Methods for preparation of sheets to be used for fabrication of a welded steel blank and fabricating a welded blank
11826856 · 2023-11-28
Assignee
Inventors
- Francis Schmit (Clermont, FR)
- Rene Vierstraete (Maisons-Laffitte, FR)
- Qingdong Yin (Montataire, FR)
- Wolfram Ehling (Ghent, BE)
Cpc classification
B23K26/348
PERFORMING OPERATIONS; TRANSPORTING
B23K26/211
PERFORMING OPERATIONS; TRANSPORTING
B23K2103/08
PERFORMING OPERATIONS; TRANSPORTING
B23K26/361
PERFORMING OPERATIONS; TRANSPORTING
B23K9/167
PERFORMING OPERATIONS; TRANSPORTING
B23K26/40
PERFORMING OPERATIONS; TRANSPORTING
B23K2101/34
PERFORMING OPERATIONS; TRANSPORTING
B23K28/02
PERFORMING OPERATIONS; TRANSPORTING
B23K26/32
PERFORMING OPERATIONS; TRANSPORTING
B23K2103/50
PERFORMING OPERATIONS; TRANSPORTING
International classification
B23K26/211
PERFORMING OPERATIONS; TRANSPORTING
B23K26/32
PERFORMING OPERATIONS; TRANSPORTING
B23K26/348
PERFORMING OPERATIONS; TRANSPORTING
B23K26/361
PERFORMING OPERATIONS; TRANSPORTING
B23K26/40
PERFORMING OPERATIONS; TRANSPORTING
B23K28/02
PERFORMING OPERATIONS; TRANSPORTING
B23K9/167
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A method for the preparation of steel sheets for fabricating a welded steel blank is provided. The method includes a step of removing at least part of the first and second metal alloy layers in first and second peripheral zones of pre-coated steel first and second sheets, respectively, by simultaneously ablating the first and second precoatings in the first and second peripheral zones of the pre-coated steel first and second sheets to define first and second ablation zones, the first and second peripheral zones being zones of the first and second principal faces closest to the median plane and located on either side of the median plane.
Claims
1. A method for preparation of sheets to be used for fabrication of a welded steel blank, the method comprising the steps of: providing a pre-coated steel first sheet and a pre-coated steel second sheet, the pre-coated steel first sheet comprising a first steel substrate and a first precoating including a first metal alloy layer and a first intermetallic layer in contact with the first steel substrate, the first intermetallic layer topped by the first metal alloy layer, the pre-coated steel first sheet defining a first principal face, a first opposite principal face and a first secondary face, the pre-coated steel second sheet comprising a second steel substrate and a second precoating including a second metal alloy layer and a second intermetallic layer in contact with the second steel substrate, the second intermetallic layer topped by the second metal alloy layer, the pre-coated steel second sheet defining a second principal face, a second opposite principal face and a second secondary face; positioning the pre-coated steel first and second sheets to define a median plane perpendicular to the first and second principal faces; and removing at least part of the first and second metal alloy layers in first and second peripheral zones of the pre-coated steel first and second sheets, respectively, by simultaneously ablating the first and second precoatings in the first and second peripheral zones of the pre-coated steel first and second sheets to define first and second ablation zones, the first and second peripheral zones being zones of the first and second principal faces closest to the median plane and located on either side of the median plane; and removing at least part of the first and second metal alloy layers in opposite first and second peripheral zones of the pre-coated steel first and second sheets, respectively, by simultaneously ablating the first and second precoatings in the opposite first and second peripheral zones of the pre-coated steel first and second sheets to define opposite first and second ablation zones, the opposite first and second peripheral zones being zones of the first and second opposite principal faces closest to the median plane, the removing of the at least part of the first and second metal alloy layers in the opposite first and second peripheral zones occurring simultaneously with the removing of the at least part of the first and second metal alloy layers in the first and second peripheral zones.
2. The method as recited in claim 1 wherein after the removing steps the first and second secondary faces include no aluminum from the first and second metal alloy layers, the first and second secondary faces facing the median plane.
3. The method as recited in claim 1 wherein a width of the first ablation zone and a width of the second ablation zone is each between 0.25 and 3 mm.
4. The method as recited in claim 3 wherein the width of the first ablation zone is identical to the width of the second ablation zone.
5. The method as recited in claim 4 wherein the width of the first ablation zone is different from the width of the second ablation zone.
6. The method as recited in claim 1 wherein a total ablation width of the first ablation zone and the second ablation zone varies by less than 10%.
7. The method as recited in claim 1 wherein an average total width of the first ablation zone and the second ablation zone is 1.92 mm.
8. The method as recited in claim 1 wherein the removing steps are carried out by using the median plane as a single reference plane.
9. The method as recited in claim 1, wherein no mechanical bond is formed between the pre-coated steel first and second sheets.
10. The method as recited in claim 1 wherein the removing steps are carried out by a laser beam spanning the median plane.
11. The method as recited in claim 1 wherein the first metal layer and the second metal layer each comprises aluminum metal or an aluminum-based alloy.
12. A method for fabricating a welded blank using the method as recited in claim 1, further comprising: welding the pre-coated steel first and second sheets at the median plane.
13. The method as recited in claim 12 wherein the pre-coated steel first and second sheets are welded by laser beam welding.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) Other characteristics and advantages of the invention will become apparent from the following description, which is presented by way of example and refers to the accompanying figures listed below, in which:
(2)
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DETAILED DESCRIPTION
(9) It will be noted that the diagrams do not attempt to reproduce the relative dimensions of the different elements among one another, but are intended merely to facilitate the description of the different constituent parts of the invention.
(10) In the methods of the prior art, where the removal of the metallic alloy layer is the result of melting, more or less significant quantities of aluminum that flow over the secondary face are present. This situation is illustrated in
(11) The inventors have shown that this phenomenon of flow along the secondary face can be prevented by the following method. As illustrated in
(12) These sheets are made up of a steel substrate 25 and 26, which can be in particular in the form of a hot-rolled sheet or cold-rolled sheet, depending on the desired thickness. The composition of the substrates can be identical or different, depending on the desired distribution of the mechanical characteristics over the final part. These steels are heat-treatable steels, which are capable of undergoing a martensitic or bainitic quenching after an austenitization treatment. The thickness of the sheets is preferably between approximately 0.5 and 4 mm, the thickness range used in particular in the fabrication of structural or reinforcement parts for the automobile industry.
(13) The sheets 11 and 12 respectively include principal faces 111, 112 and 121, 122. On the surface of each of these faces, there is a pre-coating 15 and 16, the thickness and composition of which can be identical or different in the sheets 1 and 2. These pre-coatings 15 and 16 are both obtained by dipping in an aluminizing bath.
(14) The pre-coating 15 is itself composed:
(15) of a layer of inter-metallic alloy 17 in contact with the substrate 25. This is an alloy layer of the type Fe.sub.xAl.sub.y formed by reaction between the substrate 25 and the molten metal of the aluminizing bath during the continuous passage of the sheets through the aluminizing bath. This layer typically has a thickness of 3 to 10 μm. The aluminizing bath is a bath of aluminum or aluminum alloy in which aluminum is present in a percentage by weight greater than 50%, or an aluminum-based alloy. In this latter case, the aluminum is the main component of the alloy.
(16) of a metallic alloy layer 19, the composition of which is practically the same as that of the bath of aluminum, aluminum alloy or aluminum-based alloy.
(17) Likewise, in the sheet 12, the pre-coating 16 is constituted by an intermetallic alloy layer in contact with the substrate 26 and a surface metallic layer.
(18) Preferably, the metallic alloy 19, 20 of the pre-coating can contain from 8 to 11 by weight silicon and from 2 to 4% iron, the balance of the composition made up of aluminum and unavoidable impurities. The addition of silicon makes it possible in particular to reduce the thickness of the intermetallic layer 17.
(19) The two sheets 11 and 12 can be positioned so that their principal faces 111 and 112 are in the same plane 41. In this manner, a laser beam placed simultaneously over these two sheets will interact with them identically. However, the two sheets 11 and 12 can also be positioned not exactly in the same plane, i.e. the focal point of the laser beam is not positioned exactly on the same level in relation to the surface of the two sheets with an identical pre-coating. This situation can be encountered, for example, in the case of a difference of thickness between the two sheets 11 and 12. Even in this case, the inventors have verified that the desired results, in particular the absence of a flow of the pre-coating along the secondary faces, are obtained when the method is according to the invention is used.
(20) The two sheets 11 and 12 are positioned to place with their secondary faces 71 and 72 end to end. This positioning therefore defines a median plane 51 between the sheets 11 and 12, perpendicular to their principal faces, and a gap 31 between the sheets.
(21) According to the invention, the respective metallic alloy layers 19 and 29 are then removed simultaneously, by a method including a melting and a vaporization, over a peripheral portion 61 of the sheet 11 and a peripheral portion 62 of the sheet 12. As a general rule, the majority of this removal is due to a melting phenomenon. This rules out methods where the layers 19 and 20 are removed purely by vaporization. This removal, which is also called an ablation, is preferably carried out by a pulsed laser beam. The impact of the high power and high energy density laser on the pre-coating causes a liquefaction and vaporization of the surface of the latter. On account of the plasma pressure, the liquefied pre-coating is expelled toward the periphery of the zone where the ablation is taking place. A succession of short laser pulses with appropriate parameters results in an ablation of the metallic layer 19 and 20, leaving the intermetallic alloy layer 17 and 18 in place. However, depending on the degree of corrosion resistance desired on the finished part, it is also possible to remove a more or less large portion of the intermetallic layer 17 and 18, for example more than 50% of this layer. The interaction of a pulsed laser beam directed toward the periphery 61 and 62 of pre-coated sheets, in relative translation with reference to these sheets, therefore results in a removal of the metallic layer 19 and 20.
(22) The ablation is carried out simultaneously on the sheets 11 and 12, i.e. the means of melting and vaporization are applied simultaneously to the peripheral zones 61 and 62 facing each other. In particular, when the ablation is carried out using a laser beam, the laser beam impacts zones 61 and 62, spanning the median plane 51. In one preferred mode, a pulsed laser beam with a rectangular shape is used. A smaller laser beam can also be used, which is made to oscillate so that it covers the width to be processed. The method can also be carried out using a principal beam divided into two rectangular sub-beams, each spanning the median plane 51. These two sub-beams can be positioned symmetrically with reference to the plane 51, or can be longitudinally offset in relation to each other in the direction of welding. These two sub-beams can be of identical or different sizes.
(23) In these different simultaneous ablation modes, it would then be expected that the aluminum resulting from the melting due to the impact of the laser beam would flow over the secondary phases 71 and 72 under the influence of gravity and the plasma pressure generated by the beam.
(24) Surprisingly, the inventors have shown that the secondary faces 71 and 72 do not experience a flow of aluminum when the gap 31 is between 0.02 and 2 mm. Without being bound by a theory, it is thought that the secondary faces 71 and 72 are covered by a very thin layer of iron and/or aluminum oxide originating from the cutting of the sheets 11 and 12. Taking into consideration the interfacial tension between this thin layer of oxides and liquid aluminum on one hand and the specific gap 31 on the other, the surface free of liquid aluminum between the sheets 11 and 12 bends to form a wetting angle, without the liquid flowing into the space 31. A minimal gap of 0.02 mm makes it possible for the beam to pass between the sheets 11 and 12, removing potential traces of aluminum that may have been on the secondary face. Moreover, as will be explained below, in one variant of the method, the welding is carried out immediately after this ablation operation.
(25) The gap 31 is advantageously greater than 0.04 mm, which makes it possible to use mechanical cutting methods, the tolerance of which does not have to be controlled with extreme precision, which in turn makes it possible to reduce the costs of production.
(26) In addition, as explained above, the guidance of the welding laser beam is more difficult in the case of sheets from which the coating has been removed on the periphery on account of their darker appearance. The inventors have shown that a width of the gap 31 greater than 0.06 mm makes it possible to increase significantly the optical contrast of the joint plane, which appears differentiated in relation to the peripheral ablation zones, and therefore ensures that the weld is properly positioned with respect to the median plane 51.
(27) In addition, the inventors have found that when the gap 31 is greater than 2 mm, the mechanism explained above is no longer operative to prevent the flow of liquid aluminum, as the experimental results illustrated in
(28) The gap can advantageously be between 0.02 and 0.2 mm.
(29) For the ablation process, a Q-switched type laser with a nominal power of several hundred watts can advantageously be used, which delivers pulses of a duration on the order of 1/50 of a nanosecond with a maximum power of 1-20 megawatts. This type of laser makes it possible, for example, to obtain an impact zone of the rectangular beam of 2 mm (in a direction perpendicular to the median plane 51) and 1 mm, or less than 1 mm (for example 0.5 mm) in the direction of the length of this median plane. The displacement of the beam then makes it possible to create ablation zones 61 and 62 on either side of the plane 51 without the occurrence of a flow along the faces 71 and 72.
(30) The morphology of the ablation zones 61 and 62 will naturally be adapted to the welding conditions that follow, in particular to the width of the welded zone. It is thus possible, depending on the nature and the power of the welding process that will follow, for the width of each of the ablation zones 61 and 62 to be between 0.25 and 2.5 mm or, for example, in the case of hybrid laser arc or plasma welding, between 0.25 and 3 mm. The ablation conditions will be selected so that the sum of the widths of the ablation zones 61 and 62 is greater than the width of the welded zone.
(31) If the sheets 11 and 12 are identical, it is possible to specify that the widths of the ablation zones 61 and 62 are also identical. But it is also possible to specify, for example using a horizontal shift of the laser beam in the lateral direction with reference to the median plane 51, for the widths of these ablation zones to be different.
(32) According to the invention, the ablation can be carried out only one side of the principal faces.
(33) However, to minimize, as far as possible, the introduction of aluminum during welding to be carried out on the sheets, it is also possible to preferably carry out this simultaneous peripheral ablation on all of the faces, i.e. 111, 121, 112, 122. For this purpose, in the case of an ablation by laser welding, a device of the “power switch” type can be advantageously used, which divides the power of the beam, one part being used for the simultaneous ablation of the phases 111 and 121, and the other part for the simultaneous ablation of the faces 112 a 122. It is also possible to use a second laser which is separate from the first.
(34) After this simultaneous ablation operation, there will be two sheets, from the periphery of which the metallic alloy layer has been removed, that are suitable for welding. This welding can be done later and the sheets can be either kept facing each other or separated. They can be separated easily because the method according to the invention makes it possible to limit the flow of liquid aluminum between the sheets so that a solidified flow does not create any undesirable mechanical bond.
(35) But the inventors have also discovered that an in-line welding operation can be advantageously carried out on the sheets prepared in the manner described above. On account of the absence of a flow of aluminum over the secondary face, the prepared sheets can be welded immediately without the need to remove the sheets from the line and then reposition them after cleaning. The interval of time that elapses between the simultaneous ablation operation and the welding operation is less than one minute, which minimizes oxidation on the faces 71 and 72 and achieves higher productivity. In addition, when this interval of time is short, the welding is done on the sheets that have been preheated by the ablation operation so that the quantity of energy to be applied for the welding can be reduced.
(36) It is also possible to use any continuous welding method appropriate to the thicknesses and productivity and quality conditions required for the welded joints, and in particular: laser beam welding; electric arc welding, in particular using the TIG (“Tungsten Inert Gas”), plasma, MIG (“Metal Inert Gas”) or MAG (“Metal Active Gas”) methods; electron beam welding.
(37) Laser welding is one method that can be used advantageously on account of the high energy density inherent to this method, which makes it possible to obtain a narrow molten zone which varies within small proportions. This method can be used by itself or in combination with a filler rod 82, as illustrated in
(38) According to one variant of the invention, the devices that carry out the simultaneous ablation and welding operations are combined into a single piece of equipment. This equipment is driven at a single rate of relative displacement with reference to the sheets. In this equipment, the rate of simultaneous ablation is identical to the welding speed, which makes it possible to conduct fabrication under optimal conditions of productivity and efficiency.
(39)
(40) At a certain distance 64 from this first ablation zone, a laser beam 95 carries out the welding of the sheets 11 and 12 to create a welded zone 63. The distance between the ablation and welding devices is kept constant using a device, which is itself known and is represented schematically as 96. The sheets 11 and 12 are displaced with reference to this assembly 96 along to the path indicated by 97.
(41) The sheets 11 and 12 are advantageously clamped using a clamping device, which is not shown in
(42) The maximum distance between the points of impact of the beams 80, 81 on one hand and 95 on the other hand depends in particular on the welding speed. As described above, the welding speed will be determined in particular so that the time that elapses between the impacts of the beams (80, 81) and 95 is less than one minute. This maximum distance can be preferably less than 2 m so that the equipment is particularly compact.
(43) The minimum distance 64 between these points of impact can be reduced to 0.5 mm. A distance smaller than 0.5 mm would result in an undesirable interaction between the ablation beams 80, 81 on one hand and the “keyhole” which is inherently present during welding by the beam 95 on the other hand.
(44) A short distance 64 can also be obtained by combining the two ablation and welding heads (the heads being defined as the devices from which the laser beams are emitted) into a single more compact head, whereby the latter can use, for example, the same focusing element for the ablation and welding operation.
(45) A very small distance 64 makes it possible to implement the method using a particularly compact unit and to proceed so that a certain quantity of the thermal energy delivered by the laser beams 80 and 81 is added to the linear welding energy delivered by the beam 95, thereby increasing the total energy efficiency of the method. A very small distance makes it possible to shorten the cycle time necessary for the unit production of a welded blank, and thus to increase productivity. These effects are obtained in particular when the distance 64 is less than 600 mm or even less than 5 mm.
(46)
(47) Optionally, a second laser beam, of a type similar to 95, can be applied in the lower portion, i.e. on the opposite face. This arrangement makes it possible to increase the welding speed and/or to reduce the unit power of the source 95.
(48) This beam 95 can be guided either by its own guidance device which is separate from 94 (case not illustrated in
(49) Optionally, the assembly can include a filler rod device 82 to modify the composition of the molten zone thanks to a composition of the filler rod that is different from the compositions of the sheets 25 and 26.
(50) The sheets 11 and 12 are moved from the station A toward the station D to obtain a relative displacement of the sheets with reference to the laser beams 80 and 95, the latter being positioned on the same line with reference to the median plane 51, and at a fixed distance 64 from each other.
(51) As noted above, this distance 64 is preferably between 0.5 mm and 2 m, preferably between 0.5 mm and 600 mm, or between 0.5 mm and 5 mm.
(52) The welded blank obtained by the method according to the invention has the following specific characteristics: as illustrated in
(53) In summary,
(54) In the case of the conventional method (
(55) In the case of the method according to the invention (
(56) It is therefore apparent that the welded joints constructed according to the conventional method and according to the invention differ in terms of the morphological characteristics in the solidification zones in immediate proximity to the molten metal created by welding.
(57) By way of non-limiting examples, the following embodiments illustrate the advantages achieved by the invention.
Example
(58) Steel sheets 1.2 mm thick having the following composition by weight: 0.23% C, 1.19% Mn, 0.014% P, 0.001% S, 0.27% Si, 0.028% Al, 0.034% Ti, 0.003% B and 0.18% Cr, with the balance made up of iron and impurities resulting from processing, are procured. These blanks include a pre-coating 30 μm thick on each face. This pre-coating is made up of an intermetallic layer 5 μm thick in contact with the steel substrate containing 50% by weight aluminum, 40% by weight iron and 10% by weight silicon. This intermetallic alloy layer results from the reaction between the steel substrate and the aluminum alloy bath.
(59) The intermetallic layer is topped by a metallic layer 25 μm thick, containing, by weight, 9% silicon, 3% iron and the balance made up of aluminum and unavoidable impurities.
(60) The dimensions of these sheets are 400 mm×800 mm. The welding is to be carried out on the edges 400 mm long.
(61) Two of these sheets are positioned so that the gap between their facing edges is 0.1 mm. The metallic layer on the periphery of these sheets is then removed using a pulsed laser with an average power of 800 W.
(62) This ablation is carried out simultaneously by two beams on each of the opposite faces of the sheet. The sheets are placed in motion with reference to the beam at a constant speed V=6 m/min. Each of the beams is focused to obtain a rectangular focal spot 2 mm×0.5 mm, the distance of 2 mm extending in the transverse direction with reference to the median plane of the two sheets. In this manner, two sheets are created simultaneously, from the periphery of which the metallic layer is removed over a width of practically 1 mm on each of the sheets. This ablation operation is guided by a sensor that detects the position of the median plane between the two sheets, located immediately upstream with reference to the two pulsed ablation laser beams, in a position identified as x.sub.0. The sensor is located at a distance d.sub.1 approximately 100 mm from the ablation beams. At the level of the sensor, the coordinates (x.sub.0, y.sub.0) of the position of the median plane are recorded at an instant t.sub.0 by computerized means. As the sheets move at a speed v, this plane position reaches the level of the pulsed ablation beams at an instant
(63)
Thanks to a guidance device of the laser beams, the exact position of the impact of the laser beams on the sheets that occurs at the instant ti is adapted so that it corresponds exactly to the ablation zone defined on the basis of the position of the median plane.
(64) After ablation, a laser beam located at a fixed distance d.sub.2 of 200 mm from the pulsed laser beams makes it possible to create a welded joint between these sheets. The welding is carried out with a linear power of 0.6 kJ/cm, under the protection of helium, to prevent decarburization, oxidation and hydrogen absorption phenomena. The length of time that elapses between the ablation operation and the welding is 2 seconds.
(65) The welding laser beam is guided here again using the sensor located upstream of the ablation operation. The position of the median plane recorded at the instant to arrives at the level of the welding laser beam at the instant
(66)
The precise position of the impact of the welding laser beam is then adjusted using the optical guidance device of the laser beam, so that it is centered on the position of the previously defined median plane.
(67)
(68)
(69) In addition, a Castaing microprobe was used to analyze the aluminum content of the welded zone thus created. The aluminum content remains below 0.3%, which clearly indicates that the quantity of aluminum on the secondary faces, after the ablation step and before welding, is practically zero.
(70) A welded blank assembled under the conditions of the invention was then heated in a furnace to a temperature of 900° C. and held at this temperature, whereby the total hold time in the furnace was 6 minutes. The heated blank was then hot stamped to form a part, which was held in the stamping press tool to cool the part at a rate greater than the critical martensitic tempering rate of the steel.
(71) It was then found that the welded zone on the hot stamped piece did not contain any brittle Fe—Al intermetallic compounds, and that the hardness of the melted zone was practically identical to that of the base metal.
(72) The invention therefore makes it possible to economically produce structural and safety parts for the automobile industry from aluminized sheets having a welded joint.