Compact absorption column for CO.SUB.2 .capture

Abstract

An acid gas absorber includes a co-current flue gas-lean solution section and a packed counter-current flue gas-liquid phase section useful in a method of capturing an acid gas from flue gas in a more efficient and cost effective manner.

Claims

1. An acid gas absorber, comprising: a co-current flue gas-lean solution packing-free section; at least one heat exchanger positioned in the co-current flue gas-lean solution packing-free section; and a packed counter-current flue gas-liquid phase section.

2. The acid gas absorber of claim 1, wherein the co-current flue gas-lean solution packing-free section at least partially overlies the packed counter-current flue gas-liquid phase section.

3. The acid gas absorber of claim 1, wherein the co-current flue gas-lean solution packing-free section includes a lean solution inlet nozzle adapted for producing a fog of lean solution in a first subsection of the co-current flue gas-lean solution section.

4. The acid gas absorber of claim 3, further including a gas riser connecting the packed counter-current flue gas-liquid phase section with the co-current flue gas-lean solution packing-free section, said gas riser being adapted to deliver flue gas from the counter-current flue gas-liquid phase section to the first subsection of the co-current flue gas-lean solution packing-free section.

5. The acid gas absorber of claim 1, wherein the co-current flue gas-lean solution packing-free section further includes a froth generator separating a second subsection of the co-current flue gas-lean solution packing-free section from a first subsection of the co-current flue gas-lean solution packing-free section.

6. The acid gas absorber of claim 5, wherein the froth in the second subsection coalesces into a liquid phase that passes through a discharge port from the co-current flue gas-lean solution packing-free section to the packed counter-current flue gas-liquid phase section.

7. The acid gas absorber of claim 1, wherein said at least one heat exchanger is positioned in a first subsection of the co-current flue gas-lean solution packing-free section.

8. The acid gas absorber of claim 1, wherein said at least one heat exchanger includes a first heat exchanger positioned in a first subsection of the co-current flue gas-lean solution packing-free section and a second heat exchanger positioned in a second subsection of the co-current flue gas-lean solution packing-free section.

9. The acid gas absorber of claim 1, further including structured packing or random packing in the packed counter-current flue gas-liquid phase section.

10. The acid gas absorber of claim 9, further including a liquid distributor overlying the structured packing or random packing in the packed counter-current flue gas-liquid phase section.

11. The acid gas absorber of claim 10, further including a flue gas inlet in the packed counter-current flue gas-liquid phase section and located below the structured packing or random packing.

12. The acid gas absorber of claim 11, further including a rich amine outlet in the packed counter-current flue gas-liquid phase section and located below the flue gas inlet.

Description

BRIEF DESCRIPTION OF THE DRAWING FIGURES

(1) The accompanying drawing figures incorporated herein and forming a part of the patent specification, illustrate several aspects of the apparatus and method and together with the description serve to explain certain principles thereof.

(2) FIG. 1 is a schematic diagram of a state-of-the-art post combustion CO.sub.2 capture apparatus that uses aqueous amine solvent as the acid gas capture agent.

(3) FIG. 2 is a graph of temperature as a function of height in a 0.7 MWe Small Pilot Absorber.

(4) FIG. 3 is a graph illustrating the effectiveness of CO.sub.2 absorber along column height where YCO.sub.2 is the CO.sub.2 gas phase concentration and dY*CO.sub.2 is the driving force between the gas and liquid for mass transfer.

(5) FIG. 4 is a schematic illustration of the new and improved apparatus, in the form of a compact absorber, useful in a new and improved method of capturing acid gas/CO.sub.2 using an aqueous amine solvent.

(6) FIG. 5 is a graph of CO.sub.2 capture efficiency as a function of carbon loading for 30 wt % MEA solutions containing various amounts of S554 Surfactant.

(7) FIG. 6 is a graph of surface elasticity as a function of carbon loading (C/N) with and without S-554 in different amine solutions at room temperature.

(8) Reference will now be made in detail to the present preferred embodiments of the apparatus and method, examples of which are illustrated in the accompanying drawing figures.

DETAILED DESCRIPTION

(9) As illustrated in FIG. 4, the new and improved acid gas absorber 10 includes a packing-free, co-current flue gas-lean solution section, generally designated by reference numeral 14, and a packed counter-current flue gas-liquid phase section, generally designated by reference numeral 16. In the illustrated embodiment, the co-current flue gas-lean solution section 14 at least partially overlies the packed counter-current flue gas-liquid phase section 16.

(10) The packed counter-current flue gas-liquid phase section 16 includes an internal chamber 17. A flue gas inlet 20, in the packing-free section 12 functions to deliver flue gas to the packing section 18. Structured or random packing 22 is provided in the packing section 18 above the flue gas inlet 20. Such structured or random packing 22 is known in the art to aid in the capture of carbon dioxide from the flue gas. A liquid distributor 24 extends across the packing section 18 above the structured or random packing 22. The function of the liquid distributor 24 will be discussed later in this document.

(11) A gas riser 26 connects the top of the packed counter-current flue gas-liquid phase section 16 with the packing-free, co-current flue gas-lean solution section 14. More specifically, the flue gas riser 26 includes an inlet 28 connected to the packed counter-current flue gas-liquid phase section 16 and an outlet 30 connected to the co-current flue gas-lean solution section 14.

(12) The co-current flue gas-lean solution section 14 includes a chamber 32 that is divided by a froth generator 34 into a first or fog subsection 36 and a second or froth subsection 38 wherein the first subsection overlies the second subsection. The froth generator 34 may comprise a screen or any other structure known in the art to be adapted for generating a froth from an amine solution of the type adapted to capture carbon dioxide from a flue gas stream. Such amine solutions include but are not necessarily limited to monoethanolamine (MEA), piperazine (PZ) and methyldiethanolamine (MDEA). As illustrated in FIG. 4, the top of the co-current flue gas-lean solution section 14 includes a lean amine inlet 40 having a nozzle 42 adapted to produce a fog F of lean amine solution in the first subsection 36.

(13) In the illustrated embodiment, a first heat exchanger 44 is positioned in the first subsection 36 to allow a coolant, such as water or other appropriate fluid, to be circulated through the first subsection and a second heat exchanger 46 is positioned in the second subsection 38 to allow a coolant, such as water or other appropriate fluid, to be circulated through the second subsection. Together, the two heat exchangers 44, 46 may be operated to provide cooling to the lean amine solution and maintain an optimum operating temperature (i.e. 35-50° C.) within the co-current flue gas-lean solution section 14 in order to increase the capture efficiency of the lean amine solution. That temperature may be monitored by one or more temperature sensors within the absorber 10. Coolant flow to maintain the desired temperature range may be controlled by adjusting a flow control valve or pump (not shown).

(14) A treated flue gas outlet 48 in the packing-free section 12 provides for the discharge of treated flue gas from the second subsection 38. A rich amine outlet 50 in the packing-free section 12 provides for the discharge of rich amine from the packing section 18 of the packed counter-current flue gas-liquid phase section 16. A discharge port 52, at the bottom of the second section 38 provides for the delivery of the liquid phase L of the amine solution from the second subsection to the packed counter-current flue gas-liquid phase section 16.

(15) The method of operation of the acid gas absorber 10, illustrated in FIG. 4 and described above, will now be described. Untreated flue gas is delivered to the packing section of the packed counter-current flue gas-liquid phase section 16 through the flue gas inlet 20. Simultaneously, lean amine solution is delivered to the first subsection 36 of the co-current flue gas-lean solution section 14 at the lean amine inlet 40.

(16) The flue gas delivered to the packing section 18 rises upwardly (note action arrow A) mixing with the liquid phase of the amine solution that is moving downwardly (note action arrow B) under the force of gravity. Thus, a counter-current flow of flue gas and amine solution is provided. That liquid phase of the amine solution received from the co-current flue gas-lean solution section 14 is efficiently distributed over the structured or random packing 22 by the liquid distributor 24. The structured or random packing 22 provides desired mixing and exposed surface area to promote the capture of the carbon dioxide in the flue gas by the liquid phase of the amine solution. The now carbon dioxide rich amine solution is discharged from the rich amine outlet 50 at the bottom of the packing section 18 and delivered to a stripper (not shown) for the stripping of the carbon dioxide from the amine solution. This generates a lean amine solution that is recycled back to the absorber 10 at the lean amine inlet 40.

(17) The now partially treated flue gas enters the gas riser 26 through the inlet 28 at the top of the packed counter-current flue gas-liquid phase section 16 and is then delivered to the first subsection 36 of the co-current flue gas-lean solution section 14. There the partially treated flue gas comes into contact with the fog F of lean amine solution generated by the nozzle(s) 42 at the lean solution inlet 40. The droplets of lean amine solution forming the fog are typically, on average, less than 50 μm in diameter, thereby providing a large surface area for reaction and capture of any remaining carbon dioxide in the partially treated flue gas. The controlled operation of the first heat exchanger 44 ensures the temperature of the lean amine solution in the first subsection 36 is at the best temperature to optimize CO.sub.2 capture. The lean amine solution and the flue gas are now moving in the same direction (note action arrow C) in a downwardly co-current flow toward the froth generator 34.

(18) The froth generator 34 separating the two subsections 36, 38 of the co-current flue gas-lean solution section 14 generates a froth FR with bubbles on average of about 3-8 mm in size. Those bubble generally have a film thickness of about 10 μm or less. Those bubbles also provide a large surface area for contact with the carbon dioxide remaining in the partially treated flue gas so as to increase the efficiency of the CO.sub.2 capture by the lean amine solution. About 60-80% of the CO.sub.2 capture occurs in the packing-free co-current flue gas-lean solution section 14. The second heat exchanger 46 maintains the froth at an optimum temperature for carbon capture by the amine solution.

(19) The CO.sub.2 capture efficiency and frothing action of the amine solution may be enhanced by as much as 15-20% throughout the carbon loading range by adding surfactant to change the solvent surface tension. Chemguard S-554, a perfluoro-based ethylated nonionic fluorosurfactant) is a surfactant particularly useful for this purpose (see FIGS. 5 and 6). However, other types of surfactants may be used to produce the desired results. At lean loading a significant amount of foaming is observed and foaming decreases until, at the rich condition, it becomes negligible.

(20) The now fully treated flue gas is then discharged from the second subsection 38 at the treated flue gas outlet 48. The froth coalesces into a liquid phase at the bottom of the second subsection 38 and it is this liquid phase of amine solution that is delivered to the liquid distributor 24 and distributed over and across the structured or random packing in the internal chamber 18 of the packed counter-current flue gas-liquid phase section 16.

(21) Summarizing, the method of capturing acid gas from flue gas may be generally described as including the steps of contacting the flue gas with a liquid phase amine solution in a packed counter-current flue gas-liquid phase section 16 of an acid gas absorber 10 to provide a partially treated flue gas and delivering the partially treated flue gas from the packed counter-current flue gas-liquid phase section 16 to a co-current flue gas-lean solution section 14 of the acid gas absorber.

(22) The method may also include the steps of contacting the partially treated flue gas with a fog F of lean amine solution and coalescing the fog F of amine solution into the liquid phase amine solution that contacts the flue gas in the counter-current flue gas-liquid phase section 16 of the acid gas absorber 10. Further, the method may also include the steps of contacting the partially treated flue gas with a froth FR of the amine solution and coalescing the froth of the amine solution into the liquid phase amine solution that contacts the flue gas in the co-current flue gas-liquid phase section 14 of the acid gas absorber 10. Still further, as previously described above, the method may also include the steps of transferring the liquid phase amine solution from the co-current flue gas-lean solution section 14 to the counter-current flue gas-liquid phase section 16 of an acid gas absorber 10 and discharging the treated flue gas from the co-current flue gas-lean solution section.

(23) Each of the following terms written in singular grammatical form: “a”, “an”, and the”, as used herein, means “at least one”, or “one or more”. Use of the phrase One or more” herein does not alter this intended meaning of “a”, “an”, or “the”. Accordingly, the terms “a”, “an”, and “the”, as used herein, may also refer to, and encompass, a plurality of the stated entity or object, unless otherwise specifically defined or stated herein, or, unless the context clearly dictates otherwise. For example, the phrases: “a unit”, “a device”, “an assembly”, “a mechanism”, “a component, “an element”, and “a step or procedure”, as used herein, may also refer to, and encompass, a plurality of units, a plurality of devices, a plurality of assemblies, a plurality of mechanisms, a plurality of components, a plurality of elements, and, a plurality of steps or procedures, respectively.

(24) Each of the following terms: “includes”, “including”, “has”, “having”, “comprises”, and “comprising”, and, their linguistic/grammatical variants, derivatives, or/and conjugates, as used herein, means “including, but not limited to”, and is to be taken as specifying the stated component(s), feature(s), characteristic(s), parameter(s), integer(s), or step(s), and does not preclude addition of one or more additional component(s), feature(s), characteristic(s), parameter(s), integer(s), step(s), or groups thereof.

(25) The term “method”, as used herein, refers to steps, procedures, manners, means, or/and techniques, for accomplishing a given task including, but not limited to, those steps, procedures, manners, means, or/and techniques, either known to, or readily developed from known steps, procedures, manners, means, or/and techniques, by practitioners in the relevant field(s) of the disclosed invention.

(26) Terms of approximation, such as the terms about, substantially, approximately, etc., as used herein, refers to ±10% of the stated numerical value. Use of the terms parallel or perpendicular are meant to mean approximately meeting this condition, unless otherwise specified.

(27) It is to be fully understood that certain aspects, characteristics, and features, of the acid gas absorber and method, which are, for clarity, illustratively described and presented in the context or format of a plurality of separate embodiments, may also be illustratively described and presented in any suitable combination or sub-combination in the context or format of a single embodiment. Conversely, various aspects, characteristics, and features, of the acid gas absorber and method which are illustratively described and presented in combination or sub-combination in the context or format of a single embodiment may also be illustratively described and presented in the context or format of a plurality of separate embodiments.

(28) Although the acid gas absorber and method have been illustratively described and presented by way of specific exemplary embodiments, and examples thereof, it is evident that many alternatives, modifications, or/and variations, thereof, will be apparent to those skilled in the art. Accordingly, it is intended that all such alternatives, modifications, or/and variations, fall within the spirit of, and are encompassed by, the broad scope of the appended claims.