MICRO-TUBE METAL MATRIX HEAT EXCHANGER AND METHOD OF MANUFACTURE
20230384037 · 2023-11-30
Inventors
Cpc classification
B22F7/064
PERFORMING OPERATIONS; TRANSPORTING
International classification
F28D7/00
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Abstract
A heat exchanger is characterized by having two or more fluid flow circuits, each formed by multiple small cross-section “micro-tubes” contained within a surrounding metal structure, or “metal matrix.” Its function is to efficiently transfer heat from one fluid to another in a highly compact assembly. Most any metal or metal alloy can be considered for the micro-tubes. The micro-tubes, while typically arranged in alternating layers of alternating flow circuits, may be organized in any number of arrangements including co-linear and at cross angles to provide for co-flow, counter flow and cross flow. The metal matrix, is provided in one embodiment by a metal or metal alloy powder consolidated in a hot isostatic pressing (HIP) process. This process also joins the tubes together and to the matrix itself, producing a monolithic structure.
Claims
1. A method for forming a heat exchanger for transferring heat between two separate fluids, the method including the steps of: arranging a plurality of first tubes formed of a first material adjacent to a plurality of second tubes formed of a second material, and with interstices between the plurality of first tubes and the plurality of second tubes; at least partially filling the interstices of said arranging step with a metal powder formed of a third material, the third material different from at least the first material; at least partially filling at least some of the plurality of first tubes and/or the plurality of second tubes with a removable support media; and raising a combination of the plurality of first tubes, the plurality of second tubes, and the metal powder up to a sintering temperature for the third material, to sinter the metal powder into a metal matrix between the plurality of first tubes and the plurality of second tubes.
2. The method of claim 1 wherein said at least partially filling step includes the media having a melting point higher than the sintering temperature.
3. The method of claim 1 including the further step of removing the media after said raising step.
4. The method of claim 1 wherein said heating step occurs under pressure greater than atmospheric pressure.
5. The method of claim 4 wherein said heating step occurs within a hot isostatic press.
6. The method of claim 5 wherein the first material and the second material of said arranging step are different from each other.
7. The method of claim 5 wherein the first material and the second material of said arranging step are the same.
8. The method of claim 1 wherein said arranging step includes the first material forming the plurality of first tubes having a melting point higher than the temperature of said raising step.
9. The method of claim 1 wherein said arranging step includes the plurality of first tubes having a circular cross-section.
10. The method of claim 1 wherein said arranging step includes the plurality of first tubes and the plurality of second tubes being arranged with elongate central axes thereof parallel to each other for at least a portion of a length of the plurality of first tubes and the plurality of second tubes.
11. The method of claim 10 wherein said arranging step includes the plurality of first tubes and the plurality of second tubes being arranged in planar layers which alternate with each other.
12. The method of claim 11 wherein said arranging step includes the plurality of first tubes and the plurality of second tubes being arranged in a hexagonal close packed arrangement.
13. The method of claim 1 wherein the plurality of first tubes and the plurality of second tubes of said arranging step are arranged in a counter-flow relationship within the heat exchanger.
14. The method of claim 1 wherein said first set of tubes and said second set of tubes of said arranging step are arranged in a cross-flow relationship within the heat exchanger.
15. The method of claim 1 wherein at least the plurality of first tubes of said arranging step include protuberances on an inside surface of the plurality of first tubes, said protuberances enhancing a surface area of said inside surface of the plurality of first tubes relative to a plain cylindrical inside surface.
16. The method of claim 1 wherein said arranging step includes the heat exchanger having two pairs of opposing faces including two opposing side faces and two opposing end faces, said opposing side faces supporting opposing ends of the plurality of first tubes, said opposing end faces supporting opposing ends of the plurality of second tubes, the plurality of first tubes having central portions thereof extending parallel with central portions of the plurality of second tubes.
17. The method of claim 16 wherein the plurality of first tubes of said arranging step includes said central portions thereof extending in a direction parallel to a plane of said lateral faces, the plurality of first tubes including inlet portions thereof and outlet portions thereof between said central portions and said lateral faces which are oriented perpendicular to a plane of said lateral faces.
18. The method of claim 16 wherein the plurality of first tubes of said arranging step have at least portions thereof each including a matching series of regularly spaced bends between ends of each of the plurality of first tubes; and wherein the plurality of second tubes of said arranging step have at least portions thereof each including a matching series of regularly spaced bends between ends of each of the plurality of second tubes, the plurality of first tubes and the plurality of second tubes having a similar form to maintain a parallel relationship along at least portions thereof which include said series of regularly spaced bends therein.
19. The method of claim 18 wherein said regularly spaced bends are spaced from each other by linear sections such that the plurality of first tubes and the plurality of second tubes have a zig-zag form over portions thereof.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DESCRIPTION OF THE PREFERRED EMBODIMENT
[0057] Referring to the drawings, wherein like reference numerals represent like parts throughout the various drawing figures, reference numeral 10 (
[0058] In essence, and with particular reference to
[0059] To form the heat exchanger 10, in one embodiment, first tubes are arranged in a first layer 25, followed by second tubes 50 within a layer 45. Another layer 25 of first tubes 30 is then provided, followed by another layer 45 of second tubes 50. This process is repeated until a full array 100 of tubes 30, 50 have been provided. Space between the tubes 30, 50 is filled with metal powder 62 to fully embed the tubes 30, 50, except for at ends thereof. The assembly is then placed within a hot isostatic press (or other heat and/or temperature applying equipment) and the powder 62 is sintered or otherwise solidified into a solid matrix 60 within which the array 100 of tubes 30, 50 are embedded. Finally, manifolds 70, 72, 74, 76 are placed over ends of the tubes 30, 50 from similar circuits 20, 40 for supply and removal of fluids passing through the heat exchanger 10.
[0060] The novel HX of the present invention is described as a micro-tube metal matrix heat exchanger, a completed version of which is shown in
[0061] Although similar in outer appearance to other compact heat exchangers such as PCHEs/CPHXs, there are significant differences in the design and layout of the heat exchanger 10 internal passages as illustrated by
[0062] The layouts of
[0063] In the heat exchanger 10, primary structural integrity is provided by the tube 30, 50 walls 32, 52, with secondary structure provided by the metal matrix 60, intrinsically producing a more robust design than that available from the planer diffusion bonded PCHE/CPHX D, due to redundancy. The HIP processing of the heat exchanger 10 bonds the tubes 30, 50 and matrix 60 together, to produce a monolithic structure.
[0064] As mentioned, the tubes from which the heat exchanger 10 are produced are commercially available as either fractional or hypodermic tubing 30, 50. While both welded and seamless extruded tubing are available, seamless is the preferred embodiment from a structural standpoint, but with the supporting matrix 60, welded tubing 30, 50 will be acceptable for certain applications. Stainless steel, nickel based alloys and even refractory alloys are available in the sizes and wall 32, 52 thicknesses of interest and custom materials are readily produced. Tube 30, 50 configurations can also be varied to enhance heat transfer. Along with the wavy tubes 12 previously described, tubes 30, 50 can have internal protuberances and/or be twisted or otherwise configured to enhance heat transfer while minimizing pressure drop. Internal protuberances can be formed by simply dimpling the tube 30, 50 from the outside.
[0065] With the heat exchanger 10 construction, it is possible to mix materials to provide the optimal selection for corrosion and thermal compatibility and cost effectiveness with the respective circuit 20, 40 fluids at desired service temperatures. For example, for a fluoride molten salt HX that is coupled with H.sub.2O (Rankine cycle) or sCO.sub.2 (Brayton cycle) at temperatures in excess of 700° C., a high nickel alloy tube 30, 50 can be used on the salt circuit while lower cost stainless steel tubes 50, 30 can be applied to the opposite circuit, all contained within a low-cost stainless steel matrix 60. A significant advantage when compared to a typical PCHE/CPHX D that would require fabrication entirely from the high cost material. For another example, a type of molten salt reactor that utilizes two types of salts, e.g. fuel salts and chloride/fluoride salts, as a means of transferring heat from the reactor to secondary heat exchanger would inherently require two different types of corrosion resistant materials to combat the differing corrosion issues associated with the two types of salts.
[0066] An additional benefit of the heat exchanger 10 technology of this invention lies in the tolerance available from the use of tubing 30, 50 to form the passageways. The inside diameter of the micro-tubing used, in the sizes of interest, are expected to vary ˜+/−0.002″ or less. For an equivalent sized passage in a PCHE D or CPHX, the variation would be approximately double this amount. This tolerance control leads to a lower variation in pressure drop and improved performance.
[0067] The process for producing the matrix 60 is well-known, typically referred to as Powder Metallurgy—Hot Isostatic Pressing or PM-HIP. This process is used to make powder metallurgy billets and near-net components. Considerable interest and effort has been expended by the nuclear industry to investigate and allow PM-HIP components for pressure containing devices such as valve bodies and pump housings. The aerospace industry has also investigated and utilizes the process. As mentioned, the matrix 60 can be selected from any number of low cost alloys compatible with the process and application but it can also be a material such as copper or other high conductivity material to enhance heat transfer.
[0068] While a fully densified matrix 60 has been discussed so far, a compliant matrix 60 is also possible. One method to produce this would be low temperature sintering. This process would leave voids in the matrix 60 that would reduce its stiffness and aid compliance if required for the desired application.
[0069] Heat exchanger 10 core (
[0070] In summary, the multiple attributes of the heat exchanger 10 make it ideal for cost-effective, high temperature and corrosion resistant heat exchangers for next generation applications and existing applications requiring high performance at low cost. The approach makes efficient use of dedicated materials to address corrosion and cost issues while utilizing available technologies and manufacturing processes.
[0071] More specifically, and with particular reference to
[0072] Each of the first tubes 30 within the layer 25 extend from an inlet end 22 to an outlet end 24. Similarly, each of the second tubes 50 within the layer 45 including an entry 42 opposite an exit 44. The layers 25, 45 provide portions of separate circuits 20, 40 passing through the heat exchanger 10. These ends 22, 24 and entry/exit 42, 44 are grouped together at locations on the heat exchanger 10 separate from other groupings, so that manifolds 70, 72, 74, 76 can most conveniently be attached to the heat exchanger 10.
[0073] While in this one embodiment (
[0074] With particular reference to
[0075] Which particular reference to
[0076] Each of the first tubes 30 is made up of walls 32 having a wall thickness defined by a distance between an inner surface 34 and an outer surface 36. Inner surfaces 34 define that portion of the first tube 30 which are in direct contact with fluids passing through the tubes 30 of circuit A 40. The outer surface 36 comes into contact with second tubes 50 as well as with other first tubes 30 in typical embodiments, and into contact with the metal matrix 60 which fills gaps between the tubes 30, 50.
[0077] Thickness of these walls 32 can be made thinner than might otherwise be the case to handle pressures of fluids passing therethrough, because the walls 32 are supported on an exterior side thereof by the matrix 60, as well as by adjacent tubes 30, 50. Furthermore, thinner walls can save on exotic material costs which might be utilized to handle challenging fluid characteristics including corrosiveness, and extremes of temperature and pressure, when the heat exchanger 10 is operating as intended, or when experiencing off design states of operation.
[0078] While each of the first tubes 30 are shown with a circular cross-section, these first tubes 30 could alternatively have some other cross-section, such as a square cross-section or other cross-sectional form. In one embodiment, protuberances 35 extend inwardly from the inner surface 34 of the walls 32. Such protuberances can promote turbulence and improve heat transfer effectiveness. In one embodiment, such protuberances 35 are formed by forming dimples 37 on the outer surface 36, and with the walls 32 being sufficiently thin that the dimples 37 extend through the walls 32 to leave the protuberances 35 on the inner surface 34.
[0079] Similar to the first tubes 30, the second tubes 50 also include walls 52 bounded by an inner surface 54 opposite an outer surface 56, and with optional protuberances 55 and/or dimples 57 thereon. Other characteristics of the second tubes 50 can vary in a manner similar to that described above with respect the first tubes 30. Typically, the second tubes 50 are formed from a different material than that from which the first tubes 30 are formed. In one embodiment, one of the fluids passing through the heat exchanger 10 is non-corrosive, or less corrosive, or corrosive in a different way than the tubes 30 of the alternate circuit within heat exchanger 10. The tubes 50 can thus be optimized for the fluid they are containing, and to minimize cost. In one embodiment, the second tubes 50 can be formed of a similar material from which the matrix 60 is formed. As another alternative, the first tubes 30 and second tubes 50 can be formed of a common material which is different from that of the metal matrix 60.
[0080] While the tubes 30, 50 have been described as being within two circuits 20, 40, it is conceivable that more than two circuits 20, 40 might be provided in an alternative heat exchanger. For instance, a heat exchanger might be configured which exchanges heat between three different fluids passing through three different circuits, while each of the different circuits could be made of tubes formed of similar or different materials to the materials forming the other tubes of the other circuits and providing the matrix 60.
[0081] With particular reference to
[0082] With particular reference to
[0083] The heat exchanger 10 can then be removed from the press. Finally, ends of the first tubes 30 and second tubes 50 within the two circuits 20, 40 can be ground if necessary or otherwise cut to final size (if needed), and manifolds can be added. In particular, the first inlet manifold 70 can overlay inlet end 22 of circuit A 20. A first outlet manifold 72 can be placed over the outlet end 24 of tubes 30 of circuit A 20. A second inlet manifold 74 can be placed over entry end 42 of second tubes 50 within circuit B 40. A second outlet manifold 76 can be placed over exit 44 ends of the second tubes 50 within circuit B 40. The manifolds 70, 72, 74, 76 facilitate flow along the various circuits 20, 40 including circuit A flow along arrow A and circuit B flow along arrow B. While these arrows generally illustrate counterflow, other forms of flow could be provided by rearranging the tubes 30, 40 within the heat exchanger 10 or adjacent plumbing.
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[0085] As an option when manufacturing the heat exchanger 10, the tubes 30, 50 (at least some of them) can be at least partially filled with support media. In one embodiment, the media is in the form of small pellets sized small enough that they can substantially fill interiors of the tubes 30, 50. Filling of the tubes 30, 50 with media allows for the HIP process to occur without deforming the tubes, 30, 50, especially by collapsing the tubes 30, 50 due to the pressure associated with the HIP process. Other related processes which involve pressure and/or heat could similarly minimize tube 30, 50 deformation by placing the media into the tubes, 30, 50. The media is typically in the form of beads of microscopic or near microscopic size. At a minimum, the media is a form of beads that are at least an order of magnitude smaller than a diameter of the tubes 30, 50.
[0086] The media is preferably formed of a material which can withstand high temperatures and high pressures without significant deformation. As one example, alumina ceramic beads of about 10 micron average size can be used as the media. A shape of the media in one embodiment is spherical.
[0087] With reference to
[0088] While it is generally desirable that the media does not collapse at all under pressures applied by the HIP or other process, some deformation of the media could occur, provided the media can still be removed after the matrix material has been sintered from a powder into a more solid form. While it is also generally desirable that the media does not melt under the temperatures associated with the HIP or other process to solidify the matrix, the media could, in at least one embodiment, melt into a liquid provided that the ends of the tubes 30, 50 are plugged to avoid such liquid escaping in an appreciable amount, or the process would need to be sufficiently rapid that the application of pressure would cease before an appreciable amount of such liquid escapes from the tubes 30, 50.
[0089] When such support media is utilized inside of the tubes 30, 50, a final step involves removing the media, typically before manifolds are added to the ends of the tubes 30, 50. Options for such a removal step can include application of suction, application of pressurized air, utilization of at least one elongate fiber placed in the end of the tube 30, 50 to push out the media, utilizing gravity, vibration and/or other appropriate media removal techniques (alone or in combination).
[0090] In an alternative embodiment, the media can be selected from a material which does deform slightly under pressure, or the media could less than entirely fill at least some of the tubes 30, 50 and the pressure associated with the HIP or other process would cause small amounts of tube 30, 50 deformation. Such small amounts of deformation could have the beneficial effect of roughening interior surfaces of the tubes 30, 50 to enhance heat transfer therealong, and could also facilitate some degree of compaction of the tubes 30, 50 together, which, in turn, could cause the heat exchanger 10 to have a more compact volume after completion of manufacture.
[0091] Utilizing the media also can beneficially allow for wall thicknesses of the tubes 30, 50 to be reduced to thicknesses less than would otherwise be able to withstand the pressure associated with the HIP or other matrix solidification process, so the thicknesses of the tubes 30, 50 can be optimized beyond what would otherwise be possible. Thus, in one embodiment, wall thicknesses for the tubes 30 and/or tubes 50 are less than a thickness which could withstand the pressure associated with the HIP process, without the presence of the media within the tubes 30, 50. One example pressure for one HIP process is about 15,000 psi (or greater).
[0092] This disclosure is provided to reveal a preferred embodiment of the invention and a best mode for practicing the invention. Having thus described the invention in this way, it should be apparent that various different modifications can be made to the preferred embodiment without departing from the scope and spirit of this invention disclosure. When embodiments are referred to as “exemplary” or “preferred” this term is meant to indicate one example of the invention, and does not exclude other possible embodiments. When structures are identified as a means to perform a function, the identification is intended to include all structures which can perform the function specified. When structures of this invention are identified as being coupled together, such language should be interpreted broadly to include the structures being coupled directly together or coupled together through intervening structures. Such coupling could be permanent or temporary and either in a rigid fashion or in a fashion which allows pivoting, sliding or other relative motion while still providing some form of attachment, unless specifically restricted.