ELECTRICAL DEVICE, IN PARTICULAR MICROBATTERY, AND METHOD FOR THE PRODUCTION
20230021960 · 2023-01-26
Assignee
Inventors
Cpc classification
Y02P70/50
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
H01M50/3425
ELECTRICITY
H01M50/172
ELECTRICITY
C03C2204/00
CHEMISTRY; METALLURGY
H01M50/154
ELECTRICITY
Y02E60/10
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
H01M50/188
ELECTRICITY
H01M50/182
ELECTRICITY
Y02E60/13
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
H01M50/14
ELECTRICITY
International classification
H01M50/188
ELECTRICITY
H01M50/172
ELECTRICITY
H01M50/198
ELECTRICITY
Abstract
An electrical device includes: a housing part made of a metal and including a feedthrough therethrough, an opening of the feedthrough, a first region, and a second region, the opening receiving a conductive material or a conductor in a glass material or a glass-ceramic material, wherein: (i) the conductive material has a first coefficient of expansion α.sub.1, the glass material or the glass-ceramic material has a second coefficient of expansion α.sub.2, and the housing part has a third coefficient of expansion α.sub.3, the third coefficient of expansion α.sub.3 being always greater than the second coefficient of expansion α.sub.2; or (ii) the first region including a width W that is substantially perpendicular to the axis of the at least one opening, the width W of the first region being always greater than a thickness D.sub.2 and a thickness D.sub.E of the second region; or (iii) a combination of (i) and (ii).
Claims
1. An electrical device, comprising: a housing part of a housing, the housing part being made of a metal and including a feedthrough therethrough, at least one opening as a part of the feedthrough, a first region, and a second region, the at least one opening extending about an axis, the first region including the at least one opening, the second region being adjacent to the at least one opening, the at least one opening receiving a conductive material or a conductor in a glass material or a glass-ceramic material, wherein: (i) the conductive material has a first coefficient of expansion α.sub.1, the glass material or the glass-ceramic material has a second coefficient of expansion α.sub.2, and the housing part has a third coefficient of expansion α.sub.3, the third coefficient of expansion α.sub.3 being always greater than the second coefficient of expansion α.sub.2; or (ii) the first region including a width W that is substantially perpendicular to the axis of the at least one opening, the width W of the first region being always greater than a thickness D.sub.2 and a thickness D.sub.E of the second region; or (iii) a combination of (i) and (ii).
2. The electrical device according to claim 1, wherein the housing part includes a flange or a flexible flange, the flange or the flexible flange having a free space F between a raised region or a lowered region of the housing part and having a connecting region, wherein the flange or the flexible flange is connected to the housing.
3. The electrical device according to claim 2, wherein the flange or the flexible flange is connected to the housing by way of welding or laser welding or soldering, in such a manner that a connection therebetween is substantially gas-tight and that a helium leakage rate of less than 10−8 mbar l/sec is provided.
4. The electrical device according to claim 2, wherein the flexible flange is produced by reshaping of a sheet material part, wherein the flexible flange has a thickness D.sub.2 of the sheet material part.
5. The electrical device according to claim 2, wherein the flexible flange consists of one of the following materials: a ferritic high grade steel with a coefficient of expansion in a range of 10 to 12.Math.10−K−1; a normal steel with a coefficient of expansion in a range of 12 to 13.Math.10−K−1; a Duplex high grade steel with a coefficient of expansion in a range of 13 to 14.Math.10−K−1; an austenitic high grade steel with a coefficient of expansion in a range of 16 to 18.Math.10−6 K−1.
6. The electrical device according to claim 1, wherein: (i) the thickness D.sub.2 and the thickness D.sub.E are in a range of 0.1 mm to 1 mm or 0.1 mm to 0.6 mm; or (ii) the width W is in a range of 0.6 mm to 1 mm or in a range of 0.7 mm to 0.9 mm; or (iii) a combination of (i) and (ii).
7. The electrical device according to claim 1, wherein at least one of: the third coefficient of expansion α.sub.3 is in a range of 12.Math.10−6 1/K to 19.Math.10−6 1/K; the second coefficient of expansion α.sub.2 is in a range of 9.Math.10−6 1/K to 11.Math.10−6 1/K; and the first coefficient of expansion α.sub.1 is in a range of 6.Math.10−6 1/K to 11.Math.10−6 1/K.
8. The electrical device according to claim 1, wherein at least one of a metal of the housing, the metal of the housing part, and/or a metal of the conductor is iron, an iron alloy, an iron-nickel alloy, an iron-nickel-cobalt alloy, KOVAR, steel, stainless steel, high grade steel, aluminum, an aluminum alloy, AISiC, magnesium, a magnesium alloy, copper, a copper alloy, titanium, or a titanium alloy.
9. The electrical device according to claim 1, wherein the housing part in the first region in a region of the at least one opening comprises a collar, thereby forming an inside wall having a height that is greater than a material thickness or the thickness D.sub.2.
10. The electrical device according to claim 9, wherein the collar is domed or reshaped with at least one of an indentation and a protrusion.
11. The electrical device according to claim 9, wherein a glassing length EL of the glass material or the glass-ceramic material is determined by a height of the collar.
12. The electrical device according to claim 9, wherein the material thickness or the thickness D.sub.2 of the second region is equal to a material thickness or a thickness of at least one of at least a component elected from the collar, an indentation of the collar, and a protrusion of the collar.
13. The electrical device according to claim 1, wherein the electrical device has a total height which is at most 40 mm, at most 20 mm, at most 5 mm, at most 4 mm, at most 3 mm, in a range of 1 mm to 40 mm, in a range of 1 mm to 5 mm, or in a range of 1 mm to 3 mm.
14. The electric device according to claim 1, wherein the housing part includes a flange or a flexible flange, wherein a material of the flange or the flexible flange is selected such that an expulsion force of the conductor is set by glass pre-stresses which act via the glass material upon the conductor.
15. The electrical device according to claim 14, wherein by adjustment of the expulsion force of the conductor a safety vent function of the conductor is set.
16. The electrical device according to claim 1, wherein an expulsion force of the conductor and a safety vent function of the conductor is set by at least one of the following measurements: a thickness of a glassing; using different ones of a plurality of glass materials; a different bubble content in a glass; a structured glass surface based on a shape of a glass part prior to sealing; a structured glass surface based on a shape of a glass part during sealing; a structured glass surface through a laser treatment after sealing; a plurality of notches or a plurality of tapers in the glass material, on one or both sides of the housing; a plurality of notches or a plurality of tapers in at least one of the conductor, the housing, the housing part, and a base body of the housing.
17. The electrical device according to claim 1, wherein the electrical device is an electrical storage device or a sensor housing.
18. The electrical device according to claim 1, wherein the electrical device is a microbattery or a condensator.
19. A method to produce an electrical device, the method comprising the steps of: providing that the electrical device includes a feedthrough and a housing part, the housing part including at least one opening, the at least one opening receiving a conductive material or a conductor in a glass material or a glass-ceramic material, the housing part being a sheet metal part having a material thickness or a thickness D.sub.1; introducing the at least one opening into the sheet metal part; pressing outside a region around the at least one opening down to a thickness D.sub.2; inserting the conductor in the glass material or the glass-ceramic material into the at least one opening; and heating the sheet metal part with a material inserted into the at least one opening, so that a compression seal of the conductor in the glass material or the glass-ceramic material is performed.
20. A method to produce an electrical device, the method comprising the steps of: providing that the electrical device includes a feedthrough and a housing part, the housing part including at least one opening, the at least one opening receiving a conductive material or a conductor in a glass material or a glass-ceramic material, the housing part being a sheet metal part having a material thickness or a thickness D.sub.2; introducing the at least one opening into the sheet metal part; drawing up a collar around the at least one opening by way of reshaping or providing a collar around the at least one opening with at least one of an indentation and a protrusion; inserting the conductor in the glass material or the glass-ceramic material into the at least one opening with the collar; and heating the sheet metal part with a material inserted into the at least one opening, so that a compression seal of the conductor in the glass material or the glass-ceramic material is performed.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0296] The above-mentioned and other features and advantages of this invention, and the manner of attaining them, will become more apparent and the invention will be better understood by reference to the following description of embodiments of the invention taken in conjunction with the accompanying drawings, wherein:
[0297]
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[0299]
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[0310] Corresponding reference characters indicate corresponding parts throughout the several views. The exemplification set out herein illustrate embodiments of the invention, and such exemplifications are not to be construed as limiting the scope of the invention in any manner.
DETAILED DESCRIPTION OF THE INVENTION
[0311] In
[0312] In
[0313] The housing part consists optionally of a Duplex high grade steel with a coefficient of expansion of approximately 15.Math.10.sup.−6 1/K or of an austenitic material with a coefficient of expansion of approximately 18.Math.10.sup.−6 1/K. With the illustrated embodiment of a housing or sheet metal part, a compression seal is provided even with a very thin sheet metal wall thickness and a seal length of only 0.6 mm. Despite the thin sheet thickness of only 0.6 mm, the ring with thickness D.sub.1 surrounding the opening provides sufficient prestress for the compression seal.
[0314] The connection to the remaining housing part of a battery housing is made in the region of the thin sheet metal part with thickness D.sub.2 by a protrusion 7 inserted into the thin sheet metal part, for example by way of a welded joint.
[0315]
[0316] An additional embodiment may provide that thickness D.sub.2 corresponds with thickness D.sub.1.
[0317] Instead of the sealing ring as shown in
[0318] The advantage of the method according to
[0319] Due to the different coefficient of thermal expansion α.sub.3 of the sheet metal part, which is significantly higher than that of the conductor or the glass or glass material, raised collar 40 with bulges 44 as shown in
[0320] Compared to massive plates, the version according to the present invention is characterized by a very thin wall thickness D.sub.2, according to
[0321]
[0322] The housing part, optionally the sheet metal part is in particular a part of a housing of an electrical storage device, in particular a battery cover. Laser welding of the illustrated housing part 1 to the rest of the housing occurs at tip 302 of flexible flange 380. In the region of tip 302, the thickness of the flange is weakened and is only 0.15 mm instead of, for example, 0.2 mm for the sheet metal part. Flange 380 of the housing part with opening or respectively feedthrough, which is weakened in the region of tip 302, can be connected directly with a remaining housing of the electrical storage device, resulting in the electrical storage device. Due to laser welding, the entire component, including the glass or glass ceramic material, is heated. In feedthroughs without compression seals, the feedthrough, in other words the glass and/or glass ceramic material, could come loose, and the feedthrough would leak. This is avoided in a compression seal. The housing of the storage device includes a housing part with opening or respectively a feedthrough according to the present invention. Since the feedthrough or respectively the housing part with the opening is very compact due to the very thin material thickness D.sub.2 of only 0.1 mm to 1 mm of the housing part or respectively the battery cover, a very compact storage device, in particular a microbattery can be provided when such a sheet metal part is installed as part of a feedthrough in a battery housing, for example by welding in the area of the tip 302 of the flexible flange to the rest of the housing of the storage device.
[0323]
[0324]
[0325] In order to provide such a compression seal, especially with steel as material, a wall thickness D.sub.Wall would be necessary over the entire seal length EL, as shown in
[0326] Surprisingly, it has been shown that when using an austenitic high grade steel material with a thermal coefficient of expansion α in range of 16 to 18.Math.10.sup.−6 K.sup.−1 or a Duplex high grade steel material with a thermal coefficient of expansion α in the range of 13 to 14.Math.10.sup.−6 K.sup.−1, it is possible to provide a secure compression seal with sufficient prestress force if a pressure is not applied over the entire seal length EL as shown in
[0327] For a compression seal with a design with flex-flange 1380 according to
[0328] With the selection of the various ring materials or respectively materials for the flex-flange into which sealing occurs, the expulsion force of the pin or conductor can be influenced by the different glass pre-stresses which act via the glass also upon the pin or conductor. This influence can be used to set a safety vent function of the pin or conductor, in other words, opening of the battery in the event of battery overpressure in the case of damage.
[0329] Additional control possibilities to influence the opening force of the sealed in pin or conductor, would be to change the thickness of the seal, use of different glass materials, use of glass materials with different bubble content in the glass, structuring of the glass surface through the shape of the glass part prior to sealing, structuring of the glass surface through the shape of the glass part during sealing, structuring of the glass surface through laser treatment after sealing. Structuring of the glass surface can occur, for example, through introduction of one or several notches and/or taper.
[0330] Such a safety vent function can also be achieved by notches and/or tapers of the sealed-in pin and/or the base body. The aforementioned measures can be carried out individually or in combination. The introduction of structuring, especially of notches and/or tapers can occur on one side of the housing part or base body with a top and bottom side in the glass, housing part and/or conductor, or on both sides, in other words on the top side as well as the bottom side, that is on both sides.
[0331] The advantage of structuring the glass material for a safety vent function is, that the glass as a formed body is precisely dimensioned, so that the trigger point of the safety vent function can be regulated very precisely. It is optional, if for the safety vent function a groove is introduced into the glass material by way of laser. It is then possible, independently of the glass density and/or thickness of the base body, therefore of the ring thickness, to specifically set an expulsion force for the conductor and thus the trigger point.
[0332] The ejection force or expulsion force for the conductor can also be influenced by the length of the seal and/or the formation of menisci.
[0333] With the aid of the safety vent function of the conductor, it is possible in particular to set an opening of a storage device, in particular a battery in the event of overpressure in case of damage.
[0334] In addition to the previously described measures, the expulsion force and thus the safety vent function of the conductor can be adjusted through one or several of the measures described below:
[0335] Thickness of seal;
[0336] Use of different glass materials;
[0337] Different bubble content in glass;
[0338] A structured glass surface through the shape of the glass part prior to sealing;
[0339] A structured glass surface through the shape of the glass part during sealing;
[0340] A structured glass surface through laser treatment after sealing;
[0341] Notches or tapers in glass material, on one or both sides;
[0342] Length of seal and formation of menisci.
[0343]
[0344] Due to the compact feedthrough the height of the entire microbattery is 5 mm at most, optionally no more than 3 mm, in particular in the range of 1 mm-5 mm. The dimensions in the region of the sheet metal part as a part of the feedthrough with flexible flange according to
[0345] Whereas
[0346]
[0347]
[0348] In contrast,
[0349] The feedthrough according to the present invention is used in particular for housings of electrical storage devices, in particular batteries or capacitors. With very flat feedthroughs according to the present invention for an electrical storage device, an electrical storage device can be provided having a maximum height of 5 mm.
[0350] By compression sealing the conductor into the glass material a hermetically sealed feedthrough is provided.
[0351] In particular, in the use of a flex-flange design in a compression seal a greater pin or conductor contact pressure is achieved, in particular when using Duplex high grade steel or austenitic steel. The flex-flange design as a compression seal is moreover mechanically more reliable and displays greater expulsion forces for the sealed-in conductor than conventional seals.
[0352] While this invention has been described with respect to at least one embodiment, the present invention can be further modified within the spirit and scope of this disclosure. This application is therefore intended to cover any variations, uses, or adaptations of the invention using its general principles. Further, this application is intended to cover such departures from the present disclosure as come within known or customary practice in the art to which this invention pertains and which fall within the limits of the appended claims.