XRF ANALYZER WITH IMPROVED RESOLUTION BY USING MICRO-RESET
20220342090 · 2022-10-27
Inventors
Cpc classification
G01N23/00
PHYSICS
G01N23/223
PHYSICS
International classification
G01N23/223
PHYSICS
G01T1/17
PHYSICS
Abstract
Disclosed is an electronic system for resetting the voltage of a charge-sensitive pre-amplifier having input from an X-ray detector and output to an ADC. The pre-amplifier gain is increased so that the RMS ADC noise is less than 1% of a representative digitized X-ray signal. The reset logic is configured to avoid loss of X-ray counts and to prevent the pre-amplifier output being outside the allowable input range of the ADC. Reset is initiated when the pre-amplifier output rises above an upper level, which is below the maximum allowable ADC input. Reset is also initiated when a pile-up event is detected, provided that such reset will not cause the pre-amplifier output to fall below the minimum allowable ADC input. At each reset a known amount of charge is removed from the pre-amplifier, and the reset time is continuously adjusted to ensure that the charge amount does not drift.
Claims
1. An X-ray detector reset control circuit used in an X-ray analytical instrument, the instrument is configured to induce and analyze a series of events of induced X-rays, the -ray detector reset control circuit comprising: an X-ray detector configured to detect the events of induced X-rays with energy E ke V and send detector analog voltage response signals indicative of the events of X-rays; a charge-sensitive preamplifier connected to the detector and configured to amplify the response signals and produce amplified signals; an analog-to-digital converter (ADC) for providing a digitization of the amplified signals, the ADC having an ADC output level and producing a series of digitized signal values corresponding to the events of X-rays, the series of digitized signal values causing a stair-like increase of the ADC output level; and a micro-reset unit configured to receive signals from the ADC and trigger a reset for a reset time t.sub.R to decrease the ADC output level with a charge reset drop and vary the reset time t.sub.R according to the ADC output level.
2. The X-ray detector reset control circuit of claim 1, wherein the micro-reset unit is configured to trigger the reset according to two or more reset logic criteria including a) an upper level reset criterion, for which the ADC output level has surpassed an upper level threshold, and b) a pile-up reset criterion, for which two of the events of X-rays are within a predetermined time with or without surpassing the upper level threshold.
3. The X-ray detector reset control circuit of claim 2, including: a pulse indicator producing a fast pulse timing signal indicative of each of the events of X-rays; and wherein the micro-reset unit includes a fast logic unit configured to receive the ADC output level and the fast pulse timing signal as input and produce an upper level reset signal and a pile-up reset enable signal as output to detect the pile-up reset criterion.
4. The X-ray detector reset control circuit of claim 3, wherein: a) the upper level reset criterion includes the ADC output level surpassing the upper level threshold and a predetermined peaking time t.sub.p elapsing since a most recent of the fast pulse timing signals; and b) the pile-up reset criterion includes the corresponding fast pulse timing signals of two of the events of X-rays being within the peaking time t.sub.p.
5. The X-ray detector reset control circuit of claim 3, wherein the micro-reset unit is configured to: a) receive the digitized signal values with the corresponding fast pulse timing signals, b) wait until the ADC output level has surpassed an upper level threshold, c) wait until a peaking time t.sub.p has elapsed since a most recent of the fast pulse timing signals, wherein the peaking time t.sub.p is indicative of a time span required to establish the ADC output level after the corresponding fast pulse timing signal, and d) triggering a reset.
6. The X-ray detector reset control circuit of claim 3, wherein the micro-reset unit is configured to: a) receive a first of the signal values with a first of the corresponding pulse timing signals, b) determine whether a second of the signal values with a second of the corresponding pulse timing signals is received before the peaking time t.sub.p has elapsed since the first of the pulse timing signals, c) determine whether the ADC output level is above a lower level threshold, and d) trigger a reset when b) and c) are true.
7. The X-ray detector reset control circuit of claim 1, wherein the charge reset drop is a variable value depending on the value of the ADC output level.
8. The X-ray detector reset control circuit of claim 1, wherein the charge reset drop is a predetermined reset drop determined by the reset time t.sub.R which is an input to the micro-reset unit.
9. The X-ray detector reset control circuit of claim 8, further including a reset time adjustment unit which receives digitized signal values from the ADC indicative of an actual charge reset drop for each reset, wherein the reset time adjustment unit is configured to provide an adjusted reset time to replace the reset time t.sub.R in order to increase or decrease the actual charge reset drop during the reset to be substantially equal to the predetermined charge reset drop.
10. The X-ray detector reset control circuit of claim 1, wherein the decision module further includes a lower level threshold, and is configured to ignore the reset decision when the ADC output level is lower than the lower level threshold.
11. An automated method of measurement of X-rays using an X-ray analytical instrument, the method comprising: generating analog voltage response signals associated with detected X-ray events; digitizing the generated analog voltage response signals to a series of digitized signal values corresponding to the detected X-ray events; resetting the series of digitized signal values for a reset time using a first signal reset drop when the series of digitized signal values increases to a predetermined upper signal level; varying the reset time according to the digitized signal values; and resetting the series of digitized signal values using a second signal reset drop when detecting an X-ray pile-up event that includes two of the detected X-ray events occurring within a predetermined X-ray pile-up event detection time, wherein the second signal reset drop is less than the first signal reset drop.
12. The method of claim 11, wherein the generating the analog voltage response signals includes generating the analog voltage response signals using a pre-amplifier; and wherein the resetting the series of digitized values includes resetting the pre-amplifier using a first reset time duration when the series of digitized signal values increases to the predetermined upper signal level, and resetting the pre-amplifier using a second reset time duration shorter than the first reset time duration when detecting the X-ray pile-up event.
13. The method of claim 12, including: converting the analog voltage response signals to the series of digitized signal values using an analog-to-digital converter (ADC) circuit; determining one or both of a first change in the digitized signal values resulting from the first reset time and a second change in the digitized signal values resulting from the second reset time; and changing one or both of the first reset time and the second reset time based on the determined one or both of the first change and the second change in the digitized signal values.
14. The method of claim 12, wherein resetting the pre-amplifier using the second reset time includes resetting the pre-amplifier using a second reset time based on a digitized signal value when detecting the X-ray pile-up event,
15. The method of claim 11, wherein the digitizing the generated analog voltage response signals includes converting the analog voltage response signals using an analog-to-digital converter (ADC) circuit having a least significant bit (LSB) signal value; and wherein the resetting the series of digitized signals includes decreasing the output of the ADC circuit a first number of LSB signal values when the series of digitized signals increases to the predetermined upper signal level, and decreasing the output of the ADC circuit a second number of LSB signal values less than the first number of LSB signal values when detecting the X-ray pile-up event.
16. The method of claim 11, including: generating a pulse timing signal in response to a detected X-ray event; and wherein the detecting the X-ray pile-up event includes detecting two pulse timing signals occurring within the predetermined X-ray pile-up event detection time.
17. The method of claim 11, wherein the digitizing the generated analog voltage response signals includes converting the analog voltage response signals using an analog-to-digital converter (ADC) circuit; and wherein the detecting the X-ray pile-up event includes detecting two X-ray events within a time duration to establish an ADC circuit output value.
18. The method of claim 17, wherein the resetting the series of digitized signal values includes resetting the series of digitized signal values using the first signal reset drop when the series of digitized signals increases to the predetermined upper signal level and the time duration to establish the ADC circuit output value has elapsed since a detected X-ray event.
19. The method of claim 11, wherein the second signal reset drop is a fixed predetermined value.
20. The method of claim 19, further including not resetting the series of digitized signal values using the second signal reset drop when detecting the X-ray pile-up event and a current digitized signal value of the series of digitized signal values is less than a predetermined lower level signal value.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0017]
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DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS
[0027] Note that in the description below, the term “voltage” is used to designate analog signals, and the term “value” is used to designate digital quantities. Note also that in the description and the drawings a symbol without angle brackets is used to denote an analog quantity, and a symbol with angle brackets is used to denote a digital quantity. For example, the analog value of a charge is Q, and its digitized equivalent is <Q>. In addition, unprimed numerals, such as 6, denote components related to the present disclosure, whereas primed numerals, such as 6′, denote components of existing practice. Numerals preceded by “S”, such as S-16, denote a signal line.
[0028] Referring to
[0029] Optionally, and not shown in
[0030] Reference is now made to
[0031] It should be noted that unlike systems in existing practice where the gain of pre-amplifier 6 is set such that the average step height response to an incident X-ray corresponds to about 100 to 200 LSBs, the novel design of the present disclosure enables the gain of pre-amplifier 6 to be set at least ten times higher, and preferably 15 to 30 times higher, so that the average step height response to an incident X-ray corresponds to about 1,500 to 6,000 LSBs. Whereas, in existing systems, typically 300-600 incident X-rays will cause ADC output S-10 to rise sufficiently so that reset is required, in the system of the present disclosure reset occurs on average after only 10-100 incident X-rays.
[0032] Note that, in common with existing systems, the RMS noise of ADC 10 is about 3 LSBs RMS (equivalent to about 20 LSBs peak-to-peak noise). However, in the system of the present disclosure the RMS noise typically represents only 0.05%-0.2% of the signal, and is always less than 1% of the signal, compared to existing systems where the ADC RMS noise is several percent of the signal. In existing practice, the contribution from pre-amplifier noise is usually much smaller than the ADC noise. In the system according to the present disclosure, the pre-amplifier gain may be increased until the pre-amplifier noise is equal to or slightly less than the ADC noise.
[0033] In XRF systems the characteristic X-ray emission of iron, having an energy of about 6.4 keV, is often used as a calibration standard. In the present system, the gain of pre-amplifier 6 may be set so that the step height response of ADC output S-10 due to an incident iron X-ray corresponds to at least 1,500 LSBs, so that the RMS noise of ADC 10 at about 3 LSBs typically corresponds to 0.2% or less of the iron X-ray signal, and is always less than 1% of the iron X-ray signal.
[0034] Increasing the gain of pre-amplifier 6 is an important and novel aspect of the present invention, allowing a significant improvement in energy resolution due to reduction in the relative importance of ADC noise. However, increasing the gain of pre-amplifier 6 means that more frequent resets are required and, therefore, it would be unacceptable to lose X-ray counts at each reset in the same manner as existing systems. Loss of X-rays counts is avoided by a further novel and important aspect of the present invention, which is use of a micro-reset decision module providing a logical framework designed to avoid unnecessary loss of X-ray counts. In this context, “micro-reset” implies that, unlike in existing practice, reset may occur over only a part of the full voltage range of pre-amplifier 6, corresponding to only part of the full bit range of ADC 10.
[0035] Referring again to
[0036] After waiting for peaking time t.sub.p, micro-reset occurs, as shown by a graph falling portion 46, which lasts for a reset time t.sub.R. Reset time t.sub.R has a duration of 20-100 nanoseconds, which is 10 to 50 times shorter than the reset time in existing systems. The duration of reset time t.sub.R is adjusted so that at each micro-reset, a predetermined constant charge amount Q is removed from pre-amplifier 6. A charge reset drop <Q>, the digital equivalent of charge amount Q, is shown in
[0037] Note that, as illustrated in
[0038] A lower ADC level 41 is defined as being above bottom ADC level 40 by the amount of charge reset drop <Q>. Falling portions 46 and 46a result in ADC output S-10 being below lower ADC level 41, but above bottom ADC level 40. Micro-reset in the present system never allows ADC output S-10 to fall to bottom ADC level 40, and therefore there is no dead time after reset due to pre-amplifier output voltage S-6 being out of range. Moreover, because the reset occurs over a small part of the full output range of pre-amplifier 6, there is much less undershoot than in existing systems, and the recovery time is much shorter. On average, undershoot recovery occurs in a time equivalent to one or two times peaking time t.sub.p, and consequently the total dead time after reset is very small.
[0039] The reset condition in which micro-reset decision module 16 performs a reset when ADC output S-10 exceeds upper ADC level 42 is referred to herein as an “upper level reset”, and the associated logic is further described below in connection with
[0040]
[0041] Falling portions 46, 46a and 49 have the same duration, which is reset time t.sub.R, and each results in a reduction of ADC output S-10 by an amount <Q>. However, if an X-ray signal corresponding to an X-ray with energy E arrives during reset time t.sub.R, then the reduction of ADC output S-10 would be equal to
<Qx>=<Q>−<E> (1)
where <Qx> is the measured reduction of ADC output S-10 when an X-ray arrives during the reset, and <E> is the digital representation of X-ray energy E. Thus, because the reduction of ADC output S-10 due to each micro-reset is known and equal to <Q>, X-rays arriving during the reset time are not lost. Their energy may be determined from the relationship
<E>=<Q>−<Qx> (2)
and such X-ray energies may be added to the X-ray spectrum.
[0042] As shown in
[0043]
<Q.sub.1>=<Q.sub.1>(1+k(i−1)) (3)
where <Q.sub.1> is the charge reset drop when ADC output S-10 is within zone i, and k is a constant.
[0044] As shown in
[0045] It should be noted that division into four zones as shown in
[0046] Referring now to
[0047] Fast logic unit 22 receives input from ADC output S-10 and pulse timing signal S-12, and produces more than one, such as two logical output signals as shown, namely an upper level reset signal S-22a and a pile-up reset enable signal S-22b. AND gate 24 receives inputs from pulse timing signal S-12 and pile-up reset enable signal S-22b, and produces a pile-up reset signal S-24 only if both input signals are present. OR gate 26 receives inputs from upper level reset signal S-22a and pile-up reset signal S-24, and produces reset signal S-16 if any one of the two input signals is present. Reset signal S-16 instructs micro-reset circuit 8 to reset output voltage S-6.
[0048] Optionally, in the event that fast logic unit 22 is disabled or otherwise unavailable, such as during initial manufacturer testing of detector 4 and pre-amplifier 6, a comparator 20 is available to perform a reset if required. This is referred to herein as a “backup reset” and the details of its usage are described in connection with
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[0050]
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[0052] If, at step 606, it is determined that ADC output S-10 crossed upper ADC level 42 during a pulse caused by an incident X-ray, then in order to properly measure the energy of that pulse it is necessary to wait until peaking time t.sub.p has elapsed. Waiting commences at step 610, and fast logic unit 22 at step 614 checks pulse timing signal S-12 throughout the wait time to determine whether or not a second pulse arrives. If not, and if at step 616 the wait time since the last pulse has reached peaking time t.sub.p, then a micro-reset is triggered at step 620 by sending upper level reset signal S-22a via OR gate 26 to micro-reset circuit 8. After the micro-reset at step 620 the process loops back to measuring ADC output S-10 at step 602.
[0053] Similarly, if at step 608 it is determined that the most recent pulse ended less than peaking time t.sub.p ago, in order to properly measure the energy of that pulse it is necessary to wait until peaking time t.sub.p has elapsed. As before, waiting commences at step 610, and fast logic unit 22 at step 614 checks pulse timing signal S-12 throughout the wait time to determine whether or not a second pulse arrives. If not, and if at step 616 the wait time since the last pulse has reached peaking time t.sub.p, then a micro-reset is triggered at step 620 by sending upper level reset signal S-22a via OR gate 26 to micro-reset circuit 8. After the micro-reset at step 620 the process loops back to measuring ADC output S-10 at step 602.
[0054] If at step 614 it is determined that a second pulse arrives before the wait for peaking time t.sub.p after arrival of the first pulse has elapsed, then a pile-up event has occurred prior to the upper level reset. Since pile-up reset enable signal S-22b will be high since arrival of the first pulse (see
[0055] It should be noted that the upper level reset logic depicted in
[0056]
[0057] If, at step 712, pulse timing signal S-12 does not indicate that a second pulse has arrived, then at step 714 it is determined whether or not the wait time since the first pulse has reached peaking time t.sub.p. If not, waiting continues at step 710. If peaking time t.sub.p has elapsed, then no pile-up event has occurred, pile-up enable signal S-22b is disabled at step 716 and the process returns to measuring pulse timing signal S-12 at step 702.
[0058] It should be noted that the pile-up reset logic depicted in
[0059]
[0060] Although the present invention has been described in relation to particular embodiments thereof, it can be appreciated that various designs can be conceived based on the teachings of the present disclosure, and all are within the scope of the present disclosure.