REDETACHABLE SELF-ADHESIVE PRODUCTS

Abstract

Self-adhesive product redetachable by extensive stretching comprises a pressure-sensitive adhesive comprising: a) an elastomer component, where i. the elastomer component comprises a hydrogenated polyvinylaromatic-polydiene block copolymer described herein, ii. the polydiene blocks are substantially fully hydrogenated, iii. the hydrogenated polyvinylaromatic-polydiene block copolymer has a construction described herein, and iv. the elastomer component comprises a hydrogenated diblock copolymer having a construction described herein, b) a tackifying resin component, c) optionally a plasticizer, d) optionally further adjuvants, and also at least one ply of a temporary carrier material.

Claims

1. Self-adhesive product redetachable by extensive stretching and comprising at least one layer of a pressure-sensitive adhesive comprising: a) at least 28 wt % and at most 58 wt % of an elastomer component, where i. the elastomer component comprises at least 60 wt % and optionally at most 90 wt %, based in each case on the elastomer component, of a hydrogenated polyvinylaromatic-polydiene block copolymer having a polyvinylaromatic fraction of at least 18 wt % and a peak molecular weight of 100 000 to 500 000 g/mol, determined by GPC (Test I), ii. the polydiene blocks are substantially fully hydrogenated, iii. the hydrogenated polyvinylaromatic-polydiene block copolymer has an ABA construction, (AB).sub.nZ construction with n=2 or radial (AB).sub.n construction or radial (AB).sub.n-Z construction with n≥3, where A=polyvinylaromatic, B=ethylene and butylene or ethylene and propylene, and Z=derivative of a coupling substance, and where the ethylene fraction in the B blocks is optionally at least 50 wt %, and iv. the elastomer component comprises up to 35 wt %, based on the elastomer component, of at least one kind of a hydrogenated diblock copolymer having an A′B′ construction or (A′B′).sub.nZ construction with n=1, where A′=polyvinylaromatic, B′=ethylene and butylene or ethylene and propylene, Z=derivative of a coupling substance, and A′ may=A and/or B′ may=B, b) a tackifying resin component, c) optionally a plasticizer component, d) optionally further adjuvants, where the fraction of the elastomer component is based on the total weight of the pressure-sensitive adhesive and also at least one ply of a temporary carrier material (“release liner”).

2. Self-adhesive product redetachable by extensive stretching according to claim 1, wherein the plasticizer component is present at not less than 2 wt % and not more than 30 wt %.

3. Self-adhesive product redetachable by extensive stretching according to claim 1, wherein the self-adhesive product comprises not only the at least one ply of a temporary carrier material (“release liner”) but also at least one ply of an extensible permanent carrier material.

4. Self-adhesive product redetachable by extensive stretching according to claim 1, wherein the fraction of elastomer component in the layer of the pressure-sensitive adhesive is 35 wt % to 55 wt %, based on the total weight of the pressure-sensitive adhesive.

5. Self-adhesive product redetachable by extensive stretching according to claim 1, wherein the polyvinylaromatic-polydiene block copolymers have a polyvinylaromatic fraction of 18 wt % to 35 wt %.

6. Self-adhesive product redetachable by extensive stretching according to claim 1, wherein the elastomer component, in addition to a hydrogenated polyvinylaromatic-polydiene block copolymer having a linear or radial construction, comprises a polyvinylaromatic-polydiene diblock copolymer AB, where with further preference A′=A and B′=B and the polydiene blocks are substantially fully hydrogenated.

7. Self-adhesive product redetachable by extensive stretching according to claim 6, wherein the elastomer component comprises at least one diblock copolymer having a peak molecular weight, determined by GPC, of <100 000 g/mol and its fraction based on the elastomer component is at most 35 wt %.

8. Self-adhesive product redetachable by extensive stretching according to claim 1, wherein the fraction of tackifying resin component is 28 to 55 wt %, based on the total weight of the pressure-sensitive adhesive.

9. Self-adhesive product redetachable by extensive stretching according to claim 1, wherein the tackifying resin component comprises partially or completely hydrogenated resin based on dicyclopentadiene, partially or completely hydrogenated hydrocarbon resins based on C.sub.5, C.sub.5/C.sub.9 or C.sub.9 monomer streams, polyterpene resins based on α-pinene and/or β-pinene and δ-limonene, or a hydrogenated polymer of pure C.sub.8 or C.sub.9 aromatics, the resin being partially or completely hydrogenated.

10. Self-adhesive product redetachable by extensive stretching according to claim 1, wherein the fraction of plasticizer in the pressure-sensitive adhesive is not more than 30 wt %, based on the total weight of the pressure-sensitive adhesive.

11. Self-adhesive product redetachable by extensive stretching according to claim 1, wherein the plasticizer is selected from the group consisting of ethylene/propylene copolymer, ethylene/butylene copolymer, and butylene/isobutylene (co)polymer.

12. Self-adhesive product redetachable by extensive stretching according to claim 11, wherein the plasticizer has a weight-average molar mass of at least 100 000 g/mol and at most 1 000 000 g/mol and is an ethylene/propylene copolymer or ethylene/butylene copolymer with linear or radial structure.

13. Self-adhesive product redetachable by extensive stretching according to claim 11, wherein the plasticizer has a weight-average molar mass of at least 3000 g/mol and at most 20 000 g/mol and is a butylene/isobutylene (co)polymer.

14. Self-adhesive product redetachable by extensive stretching according to claim 1, wherein said extensible permanent carrier material used comprises extensive films composed of polyolefins, of polyurethanes, of polyester polyurethanes, of polyether polyurethanes, of polycaprolactone polyurethanes, or of rubber-based materials.

15. Self-adhesive product redetachable by extensive stretching according to claim 1, wherein the self-adhesive product is a single-layer, double-sidedly self-adhesive tape, consisting of a single layer of the pressure-sensitive adhesive in combination with a temporary carrier material, or a multi-layer, double-sidedly self-adhesive tape, in which the layers each consist of the pressure-sensitive adhesive in combination with a temporary carrier material, or a multi-layer, double-sidedly self-adhesive tape having a permanent carrier which is arranged either in a layer of the pressure-sensitive adhesive or between two layers of the pressure-sensitive adhesive, in each case in combination with a temporary carrier material.

16. Self-adhesive product redetachable by extensive stretching according to claim 15, wherein the self-adhesive product consists of a single-layer permanent carrier (intermediate carrier), optionally containing polyolefin, the carrier having an elongation at break of at least 100%, and optionally a resilience of less than 50% (Test X), where a layer of the pressure-sensitive adhesive is applied on each of the two sides of the carrier, the adhesive being based optionally on hydrogenated vinylaromatic block copolymers and tackifying resins, where optionally the composition of the adhesives is identical.

17. Self-adhesive product redetachable by extensive stretching according to claim 1, wherein the self-adhesive product consists of a single-layer permanent carrier, optionally composed of polyurethane, the carrier having an elongation at break of at least 100%, optionally at least 300%, and optionally a resilience of more than 50% (Test X), where a layer of the pressure-sensitive adhesive is applied on each of the two sides of the carrier, where optionally the composition of the adhesives is identical.

18. Substrate comprising ethylene (co)polymer, propylene (co)polymer, EPR, EPM and/or EPDM, bearing an applied self-adhesive product according to claim 1.

19. A method of bonding a substrate comprising applying a self-adhesive product according to claim 1 to the substrate.

Description

EXAMPLES (“I” AS PER INVENTION; “C” COMPARATIVE)

[0153] (i) Multi-Layer, Carrier-Containing Product Constructions

TABLE-US-00004 I1.1 I1.2 I1.3 I1.4 I1.5 I1.6 Kraton G1651 Kraton 40.0% 40.0% 40.0% 40.0% 30.0% G1654 Kraton 10.0% 15.0% 10.0% 15.0% G1726 Kraton 30.0% G1633 Regalite 40.0% 40.0% R1125 Eastotac 45.0% 43.0% 43.0% H100W Dercolyte 40.0% A115 Regalite R1010 Ter Pib 2600 5.0% 10.0% 5.0% 27.0% 27.0% Kraton 5.0% G1750 Figures in % are each wt %

TABLE-US-00005 Tearing rate 10% 0% 18% 0% 0% 20% Manual (PC/PC)* SAFT (200 171.5° C. 177.5° C. 127.3° C. 203.0° C. 137.0° C. 117.0° C. g)** Peel 5.5 N/cm 6.9 N/cm 7.6 N/cm 5.5 N/cm 4.0 N/cm 8.9 N/cm adhesion, steel, fresh** Peel 3.6 N/cm 3.8 N/cm 6.7 N/cm 4.8 N/cm 8.1 N/cm 7.2 N/cm adhesion, PP/EPR** *2 × 50 μm on 30 μm polyester polyurethane film **50 μm on 36 μm polyester film

TABLE-US-00006 C2.1 C2.2 C2.3 C2.4 C2.5 C2.6 Kraton 28.0% 29.2% 28.0% 50% G1657 Kraton 12.0% 12.5% 12.0% 50% G1650 Septon 2063 50% Regalite 26.0% 50.0% 26.0% 50% 50% R1100 Regalite 50% R1090 Regalite 34.0% 8.3% R1010 Pionier 34.0% 2070P Figures in % are each wt %

TABLE-US-00007 Tearing rate 95% 100% 100% 67.5% Not 60% Manual determined (PC/PC)* SAFT (200 94° C. 106° C. 80° C. 91° C. 96° C. 160° C. g)** Peel 5.1 N/cm 7.1 N/cm 0.3 N/cm 6.2 N/cm 11.4 N/cm 6.7 N/cm adhesion, steel** Peel 4.2 N/cm 1.5 N/cm 0.4 N/cm 3.9 N/m 9.7 N/cm 3.7 N/cm adhesion, PP/EPR** *2 × 50 μm on 30 μm polyester polyurethane film **50 μm on 36 μm polyester film

TABLE-US-00008 I3.1 I3.2 C3.3 C3.4 I3.5 Kraton G1652 40% Kraton G1650 40% Kraton G1654 40% 55% Kraton G1651 40% Kraton G1726 10% 10% 10% 10% Regalite R1100 45% 45% 45% 45% 40% Kraton G1750  5%  5%  5%  5%  5% Figures in % are each wt %

TABLE-US-00009 Tearing rate Manual (PC/PC)* 0% 20% 0% 0% 20% SAFT (200 g)** 192° C. 203° C. 110° C. 131° C. 180° C. Peel adhesion, 6.3 N/cm 5.7 N/cm 2.2 N/cm 2.5 N/cm 5.1 N/cm steel** Peel adhesion, 2.2 N/cm 3.7 N/cm 0.1 N/cm 1.3 N/cm 2.9 N/cm PP/EPR** *2 × 50 μm on 30 μm polyester polyurethane film **50 μm on 36 μm polyester film

TABLE-US-00010 I4.1 I4.2 I4.3 C4.4 I4.5 Kraton G1654 40% 40% 40% 40% Kraton G1651 20% Kraton G1726 10% 10% 10% 10% Regalite R1100 30% 35% 50% 35% Foral 105-E 10% Eastotac H100W 42% TerPib 2600 20% 15% 38%  5% Figures in % are each wt %

TABLE-US-00011 Tearing rate Manual (PC/PC)* 20% 0% 10% 33% 10% SAFT 200 g)** 180° C. 125° C. 191° C. 112° C. 179° C. Peel adhesion, 6.2 N/cm 5.1 N/cm 7.9 N/cm 14.2 N/cm 6.4 N/cm steel** Peel adhesion, 5.6 N/cm 3.3 N/cm 5.6 N/cm 9.4 N/cm 5.8 N/cm PP/EPR** *2 × 50 μm on 30 μm polyester polyurethane film **50 μm on 36 μm polyester film

TABLE-US-00012 I5.1 I5.2 I5.3 I5.4 I5.5 Kraton G1654 40% 40% 40% 40% 40% Kraton G1726 10% 10% 10% 10% 10% Regalite R1100 45% 45% 45% 45% 35% Foral 105-E 10% Oppanol B10  5% TerPib 950  5% TerPib 1300  5% Indopol H6000  5% Foralyn 5020  5% Figures in % are each wt %

TABLE-US-00013 Tearing rate Manual (PC/PC)* 10% 20% 0% 20% 20% SAFT (200 g)** 171° C. 124° C. 198° C. 172° C. 177° C. Peel adhesion, 4.8 N/cm 5.5 N/cm 4.9 N/cm 5.4 N/cm 6.6 N/cm steel** Peel adhesion, 2.7 N/cm 5.0 N/cm 3.8 N/cm 3.8 N/cm 5.5 N/cm PP/EPR** *2 × 50 μm on 30 μm polyester polyurethane film **50 μm on 36 μm polyester film

TABLE-US-00014 C6.1 C6.2 C6.3 C6.4 Kraton G1654 30% 20% 45% Kraton G1726 20%  5% 15% Kraton G1642 30% Regalite R1100 45% 45% 35% Regalite R1090 40% Kraton G1750  5% Terpib 2600 30%  5% Oppanol B10 30% Figures in % are each wt %

TABLE-US-00015 Tearing rate Manual (PC/PC)* 100% 100% SAFT (200 g)** 83° C. Peel adhesion, 1.4 N/cm steel** Peel adhesion, 4.3 N/cm PP/EPR** *2 × 50 μm on 30 μm polyester polyurethane film **50 μm on 36 μm polyester film

TABLE-US-00016 I7.1 I7.2 I7.3 I7.4 Kraton G1654 40% 37% 35% .sup. 35% Kraton G1726 15% 15% 15% .sup. 15% Regalite R1100 40% 43% 45% 31.5% Regalite R1125 13.5% TerPib 2600  5%  5%  5%   5% Layer thickness 530 μm 1080 μm 510 μm 500 μm Figures in % are each wt %

TABLE-US-00017 Tearing rate Manual (PC/PC) 0% 0% 0% 0% SAFT (200 g) 162° C. 157° C. 138° C. 165° C. Peel adhesion, 14.4 N/cm 23.8 N/cm 18.3 N/cm 24.3 N/cm steel* Peel adhesion, 12.7 N/cm 19.8 N/cm 14.5 N/cm 16.5 N/cm ABS* *on 75 μm polyester film