5 Y-4O-O4 6.0 Σ 100.0

TABLE-US-00063 Mixture M59 B(S)-2O-O4 5.0 Clp. [° C.]: 77 B(S)-2O-O5 5.0 Δn [589 nm, 20° C.]: 0.1146 B(S)-2O-O6 4.0 ε.sub.∥ [1 kHz, 20° C.]: 4.3 CC-3-V 31.5 ε.sub.⊥ [1 kHz, 20° C.]: 10.8 CLY-2-O4 4.5 Δε [1 kHz, 20° C.]: −6.5 CLY-3-O2 6.0 K.sub.1 [pN, 20° C.]: 16.0 CLY-3-O3 5.0 K.sub.3 [pN, 20° C.]: 13.7 CLY-4-O2 4.0 V.sub.0 [V, 20° C.]: 1.54 CLY-5-O2 5.0 γ.sub.1 [mPa s, 20° C.]: 119 COB(S)-2-O4 8.5 LTS bulk [h, −20° C.]: 264 CCP-3-1 4.0 LTS bulk [h, −30° C.]: 96 CY-3-O2 1.5 PY-3-O2 7.0 B(S)-4O-O6 3.0 Y-4O-O4 6.0 Σ 100.0

TABLE-US-00064 Mixture M60 B(S)-2O-O5 4.0 Clp. [° C.]: 70.1 B-2O-O5 6.0 Δn [589 nm, 20° C.]: 0.1074 CPP-3-2 16.0 ε.sub.∥ [1 kHz, 20° C.]: 3.7 CC-2-3 18.0 ε.sub.⊥ [1 kHz, 20° C.]: 6.0 CC-3-4 4.0 Δε [1 kHz, 20° C.]: −2.3 CC-3-5 3.0 K.sub.1 [pN, 20° C.]: 15.5 CCP-3-1 13.0 K.sub.3 [pN, 20° C.]: 12.7 CCP-3-3 8.0 V.sub.0 [V, 20° C.]: 2.40 CLY-3-O2 8.0 γ.sub.1 [mPa s, 20° C.]: 80 PP-1-4 5.0 PY-3-O2 5.0 Y-4O-O4 10.0 Σ 100.0

TABLE-US-00065 Mixture M61 B(S)-2O-O4 4.0 Clp. [° C.]: 75.2 B(S)-2O-O5 3.0 Δn [589 nm, 20° C.]: 0.1068 B-2O-O5 3.0 ε.sub.∥ [1 kHz, 20° C.]: 3.6 CPP-3-2 5.75 ε.sub.⊥ [1 kHz, 20° C.]: 6.1 BCH-52 2.5 Δε [1 kHz, 20° C.]: −2.5 CC-3-V 36.25 K.sub.1 [pN, 20° C.]: 13.9 CC-4-V 3.25 K.sub.3 [pN, 20° C.]: 13.3 CCP-V-1 14.25 V.sub.0 [V, 20° C.]: 2.39 CLY-3-O2 4.75 γ.sub.1 [mPa s, 20° C.]: 69 CLY-3-O3 5.5 CPY-3-O2 1.75 PGIY-2-O4 6.0 PY-3-O2 5.0 Y-4O-O4 5.0 Σ 100.0

TABLE-US-00066 Mixture M62 B(S)-2O-O4 4.0 Clp. [° C.]: 75.2 B(S)-2O-O5 3.0 Δn [589 nm, 20° C.]: 0.1067 B-2O-O5 3.0 ε.sub.∥ [1 kHz, 20° C.]: 3.5 CPP-3-2 3.83 ε.sub.⊥ [1 kHz, 20° C.]: 6.1 BCH-52 1.67 Δε [1 kHz, 20° C.]: −2.6 CC-3-V 40.17 K.sub.1 [pN, 20° C.]: 13.7 CC-4-V 2.16 K.sub.3 [pN, 20° C.]: 13.3 CCP-V-1 12.33 V.sub.0 [V, 20° C.]: 2.40 CLY-3-O2 3.83 γ.sub.1 [mPa s, 20° C.]: 70 CLY-3-O3 5.17 CPY-2-O2 3.34 CPY-3-O2 1.17 CY-3-O2 1.67 PGIY-2-O4 6.0 PY-3-O2 3.33 PYP-2-3 2.0 Y-4O-O4 3.33 Σ 100.0

TABLE-US-00067 Mixture M63 B(S)-2O-O4 4.0 Clp. [° C.]: 75.7 B(S)-2O-O5 3.0 Δn [589 nm, 20° C.]: 0.1084 B-2O-O5 3.0 ε.sub.∥ [1 kHz, 20° C.]: 3.6 CPP-3-2 16.0 ε.sub.⊥ [1 kHz, 20° C.]: 6.2 CC-2-3 18.0 Δε [1 kHz, 20° C.]: −2.6 CC-3-O1 8.0 K.sub.1 [pN, 20° C.]: 15.4 CC-3-4 5.0 K.sub.3 [pN, 20° C.]: 13.2 CC-3-5 3.0 V.sub.0 [V, 20° C.]: 2.38 CCP-3-1 13.0 γ.sub.1 [mPa s, 20° C.]: 86 CLY-3-O2 6.5 CPY-3-O2 5.0 PY-3-O2 2.0 PYP-2-3 4.5 Y-4O-O4 9.0 Σ 100.0

TABLE-US-00068 Mixture M64 CCY-3-O2 7.0 Clp. [° C.]: 84.6 CPY-3-O2 12.0 Δn [589 nm, 20° C.]: 0.1121 CLY-3-O2 7.0 ε.sub.∥ [1 kHz, 20° C.]: 3.7 CLY-3-O3 7.0 ε.sub.⊥ [1 kHz, 20° C.]: 7.7 PY-3-O2 5.0 Δε [1 kHz, 20° C.]: −4.0 Y-4O-O4 2.0 K.sub.1 [pN, 20° C.]: 16.6 PGIY-2-O4 6.0 K.sub.3 [pN, 20° C.]: 16.9 B-2O-O5 5.0 V.sub.0 [V, 20° C.]: 2.14 B(S)-2O-O5 5.0 γ.sub.1 [mPa s, 20° C.]: 104 CC-3-V 34.0 CC-3-V1 10.0 Σ 100.0

TABLE-US-00069 Mixture M65 B(S)-2O-O4 6.0 Clp. [° C.]: 73.8 B(S)-2O-O5 3.0 Δn [589 nm, 20° C.]: 0.1075 B-2O-O5 3.0 ε.sub.∥ [1 kHz, 20° C.]: 3.6 CPP-3-2 14.5 ε.sub.⊥ [1 kHz, 20° C.]: 6.3 CC-2-3 18.0 Δε [1 kHz, 20° C.]: −2.7 CC-3-4 5.0 K.sub.1 [pN, 20° C.]: 15.8 CC-3-5 3.0 K.sub.3 [pN, 20° C.]: 13.8 CCP-3-1 13.0 V.sub.0 [V, 20° C.]: 2.37 CCP-3-3 5.0 γ.sub.1 [mPa s, 20° C.]: 88 CLY-3-O2 8.0 PCH-302 7.0 PY-3-O2 6.5 Y-4O-O4 8.0 Σ 100.0

TABLE-US-00070 Mixture M66 B(S)-2O-O5 4.0 Clp. [° C.]: 87.8 CC-3-V 35.0 Δn [589 nm, 20° C.]: 0.1024 CC-3-V1 5.0 ε.sub.∥ [1 kHz, 20° C.]: 3.6 CCY-3-O2 6.0 ε.sub.⊥ [1 kHz, 20° C.]: 7.5 CCY-4-O2 3.0 Δε [1 kHz, 20° C.]: −3.9 CCY-5-O2 6.0 K.sub.1 [pN, 20° C.]: 16.0 CLY-3-O2 6.0 K.sub.3 [pN, 20° C.]: 16.5 CLY-3-O3 6.0 V.sub.0 [V, 20° C.]: 2.16 CLY-4-O2 4.0 γ.sub.1 [mPa s, 20° C.]: 113 CLY-5-O2 4.0 CPY-3-O2 5.0 PGIY-2-O4 6.0 PY-3-O2 5.0 Y-4O-O4 5.0 Σ 100.0

TABLE-US-00071 Mixture M67 CCY-3-O2 6.0 Clp. [° C.]: 87.5 CCY-3-O3 4.5 Δn [589 nm, 20° C.]: 0.1033 CCY-5-O2 6.0 ε.sub.∥ [1 kHz, 20° C.]: 3.6 CLY-3-O2 6.0 ε.sub.⊥ [1 kHz, 20° C.]: 7.6 CLY-3-O3 6.0 Δε [1 kHz, 20° C.]: −4.0 CLY-4-O2 2.0 K.sub.1 [pN, 20° C.]: 16.4 CPY-3-O2 6.0 K.sub.3 [pN, 20° C.]: 16.8 PGIY-2-O4 5.0 V.sub.0 [V, 20° C.]: 2.16 Y-4O-O4 4.0 γ.sub.1 [mPa s, 20° C.]: 107 B(S)-2O-O4 4.0 LTS bulk [h, −20° C.]: 264 B(S)-2O-O5 4.0 CC-3-V 35.0 CC-3-V1 8.0 PY-3-O2 3.5 Σ 100.0

TABLE-US-00072 Mixture M68 B(S)-2O-O4 2.0 Clp. [° C.]: 87.4 B(S)-2O-O5 1.5 Δn [589 nm, 20° C.]: 0.1117 CC-3-V 33.0 ε.sub.∥ [1 kHz, 20° C.]: 3.7 CC-3-V1 4.0 ε.sub.⊥ [1 kHz, 20° C.]: 7.9 CCY-3-O1 4.5 Δε [1 kHz, 20° C.]: −4.2 CCY-3-O2 7.0 K.sub.1 [pN, 20° C.]: 16.1 CLY-3-O2 6.0 K.sub.3 [pN, 20° C.]: 16.8 CLY-3-O3 5.0 V.sub.0 [V, 20° C.]: 2.11 CLY-4-O2 4.0 γ.sub.1 [mPa s, 20° C.]: 120 CLY-5-O2 4.0 LTS bulk [h, −20° C.]: 1000 CPY-3-O2 10.0 PGIY-2-O4 6.0 PY-1-O4 5.0 PY-3-O2 5.0 Y-4O-O4 3.0 Σ 100.0

TABLE-US-00073 Mixture M69 B(S)-2O-O4 3.0 Clp. [° C.]: 75.9 B(S)-2O-O5 1.75 Δn [589 nm, 20° C.]: 0.1073 B-2O-O5 2.75 ε.sub.∥ [1 kHz, 20° C.]: 3.7 CPP-3-2 8.0 ε.sub.⊥ [1 kHz, 20° C.]: 6.4 CPPC-3-3 2.0 Δε [1 kHz, 20° C.]: −2.7 CGPC-3-3 1.0 K.sub.1 [pN, 20° C.]: 14.1 CC-2-3 15.75 K.sub.3 [pN, 20° C.]: 14.1 CC-3-O1 12.5 V.sub.0 [V, 20° C.]: 2.42 CC-3-4 2.0 γ.sub.1 [mPa s, 20° C.]: 102 CC-3-5 1.5 LTS bulk [h, −20° C.]: 1000 CCP-3-1 13.25 CCP-3-3 2.0 CLY-3-O2 4.0 CPY-3-O2 8.25 CY-3-O2 7.5 CY-5-O2 0.75 PGIGI-3-F 2.0 PY-3-O2 0.75 PYP-2-3 5.0 Y-4O-O4 6.25 Σ 100.0

TABLE-US-00074 Mixture M70 CCY-3-O2 7.0 Clp. [° C.]: 84.6 CPY-3-O2 12.0 Δn [589 nm, 20° C.]: 0.1121 CLY-3-O2 7.0 ε.sub.∥ [1 kHz, 20° C.]: 3.7 CLY-3-O3 7.0 ε.sub.⊥ [1 kHz, 20° C.]: 7.7 PY-3-O2 5.0 Δε [1 kHz, 20° C.]: −4.0 Y-4O-O4 2.0 K.sub.1 [pN, 20° C.]: 16.6 PGIY-2-O4 6.0 K.sub.3 [pN, 20° C.]: 16.9 B-2O-O5 5.0 V.sub.0 [V, 20° C.]: 2.14 B(S)-2O-O5 5.0 γ.sub.1 [mPa s, 20° C.]: 104 CC-3-V 34.0 CC-3-V1 10.0 Σ 100.0

TABLE-US-00075 Mixture M71 CC-3-V 17.0 Clp. [° C.]: 75.1 CLY-2-O4 5.0 Δn [589 nm, 20° C.]: 0.1221 CLY-3-O2 8.0 ε.sub.∥ [1 kHz, 20° C.]: 4.4 CLY-3-O3 6.0 ε.sub.⊥ [1 kHz, 20° C.]: 10.6 CLY-4-O2 5.0 Δε [1 kHz, 20° C.]: −6.1 COB(S)-2-O4 6.0 K.sub.1 [pN, 20° C.]: 13.0 CPY-2-O2 6.0 K.sub.3 [pN, 20° C.]: 13.4 CPY-3-O2 6.0 V.sub.0 [V, 20° C.]: 1.56 CY-3-O2 6.5 γ.sub.1 [mPa s, 20° C.]: 167 CY-3-O4 15.0 PGIY-2-O4 5.0 PY-2-O2 5.0 PYP-2-3 6.0 Y-4O-O4 3.5 Σ 100.0

TABLE-US-00076 Mixture M72 Y-4O-O4 4.0 Clp. [° C.]: 71 CY-3-O2 14.0 Δn [589 nm, 20° C.]: 0.1099 PY-3-O2 12.0 Δε [1 kHz, 20° C.]: −6.0 CCY-3-O1 4.0 K.sub.1 [pN, 20° C.]: 11.2 CCY-3-O2 7.0 K.sub.3 [pN, 20° C.]: 12.5 CCY-3-O3 4.0 V.sub.0 [V, 20° C.]: 1.65 CCY-4-O2 4.0 γ.sub.1 [mPa s, 20° C.]: 125 CLY-3-O2 6.0 CLY-3-O3 6.0 B(S)-2O-O4 4.0 B(S)-(c5)1O-O2 4.0 PGIY-2-O4 5.0 CC-3-V 21.5 CCP-V-1 4.5 Σ 100.0

TABLE-US-00077 Mixture M73 Y-4O-O4 4.0 Clp. [° C.]: 72 CY-(c5)-O2 14.0 Δn [589 nm, 20° C.]: 0.1111 PY-3-O2 12.0 Δε [1 kHz, 20° C.]: −6.2 CCY-3-O1 4.0 γ.sub.1 [mPa s, 20° C.]: 138 CCY-3-O2 7.0 CCY-3-O3 4.0 CCY-4-O2 4.0 CLY-3-O2 6.0 CLY-3-O3 6.0 B(S)-2O-O4 4.0 B(S)-2O-O5 4.0 PGIY-2-O4 5.0 CC-3-V 21.5 CCP-V-1 4.5 Σ 100.0

[0462] Polymerisable Mixtures

[0463] The following polymerisable mixtures are prepared from the nematic mixtures given in Table 1 by adding a reactive mesogen (RM) selected from the group of compounds of the formulae RM1. RM2, RM3 and RM4 in the amount given in Table 1 (% RM).

TABLE-US-00078 TABLE 1 Polymerisable Mixtures. LC Mixture Host RM % RM P1 M1 RM1 0.3 P2 M3 RM2 0.3 P3 M5 RM3 0.3 P4 M7 RM4 0.3 P5 M10 RM1 0.25 P6 M11 RM2 0.25 P7 M12 RM3 0.25 P8 M13 RM4 0.25 [00288] RM1 [00289] RM2 [00290] RM3 [00291] RM4

[0464] The preceding examples can be repeated with similar success by substituting the generically or specifically described reactants and/or operating conditions of this invention for those used in the preceding examples.

[0465] Without further elaboration, it is believed that one skilled in the art can, using the preceding description, utilize the present invention to its fullest extent. The preceding preferred specific embodiments are, therefore, to be construed as merely illustrative, and not limitative of the remainder of the disclosure in any way whatsoever. From the description, one skilled in the art can easily ascertain the essential characteristics of this invention and, without departing from the spirit and scope thereof, can make various changes and modifications of the invention to adapt it to various usages and conditions.

[0466] The entire disclosures of all applications, patents and publications, cited herein and of corresponding EP application No. 22172035.2, filed May 6, 2022, are incorporated by reference herein.